MX2012004841A - Catalizador para la produccion de etanol por hidrogenacion de acido acetico que comprende platino-estaño sobre un soporte silicaceo. - Google Patents

Catalizador para la produccion de etanol por hidrogenacion de acido acetico que comprende platino-estaño sobre un soporte silicaceo.

Info

Publication number
MX2012004841A
MX2012004841A MX2012004841A MX2012004841A MX2012004841A MX 2012004841 A MX2012004841 A MX 2012004841A MX 2012004841 A MX2012004841 A MX 2012004841A MX 2012004841 A MX2012004841 A MX 2012004841A MX 2012004841 A MX2012004841 A MX 2012004841A
Authority
MX
Mexico
Prior art keywords
ethanol
acetic acid
catalyst
platinum
tin
Prior art date
Application number
MX2012004841A
Other languages
English (en)
Inventor
Victor J Johnston
Heiko Weiner
John L Potts
Radmila Jevtic
Original Assignee
Celanese Int Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/588,727 external-priority patent/US8309772B2/en
Application filed by Celanese Int Corp filed Critical Celanese Int Corp
Publication of MX2012004841A publication Critical patent/MX2012004841A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B01J23/622—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead
    • B01J23/626—Platinum group metals with gallium, indium, thallium, germanium, tin or lead with germanium, tin or lead with tin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6567—Rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describe un proceso para la formación selectiva de etanol a partir de ácido acético que incluye poner en contacto una corriente de alimentación que contiene ácido acético e hidrógeno a una temperatura elevada con un catalizador que comprende platino y estaño sobre una sílice de área superficial alta promovida con metasilicato de calcio; las selectividades para etanol de más de 85% se obtienen a 280°C con una vida de catalizador en los cientos de horas.
MX2012004841A 2009-10-26 2010-10-26 Catalizador para la produccion de etanol por hidrogenacion de acido acetico que comprende platino-estaño sobre un soporte silicaceo. MX2012004841A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/588,727 US8309772B2 (en) 2008-07-31 2009-10-26 Tunable catalyst gas phase hydrogenation of carboxylic acids
PCT/US2010/054134 WO2011056595A1 (en) 2009-10-26 2010-10-26 Catalyst for the production of ethanol by hydrogenation of acetic acid comprising platinum -tin on silicaceous support

Publications (1)

Publication Number Publication Date
MX2012004841A true MX2012004841A (es) 2012-05-29

Family

ID=46506679

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012004841A MX2012004841A (es) 2009-10-26 2010-10-26 Catalizador para la produccion de etanol por hidrogenacion de acido acetico que comprende platino-estaño sobre un soporte silicaceo.

Country Status (11)

Country Link
EP (1) EP2493609A1 (es)
JP (1) JP5775087B2 (es)
CN (1) CN102300635B (es)
AU (1) AU2010315552B2 (es)
BR (1) BR112012009770A2 (es)
CA (1) CA2778957A1 (es)
IL (1) IL219400A0 (es)
MX (1) MX2012004841A (es)
RU (1) RU2549893C2 (es)
WO (1) WO2011056595A1 (es)
ZA (1) ZA201202847B (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112014015080A2 (pt) * 2011-12-29 2017-06-13 Celanese Int Corp catalisador de cobalto e estanho para produzir etanol
US9333496B2 (en) 2012-02-29 2016-05-10 Celanese International Corporation Cobalt/tin catalyst for producing ethanol
US9079172B2 (en) 2012-03-13 2015-07-14 Celanese International Corporation Promoters for cobalt-tin catalysts for reducing alkanoic acids
WO2013103399A1 (en) * 2012-01-06 2013-07-11 Celanese International Corporation Hydrogenation catalysts with cobalt-modified supports
US9079851B2 (en) * 2012-02-01 2015-07-14 Greenyug, Llc Ethyl acetate production
US8927786B2 (en) 2012-03-13 2015-01-06 Celanese International Corporation Ethanol manufacturing process over catalyst having improved radial crush strength
CN102658165B (zh) * 2012-04-06 2014-11-05 华东理工大学 乙酸气相加氢制备乙醇的催化剂及其制备方法
CN104107701B (zh) * 2013-04-16 2016-08-03 中国石油化工股份有限公司 高活性Pt基催化剂、制备方法及其用途
DE102013106787A1 (de) 2013-06-28 2014-12-31 Oxea Gmbh Verfahren zur Herstellung von n-Butanderivaten
DE102013106790A1 (de) 2013-06-28 2014-12-31 Oxea Gmbh Verfahren zur Herstellung von 1,3-Butandiol
CN103331158B (zh) * 2013-07-15 2017-08-25 上海华谊（集团）公司 一种醋酸加氢制乙醇的催化剂及制备方法
CN111359618B (zh) * 2020-04-23 2022-10-25 上海亚铂化工科技有限公司 催化剂及其制备方法和应用以及催化酯加氢反应的方法

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GB8509530D0 (en) * 1985-04-13 1985-05-15 Bp Chem Int Ltd Hydrogenation of carboxylic acids
US5149680A (en) 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
GB8707595D0 (en) 1987-03-31 1987-05-07 British Petroleum Co Plc Chemical process
US5821111A (en) 1994-03-31 1998-10-13 Bioengineering Resources, Inc. Bioconversion of waste biomass to useful products
USRE35377E (en) 1993-05-27 1996-11-12 Steinberg; Meyer Process and apparatus for the production of methanol from condensed carbonaceous material
DE19720657A1 (de) * 1997-05-16 1998-11-19 Basf Ag Verfahren zur Herstellung von aliphatischen Alkoholen
JP3780669B2 (ja) * 1997-11-17 2006-05-31 三菱化学株式会社 アルデヒド類及び、又はアルコール類の製造方法
JP3911955B2 (ja) * 1999-04-28 2007-05-09 三菱化学株式会社 ルテニウム−スズ系担持触媒の製造方法。
US6232352B1 (en) 1999-11-01 2001-05-15 Acetex Limited Methanol plant retrofit for acetic acid manufacture
US6657078B2 (en) 2001-02-07 2003-12-02 Celanese International Corporation Low energy carbonylation process
US6685754B2 (en) 2001-03-06 2004-02-03 Alchemix Corporation Method for the production of hydrogen-containing gaseous mixtures
EP1277826A1 (en) * 2001-07-18 2003-01-22 ATOFINA Research Hydrogenation and dehydrogenation processes and catalysts therefor
DE102004007498A1 (de) * 2004-02-13 2005-09-01 Basf Ag Hydrierverfahren zur Herstellung optisch aktiver Alkohole oder Carbonsäuren
KR100922998B1 (ko) * 2008-03-06 2009-10-22 한국화학연구원 모노카르복실산 또는 그의 유도체로부터 일가 알콜의 제조방법

Also Published As

Publication number Publication date
AU2010315552A1 (en) 2012-05-17
JP5775087B2 (ja) 2015-09-09
ZA201202847B (en) 2013-06-26
JP2013508423A (ja) 2013-03-07
CN102300635A (zh) 2011-12-28
CN102300635B (zh) 2014-10-29
IL219400A0 (en) 2012-06-28
RU2549893C2 (ru) 2015-05-10
EP2493609A1 (en) 2012-09-05
WO2011056595A1 (en) 2011-05-12
RU2012121807A (ru) 2013-12-10
CA2778957A1 (en) 2011-05-12
BR112012009770A2 (pt) 2016-05-17
AU2010315552B2 (en) 2016-05-12

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