WO2011137756A2 - 复合材料以及电子设备 - Google Patents
复合材料以及电子设备 Download PDFInfo
- Publication number
- WO2011137756A2 WO2011137756A2 PCT/CN2011/073751 CN2011073751W WO2011137756A2 WO 2011137756 A2 WO2011137756 A2 WO 2011137756A2 CN 2011073751 W CN2011073751 W CN 2011073751W WO 2011137756 A2 WO2011137756 A2 WO 2011137756A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composite material
- layer
- adhesive layer
- conductive
- insulating layer
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/0201—Thermal arrangements, e.g. for cooling, heating or preventing overheating
- H05K1/0203—Cooling of mounted components
- H05K1/0204—Cooling of mounted components using means for thermal conduction connection in the thickness direction of the substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L23/00—Details of semiconductor or other solid state devices
- H01L23/552—Protection against radiation, e.g. light or electromagnetic waves
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L24/00—Arrangements for connecting or disconnecting semiconductor or solid-state bodies; Methods or apparatus related thereto
- H01L24/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L24/18—High density interconnect [HDI] connectors; Manufacturing methods related thereto
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/0213—Electrical arrangements not otherwise provided for
- H05K1/0216—Reduction of cross-talk, noise or electromagnetic interference
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K7/00—Constructional details common to different types of electric apparatus
- H05K7/20—Modifications to facilitate cooling, ventilating, or heating
- H05K7/2039—Modifications to facilitate cooling, ventilating, or heating characterised by the heat transfer by conduction from the heat generating element to a dissipating body
- H05K7/20436—Inner thermal coupling elements in heat dissipating housings, e.g. protrusions or depressions integrally formed in the housing
- H05K7/20445—Inner thermal coupling elements in heat dissipating housings, e.g. protrusions or depressions integrally formed in the housing the coupling element being an additional piece, e.g. thermal standoff
- H05K7/20472—Sheet interfaces
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0007—Casings
- H05K9/002—Casings with localised screening
- H05K9/0022—Casings with localised screening of components mounted on printed circuit boards [PCB]
- H05K9/0024—Shield cases mounted on a PCB, e.g. cans or caps or conformal shields
- H05K9/003—Shield cases mounted on a PCB, e.g. cans or caps or conformal shields made from non-conductive materials comprising an electro-conductive coating
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0007—Casings
- H05K9/002—Casings with localised screening
- H05K9/0022—Casings with localised screening of components mounted on printed circuit boards [PCB]
- H05K9/0024—Shield cases mounted on a PCB, e.g. cans or caps or conformal shields
- H05K9/0031—Shield cases mounted on a PCB, e.g. cans or caps or conformal shields combining different shielding materials
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K9/00—Screening of apparatus or components against electric or magnetic fields
- H05K9/0007—Casings
- H05K9/002—Casings with localised screening
- H05K9/0022—Casings with localised screening of components mounted on printed circuit boards [PCB]
- H05K9/0024—Shield cases mounted on a PCB, e.g. cans or caps or conformal shields
- H05K9/0032—Shield cases mounted on a PCB, e.g. cans or caps or conformal shields having multiple parts, e.g. frames mating with lids
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/07—Electric details
- H05K2201/0707—Shielding
- H05K2201/0715—Shielding provided by an outer layer of PCB
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/20—Details of printed circuits not provided for in H05K2201/01 - H05K2201/10
- H05K2201/2018—Presence of a frame in a printed circuit or printed circuit assembly
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02D—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN INFORMATION AND COMMUNICATION TECHNOLOGIES [ICT], I.E. INFORMATION AND COMMUNICATION TECHNOLOGIES AIMING AT THE REDUCTION OF THEIR OWN ENERGY USE
- Y02D30/00—Reducing energy consumption in communication networks
- Y02D30/70—Reducing energy consumption in communication networks in wireless communication networks
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/30—Self-sustaining carbon mass or layer with impregnant or other layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
Definitions
- the invention belongs to the technical field of electronic assembly, and particularly relates to a composite material and an electronic device.
- the existing electronic equipment generally adopts a combination of a thermal pad 6 and a shield cover 7.
- the electronic component 2 is mounted on the circuit board 1, and the heat generated by the electronic component 2 is transferred to the outer casing 8 by the heat conductive material 5, and the thermal pad 6 is filled between the electronic component 2, the heat conductive material 5 and the outer casing 8. , to achieve heat dissipation.
- the function of the heat conductive material 5 is mainly to uniformly disperse heat to prevent the local temperature of the electronic device from being excessively high; some electronic devices do not have the heat conductive material 5, and the heat generated by the electronic component 2 is directly transmitted to the outer casing 8 by the thermal pad 6. .
- electromagnetic shielding of the electronic component 2 is achieved by the shield case 7 which is attached to the shield frame 3.
- the existing electronic device realizes heat dissipation and electromagnetic shielding by the thermal pad and the shield cover, respectively, resulting in an excessively complicated internal structure of the electronic device.
- Embodiments of the present invention provide a composite material and an electronic device that achieve heat dissipation and electromagnetic shielding in a simpler structure.
- the composite material includes a conductive heat conductive layer, an adhesive layer and an insulating layer which are adhered to each other, and the conductive heat conductive layer and the insulating layer are respectively attached to both sides of the adhesive layer;
- the adhesive layer is electrically conductive.
- the electronic device includes a circuit board and a composite material; the circuit board has an electronic component and a shielding frame; the composite material comprises an electrically conductive layer, an adhesive layer and an insulating layer which are adhered to each other, and the conductive and heat conducting layer
- the insulating layer is respectively attached to both sides of the adhesive layer; the adhesive layer has electrical conductivity; the insulating layer forms a gap at a position corresponding to the electronic component and/or the shielding frame, and is exposed The adhesive layer is adhered to the electronic component and/or the shielding frame through the adhesive layer.
- the above technical solution provided by the present invention has the following advantages: the composite material is adhered to the electronic component through the adhesive layer, and the contact between the conductive heat conductive layer and the electronic component can be made stronger; the adhesive layer is further It can fill the gap between its contact faces, reduce the thermal resistance, and achieve heat dissipation.
- the composite material is adhered to the shield frame by the adhesive layer, and the adhesive layer also has electrical conductivity, so that the conductive heat conductive layer and the shield frame can be formed into a more stable electrical connection to achieve electromagnetic shielding.
- the technical solution provided by the invention can realize heat dissipation and electromagnetic shielding at the same time by only one composite material, and solves the problem that the existing electronic equipment realizes heat dissipation and electromagnetic shielding by the thermal pad and the shield cover respectively, and the internal structure of the electronic device is too complicated. technical problem.
- 1 is a schematic view showing the internal structure of an existing electronic device
- FIG. 2 is a schematic structural view of a composite material according to Embodiment 1 of the present invention
- FIG. 3 is a schematic view showing an embodiment of a composite material provided by Embodiment 1 of the present invention
- Figure 4 is a schematic view showing an embodiment of a composite material provided in Example 2 of the present invention.
- Figure 5 is a schematic structural view of a composite material according to Embodiment 3 of the present invention
- 6 is a schematic structural diagram of an electronic device according to Embodiment 4 of the present invention
- FIG. 7 is a schematic structural diagram of an electronic device according to Embodiment 5 of the present invention
- FIG. 8 is an electronic device according to Embodiment 6 of the present invention
- Embodiments of the present invention provide a composite material and an electronic device.
- the composite material provided by the embodiment of the present invention includes a conductive heat conductive layer 41, an adhesive layer 42 and an insulating layer 43 which are adhered to each other, and the conductive heat conductive layer 41 and the insulating layer 43 are respectively adhered.
- the adhesive layer 42 On both sides of the adhesive layer 42; the adhesive layer 42 has electrical conductivity.
- the composite material has a bendable property, and is similar in appearance to paper, and is also light, thin, soft, and can be stretched and stretched in a small amount.
- the conductive and thermally conductive layer 4 1 is one or more of copper, graphite, aluminum, ceramics, etc., and the conductive and thermally conductive layer 4 1 is formed in the form of a thin layer, and the thermal conductivity thereof can reach 50 W/m ⁇ K or more. If graphite is used, its thermal conductivity is related to the direction, the thermal conductivity in the plane direction is 5 OW/m ⁇ K or more, and the thermal conductivity in the normal direction is 5 W/m ⁇ K or more.
- the adhesive layer 42 is preferably a single layer structure formed of one or more of a propylene-based adhesive, a polyester film, or a multilayer structure.
- the insulating layer 43 forms a gap at a position corresponding to the electronic component 2 and/or the shield frame 3, exposing the adhesive layer 42, and sticking the composite material to the electronic component 2 through the adhesive layer 42.
- the contact between the conductive and thermally conductive layer 4 1 and the electronic component 2 can be made stronger; although the thermal conductivity of the adhesive layer 42 is lower than that of the conductive and thermally conductive layer 41, the adhesive layer 42 can fill the composite material and the electronic component 2
- the gap of the contact surface can reduce the thermal resistance and achieve heat dissipation.
- the composite material is adhered to the shield frame 3 through the adhesive layer 42, and the adhesive layer 42 is also electrically conductive, so that the conductive heat conductive layer can be made 41 forms a more stable electrical connection with the shield frame 3 to achieve electromagnetic shielding.
- the composite material only needs to be electrically connected to the shield frame 3. Since the insulating layer 43 forms a notch only at a position corresponding to the electronic component 2 and/or the shield frame 3, the other portions of the composite material are still covered with the insulating layer 43, which does not form an unreasonable electrical connection with these pins, resulting in Short circuit and other conditions.
- This embodiment is basically the same as the first embodiment, and the difference is that: in this embodiment, as shown in FIG. 4, some pins 21 are sometimes exposed on the electronic component 2 to form on the insulating layer 43. In the case of the notch, the insulating layer 43 is left only in the corresponding position, and after the composite material is adhered to the electronic component 2 through the adhesive layer 42, the pin 21 on the electronic component 2 can be prevented from being electrically conductive and thermally conductive by the insulating layer 43. Layer 41 forms an electrical connection.
- the thickness of the electrically and thermally conductive layer 41 is less than or equal to 2 mm.
- the conductive and thermally conductive layer requires only 2 mm to achieve good electrical conductivity and thermal conductivity.
- the conductive and thermally conductive layer 41 can be made thinner in order to take up as little space as possible.
- the thickness of the adhesive layer 42 is less than or equal to 0.2 mm.
- the adhesive layer 42 mainly serves as a fixing function and reduces the thermal resistance, but its resistivity is large, so the thinner the better.
- the insulating layer 43 has a thickness of 0.5 mm or less. Since the gap is formed on the insulating layer 43 at the time of use and the insulating effect is ensured, the thickness of the insulating layer 43 should be moderate.
- This embodiment is basically the same as the second embodiment, and the difference is that, as shown in FIG. 5, in the embodiment, the opposite side of the conductive and thermally conductive layer 41 and the adhesive layer 42 is also provided with an insulating layer 44.
- one side of the composite material is bonded to the electronic component and/or the shielding frame, and the other side is exposed to the conductive and heat conducting layer 41, in order to prevent other parts from being
- the electrically and thermally conductive layer 41 forms an unreasonable electrical connection, so in this embodiment, this face is also covered with an insulating layer 44.
- an electronic device includes a circuit board 1 and a composite material 4; the circuit board 1 has an electronic component 2 and a shielding frame 3; and the composite material 4 includes a mutual bonding.
- the conductive and heat conducting layer, the adhesive layer and the insulating layer, the conductive heat conducting layer and the insulating layer are respectively adhered to both sides of the adhesive layer; the adhesive layer has electrical conductivity; the insulating layer is in contact with the electronic component 2 and/or the shielding frame 3, the corresponding position forms a gap, exposing the adhesive layer, and the composite material 4 is adhered to the electronic component 2 and/or the shield frame 3 through the adhesive layer.
- a composite material 4 can satisfy the heat dissipation and/or electromagnetic shielding of the plurality of electronic components 2.
- Some electronic components 2 require both heat dissipation and electromagnetic shielding, so the composite material 4 should be adhered to the shielded frame 3 on the electronic component 2 and around it (as shown in Figure 8, the left electronic component 2);
- the electronic component 2 only needs electromagnetic shielding without heat dissipation, so the composite material 4 only needs to be adhered to the shielding frame 3 around the electronic component 2 (as shown in Fig. 8, the middle electronic component 2); 2 Only need to dissipate heat without electromagnetic shielding, so the composite material 4 only needs to be glued to the electronic component 2 (as shown in Figure 8, the right electronic component 2).
- the embodiment of the present invention has the same technical features as the composite material provided in the first embodiment of the present invention, the same technical effects can be produced to solve the same technical problem.
- the embodiment is basically the same as the embodiment 4, and the difference is as follows: as shown in FIG. 7, in this embodiment, the electronic component 2 and the shielding frame 3 are provided on both sides of the circuit board 1; the electrons on both sides of the circuit board 1 The component 2 and/or the frame 3 are adhered to the composite material 4, and the composite material 4 is a single piece, and the composite material 4 is bent and wrapped on both sides of the circuit board 1.
- the composite material 4 is light, thin, soft, bendable and bendable, and can be stretched and stretched at a small extent, an electronic element bonded to both sides of the circuit board 1 by a composite material 4 is used.
- the electromagnetic shielding effect can be improved, and the heat on both sides of the circuit board 1 can be evenly distributed to improve the heat dissipation effect.
- This embodiment is basically the same as the embodiment 4, and the difference is that, as shown in Fig. 8, in the present embodiment, the composite material 4 extends to other heat generating portions other than the circuit board 1. Use a larger composite material 4 and extend it beyond the board 1. For example, the battery in the phone 9 1 , display 92.
- the composite material 4 is adhered to the electronic component 2 and/or the shield frame 3 on the circuit board 1, and is also in contact with the battery 9 1 and the display screen 92 to enable the circuit board 1, the battery 9 1 and the display screen 9 2
- the heat is evenly distributed, which makes the overall heat dissipation effect of the mobile phone better.
- This embodiment is basically the same as the embodiment 4, and the difference is that: in this embodiment, the opposite side of the conductive heat conductive layer and the adhesive layer is also provided with an insulating layer.
- one side of the composite material is bonded to the electronic component and/or the shielding frame, and the other surface is exposed to the conductive heat conductive layer. In order to prevent other parts from forming an unreasonable electrical connection with the conductive heat conductive layer from the surface, Therefore, in this embodiment, this face is also covered with an insulating layer.
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- Microelectronics & Electronic Packaging (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Computer Hardware Design (AREA)
- Electromagnetism (AREA)
- Thermal Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Shielding Devices Or Components To Electric Or Magnetic Fields (AREA)
- Cooling Or The Like Of Electrical Apparatus (AREA)
- Elimination Of Static Electricity (AREA)
- Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11777176.6A EP2685797B1 (en) | 2011-05-06 | 2011-05-06 | Composite material and electron device |
PCT/CN2011/073751 WO2011137756A2 (zh) | 2011-05-06 | 2011-05-06 | 复合材料以及电子设备 |
CN2011800003273A CN102187751A (zh) | 2011-05-06 | 2011-05-06 | 复合材料以及电子设备 |
JP2014508670A JP5743251B2 (ja) | 2011-05-06 | 2011-05-06 | 複合材料及び電子デバイス |
US14/072,199 US9363884B2 (en) | 2011-05-06 | 2013-11-05 | Composite material and electronic device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CN2011/073751 WO2011137756A2 (zh) | 2011-05-06 | 2011-05-06 | 复合材料以及电子设备 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US14/072,199 Continuation US9363884B2 (en) | 2011-05-06 | 2013-11-05 | Composite material and electronic device |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2011137756A2 true WO2011137756A2 (zh) | 2011-11-10 |
WO2011137756A3 WO2011137756A3 (zh) | 2012-04-05 |
Family
ID=44572396
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CN2011/073751 WO2011137756A2 (zh) | 2011-05-06 | 2011-05-06 | 复合材料以及电子设备 |
Country Status (5)
Country | Link |
---|---|
US (1) | US9363884B2 (zh) |
EP (1) | EP2685797B1 (zh) |
JP (1) | JP5743251B2 (zh) |
CN (1) | CN102187751A (zh) |
WO (1) | WO2011137756A2 (zh) |
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EP2685797A4 (en) | 2015-04-15 |
US9363884B2 (en) | 2016-06-07 |
EP2685797A2 (en) | 2014-01-15 |
CN102187751A (zh) | 2011-09-14 |
EP2685797B1 (en) | 2017-12-13 |
US20140055957A1 (en) | 2014-02-27 |
WO2011137756A3 (zh) | 2012-04-05 |
JP5743251B2 (ja) | 2015-07-01 |
JP2014514771A (ja) | 2014-06-19 |
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