WO2009104427A1 - 磁気ランダムアクセスメモリ - Google Patents
磁気ランダムアクセスメモリ Download PDFInfo
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- WO2009104427A1 WO2009104427A1 PCT/JP2009/050185 JP2009050185W WO2009104427A1 WO 2009104427 A1 WO2009104427 A1 WO 2009104427A1 JP 2009050185 W JP2009050185 W JP 2009050185W WO 2009104427 A1 WO2009104427 A1 WO 2009104427A1
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C11/00—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
- G11C11/02—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
- G11C11/16—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
- G11C11/161—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect details concerning the memory cell structure, e.g. the layers of the ferromagnetic memory cell
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C11/00—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
- G11C11/02—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
- G11C11/16—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
- G11C11/165—Auxiliary circuits
- G11C11/1653—Address circuits or decoders
- G11C11/1655—Bit-line or column circuits
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C11/00—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
- G11C11/02—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
- G11C11/16—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
- G11C11/165—Auxiliary circuits
- G11C11/1659—Cell access
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C11/00—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
- G11C11/02—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
- G11C11/16—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
- G11C11/165—Auxiliary circuits
- G11C11/1673—Reading or sensing circuits or methods
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11C—STATIC STORES
- G11C11/00—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
- G11C11/02—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements
- G11C11/16—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using magnetic elements using elements in which the storage effect is based on magnetic spin effect
- G11C11/165—Auxiliary circuits
- G11C11/1675—Writing or programming circuits or methods
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B61/00—Magnetic memory devices, e.g. magnetoresistive RAM [MRAM] devices
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- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10N50/00—Galvanomagnetic devices
- H10N50/10—Magnetoresistive devices
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/902—Specified use of nanostructure
- Y10S977/932—Specified use of nanostructure for electronic or optoelectronic application
- Y10S977/933—Spintronics or quantum computing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/902—Specified use of nanostructure
- Y10S977/932—Specified use of nanostructure for electronic or optoelectronic application
- Y10S977/933—Spintronics or quantum computing
- Y10S977/935—Spin dependent tunnel, SDT, junction, e.g. tunneling magnetoresistance, TMR
Definitions
- the present invention relates to a magnetic random access memory (MRAM: “Magnetic Random Access Memory”).
- MRAM Magnetic Random Access Memory
- the present invention relates to a spin injection magnetization reversal MRAM.
- the MRAM is a non-volatile random access memory using a magnetoresistive element such as a magnetic tunnel junction (Magnetic Tunnel Junction) element as a storage element.
- MRAM is capable of high-speed operation and can have endurance of infinite rewriting. Therefore, active research and development has been carried out, and in recent years commercialization has been achieved.
- it is required to reduce the write current and increase the read signal. This is because when the write current is reduced, not only the power consumption during operation is reduced, but also the cost is reduced by reducing the chip area.
- the read signal amount is increased, the read time is shortened to operate at a higher speed. This is because it becomes possible.
- the following spin transfer magnetization switching method has been proposed. For example, consider a storage element in which a first magnetic layer having reversible magnetization, a nonmagnetic layer, and a second magnetic layer having a fixed magnetization direction are stacked. According to the spin injection magnetization reversal method, a write current is passed between the second magnetic layer and the first magnetic layer, spin-polarized conduction electrons that carry the write current, and localization in the first magnetic layer. Due to the interaction with the electrons, the magnetization of the first magnetic layer is reversed.
- the direct flow of current to the memory element at the time of data writing is performed by applying a magnetic field application method (a general writing method) (first by applying a magnetic field generated by flowing a write current to a wiring arranged near the memory element).
- a magnetic field application method a general writing method
- magnetization reversal occurs when the current density exceeds a certain threshold. Since the current density increases as the cell size is reduced, the write current can also be reduced with miniaturization. That is, the write current scaling property is improved.
- Patent Document 1 discloses material characteristics such that the threshold current density for magnetization reversal is a desired value or less. According to this, the threshold current density can be reduced by using a perpendicularly magnetized film as a magnetic layer and appropriately adjusting the magnetic anisotropy energy density and the saturation magnetization.
- MR ratio magnetoresistive effect ratio
- an MTJ element that exhibits a high magnetoresistive effect ratio has been actively developed. Hayaka et al. , Effect of high annealing temperature on giant tunnel magnetoresistance ratio of CoFeB / MgO / CoFeB magnetotunnel junctions, APPLIED PHYSILS. 89, p.
- Non-patent document 1 a very large MR ratio (about 500% at room temperature) is obtained in a Co—Fe—B / Mg—O / Co—Fe—B MTJ.
- the reason why such a high MR ratio can be obtained in a Co—Fe—B / Mg—O / Co—Fe—B MTJ is considered as follows: (1) Co—Fe—B is high (2) Annealed Mg—O sandwiched between amorphous Co—Fe—B at a high temperature to form a (001) oriented polycrystalline MgO having a high spin filtering effect. Is done.
- a perpendicular magnetization film with appropriately adjusted material characteristics is used as the magnetic layer. Can be considered.
- an MTJ composed of a magnetic layer having a high spin polarizability and an insulating layer exhibiting a high spin filtering effect.
- Patent Document 1 states that saturation magnetization is smaller as a suitable material characteristic of the perpendicular magnetization film.
- the spin polarizability of the magnetic layer generally increases as the saturation magnetization increases, and decreases as the saturation magnetization decreases. Therefore, with a suitable material characteristic of the perpendicular magnetization film, a high spin polarizability cannot be obtained, and it is difficult to improve the MR ratio. That is, the reduction of the write threshold current density in the spin transfer magnetization reversal and the improvement of the MR ratio are in a mutually contradictory relationship.
- the Co—Fe—B thin film having a high spin polarizability is an in-plane magnetization film in which the magnetic anisotropy is parallel to the film surface.
- an in-plane magnetization film is used as a magnetic layer, it is difficult to sufficiently reduce the write threshold current density in spin injection magnetization reversal.
- One object of the present invention is to provide a technique capable of suppressing variations in the reference level at the time of data reading in a spin injection magnetization reversal type MRAM.
- a spin injection magnetization reversal type MRAM includes a memory cell and a reference cell that is referenced to generate a reference level when reading data.
- the memory cell includes a first magnetoresistive element, and the reference cell includes a second magnetoresistive element.
- the first magnetoresistive element includes a first magnetization fixed layer whose magnetization direction is fixed, a first magnetization free layer whose magnetization direction can be reversed, a first magnetization fixed layer, and a first magnetization free layer sandwiched between the first magnetization fixed layer and the first magnetization free layer.
- a nonmagnetic layer a nonmagnetic layer, a second magnetization fixed layer whose magnetization direction is fixed, a second magnetization free layer whose magnetization direction can be reversed, and a second magnetization sandwiched between the second magnetization fixed layer and the second magnetization free layer A nonmagnetic layer.
- the first magnetization fixed layer and the first magnetization free layer have perpendicular magnetic anisotropy
- the second magnetization fixed layer and the second magnetization free layer have in-plane magnetic anisotropy.
- the first magnetization free layer and the second magnetization free layer are magnetically coupled to each other. In the first plane parallel to each layer, the center of gravity of the second magnetization free layer is shifted in the first direction from the center of gravity of the first magnetization free layer.
- the second magnetoresistive element includes a third magnetization free layer whose easy axis is parallel to the second direction, a third magnetization fixed layer whose magnetization direction is fixed in a third direction orthogonal to the second direction, and a third magnetization A third nonmagnetic layer sandwiched between the fixed layer and the third magnetization free layer.
- the third magnetization fixed layer and the third magnetization free layer have in-plane magnetic anisotropy.
- write characteristics and read characteristics can be independently improved in a spin injection magnetization reversal MRAM. Furthermore, it is possible to suppress variations in the reference level when reading data.
- FIG. 1A is a perspective view showing an example of a first magnetoresistive element according to an exemplary embodiment of the present invention.
- FIG. 1B is an xy plan view of the structure shown in FIG. 1A.
- FIG. 1C is an xz side view of the structure shown in FIG. 1A.
- FIG. 2A is a conceptual diagram for explaining the principle of the first magnetoresistive element.
- FIG. 2B is a conceptual diagram for explaining the principle of the first magnetoresistive element.
- FIG. 2C is an xz side view for explaining a memory state of the first magnetoresistive element.
- FIG. 2D is an xz side view for explaining a memory state of the first magnetoresistive element.
- FIG. 1A is a perspective view showing an example of a first magnetoresistive element according to an exemplary embodiment of the present invention.
- FIG. 1B is an xy plan view of the structure shown in FIG. 1A.
- FIG. 1C is an xz side view of the
- FIG. 3A is a conceptual diagram for explaining a method of writing information to the first magnetoresistive element.
- FIG. 3B is a conceptual diagram for explaining a method of writing information to the first magnetoresistive element.
- FIG. 4A is a conceptual diagram for explaining a method of reading information from the first magnetoresistive element.
- FIG. 4B is a conceptual diagram for explaining a method of reading information from the first magnetoresistive element.
- FIG. 5A is a perspective view showing a first modification of the first magnetoresistive element.
- FIG. 5B is an xy plan view of the structure shown in FIG. 5A.
- FIG. 5C is an xz side view of the structure shown in FIG. 5A.
- FIG. 5D is a yz side view of the structure shown in FIG. 5A.
- FIG. 5A is a perspective view showing a first modification of the first magnetoresistive element.
- FIG. 5B is an xy plan view of the structure shown in FIG. 5A.
- FIG. 6A is a perspective view showing a second modification of the first magnetoresistive element.
- FIG. 6B is an xy plan view of the structure shown in FIG. 6A.
- FIG. 6C is an xz side view of the structure shown in FIG. 6A.
- FIG. 7A is a conceptual diagram for explaining a method of writing information to the first magnetoresistive element according to the second modification.
- FIG. 7B is a conceptual diagram for explaining a method of reading information from the first magnetoresistance element according to the second modification.
- FIG. 8A is a perspective view showing another example of the first magnetoresistance element.
- FIG. 8B is an xy plan view of the structure shown in FIG. 8A.
- FIG. 8C is an xz side view of the structure shown in FIG. 8A.
- FIG. 9A is a perspective view showing a third modification of the first magnetoresistive element.
- FIG. 9B is an xy plan view of the structure shown in FIG. 9A.
- FIG. 9C is an xz side view of the structure shown in FIG. 9A.
- FIG. 10A is an xz side view for explaining a memory state of the first magnetoresistance element according to the third modification example.
- FIG. 10B is an xz side view for explaining a memory state of the first magnetoresistance element according to the third modification example.
- FIG. 11A is a conceptual diagram for explaining a method of writing information to the first magnetoresistive element according to the third modification.
- FIG. 11B is a conceptual diagram for explaining a method of reading information from the first magnetoresistive element according to the third modification.
- FIG. 11A is a conceptual diagram for explaining a method of writing information to the first magnetoresistive element according to the third modification.
- FIG. 11B is a conceptual diagram for explaining a method of reading
- FIG. 12A is a perspective view showing a fourth modification of the first magnetoresistance element.
- FIG. 12B is an xy plan view of the structure shown in FIG. 12A.
- FIG. 12C is an xz side view of the structure shown in FIG. 12A.
- FIG. 13A is a conceptual diagram for explaining a method of writing information to the first magnetoresistive element according to the fourth modification.
- FIG. 13B is a conceptual diagram for explaining a method of reading information from the first magnetoresistance element according to the fourth modification example.
- FIG. 14 is a schematic diagram showing the configuration of a typical MRAM.
- FIG. 15 is a perspective view showing an example of the first magnetoresistance element according to the exemplary embodiment of the present invention.
- FIG. 16 is a plan view showing the magnetization state of the first magnetoresistive element shown in FIG.
- FIG. 17 is a conceptual diagram showing variations in the magnetization state.
- FIG. 18 is a histogram for explaining the variation of the reference level.
- FIG. 19A is a perspective view showing an example of the second magnetoresistance element according to the exemplary embodiment of the present invention.
- FIG. 19B is a plan view showing the magnetization state of the second magnetoresistive element shown in FIG. 19A.
- FIG. 20A is a perspective view showing another example of the second magnetoresistance element according to the exemplary embodiment of the present invention.
- FIG. 20B is an xy plan view of the structure shown in FIG. 20A.
- FIG. 21A is a perspective view showing still another example of the second magnetoresistance element according to the exemplary embodiment of the present invention.
- FIG. 21B is an xy plan view of the structure shown in FIG. 21A.
- FIG. 22A is a perspective view showing still another example of the second magnetoresistance element according to the exemplary embodiment of the present invention.
- FIG. 22B is an xy plan view of the structure shown in FIG. 22A.
- FIG. 23 is a schematic diagram showing the configuration of the MRAM according to the embodiment of the present invention.
- FIG. 24 is a conceptual diagram showing magnetization states of the memory cell and the reference cell according to the embodiment of the present invention.
- FIG. 1A is a perspective view showing a structure of a first magnetoresistance element 1 according to an exemplary embodiment of the present invention.
- 1B and 1C are respectively an xy plan view and an xz side view of the structure shown in FIG. 1A.
- the first magnetoresistive element 1 has a laminated structure composed of a plurality of layers, and the lamination direction is defined as the z-axis direction.
- a plane parallel to each layer of the stacked structure is an xy plane.
- the first magnetoresistive element 1 includes a first magnetization fixed layer 10, a first spacer layer 20, a first magnetization free layer 30, a second magnetization free layer 40, a second spacer layer 50, and a second A magnetization fixed layer 60 is provided.
- the first magnetization fixed layer 10 is provided adjacent to one surface of the first spacer layer 20, and the first magnetization free layer 30 is provided adjacent to the other surface of the first spacer layer 20. That is, the first spacer layer 20 is sandwiched between the first magnetization fixed layer 10 and the first magnetization free layer 30.
- the second magnetization fixed layer 60 is provided adjacent to one surface of the second spacer layer 50, and the second magnetization free layer 40 is provided adjacent to the other surface of the second spacer layer 50. Yes. That is, the second spacer layer 50 is sandwiched between the second magnetization fixed layer 60 and the second magnetization free layer 40.
- the first magnetoresistive element 1 further includes a first conductive layer 70 and a second conductive layer 80.
- the first conductive layer 70 is provided so as to be electrically connected to the first magnetization free layer 30 and the second magnetization free layer 40.
- the first conductive layer 70 is sandwiched between the first magnetization free layer 30 and the second magnetization free layer 40.
- the second conductive layer 80 is provided so as to be electrically connected to the first conductive layer 70.
- Each of the first spacer layer 20 and the second spacer layer 50 is a nonmagnetic layer formed of a nonmagnetic material.
- the first spacer layer 20 and the second spacer layer 50 may have any electrical characteristics, and the material may be a conductor, an insulator, or a semiconductor.
- the second spacer layer 50 is preferably formed of an insulator.
- Each of the first magnetization fixed layer 10, the first magnetization free layer 30, the second magnetization free layer 40, and the second magnetization fixed layer 60 is a ferromagnetic layer formed of a ferromagnetic material.
- the first magnetization fixed layer 10 and the first magnetization free layer 30 are a perpendicular magnetization film having a perpendicular magnetic anisotropy. That is, the first magnetization fixed layer 10 and the first magnetization free layer 30 have magnetic anisotropy in the direction perpendicular to the film surface (z-axis direction).
- the second magnetization free layer 40 and the second magnetization fixed layer 60 are in-plane magnetization films having in-plane magnetic anisotropy. That is, the second magnetization free layer 40 and the second magnetization fixed layer 60 have magnetic anisotropy in the direction parallel to the film surface.
- FIG. 1C shows the magnetization direction of each layer.
- the magnetization direction of the first magnetization fixed layer 10 is substantially fixed in one direction.
- the magnetization direction of the first magnetization free layer 30 can be reversed. Since the first magnetization fixed layer 10 and the first magnetization free layer 30 have perpendicular magnetic anisotropy, their magnetization directions are substantially parallel to the z-axis.
- the magnetization of the first magnetization fixed layer 10 is fixed in the + z direction.
- the magnetization of the first magnetization free layer 30 is allowed to be in the + z direction or the ⁇ z direction. That is, the magnetization direction of the first magnetization free layer 30 can be parallel or antiparallel to the magnetization direction of the first magnetization fixed layer 10.
- the magnetization direction of the second magnetization fixed layer 60 is substantially fixed in one direction.
- the magnetization direction of the second magnetization free layer 40 can be reversed. Since the second magnetization fixed layer 60 and the second magnetization free layer 40 have in-plane magnetic anisotropy, their magnetization directions are substantially parallel to the film surface (xy plane).
- the magnetization of the second magnetization fixed layer 60 is fixed in the + x direction.
- the magnetization of the second magnetization free layer 40 has a component in the + x direction or the ⁇ x direction. That is, the magnetization of the second magnetization free layer 40 has a component that is parallel or antiparallel to the magnetization direction of the second magnetization fixed layer 60.
- the first magnetization free layer 30 and the second magnetization free layer 40 are formed in different layers, but are magnetically coupled to each other. In other words, the magnetization state of the first magnetization free layer 30 and the magnetization state of the second magnetization free layer 40 affect each other. As will be described later, it is important that the magnetization state of the first magnetization free layer 30 affects the magnetization state of the second magnetization free layer 40.
- FIG. 1B also shows the positions of the centroid G30 of the first magnetization free layer 30 and the centroid G40 of the second magnetization free layer 40 in the xy plane.
- ⁇ i means the total sum related to i.
- the center of gravity is the intersection of diagonal lines, and in the case of an ellipse, the center of gravity is the center.
- the centroid G30 of the first magnetization free layer 30 and the centroid G40 of the second magnetization free layer 40 are shifted in the xy plane. That is, in the xy plane, the center G40 of the second magnetization free layer 40 is shifted from the center G30 of the first magnetization free layer 30 in the “first direction” parallel to the film surface.
- the first direction (shift direction) is the + x direction.
- the first magnetization free layer 30 and the second magnetization free layer 40 may overlap at least partially, or may not overlap.
- each layer in the xy plane is not limited to a rectangle, and may be a circle, an ellipse, a rhombus, a hexagon, or the like.
- FIG. 2A and 2B schematically show a leakage magnetic field (leakage magnetic flux) generated in the periphery by the magnetization of the first magnetization free layer 30.
- FIG. FIG. 2A shows a state in the xz plane
- FIG. 2B shows a state in the xy plane.
- the magnetic field lines of the leakage magnetic field have a dipole shape as shown in FIG. 2A, and come out from the upper surface (positive magnetic pole side) of the first magnetization free layer 30 and smoothly connect to the lower surface (negative magnetic pole side). .
- the leakage magnetic field spreads radially from the center of gravity G30 of the first magnetization free layer 30.
- the leakage magnetic field is substantially in the z direction, and as the end of the first magnetization free layer 30 is approached, the leakage magnetic field has a larger xy component (component in the film plane parallel direction). Will have.
- the centroid G40 of the second magnetization free layer 40 is shifted in the “first direction” from the centroid G30 of the first magnetization free layer 30 in the xy plane. Accordingly, the leakage magnetic field generated by the magnetization of the first magnetization free layer 30 has an xy component along the “first direction” at the position of the center of gravity G40 of the second magnetization free layer 40. That is, the magnetization of the first magnetization free layer 30 exerts a magnetic force substantially parallel or substantially antiparallel to the “first direction” on the second magnetization free layer 40. As a result, the magnetization of the second magnetization free layer 40 has a component substantially parallel or substantially antiparallel to the “first direction”.
- 2C and 2D illustrate two memory states that the first magnetoresistive element 1 can take.
- the magnetization direction of the first magnetization fixed layer 10 is fixed in the + z direction
- the magnetization direction of the second magnetization fixed layer 60 is fixed in the + x direction.
- the shift direction (first direction) of the centroid G40 of the second magnetization free layer 40 with respect to the centroid G30 of the first magnetization free layer 30 is the + x direction.
- This first direction is also arbitrary. However, it is desirable that the first direction is substantially parallel or substantially antiparallel to the magnetization direction of the second magnetization fixed layer 60.
- the magnetization of the first magnetization free layer 30 is in the + z direction.
- the leakage magnetic field from the first magnetization free layer 30 has a + x component along the first direction at the position of the center of gravity G40 of the second magnetization free layer 40. Therefore, due to the magnetic coupling between the first magnetization free layer 30 and the second magnetization free layer 40, the magnetization of the second magnetization free layer 40 has a component in the + x direction.
- the magnetization direction of the second magnetization free layer 40 has a component that is “parallel” to the magnetization direction of the second magnetization fixed layer 60, and the second magnetization free layer 40, the second spacer layer 50, and the second magnetization fixed pinion.
- the resistance value of the MTJ composed of the layer 60 is relatively small.
- the memory state shown in FIG. 2C is hereinafter referred to as a “0” state.
- the magnetization of the first magnetization free layer 30 is in the ⁇ z direction.
- the leakage magnetic field from the first magnetization free layer 30 has a ⁇ x component along the first direction at the position of the center of gravity G40 of the second magnetization free layer 40. Accordingly, the magnetic coupling between the first magnetization free layer 30 and the second magnetization free layer 40 causes the magnetization of the second magnetization free layer 40 to have a component in the ⁇ x direction.
- the magnetization direction of the second magnetization free layer 40 has a component that is “anti-parallel” to the magnetization direction of the second magnetization fixed layer 60, and the second magnetization free layer 40, the second spacer layer 50, and the second magnetization
- the resistance value of the MTJ composed of the fixed layer 60 is relatively large.
- the memory state shown in FIG. 2D is hereinafter referred to as “1” state.
- the magnetization direction of the second magnetization free layer 40 depends on the magnetization direction of the first magnetization free layer 30 due to the shift of the center of gravity between the magnetization free layers 30 and 40 and magnetic coupling. Determined as “unique”.
- the magnetization direction of the first magnetization free layer 30 is reversed, the magnetization direction of the second magnetization free layer 40 also changes.
- a difference occurs in the relative angle of the magnetization direction between the second magnetization free layer 40 and the second magnetization fixed layer 60, and two memory states of “0” state and “1” state are realized. That is, two memory states are realized according to the magnetization direction of the first magnetization free layer 30.
- the direction of fixed magnetization of the second magnetization fixed layer 60 is substantially parallel or substantially antiparallel to the direction of shift of the center of gravity (first direction) between the first magnetization free layer 30 and the second magnetization free layer 40.
- first direction the direction of shift of the center of gravity
- variable magnetization of the second magnetization free layer 40 has a component that is substantially parallel or substantially antiparallel to the first direction depending on the magnetization direction of the first magnetization free layer 30.
- the information stored as the perpendicular magnetization component in the first magnetization free layer 30 is transmitted to the magnetization component in the film surface direction of the second magnetization free layer 40 through magnetic coupling. It can be said.
- the magnetic coupling method is not limited to the one using the above-described leakage magnetic field.
- the first magnetization free layer 30 and the second magnetization free layer 40 can be magnetically related by any magnetic coupling method such as a method using exchange coupling.
- the easy axis of magnetization of the second magnetization free layer 40 may be along any direction.
- the magnetization of the second magnetization free layer 40 is reversed between the directions along the easy magnetization axis.
- the magnetization of the second magnetization free layer 40 rotates in the hard axis direction centering on the easy axis.
- the magnetic anisotropy of the second magnetization free layer 40 may be imparted by crystal magnetic anisotropy or may be imparted by shape magnetic anisotropy.
- FIGS. 3A and 3B are conceptual diagrams for explaining a method of writing data to the first magnetoresistive element 1.
- Data writing is realized by the “spin injection magnetization reversal method”. Specifically, the first magnetization fixed layer 10, the first spacer layer 20, and the first magnetization free layer 30 are used, and the write current Iwrite flows between the first magnetization fixed layer 10 and the first magnetization free layer 30. It is.
- FIG. 3A shows a transition from the “0” state (see FIG. 2C) to the “1” state (see FIG. 2D), that is, the path of the write current Iwrite at the time of writing “1”.
- the magnetization direction of the first magnetization fixed layer 10 is fixed in the + z direction, and the conduction electrons having the spin angular momentum in the ⁇ z direction are compared with the conduction electrons having the spin angular momentum in the + z direction. More reflections are made at the interface of the single magnetization fixed layer 10.
- the first magnetization free layer 30 electrons having a spin angular momentum in the ⁇ z direction become the majority, and magnetization reversal in the ⁇ z direction is induced.
- the magnetization of the second magnetization free layer 40 has a component in the ⁇ x direction due to the magnetic coupling described above. That is, the “1” state shown in FIG. 2D is obtained.
- FIG. 3B shows a transition from the “1” state (see FIG. 2D) to the “0” state (see FIG. 2C), that is, the path of the write current Iwrite at the time of writing “0”.
- a write current Iwrite is introduced in the direction of the arrow in the “1” state as shown in FIG. 3B.
- the write current Iwrite flows from the first magnetization free layer 30 to the first magnetization fixed layer 10 through the first spacer layer 20, and conduction electrons pass through the first magnetization fixed layer 10 through the first spacer layer 20 to the first magnetization. It flows to the free layer 30.
- FIG. 3B shows a transition from the “1” state (see FIG. 2D) to the “0” state (see FIG. 2C), that is, the path of the write current Iwrite at the time of writing “0”.
- the magnetization direction of the first magnetization fixed layer 10 is fixed in the + z direction, and many conduction electrons having a spin angular momentum in the + z direction flow into the first magnetization free layer 30.
- electrons having a spin angular momentum in the + z direction become majority, and magnetization reversal in the + z direction is induced.
- the magnetization of the second magnetization free layer 40 has a component in the + x direction due to the magnetic coupling described above. That is, the “0” state shown in FIG. 2C is obtained.
- 4A and 4B are conceptual diagrams for explaining a method of reading data from the first magnetoresistive element 1.
- data reading the magnitude of the resistance value due to the magnetoresistive effect is detected.
- the second magnetization free layer 40, the second spacer layer 50, and the second magnetization fixed layer 60 are used, and a read current Iread flows between the second magnetization free layer 40 and the second magnetization fixed layer 60.
- FIG. 4A shows the case of the “0” state (see FIG. 2C). In this case, the resistance value of the second magnetoresistive element is relatively small.
- FIG. 4B shows the case of the “1” state (see FIG. 2D). In this case, the resistance value of the second magnetoresistive element is relatively large. That is, the read current Iread or the magnitude of the read voltage corresponding to the read current Iread varies depending on the “0” state or the “1” state. Therefore, by comparing the read current Iread or the read voltage with a predetermined reference level, it is possible to determine whether the state is “0” or “1”.
- the first magnetization fixed layer 10, the first spacer layer 20, and the first magnetization free layer 30 are used at the time of data writing.
- the first magnetization fixed layer 10, the first spacer layer 20, and the first magnetization free layer 30 are referred to as a “write layer group”.
- the second magnetization free layer 40, the second spacer layer 50, and the second magnetization fixed layer 60 are used when reading data. In this sense, the second magnetization free layer 40, the second spacer layer 50, and the second magnetization fixed layer 60 are referred to as a “read layer group”.
- the write layer group and the read layer group are provided separately, but are related to each other through magnetic coupling.
- Information written to the first magnetization free layer 30 of the write layer group is transmitted to the second magnetization free layer 40 of the read layer group via magnetic coupling.
- the write layer group and the read layer group can be optimized independently so that desired characteristics can be obtained.
- the first magnetization fixed layer 10 and the first magnetization free layer 30 that are perpendicular magnetization films are formed of a ferromagnetic material including at least one material selected from Fe, Co, and Ni. Moreover, perpendicular magnetic anisotropy can be stabilized by adding Pt or Pd.
- Pt or Pd perpendicular magnetic anisotropy
- Specific materials include Co, Co—Pt, Co—Pd, Co—Cr, Co—Pt—Cr, Co—Cr—Ta, Co—Cr—B, Co—Cr—Pt—B, and Co—Cr.
- -Ta-B Co-V, Co-Mo, Co-W, Co-Ti, Co-Ru, Co-Rh, Fe-Pt, Fe-Pd, Fe-Co-Pt, Fe-Co-Pd, Sm -Co, Gd-Fe-Co, Tb-Fe-Co, Gd-Tb-Fe-Co and the like are exemplified.
- perpendicular magnetic anisotropy can also be exhibited by laminating a layer containing any one material selected from Fe, Co, and Ni with different layers. Specifically, a laminated film of Co / Pd, Co / Pt, Co / Ni, Fe / Au, etc. is exemplified.
- the second magnetization free layer 40 and the second magnetization fixed layer 60 that are in-plane magnetization films are formed of a ferromagnetic material including at least one material selected from Fe, Co, and Ni.
- a ferromagnetic material including at least one material selected from Fe, Co, and Ni.
- B, C, N, O, Al, Si, P, Ti, V, Cr, Mn, Cu, Zn, Zr, Nb, Mo, Tc, Ru, Rh, Ag, Hf, Ta, W , Re, Os, Ir, Au, etc. can be added to adjust the magnetic properties.
- Specific examples of the material include Ni—Fe, Co—Fe, Fe—Co—Ni, Ni—Fe—Zr, Co—Fe—B, and Co—Fe—Zr—B.
- the first spacer layer 20 can be used for various materials. For example, a conductor such as Al, Cr, or Cu can be used. Further, an insulator such as Mg—O may be used. As shown in FIGS. 3A and 3B, the first spacer layer 20 exists on the path of the write current. Generally, it is desirable that the resistance of the write current path is low. In this respect, a material having low resistance is preferable. On the other hand, if the first spacer layer 20 has a filtering effect that preferentially passes one spin-polarized electron, the current density required for writing is reduced. In this respect, Mg—O is preferable.
- the second spacer layer 50 is preferably formed of an insulating material.
- the material include Mg—O, Al—O, Al—N, Ni—O, and Hf—O.
- the second magnetization free layer 40, the second spacer layer 50, and the second magnetization fixed layer 60 are present on the read current path as shown in FIGS. 4A and 4B, and thus exhibit a high MR ratio. It is preferable to form with such a material. For example, in recent years, it has been reported that a very large MR ratio of 500% is obtained in a magnetic tunnel junction (MTJ) of Co—Fe—B / Mg—O / Co—Fe—B system (Non-patent Document 1). reference). From this point of view, the second spacer layer 50 preferably contains Mg—O. Further, it is preferable that at least one of the second magnetization free layer 40 and the second magnetization fixed layer 60 contains Co—Fe—B.
- MTJ magnetic tunnel junction
- a laminated film (laminated ferri-coupled film) in which the magnetizations are antiparallel coupled can be applied to a magnetization fixed layer such as the first magnetization fixed layer 10 or the second magnetization fixed layer 60.
- the magnetization of the magnetization fixed layer can be more firmly fixed, and the influence of the leakage magnetic field to the outside can be reduced.
- an antiferromagnetic layer adjacent to a magnetization fixed layer such as the first magnetization fixed layer 10 or the second magnetization fixed layer 60, the magnetization can be more firmly fixed.
- the material of the antiferromagnetic layer include Pt—Mn, Ir—Mn, and Fe—Mn.
- the first conductive layer 70 and the second conductive layer 80 are preferably formed of a material having a small electrical resistance.
- the first conductive layer 70 sandwiched between the first magnetization free layer 30 and the second magnetization free layer 40 may be formed of a magnetic material such as Fe, Co, or Ni.
- the leakage magnetic flux from the first magnetization free layer 30 can be efficiently transmitted to the second magnetization free layer 40, which is preferable from the viewpoint of the magnetic coupling described above.
- the first conductive layer 70 is preferably formed of a material having high magnetic permeability.
- the write characteristics, the recording data retention characteristics, and the read characteristics can be independently improved in the spin injection magnetization reversal MRAM. This is because, in the first magnetoresistive element 1 according to the present exemplary embodiment, a portion responsible for writing and recording data is different from a portion responsible for reading.
- spin injection magnetization reversal can be performed at a write threshold current density of 5 MA / cm 2 or less by using a perpendicular magnetization film in which various constants are appropriately set.
- an MR ratio close to 500% can be obtained by using an MTJ having a certain laminated structure.
- the present embodiment it is possible to reduce the write threshold current density by forming the first magnetization fixed layer 10 and the first magnetization free layer 30 that control data writing / holding with the perpendicular magnetization film.
- the second magnetization free layer 40 and the second magnetization fixed layer 60 that are responsible for data reading with in-plane magnetization films, it is possible to increase the MR ratio and increase the read signal.
- First Modified Example relates to the positional relationship between the first magnetization free layer 30 and the second magnetization free layer 40 in the xy plane.
- the positional relationship between the first magnetization free layer 30 and the second magnetization free layer 40 is not limited to the above example.
- the center of gravity G40 of the second magnetization free layer 40 may be positioned in the “first direction” with respect to the center of gravity G30 of the first magnetization free layer 30.
- FIG. 5A is a perspective view showing an example of the first magnetoresistive element 1.
- 5B, 5C, and 5D are respectively an xy plan view, an xz side view, and a yz side view of the structure shown in FIG. 5A.
- the shift direction (first direction) between the first magnetization free layer 30 and the second magnetization free layer 40 is the y-axis direction. That is, in the xy plane, the center G40 of the second magnetization free layer 40 is shifted from the center G30 of the first magnetization free layer 30 in the y-axis direction.
- the magnetization direction of the second magnetization free layer 40 is uniquely determined by the leakage magnetic field that spreads radially from the first magnetization free layer 30.
- the magnetization of the second magnetization free layer 40 has a component in the + y direction or the ⁇ y direction depending on the magnetization direction of the first magnetization free layer 30.
- the magnetization direction of the second magnetization fixed layer 60 is preferably fixed in either the + y direction or the ⁇ y direction.
- Second Modification A second modification relates to the positional relationship in the z-axis direction (stacking direction) of each layer constituting the first magnetoresistive element 1.
- the first magnetization fixed layer 10, the first spacer layer 20, and the first magnetization free layer 30 constitute a “write layer group”, and the second magnetization free layer 40, the second spacer layer 50, and the first magnetization layer 30.
- the two magnetization fixed layers 60 constitute a “read layer group”.
- the first conductive layer 70 and the second conductive layer 80 constitute a “plug group” that introduces a current into the write layer group and the read layer group.
- the positional relationship among the write layer group, the read layer group, and the plug group is not limited to that shown in the above example.
- the first magnetization free layer 30 of the write layer group and the second magnetization free layer 40 of the read layer group may be formed in different layers and magnetically coupled to each other.
- FIG. 6A is a perspective view showing an example of the first magnetoresistive element 1.
- 6B and 6C are respectively an xy plan view and an xz side view of the structure shown in FIG. 6A.
- the write layer group is provided above the read layer group.
- the second conductive layer 80 is provided on the reading layer group side (lower side) with respect to the first conductive layer 70.
- the first magnetization free layer 30 of the write layer group and the second magnetization free layer 40 of the read layer group are magnetically coupled to each other.
- the centroid G40 of the second magnetization free layer 40 is shifted from the centroid G30 of the first magnetization free layer 30 in the xy plane. Therefore, the magnetization direction of the second magnetization free layer 40 is uniquely determined by the leakage magnetic field that spreads radially from the first magnetization free layer 30.
- FIG. 7A conceptually shows the write current Iwrite in the example shown in FIGS. 6A to 6C. Similar to the above example, the write current Iwrite flows from the plug group to the write layer group or from the write layer group to the plug group. By changing the direction of the write current Iwrite, both “0” write and “1” write can be realized.
- FIG. 7B conceptually shows the read current Iread in the example shown in FIGS. 6A to 6C. Similar to the above example, by using the plug group, the read current Iread is introduced into the read layer group.
- FIG. 8A is a perspective view showing another example of the first magnetoresistive element 1.
- 8B and 8C are respectively an xy plan view and an xz side view of the structure shown in FIG. 8A.
- the write layer group is provided above the read layer group.
- the second conductive layer 80 is provided on the writing layer group side (upper side) with respect to the first conductive layer 70.
- the first magnetoresistance element 1 includes a plurality of write layer groups.
- Each of the plurality of write layer groups includes the first magnetization fixed layer 10, the first spacer layer 20, and the first magnetization free layer 30 described above.
- FIG. 9A is a perspective view showing an example of the first magnetoresistive element 1.
- 9B and 9C are an xy plan view and an xz side view of the structure shown in FIG. 9A, respectively.
- the first magnetoresistive element 1 includes a first write layer group, a second write layer group, a first conductive layer 70, and a read layer group (40 to 60). ing.
- the first write layer group includes a first magnetization fixed layer 10a, a first spacer layer 20a, and a first magnetization free layer 30a.
- the second write layer group includes a first magnetization fixed layer 10b, a first spacer layer 20b, and a first magnetization free layer 30b.
- the first magnetization fixed layer 10a and the first magnetization fixed layer 10b are formed in the same layer and have the same material, shape, and film thickness.
- the first spacer layer 20a and the first spacer layer 20b are formed in the same layer and have the same material, shape, and film thickness.
- the first magnetization free layer 30a and the first magnetization free layer 30b are formed in the same layer and have the same material, shape, and film thickness.
- both the first magnetization free layer 30a and the first magnetization free layer 30b are in contact with one surface of the first conductive layer 70, and the other surface has a second magnetization magnetization.
- the free layer 40 is in contact.
- the first magnetization free layer 30a and the second magnetization free layer 40 are magnetically coupled to each other.
- the center of gravity G40 of the second magnetization free layer 40 is shifted from the center of gravity G30a of the first magnetization free layer 30a. Therefore, the magnetization of the first magnetization free layer 30 a exerts a magnetic force in the in-plane direction on the second magnetization free layer 40.
- the first magnetization free layer 30b and the second magnetization free layer 40 are magnetically coupled to each other.
- the center of gravity G40 of the second magnetization free layer 40 is shifted from the center of gravity G30b of the first magnetization free layer 30b. Accordingly, the magnetization of the first magnetization free layer 30 b exerts a magnetic force in the in-plane direction on the second magnetization free layer 40.
- the centroid G40 of the second magnetization free layer 40 is located between the centroid G30a of the first magnetization free layer 30a and the centroid G30b of the first magnetization free layer 30b in the xy plane.
- the centroid G30a of the first magnetization free layer 30a, the centroid G40 of the second magnetization free layer 40, and the centroid G30b of the first magnetization free layer 30b are aligned on a straight line. is there. In the example shown in FIGS.
- the center G40 of the second magnetization free layer 40 is shifted in the + x direction from the center G30a of the first magnetization free layer 30a, and the center G30b of the first magnetization free layer 30b is The second magnetization free layer 40 is shifted from the center of gravity G40 in the + x direction.
- FIG. 10A and FIG. 10B each illustrate two memory states that the first magnetoresistive element 1 shown in FIGS. 9A to 9C can take.
- the magnetization directions of the first magnetization fixed layers 10a and 10b are parallel to each other and fixed in the same + z direction.
- the magnetization direction of the second magnetization fixed layer 60 is fixed in the + x direction.
- the magnetization of the first magnetization free layer 30a is oriented in the + z direction, while the magnetization of the first magnetization free layer 30b is oriented in the ⁇ z direction. That is, the magnetization directions of the first magnetization free layers 30a and 30b are substantially antiparallel to each other.
- both the leakage magnetic fields from the first magnetization free layers 30a and 30b have a + x component at the position of the center of gravity G40 of the second magnetization free layer 40. This is because the center of gravity G40 of the second magnetization free layer 40 is located between the centers of gravity G30a and G30b of the first magnetization free layers 30a and 30b.
- the center of gravity G40 is located between the centers of gravity G30a and G30b and the magnetization directions of the first magnetization free layers 30a and 30b are antiparallel, the magnetic force generated by the first magnetization free layers 30a and 30b is reduced to the second magnetization free layer. It strengthens each other at 40 positions. The strengthening effect of magnetic force is maximized when the centers of gravity G30a, G40, and G30b are aligned.
- the magnetization of the second magnetization free layer 40 has a component in the + x direction. At this time, the magnetization direction of the second magnetization free layer 40 has a component “parallel” to the magnetization direction of the second magnetization fixed layer 60 (“0” state).
- the magnetization of the first magnetization free layer 30a faces the ⁇ z direction
- the magnetization of the first magnetization free layer 30b faces the + z direction.
- both the leakage magnetic fields from the first magnetization free layers 30 a and 30 b have a ⁇ x component at the position of the center of gravity G 40 of the second magnetization free layer 40.
- the magnetization of the second magnetization free layer 40 has a component in the ⁇ x direction.
- the magnetization direction of the second magnetization free layer 40 has a component “anti-parallel” to the magnetization direction of the second magnetization fixed layer 60 (“1” state).
- the write current Iwrite flows between the first magnetization fixed layer 10 and the first magnetization free layer 30 in each of the write layer groups.
- the direction of the write current Iwrite in each write layer group is appropriately set so that the magnetization of each first magnetization free layer 30 is reversed.
- FIG. 11A shows an example of the write current Iwrite in the third modification.
- the magnetization directions of the first magnetization fixed layers 10a and 10b are parallel to each other, and the magnetization directions of the first magnetization free layers 30a and 30b are antiparallel to each other. Therefore, the direction of the write current Iwrite flowing between the first magnetization fixed layer 10a and the first magnetization free layer 30a of the first write layer group is the same as that of the first magnetization fixed layer 10b and the first magnetization fixed layer 10b of the second write layer group. It is set opposite to the direction of the write current Iwrite flowing between the magnetization free layer 30b. As a result, both antiparallel magnetizations of the first magnetization free layers 30a and 30b are reversed.
- the write current Iwrite is passed between the first write layer group and the second write layer group via the first conductive layer 70, and the direction of the write current Iwrite is changed.
- both “0” writing and “1” writing can be realized.
- FIG. 11B shows an example of a method for introducing the read current Iread.
- the read current Iread is introduced via the second write layer group.
- the read current Iread may pass through the first write layer group, or may pass through both the first write layer group and the second write layer group.
- the read signal further increases.
- two or more first magnetization free layers 30 that are sources of leakage magnetic fields that contribute to the rotation of magnetization of the second magnetization free layer 40 are provided. Therefore, the magnitude of the magnetic field acting on the second magnetization free layer 40 is more than twice, and the magnetization of the second magnetization free layer 40 rotates more greatly. As a result, a large magnetoresistive effect is exhibited, and a large read signal is obtained.
- the manufacturing process is simplified.
- the writing layer group (10 to 30) and the second conductive layer 80 are arranged in the same layer, they must be manufactured in separate steps.
- the first writing layer group and the second writing layer group can be manufactured in the same process. Therefore, the number of manufacturing processes is reduced, and the manufacturing cost is reduced.
- FIG. 12A is a perspective view showing an example of the first magnetoresistive element 1.
- 12B and 12C are respectively an xy plan view and an xz side view of the structure shown in FIG. 12A.
- the second conductive layer 80 is omitted, and the first magnetoresistive element 1 is a two-terminal element.
- the first magnetization free layer 30 and the second magnetization free layer 40 are magnetically coupled, and the center G40 of the second magnetization free layer 40 is shifted from the center G30 of the first magnetization free layer 30. ing. Therefore, the magnetization direction of the second magnetization free layer 40 is uniquely determined according to the magnetization direction of the first magnetization free layer 30.
- FIGS. 13A and 13B show paths of the write current Iwrite and the read current Iread in the present modification, respectively. Since the first magnetoresistive element 1 according to this modification is a two-terminal element, the write current Iwrite introduced into the write layer group during data writing also flows through the read layer group. Further, the read current Iread introduced into the read layer group at the time of data reading also flows through the write layer group. That is, the path of the write current Iwrite and the path of the read current Iread are the same.
- the read current Iread is set small. Further, it is necessary to prevent the spin injection magnetization reversal from occurring in the second magnetization free layer 40 due to the write current Iwrite during data writing. For this purpose, it is desirable to make the current density of the write current Iwrite flowing through the read layer group (40, 50, 60) smaller than the current density of the write current Iwrite flowing through the write layer group (10, 20, 30). For example, the area of the read layer group in the xy plane is designed to be larger than the area of the write layer group in the xy plane.
- the structure is simplified and the cell area is reduced.
- FIG. 14 schematically shows a configuration of a typical MRAM.
- An MRAM memory cell array has a plurality of cells arranged in a matrix. More specifically, the cell includes a memory cell MC for data recording and reference cells RC0 and RC1 that are referred to for generating a reference level when reading data.
- the memory cell MC and the reference cells RC0 and RC1 have magnetoresistive elements having the same structure.
- Data “0” or data “1” is stored in the memory cell MC.
- the resistance value of the magnetoresistive element of the memory cell MC is R0 when the data is “0”, and R1 when the data is “1”.
- the reference cell RC0 is set to data “0”, and the resistance value of the magnetoresistive element is R0.
- the reference cell RC1 is set to data “1”, and the resistance value of the magnetoresistive element is R1.
- Such setting of the reference cells RC0 and RC1 is performed by the same method as the data writing to the memory cell MC, and a dedicated set controller is provided for this purpose.
- a read current is supplied to the reference cells RC0 and RC1 in addition to the memory cell MC to be read.
- the read circuit generates a read level corresponding to the recording data of the memory cell MC based on the read current flowing through the memory cell MC.
- the read circuit generates a reference level corresponding to an intermediate resistance value between the resistance values R0 and R1, based on the read current flowing through each of the reference cells RC0 and RC1. Then, the read circuit determines the recording data of the memory cell MC by comparing the read level with the reference level.
- the first magnetoresistive element 1 described above is applied to the memory cell MC and the reference cells RC0 and RC1.
- the write layer group (10 to 30) and the read layer group (40 to 60) are separated.
- the magnetization state of the second magnetization free layer 40 of the read layer group that is, the MTJ resistance value of the read layer group is determined remotely depending on the magnetization state of the first magnetization free layer 30.
- the MTJ resistance value (R0 or R1) of the read layer group may vary even between the memory cells MC in which the same data is recorded. The same applies to the reference cells RC0 and RC1.
- the resistance value R0 of the readout layer group may vary between the reference cells RC0 set to data “0”, and the resistance value R1 of the readout layer group between the reference cells RC1 set to data “1” is May vary.
- an increase in variation in the resistance value of each of the reference cells RC0 and RC1 results in an increase in variation in the reference level.
- the variation in the reference level means an indefinite reference level, which increases the probability of erroneous data reading.
- FIG. 15 is a perspective view showing an example of the first magnetoresistive element 1
- FIG. 16 is a plan view showing the magnetization state of the first magnetoresistive element 1 shown in FIG.
- the displacement direction (first direction) of the second magnetization free layer 40 with respect to the first magnetization free layer 30 is the x direction
- the easy magnetization axis of the second magnetization free layer 40 is Along the y direction orthogonal to the x direction.
- the perpendicular magnetization of the first magnetization free layer 30 applies a magnetization component in the + x direction or the ⁇ x direction to the second magnetization free layer 40, and as shown in FIG.
- Magnetization rotates in the direction of the hard axis (x axis) about the easy axis (y axis).
- the magnetization direction of the second magnetization fixed layer 60 is fixed parallel or antiparallel to the first direction, and is orthogonal to the easy magnetization axis direction of the second magnetization free layer 40.
- a difference occurs in the relative angle of the magnetization direction between the second magnetization free layer 40 and the second magnetization fixed layer 60, and two memory states of data “0” and data “1” are realized.
- the second magnetization free layer 40 of the read layer group Variations in the magnetization state occur. That is, in a cell having a relatively large magnetic anisotropy of the second magnetization free layer 40, the amount of rotation of magnetization with respect to the easy axis is small. On the contrary, in a cell having a relatively small magnetic anisotropy of the second magnetization free layer 40, the amount of rotation of magnetization with respect to the easy axis of magnetization becomes large.
- Such variation in the amount of rotation of magnetization means variation in the MTJ resistance value (R0 or R1) of the read layer group. That is, the resistance value R0 varies between reference cells RC0 set to data “0”, and the resistance value R1 varies between reference cells RC1 set to data “1”.
- FIG. 18 conceptually shows the distribution of data “0” cells and data “1” cells, with the vertical axis representing frequency and the horizontal axis representing MTJ resistance.
- the resistance value R0 varies between cells with data “0”
- the resistance value R1 varies between cells with data “1”. Accordingly, when the reference level is generated by referring to the two types of reference cells RC0 and RC1 in which the complementary data is recorded, the reference level varies and becomes uncertain. Such an uncertain reference level increases the probability of erroneous data reading.
- Second Magnetoresistive Element Therefore, according to the present embodiment, a “second magnetoresistive element 100” different from the first magnetoresistive element 1 is proposed for the reference cell. As will be described in detail below, the resistance value of the second magnetoresistive element 100 is fixed to an intermediate value between R0 and R1 (hereinafter referred to as “R0.5”; see FIG. 18). Yes. That is, the second magnetoresistive element 100 is formed in advance so that its resistance value is R0.5 alone. By applying such second magnetoresistive element 100 to the reference cell, variations in the reference level can be prevented.
- FIG. 19A is a perspective view showing an example of the second magnetoresistance element 100 according to the present exemplary embodiment.
- FIG. 19B is a plan view showing the magnetization state of the second magnetoresistance element 100 shown in FIG. 19A.
- the second magnetoresistive element 100 according to this example has the same structure as that in which the write layer group (10 to 30) is omitted from the first magnetoresistive element 1 shown in FIG.
- the second magnetoresistive element 100 includes a third magnetization free layer 140, a third spacer layer 150, a third magnetization fixed layer 160, a third conductive layer 170, and a fourth conductive layer 180.
- the third magnetization free layer 140 is provided adjacent to one surface of the third spacer layer 150
- the third magnetization fixed layer 160 is provided adjacent to the other surface of the third spacer layer 150. That is, the third spacer layer 150 is sandwiched between the third magnetization free layer 140 and the third magnetization fixed layer 160.
- the third conductive layer 170 is electrically connected to the third magnetization free layer 140
- the fourth conductive layer 180 is electrically connected to the third conductive layer 170.
- the third magnetization free layer 140 and the third magnetization fixed layer 160 are ferromagnetic layers formed of a ferromagnetic material. Furthermore, the third magnetization free layer 140 and the third magnetization fixed layer 160 are in-plane magnetization films having in-plane magnetic anisotropy.
- the in-plane magnetization film is formed of a ferromagnetic material including at least one material selected from Fe, Co, and Ni.
- B, C, N, O, Al, Si, P, Ti, V, Cr, Mn, Cu, Zn, Zr, Nb, Mo, Tc, Ru, Rh, Ag, Hf, Ta, W , Re, Os, Ir, Au, etc. can be added to adjust the magnetic properties.
- the third spacer layer 150 is a nonmagnetic layer formed of a nonmagnetic material.
- the third spacer layer 150 is preferably formed of an insulator.
- Specific examples of the material include Mg—O, Al—O, Al—N, Ni—O, and Hf—O.
- the MTJ is formed by the third magnetization free layer 140, the third spacer layer 150, and the third magnetization fixed layer 160.
- the magnetization direction of the third magnetization fixed layer 160 is fixed in one direction in the plane.
- the magnetization direction of the third magnetization fixed layer 160 is fixed in the ⁇ x direction.
- the easy axis of magnetization of the third magnetization free layer 140 is orthogonal to the magnetization direction of the third magnetization fixed layer 160. That is, the easy magnetization axis of the third magnetization free layer 140 is orthogonal to the x direction and parallel to the y direction.
- the planar shape of the third magnetization free layer 140 is an ellipse, and the major axis of the ellipse is along the y direction.
- the third magnetization free layer 140, the third spacer layer 150, and the third magnetization fixed layer 160 described above constitute a “reading layer group”. That is, when reading data, a read current flows between the third magnetization free layer 140 and the third magnetization fixed layer 160 so as to penetrate the MTJ.
- the second magnetoresistive element 100 according to this example is not provided with a structure corresponding to the write layer group. That is, no perpendicular magnetization film that remotely affects the magnetization state of the third magnetization free layer 140 of the readout layer group is provided.
- the magnetization direction of the third magnetization free layer 140 is oriented along the easy axis direction (y-axis direction).
- the magnetization direction of the third magnetization free layer 140 is the + y direction.
- the magnetization direction of the third magnetization fixed layer 160 is fixed in the direction orthogonal to the easy magnetization axis of the third magnetization free layer 140. Accordingly, the resistance value of the readout layer group is an intermediate value “R0.5” between R0 and R1. That is, the second magnetoresistive element 100 is formed in advance so that the MTJ resistance value alone becomes “R0.5”.
- FIG. 20A is a perspective view showing another example of the second magnetoresistive element 100.
- FIG. 20B is an xy plan view of the structure shown in FIG. 20A.
- the second magnetoresistive element 100 according to this example has a structure corresponding to the write layer group (10 to 30) of the first magnetoresistive element 1 in addition to the structure shown in FIGS. 19A and 19B.
- the center of gravity of the first magnetoresistive element 1 is intentionally shifted, but the center of gravity of the second magnetoresistive element 100 of this example is the same.
- the same components as those illustrated in FIGS. 19A and 19B are denoted by the same reference numerals, and redundant description will be omitted as appropriate.
- the second magnetoresistive element 100 further includes a fourth magnetization fixed layer 110, a fourth spacer layer 120, and a fourth magnetization free layer 130 in addition to the readout layer group (140 to 160). ing.
- the fourth magnetization fixed layer 110 is provided adjacent to one surface of the fourth spacer layer 120
- the fourth magnetization free layer 130 is provided adjacent to the other surface of the fourth spacer layer 120. That is, the fourth spacer layer 120 is sandwiched between the fourth magnetization fixed layer 110 and the fourth magnetization free layer 130.
- the third conductive layer 170 is sandwiched between the fourth magnetization free layer 130 and the third magnetization free layer 140.
- the fourth conductive layer 180 may or may not be present.
- the fourth magnetization fixed layer 110 and the fourth magnetization free layer 130 are ferromagnetic layers formed of a ferromagnetic material.
- the fourth magnetization fixed layer 110 and the fourth magnetization free layer 130 are perpendicular magnetization films having perpendicular magnetic anisotropy, and the material thereof is the same as that of the perpendicular magnetization film of the first magnetoresistance element 1. While the magnetization direction of the fourth magnetization fixed layer 110 is substantially fixed, the magnetization direction of the fourth magnetization free layer 130 can be reversed. For example, in FIG. 20A, the magnetization direction of the fourth magnetization fixed layer 110 is fixed in the + z direction, and the magnetization direction of the fourth magnetization free layer 130 is the + z direction or the ⁇ z direction.
- the fourth spacer layer 120 is a nonmagnetic layer formed of a nonmagnetic material. The material of the fourth spacer layer 120 may be a conductor, an insulator, or a semiconductor.
- the fourth magnetization free layer 130 having perpendicular magnetic anisotropy and the third magnetization free layer 140 having in-plane magnetic anisotropy in the readout layer group are magnetically coupled to each other.
- the centroid G130 of the fourth magnetization free layer 130 and the centroid G140 of the third magnetization free layer 140 coincide with each other in the xy plane. Therefore, the perpendicular magnetization of the fourth magnetization free layer 130 does not change the direction of the in-plane magnetization of the third magnetization free layer 140.
- the magnetization direction of the third magnetization free layer 140 remains parallel to the easy axis direction. That is, the readout layer group is in the state shown in FIG. 19B, and “R0.5” is realized.
- FIG. 21A is a perspective view showing still another example of the second magnetoresistive element 100.
- FIG. 21B is an xy plan view of the structure shown in FIG. 21A.
- the second magnetoresistive element 100 according to this example has the same components as those shown in FIGS. 20A and 20B. However, the positional relationship of the center of gravity is different.
- the same components as those illustrated in FIGS. 20A and 20B are denoted by the same reference numerals, and redundant description will be omitted as appropriate.
- the gravity center G130 of the fourth magnetization free layer 130 having perpendicular magnetic anisotropy is shifted from the gravity center G140 of the third magnetization free layer 140 having in-plane magnetic anisotropy.
- the direction of deviation coincides with the easy axis direction of magnetization of the third magnetization free layer 140.
- the center of gravity G130 of the fourth magnetization free layer 130 is shifted from the center of gravity G140 of the third magnetization free layer 140 in the y direction.
- the shift direction is parallel to the easy axis direction (y-axis direction) of the third magnetization free layer 140 and is orthogonal to the magnetization direction of the third magnetization fixed layer 160.
- the perpendicular magnetization of the fourth magnetization free layer 130 applies a magnetization component in the + y direction or the ⁇ y direction to the third magnetization free layer 140. Since the magnetization component coincides with the easy axis direction, the in-plane magnetization of the third magnetization free layer 140 does not rotate. The magnetization direction of the third magnetization free layer 140 remains parallel to the easy axis direction. That is, the readout layer group is in the state shown in FIG. 19B, and “R0.5” is realized.
- FIG. 22A is a perspective view showing still another example of the second magnetoresistive element 100.
- FIG. 22B is an xy plan view of the structure shown in FIG. 22A.
- the second magnetoresistive element 100 shown in FIGS. 22A and 22B is similar to the first magnetoresistive element 1 shown in FIGS. 9A to 9C, in addition to the readout layer group (140 to 160).
- a plurality of layer groups each including the fourth magnetization fixed layer 110, the fourth spacer layer 120, and the fourth magnetization free layer 130 are provided.
- the first layer group includes the fourth magnetization fixed layer 110a, the fourth spacer layer 120a, and the fourth magnetization free layer 130a
- the second layer group includes the fourth magnetization fixed layer 110b, The fourth spacer layer 120b and the fourth magnetization free layer 130b are included.
- the centroids G130a and G130b of the fourth magnetization free layers 130a and 130b having perpendicular magnetic anisotropy are the third magnetization free having in-plane magnetic anisotropy. It is offset from the center of gravity G140 of the layer 140. In the xy plane, the direction of deviation coincides with the easy axis direction of magnetization of the third magnetization free layer 140.
- the centers of gravity G130a, G140, and G130b are aligned along the y axis in this order. That is, the centroids G130a and G130b are shifted from the centroid G140 in the ⁇ y direction and the + y direction, respectively.
- the shift direction is parallel to the easy axis direction (y-axis direction) of the third magnetization free layer 140 and is orthogonal to the magnetization direction of the third magnetization fixed layer 160.
- the perpendicular magnetization of the fourth magnetization free layers 130a and 130b applies a magnetization component in the + y direction or the ⁇ y direction to the third magnetization free layer 140. Since the magnetization component coincides with the easy axis direction, the in-plane magnetization of the third magnetization free layer 140 does not rotate. The magnetization direction of the third magnetization free layer 140 remains parallel to the easy axis direction. That is, the readout layer group is in the state shown in FIG. 19B, and “R0.5” is realized.
- the directions of the in-plane magnetization components applied to the third magnetization free layer 140 by the fourth magnetization free layers 130a and 130b coincide with each other.
- the in-plane magnetization direction of the third magnetization free layer 140 becomes more stable.
- the perpendicular magnetization directions of the fourth magnetization free layers 130a and 130b are preferably opposite to each other.
- FIG. 23 schematically shows a configuration of the MRAM according to the embodiment of the present invention.
- An MRAM memory cell array has a plurality of cells arranged in a matrix. More specifically, the cell includes a memory cell MC for data recording and a reference cell RC that is referred to for generating a reference level when data is read.
- the first magnetoresistive element 1 is applied to the memory cell MC.
- the second magnetoresistive element 100 is applied to the reference cell RC.
- each layer of the first magnetoresistive element 1 and each layer of the second magnetoresistive element 100 are preferably formed in the same layer.
- the third magnetization free layer 140, the third spacer layer 150, the third magnetization fixed layer 160, and the third conductive layer 170 have the first magnetoresistance.
- the second magnetization free layer 40, the second spacer layer 50, the second magnetization fixed layer 60, and the first conductive layer 70 of the element 1 are formed in the same layer.
- the fourth magnetization fixed layer 110, the fourth spacer layer 120, and the fourth magnetization free layer 130 also have the The first magnetoresistive element 1 is formed in the same layer as the first magnetization fixed layer 10, the first spacer layer 20, and the first magnetization free layer 30.
- the first magnetoresistive element 1 included in the memory cell MC may be any of the above-described examples (see FIGS. 1A to 13B, FIG. 15, and FIG. 16).
- the second magnetoresistive element 100 included in the reference cell RC may be any of the above-described examples (see FIGS. 19A to 22B). That is, the combination of the 1st magnetoresistive element 1 and the 2nd magnetoresistive element 100 is free. In determining the combination, ease of the manufacturing process may be considered. For example, when the first magnetoresistive element 1 shown in FIGS. 9A to 9C is used, the one shown in FIGS. 22A and 22B having a similar structure is used as the second magnetoresistive element 100. Good.
- the resistance value of the read layer group (40 to 60) of the first magnetoresistive element 1 switches between R0 and R1 according to the recording data, and the second magnetoresistive element 100
- the resistance value of the readout layer group (140 to 160) is fixed to the intermediate value “R0.5”.
- a read current is passed through the memory cell MC to be read and the reference cell RC.
- the read circuit generates a read level corresponding to the recording data (R0 or R1) of the memory cell MC based on the read current flowing through the memory cell MC.
- the read circuit generates a reference level corresponding to the intermediate resistance value R0.5 based on the read current flowing through the reference cell RC. Then, the read circuit determines the recording data (R0 or R1) of the memory cell MC by comparing the read level with the reference level.
- FIG. 24 shows an example of the magnetization states of the second magnetization free layer 40 of the memory cell MC and the third magnetization free layer 140 of the reference cell RC.
- the first magnetoresistive element 1 shown in FIGS. 15 and 16 is applied to the memory cell MC. That is, the magnetization of the second magnetization free layer 40 rotates around the easy axis.
- the magnetization rotation amount (resistance value R0) varies among memory cells MC with data “0”, and the magnetization rotation amount (resistance value R1) varies between memory cells MC with data “1” (see also FIG. 17).
- the magnetization direction of the third magnetization free layer 140 is completely along the easy axis. Therefore, even if the magnetization rotation amount varies in the memory cell MC, it is possible to accurately determine the magnetization rotation direction, that is, the recording data (R0 or R1).
- the resistance value R0 may vary between cells with data “0”, and the resistance value R1 may vary between cells with data “1”.
- the reference cell RC is surely set to “R0.5”, and there is almost no variation in resistance value at least with respect to the reference cell RC. This means that variations in the reference level are suppressed and a more accurate reference level can be obtained.
- R0.5 an accurate reference level
- the first magnetoresistive element 1 applied to the memory cell MC may be any of the above-described examples. What is important is that the dispersion of the magnetization state in the reference cell RC is suppressed.
- the second magnetoresistive element 100 having a resistance value of R0.5 alone is used. Therefore, it is not necessary to prepare two types of reference cells RC0 and RC1 (see FIG. 14) in which complementary data (R0 and R1) are recorded. Only one type of reference cell RC (see FIG. 23) having the second magnetoresistive element 100 is sufficient.
- the reference cell RC is formed in advance so that the resistance value is R0.5, and the initial setting process of the reference cell RC is not necessary. Therefore, the manufacturing time is shortened and the manufacturing cost is reduced. Further, since an initial setting controller is not necessary, the area of the MRAM is reduced.
- the read circuit needs to calculate the reference level corresponding to the intermediate resistance value between the resistance values R0 and R1 with reference to the two types of reference cells RC0 and RC1.
- the reference level is obtained directly by referring to one type of reference cell RC whose resistance value is fixed to R0.5. Therefore, the circuit configuration is simplified and the area of the MRAM is reduced.
- FIG. 14 two rows are required to arrange two types of reference cells RC0 and RC1.
- FIG. 23 one row is sufficient for arranging one type of reference cell RC. Since the area for the reference cell is not required for one column, the area of the memory cell array is reduced. Particularly in the case of a small-scale array, the area reduction effect becomes remarkable.
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Abstract
Description
1-1.構成
図1Aは、本発明の実施の形態に係る第1磁気抵抗素子1の構造を示す斜視図である。図1B及び図1Cのそれぞれは、図1Aで示された構造のx-y平面図及びx-z側面図である。尚、第1磁気抵抗素子1は複数の層からなる積層構造を有しており、その積層方向がz軸方向として規定される。積層構造の各層に平行な平面がx-y平面である。
次に、本実施の形態に係る第1磁気抵抗素子1の原理を詳細に説明する。図2A及び図2Bには、第1磁化自由層30の磁化によって周辺に発生する漏れ磁界(漏れ磁束)が模式的に示されている。図2Aはx-z面内における状態を示し、図2Bはx-y面内における状態を示している。
図3A及び図3Bは、第1磁気抵抗素子1へのデータ書き込み方法を説明するための概念図である。データ書き込みは、「スピン注入磁化反転方式」により実現される。具体的には、第1磁化固定層10、第1スペーサー層20及び第1磁化自由層30が利用され、第1磁化固定層10と第1磁化自由層30との間に書き込み電流Iwriteが流される。
垂直磁化膜である第1磁化固定層10及び第1磁化自由層30は、Fe、Co、Niのうちから選択される少なくとも一つの材料を含む強磁性体で形成される。また、PtやPdを添加することにより、垂直磁気異方性を安定化することができる。これに加えて、B、C、N、O、Al、Si、P、Ti、V、Cr、Mn、Cu、Zn、Zr、Nb、Mo、Tc、Ru、Rh、Ag、Hf、Ta、W、Re、Os、Ir、Au、Smなどを添加することにより、磁気特性を調整することができる。具体的な材料としては、Co、Co-Pt、Co-Pd、Co-Cr、Co-Pt-Cr、Co-Cr-Ta、Co-Cr-B、Co-Cr-Pt-B、Co-Cr-Ta-B、Co-V、Co-Mo、Co-W、Co-Ti、Co-Ru、Co-Rh、Fe-Pt、Fe-Pd、Fe-Co-Pt、Fe-Co-Pd、Sm-Co、Gd-Fe-Co、Tb-Fe-Co、Gd-Tb-Fe-Coなどが例示される。そのほか、Fe、Co、Niのうちから選択されるいずれか一つの材料を含む層を、異なる層と積層させることにより垂直磁気異方性を発現させることもできる。具体的には、Co/Pd、Co/Pt、Co/Ni、Fe/Auなどの積層膜が例示される。
本実施の形態によれば、スピン注入磁化反転方式のMRAMにおいて、書き込み特性及び記録データ保持特性と読み出し特性とを独立に向上させることができる。これは、本実施の形態に係る第1磁気抵抗素子1において、書き込み及び記録データの保持を担う部分と、読み出しを担う部分が異なることに起因する。特許文献1で述べられているように、諸定数が適切に設定された垂直磁化膜を用いることにより、5MA/cm2以下の書き込み閾値電流密度でスピン注入磁化反転を行うことができる。一方、非特許文献1で述べられているように、ある積層構成からなるMTJを用いることにより、500%に近いMR比を得ることができる。本実施の形態によれば、データ書き込み/保持を司る第1磁化固定層10及び第1磁化自由層30を垂直磁化膜で形成することにより、書き込み閾値電流密度を低減することが可能となる。且つ、データ読み出しを司る第2磁化自由層40及び第2磁化固定層60を面内磁化膜で形成することにより、MR比を高めて読み出し信号を増大させることが可能となる。
第1の変形例は、第1磁化自由層30と第2磁化自由層40のx-y平面内の位置関係に関する。第1磁化自由層30と第2磁化自由層40の位置関係は既出の例に限られない。x-y平面において、第2磁化自由層40の重心G40は、第1磁化自由層30の重心G30に対して“第1の方向”に位置していればよい。
第2の変形例は、第1磁気抵抗素子1を構成する各層のz軸方向(積層方向)の位置関係に関する。上述の通り、第1磁化固定層10、第1スペーサー層20及び第1磁化自由層30は、「書き込み層群」を構成しており、第2磁化自由層40、第2スペーサー層50及び第2磁化固定層60は、「読み出し層群」を構成している。また、第1導電層70及び第2導電層80は、書き込み層群及び読み出し層群に電流を導入する「プラグ群」を構成している。これら書き込み層群、読み出し層群、及びプラグ群の位置関係は、既出の例で示されたものに限られない。書き込み層群の第1磁化自由層30と読み出し層群の第2磁化自由層40が、異なる層に形成され、互いに磁気的に結合していればよい。
第3の変形例において、第1磁気抵抗素子1は、複数の書き込み層群を備える。そして、複数の書き込み層群の各々が、上述の第1磁化固定層10、第1スペーサー層20、及び第1磁化自由層30を有する。
第4の変形例では、第2導電層80が省略される。図12Aは、第1磁気抵抗素子1の一例を示す斜視図である。図12B及び図12Cのそれぞれは、図12Aで示された構造のx-y平面図及びx-z側面図である。図12A~図12Cに示されるように、第2導電層80は省略され、第1磁気抵抗素子1は2端子の素子となる。この場合でも、第1磁化自由層30と第2磁化自由層40は磁気的に結合しており、また、第2磁化自由層40の重心G40は、第1磁化自由層30の重心G30からずれている。従って、第1磁化自由層30の磁化方向に応じて、第2磁化自由層40の磁化方向は一意に定まる。
図14は、典型的なMRAMの構成を概略的に示している。MRAMのメモリセルアレイは、マトリックス状に配置された複数のセルを有している。より詳細には、セルには、データ記録用のメモリセルMCと、データ読み出し時にリファレンスレベルを生成するために参照されるリファレンスセルRC0、RC1が含まれる。メモリセルMC、リファレンスセルRC0及びRC1は、同一の構造の磁気抵抗素子を有している。
そこで、本実施の形態によれば、リファレンスセル用に、第1磁気抵抗素子1とは異なる「第2磁気抵抗素子100」が提案される。以下に詳述されるように、第2磁気抵抗素子100の抵抗値は、上記R0とR1の間の中間値(以下、「R0.5」と参照される;図18参照)に固定されている。つまり、第2磁気抵抗素子100は、その抵抗値が単独でR0.5となるようにあらかじめ形成される。そのような第2磁気抵抗素子100をリファレンスセルに適用することによって、リファレンスレベルのばらつきが防止される。
図19Aは、本実施の形態に係る第2磁気抵抗素子100の一例を示す斜視図である。図19Bは、図19Aで示された第2磁気抵抗素子100の磁化状態を示す平面図である。本例に係る第2磁気抵抗素子100は、既出の図15で示された第1磁気抵抗素子1から書き込み層群(10~30)が省略されたものと同様の構造を有している。
図20Aは、第2磁気抵抗素子100の他の例を示す斜視図である。図20Bは、図20Aで示された構造のx-y平面図である。本例に係る第2磁気抵抗素子100は、図19A及び図19Bで示された構造に加えて、第1磁気抵抗素子1の書き込み層群(10~30)に相当する構造を備えている。但し、第1磁気抵抗素子1では重心が故意にずらされていたが、本例の第2磁気抵抗素子100では重心が一致している。図19A及び図19Bで示された構成と同じ構成には同一の符号が付され、重複する説明は適宜省略される。
図21Aは、第2磁気抵抗素子100の更に他の例を示す斜視図である。図21Bは、図21Aで示された構造のx-y平面図である。本例に係る第2磁気抵抗素子100は、図20A及び図20Bで示された構成要素と同様のものを有する。但し、重心の位置関係が異なっている。図20A及び図20Bで示された構成と同じ構成には同一の符号が付され、重複する説明は適宜省略される。
図23は、本発明の実施の形態に係るMRAMの構成を概略的に示している。MRAMのメモリセルアレイは、マトリックス状に配置された複数のセルを有している。より詳細には、セルには、データ記録用のメモリセルMCと、データ読み出し時にリファレンスレベルを生成するために参照されるリファレンスセルRCが含まれる。本発明によれば、メモリセルMCには第1磁気抵抗素子1が適用される。一方、リファレンスセルRCには、第2磁気抵抗素子100が適用される。
Claims (14)
- 第1磁気抵抗素子を含むメモリセルと、
第2磁気抵抗素子を含み、前記メモリセルからのデータ読み出し時にリファレンスレベルを生成するために参照されるリファレンスセルと
を具備し、
前記第1磁気抵抗素子は、
磁化方向が固定された第1磁化固定層と、
磁化方向が可変な第1磁化自由層と、
前記第1磁化固定層と前記第1磁化自由層とに挟まれた第1非磁性層と、
磁化方向が固定された第2磁化固定層と、
磁化方向が可変な第2磁化自由層と、
前記第2磁化固定層と前記第2磁化自由層とに挟まれた第2非磁性層と
を備え、
前記第1磁化固定層と前記第1磁化自由層は、垂直磁気異方性を有し、
前記第2磁化固定層と前記第2磁化自由層は、面内磁気異方性を有し、
前記第1磁化自由層と前記第2磁化自由層は、互いに磁気的に結合しており、
各層に平行な第1平面において、前記第2磁化自由層の重心は、前記第1磁化自由層の重心から第1方向にずれており、
前記第2磁気抵抗素子は、
磁化容易軸が第2方向に平行な第3磁化自由層と、
磁化方向が前記第2方向と直交する第3方向に固定された第3磁化固定層と、
前記第3磁化固定層と前記第3磁化自由層とに挟まれた第3非磁性層と
を備え、
前記第3磁化固定層と前記第3磁化自由層は、面内磁気異方性を有する
磁気ランダムアクセスメモリ。 - 請求の範囲1に記載の磁気ランダムアクセスメモリであって、
前記第2磁化自由層の磁化容易軸は前記第1方向と直交しており、
前記第2磁化固定層の磁化方向は前記第1方向と平行あるいは反平行である
磁気ランダムアクセスメモリ。 - 請求の範囲1又は2に記載の磁気ランダムアクセスメモリであって、
前記第3磁化自由層の平面形状の長軸方向は前記第2方向である
磁気ランダムアクセスメモリ。 - 請求の範囲1乃至3のいずれか一項に記載の磁気ランダムアクセスメモリであって、
前記第2磁化固定層と前記第3磁化固定層は同じ層に形成され、
前記第2磁化自由層と前記第3磁化自由層は同じ層に形成され、
前記第2非磁性層と前記第3非磁性層は同じ層に形成された
磁気ランダムアクセスメモリ。 - 請求の範囲1乃至4のいずれか一項に記載の磁気ランダムアクセスメモリであって、
前記第2磁気抵抗素子は、
磁化方向が固定された第4磁化固定層と、
磁化方向が可変な第4磁化自由層と、
前記第4磁化固定層と前記第4磁化自由層とに挟まれた第4非磁性層と
を更に備え、
前記第4磁化固定層と前記第4磁化自由層は、垂直磁気異方性を有し、
前記第3磁化自由層と前記第4磁化自由層は、互いに磁気的に結合しており、
前記第3磁化自由層の磁化方向は前記第2方向と平行である
磁気ランダムアクセスメモリ。 - 請求の範囲5に記載の磁気ランダムアクセスメモリであって、
前記第1平面において、前記第3磁化自由層の重心は、前記第4磁化自由層の重心と一致している
磁気ランダムアクセスメモリ。 - 請求の範囲5に記載の磁気ランダムアクセスメモリであって、
前記第1平面において、前記第3磁化自由層の重心は、前記第4磁化自由層の重心から前記第2方向にずれている
磁気ランダムアクセスメモリ。 - 請求の範囲5乃至7のいずれか一項に記載の磁気ランダムアクセスメモリであって、
前記第2磁化固定層と前記第3磁化固定層は同じ層に形成され、
前記第2磁化自由層と前記第3磁化自由層は同じ層に形成され、
前記第2非磁性層と前記第3非磁性層は同じ層に形成され、
前記第1磁化固定層と前記第4磁化固定層は同じ層に形成され、
前記第1磁化自由層と前記第4磁化自由層は同じ層に形成され、
前記第1非磁性層と前記第4非磁性層は同じ層に形成された
磁気ランダムアクセスメモリ。 - 請求の範囲1乃至8のいずれか一項に記載の磁気ランダムアクセスメモリであって、
前記メモリセルへのデータ書き込み時、前記第1磁化自由層と前記第1磁化固定層との間に書き込み電流が流れ、
前記メモリセルからのデータ読み出し時、前記第2磁化自由層と前記第2磁化固定層との間に読み出し電流が流れる
磁気ランダムアクセスメモリ。 - 請求の範囲9に記載の磁気ランダムアクセスメモリであって、
前記書き込み電流は更に、前記第2磁化自由層と前記第2磁化固定層との間にも流れる
磁気ランダムアクセスメモリ。 - 請求の範囲1乃至9のいずれか一項に記載の磁気ランダムアクセスメモリであって、
前記第1磁気抵抗素子は、複数の書き込み層群を備え、
前記複数の書き込み層群の各々が、前記第1磁化固定層、前記第1磁化自由層、及び前記第1非磁性層を有する
磁気ランダムアクセスメモリ。 - 請求の範囲11に記載の磁気ランダムアクセスメモリであって、
前記複数の書き込み層群は、第1書き込み層群と第2書き込み層群を含み、
前記第1平面において、前記第2磁化自由層の重心は、前記第1書き込み層群の前記第1磁化自由層の重心と前記第2書き込み層群の前記第1磁化自由層の重心との間に位置する
磁気ランダムアクセスメモリ。 - 請求の範囲12に記載の磁気ランダムアクセスメモリであって、
前記第1書き込み層群の前記第1磁化自由層の磁化方向は、前記第2書き込み層群の前記第1磁化自由層の磁化方向と反平行であり、
前記第1書き込み層群の前記第1磁化固定層の磁化方向は、前記第2書き込み層群の前記第1磁化固定層の磁化方向と平行である
磁気ランダムアクセスメモリ。 - 請求の範囲13に記載の磁気ランダムアクセスメモリであって、
データ書き込み時、前記第1書き込み層群と前記第2書き込み層群の各々において、前記第1磁化自由層と前記第1磁化固定層との間に書き込み電流が流され、
前記第1書き込み層群を流れる前記書き込み電流の方向は、前記第2書き込み層群を流れる前記書き込み電流の方向の逆である
磁気ランダムアクセスメモリ。
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011091342A (ja) * | 2009-10-26 | 2011-05-06 | Nec Corp | 磁気抵抗素子、及び磁壁ランダムアクセスメモリ |
JP2013030685A (ja) * | 2011-07-29 | 2013-02-07 | Toshiba Corp | 磁気抵抗素子及び磁気メモリ |
US10068946B2 (en) | 2015-09-16 | 2018-09-04 | Kabushiki Kaisha Toshiba | Magnetic memory |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010004881A1 (ja) * | 2008-07-10 | 2010-01-14 | 日本電気株式会社 | 磁気ランダムアクセスメモリ、並びに磁気ランダムアクセスメモリの初期化方法及び書き込み方法 |
US8994130B2 (en) * | 2009-01-30 | 2015-03-31 | Nec Corporation | Magnetic memory element and magnetic memory |
JP5492144B2 (ja) * | 2011-05-27 | 2014-05-14 | 株式会社日立製作所 | 垂直磁化磁気抵抗効果素子及び磁気メモリ |
JP5982795B2 (ja) * | 2011-11-30 | 2016-08-31 | ソニー株式会社 | 記憶素子、記憶装置 |
JP5987302B2 (ja) * | 2011-11-30 | 2016-09-07 | ソニー株式会社 | 記憶素子、記憶装置 |
KR102638584B1 (ko) | 2016-09-06 | 2024-02-22 | 삼성전자주식회사 | 반도체 메모리 장치 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005116888A (ja) * | 2003-10-09 | 2005-04-28 | Toshiba Corp | 磁気メモリ |
JP2006073930A (ja) * | 2004-09-06 | 2006-03-16 | Canon Inc | 磁壁移動を利用した磁気抵抗効果素子の磁化状態の変化方法及び該方法を用いた磁気メモリ素子、固体磁気メモリ |
JP2007103663A (ja) * | 2005-10-04 | 2007-04-19 | Toshiba Corp | 磁気素子、記録再生素子、論理演算素子および論理演算器 |
JP2007258460A (ja) * | 2006-03-23 | 2007-10-04 | Nec Corp | 磁気メモリセル、磁気ランダムアクセスメモリ、半導体装置及び半導体装置の製造方法 |
JP2008147488A (ja) * | 2006-12-12 | 2008-06-26 | Nec Corp | 磁気抵抗効果素子及びmram |
JP2009054715A (ja) * | 2007-08-24 | 2009-03-12 | Nec Corp | 磁壁ランダムアクセスメモリ |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4143020B2 (ja) | 2003-11-13 | 2008-09-03 | 株式会社東芝 | 磁気抵抗効果素子および磁気メモリ |
JP4413603B2 (ja) | 2003-12-24 | 2010-02-10 | 株式会社東芝 | 磁気記憶装置及び磁気情報の書込み方法 |
JP4932275B2 (ja) | 2005-02-23 | 2012-05-16 | 株式会社日立製作所 | 磁気抵抗効果素子 |
JP2007073930A (ja) * | 2005-08-11 | 2007-03-22 | Furukawa Electric Co Ltd:The | ウエハ加工用テープ |
JP4444241B2 (ja) | 2005-10-19 | 2010-03-31 | 株式会社東芝 | 磁気抵抗効果素子、磁気ランダムアクセスメモリ、電子カード及び電子装置 |
JP5201539B2 (ja) * | 2007-03-29 | 2013-06-05 | 日本電気株式会社 | 磁気ランダムアクセスメモリ |
JP5093234B2 (ja) * | 2007-05-29 | 2012-12-12 | 日本電気株式会社 | 磁気ランダムアクセスメモリ |
-
2009
- 2009-01-09 US US12/865,197 patent/US8159872B2/en active Active
- 2009-01-09 JP JP2009554238A patent/JP5299642B2/ja active Active
- 2009-01-09 WO PCT/JP2009/050185 patent/WO2009104427A1/ja active Application Filing
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005116888A (ja) * | 2003-10-09 | 2005-04-28 | Toshiba Corp | 磁気メモリ |
JP2006073930A (ja) * | 2004-09-06 | 2006-03-16 | Canon Inc | 磁壁移動を利用した磁気抵抗効果素子の磁化状態の変化方法及び該方法を用いた磁気メモリ素子、固体磁気メモリ |
JP2007103663A (ja) * | 2005-10-04 | 2007-04-19 | Toshiba Corp | 磁気素子、記録再生素子、論理演算素子および論理演算器 |
JP2007258460A (ja) * | 2006-03-23 | 2007-10-04 | Nec Corp | 磁気メモリセル、磁気ランダムアクセスメモリ、半導体装置及び半導体装置の製造方法 |
JP2008147488A (ja) * | 2006-12-12 | 2008-06-26 | Nec Corp | 磁気抵抗効果素子及びmram |
JP2009054715A (ja) * | 2007-08-24 | 2009-03-12 | Nec Corp | 磁壁ランダムアクセスメモリ |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011091342A (ja) * | 2009-10-26 | 2011-05-06 | Nec Corp | 磁気抵抗素子、及び磁壁ランダムアクセスメモリ |
JP2013030685A (ja) * | 2011-07-29 | 2013-02-07 | Toshiba Corp | 磁気抵抗素子及び磁気メモリ |
US10068946B2 (en) | 2015-09-16 | 2018-09-04 | Kabushiki Kaisha Toshiba | Magnetic memory |
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