WO2010082530A1 - 化粧料 - Google Patents
化粧料 Download PDFInfo
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- WO2010082530A1 WO2010082530A1 PCT/JP2010/050124 JP2010050124W WO2010082530A1 WO 2010082530 A1 WO2010082530 A1 WO 2010082530A1 JP 2010050124 W JP2010050124 W JP 2010050124W WO 2010082530 A1 WO2010082530 A1 WO 2010082530A1
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- polyurethane
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/044—Suspensions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/60—Particulates further characterized by their structure or composition
- A61K2800/61—Surface treated
Definitions
- the present invention relates to a cosmetic containing a polyurethane particle group, and particularly to a cosmetic containing a polyurethane particle group having excellent sebum absorption.
- Patent Document 1 uses polyurethane particles made of hexamethylene diisocyanate / trimethylol hexyl lactone crosslinked polymer / silicic anhydride.
- the present inventor has discovered that polyurethane particles having a specific configuration are excellent in sebum absorption (Japanese Patent Application No. 2008-310341). If the present inventors include such a group of polyurethane particles as a component of cosmetics, in order to give a conventional slip feeling or hide fine lines and pores and absorb sebum well, I thought that it would be possible to obtain cosmetics with a long period of time. Then, when it evaluated using the cosmetics with which this polyurethane particle group was mix
- the present invention relates to a cosmetic comprising a polyurethane particle group, wherein the polyurethane particle has a polyurethane particle body surface coated with a hydrophilic silica fine powder group, and the polyurethane particle body comprises a polyisocyanate component and polytetramethylene.
- the present invention relates to a cosmetic characterized in that an isocyanate-terminated urethane prepolymer obtained by a reaction with a polyol component containing glycol is three-dimensionally polymerized with a trifunctional or higher polyfunctional amine.
- the polyurethane particle means a single particle in which the surface of the polyurethane particle body is coated with a hydrophilic silica fine powder group.
- the polyurethane particle group means a large number of polyurethane particles, that is, an aggregate of polyurethane particles. That is, “group” is used in the meaning of “s” added to the end of an English noun to indicate a plurality.
- the polyurethane particle body means a product obtained by removing the hydrophilic silica fine powder group from the polyurethane particles.
- the present invention relates to a cosmetic containing a polyurethane particle group.
- the polyurethane particles are obtained by coating the surface of the polyurethane particle body with a hydrophilic silica fine powder group.
- the hydrophilic silica fine powder used in the present invention is a fine powder mainly composed of SiO 2 and having substantially no hydrophobic group on the surface thereof.
- Such hydrophilic silica fine powder is conventionally known, for example, Aerosil 200, 200V, 200CF, 200FAD, 300, 300CF, 380, 50, 90G, 130, OX50, MOX80, sold by Nippon Aerosil Co., Ltd. MOX170, COK84, etc. are known.
- such conventionally known hydrophilic silica fine powder is used.
- the particle size of the hydrophilic silica fine powder should just be finer than the particle size of the polyurethane particle obtained.
- the surface of the polyurethane particle body is covered with the hydrophilic silica fine powder group.
- the average particle size of the obtained polyurethane particle group is 1 to 50 ⁇ m, and the average particle size of the hydrophilic silica fine powder group is 5 to 40 nm. It is preferably at least 20 times the particle size of the powder.
- the average particle diameter of hydrophilic silica fine powder group it is a nominal value.
- any conventionally known compound may be used as long as it is a compound having two or more isocyanate groups in the molecule.
- polytetramethylene glycol is used as a polyol component used for polyurethane production.
- polyol components may be appropriately mixed together with polytetramethylene glycol. Any other polyol component may be used as long as it is conventionally used for producing polyurethane.
- the number average molecular weight of polytetramethylene glycol is a matter that can be appropriately determined, but in the present invention, those having a number average molecular weight of 650 to 3000 are generally used.
- the trifunctional or higher polyfunctional amine used for the production of polyurethane is for three-dimensionally polymerizing a urethane prepolymer obtained by reacting a polyisocyanate component and a polyol component.
- a trifunctional or higher polyfunctional amine diethylenetriamine, triethylenetetramine, tetraethylenepentamine, 3,3'-diaminodipropylamine, and the like are used.
- the polyurethane particles used in the present invention can be obtained, for example, by the following method using the raw materials described above.
- a step of removing the dispersant from water to obtain an aqueous polyurethane sphere dispersion liquid, and the polyurethane sphere aqueous dispersion liquid and the hydrophilic silica fine powder group in water After obtaining a polyurethane sphere group by polymerizing the polyurethane sphere group, a step of removing the dispersant from water to obtain an aqueous polyurethane sphere dispersion liquid, and the polyurethane sphere aqueous dispersion liquid and the hydrophilic silica fine powder group in water.
- the polyurethane dispersion is sprayed in a high-temperature atmosphere using a spray dryer to evaporate water, thereby forming polyurethane particle body groups with the polyurethane sphere groups, and the hydrophilic silica on each polyurethane particle body surface.
- a polyurethane particle group can be obtained through a process of coating the fine powder group.
- a polyisocyanate component and a polyol component containing polytetramethylene glycol are reacted by a well-known method to obtain an isocyanate-terminated urethane prepolymer.
- the number of moles of the NCO group of the polyisocyanate component may be excessively increased with respect to the number of moles of the OH group of the polyol component.
- this reaction is generally carried out by dissolving in an organic solvent such as ethyl acetate or methyl ethyl ketone, and using a tin-based catalyst such as dibutyltin dilaurate or an amine-based catalyst such as diazabicycloundecene.
- organic solvent such as ethyl acetate or methyl ethyl ketone
- a tin-based catalyst such as dibutyltin dilaurate or an amine-based catalyst such as diazabicycloundecene.
- the polyol component containing polytetramethylene glycol is generally composed only of polytetramethylene glycol, but may be a mixture of polytetramethylene glycol and other polyols.
- polyols conventionally known polyhydric alcohols, polyether polyols, polyester polyols, polycarbonate polyols, polyolefin polyols, polyacrylic polyols, or castor oil can be used.
- the polytetramethylene glycol is preferably mixed in a proportion of 50% by mass or more.
- polytetramethylene glycol is a component that improves the sebum absorption capacity, if it is less than 50% by mass, the sebum absorption capacity tends to be insufficient.
- the polyurethane particle body made of polyurethane spheres when 100% by mass of polytetramethylene glycol is used, the polyurethane particle body tends to be flexible, and when polycarbonate polyol is mixed as another polyol, As the content thereof increases, the polyurethane particle body gradually becomes harder.
- the isocyanate group (NCO group) content of the isocyanate-terminated urethane prepolymer is about 2.0 to 10% by mass, and preferably 2.5 to 3.5% by mass.
- the isocyanate group content exceeds 10% by mass, the content of urethane bonds increases so that the sebum absorption ability tends to be insufficient.
- the isocyanate group content is less than 2.0% by mass, the molecular weight of the isocyanate-terminated urethane prepolymer increases and the viscosity increases, so that the handleability and workability tend to deteriorate.
- an isocyanate-terminated urethane prepolymer After obtaining an isocyanate-terminated urethane prepolymer, this is added to an aqueous solution in which a dispersant is dissolved and stirred to obtain an oil-in-water emulsion. Specifically, an oil-in-water emulsion is obtained by the following method.
- an aqueous solution in which the dispersant is dissolved is prepared.
- Any dispersant can be used as long as it can emulsify the isocyanate-terminated urethane prepolymer in water.
- known surfactants such as various surfactants such as nonionic surfactants and various polymer dispersants such as polyvinyl alcohol are used.
- this dispersant is dissolved in water to obtain an aqueous solution.
- the dispersant is dissolved in water, it is preferable to warm the water so that the dispersant is easily dissolved. And after a dispersing agent melt
- the degree of warming can be appropriately determined depending on the solubility of the dispersant, but for example, when polyvinyl alcohol having a saponification degree of about 86.5 to 89.0 is used, it is about 90 ° C.
- the concentration of the dispersing agent can be appropriately determined based on the degree to which the isocyanate-terminated urethane prepolymer is emulsified and dispersed. Generally, the concentration is about 3 to 20% by mass.
- the isocyanate-terminated urethane prepolymer is added to the aqueous dispersant solution cooled to room temperature and stirred.
- the addition amount of the isocyanate-terminated urethane prepolymer may be arbitrary, and is generally about 3 to 20 parts by mass with respect to 100 parts by mass of the aqueous dispersant solution.
- the stirring means and the degree of stirring can be appropriately determined so that the isocyanate-terminated urethane prepolymer is emulsified and dispersed to a desired particle size.
- a known stirrer such as a homomixer, a homogenizer, a high-pressure homogenizer, or an ultrasonic disperser can be used.
- the degree of stirring for example, when a homomixer is used, it is about 8000 rpm for about 5 minutes.
- addition stirring is normally performed at room temperature, in order to make it easy to stir especially, you may carry out slightly heating.
- trifunctional or higher functional amine is added here.
- the trifunctional or higher polyfunctional amine is for obtaining a polyurethane having a network structure by three-dimensionally polymerizing an isocyanate-terminated urethane prepolymer, and various compounds can be used.
- the polyfunctional amine is added as it is or in the form of a solution dissolved in a solvent such as water.
- the addition amount of the polyfunctional amine is preferably equivalent to the isocyanate group of the isocyanate-terminated urethane prepolymer in the oil-in-water emulsion.
- the polyfunctional amine in such an amount that the amino group of the polyfunctional amine and the isocyanate group of the isocyanate-terminated urethane prepolymer are equivalent.
- the amino group of the polyfunctional amine reacts with the isocyanate group of the isocyanate-terminated urethane prepolymer to polymerize in three dimensions. Therefore, in order to suppress three-dimensional polymerization, the amount of polyfunctional amine added may be slightly less than the equivalent, for example, 0.8 equivalent or more and less than 1.0 equivalent. In order to ensure three-dimensional polymerization, the amount of polyfunctional amine added may be slightly larger than the equivalent, for example, more than 1.0 equivalent and 1.2 equivalent or less.
- a polyfunctional amine having 3 or more functional groups but also a compound that reacts with an isocyanate group such as a bifunctional amine or a polyhydric alcohol may be added together with the polyfunctional amine. Since these compounds suppress or promote the three-dimensional polymerization of the isocyanate-terminated urethane prepolymer, the degree of the three-dimensional polymerization can be adjusted.
- heating is generally used to accelerate the polymerization reaction. And do it. What is necessary is just to determine the temperature of a heating suitably according to the reactivity of a polyfunctional amine. For example, when 3,3'-diaminodipropylamine is employed as the polyfunctional amine, when the temperature of the oil-in-water emulsion is about 80 ° C., the three-dimensional polymerization reaction is almost completed in about 20 hours.
- the oil droplets in the oil-in-water emulsion become polyurethane spheres. That is, a dispersion in which polyurethane sphere groups are dispersed is obtained. Since the dispersant remains in this dispersion, it is removed.
- a means such as filtration or centrifugation is applied to the dispersion to recover the polyurethane sphere group, and water is added to the dispersion to redisperse the dispersion, and a means such as filtration or centrifugation is used. Apply.
- the dispersant is almost completely removed, and an aqueous polyurethane sphere dispersion in which the polyurethane sphere group is dispersed in water is obtained.
- an aqueous silica dispersion in which hydrophilic silica fine powder groups are dispersed in water is prepared.
- the aqueous silica dispersion can be easily prepared by adding and stirring the hydrophilic silica fine powder group in water.
- the conditions for the addition stirring and the like, and the concentration of the hydrophilic silica fine powder group in the silica aqueous dispersion can be appropriately determined so that the hydrophilic silica fine powder group is uniformly dispersed in water without agglomeration.
- the silica aqueous dispersion can be easily obtained by stirring for 10 minutes at 10,000 rpm using a homomixer. Can be obtained.
- the silica aqueous dispersion obtained above and the polyurethane sphere aqueous dispersion obtained above are mixed to obtain a mixed aqueous dispersion.
- the mixing ratio of both is a matter that can be appropriately determined as long as the amount of the hydrophilic silica fine powder group and the polyurethane sphere group, which are solid contents, is appropriate, and is arbitrary.
- the amount of water added is also a matter that can be determined as appropriate, but it is preferably about the same mass part as the polyurethane sphere aqueous dispersion.
- the obtained mixed aqueous dispersion is dried using a spray dryer.
- a drying mode is generally referred to as spray drying, and there are a nozzle spray method and a disk spray method.
- the mixed aqueous dispersion is sprayed and dried in a high temperature atmosphere from a hole such as a nozzle.
- the disk is rotated and the mixed aqueous dispersion is sprayed and dried in a high temperature atmosphere by centrifugal force.
- the feature of the spray drying in the present invention is that each of the polyurethane sphere groups present in the mixed aqueous dispersion is sprayed in the form as it is, that is, without being atomized at the time of spraying.
- the polyurethane spheres in the mixed aqueous dispersion are three-dimensionally polymerized and are not destroyed even when sprayed.
- the hydrophilic silica fine powder group is present in the water, and therefore, the hydrophilic silica fine powder group adheres to the polyurethane sphere surface during drying.
- the high-temperature atmosphere introduced for drying can be appropriately determined so as to have a desired water evaporation capability.
- it can fully dry by spraying in the high temperature atmosphere generally employ
- the polyurethane spheres when the polyurethane spheres are sprayed and dried, the polyurethane spheres remain as one piece, or two or more of them join together to form the polyurethane particle body.
- the polyurethane sphere is soft or the surface thereof is sticky, two or more of them are easily bonded to form a polyurethane particle body.
- the polyurethane sphere is hard, the polyurethane particle body tends to remain as it is.
- the polyurethane spheres become the polyurethane particle main body, and the surface of the particle main body is covered with the hydrophilic silica fine powder group.
- the hydrophilic silica fine powder group may simply cover the surface of the particle main body, or may cover the part of the hydrophilic silica fine powder embedded in the particle main body. The latter state occurs when the polyurethane sphere or the polyurethane particle body is relatively soft.
- the average particle size of the polyurethane particles obtained is the average particle size of the polyurethane spheres produced when preparing the mixed aqueous dispersion, the property that the polyurethane particles are soft or the surface is sticky, the conditions of spray drying, etc.
- the average particle diameter of a polyurethane particle group is an average primary particle diameter, and is measured by the following methods. That is, the primary particle diameter of each of 100 particles is measured with an optical microscope, an electron microscope, or the like, and the number average is obtained. At this time, when two or several polyurethane particles are aggregated, the aggregation is released, and the primary particle size of each dispersed particle is measured.
- the polyurethane particles used in the present invention may be directly added to the cosmetic base, or may be added to the cosmetic base after a known hydrophobic treatment such as silicone treatment or fluorine treatment.
- the polyurethane particles used in the present invention absorb sebum and oleic acid well, but also absorb other oils to some extent. Therefore, various oils, medicinal components, ultraviolet absorbers, moisturizers, emollient components, fragrance components, bactericides, antioxidants, etc. may be absorbed and supported to such an extent that the sebum absorption ability does not extremely decrease.
- the blending amount of the polyurethane particle group is a matter that can be determined as appropriate, but generally 0.1 to 30% by weight, more preferably 1 to 20% by weight, and still more preferably based on the total amount of the cosmetic. 3 to 15% by mass.
- any conventionally known base can be used. Since the polyurethane particles used in the present invention absorb oil to some extent, it is preferable to employ a cosmetic base with as little oil as possible.
- the properties of the cosmetics according to the present invention are matters that can be determined as appropriate, and are generally solid cosmetics, solid powder cosmetics, gel cosmetics (cream cosmetics), or liquid cosmetics.
- the solid cosmetic is obtained by molding a cosmetic base and solidifying it to a certain size. Solid cosmetics are used in facial cleansing cosmetics, foundations and the like.
- the solid powder cosmetic is a cosmetic whose appearance is in the form of a powder, and generally has a powder amount of 80% by mass or more based on the total amount of the cosmetic amount.
- Solid powder cosmetics are used in foundations, white powder, eye shadow, teak, body powder, deodorant powder, fragrance powder, and the like.
- Gel cosmetics are so-called jelly-like cosmetics, and are used for hair styling, basic cosmetics, hand creams, and the like.
- a liquid cosmetic is a cosmetic that has become liquid like an aqueous solution or an emulsion.
- Liquid cosmetics are used in lotions, milky lotions, basic cosmetics, hair styling, and the like.
- it is good also as a sheet-like cosmetic material by containing or impregnating solid powder cosmetics or liquid cosmetics in sheets, such as a nonwoven fabric. In the sheet-like cosmetic, the solid powder cosmetic or liquid cosmetic is applied to the skin by wiping the skin with this.
- the cosmetic according to the present invention can be used as a conventionally known cosmetic.
- it can be used as makeup cosmetics, skin care cosmetics, acne care cosmetics, antiperspirant cosmetics, UV protection cosmetics, hair cosmetics, pack cosmetics or fragrance cosmetics.
- a drug that is gradually released from the polyurethane particles and can be used over a long period of time is obtained.
- the cosmetic according to the present invention includes a group of polyurethane particles having excellent sebum absorbability. Therefore, if the cosmetic according to the present invention is applied to the skin or hair, the sebum secreted from the surface of the skin or the like is well absorbed. Therefore, it is difficult for sebum to stay between the surface of the skin or the like and the cosmetic, and it is possible to prevent makeup from being removed due to the sebum staying. That is, when used as a conventionally known cosmetic such as the makeup cosmetics described above, it is possible to prevent the makeup from being removed and to maintain the original makeup effect for a long time.
- Production example 1 of polyurethane particle group [Preparation of isocyanate-terminated urethane prepolymer] A four-necked separable flask equipped with a stirrer, a nitrogen inlet tube, a thermometer, and a condenser was charged with 300 parts by mass of polytetramethylene glycol ether (number average molecular weight 1000) and 20 parts by mass of ethyl acetate, and isophorone diisocyanate 104.6. Part by mass and 0.04 part by mass of dibutyltin dilaurate were added, and the reaction was carried out at a temperature of 75 to 80 ° C. under a nitrogen stream for 5 hours to obtain an isocyanate-terminated urethane prepolymer having an isocyanate group content of 3.6%.
- aqueous silica dispersion [Preparation of aqueous silica dispersion] Separately, 95 mass parts of deionized water was charged into a stirrer, and a hydrophilic silica fine powder group (trade name “Aerosil 200” manufactured by Nippon Aerosil Co., Ltd., average particle diameter of about 20 nm) was stirred with a homomixer at 10,000 rpm. 5 parts by mass was added and mixed with stirring for 10 minutes to obtain an aqueous silica dispersion.
- a hydrophilic silica fine powder group trade name “Aerosil 200” manufactured by Nippon Aerosil Co., Ltd., average particle diameter of about 20 nm
- each polyurethane particle had a particle body surface coated with a hydrophilic silica fine powder group.
- Each polyurethane particle group was hardly fused and hardly agglomerated, and was in a state of being separated and separated one by one.
- the average particle size of the polyurethane particle group was about 12 ⁇ m.
- Production example 2 of polyurethane particle group [Preparation of isocyanate-terminated urethane prepolymer]
- the isocyanate group content is 2. in the same manner as in Production Example 1, except that polytetramethylene glycol ether having a number average molecular weight of 3000 is used and the addition amount of isophorone diisocyanate is 45.0 parts by mass. A 5% isocyanate-terminated urethane prepolymer was obtained.
- a polyurethane sphere aqueous solution was prepared in the same manner as in Production Example 1, except that the above oil-in-water emulsion was used and the addition amount of a 10% aqueous solution of 3,3′-diaminodipropylamine was 24.5 parts by mass. A dispersion was obtained.
- a silica aqueous dispersion was obtained in the same manner as in Production Example 1.
- a mixed aqueous dispersion was obtained in the same manner as in Production Example 1, except that the polyurethane sphere aqueous dispersion was used.
- a polyurethane particle group was obtained in the same manner as in Production Example 1 except that the above mixed aqueous dispersion was used. The properties of this polyurethane particle group were the same as those obtained in Production Example 1. The average particle size of the polyurethane particle group was about 15 ⁇ m.
- Example 1 A solid powder cosmetic (foundation) having the following composition was obtained.
- Polyurethane particle group of Production Example 1 5% by mass Silicone-treated mica 20% by mass Mica 5% by mass Methyl hydrogen polysiloxane-coated titanium oxide 10% by mass Fine particle titanium oxide 5% by mass Alkyl-treated iron oxide 3.44% by mass Silicone elastomer (“KSP-100” manufactured by Shin-Etsu Chemical Co., Ltd.) 8% by mass Active zinc white 8.5% by mass Barium sulfate / aluminum oxide coated mica 6% by mass Chlorphenesin 0.2% by mass Olefin oligomer 1% by mass Methylphenylpolysiloxane 2% by mass 2.5% by mass of diisostearyl malate 2-Methyl paramethoxycinnamate 3% by weight Sorbitan sesquiisostearate 1.2% by mass Tocopherol 0.02% by mass Methyl hydrogen polysiloxane coated talc
- Example 2 A solid powder cosmetic was obtained with the same composition and blending amount as in Example 1 except that the blending amounts of the polyurethane particles and the silicone elastomer in the solid powder cosmetic according to Example 1 were changed as follows. 10% by mass of polyurethane particles in Production Example 1 Silicone elastomer (“KSP-100” manufactured by Shin-Etsu Chemical Co., Ltd.) 3% by mass
- Example 3 The solid powder cosmetic composition has the same composition and blend amount as in Example 1 except that the blending amount of the polyurethane particles in the solid powder cosmetic composition according to Example 1 is changed as follows and no silicone elastomer is used.
- Comparative Example 1 Solid powder makeup with the same composition and blending amount as in Example 1 except that the polyurethane particles in the solid powder cosmetic according to Example 1 were not used and the blending amount of the silicone elastomer was changed as follows. I got a fee. Polyurethane particles in Production Example 1 (not used) Silicone elastomer (“KSP-100” manufactured by Shin-Etsu Chemical Co., Ltd.) 13% by mass
- Comparative Example 2 Instead of 5 mass% of the polyurethane particles in the solid powder cosmetic according to Example 1, hexamethylene diisocyanate / trimethylol hexyl lactone cross-linked polymer / silicic anhydride (“PLASTIC POWDER D-400” manufactured by Toshi Pigment Co., Ltd., average A solid powder cosmetic was obtained with the same composition and blending amount as in Example 1 except that 5% by mass (particle size: about 13 ⁇ m) was used.
- Example 4 A solid powder cosmetic (loose powder) having the following composition was obtained.
- Polyurethane particle group of Production Example 2 8.5% by mass Silicone-treated mica 20% by mass Iron oxide 0.05% by mass Active zinc white 1% by mass Zinc myristate 4% by mass Methyl hydrogen polysiloxane coated talc
- Comparative Example 3 Instead of 8.5% by mass of the polyurethane particles in the solid powder cosmetic according to Example 4, hexamethylene diisocyanate / trimethylol hexyl lactone cross-linked polymer / silicic anhydride (“PLASTIC POWDER D-400” manufactured by Tohoku Pigment Co., Ltd.) A solid powder cosmetic was obtained with the same composition and blending amount as in Example 4 except that 8.5% by mass) (average particle size of about 13 ⁇ m) was used.
- Example 4 is different from Example 4 except that 8.5% by mass of the silicone elastomer (“KSP-100” manufactured by Shin-Etsu Chemical Co., Ltd.) is used in place of 8.5% by mass of the polyurethane particle group in the solid powder cosmetic according to Example 4.
- KSP-100 manufactured by Shin-Etsu Chemical Co., Ltd.
- a solid powder cosmetic was obtained with the same composition and blending amount.
- Example 4 using a specific polyurethane particle group used in the present invention is more compared to Comparative Example 3 using a conventional polyurethane particle group and Comparative Example 4 using a conventional silicone elastomer. It can be seen that the effect of makeup retention is improved. This indicates that the specific polyurethane particle group used in the present invention has good sebum absorbability, thereby preventing makeup removal due to sebum.
- Example 5 A solid powder cosmetic (powder foundation) having the following composition was obtained.
- Polyurethane particle group of Production Example 1 5% by mass Dimethylpolysiloxane 5% by mass Isostearic acid 0.5% by mass 3% by mass of diisostearyl malate 1% by mass of glyceryl tri-2-ethylhexanoate 1% by weight sorbitan sesquiisostearate
- Spherical PMMA polymethylmethacrylate
- -coated mica 6% by mass Pearl agent 1% by mass Fine zinc oxide 0.5% by mass Fine titanium oxide 2% by mass Synthetic phlogopite 2% by mass Metal soap treated talc 8% by mass Vitamin E acetate 0.1% by mass ⁇ -Tocopherol 0.1% by mass Ethylparaben
- Appropriate amount Methyl bis (trimethylsiloxy) silylisopentyl trimethoxycinnamate 1% by mass 2-methoxyhexyl paramethoxyc
- Example 6 A solid powder cosmetic (powder foundation) having the following composition was obtained.
- Polyurethane particle group of Production Example 1 8% by mass Synthetic hydrocarbon wax particles 2% by mass Dimethylpolysiloxane 6% by mass Purified lanolin 5% by mass Glyceryl tri-2-ethylhexanoate 2% by mass Sorbitan sesquiisostearate 0.5% by mass Acicular fine particle titanium oxide 5% by mass Fine zinc oxide 1% by mass Silicone-coated iron oxide / titanium oxide sintered product 7% by mass Barium sulfate 8% by mass Titanium reduction-treated mica titanium pearl pigment 2% by mass Silicone-coated synthetic phlogopite 5% by mass Silicone-coated talc 2% by mass Silicone-coated mica 15% by mass Stearyl glycyrrhetinate 0.1% by mass Ascorbyl dipalmitate 0.1% by mass DL- ⁇ -tocopherol acetate 0.1% by mass D- ⁇ -tocopherol 0.1%
- Example 7 A liquid cosmetic (skin lotion) having the following composition was obtained.
- 3% by mass of polyurethane particles in Production Example 1 Ethanol 5% by mass Glycerin 1% by mass 1,3-butylene glycol 5% by mass Polyoxyethylene polyoxypropylene decyl tetradecyl ether 0.2% by mass Sodium hexametaphosphate 0.03% by mass Trimethylglycine 1% by mass Sodium polyaspartate 0.1% by mass ⁇ -tocopherol 2-L-ascorbic acid potassium phosphate diester 0.1% by mass Thiotaurine 0.1% by mass Green tea extract 0.1% by mass Western mint extract 0.1% by mass Iris root extract 0.1% by mass EDTA3 sodium 0.1% by mass Carboxyvinyl polymer 0.05% by mass Potassium hydroxide 0.02% by mass Phenoxyethanol appropriate amount Fragrance appropriate amount Purified water Residue
- Example 8 A liquid cosmetic (skin lotion) having the following composition was obtained.
- 1% by mass of polyurethane particles in Production Example 1 Ethanol 10% by mass Glycerin 2% by mass Isostearic acid 0.1% by mass 1% by mass of poly (oxyethylene / oxypropylene) / methylpolysiloxane copolymer Lauryldimethylaminoacetic acid betaine 0.1% by mass Citric acid 0.02% by mass Sodium citrate 0.08% by mass Sodium hexametaphosphate 0.01% by mass Hipotaurine 0.1% by mass Chamomile extract 0.1% by mass Lavender oil 0.001% by mass Phenoxyethanol appropriate amount Active hydrogen water 1% by mass Purified water residue
- Example 9 A liquid cosmetic (skin lotion) having the following composition was obtained.
- 1% by mass of polyurethane particles in Production Example 1 Ethanol 40% by mass Dipropylene glycol 1% by mass Polyoxyethylene polyoxypropylene decyl tetradecyl ether 0.1% by mass Silica anhydride 1% by mass Salicylic acid 0.1% by mass Sodium citrate 0.2% by mass Zinc paraphenolsulfonate 0.2% by mass Dipotassium glycyrrhizinate 0.1% by mass Pyridoxine hydrochloride 0.1% by mass L-menthol 0.05% by mass EDTA3 sodium 0.05 mass% Bentonite 0.8% by mass Purified water residue
- Example 10 A powder cosmetic (deodorant spray) having the following composition was obtained.
- (Powder part) Polyurethane particle group of Production Example 1 1.5% by mass Alum (average particle size 20 ⁇ m) 3% by mass 2% by mass of silver ion, zinc ion, ammonium ion-supported zeolite (average particle size is about 5 ⁇ m, and particle size exceeding 15 ⁇ m is 1% by mass or less)
- Ole Polyoxyethylene nonylphenyl ether 0.5% by mass Dimethylpolysiloxane (20 mPa ⁇ s, 25 ° C.) 0.1% by mass Isopropyl myristate 0.5% by mass
- (Additive) Polyoxyethylene sorbitan monooleate 0.1% by mass Fragrance 0.1% by mass (Propellant) 92% by mass of liquefied petroleum gas
- this deodorant spray is obtained by the following manufacturing method.
- the powder part is mixed with a kneader.
- the oil is mixed with a blender and the additive is added to the mixed oil.
- the oil part with which the powder part and the additive were added was filled in the spray can sequentially, and also the propellant was filled in the can, and the deodorant spray was obtained.
- Example 11 A solid powder cosmetic (loose powder) having the following composition was obtained. 20% by mass of polyurethane particles of Production Example 1 Alkyl-modified silicone resin-coated mica titanium 25% by mass Alkyl-modified silicone resin-coated sericite 30% by mass Mukuroji extract 0.01% by mass Hemp cellulose powder 0.1% by mass Alkyl-modified silicone resin coated talc
- Example 12 A liquid cosmetic (water-in-oil makeup base) having the following composition was obtained. 3% by mass of polyurethane particles in Production Example 1 Dimethylpolysiloxane (6 mPa ⁇ s) 5% by mass Decamethylcyclopentasiloxane 30% by mass Polyoxyethylene / methylpolysiloxane copolymer 3% by mass 1% by mass of dodecamethylcyclohexasiloxane Glycerin 5% by mass Dipropylene glycol 5% by mass Sage oil 0.1% by mass Talc 0.1% by mass Mica titanium 0.1% by mass Polymethylsilsesquioxane powder 10% by mass Tocopherol acetate 0.1% by mass ⁇ -Tocopherol 0.1% by mass Thiotaurine 0.1% by mass Western mint extract 0.1% by mass P-hydroxybenzoate appropriate amount phenoxyethanol appropriate amount edetate trisodium appropriate amount colored pigment appropriate amount dimethyl distearyl ammonium hectorite 1.5% by mass Purified water residue
- Example 13 A liquid cosmetic (emulsion foundation) having the following composition was obtained.
- Polyurethane particle group of Production Example 1 4% by mass Microcrystalline wax 1% by mass Dimethylpolysiloxane 15% by mass Decamethylcyclohexasiloxane 2% by mass 1,3-butylene glycol 6% by mass Candelilla wax 3% by mass Isostearic acid 1% by mass Ethylene glycol fatty acid ester 0.1% by mass Lanolin fatty acid octyldodecyl 0.5% by mass 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine 4% by mass Titanium oxide 14.5% by mass Barium sulfate 5% by mass Talc 3% by mass Cross-linked silicone powder 0.1% by mass Sodium metaphosphate 0.1% by mass Hydroxypropyl- ⁇ -cyclodextrin 0.1% by mass DL- ⁇ -tocopherol acetate 0.1% by mass Hamamelis extract 0.1% by mass Pe
- Example 14 A gel cosmetic (hair wax) having the following composition was obtained. 10% by mass of polyurethane particles in Production Example 1 Microcrystalline wax 5% by mass Ceresin 10% by mass Semawari oil 1% by mass 10% by mass of diglycerol sorbitan penta-octanoate Lipophilic glyceryl monostearate 5% by mass Self-emulsifying glyceryl monostearate 5% by mass Silicic anhydride 5% by mass Tetra-2-ethylhexanoic acid pentaerythrid residue
- Example 15 A powder cosmetic (powder-like cleaning material) having the following composition was obtained. 3% by mass of polyurethane particles in Production Example 1 Palm oil fatty acid ethyl ester sodium sulfonate 10% by mass Lauroylmethyl taurine sodium 1% by mass N-myristoyl-potassium L-glutamate 10% by mass 20% by mass of sodium N-lauroyl-L-glutamate Polymer JR-400 (Union Carbide) 0.2% by mass Talc 10% by mass Hydroxypropyl methylcellulose 0.2% by mass Dipotassium glycyrrhizinate 0.1% by mass Trimethylglycine 0.1% by mass Clara extract appropriate amount Yukinoshita extract appropriate amount perilla extract appropriate amount D-Mannit remainder
- Example 16 A gel cosmetic (gel base) having the following composition was obtained. 7% by mass of polyurethane particles in Production Example 1 4% by mass of ethanol 1,3-butylene glycol 7% by mass Glycerin 8% by mass Hydrophobic modified polyether urethane 2% by mass Succinoglucan 0.15% by mass Citric acid 0.02% by mass Sodium citrate 0.08% by mass Iron oxide 0.01% by mass Phenoxyethanol 0.5% by mass Edetate trisodium 0.1% by mass Purified water residue
- Example 17 A liquid cosmetic (sunscreen cosmetic) having the following composition was obtained.
- Polyurethane particle group of Production Example 1 5% by mass Decamethylcyclopentasiloxane 20% by mass Trimethylsiloxysilicic acid 1% by mass Polyoxyethylene / methylpolysiloxane copolymer 2% by mass Dipropylene glycol 4% by mass Squalane 5% by mass Silicone coated fine particle titanium oxide (average particle size 20 nm) 10% by mass Talc (hydrophobized product) 6% by mass Paraben appropriate amount
- Phenoxyethanol appropriate amount Edetate trisodium 0.02% by mass 4-t-butyl-4′-methoxydibenzoylmethane 0.1% by mass 2-methoxyhexyl paramethoxycinnamate 7% by mass Diparamethoxycinnamic acid mono-2-ethylhexanoate glyceryl 0.5% by mass Dimethyl distearyl ammonium hectorite 1% by mass Per
- Each of the cosmetics according to Examples 5 to 17 also prevented makeup from being removed and had a long makeup.
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Abstract
Description
[イソシアネート末端ウレタンプレポリマーの調製]
攪拌装置、窒素導入管、温度計及びコンデンサーを付けた4つ口セパラブルフラスコに、ポリテトラメチレングリコールエーテル(数平均分子量1000)300質量部及び酢酸エチル20質量部を仕込み、イソホロンジイソシアネート104.6質量部及びジブチル錫ジラウレート0.04質量部を添加し、75~80℃の温度で窒素気流下5時間反応を行い、イソシアネート基含有率が3.6%のイソシアネート末端ウレタンプレポリマーを得た。
攪拌装置、窒素導入管、温度計及びコンデンサーを付けた4つ口セパラブルフラスコに、分散剤であるポリビニルアルコール(クラレ社製「PVA-205」:鹸化度86.5~89.0)100質量部及び脱イオン水900質量部を仕込み、90℃に加熱してポリビニルアルコール水溶液を得た。このポリビニルアルコール水溶液中に、上記で得られたイソシアネート末端ウレタンプレポリマー100質量部を添加した後、ホモミキサーを用いて8000rpmで5分間攪拌混合した。そして、イソシアネート末端ウレタンプレポリマーが油滴となって存在する水中油滴型エマルジョンを得た。
上記で得られた水中油滴型エマルジョンに、3,3’-ジアミノジプロピルアミンの10%水溶液35.7質量部を添加した。そして、攪拌しながら80℃まで昇温し、同温度を保持しつつ、20時間反応させた。この結果、油滴中のイソシアネート末端ウレタンプレポリマーとジエチレントリアミンとが反応し、イソシアネート末端ウレタンプレポリマーは三次元的に高分子化され、ポリウレタン球体が生成した。この後、遠心分離を行って、ポリウレタン球体を沈降させた後、ポリウレタン球体を回収し、水を加えて再分散、遠心分離のサイクルを6回行って、分散剤であるポリビニルアルコールの除去を行い、ポリウレタン球体を40質量%含有するポリウレタン球体水性分散液を得た。
別途、攪拌装置に脱イオン水95質量部を仕込み、ホモミキサーを用いて10000rpmで攪拌しながら、親水性シリカ微粉末群(日本アエロジル社製、商品名「アエロジル200」、平均粒径約20nm)5質量部を添加して、10分間攪拌混合して、シリカ水性分散液を得た。
上記で得られたポリウレタン球体水性分散液100質量部、上記で得られたシリカ水性分散液80質量部、及び別途脱イオン水110質量部を混合して、混合水性分散液を得た。
上記で得られた混合水性分散液を、噴霧乾燥機(大川原化工機社製、型番「L-8i」)を用いて、噴霧圧力0.3MPa、熱風の入口温度140℃、乾燥室内温度70℃の条件で噴霧乾燥を行い、ポリウレタン粒子群を得た。この噴霧乾燥によって、混合水性分散液中の水が蒸発し、ポリウレタン球体群は乾燥してポリウレタン粒子本体群を形成すると共に、親水性シリカ微粉末群は各ポリウレタン粒子本体表面に埋入した状態で付着した。したがって、各ポリウレタン粒子は、粒子本体表面が親水性シリカ微粉末群で被覆されたものとなっていた。そして、各ポリウレタン粒子群は殆ど融着しておらず、また殆ど凝集しておらず、一個づつ分離したサラサラとした状態であった。なお、ポリウレタン粒子群の平均粒径は、約12μmであった。
[イソシアネート末端ウレタンプレポリマーの調製]
ポリテトラメチレングリコールエーテルとして数平均分子量3000のものを使用し、かつ、イソホロンジイソシアネートの添加量を45.0質量部とした他は、製造例1と同一の方法により、イソシアネート基含有率が2.5%のイソシアネート末端ウレタンプレポリマーを得た。
上記イソシアネート末端ウレタンプレポリマーを用いた他は、製造例1と同一の方法により、水中油滴型エマルジョンを得た。
上記水中油滴型エマルジョンを用い、かつ、3,3’-ジアミノジプロピルアミンの10%水溶液の添加量を24.5質量部とした他は、製造例1と同一の方法により、ポリウレタン球体水性分散液を得た。
製造例1と同一の方法でシリカ水性分散液を得た。
[混合水性分散液の調製]
上記ポリウレタン球体水性分散液を用いた他は、製造例1と同一の方法で混合水性分散液を得た。
[ポリウレタン粒子群の製造]
上記混合水性分散液を用いる他は、製造例1と同一の方法でポリウレタン粒子群を得た。このポリウレタン粒子群の性状は、製造例1で得られたものと同様であった。なお、ポリウレタン粒子群の平均粒径は、約15μmであった。
下記組成の固形粉末化粧料(ファンデーション)を得た。
製造例1のポリウレタン粒子群 5質量%
シリコーン処理マイカ 20質量%
マイカ 5質量%
メチルハイドロジェンポリシロキサン被覆酸化チタン 10質量%
微粒子酸化チタン 5質量%
アルキル処理酸化鉄 3.44質量%
シリコーンエラストマー(信越化学社製「KSP-100」)8質量%
活性亜鉛華 8.5質量%
硫酸バリウム・酸化アルミニウム被覆マイカ 6質量%
クロルフェネシン 0.2質量%
オレフィンオリゴマー 1質量%
メチルフェニルポリシロキサン 2質量%
リンゴ酸ジイソステアリル 2.5質量%
パラメトキシ桂皮酸2-エチルへキシル 3質量%
セスキイソステアリン酸ソルビタン 1.2質量%
トコフェロール 0.02質量%
メチルハイドロジェンポリシロキサン被覆タルク 残余
実施例1に係る固形粉末化粧料中のポリウレタン粒子群及びシリコーンエラストマーの配合量を下記のとおり変更した他は、実施例1と同一の組成及び配合量で、固形粉末化粧料を得た。
製造例1のポリウレタン粒子群 10質量%
シリコーンエラストマー(信越化学社製「KSP-100」)3質量%
実施例1に係る固形粉末化粧料中のポリウレタン粒子群の配合量を下記のとおり変更し、かつ、シリコーンエラストマーを使用しない他は、実施例1と同一の組成及び配合量で、固形粉末化粧料を得た。
製造例1のポリウレタン粒子群 13質量%
シリコーンエラストマー(信越化学社製「KSP-100」)(使用せず)
実施例1に係る固形粉末化粧料中のポリウレタン粒子群を使用せず、かつ、シリコーンエラストマーの配合量を下記のとおり変更した他は、実施例1と同一の組成及び配合量で、固形粉末化粧料を得た。
製造例1のポリウレタン粒子群 (使用せず)
シリコーンエラストマー(信越化学社製「KSP-100」)13質量%
実施例1に係る固形粉末化粧料中のポリウレタン粒子群5質量%に代えて、ヘキサメチレンジイソシアネート/トリメチロールヘキシルラクトン架橋ポリマー・無水ケイ酸(東色ピグメント社製「PLASTIC POWDER D-400」、平均粒径約13μm)5質量%を用いる他は、実施例1と同一の組成及び配合量で、固形粉末化粧料を得た。
(評価点基準)
5点:非常に優れている。
4点:優れている。
3点:普通
2点:劣る。
1点:非常に劣る。
(実用特定評価)
◎:平均点が、4.4点以上
○:平均点が、3.5~4.4点
△:平均点が、2.6~3.5点
×:平均点が、2.6点未満
━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━
化粧持ち のびの軽さ なめらかさ 凹凸補正効果
━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━
実施例1 ○ ○ ○ ○
実施例2 ◎ ◎ ◎ ◎
実施例3 ◎ ◎ ◎ ◎
比較例1 △ ○ ○ ○
比較例2 △ △ △ ○
━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━
下記組成の固形粉末化粧料(ルースパウダー)を得た。
製造例2のポリウレタン粒子群 8.5質量%
シリコーン処理マイカ 20質量%
酸化鉄 0.05質量%
活性亜鉛華 1質量%
ミリスチン酸亜鉛 4質量%
メチルハイドロジェンポリシロキサン被覆タルク 残余
実施例4に係る固形粉末化粧料中のポリウレタン粒子群8.5質量%に代えて、ヘキサメチレンジイソシアネート/トリメチロールヘキシルラクトン架橋ポリマー・無水ケイ酸(東色ピグメント社製「PLASTIC POWDER D-400」、平均粒径約13μm)8.5質量%を用いる他は、実施例4と同一の組成及び配合量で、固形粉末化粧料を得た。
実施例4に係る固形粉末化粧料中のポリウレタン粒子群8.5質量%に代えて、シリコーンエラストマー(信越化学社製「KSP-100」)8.5質量%を用いる他は、実施例4と同一の組成及び配合量で、固形粉末化粧料を得た。
━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━
化粧持ち のびの軽さ なめらかさ 凹凸補正効果
━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━
実施例4 ◎ ○ ◎ ○
比較例3 △ ○ △ ○
比較例4 △ ○ ○ ○
━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━━
下記組成の固形粉末化粧料(パウダリーファンデーション)を得た。
製造例1のポリウレタン粒子群 5質量%
ジメチルポリシロキサン 5質量%
イソステアリン酸 0.5質量%
リンゴ酸ジイソステアリル 3質量%
トリ2-エチルヘキサン酸グリセリル 1質量%
セスキイソステアリン酸ソルビタン 1質量%
球状PMMA(ポリメチルメタクリレート)被覆雲母 6質量%
パール剤 1質量%
微粒子酸化亜鉛 0.5質量%
微粒子酸化チタン 2質量%
合成金雲母 2質量%
金属石鹸処理タルク 8質量%
ビタミンEアセテート 0.1質量%
δ-トコフェロール 0.1質量%
エチルパラベン 適量
トリメトキシ桂皮酸メチルビス(トリメチルシロキシ)シリルイソペンチル 1質量%
パラメトキシ桂皮酸2-エチルヘキシル 1質量%
球状ポリアクリル酸アルキル粉末 6質量%
メチルハイドロジェンポリシロキサン被覆セリサイト 20質量%
メチルハイドロジェンポリシロキサン被覆酸化チタン 15質量%
メチルハイドロジェンポリシロキサン被覆顔料(色剤) 5質量%
メチルハイドロジェンポリシロキサン被覆タルク 残余
下記組成の固形粉末化粧料(パウダリーファンデーション)を得た。
製造例1のポリウレタン粒子群 8質量%
合成炭化水素ワックス粒子 2質量%
ジメチルポリシロキサン 6質量%
精製ラノリン 5質量%
トリ2-エチルヘキサン酸グリセリル 2質量%
セスキイソステアリン酸ソルビタン 0.5質量%
針状微粒子酸化チタン 5質量%
微粒子酸化亜鉛 1質量%
シリコーン被覆酸化鉄・酸化チタン焼結物 7質量%
硫酸バリウム 8質量%
チタン還元処理雲母チタンパール顔料 2質量%
シリコーン被覆合成金雲母 5質量%
シリコーン被覆タルク 2質量%
シリコーン被覆マイカ 15質量%
グリチルレチン酸ステアリル 0.1質量%
ジパルミチン酸アスコルビル 0.1質量%
酢酸DL-α-トコフェロール 0.1質量%
D-δ-トコフェロール 0.1質量%
パラオキシ安息香酸エステル 適量
パラメトキシ桂皮酸2-エチルヘキシル 3質量%
シリコーン被覆ベンガラ 1質量%
シリコーン被覆黄酸化鉄 1質量%
シリコーン被覆黒酸化鉄 1質量%
球状ポリアクリル酸アルキル 3質量%
香料 適量
焼成セリサイト 残余
下記組成の液体化粧料(化粧水)を得た。
製造例1のポリウレタン粒子群 3質量%
エタノール 5質量%
グリセリン 1質量%
1,3-ブチレングリコール 5質量%
ポリオキシエチレンポリオキシプロピレンデシルテトラデシルエーテル
0.2質量%
ヘキサメタリン酸ナトリウム 0.03質量%
トリメチルグリシン 1質量%
ポリアスパラギン酸ナトリウム 0.1質量%
α-トコフェロール2-L-アスコルビン酸リン酸ジエステルカリウム
0.1質量%
チオタウリン 0.1質量%
緑茶エキス 0.1質量%
西洋ハッカエキス 0.1質量%
イリス根エキス 0.1質量%
EDTA3ナトリウム 0.1質量%
カルボキシビニルポリマー 0.05質量%
水酸化カリウム 0.02質量%
フェノキシエタノール 適量
香料 適量
精製水 残余
下記組成の液体化粧料(化粧水)を得た。
製造例1のポリウレタン粒子群 1質量%
エタノール 10質量%
グリセリン 2質量%
イソステアリン酸 0.1質量%
ポリ(オキシエチレン・オキシプロピレン)・メチルポリシロキサン共重合体 1質量%
ラウリルジメチルアミノ酢酸ベタイン 0.1質量%
クエン酸 0.02質量%
クエン酸ナトリウム 0.08質量%
ヘキサメタリン酸ナトリウム 0.01質量%
ヒポタウリン 0.1質量%
カモミラエキス 0.1質量%
ラベンダー油 0.001質量%
フェノキシエタノール 適量
活性水素水 1質量%
精製水 残余
下記組成の液体化粧料(化粧水)を得た。
製造例1のポリウレタン粒子群 1質量%
エタノール 40質量%
ジプロピレングリコール 1質量%
ポリオキシエチレンポリオキシプロピレンデシルテトラデシルエーテル
0.1質量%
無水ケイ酸 1質量%
サリチル酸 0.1質量%
クエン酸ナトリウム 0.2質量%
パラフェノールスルホン酸亜鉛 0.2質量%
グリチルリチン酸ジカリウム 0.1質量%
塩酸ピリドキシン 0.1質量%
L-メントール 0.05質量%
EDTA3ナトリウム 0.05質量%
ベントナイト 0.8質量%
精製水 残余
下記組成の粉体化粧料(デオドラントスプレー)を得た。
(粉末部)
製造例1のポリウレタン粒子群 1.5質量%
ミョウバン(平均粒径20μm) 3質量%
銀イオン、亜鉛イオン、アンモニウムイオン担持ゼオライト(平均粒径約5μmであって、粒子径15μmを超えるものが1質量%以下のもの)2質量%
酸化亜鉛 0.2質量%
(油分)
ポリオキシエチレンノニルフェニルエーテル 0.5質量%
ジメチルポリシロキサン(20mPa・s、25℃) 0.1質量%
ミリスチン酸イソプロピル 0.5質量%
(添加剤)
ポリオキシエチレンソルビタンモノオレエート 0.1質量%
香料 0.1質量%
(噴射剤)
液化石油ガス 92質量%
なお、このデオドラントスプレーは、以下の如き製法で得られるものである。すなわち、粉末部をニーダーにて混合する。油分はブレンダーで混合し、添加剤はこの混合した油分に添加する。そして、粉末部及び添加剤が添加された油分を、順次、スプレー缶に充填し、さらに噴射剤を缶に充填して、デオドラントスプレーを得た。
下記組成の固形粉末化粧料(ルースパウダー)を得た。
製造例1のポリウレタン粒子群 20質量%
アルキル変性シリコン樹脂被覆雲母チタン 25質量%
アルキル変性シリコン樹脂被覆セリサイト 30質量%
ムクロジエキス 0.01質量%
麻セルロース末 0.1質量%
アルキル変性シリコン樹脂被覆タルク 残余
下記組成の液体化粧料(油中水型化粧下地)を得た。
製造例1のポリウレタン粒子群 3質量%
ジメチルポリシロキサン(6mPa・s) 5質量%
デカメチルシクロペンタシロキサン 30質量%
ポリオキシエチレン・メチルポリシロキサン共重合体 3質量%
ドデカメチルシクロヘキサシロキサン 1質量%
グリセリン 5質量%
ジプロピレングリコール 5質量%
セージ油 0.1質量%
タルク 0.1質量%
雲母チタン 0.1質量%
ポリメチルシルセスキオキサン粉末 10質量%
酢酸トコフェロール 0.1質量%
δ-トコフェロール 0.1質量%
チオタウリン 0.1質量%
西洋ハッカエキス 0.1質量%
パラオキシ安息香酸エステル 適量
フェノキシエタノール 適量
エデト酸3ナトリウム 適量
有色顔料 適量
ジメチルジステアリルアンモニウムヘクトライト 1.5質量%
精製水 残余
下記組成の液体化粧料(乳化ファンデーション)を得た。
製造例1のポリウレタン粒子群 4質量%
マイクロクリスタリンワックス 1質量%
ジメチルポリシロキサン 15質量%
デカメチルシクロヘキサシロキサン 2質量%
1,3-ブチレングリコール 6質量%
キャンデリラロウ 3質量%
イソステアリン酸 1質量%
エチレングリコール脂肪酸エステル 0.1質量%
ラノリン脂肪酸オクチルドデシル 0.5質量%
2-アルキル-N-カルボキシメチル-N-ヒドロキシエチルイミダゾリニウムベタイン 4質量%
酸化チタン 14.5質量%
硫酸バリウム 5質量%
タルク 3質量%
架橋型シリコーン末 0.1質量%
メタリン酸ナトリウム 0.1質量%
ヒドロキシプロピル-β-シクロデキストリン 0.1質量%
酢酸DL-α-トコフェロール 0.1質量%
ハマメリス抽出液 0.1質量%
シャクヤクエキス 0.1質量%
コンドロイチン硫酸ナトリウム 0.1質量%
ヒアルロン酸ナトリウム 0.1質量%
パラオキシ安息香酸エステル 適量
ベンガラ 適量
黄酸化鉄 適量
黒酸化鉄 適量
キサンタンガム 0.2質量%
カルボキシメチルセルロース 0.2質量%
メリロートエキス 2質量%
精製水 残余
下記組成のジェル化粧料(ヘアワックス)を得た。
製造例1のポリウレタン粒子群 10質量%
マイクロクリスタリンワックス 5質量%
セレシン 10質量%
セマワリ油 1質量%
ペンタ-オクタン酸ジグリセロールソルビタン 10質量%
親油型モノステアリン酸グリセリン 5質量%
自己乳化型モノステアリン酸グリセリン 5質量%
シリル化処理無水ケイ酸 5質量%
テトラ2-エチルヘキサン酸ペンタエリスリット 残余
下記組成の粉体化粧料(パウダー状洗浄料)を得た。
製造例1のポリウレタン粒子群 3質量%
ヤシ油脂肪酸エチルエステルスルホン酸ナトリウム 10質量%
ラウロイルメチルタウリンナトリウム 1質量%
N-ミリストイル-L-グルタミン酸カリウム 10質量%
N-ラウロイル-L-グルタミン酸ナトリウム 20質量%
ポリマーJR-400(ユニオンカーバイド社製) 0.2質量%
タルク 10質量%
ヒドロキシプロピルメチルセルロース 0.2質量%
グリチルリチン酸ジカリウム 0.1質量%
トリメチルグリシン 0.1質量%
クララエキス 適量
ユキノシタエキス 適量
シソエキス 適量
D-マンニット 残余
下記組成のジェル化粧料(ジェル状下地)を得た。
製造例1のポリウレタン粒子群 7質量%
エタノール 4質量%
1,3-ブチレングリコール 7質量%
グリセリン 8質量%
疎水変性ポリエーテルウレタン 2質量%
サクシノグルカン 0.15質量%
クエン酸 0.02質量%
クエン酸ナトリウム 0.08質量%
酸化鉄 0.01質量%
フェノキシエタノール 0.5質量%
エデト酸三ナトリウム 0.1質量%
精製水 残余
下記組成の液状化粧料(日焼け止め化粧料)を得た。
製造例1のポリウレタン粒子群 5質量%
デカメチルシクロペンタシロキサン 20質量%
トリメチルシロキシケイ酸 1質量%
ポリオキシエチレン・メチルポリシロキサン共重合体 2質量%
ジプロピレングリコール 4質量%
スクワラン 5質量%
シリコーン被覆微粒子酸化チタン(平均粒径20nm) 10質量%
タルク(疎水化処理品) 6質量%
パラベン 適量
フェノキシエタノール 適量
エデト酸三ナトリウム 0.02質量%
4-t-ブチル-4’-メトキシジベンゾイルメタン 0.1質量%
パラメトキシ桂皮酸2-エチルヘキシル 7質量%
ジパラメトキシ桂皮酸モノ-2-エチルヘキサン酸グリセリル 0.5質量%
ジメチルジステアリルアンモニウムヘクトライト 1質量%
香料 適量
精製水 残余
Claims (9)
- ポリウレタン粒子群を含む化粧料において、前記ポリウレタン粒子は、ポリウレタン粒子本体表面に親水性シリカ微粉末群が被覆されてなり、該ポリウレタン粒子本体は、ポリイソシアネート成分とポリテトラメチレングリコールを含むポリオール成分との反応により得られるイソシアネート末端ウレタンプレポリマーを、3官能以上の多官能アミンで三次元的に高分子化してなるものであることを特徴とする化粧料。
- ポリウレタン粒子が、ポリウレタン粒子本体表面に親水性シリカ微粉末群が埋入した状態で被覆されてなるものである請求項1記載の化粧料。
- ポリテトラメチレングリコールの数平均分子量が650~3000である請求項1記載の化粧料。
- ポリイソシアネート成分としてイソホロンジイソシアネートを用い、ポリオール成分としてポリテトラメチレングリコールを用いる請求項1記載の化粧料。
- 多官能アミンとして3,3’-ジアミノジプロピルアミンを用いる請求項1記載の化粧料。
- ポリウレタン粒子の粒径は、親水性シリカ微粉末の粒径の20倍以上である請求項1記載の化粧料。
- ポリウレタン粒子群の平均粒径は、1~50μmである請求項1記載の化粧料。
- ポリウレタン粒子群の含有割合が0.1~30質量%である請求項1記載の化粧料。
- 化粧料が、固形化粧料、固形粉末化粧料、ジェル化粧料及び液体化粧料よりなる群から選ばれたものである請求項1記載の化粧料。
Priority Applications (3)
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CN201080009411.7A CN102333519B (zh) | 2009-01-15 | 2010-01-08 | 化妆品 |
EP10731199A EP2380557A1 (en) | 2009-01-15 | 2010-01-08 | Cosmetic |
US13/181,852 US20120009234A1 (en) | 2009-01-15 | 2011-07-13 | Cosmetics |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2009006875A JP5455168B2 (ja) | 2009-01-15 | 2009-01-15 | 化粧料 |
JP2009-006875 | 2009-01-15 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US13/181,852 Continuation US20120009234A1 (en) | 2009-01-15 | 2011-07-13 | Cosmetics |
Publications (1)
Publication Number | Publication Date |
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WO2010082530A1 true WO2010082530A1 (ja) | 2010-07-22 |
Family
ID=42339783
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2010/050124 WO2010082530A1 (ja) | 2009-01-15 | 2010-01-08 | 化粧料 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20120009234A1 (ja) |
EP (1) | EP2380557A1 (ja) |
JP (1) | JP5455168B2 (ja) |
KR (1) | KR20110108392A (ja) |
CN (1) | CN102333519B (ja) |
TW (1) | TWI483745B (ja) |
WO (1) | WO2010082530A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009029867A (ja) * | 2007-07-25 | 2009-02-12 | Konishi Co Ltd | 膨潤型吸油性ポリマー粒子 |
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JP5178920B2 (ja) * | 2010-10-06 | 2013-04-10 | 株式会社 資生堂 | 固形粉末化粧料 |
US8821839B2 (en) | 2010-10-22 | 2014-09-02 | Conopco, Inc. | Compositions and methods for imparting a sunless tan with a vicinal diamine |
CN103370071B (zh) * | 2010-12-22 | 2016-10-05 | 雅芳产品公司 | 基于粉末的持久性化妆品组合物 |
JP4782891B1 (ja) * | 2010-12-28 | 2011-09-28 | 株式会社コスモビューティー | 洗浄用化粧料 |
IN2014MN00857A (ja) * | 2011-11-18 | 2015-04-17 | Unilever Plc | |
US8961942B2 (en) | 2011-12-13 | 2015-02-24 | Conopco, Inc. | Sunless tanning compositions with adjuvants comprising sulfur comprising moieties |
ES2700148T3 (es) * | 2012-03-09 | 2019-02-14 | Covestro Deutschland Ag | Dispersión acuosa de poliuretano para el tratamiento del acné |
CN102631305B (zh) * | 2012-05-11 | 2013-04-10 | 苏州宜生生物技术有限公司 | 一种定妆液 |
KR101633640B1 (ko) * | 2014-01-02 | 2016-06-27 | 한국콜마주식회사 | 속눈썹 탄력 지속 강화 조성물 |
JP5812556B1 (ja) * | 2014-03-28 | 2015-11-17 | 株式会社マンダム | デオドラント剤又は清涼化粧料、並びに非エアゾール型スプレー製品 |
EP3226828B1 (en) * | 2014-12-02 | 2020-02-12 | Dow Global Technologies LLC | Polyurethane microparticles coated with a zinc salt and methods for the preparation thereof |
JP6674797B2 (ja) * | 2016-03-07 | 2020-04-01 | 株式会社ファンケル | 油中水型乳化化粧料 |
CN108779254B (zh) * | 2016-10-06 | 2021-10-01 | 瓦克化学股份公司 | 生产球形聚倍半硅氧烷颗粒的方法 |
WO2019055445A2 (en) | 2017-09-13 | 2019-03-21 | Living Proof, Inc. | COLOR PROTECTION COMPOSITIONS |
JP6976800B2 (ja) * | 2017-10-04 | 2021-12-08 | ポーラ化成工業株式会社 | 化粧料 |
DE102018201598A1 (de) * | 2018-02-02 | 2019-08-08 | Beiersdorf Ag | Stabile Wundheilsalbe |
CN112041365A (zh) * | 2018-04-27 | 2020-12-04 | 生活实验公司 | 持久性化妆品组合物 |
JP2020186203A (ja) * | 2019-05-14 | 2020-11-19 | 東色ピグメント株式会社 | 毛髪用化粧料とその使用方法 |
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- 2010-01-08 CN CN201080009411.7A patent/CN102333519B/zh not_active Expired - Fee Related
- 2010-01-08 WO PCT/JP2010/050124 patent/WO2010082530A1/ja active Application Filing
- 2010-01-08 EP EP10731199A patent/EP2380557A1/en not_active Withdrawn
- 2010-01-15 TW TW099101039A patent/TWI483745B/zh active
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2011
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Also Published As
Publication number | Publication date |
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TW201031432A (en) | 2010-09-01 |
TWI483745B (zh) | 2015-05-11 |
CN102333519B (zh) | 2014-04-16 |
US20120009234A1 (en) | 2012-01-12 |
EP2380557A1 (en) | 2011-10-26 |
KR20110108392A (ko) | 2011-10-05 |
JP5455168B2 (ja) | 2014-03-26 |
JP2010163389A (ja) | 2010-07-29 |
CN102333519A (zh) | 2012-01-25 |
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