WO2009044912A1 - Agent d'enrobage hydrophile, film d'enrobage hydrophile et base hydrophile - Google Patents

Agent d'enrobage hydrophile, film d'enrobage hydrophile et base hydrophile Download PDF

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Publication number
WO2009044912A1
WO2009044912A1 PCT/JP2008/068164 JP2008068164W WO2009044912A1 WO 2009044912 A1 WO2009044912 A1 WO 2009044912A1 JP 2008068164 W JP2008068164 W JP 2008068164W WO 2009044912 A1 WO2009044912 A1 WO 2009044912A1
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WO
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Prior art keywords
hydrophilic coating
component
hydrophilic
coating agent
agent
Prior art date
Application number
PCT/JP2008/068164
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English (en)
Japanese (ja)
Inventor
Ryoichi Nakai
Original Assignee
Harima Chemicals, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Harima Chemicals, Inc. filed Critical Harima Chemicals, Inc.
Priority to JP2009536133A priority Critical patent/JP5589386B2/ja
Priority to KR1020107000871A priority patent/KR101136759B1/ko
Priority to CN200880109530A priority patent/CN101809101A/zh
Publication of WO2009044912A1 publication Critical patent/WO2009044912A1/fr

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08Homopolymers or copolymers of acrylic acid esters
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062Copolymers with monomers not covered by C09D133/06
    • C09D133/066Copolymers with monomers not covered by C09D133/06 containing -OH groups
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/38Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3893Low-molecular-weight compounds having heteroatoms other than oxygen containing silicon
    • C08G18/3895Inorganic compounds, e.g. aqueous alkalimetalsilicate solutions; Organic derivatives thereof containing no direct silicon-carbon bonds
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/62Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225Polymers of esters of acrylic or methacrylic acid
    • C08G18/6229Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
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    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/62Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/625Polymers of alpha-beta ethylenically unsaturated carboxylic acids; hydrolyzed polymers of esters of these acids
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    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/71Monoisocyanates or monoisothiocyanates
    • C08G18/718Monoisocyanates or monoisothiocyanates containing silicon
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/7806Nitrogen containing -N-C=0 groups
    • C08G18/7818Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
    • C08G18/7831Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups containing biuret groups
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    • C09D161/00Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/26Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
    • C09D161/28Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
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    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
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    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/67Particle size smaller than 100 nm
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/66Additives characterised by particle size
    • C09D7/68Particle size between 100-1000 nm
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2290/00Compositions for creating anti-fogging
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
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    • C08L2312/00Crosslinking
    • C08L2312/08Crosslinking by silane

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  • Chemical & Material Sciences (AREA)
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  • Wood Science & Technology (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Paints Or Removers (AREA)

Abstract

La présente invention concerne un film d'enrobage hydrophile alliant des propriétés antibuée du fait de son hydrophilicité élevée, à une grande dureté et à une bonne résistance à l'eau et aux alcalis. L'invention concerne, plus précisément, un agent d'enrobage hydrophile caractérisé en ce qu'il contient un sol de silice colloïdale (A), un polymère acrylique (B) comportant un hydrogène actif et d'une masse moléculaire moyenne en masse de 5 000 à 200 000, un agent de pontage silane réactif (C) et un agent de durcissage (D) pour le polymère acrylique (B). Cet agent d'enrobage hydrophile est également caractérisé en ce que le rapport pondéral entre le composant (A) et le composant (B), à savoir (A)/(B), se situe dans une fourchette de 5/95 à 95/5 et en ce que le rapport pondéral entre le composant (A) plus le composant (B) d'une part et le composant (C) d'autre part, à savoir (A + B)/(C) se situe dans une fourchette de 30/70 à 95/5.
PCT/JP2008/068164 2007-10-05 2008-10-06 Agent d'enrobage hydrophile, film d'enrobage hydrophile et base hydrophile WO2009044912A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2009536133A JP5589386B2 (ja) 2007-10-05 2008-10-06 親水性被覆剤、親水性被膜、及び親水性基材
KR1020107000871A KR101136759B1 (ko) 2007-10-05 2008-10-06 친수성 피복제, 친수성 피막 및 친수성 기재
CN200880109530A CN101809101A (zh) 2007-10-05 2008-10-06 亲水性被覆剂、亲水性被膜以及亲水性基材

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007262588 2007-10-05
JP2007-262588 2007-10-05

Publications (1)

Publication Number Publication Date
WO2009044912A1 true WO2009044912A1 (fr) 2009-04-09

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Application Number Title Priority Date Filing Date
PCT/JP2008/068164 WO2009044912A1 (fr) 2007-10-05 2008-10-06 Agent d'enrobage hydrophile, film d'enrobage hydrophile et base hydrophile

Country Status (4)

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JP (1) JP5589386B2 (fr)
KR (1) KR101136759B1 (fr)
CN (1) CN101809101A (fr)
WO (1) WO2009044912A1 (fr)

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WO2009144999A1 (fr) * 2008-05-26 2009-12-03 ハリマ化成株式会社 Agent de revêtement hydrophile, film de revêtement hydrophile et base hydrophile
WO2010143413A1 (fr) * 2009-06-08 2010-12-16 三菱レイヨン株式会社 Matériau de revêtement à base d'eau et articles revêtus
JP2012251094A (ja) * 2011-06-06 2012-12-20 Nippon Paint Co Ltd 補修用水性下塗り塗料組成物および補修方法
JP2013194091A (ja) * 2012-03-16 2013-09-30 Nippon Synthetic Chem Ind Co Ltd:The 活性エネルギー線硬化性樹脂組成物およびその製造方法、ならびにコーティング剤、積層体
KR20130113379A (ko) 2012-04-05 2013-10-15 신에쓰 가가꾸 고교 가부시끼가이샤 방오성 부여 하드 코팅 조성물
JP2014503636A (ja) * 2010-12-17 2014-02-13 アクゾ ノーベル コーティングス インターナショナル ビー ヴィ 有機−無機ハイブリッド塗料組成物
WO2014024686A1 (fr) * 2012-08-10 2014-02-13 ハリマ化成株式会社 Agent de revêtement durcissable de type en deux parties
WO2014034828A1 (fr) * 2012-09-03 2014-03-06 三井化学株式会社 Composition permettant la prévention de la rouille et dispersion aqueuse qui contient cette dernière
JP2014055224A (ja) * 2012-09-12 2014-03-27 Kikusui Chemical Industries Co Ltd ガラス飛散防止用塗料、及び飛散防止ガラス材
JP5497971B1 (ja) * 2013-03-21 2014-05-21 日本パーカライジング株式会社 排水性に優れたアルミニウム含有金属製熱交換器の親水性表面処理剤
JP2016172853A (ja) * 2010-06-24 2016-09-29 スリーエム イノベイティブ プロパティズ カンパニー 有機乳化剤を含まない重合性組成物、並びにそのポリマー及び製造方法
US9752046B2 (en) 2013-03-21 2017-09-05 Nihon Parkerizing Co., Ltd. Aqueous hydrophilic coating composition capable of forming coating film having excellent self-cleaning ability against stains adhered thereon, and surface-treated material having formed thereon coating film having excellent self-cleaning ability against stains adhered thereon
JPWO2017159564A1 (ja) * 2016-03-14 2018-08-09 旭化成株式会社 高耐久防曇塗膜およびコーティング組成物
WO2018185590A1 (fr) * 2017-04-05 2018-10-11 3M Innovative Properties Company Stratifié hydrophile de revêtement dur et son procédé de fabrication
WO2019053907A1 (fr) * 2017-09-13 2019-03-21 Nissan Chemical Corporation Fluide chimique de récupération de pétrole brut
CN109651578A (zh) * 2018-12-12 2019-04-19 中昊北方涂料工业研究设计院有限公司 一种耐烧蚀阻燃有机-无机树脂及其制备
US10377942B2 (en) 2017-04-06 2019-08-13 Nissan Chemical America Corporation Hydrocarbon formation treatment micellar solutions
US10377777B2 (en) 2015-10-09 2019-08-13 Ceko Co., Ltd. Anti-fogging agent
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WO2020031885A1 (fr) * 2018-08-10 2020-02-13 トーヨーポリマー株式会社 Composition de revêtement antibuée thermodurcissable à base d'eau en une partie et film de revêtement antibuée
JP2020164842A (ja) * 2019-03-29 2020-10-08 日油株式会社 防曇剤組成物、該組成物から形成される防曇膜を有する防曇性物品
WO2020201883A1 (fr) 2019-04-01 2020-10-08 3M Innovative Properties Company Stratifié et agent de revêtement hydrophiles transparents, absorbant les ultraviolets
US10801310B2 (en) 2017-09-26 2020-10-13 Nissan Chemcial America Corporation Using gases and hydrocarbon recovery fluids containing nanoparticles to enhance hydrocarbon recovery
JPWO2019163918A1 (ja) * 2018-02-23 2020-12-17 旭化成株式会社 高耐久防曇塗膜およびコーティング組成物
US10870794B2 (en) 2017-11-03 2020-12-22 Nissan Chemical America Corporation Using brine resistant silicon dioxide nanoparticle dispersions to improve oil recovery
JP2021031620A (ja) * 2019-08-27 2021-03-01 旭化成株式会社 高耐久防曇塗膜およびコーティング組成物
JP2021031619A (ja) * 2019-08-27 2021-03-01 旭化成株式会社 コーティング組成物及び防曇塗膜
US10934478B2 (en) 2018-11-02 2021-03-02 Nissan Chemical America Corporation Enhanced oil recovery using treatment fluids comprising colloidal silica with a proppant
WO2021182331A1 (fr) 2020-03-10 2021-09-16 日油株式会社 Composition anti-buée, et article anti-buée possédant un film anti-buée formé à partir de cette composition
WO2022107879A1 (fr) * 2020-11-20 2022-05-27 昭和電工マテリアルズ株式会社 Agent antibuée, agent d'hydrophilisation et procédé antibuée pour structure de lampe de véhicule
WO2022107878A1 (fr) * 2020-11-20 2022-05-27 昭和電工マテリアルズ株式会社 Procédé antibuée pour structure de lampe de véhicule, agent antibuée, agent rendant hydrophile, film antibuée et structure de lampe de véhicule
CN114829510A (zh) * 2019-12-12 2022-07-29 Posco公司 耐热性和胶带粘附性优异的电镀锌钢板用涂覆组合物、利用其进行表面处理的钢板及制造该钢板的方法
CN116004071A (zh) * 2023-02-14 2023-04-25 深圳市深赛尔股份有限公司 一种水性防雾自清洁汽车玻璃涂料及其制备方法
CN116656193A (zh) * 2023-05-11 2023-08-29 东南大学 一种超亲水涂料及形成耐磨、耐煮超亲水涂层的方法
CN116004071B (zh) * 2023-02-14 2024-05-28 深圳市深赛尔股份有限公司 一种水性防雾自清洁汽车玻璃涂料及其制备方法

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