WO2009110698A3 - 모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법 - Google Patents

모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법 Download PDF

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WO2009110698A3
WO2009110698A3 PCT/KR2009/000963 KR2009000963W WO2009110698A3 WO 2009110698 A3 WO2009110698 A3 WO 2009110698A3 KR 2009000963 W KR2009000963 W KR 2009000963W WO 2009110698 A3 WO2009110698 A3 WO 2009110698A3
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catalyst
monohydric alcohol
derivative
monocarboxylic acid
components
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PCT/KR2009/000963
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French (fr)
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WO2009110698A2 (ko
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이정호
장종산
황영규
신현관
조광명
송봉근
김용환
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한국화학연구원
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Priority to EP09718149.9A priority Critical patent/EP2248793B8/en
Priority to US12/594,025 priority patent/US7847134B2/en
Publication of WO2009110698A2 publication Critical patent/WO2009110698A2/ko
Publication of WO2009110698A3 publication Critical patent/WO2009110698A3/ko

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8966—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen

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  • Chemical & Material Sciences (AREA)
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  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

본 발명은 모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법에 있어서, 아연산화물(ZnO)을 담체로 한 Ru 및 Sn 성분으로 구성된 촉매이거나, 또는 상기 성분으로 구성된 촉매에서 성형성을 부여하기 위해 실리카나 알루미나, 또는 티타늄 산화물등의 무기물 바인더를 제한된 범위에서 추가로 첨가하여 제조된 촉매이거나, 또는 촉매의 환원 능력을 개량하기 위해 Co, Ni, Cu, Ag, Rh, Pd, Re, Ir, 및 Pt 등 환원성 성분으로 이루어진 군에서 선택되는 적어도 하나 이상의 개량 성분을 추가로 첨가하여 개질된 촉매를 사용함으로써 원료물질인 모노카르복실산 또는 그의 유도체의 물의 함유 여부에 상관없이 고수율로 일가 알콜을 제조할 수 있고, 공지의 발명 촉매보다 매우 온화한 반응조건하에서 운전 가능하면서도 고선택적이고 고생산성을 나타내므로 경제적인 방법으로 일가 알콜을 제조할 수 있으며, 촉매의 장기 반응 안정성이 우수하므로 상업 생산적용에 유리하게 이용될 수 있다.
PCT/KR2009/000963 2008-03-06 2009-02-27 모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법 WO2009110698A2 (ko)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP09718149.9A EP2248793B8 (en) 2008-03-06 2009-02-27 Production method for a monohydric alcohol from a monocarboxylic acid or from a derivative thereof
US12/594,025 US7847134B2 (en) 2008-03-06 2009-02-27 Process of producing monohydric alcohols from monocarboxylic acids or derivatives thereof

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Application Number Priority Date Filing Date Title
KR10-2008-0021115 2008-03-06
KR1020080021115A KR100922998B1 (ko) 2008-03-06 2008-03-06 모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법

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WO2009110698A2 WO2009110698A2 (ko) 2009-09-11
WO2009110698A3 true WO2009110698A3 (ko) 2009-11-19

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US (1) US7847134B2 (ko)
EP (1) EP2248793B8 (ko)
JP (1) JP5275080B2 (ko)
KR (1) KR100922998B1 (ko)
WO (1) WO2009110698A2 (ko)

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Publication number Publication date
EP2248793B8 (en) 2013-09-25
WO2009110698A2 (ko) 2009-09-11
EP2248793B1 (en) 2013-08-14
US20100113843A1 (en) 2010-05-06
EP2248793A2 (en) 2010-11-10
EP2248793A4 (en) 2012-07-11
KR100922998B1 (ko) 2009-10-22
JP5275080B2 (ja) 2013-08-28
JP2009215289A (ja) 2009-09-24
KR20090095892A (ko) 2009-09-10
US7847134B2 (en) 2010-12-07

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