WO2011063696A1 - 一种真空玻璃封接方法及真空玻璃产品 - Google Patents

一种真空玻璃封接方法及真空玻璃产品 Download PDF

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Publication number
WO2011063696A1
WO2011063696A1 PCT/CN2010/078234 CN2010078234W WO2011063696A1 WO 2011063696 A1 WO2011063696 A1 WO 2011063696A1 CN 2010078234 W CN2010078234 W CN 2010078234W WO 2011063696 A1 WO2011063696 A1 WO 2011063696A1
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WO
WIPO (PCT)
Prior art keywords
glass
metal
sheets
sealed
sheet
Prior art date
Application number
PCT/CN2010/078234
Other languages
English (en)
French (fr)
Inventor
李彦兵
王章生
Original Assignee
洛阳兰迪玻璃机器有限公司
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 洛阳兰迪玻璃机器有限公司 filed Critical 洛阳兰迪玻璃机器有限公司
Priority to JP2012540265A priority Critical patent/JP5450831B2/ja
Priority to US13/511,740 priority patent/US8899472B2/en
Priority to DE112010004568T priority patent/DE112010004568T5/de
Publication of WO2011063696A1 publication Critical patent/WO2011063696A1/zh

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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C27/00Joining pieces of glass to pieces of other inorganic material; Joining glass to glass other than by fusing
    • C03C27/06Joining glass to glass by processes other than fusing
    • C03C27/08Joining glass to glass by processes other than fusing with the aid of intervening metal
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K1/00Soldering, e.g. brazing, or unsoldering
    • B23K1/0008Soldering, e.g. brazing, or unsoldering specially adapted for particular articles or work
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/06Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/663Elements for spacing panes
    • E06B3/66304Discrete spacing elements, e.g. for evacuated glazing units
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/663Elements for spacing panes
    • E06B3/66309Section members positioned at the edges of the glazing unit
    • E06B3/66342Section members positioned at the edges of the glazing unit characterised by their sealed connection to the panes
    • E06B3/66357Soldered connections or the like
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/673Assembling the units
    • E06B3/67326Assembling spacer elements with the panes
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/66Units comprising two or more parallel glass or like panes permanently secured together
    • E06B3/673Assembling the units
    • E06B3/67326Assembling spacer elements with the panes
    • E06B3/67334Assembling spacer elements with the panes by soldering; Preparing the panes therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/24Structural elements or technologies for improving thermal insulation
    • Y02A30/249Glazing, e.g. vacuum glazing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00Architectural or constructional elements improving the thermal performance of buildings
    • Y02B80/22Glazing, e.g. vaccum glazing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/21Circular sheet or circular blank
    • Y10T428/215Seal, gasket, or packing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322Composite web or sheet
    • Y10T428/24331Composite web or sheet including nonapertured component

Definitions

  • the present invention relates to a vacuum glass sealing method and a vacuum glass product processed by the method. Background technique
  • Vacuum glass composed of a plurality of glass sheets has been highly valued by people for its excellent sound insulation, heat insulation and heat insulation properties, and has become a subject of research.
  • the existing sealing methods of vacuum glass mainly include:
  • the sealing temperature is generally between 400 °C and 500 °C.
  • the low-melting glass frit is melted by flame or electric heating to complete the composite sealing between the glass plate and the glass plate.
  • the low-melting glass used in the process is usually lead-zinc (PbO-ZnO) sealing glass. Due to the environmental hazard of lead, this material is not conducive to environmental protection in the long-term development, and its processing equipment and processes are complicated.
  • the composite sealed glass sheet often also produces edge thermal stress, so proper annealing is required, which greatly reduces the production efficiency.
  • the material of laminated glass is processed by placing the above material between two glass plates to form a preform, and then pressing the preform under appropriate conditions. This process is similar to the process of making laminated glass. Although the process can achieve composite sealing between glass plates, most plastic and resin materials have much higher gas permeability and moisture permeability than glass, and most The organic material and the surface of the glass plate are only physically bonded, and it is difficult to ensure that the joint does not leak, and once the infiltration of gas (including water vapor) occurs, the sealing strength is weakened, condensation in the interlayer, and mildew of the glass are directly caused. In addition, over time, the aging of organic materials directly affects the sealing effect and life of composite glass sheets.
  • FIG. 1 The vacuum glass of the structure shown, whether used as a glazing or as a thermal insulation member, is prone to temperature deformation as shown in Fig. 2, and once the deformation is at the sealing edge of the glass plate, the stress is formed. Exceeding the limit of the sealing edge will inevitably cause damage to the vacuum glass and thus pose a danger to the place where the vacuum glass is used. Summary of the invention
  • the object of the present invention is to provide a vacuum glass sealing method with simple process, reliable sealing and firmness, and the vacuum glass sealed by the method can well adapt to the temperature difference between the inner and outer glass plates.
  • the resulting deformation avoids excessive temperature stress at the sealing edge and ensures safe use of the vacuum glass.
  • the invention also provides a vacuum glass product processed according to the sealing method of the invention ⁇
  • the vacuum glass sealing method of the present invention is specifically:
  • the hermetic sealing of the edges of the two glass sheets is achieved by hermetically welding the metal sealing sheets between the metallized layers of the two sheets of glass to be sealed.
  • the sintering process specifically includes:
  • the glass sheet heating the glass sheet to sinter the metal paste coating into a metallized layer that is consolidated with the glass sheet. Further, the metal paste coating is prepared on the surface of the glass sheet by dip coating, spray coating, screen printing, hand coating or mechanical coating.
  • the metal sealing piece is composed of two metal pieces.
  • the two metal pieces are firstly treated by a metal brazing process or an ultrasonic welding process.
  • the metallized layer on the sealed two sheets of glass is hermetically welded and then hermetically bonded to the edges of the two sheets by means of hermetic welding between the two sheets of metal.
  • the two metal sheets are respectively taken out from the connected glass sheets, they are hermetically welded to each other by a metal brazing process or an ultrasonic welding process or a fusion welding process.
  • the two metal sheets are taken out from between the two sealed glass sheets, and the two metal sheets are respectively hermetically welded to the metallized layer on the inner surface of the two sealed glass sheets.
  • one of the two metal sheets is taken out from between the two sealed glass sheets, and is hermetically welded to the metallized layer on the inner surface of one of the glass sheets, and the other metal sheet and the other The metallization layer on the outer surface of a piece of glass sheet is hermetically welded.
  • the two metal sheets are respectively hermetically welded to the metallized layer on the outer surface of the two sealed glass sheets.
  • the metallization layer is prepared on the edge of the glass plate to be sealed; the metal sealing piece is composed of a piece of metal piece, and the metal piece is respectively treated with a metal brazing process or an ultrasonic welding process.
  • the metallized layer on the sealed two sheets of glass is hermetically welded.
  • the metal sealing piece is composed of a metal piece having a U-shaped cross section, and the U-shaped metal piece The two sides are respectively hermetically welded to the metallization layer on the two glass plates to be sealed.
  • the U-shaped metal piece is located between the two sealed glass plates, and the sides thereof are hermetically welded to the metallized layer by a metal brazing process.
  • the two sides of the U-shaped metal piece are located between the two sealed glass plates, and are hermetically welded to the metallized layer by a metal brazing process, and the bottom portion of the U-shaped cross section of the metal piece protrudes to Two sheets of glass outside.
  • one side of the U-shaped metal piece is located between the two sealed glass plates, and the metallized layer gas on the inner surface of one of the glass plates is processed by a metal brazing process or an ultrasonic welding process.
  • the densely welded joint after the other side of the metal sheet is passed around the edge of the other glass sheet, is hermetically connected to the metallized layer on the outer surface of the glass sheet by a metal brazing process or an ultrasonic welding process.
  • the U-shaped metal sheet covers the edges of the two sealed glass sheets, and the two sides thereof are respectively subjected to a metal brazing process or an ultrasonic welding process to the metalized layer gas on the outer surfaces of the two glass sheets. Close welded connection.
  • a vacuum glass comprising at least two sheets of glass laminated with each other, the periphery of the vacuum glass being hermetically sealed according to the sealing method described above.
  • the invention provides a new technical means for making vacuum glass by sintering a metallized layer on the surface of the glass plate and sealing the edge of the glass plate with the metallized layer and the metal sealing piece.
  • the method of the invention not only has the advantages of strong connection of the sealing portion, high air tightness, good thermal shock resistance, and the like, and the metal sealing piece can be well adapted to the temperature difference caused by the sealed two glass plates. The temperature is deformed to avoid excessive stress on the sealing edge of the vacuum glass to ensure the safety of the vacuum glass.
  • Figure 1 is a schematic view showing the structure of a conventional vacuum glass
  • FIG. 2 is a schematic view showing a state in which the conventional vacuum glass of FIG. 1 is deformed due to a temperature difference between inside and outside;
  • Figure 3 is a schematic view of the surface of the glass plate to be sealed after the surface of the portion to be sealed;
  • Embodiment 4 is a schematic structural view of Embodiment 1 of a vacuum glass according to the present invention.
  • Figure 5 is an enlarged schematic cross-sectional view of the metal piece 7 in the first embodiment
  • Figure 6 is a schematic structural view of Embodiment 2 of the present invention.
  • Figure 7 is a schematic structural view of Embodiment 3 of the present invention.
  • Figure 8 is a schematic structural view of Embodiment 4 of the present invention.
  • Figure 9 is a schematic structural view of Embodiment 5 of the present invention.
  • Figure 10 is a schematic structural view of Embodiment 6 of the present invention
  • Figure 11 is a schematic structural view of Embodiment 7 of the present invention
  • Figure 12 is a schematic structural view of Embodiment 8 of the present invention.
  • Figure 13 is a schematic structural view of Embodiment 9 of the present invention.
  • Figure 14 is a schematic structural view of Embodiment 10 of the present invention.
  • Figure 15 is a schematic view showing the structure of an embodiment 11 of the present invention.
  • 1 is the upper glass plate
  • 2 is the lower glass plate
  • 3 is the intermediate support
  • 4 is the steel sealing edge on the existing vacuum glass
  • 5 is the vacuum space between the two glass plates
  • 6 is The metallized layer sintered on the surface of the glass plate
  • 7 is a metal piece
  • 7a is the upper side of the metal piece 7 having a U-shaped cross section
  • 7b is the lower side of the metal piece 7 having a U-shaped cross section
  • 7-1 is the upper side.
  • the metal piece, 7-2 is the lower piece of metal
  • 8 is the middle glass plate
  • 9 is the arcuate connecting section on the metal piece 7.
  • a metal paste coating is prepared on the edge of the glass plate to be sealed; then, the glass plate is heated, and the metal paste is coated.
  • the layer is sintered into a metallization layer 6 bonded to the glass plate, and the sintered metallization layer 6 is as shown in FIG. 3; then, the two glass plates 1, 2 to be sealed are in the state shown in FIG.
  • a metal sheet 7 having a U-shaped cross section as shown in FIG. 5 is disposed between the two metallization layers 6 corresponding to each other on the two glass sheets 1, 2, so that the two side edges 7a, 7b of the metal sheet 7 are provided.
  • Fig. 1, 3 is an intermediate support disposed between the two glass sheets 1, 2, and 5 is a vacuum space formed between the two glass sheets 1, 2 after sealing.
  • the above metal paste coating may be prepared on the surface of the glass plate by dip coating, spray coating, screen printing, hand coating or mechanical coating.
  • the brazing material can be processed into a metal foil and then placed on the metal piece 7 and Between the metallization layers 6, the solder metal may also be pre-plated on the side edges 7a, 7b of the metal sheet 7, and/or pre-plated on the surface of the metallization layer 6, and then the subsequent soldering may be performed in accordance with the metal brazing process.
  • the solder used may be a tin alloy solder.
  • the above brazing process can be carried out under the protection of inert gas, or in the H 2 gas or N 2 gas environment. It can also be carried out under vacuum, which helps to improve the quality of brazing.
  • the metal piece 7 and the metallized layer 6 are welded to each other by a metal brazing process, the metal piece 7 and the metallized layer 6 should be made of a metal material suitable for brazing.
  • the temperature of the metal brazing process should be controlled to ⁇ 350 °C.
  • the metal brazing process can employ various suitable heating methods such as induction heating, laser heating, and microwave heating.
  • Figure 6 shows a second embodiment of the present invention.
  • the side edges 7a, 7b of the U-shaped metal sheet 7 are located between the sealed upper and lower glass sheets and are passed through a metal brazing material.
  • the process is respectively hermetically welded to the metallization layer 6 on the upper and lower glass plates, and the bottom portion of the U-shaped cross section of the metal piece 7 protrudes out of the two glass plates.
  • the metal piece 7 in this embodiment has a larger deformation margin, and can accommodate a larger temperature deformation of the two glass plates.
  • the metal piece 7 having a U-shaped cross section covers the edges of the upper and lower glass sheets 1, 2 which are sealed, and the two side edges 7a, 7b of the metal sheet 7 are respectively
  • the metallization layer 6 on the outer surface of the sheet glass sheets 1, 2 is hermetically welded.
  • one side of the U-shaped metal sheet 7 is located between the two sealed glass sheets and the metallization layer on the inner surface of the lower glass sheet. 6 Gas-tight solder joint, the other side of the metal sheet 7 is wound around the edge of the upper glass sheet and hermetically welded to the metallization layer 6 on the outer surface of the upper glass sheet.
  • the two sides of the metal piece 7 and the metallization layer 6 can be airtightly connected to each other by a metal brazing process, or can be ultrasonically connected.
  • the welding process is hermetically welded to each other.
  • the vacuum glass in the embodiment shown in FIG. 4 to FIG. 8 is composed of two glass plates, and the metal piece 7 having a U-shaped cross section is used as the metal sealing piece, and three pieces and three or more pieces of glass can also be produced. Plate of vacuum glass.
  • the vacuum glass is composed of three glass plates, and the vacuum glass combined with the two glass plates is different in that both sides of the glass plate 8 in the middle are sintered.
  • the metallization layer 6 is so as to be hermetically sealed with two sheets of glass sheets above and below the sheet metal sheet having a U-shaped cross section.
  • the metal sealing sheet used in the sealing method of the present invention may be composed of one piece of metal or two pieces of metal.
  • the sealing step is as follows:
  • Example 6 shown in FIG. 10 As an example, first, as described above, the surface to be sealed at the edge of the glass plate is burned.
  • the metallization layer 6 which is fixed together with the glass plate shown in FIG. 3; then, the upper and lower metal pieces 7-1, 7-2 and the metallization layer 6 on the upper and lower glass plates 1, 2, respectively Gas-tight soldering connection, and lead the metal sheets 7-1, 7-2 out of the glass plate to which they are connected; Finally, the two glass sheets 1, 2 are composited as shown in Fig. 10, and two pieces are The portions of the metal sheets 7-1, 7-2 that extend beyond the two glass sheets are hermetically welded to each other to achieve hermetic sealing of the edges of the two sheets of glass sheets 1, 2.
  • the metal sheets 7-1, 7-2 and the metallization layer 6 on the glass sheets 1, 2 may be hermetically welded to each other by a metal brazing process, or they may be hermetically welded to each other by an ultrasonic floating process.
  • the two may be hermetically welded to each other by a metal brazing process or an ultrasonic welding process or a fusion welding process.
  • Figure 11 shows an embodiment 7 of the present invention.
  • the metal piece 7-2 of the embodiment 7 is taken out from between two glass plates and the metallized layer on the inner surface of the lower glass plate. 6 Hermetic welded joint, the metal sheet 7-1 is hermetically welded to the metallization layer 6 on the outer surface of the upper glass sheet.
  • Fig. 12 shows an embodiment 8 of the present invention.
  • two metal sheets 7-1, 7-2 are respectively hermetically welded to the metallization layer 6 on the outer surfaces of the two glass sheets.
  • FIG 13 shows a ninth embodiment of the present invention.
  • the vacuum glass in the embodiment is composed of three glass plates.
  • the metallized layer 6 is sintered on the upper and lower surfaces of the glass plate 8 in the middle. Therefore, the metal sheets 7-1, 7-2 are respectively hermetically sealed with the two glass sheets above and below.
  • Figure 14 shows a tenth embodiment of the present invention as a specific embodiment of the present invention, in which the metallization layer 6 is sintered on the edges of the glass sheets 1, 2, and two sheets of glass sheets 1, 2 The edges are sealed by a sheet of metal 7 which is hermetically welded to the metallization layer 6 on the edges of the two sheets of glass.
  • a curved connection may be provided in the middle portion of the metal sheet 7 in the embodiment 10.
  • the embodiment shown in Fig. 14 and Fig. 15 has a simple structure and is convenient to operate, and is particularly suitable for use when the thickness of the glass plate is large.

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  • Geochemistry & Mineralogy (AREA)
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  • Organic Chemistry (AREA)
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Description

一种真空玻璃封接方法及真空玻璃产品 技术领域
本发明涉及一种真空玻璃封接方法以及利用该方法加工的真空玻璃产品。 背景技术
由多片玻璃板复合而成的真空玻璃以其优良的隔音、 隔热、 保温性能受到 人们的重视, 也成为人们竟相研究的课题。
现有真空玻璃的封接方法主要有:
( 1 ) 采用低熔点玻璃料熔化密封, 封接温度一般在 400 °C ~ 500 °C左右, 通 过火焰或电热使低熔点玻璃料熔化而完成玻璃板与玻璃板之间的复合封接。 该 工艺采用的低熔点玻璃通常为铅锌系 (PbO- ZnO )封接玻璃, 由于铅对环境和人 体的危害, 这种材料就长远发展来讲不利于环保要求, 同时其加工设备和工艺 复杂, 复合封接后的玻璃板往往还会产生边缘热应力, 因此还要进行适当的退 火处理, 结果大大降低了生产效率。
( 2 ) 采用各种塑料或树脂材料进行玻璃板之间的复合封接。 有专利文献提 到用有机玻璃, 如: PC、 ABS、 LDPE、 PVC等, 还有的专利文献中釆用 PVB、 EVA
( EN ) 等夹层玻璃的材料, 加工方法都是把上述材料置于两片玻璃板之间作成 预制件, 然后将预制件置于适当的条件下压合而成。 这种工艺类似于制作夹层 玻璃的工艺, 该工艺虽然可以实现玻璃板之间的复合封接, 但大多数塑料和树 脂材料自身的气体渗透率和透湿度都远远大于玻璃, 而且, 大多数有机材料与 玻璃板表面只是物理粘合, 很难保证结合部不渗漏, 而一旦出现气体(包括水 汽) 的渗入, 将直接导致封接强度减弱、 夹层内结露、 玻璃霉变。 另外, 随着 时间的推移, 有机材料的老化问题也直接影响到复合玻璃板的封接效果和寿命。
另外, 以前人们在利用多片玻璃板制作真空玻璃时, 通常将多片玻璃板的 边缘相互刚性连接来完成对玻璃板边缘的封接, 其结构如图 1 所示。 由于真空 玻璃具有优良的隔热保温性能, 使用过程中, 内外层玻璃板 4艮容易出现较大的 温差, 处于高温一侧的玻璃板膨胀, 处于低温一侧的玻璃板收缩, 因此, 图 1 所示结构的真空玻璃不论是作为玻璃窗使用, 还是作为隔热保温构件使用, 都 4艮容易产生如图 2 所示的温度变形, 而一旦这种变形在玻璃板封接边处所形成 的应力超过封接边的承受极限, 必将造成真空玻璃的破坏, 并由此给真空玻璃 的使用场所带来危险。 发明内容
针对现有技术存在的不足, 本发明的目的在于提供一种工艺简便、 封接可 靠、 牢固的真空玻璃封接方法, 利用该方法封接的真空玻璃可良好地适应内外 层玻璃板因温差而产生的变形, 避免封接边处形成过大的温度应力, 保证真空 玻璃的使用安全。 本发明同时还提供一种按照本发明封接方法加工的真空玻璃 产品□
为了达到上述目的, 本发明真空玻璃封接方法具体为:
1 )在玻璃板边缘待封接表面按已知烧结工艺制备与玻璃板固结在一起的金 属化层;
2 )通过在待封接的两片玻璃板的金属化层之间气密焊接连接金属封接片, 实现对两片玻璃板边缘的气密封接。
进一步, 所述烧结工艺具体包括:
1-1 )在玻璃板边缘待封接表面制备金属浆料涂层;
1-2 )加热玻璃板,将金属浆料涂层烧结成与玻璃板固结在一起的金属化层。 进一步, 所述金属浆料涂层以浸涂、 喷涂、 丝网印刷、 手工涂覆或机械涂 覆的方式制备在玻璃板表面上。
进一步, 所述金属封接片由两片金属片构成, 在对两片玻璃板边缘进行气 密封接时, 所述两片金属片首先通过金属钎焊工艺或超声波焊接工艺, 择一地 与待封接的两片玻璃板上的所述金属化层气密焊接连接, 然后再通过将两片金 属片之间气密焊接连接, 来实现对两片玻璃板边缘的气密封接。
进一步, 所述两片金属片被各自引出所连接的玻璃板后, 通过金属钎焊工 艺或超声波焊接工艺或熔化焊工艺相互气密焊接连接。
进一步, 所述两片金属片从所封接的两片玻璃板之间引出, 该两片金属片 分别与所封接的两片玻璃板内表面上的所述金属化层气密焊接连接。
进一步, 所述两片金属片其中之一从所封接的两片玻璃板之间引出, 并与 其中一片玻璃板内表面上的所述金属化层气密焊接连接, 另一个金属片与另一 片玻璃板外表面上的所述金属化层气密焊接连接。
进一步, 所述两片金属片分别与所封接的两片玻璃板外表面上的所述金属 化层气密焊接连接。
进一步, 所述金属化层被制备在所述待封接玻璃板的边沿上; 所述金属封 接片由一片金属片构成, 该金属片采用金属钎焊工艺或超声波焊接工艺分别与 所述待封接的两片玻璃板上的所述金属化层气密焊接连接。
进一步, 所述金属封接片由一个断面为 U形的金属片构成, 该 U形金属片 两侧边分别与待封接的两片玻璃板上的所述金属化层气密焊接连接。
进一步, 所述 U形金属片位于所封接的两片玻璃板之间, 其侧边通过金属 钎焊工艺与所述金属化层气密焊接连接。
进一步, 所述 U形金属片两侧边位于所封接的两片玻璃板之间, 并通过金 属钎焊工艺与所述金属化层气密焊接连接, 金属片上 U形断面底部部分伸出到 两片玻璃板外。
进一步, 所述 U形金属片的其中一个侧边位于所封接的两片玻璃板之间, 并通过金属钎焊工艺或超声波焊接工艺与其中一片玻璃板内表面上的所述金属 化层气密焊接连接, 金属片的另一个侧边绕过另一片玻璃板的边沿后, 通过金 属钎焊工艺或超声波焊接工艺与该玻璃板外表面上的所述金属化层气密悍接连 接。
进一步, 所述 U形金属片包覆所封接的两片玻璃板的边沿, 其两侧边通过 金属钎焊工艺或超声波焊接工艺分别与两片玻璃板外表面上的所述金属化层气 密焊接连接。
一种真空玻璃, 包括相互复合的至少两片玻璃板, 该真空玻璃周边按上述 封接方法进行气密封接。
本发明通过在玻璃板表面烧结金属化层, 并利用该金属化层和金属封接片 对玻璃板边缘进行气密封接, 为制作真空玻璃提供了一种全新的技术手段。 本 发明方法不仅具有封接部位连接牢固、 气密性高、 耐热冲击性好等优点, 而且, 通过采用金属封接片能够很好地适应所封接的两片玻璃板因温差而产生的温度 变形, 避免在真空玻璃封接边处出现过大的应力, 保证真空玻璃的使用安全。 附图说明
图 1为现有真空玻璃结构示意图;
图 2为图 1中现有真空玻璃因内外温差而产生变形时的示意图;
图 3为在玻璃板边缘待封接部位表面烧结金属化层后的示意图;
图 4为本发明真空玻璃实施例 1结构示意图;
图 5为实施例 1中金属片 7的断面形状放大示意图;
图 6为本发明实施例 2结构示意图;
图 7为本发明实施例 3结构示意图;
图 8为本发明实施例 4结构示意图;
图 9为本发明实施例 5结构示意图;
图 10为本发明实施例 6结构示意图; 图 11为本发明实施例 7结构示意图;
图 12为本发明实施例 8结构示意图;
图 13为本发明实施例 9结构示意图;
图 14为本发明实施例 10结构示意图;
图 15为本发明实施例 11结构示意图。
图中 1为上片玻璃板, 2为下片玻璃板, 3为中间支撑物, 4为现有真空玻 璃上的钢性封接边, 5为两片玻璃板之间的真空空间, 6为玻璃板表面烧结的金 属化层, 7为金属片, 7a为断面为 U形的金属片 7的上侧边, 7b为断面为 U形 的金属片 7的下侧边, 7- 1为上片金属片, 7-2为下片金属片, 8为中间玻璃板, 9为金属片 7上的弧形连接段。 具体实施方式
下面结合附图对本发明作进一步说明。
以图 4所示实施例 1为例, 按照本发明封接方法制作真空玻璃时, 首先, 在玻璃板边缘待封接表面制备金属浆料涂层; 然后, 加热玻璃板, 将金属浆料 涂层烧结成与玻璃板固结在一起的金属化层 6,所烧结的金属化层 6如图 3中所 示; 然后, 将待封接的两片玻璃板 1、 2按图 4所示状态进行复合, 在两片玻璃 板 1、 2上相互对应的两个金属化层 6之间设置如图 5所示断面为 U形的金属片 7 , 使金属片 7的两个侧边 7a、 7b分别与上下两片玻璃板上的金属化层 6相对, 并在金属片 7侧边 7a、 7b与金属化层 6之间设置金属钎焊焊料; 最后, 采用金 属钎焊工艺, 将金属片 7上两侧边 7a、 7b与各自对应的金属化层 6气密焊接连 接, 完成对两片玻璃板 1、 2边缘的气密封接。 图 1中 3为设置在两片玻璃板 1、 2之间的中间支撑物, 5为封接后两片玻璃板 1、 2之间形成的真空空间。
上述金属浆料涂层可以采用浸涂、 喷涂、 丝网印刷、 手工涂覆或机械涂覆 等方式将其制备在玻璃板表面上。
对金属浆料涂层进行烧结时, 可以采用激光加热、 火焰加热、 电流加热、 感应力口热或4敫波力口热等力口热方式。
在金属片 7的侧边 7a、 7b与玻璃板 1、 2上的金属化层 6之间设置金属钎 焊焊料时, 可以将钎料加工成金属箔后, 再将其放置在金属片 7 与金属化层 6 之间, 也可以将钎料金属预镀在金属片 7侧边 7a、 7b上, 和 /或预镀在金属化层 6表面, 然后, 再按照金属钎焊工艺完成后续焊接。
所用的钎料可以是锡合金钎料。
上述钎焊焊接过程可以在惰性气体保护下进行, 或在 H2气或 N2气环境中进 行, 还可以在真空环境下进行, 这样有助于提高钎焊焊接质量。
因金属片 7与金属化层 6通过金属钎焊工艺相互焊接连接, 因此,金属片 7 和金属化层 6均应由适于钎焊焊接的金属材料制成。
为了避免焊接过程对玻璃板的性能造成影响, 应控制金属钎焊工艺的温度 < 350 °C。
金属钎焊工艺可以采用感应加热、 激光加热、 微波加热等各种适当的加热 方式。
图 6所示为本发明实施例 2, 在该实施例中, 断面为 U形的金属片 7的两 侧边 7a、 7b位于所封接的上下两片玻璃板之间, 并通过金属钎悍工艺分别与上 下两片玻璃板上的金属化层 6气密焊接连接, 金属片 7上 U形断面底部部分伸 出到两片玻璃板之外。 与图 4中的实施例 1相比, 该实施方式中的金属片 7具 有更大的变形裕度, 可适应两片玻璃板相对出现的更大的温度变形。
在图 7所示的实施例 3中, 断面为 U形的金属片 7包覆所封接的上下两片 玻璃板 1、 2的边沿, 金属片 7的两个侧边 7a、 7b分别与两片玻璃板 1、 2外表 面上的金属化层 6气密焊接连接。
在图 8所示的实施例 4中, 断面为 U形的金属片 7的其中一个侧边位于所 封接的两片玻璃板之间, 并与其中下片玻璃板内表面上的金属化层 6 气密焊接 连接, 金属片 7 的另一个侧边绕过上片玻璃板的边沿后与上片玻璃板外表面上 的金属化层 6气密焊接连接。
需要指出的是, 在制作图 7和图 8所示的真空玻璃时, 金属片 7两侧边与 金属化层 6之间既可以通过金属钎焊工艺相互气密详接连接, 也可以通过超声 波焊接工艺相互气密焊接连接。
上述图 4一图 8所示实施例中的真空玻璃均由两片玻璃板复合而成,利用断 面为 U形的金属片 7作为金属封接片, 也可制作包含 3片和 3片以上玻璃板的 真空玻璃。
在图 9所示的实施例 5中, 真空玻璃由 3片玻璃板复合而成, 与两片玻璃 板复合的真空玻璃所不同的是, 位于中间的玻璃板 8 的两侧表面上均要烧结金 属化层 6, 以便通过断面为 U形的金属片 Ί分别与其上方和下方的两片玻璃板 进行气密封接。
本发明封接方法中所用的金属封接片既可以由一片金属片构成, 也可以由 两片金属片构成。
当金属封接片由两片金属片构成时, 其封接步骤如下:
以图 10所示实施例 6为例, 首先, 如前所述, 在玻璃板边缘待封接表面烧 结图 3所示的与玻璃板固结在一起的金属化层 6; 然后,将上下两片金属片 7-1、 7-2分别与上下两片玻璃板 1、 2上的金属化层 6气密焊接连接,并将金属片 7-1、 7-2引出到其所连接的玻璃板之外; 最后, 将两片玻璃板 1、 2按图 10所示状态 进行复合, 并将两片金属片 7-1、 7-2上伸出到两片玻璃板之外的部分相互气密 焊接连接, 实现对两片玻璃板 1、 2边缘的气密封接。
金属片 7-1、 7-2与玻璃板 1、 2上的金属化层 6之间可以通过金属钎焊工艺 相互气密焊接连接, 也可以采用超声波浮接工艺将其相互气密焊接连接。
对于两片金属片 7-1、 7-2上伸出到玻璃板之外的部分之间的连接, 可采用 金属钎焊工艺或超声波焊接工艺或熔化焊工艺将二者相互气密焊接连接。
图 11所示为本发明实施例 7 , 与实施例 6相比, 实施例 7中的金属片 7-2 从两片玻璃板之间引出, 并与下片玻璃板内表面上的金属化层 6气密焊接连接, 金属片 7-1与上片玻璃板外表面上的金属化层 6气密焊接连接。
图 12所示为本发明实施例 8 , 在该实施例中, 两片金属片 7-1、 7-2分别与 两片玻璃板外表面上的金属化层 6气密焊接连接。
图 1 3所示为本发明实施例 9 , 该实施例中的真空玻璃由 3片玻璃板复合而 成, 如前所述, 位于中间的玻璃板 8的上下表面均要烧结金属化层 6, 以便通过 金属片 7- 1、 7-2分别与其上方和下方的两片玻璃板进行气密封接。
图 14所示为本发明实施例 10,作为本发明的一种特殊实施方式, 在该实施 例中, 金属化层 6烧结在玻璃板 1、 2的边沿上, 并且两片玻璃板 1、 2的边缘 通过一片金属片 7进行封接, 金属片 Ί分别与两片玻璃板边沿上的金属化层 6 气密焊接连接。
为了使金属片 7 能够适应内外层玻璃板边沿因温差而相对出现较大的伸缩 变形, 如图 15中实施例 11所示, 可以在实施例 10中的金属片 7的中间部位设 置弧形连接段 9。
图 14、 图 15所示实施例结构简单, 操作方便, 尤其适合玻璃板厚度较大时 采用。
上述示例只是用于说明本发明, 本发明的实施方式并不限于这些示例, 本 领域技术人员所做出的符合本发明思想的各种具体实施方式都在本发明的保护 范围之内。

Claims

权利 要求
1、 一种真空玻璃封接方法, 其特征在于, 该封接方法具体为:
1 )在玻璃板边缘待封接表面按已知烧结工艺制备与玻璃板固结在一起的金 属化层;
2 )通过在待封接的两片玻璃板的金属化层之间气密焊接连接金属封接片, 实现对两片玻璃板边缘的气密封接。
2、 如权利要求 1所述的方法, 其特征在于, 所述烧结工艺具体包括:
1-1 )在玻璃板边缘待封接表面制备金属浆料涂层;
1-2 )加热玻璃板,将金属浆料涂层烧结成与玻璃板固结在一起的金属化层。
3、 如权利要求 2所述的方法, 其特征在于, 所述金属浆料涂层以浸涂、 喷涂、 丝网印刷、 手工涂覆或机械涂覆的方式制备在玻璃板表面上。
4、 如权利要求 1-3任一所述的方法, 其特征在于, 所述金属封接片由两片金属 片构成, 在对两片玻璃板边缘进行气密封接时 , 所述两片金属片首先通过金属 钎焊工艺或超声波焊接工艺, 择一地与待封接的两片玻璃板上的所述金属化层 气密焊接连接, 然后再通过将两片金属片之间气密焊接连接, 来实现对两片玻 璃板边缘的气密封接。
5、 如权利要求 4所述的方法, 其特征在于, 所述两片金属片被各自引出所连接 的玻璃板后, 通过金属钎焊工艺或超声波焊接工艺或熔化焊工艺相互气密焊接 连接。
6、 如权利要求 4所述的方法, 其特征在于, 所述两片金属片从所封接的两片玻 璃板之间引出, 该两片金属片分别与所封接的两片玻璃板内表面上的所述金属 化层气密焊接连接。
7、 如权利要求 4所述的方法, 其特征在于, 所述两片金属片其中之一从所封接 的两片玻璃板之间引出, 并与其中一片玻璃板内表面上的所述金属化层气密焊 接连接, 另一个金属片与另一片玻璃板外表面上的所述金属化层气密焊接连接。
8、 如权利要求 4所述的方法, 其特征在于, 所述两片金属片分别与所封接的两 片玻璃板外表面上的所述金属化层气密焊接连接。
9、 如权利要求 1所述的方法, 其特征在于, 所述金属化层被制备在所述待封接 玻璃板的边沿上; 所述金属封接片由一片金属片构成, 该金属片采用金属钎焊 工艺或超声波焊接工艺分别与所述待封接的两片玻璃板上的所述金属化层气密 焊接连接。
10、 如权利要求 9 所述的方法, 其特征在于, 所述金属封接片上分别与所述待 封接的两片玻璃板上的所述金属化层气密焊接连接的两部分之间还设置有弧形 连接段。
11、 如权利要求 1-3任一所述的方法, 其特征在于, 所述金属封接片由一个断 面为 U形的金属片构成, 该 U形金属片两侧边分別与待封接的两片玻璃板上的 所述金属化层气密焊接连接。
12、 如权利要求 11所述的方法, 其特征在于, 所述 U形金属片位于所封接的两 片玻璃板之间, 其侧边通过金属钎焊工艺与所述金属化层气密焊接连接。
13、 如权利要求 11所述的方法, 其特征在于, 所述 U形金属片两侧边位于所封 接的两片玻璃板之间, 并通过金属钎焊工艺与所述金属化层气密焊接连接, 金 属片上 U形断面底部部分伸出到两片玻璃板外。
14、 如权利要求 11所述的方法, 其特征在于, 所述 U形金属片的其中一个侧边 位于所封接的两片玻璃板之间, 并通过金属钎焊工艺或超声波焊接工艺与其中 一片玻璃板内表面上的所述金属化层气密焊接连接, 金属片的另一个侧边绕过 另一片玻璃板的边沿后, 通过金属钎焊工艺或超声波焊接工艺与该玻璃板外表 面上的所述金属化层气密焊接连接。
15、 如权利要求 11所述的方法, 其特征在于, 所述 U形金属片包覆所封接的两 片玻璃板的边沿, 其两侧边通过金属钎焊工艺或超声波焊接工艺分別与两片玻 璃板外表面上的所述金属化层气密焊接连接。
16、 一种真空玻璃, 包括相互复合的至少两片玻璃板, 其特征在于, 该真空玻 璃周边按上述权利要求 1-15任一所述方法进行气密封接。
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