WO2016020656A3 - Methanol production catalyst and methanol production process - Google Patents

Methanol production catalyst and methanol production process Download PDF

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Publication number
WO2016020656A3
WO2016020656A3 PCT/GB2015/052226 GB2015052226W WO2016020656A3 WO 2016020656 A3 WO2016020656 A3 WO 2016020656A3 GB 2015052226 W GB2015052226 W GB 2015052226W WO 2016020656 A3 WO2016020656 A3 WO 2016020656A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
methanol production
palladium
zinc
zinc oxide
Prior art date
Application number
PCT/GB2015/052226
Other languages
French (fr)
Other versions
WO2016020656A2 (en
Inventor
Shik Chi Edman Tsang
Fenglin Liao
Original Assignee
Isis Innovation Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Isis Innovation Limited filed Critical Isis Innovation Limited
Publication of WO2016020656A2 publication Critical patent/WO2016020656A2/en
Publication of WO2016020656A3 publication Critical patent/WO2016020656A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/057—Selenium or tellurium; Compounds thereof
    • B01J27/0573—Selenium; Compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
    • B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

The invention provides a process for producing methanol. The process comprises contacting a gas phase with a solid catalyst, wherein the gas phase comprises (a) H2 and (b) C02, CO or a mixture of C02 and CO, and the catalyst comprises heterometallic particles comprising palladium and zinc. The invention also provides a catalyst which comprises heterometallic particles of palladium and zinc and a support material comprising zinc oxide. Also provided is a process for producing such a catalyst, the process comprising reducing a composition comprising palladium and zinc oxide. A catalyst obtainable by this process is also provided. The invention also relates to uses of the described catalysts for the hydrogenation of C02, CO, or a mixture of C02 and CO, to produce methanol, and, more particularly, for the hydrogenation of C02 to produce methanol. The invention also provides a composition which comprises palladium, zinc oxide and a compound suitable for promoting the reduction by hydrogen gas of zinc oxide to zinc metal.
PCT/GB2015/052226 2014-08-04 2015-07-31 Methanol production process WO2016020656A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1413778.0 2014-08-04
GBGB1413778.0A GB201413778D0 (en) 2014-08-04 2014-08-04 Methanol production process

Publications (2)

Publication Number Publication Date
WO2016020656A2 WO2016020656A2 (en) 2016-02-11
WO2016020656A3 true WO2016020656A3 (en) 2016-05-06

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2015/052226 WO2016020656A2 (en) 2014-08-04 2015-07-31 Methanol production process

Country Status (2)

Country Link
GB (1) GB201413778D0 (en)
WO (1) WO2016020656A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109847742B (en) * 2019-01-09 2021-05-14 山西大学 Flocculent palladium nano material and preparation method and application thereof
CN113200818B (en) * 2021-05-06 2022-07-19 中国华能集团清洁能源技术研究院有限公司 Carbon dioxide conversion system in methanol preparation process from coal and working method thereof
CN114160143B (en) * 2021-12-08 2024-01-30 上海簇睿低碳能源技术有限公司 CO (carbon monoxide) 2 Catalyst for preparing methanol by hydrogenation and preparation method and application thereof
CN115106089B (en) * 2022-05-11 2024-03-29 中国科学技术大学 ZnO loaded composite material, preparation method and application thereof
CN114917931B (en) * 2022-05-30 2023-11-07 合肥综合性国家科学中心能源研究院(安徽省能源实验室) Copper-palladium-boron/biomass charcoal catalyst, preparation method and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4393144A (en) * 1978-09-20 1983-07-12 Sagami Chemical Research Center Method for producing methanol
US6342538B1 (en) * 1998-12-17 2002-01-29 Agency Of Industrial Science & Technology Catalyst for the synthesis of methanol and a method for the synthesis of methanol
US6413449B1 (en) * 1999-05-22 2002-07-02 Degussa-Huls Aktiengesellschaft Method of using catalyst for steam reforming of alcohols
US20060182997A1 (en) * 2003-03-17 2006-08-17 Takao Yamamoto Noble metal-magnetic metal oxide composite particle and method for producing same
US20070161717A1 (en) * 2005-12-16 2007-07-12 Battelle Memorial Institute Alcohol Synthesis From CO or CO2
US20110250122A1 (en) * 2008-11-07 2011-10-13 The Regents Of The University Of California Core-Shell Nanocatalyst For High Temperature Reactions

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4393144A (en) * 1978-09-20 1983-07-12 Sagami Chemical Research Center Method for producing methanol
US6342538B1 (en) * 1998-12-17 2002-01-29 Agency Of Industrial Science & Technology Catalyst for the synthesis of methanol and a method for the synthesis of methanol
US6413449B1 (en) * 1999-05-22 2002-07-02 Degussa-Huls Aktiengesellschaft Method of using catalyst for steam reforming of alcohols
US20060182997A1 (en) * 2003-03-17 2006-08-17 Takao Yamamoto Noble metal-magnetic metal oxide composite particle and method for producing same
US20070161717A1 (en) * 2005-12-16 2007-07-12 Battelle Memorial Institute Alcohol Synthesis From CO or CO2
US20110250122A1 (en) * 2008-11-07 2011-10-13 The Regents Of The University Of California Core-Shell Nanocatalyst For High Temperature Reactions

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
CHEOL-HYUN KIM ET AL: "The Preparation and Characterisation of Pd-ZnO Catalysts for Methanol Synthesis", TOPICS IN CATALYSIS, KLUWER ACADEMIC PUBLISHERS-PLENUM PUBLISHERS, NE, vol. 22, no. 3-4, 1 April 2003 (2003-04-01), pages 319 - 324, XP019291933, ISSN: 1572-9028 *
LEBARBIER V ET AL: "The effect of PdZn particle size on reverse-watergas-shift reaction", APPLIED CATALYSIS A: GENERAL, ELSEVIER SCIENCE, AMSTERDAM, NL, vol. 379, no. 1-2, 15 May 2010 (2010-05-15), pages 3 - 6, XP027013153, ISSN: 0926-860X, [retrieved on 20100301] *
LIANG X L ET AL: "Carbon nanotube-supported Pd-ZnO catalyst for hydrogenation of CO2 to methanol", APPLIED CATALYSIS B: ENVIRONMENTAL, ELSEVIER, AMSTERDAM, NL, vol. 88, no. 3-4, 20 May 2009 (2009-05-20), pages 315 - 322, XP026085599, ISSN: 0926-3373, [retrieved on 20081124], DOI: 10.1016/J.APCATB.2008.11.018 *

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Publication number Publication date
WO2016020656A2 (en) 2016-02-11
GB201413778D0 (en) 2014-09-17

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