WO2012021094A3 - Катализатор, способ его приготовления и способ получения смеси углеводородов - Google Patents

Катализатор, способ его приготовления и способ получения смеси углеводородов Download PDF

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WO2012021094A3
WO2012021094A3 PCT/RU2011/000625 RU2011000625W WO2012021094A3 WO 2012021094 A3 WO2012021094 A3 WO 2012021094A3 RU 2011000625 W RU2011000625 W RU 2011000625W WO 2012021094 A3 WO2012021094 A3 WO 2012021094A3
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mass
catalyst
oxide
mixture
zeolite
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PCT/RU2011/000625
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English (en)
French (fr)
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WO2012021094A2 (ru
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Саламбек Наибович ХАДЖИЕВ
Наталия Васильевна КОЛЕСНИЧЕНКО
Наталия Анатольевна МАРКОВА
Зарета Муратовна БУКИНА
Дмитрий Алексеевич ИОНИН
Руслан Владимирович КУЛУМБЕГОВ
Original Assignee
Федеральное Государственное Бюджетное Учреждение Науки Ордена Трудового Красного Знамени Институт Нефтехимического Синтеза Им. А.В.Топчиева Ран (Инхс Ран)
Открытое Акционерное Общество "Электрогорский Институт Нефтепереработки" (Оао "Элинп")
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Priority to EA201300094A priority Critical patent/EA021358B1/ru
Publication of WO2012021094A2 publication Critical patent/WO2012021094A2/ru
Publication of WO2012021094A3 publication Critical patent/WO2012021094A3/ru

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/333—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the platinum-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/334—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing molecular sieve catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Изобретение относится к получению углеводородов бензинового ряда с низким содержанием ароматических соединений из диметилового эфира в присутствии катализатора. Катализатор содержит (% масс): цеолит типа пентасила с SiО2/Al2O3 = 25-100, содержащий не более 0,1 % масс, оксида натрия, - 65.0; оксид цинка - 0.5-2.0; оксид циркония - 0.2-1.0; и/или оксид лантана - 0.2-1.0; палладий - 0.1-1.0; связующее - остальное. Способ получения этого катализатора включает модифицирование цеолита в аммонийной форме цинком, палладием, цирконием и/или лантаном, смешение со связующим, в количествах, предусмотренных составом катализатора, формование экструдатов, их сушку и прокаливание. Синтез смеси углеводородов в присутствии указанного катализатора ведут в циркуляционном режиме при кратности циркуляции 10-35, в качестве смеси газов используют смесь газов с содержанием водорода в используемом синтез-газе не менее 71% об. При этом достигается снижение содержания ароматических соединений до не более 8.0% масс., в том числе дурола - не более 0.7% масс, и повышение производительности процесса до 120 г/м3 синтез-газа.
PCT/RU2011/000625 2010-08-11 2011-08-18 Катализатор, способ его приготовления и способ получения смеси углеводородов с низким содержанием ароматических соединений WO2012021094A2 (ru)

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EA201300094A EA021358B1 (ru) 2010-08-11 2011-08-18 Катализатор, способ его приготовления и способ получения смеси углеводородов с низким содержанием ароматических соединений

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RU2010133596 2010-08-11
RU2010133596/04A RU2442650C1 (ru) 2010-08-11 2010-08-11 Катализатор, способ его приготовления и способ получения смеси углеводородов с низким содержанием ароматических соединений

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WO2012021094A3 true WO2012021094A3 (ru) 2012-04-05

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2674769C1 (ru) * 2017-07-06 2018-12-13 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Комбинированный катализатор и способ получения обогащённого триптаном экологически чистого высокооктанового бензина в его присутствии

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4440231A1 (de) * 1994-01-18 1995-07-20 V & M Metallhandelsges Mbh Katalysator zur Qualitätsverbesserung von Benzin, Verfahren zur Herstellung desselben und Verfahren zur Veredelung von Benzin
EP0903178A1 (en) * 1997-09-17 1999-03-24 China Petro-Chemical Corporation A pentasil-type molecular sieve containing composition and its preparation method
RU2160160C1 (ru) * 1999-10-22 2000-12-10 Байбурский Владимир Леонович Катализатор и способ получения жидких углеводородов из диметилового эфира
RU2175960C2 (ru) * 2000-03-03 2001-11-20 Научно-инженерный центр "Цеосит" Объединенного института катализа СО РАН Способ получения углеводородных бензиновых фракций
WO2004020335A1 (en) * 2002-08-28 2004-03-11 Albemarle Netherlands B.V. Process for the preparation of doped pentasil-type zeolites using a doped reactant
RU2248341C1 (ru) * 2003-08-07 2005-03-20 Институт нефтехимического синтеза им. А.В. Топчиева РАН (ИНХС РАН) Катализатор, способ его приготовления и способ получения экологически чистого высокооктанового бензина

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4440231A1 (de) * 1994-01-18 1995-07-20 V & M Metallhandelsges Mbh Katalysator zur Qualitätsverbesserung von Benzin, Verfahren zur Herstellung desselben und Verfahren zur Veredelung von Benzin
EP0903178A1 (en) * 1997-09-17 1999-03-24 China Petro-Chemical Corporation A pentasil-type molecular sieve containing composition and its preparation method
RU2160160C1 (ru) * 1999-10-22 2000-12-10 Байбурский Владимир Леонович Катализатор и способ получения жидких углеводородов из диметилового эфира
RU2175960C2 (ru) * 2000-03-03 2001-11-20 Научно-инженерный центр "Цеосит" Объединенного института катализа СО РАН Способ получения углеводородных бензиновых фракций
WO2004020335A1 (en) * 2002-08-28 2004-03-11 Albemarle Netherlands B.V. Process for the preparation of doped pentasil-type zeolites using a doped reactant
RU2248341C1 (ru) * 2003-08-07 2005-03-20 Институт нефтехимического синтеза им. А.В. Топчиева РАН (ИНХС РАН) Катализатор, способ его приготовления и способ получения экологически чистого высокооктанового бензина

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WO2012021094A2 (ru) 2012-02-16
EA201300094A1 (ru) 2013-06-28
EA021358B1 (ru) 2015-05-29
RU2442650C1 (ru) 2012-02-20

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