TWI455920B - 用於乙酸及/或乙酸甲酯之生產的羰基化方法 - Google Patents

用於乙酸及/或乙酸甲酯之生產的羰基化方法 Download PDF

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Publication number
TWI455920B
TWI455920B TW097147817A TW97147817A TWI455920B TW I455920 B TWI455920 B TW I455920B TW 097147817 A TW097147817 A TW 097147817A TW 97147817 A TW97147817 A TW 97147817A TW I455920 B TWI455920 B TW I455920B
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Taiwan
Prior art keywords
microns
range
zeolite
micron
average particle
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TW097147817A
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English (en)
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TW200936557A (en
Inventor
Canos Avelino Corma
Gordon John Haining
David John Law
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Bp Chem Int Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B01J29/20Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type containing iron group metals, noble metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45Nanoparticles
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/36Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/36Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/37Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by reaction of ethers with carbon monoxide

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Claims (13)

  1. 一種用於製造乙酸及乙酸甲酯中之至少一者之方法,該方法包含在結構類型MOR之沸石的存在下,使用一氧化碳羰基化選自於甲醇、二甲醚及碳酸二甲酯中之至少一種可羰基化反應物的步驟,其中該沸石具有大於50%其晶粒係於0.1微米至3微米之大小範圍。
  2. 如申請專利範圍第1項之方法,其中大於50%晶粒係於0.1微米至2微米之大小範圍。
  3. 如申請專利範圍第2項之方法,其中大於50%晶粒係於0.1微米至1.5微米之大小範圍。
  4. 如申請專利範圍第1項之方法,其中大於80%晶粒係於0.1微米至2微米之大小範圍。
  5. 如申請專利範圍第1項之方法,其中該沸石具有平均粒徑係不大於6微米。
  6. 如申請專利範圍第5項之方法,其中平均粒徑係於2微米至3.5微米之範圍。
  7. 如申請專利範圍第2項之方法,且其中平均粒徑係於2微米至6微米之範圍。
  8. 如申請專利範圍第3項之方法,且其中平均粒徑係於2微米至3.5微米之範圍。
  9. 如申請專利範圍第1項之方法,其中該沸石為H-絲光沸石。
  10. 如申請專利範圍第1項之方法,其中該沸石為已經過離 子交換之絲光沸石,或者是載荷有選自於銅、銀、金、鎳、銥、銠、鉑、鈀及鈷中之一種或多種金屬之絲光沸石。
  11. 如申請專利範圍第1項之方法,其中該沸石具有於10至40:1之氧化矽:氧化鋁比。
  12. 如申請專利範圍第1項之方法,其中該羰基化反應物為二甲醚或碳酸二甲酯及該方法的該氣體進料具有低於2.5wt%水。
  13. 如申請專利範圍第1項之方法,其中該羰基化係於氫存在下進行。
TW097147817A 2007-12-20 2008-12-09 用於乙酸及/或乙酸甲酯之生產的羰基化方法 TWI455920B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP07254975A EP2085375A1 (en) 2007-12-20 2007-12-20 Process for the production of acetic acid and/or methyl acetate in the presence of a zeolite of structure type MOR

Publications (2)

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TW200936557A TW200936557A (en) 2009-09-01
TWI455920B true TWI455920B (zh) 2014-10-11

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US (1) US8426633B2 (zh)
EP (2) EP2085375A1 (zh)
CN (2) CN101903325A (zh)
TW (1) TWI455920B (zh)
WO (1) WO2009081099A1 (zh)

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EP2199272A1 (en) * 2008-11-27 2010-06-23 BP Chemicals Limited Carbonylation process
EP2251314A1 (en) * 2009-05-14 2010-11-17 BP Chemicals Limited Carbonylation process
CN103097006B (zh) * 2010-08-27 2015-04-01 丹麦科技大学 具有铁或铜的丝光沸石型沸石scr催化剂
US8937197B2 (en) * 2011-07-16 2015-01-20 President And Fellows Of Harvard College Gold-catalyzed synthesis of carbonates and carbamates from carbon monoxide
US8927762B2 (en) * 2011-11-16 2015-01-06 Enerkem, Inc. Production of oxygenated compounds from carbon monoxide and dimethyl carbonate
US20130158290A1 (en) * 2011-11-22 2013-06-20 Stephane MARIE-ROSE Production of oxygenated compounds in the presence of a catalyst suspended in an inert liquid
CN104725229B (zh) * 2013-12-23 2017-05-31 中国科学院大连化学物理研究所 制备聚甲氧基二甲醚羰化物及甲氧基乙酸甲酯的方法
CN106365995B (zh) * 2015-07-20 2018-06-05 中国科学院大连化学物理研究所 一种乙酸甲酯的生产方法
CN106365994B (zh) * 2015-07-20 2019-01-01 中国科学院大连化学物理研究所 一种低级脂肪羧酸烷基酯的生产方法
CN106518657B (zh) 2015-09-11 2019-03-29 中国科学院大连化学物理研究所 一种通过甲醇羰基化制备乙酸的方法
CN106890665B (zh) * 2015-12-18 2020-06-09 中国科学院大连化学物理研究所 一种二甲醚羰基化生产乙酸甲酯的催化剂及其应用
CN106890669B (zh) * 2015-12-18 2019-04-02 中国科学院大连化学物理研究所 一种生产乙酸甲酯的催化剂、其制备方法及应用
CN106316846B (zh) * 2016-08-26 2018-12-25 西南化工研究设计院有限公司 一种乙酸甲酯的生产方法
CN108579794A (zh) * 2018-04-02 2018-09-28 新疆大学 负载金的分子筛催化剂用于转化甲醇为乙酸甲酯的方法
CN111822041B (zh) * 2019-04-15 2021-11-09 中国科学院大连化学物理研究所 一种复合催化剂、其制备方法及其应用
CN114433188B (zh) * 2020-10-19 2024-01-26 中国石油化工股份有限公司 一种乙酸甲酯催化剂及其制备方法和乙酸甲酯的合成方法

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Publication number Publication date
CN101903325A (zh) 2010-12-01
EP2231579A1 (en) 2010-09-29
WO2009081099A1 (en) 2009-07-02
EP2085375A1 (en) 2009-08-05
EP2231579B1 (en) 2015-11-04
US20100267985A1 (en) 2010-10-21
CN105646178B (zh) 2019-07-12
TW200936557A (en) 2009-09-01
CN105646178A (zh) 2016-06-08
US8426633B2 (en) 2013-04-23

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