WO2012085150A3 - Titano-silico-alumo-phosphat - Google Patents

Titano-silico-alumo-phosphat Download PDF

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Publication number
WO2012085150A3
WO2012085150A3 PCT/EP2011/073686 EP2011073686W WO2012085150A3 WO 2012085150 A3 WO2012085150 A3 WO 2012085150A3 EP 2011073686 W EP2011073686 W EP 2011073686W WO 2012085150 A3 WO2012085150 A3 WO 2012085150A3
Authority
WO
WIPO (PCT)
Prior art keywords
alumo
titano
silico
phosphate
hydrothermal stability
Prior art date
Application number
PCT/EP2011/073686
Other languages
English (en)
French (fr)
Other versions
WO2012085150A4 (de
WO2012085150A2 (de
Inventor
Silke Sauerbeck
Olga Manoylova
Arno Tissler
Martin DIENERSBERGER
Original Assignee
Süd-Chemie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Süd-Chemie AG filed Critical Süd-Chemie AG
Priority to US13/996,030 priority Critical patent/US20130334460A1/en
Priority to JP2013545384A priority patent/JP2014501691A/ja
Priority to EP11819094.1A priority patent/EP2655256A2/de
Priority to CN201180061797.0A priority patent/CN103269977B/zh
Publication of WO2012085150A2 publication Critical patent/WO2012085150A2/de
Publication of WO2012085150A3 publication Critical patent/WO2012085150A3/de
Publication of WO2012085150A4 publication Critical patent/WO2012085150A4/de

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0292—Phosphates of compounds other than those provided for in B01J20/048
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16—Alumino-silicates
    • B01J20/18—Synthetic zeolitic molecular sieves
    • B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3085—Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/34—Regenerating or reactivating
    • B01J20/3408—Regenerating or reactivating of aluminosilicate molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/06—Aluminophosphates containing other elements, e.g. metals, boron
    • C01B37/08—Silicoaluminophosphates [SAPO compounds], e.g. CoSAPO
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/54—Phosphates, e.g. APO or SAPO compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)

Abstract

Die vorliegende Erfindung betrifft ein Titano-Silico-Alumo-Phosphat, das tetraedrisch koordiniertes Titan in der Gerüststruktur enthält, das eine freie Koordinationsstelle für CO aufweist, das mittels einer charakteristischen IR-Bande bei 2192 ± 5 cm-1 nachgewiesen werden kann. Das Titano-Silico-Alumo-Phosphat zeigt aussergewöhnlich hohe hydrothermale Stabilität und weist eine gute Adsorptionskapazität auch bei höheren Temperaturen auf. Aufgrund der hohen hydrothermalen Stabilität kann es durch ein Hydrothermalverfahren ausgehend von einer Synthesegelmischung aus einer Aluminium-, Phosphor-, Silizium- und einer Titanquelle, sowie entsprechenden Templaten erhalten werden.
PCT/EP2011/073686 2010-12-22 2011-12-21 Titano-silico-alumo-phosphat WO2012085150A2 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US13/996,030 US20130334460A1 (en) 2010-12-22 2011-12-21 Titano-silico-alumino-phosphate
JP2013545384A JP2014501691A (ja) 2010-12-22 2011-12-21 チタノシリコアルミノホスフェート
EP11819094.1A EP2655256A2 (de) 2010-12-22 2011-12-21 Titano-silico-alumo-phosphat
CN201180061797.0A CN103269977B (zh) 2010-12-22 2011-12-21 磷酸钛硅铝

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102010055679.3 2010-12-22
DE102010055679A DE102010055679A1 (de) 2010-12-22 2010-12-22 Titano-Silico-Alumo-Phosphat

Publications (3)

Publication Number Publication Date
WO2012085150A2 WO2012085150A2 (de) 2012-06-28
WO2012085150A3 true WO2012085150A3 (de) 2012-09-07
WO2012085150A4 WO2012085150A4 (de) 2012-10-26

Family

ID=45688396

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2011/073686 WO2012085150A2 (de) 2010-12-22 2011-12-21 Titano-silico-alumo-phosphat

Country Status (6)

Country Link
US (1) US20130334460A1 (de)
EP (1) EP2655256A2 (de)
JP (1) JP2014501691A (de)
CN (1) CN103269977B (de)
DE (1) DE102010055679A1 (de)
WO (1) WO2012085150A2 (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9889437B2 (en) 2015-04-15 2018-02-13 Basf Corporation Isomorphously substituted catalyst
US9764313B2 (en) 2014-06-18 2017-09-19 Basf Corporation Molecular sieve catalyst compositions, catalyst composites, systems, and methods
US10850265B2 (en) * 2014-06-18 2020-12-01 Basf Corporation Molecular sieve catalyst compositions, catalytic composites, systems, and methods
CA2952437C (en) * 2014-06-18 2023-08-29 Basf Corporation Molecular sieve catalyst compositions, catalytic composites, systems, and methods
CN105406038A (zh) * 2015-11-03 2016-03-16 山东精工电子科技有限公司 一种溶胶凝胶法合成高容量高循环纳米级磷酸铁锰锂材料
CN108996515A (zh) * 2018-07-28 2018-12-14 瑞声科技（南京）有限公司 一种吸音材料及应用该吸音材料的扬声器箱
CN110040744B (zh) * 2019-04-08 2022-07-01 福建师范大学 一种MeAPSO-34分子筛及其制备方法
CN113120922B (zh) * 2021-06-02 2023-03-10 江西省科学院应用化学研究所 一种纳米片状形貌的La-SAPO-34分子筛的合成方法及应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4880520A (en) * 1984-04-13 1989-11-14 Uop Hydrocarbon conversion process using titanium-aluminum-phosphorus-silicon-oxide molecular sieves as catalyst

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4684617A (en) 1984-04-13 1987-08-04 Union Carbide Corporation Titanium-aluminum-phosphorus-silicon-oxide molecular sieves
US4818739A (en) * 1984-12-18 1989-04-04 Uop Hydrocracking catalysts and processes employing non-zeolitic molecular sieves
CN1011691B (zh) * 1985-04-27 1991-02-20 联合碳化公司 钛-铝-磷-硅-氧化物分子筛的制备方法
TWI234556B (en) * 1997-07-23 2005-06-21 Mitsubishi Gas Chemical Co Catalysts for methanol conversion reactions
JP2001038216A (ja) * 1999-08-04 2001-02-13 Mitsubishi Gas Chem Co Inc 触媒寿命の改善方法
JP4596116B2 (ja) * 2002-05-24 2010-12-08 三菱瓦斯化学株式会社 ８酸素員環細孔を持つ結晶質シリコアルミノリン酸塩モレキュラーシーブ及びその製造方法、並びにそれを触媒とするメチルアミン類の製造方法
EP2022565A1 (de) 2007-07-06 2009-02-11 Casale Chemicals S.A. Verfahren zur Herstellung molekularer Silicoaluminophosphat-Molekularsiebe, Katalysatoren mit besagten Sieben und katalytische Dehydrierungsprozesse mit besagten Katalysatoren
DE102009034850A1 (de) 2009-07-27 2011-02-10 Süd-Chemie AG Verfahren zur Herstellung eines Silico-Alumo-Phosphats

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4880520A (en) * 1984-04-13 1989-11-14 Uop Hydrocarbon conversion process using titanium-aluminum-phosphorus-silicon-oxide molecular sieves as catalyst

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
E GIANOTTI: "The identity of titanium centres in microporous aluminophosphates compared with Ti-MCM-41 mesoporous catalyst and titanosilsesquioxane dimer molecular complex: a spectroscopy study", JOURNAL OF MOLECULAR CATALYSIS A: CHEMICAL, vol. 204-205, 15 September 2003 (2003-09-15), pages 483 - 489, XP055027413, ISSN: 1381-1169, DOI: 10.1016/S1381-1169(03)00330-3 *
JAPPAR N ET AL: "Synthesis and characterization of a new titanium silicoaluminophosphate: TAPSO-37", MICROPOROUS AND MESOPOROUS MATERIALS, ELSEVIER SCIENCE PUBLISHING, NEW YORK, US, vol. 23, no. 3-4, 1 August 1998 (1998-08-01), pages 169 - 178, XP004149539, ISSN: 1387-1811, DOI: 10.1016/S1387-1811(98)00059-6 *

Also Published As

Publication number Publication date
WO2012085150A4 (de) 2012-10-26
DE102010055679A1 (de) 2012-06-28
EP2655256A2 (de) 2013-10-30
JP2014501691A (ja) 2014-01-23
WO2012085150A2 (de) 2012-06-28
CN103269977A (zh) 2013-08-28
US20130334460A1 (en) 2013-12-19
CN103269977B (zh) 2015-04-15

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