WO2012035631A1 - 固体電池及びその再生方法 - Google Patents
固体電池及びその再生方法 Download PDFInfo
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- WO2012035631A1 WO2012035631A1 PCT/JP2010/066031 JP2010066031W WO2012035631A1 WO 2012035631 A1 WO2012035631 A1 WO 2012035631A1 JP 2010066031 W JP2010066031 W JP 2010066031W WO 2012035631 A1 WO2012035631 A1 WO 2012035631A1
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/4242—Regeneration of electrolyte or reactants
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/61—Types of temperature control
- H01M10/615—Heating or keeping warm
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- H—ELECTRICITY
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- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/60—Heating or cooling; Temperature control
- H01M10/65—Means for temperature control structurally associated with the cells
- H01M10/657—Means for temperature control structurally associated with the cells by electric or electromagnetic means
- H01M10/6571—Resistive heaters
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
- H01M50/497—Ionic conductivity
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/26—Selection of materials as electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/60—Other road transportation technologies with climate change mitigation effect
- Y02T10/70—Energy storage systems for electromobility, e.g. batteries
Definitions
- the present invention relates to a solid battery having a solid electrolyte layer and a regeneration method thereof.
- Lithium ion secondary batteries are characterized by higher energy density than other secondary batteries and capable of operating at high voltages. For this reason, it is used as a secondary battery that can be easily reduced in size and weight in information equipment such as a mobile phone, and in recent years, there is an increasing demand for large motive power such as for electric vehicles and hybrid vehicles.
- the lithium ion secondary battery includes a positive electrode layer and a negative electrode layer (a pair of electrode layers) and an electrolyte disposed therebetween, and the electrolyte is composed of, for example, a non-aqueous liquid or solid.
- electrolytic solution a liquid (hereinafter referred to as “electrolytic solution”)
- the electrolytic solution easily penetrates into the positive electrode layer and the negative electrode layer. Therefore, an interface between the active material contained in the positive electrode layer or the negative electrode layer and the electrolytic solution is easily formed, and the performance is easily improved.
- the widely used electrolyte is flammable, it is necessary to mount a system for ensuring safety.
- solid electrolyte (hereinafter referred to as “solid electrolyte”) is nonflammable, the above system can be simplified. Therefore, a lithium ion secondary battery (hereinafter referred to as “solid battery”) having a layer containing a solid electrolyte that is nonflammable has been proposed.
- Patent Document 1 discloses a battery including a positive electrode including a movable alkali metal ion source under charge, an alkali metal negative electrode, and a polymer electrolyte.
- Patent Document 2 includes a positive electrode containing a positive electrode active material capable of inserting and extracting lithium, a negative electrode containing an alloy-based negative electrode active material, and a solid electrolyte containing a polymer or a separator impregnated with the solid electrolyte.
- a solid electrolyte secondary battery including a battery cell and control means for controlling the battery cell at the time of discharge so as to be equal to or higher than the deformable temperature of the polymer is disclosed.
- an object of the present invention is to provide a solid state battery capable of reducing overvoltage and a method for regenerating the same.
- a first aspect of the present invention is a solid electrolyte layer including a negative electrode capable of occluding and releasing alkali metal ions or alkaline earth metal ions, a solid electrolyte having ion conductivity disposed so as to be in contact with the negative electrode, And a method of regenerating a solid battery comprising a positive electrode capable of releasing and occluding alkali metal ions or alkaline earth metal ions that move between the negative electrode and heated to a temperature at which the negative electrode softens, And a step of compressing the negative electrode in a direction intersecting the surface in contact with the solid electrolyte layer.
- alkali metal ion means an ion generated from an alkali metal element such as lithium ion, sodium ion, potassium ion or the like.
- alkaline earth metal ion refers to an ion generated from an alkaline earth metal element such as calcium ion or magnesium ion.
- having ion conductivity means having a property of conducting ions (alkali metal ions or alkaline earth metal ions) moving between the negative electrode and the positive electrode.
- the “temperature at which the negative electrode softens” refers to a temperature at which at least a part of the negative electrode softens while maintaining a solid state. More specifically, the temperature is equal to or higher than the temperature at which the negative electrode starts to soften and lower than the temperature at which the negative electrode becomes completely liquid.
- the negative electrode can occlude and release lithium ions, and the heating temperature is 160 ° C. or higher and lower than 185 ° C.
- a second aspect of the present invention is a solid electrolyte layer comprising a negative electrode capable of occluding and releasing alkali metal ions or alkaline earth metal ions, and a solid electrolyte having ion conductivity disposed so as to be in contact with the negative electrode
- a positive electrode capable of releasing and occluding alkali metal ions or alkaline earth metal ions moving between the negative electrode, a heating means for heating the negative electrode to a temperature at which the negative electrode softens, and a force for bringing the solid electrolyte layer and the negative electrode into close contact with each other A solid state battery.
- the negative electrode can occlude and release lithium ions, and the heating temperature is 160 ° C. or higher and lower than 185 ° C.
- a solid battery having a negative electrode capable of occluding and releasing alkali metal ions or alkaline earth metal ions dendrite is generated in the negative electrode during charging, and dendrite grows when charging and discharging are repeated.
- the negative electrode on which the dendrite has grown is deformed, and the solid state battery having the deformed negative electrode has an increased interface resistance and an increased overvoltage.
- heating is performed in order to soften the negative electrode capable of occluding and releasing alkali metal ions or alkaline earth metal ions, and the softened negative electrode is brought into close contact with the solid electrolyte layer.
- a step of compressing is performed in order to soften the negative electrode capable of occluding and releasing alkali metal ions or alkaline earth metal ions.
- the negative electrode deformed due to the growth of dendrites can be softened to bring the negative electrode and the solid electrolyte layer into close contact with each other, and thereby the surface of the negative electrode in contact with the solid electrolyte layer can be smoothed.
- the contact area between the negative electrode and the solid electrolyte layer can be increased, and as a result, the interface resistance can be reduced and the overvoltage can be reduced. . Therefore, according to the present invention, it is possible to provide a method of regenerating a solid battery that can reduce overvoltage.
- the negative electrode can occlude and release lithium ions, and the heating temperature is 160 ° C. or higher and lower than 185 ° C., so that it is possible to reduce the overvoltage of a solid battery with high energy density.
- a method for regenerating a solid battery can be provided.
- the solid state battery according to the second aspect of the present invention has a heating means for heating the anode capable of occluding and releasing alkali metal ions or alkaline earth metal ions to a temperature at which the anode is softened, and a force for adhering the solid electrolyte layer and the anode. Fastening means to be applied. Therefore, the negative electrode deformed due to the growth of dendrites can be softened, and the negative electrode and the solid electrolyte layer can be brought into close contact with each other, whereby the surface of the negative electrode in contact with the solid electrolyte layer can be smoothed. .
- the contact area between the negative electrode and the solid electrolyte layer can be increased, and as a result, the interface resistance can be reduced and the overvoltage can be reduced. . Therefore, according to the present invention, a solid state battery capable of reducing overvoltage can be provided.
- the negative electrode can occlude and release lithium ions, and the heating temperature is 160 ° C. or higher and lower than 185 ° C., so that the energy density is high and the overvoltage can be easily reduced.
- a solid state battery can be provided.
- FIG. 1 is a diagram for explaining a method for regenerating a solid battery of the present invention (hereinafter sometimes referred to as “method of the present invention”).
- the solid battery 10 solid battery 10a
- the solid battery 10 solid battery 10b
- the subscript a is used as, for example, “solid battery 10a”.
- the subscript b may be added, for example, as "solid battery 10b”.
- the solid battery 10 includes a negative electrode 1 and a positive electrode 2, a solid electrolyte layer 3 sandwiched between the negative electrode 1 and the positive electrode 2, a negative electrode current collector 4 connected to the negative electrode 1, and a positive electrode 2.
- a direction in which the positive electrode current collector 5 connected, the heating means 6 embedded in the negative electrode current collector 4, the negative electrode 1 and the solid electrolyte layer 3 are brought into close contact the solid battery 10 is viewed from the upper end side and the lower end side in FIG.
- Fastening means 7 capable of applying a force in the direction of compression).
- the solid battery 10 is used in a state where the components shown in FIG. 1 are accommodated in an exterior material not shown.
- the negative electrode 1 contains a negative electrode active material capable of occluding and releasing lithium ions
- the positive electrode 2 contains a positive electrode active material capable of occluding and releasing lithium ions.
- the fastening means 7 is in contact with the negative electrode current collector 4 and the positive electrode current collector 5. When the solid battery 10 is used (charge / discharge), lithium ions move between the negative electrode 1 and the positive electrode 2 through the solid electrolyte layer 3.
- the solid battery 10a has lithium at the interface between the negative electrode 1a and the solid electrolyte layer 3.
- Ion conduction resistance interface resistance
- overvoltage tends to increase. Since the performance of the solid battery 10a in which the interfacial resistance is increased and the overvoltage is increased is likely to deteriorate, it is effective to reduce the interface resistance in order to improve the performance of the solid battery 10a.
- FIG. 2 is a charging curve of a solid state battery in which lithium ions move between the negative electrode and the positive electrode.
- the vertical axis in FIG. 2 is the overvoltage [V] of the solid state battery, and the horizontal axis in FIG. 2 is the capacity [mAh].
- the overvoltage gradually increases, and in the result shown in FIG. 2, the change of the overvoltage with the increase in capacity is reduced when the overvoltage is around ⁇ 0.15 V (hereinafter referred to as “overvoltage”).
- the region where the change in overvoltage accompanying the increase in capacity is small is referred to as a “plateau region”.
- the method of the present invention is performed.
- the negative electrode current collector 4 is heated using the heating means 6 to heat the negative electrode 1a in contact with the negative electrode current collector 4 and soften the negative electrode 1a.
- the softening start temperature of lithium is 160 ° C.
- the melting point of lithium is 180.54 ° C.
- the temperature at which solid lithium becomes completely liquid is 185 ° C., for example. Therefore, when the negative electrode 1a is a lithium foil, the heating means 6 is used so that the negative electrode 1a has a temperature of 160 ° C. or higher and lower than 185 ° C., more specifically, for example, the negative electrode 1a has a temperature of 160 ° C. Then, the negative electrode 1a may be softened by heating the negative electrode 1a.
- the force in the direction in which the negative electrode 1a and the solid electrolyte layer 3 are brought into close contact with each other using the fastening means 7 (the force in the direction intersecting the surface of the negative electrode 1a in contact with the solid electrolyte layer 3). Is applied to the softened negative electrode 1a to compress the negative electrode 1a. By compressing the softened negative electrode 1a, the negative electrode 1a and the solid electrolyte layer 3 can be brought into close contact with each other. As a result, the solid having the negative electrode 1b whose surface facing the solid electrolyte layer 3 is smoothed It can be regenerated into the battery 10b. As shown in FIG.
- the entire surface of the negative electrode 1 b facing the solid electrolyte layer 3 is in contact with the solid electrolyte layer 3. Therefore, compared with the solid battery 10a, the lithium ion conduction resistance (interface resistance) at the interface between the negative electrode 1b and the solid electrolyte layer 3 can be reduced, and the overvoltage can be reduced. Further, by smoothing the surface of the negative electrode 1 facing the solid electrolyte layer 3, the solid electrolyte layer 3 is formed by the negative electrode 1a having large irregularities on the surface facing the solid electrolyte layer 3 due to growth of dendrites or the like. It is possible to avoid the situation of being destroyed.
- the adhesion between the negative electrode 1a and the negative electrode current collector 4 can be improved by applying a force in the above direction to the negative electrode 1a using the fastening means 7. Therefore, as compared with the solid battery 10a, it is possible to reduce the electron conduction resistance at the interface between the negative electrode 1b and the negative electrode current collector 4b, and as a result, it is possible to reduce the overvoltage. Therefore, according to the present invention, it is possible to provide a method of regenerating a solid battery that can reduce overvoltage. In addition, by adopting a configuration in which the heating means 6 and the fastening means 7 are provided, according to the present invention, it is possible to provide the solid state battery 10 capable of reducing overvoltage.
- the negative electrode 1 contains a negative electrode active material capable of inserting and extracting lithium ions.
- a negative electrode active material include Li, Zn, Al, Ag, or an alloy of Li and another metal (for example, Zn, Al, Ag, etc.), a carbon material such as graphite, and the like.
- a known negative electrode active material that can be used for the negative electrode of the secondary battery can be appropriately used.
- the negative electrode 1 may contain a solid electrolyte, a conductive material, and a binder for binding them. When the negative electrode 1 contains a solid electrolyte, the negative electrode 1 can appropriately contain a known solid electrolyte that can be used in a solid battery.
- the negative electrode 1 when making the negative electrode 1 contain a electrically conductive material, the negative electrode 1 can be made to contain suitably the well-known electrically conductive material which can be used for a solid battery. Examples of such a conductive material include a carbon material typified by carbon black.
- the negative electrode 1 when the negative electrode 1 contains a binder, the negative electrode 1 can appropriately contain a known binder that can be used in a solid battery.
- a binder include synthetic rubbers such as fluorine rubber, and polymer materials such as polyvinylidene fluoride.
- the positive electrode 2 contains a positive electrode active material capable of inserting and extracting lithium ions.
- a positive electrode active material capable of inserting and extracting lithium ions.
- the positive electrode active material to be contained in the positive electrode 2 a known positive electrode active material that can be used for a solid battery can be appropriately used.
- a positive electrode active material lithium cobaltate etc. can be mentioned, for example.
- the positive electrode 2 may contain a solid electrolyte, a conductive material, and a binder for binding them.
- the positive electrode 2 contains a solid electrolyte, a conductive material, and a binder, the same solid electrolyte, conductive material, and binder as can be contained in the negative electrode 1 should be used. it can.
- the solid electrolyte layer 3 contains a solid electrolyte that has lithium ion conductivity and does not have electron conductivity.
- a known solid electrolyte that can be used in a solid battery can be appropriately used.
- the negative electrode current collector 4 known materials that can be used for the negative electrode current collector of the solid state battery can be appropriately used.
- the negative electrode current collector 4 for example, a copper foil or a nickel foil can be used.
- the positive electrode current collector 5 a known material that can be used for the positive electrode current collector of the solid state battery can be appropriately used.
- the positive electrode current collector 5 for example, an aluminum foil, a nickel foil, or the like can be used.
- the heating means 6 is not particularly limited in form as long as it can heat the negative electrode 1a at least to a temperature at which the negative electrode 1a begins to soften and can withstand the environment when the solid battery 10 is used. Any known heating means can be used as appropriate. As the heating means 6, for example, a known heating element that generates heat when an electric current is passed can be used. In the present invention, the time for heating the negative electrode 1a using the heating means 6 (heating time) is from when the application of force using the fastening means 7 is started until the application of force is completed. The time required for maintaining the negative electrode 1a in a softened state can be set. The heating time can be, for example, not less than 0.1 seconds and not more than 180 seconds. In addition, when the heating unit 6 is a known heating element that generates heat when an electric current is passed, the current that is passed to cause the heating unit 6 to generate heat can be, for example, 30 A or more and 500 A or less.
- the fastening means 7 can apply a compressive force capable of smoothing the surface of the negative electrode 1 facing the solid electrolyte layer 3 to the negative electrode 1 a and can withstand the environment when the solid battery 10 is used. If it is a thing, the form will not be specifically limited.
- the fastening means 7 is a known fastening means capable of applying a compressive force (fastening force) to each component housed in the exterior material for the purpose of reducing the interface resistance at the interface between the solid electrolyte layer and the negative electrode. Can be used as appropriate.
- the magnitude of the force (pressure) applied to the negative electrode 1a is not particularly limited as long as the surface of the negative electrode 1 facing the solid electrolyte layer 3 can be smoothed.
- the pressure can be set to 100 MPa or less.
- the time for applying the force to the negative electrode 1a is appropriately changed according to the magnitude of the force applied to the negative electrode 1a.
- the time for applying the force to the negative electrode 1a is not particularly limited as long as the surface of the negative electrode 1 facing the solid electrolyte layer 3 can be smoothed.
- the time is 0.1 seconds or more and 300 seconds or less. It can be.
- the compressive force applied to the negative electrode 1a only needs to exhibit a function of smoothing the surface of the negative electrode 1a facing the solid electrolyte layer 3, and the compressive force of the negative electrode 1a facing the solid electrolyte layer 3 can be reduced. It need not be applied only to smooth the surface.
- the fastening means 7 has a function of continuously applying a force in the direction in which the negative electrode 1, the solid electrolyte layer 3, and the positive electrode 2 are brought into close contact with each other regardless of the unevenness of the surface of the negative electrode 1 facing the solid electrolyte layer 3. You may do it.
- the present invention compresses the negative electrode 1a heated using the heating means 6 using the force applied before the negative electrode 1a is heated, so that the negative electrode 1 facing the solid electrolyte layer 3 is compressed. It is also possible to adopt a form in which the surface is smoothed. Even when the solid battery 10 is operated while applying a force in the direction in which the solid electrolyte layer 3 and the negative electrode 1 are brought into close contact with each other using the fastening means 7, when the interface resistance increases and the overvoltage increases, the fastening means 7 It is considered that the force applied using is smaller than the force required to smooth the surface of the negative electrode 1.
- the operation of the fastening means 7 is controlled using a control means (not shown) so as to increase the force applied using the fastening means 7, and then the heated negative electrode 1a is applied. By applying force, it may be regenerated into the negative electrode 1b (solid battery 10b including the negative electrode 1b) having a smooth surface facing the solid electrolyte layer 3b.
- the surface of the negative electrode 1 facing the solid electrolyte layer 3 is smoothed by compressing the softened negative electrode 1a at a heating temperature of 160 ° C., thereby reducing the overvoltage of the solid battery 10.
- the present invention is not limited to the form. In the present invention, it is possible to reduce the overvoltage through a process of heating the negative electrode 1a so that a part of the negative electrode 1a melts.
- the negative electrode 1a, the solid electrolyte layer 3 sandwiching the negative electrode 1a, and the negative electrode current collector 4 are accommodated in an exterior material not shown, and the interior of the exterior material in which the negative electrode 1a is to be disposed Is determined by the solid electrolyte layer 3, the negative electrode current collector 4, and the exterior material. Therefore, even if a part of the negative electrode 1a is melted, the solidified negative electrode 1b is solidified by applying a force using the fastening means 7 and solidifying the negative electrode 1 by lowering the temperature after the heating to solidify the negative electrode 1b. 3 and the negative electrode current collector 4, and the solid battery 10 b can be operated.
- the present invention may be in a form in which overvoltage is reduced through a process of heating the negative electrode 1a so that a temperature at which a part of the negative electrode 1a is melted.
- the present invention is configured to smooth the surface of the negative electrode facing the solid electrolyte layer by applying force to the softened negative electrode, the temperature at which the negative electrode is heated and softened is the negative electrode contained. It can be appropriately changed according to the composition of the active material.
- the negative electrode is heated and softened so that it is 160 ° C. or higher and lower than 185 ° C. It is preferable that
- solid battery 10 in which lithium ions move between the negative electrode 1 and the positive electrode 2 through the solid electrolyte layer 3 has been described.
- the present invention is limited to this form. is not.
- the solid battery to which the method of the present invention is applied and the solid battery of the present invention (hereinafter collectively referred to simply as “solid battery of the present invention”) are alkali metal ions other than lithium ions (for example, sodium) It is also possible to adopt a form in which ions, potassium ions, etc. (the same applies below) move between the negative electrode and the positive electrode through the solid electrolyte layer.
- the solid battery of the present invention has a form in which alkaline earth metal ions (for example, calcium ions, magnesium ions, etc., the same applies hereinafter) move between the negative electrode and the positive electrode through the solid electrolyte layer. Also good. However, from the viewpoint of providing a solid battery having a high energy density, it is preferable that lithium ions move between the negative electrode and the positive electrode via the solid electrolyte layer.
- alkaline earth metal ions for example, calcium ions, magnesium ions, etc., the same applies hereinafter
- an alkali metal simple substance that generates the alkali metal ions may be used as the negative electrode active material for the negative electrode of the solid battery of the present invention. It can.
- metals such as Zn, Al, and Ag, alloys of alkali metals that generate alkali metal ions with other metals (for example, Zn, Al, and Ag), carbon materials such as graphite, and the like as negative electrode active materials Can be used.
- the negative electrode of the solid battery of the present invention includes an alkaline earth metal simple substance that generates the alkaline earth metal ions as the negative electrode active material.
- an alkaline earth metal simple substance that generates the alkaline earth metal ions as the negative electrode active material.
- metals such as Zn, Al, and Ag, alloys of alkaline earth metals that generate alkaline earth metal ions and other metals (for example, Zn, Al, Ag, etc.), carbon materials such as graphite, etc. It can be used as a negative electrode active material.
- a known positive electrode active material that generates the alkali metal ions is appropriately used for the positive electrode of the solid battery of the present invention.
- Can do When alkaline earth metal ions are moved between the negative electrode and the positive electrode, a known positive electrode active material that generates the alkaline earth metal ions is appropriately used for the positive electrode of the solid battery of the present invention. Can do.
- the heating means 6 is embedded in the negative electrode current collector 4
- the present invention is not limited to this mode.
- the heating means may be provided in a form capable of heating the negative electrode.
- the solid battery of this invention is not limited to the said form.
- the solid battery of the present invention can also be configured in such a manner that an electrolyte is filled between the positive electrode and the solid electrolyte layer while being held by a separator as necessary.
- the electrolytic solution for example, a known electrolytic solution that can be used for a solid battery such as an aqueous electrolyte or a nonaqueous electrolytic solution can be appropriately used.
- the aqueous electrolyte include an alkaline aqueous electrolyte in which a lithium salt is dissolved, a neutral aqueous electrolyte in which a lithium salt is dissolved, and the like.
- lithium salt such as LiOH, CH 3 COOLi, LiClO 4 , Li 2 SO 4 can be dissolved in the aqueous electrolyte, and the LiOH concentration is greater than 0 mol / L and less than or equal to 5.12 mol / L. be able to. 5.12 mol / L is the saturation concentration at room temperature.
- the electrolyte concentration is less than 0.1 mol / L, the decrease in lithium ion conductivity becomes significant.
- KOH, NaOH, H 2 O 2 or (K + , Na + , H + , NH 4) of about 0.1 mol / L to 12 mol / L is separately provided.
- the solid state battery of the present invention can be operated even in a state where LiOH precipitates are present exceeding the saturation concentration of LiOH at room temperature of 5.12 mol / L.
- a non-aqueous electrolyte containing a lithium salt and an organic solvent can be used.
- Lithium salts to be contained in the non-aqueous electrolyte include inorganic lithium salts such as LiPF 6 , LiBF 4 , LiClO 4 and LiAsF 6 , LiCF 3 SO 3 , LiN (CF 3 SO 2 ) 2 , LiN (C 2 F Examples include organic lithium salts such as 5 SO 2 ) 2 and LiC (CF 3 SO 2 ) 3 .
- organic solvent used in the non-aqueous electrolyte examples include ethylene carbonate (EC), propylene carbonate (PC), dimethyl carbonate (DMC), diethyl carbonate (DEC), ethyl methyl carbonate (EMC), butylene carbonate, and ⁇ -butyrolactone. And sulfolane, acetonitrile, 1,2-dimethoxymethane, 1,3-dimethoxypropane, diethyl ether, tetrahydrofuran, 2-methyltetrahydrofuran, and mixtures thereof. Moreover, it is preferable that an organic solvent is a solvent with high oxygen solubility from a viewpoint of making it the form in which dissolved oxygen is used for reaction efficiently.
- the concentration of the lithium salt in the nonaqueous electrolytic solution can be, for example, 0.2 mol / L or more and 3 mol / L or less.
- a low-volatile liquid such as an ionic liquid
- the nonaqueous electrolytic solution can be used.
- nonwoven fabrics such as a resin nonwoven fabric and a glass fiber nonwoven fabric, etc. other than porous membranes, such as polyethylene and a polypropylene, can be used.
- the solid battery 10 was regenerated by the method of the present invention.
- the heating means 6 a heating element that generates heat when an electric current flows is used.
- the negative electrode 1a was heated to 160 ° C. using the heating means 6 and softened.
- the solid battery 10a was regenerated into the solid battery 10b by applying a compression pressure of 0.005 MPa to the softened negative electrode 1a using the fastening means 7 for 30 seconds.
- FIG. 3 shows charging curves of the solid battery 10a and the solid battery 10b.
- the vertical axis represents overvoltage [V]
- the horizontal axis represents capacity [mAh].
- the overvoltage in the plateau region of the solid battery 10a before being regenerated by the method of the present invention was ⁇ 0.1510V, but after being regenerated by the method of the present invention, the solid battery 10b
- the overvoltage in the plateau region was ⁇ 0.1481V. That is, according to the method of the present invention, the overvoltage of the solid battery 10 could be reduced by 0.0029V.
- the solid battery 10a had an overvoltage of ⁇ 0.15 V before the capacity became 0.06 mAh, but the capacity of the solid battery 10b regenerated by the method of the present invention was 0.00. Even when it exceeded 08 mAh, the overvoltage was less than -0.15V. It is considered that this result also has an effect of improving the adhesion between the negative electrode and the negative electrode current collector by carrying out the method of the present invention. As described above, according to the present invention, the overvoltage can be reduced.
- the solid battery of the present invention can be used for electric vehicles and hybrid vehicles.
- the solid battery regenerating method of the present invention can be used for reducing the overvoltage of a solid battery having such an application.
Abstract
Description
本発明の第1の態様は、アルカリ金属イオン又はアルカリ土類金属イオンを吸蔵及び放出可能な負極、該負極に接触するように配設されたイオン伝導性を有する固体電解質を含む固体電解質層、及び、負極との間を移動するアルカリ金属イオン又はアルカリ土類金属イオンを放出及び吸蔵可能な正極を備える固体電池を再生させる方法であって、負極が軟化する温度へと加熱し、軟化している負極を、固体電解質層と接触する面に交差する方向へと圧縮する工程、を有することを特徴とする、固体電池の再生方法である。
2…正極
3…固体電解質層
4、4b…負極集電体
5…正極集電体
6…加熱手段
7…締結手段
10、10a、10b…固体電池
Claims (4)
- アルカリ金属イオン又はアルカリ土類金属イオンを吸蔵及び放出可能な負極、該負極に接触するように配設されたイオン伝導性を有する固体電解質を含む固体電解質層、及び、前記負極との間を移動する前記アルカリ金属イオン又は前記アルカリ土類金属イオンを放出及び吸蔵可能な正極を備える固体電池を再生させる方法であって、
前記負極が軟化する温度へと加熱し、軟化している前記負極を、前記固体電解質層と接触する面に交差する方向へと圧縮する工程、
を有することを特徴とする、固体電池の再生方法。 - 前記負極がリチウムイオンを吸蔵放出可能であり、加熱温度が160℃以上185℃未満であることを特徴とする、請求の範囲第1項に記載の固体電池の再生方法。
- アルカリ金属イオン又はアルカリ土類金属イオンを吸蔵及び放出可能な負極と、該負極に接触するように配設されたイオン伝導性を有する固体電解質を含む固体電解質層と、前記負極との間を移動する前記アルカリ金属イオン又は前記アルカリ土類金属イオンを放出及び吸蔵可能な正極と、前記負極が軟化する温度へ前記負極を加熱する加熱手段と、前記固体電解質層及び前記負極を密着させる力を付与可能な締結手段と、を備えることを特徴とする、固体電池。
- 前記負極がリチウムイオンを吸蔵放出可能であり、加熱温度が160℃以上185℃未満であることを特徴とする、請求の範囲第3項に記載の固体電池。
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US13/819,577 US9225038B2 (en) | 2010-09-16 | 2010-09-16 | Solid battery and method for regenerating the same |
CN201080068999.3A CN103081215B (zh) | 2010-09-16 | 2010-09-16 | 固体电池及其再生方法 |
JP2012533786A JP5500260B2 (ja) | 2010-09-16 | 2010-09-16 | 固体電池及びその再生方法 |
PCT/JP2010/066031 WO2012035631A1 (ja) | 2010-09-16 | 2010-09-16 | 固体電池及びその再生方法 |
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