WO2009028576A1 - ポリマー液晶、光学異方性膜、および光学素子 - Google Patents

ポリマー液晶、光学異方性膜、および光学素子 Download PDF

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Publication number
WO2009028576A1
WO2009028576A1 PCT/JP2008/065341 JP2008065341W WO2009028576A1 WO 2009028576 A1 WO2009028576 A1 WO 2009028576A1 JP 2008065341 W JP2008065341 W JP 2008065341W WO 2009028576 A1 WO2009028576 A1 WO 2009028576A1
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polymer liquid
liquid crystal
integer
optically anisotropic
anisotropic film
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English (en)
French (fr)
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Yuji Yamamoto
Yuriko Kaida
Takashi Nakano
Yoshitomi Morizawa
Teppei Konishi
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AGC Inc
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Asahi Glass Co Ltd
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Anticipated expiration legal-status Critical
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/12—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings at least two benzene rings directly linked, e.g. biphenyls
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
    • C09K19/3001—Cyclohexane rings
    • C09K19/3003—Compounds containing at least two rings in which the different rings are directly linked (covalent bond)
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
    • C09K2019/0448—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/30—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing saturated or unsaturated non-aromatic rings, e.g. cyclohexane rings
    • C09K19/3001—Cyclohexane rings
    • C09K19/3003—Compounds containing at least two rings in which the different rings are directly linked (covalent bond)
    • C09K2019/3018—Ph-Cy-Ph
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3016—Polarising elements involving passive liquid crystal elements

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Liquid Crystal Substances (AREA)
  • Polarising Elements (AREA)
  • Optical Head (AREA)

Abstract

　透明性が高く、青色レーザー光に対する耐光性に優れた光学異方性膜を形成しうるポリマー液晶を提供する。 　下式（１）で表されるモノマーに由来するモノマー単位を２種類以上含有するコポリマーであって、重合後の精製により不純物を除去して得られた、ポリマー液晶。Ｒ１：水素原子またはメチル基。Ｒ２：アルキル基、アルコキシ基、またはフッ素原子。Ｅ１、Ｅ２、Ｅ３、Ｅ４：各々、独立に、１，４－フェニレン基またはトランス－１，４－シクロヘキシレン基。ｍ：０～６の整数。ｒ：０～６の整数。ｎ：０～６の整数。但し、ｒ＝０のとき、ｍ＋ｎは１０以下の整数。ｔ：０（ｍ＋ｒ＋ｎ＝０のとき）または１（ｍ＋ｒ＋ｎ＞０のとき）。ｈ：０または１。ｋ：０または１。 　CH2=CR1-COO-(CH2)m-(CF2)r-(CH2)n-(O)t-E1-(E2)h-(E3)k-E4-R2　(1)
PCT/JP2008/065341 2007-08-31 2008-08-27 ポリマー液晶、光学異方性膜、および光学素子 Ceased WO2009028576A1 (ja)

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JP2007-226312 2007-08-31
JP2007226312 2007-08-31

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012211283A (ja) * 2011-03-31 2012-11-01 Dic Corp 重合性液晶組成物
WO2013021826A1 (ja) * 2011-08-08 2013-02-14 Dic株式会社 重合性液晶組成物、及び光学異方体の製造方法
WO2015133332A1 (ja) * 2014-03-04 2015-09-11 Dic株式会社 メソゲン基を有する化合物を含有する重合性組成物及びその重合体
WO2015133331A1 (ja) * 2014-03-04 2015-09-11 Dic株式会社 メソゲン基を有する化合物を含有する混合物
WO2016047648A1 (ja) * 2014-09-25 2016-03-31 富士フイルム株式会社 重合性化合物を含む重合性組成物、フィルム、および投映像表示用ハーフミラー
JP2016113555A (ja) * 2014-12-16 2016-06-23 日本ゼオン株式会社 液晶性組成物、円偏光分離素子及びその製造方法、偽造防止用媒体及びその製造方法、輝度向上フィルム並びにセキュリティ媒体
JP2016186075A (ja) * 2010-09-14 2016-10-27 住友化学株式会社 重合性液晶組成物及び光学フィルム
WO2019039165A1 (ja) * 2017-08-23 2019-02-28 日本ゼオン株式会社 重合性液晶材料、重合性液晶組成物、高分子、光学フィルム、光学異方体、偏光板、反射防止フィルム、表示装置、並びに、重合性液晶組成物の製造方法
JP2019056069A (ja) * 2017-09-21 2019-04-11 日本ゼオン株式会社 重合性液晶材料、重合性液晶組成物、高分子、光学フィルム、光学異方体、偏光板、反射防止フィルム、表示装置、並びに、重合性液晶組成物の製造方法
CN114890857A (zh) * 2022-06-21 2022-08-12 中节能万润股份有限公司 一种通过分子筛由环醇一步制备环烷烃的方法

Citations (4)

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JP2005170934A (ja) * 2003-11-21 2005-06-30 Chisso Corp フッ化アルキレンを有する重合性を有する液晶性化合物およびその重合体
WO2006001096A1 (ja) * 2004-06-23 2006-01-05 Asahi Glass Company, Limited 重合性液晶化合物、液晶組成物、光学異方性材料、および光学素子
WO2007046294A1 (ja) * 2005-10-17 2007-04-26 Asahi Glass Company, Limited 重合性液晶化合物、液晶組成物、光学異方性材料、および光学素子
WO2008026482A1 (en) * 2006-08-29 2008-03-06 Asahi Glass Company, Limited Unsaturated fatty acid esters, and polymerizable liquid crystal compositions, optically anisotropic materials and optical elements, made by using the esters

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JPH10324665A (ja) * 1997-05-23 1998-12-08 Nippon Oil Co Ltd エステル化合物の製造方法
JP4200195B2 (ja) * 1998-10-09 2008-12-24 Ｄｉｃ株式会社 液晶性（メタ）アクリレート化合物、該化合物を含有する液晶組成物及びこれを用いた光学異方体
JP2002069040A (ja) * 2000-08-31 2002-03-08 Chisso Corp 光学活性フッ素置換ビフェニル誘導体
JP2005015372A (ja) * 2003-06-25 2005-01-20 Dainippon Ink & Chem Inc 液晶化合物の精製方法及び液晶組成物

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005170934A (ja) * 2003-11-21 2005-06-30 Chisso Corp フッ化アルキレンを有する重合性を有する液晶性化合物およびその重合体
WO2006001096A1 (ja) * 2004-06-23 2006-01-05 Asahi Glass Company, Limited 重合性液晶化合物、液晶組成物、光学異方性材料、および光学素子
WO2007046294A1 (ja) * 2005-10-17 2007-04-26 Asahi Glass Company, Limited 重合性液晶化合物、液晶組成物、光学異方性材料、および光学素子
WO2008026482A1 (en) * 2006-08-29 2008-03-06 Asahi Glass Company, Limited Unsaturated fatty acid esters, and polymerizable liquid crystal compositions, optically anisotropic materials and optical elements, made by using the esters

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016186075A (ja) * 2010-09-14 2016-10-27 住友化学株式会社 重合性液晶組成物及び光学フィルム
JP2012211283A (ja) * 2011-03-31 2012-11-01 Dic Corp 重合性液晶組成物
WO2013021826A1 (ja) * 2011-08-08 2013-02-14 Dic株式会社 重合性液晶組成物、及び光学異方体の製造方法
JPWO2013021826A1 (ja) * 2011-08-08 2015-03-05 Dic株式会社 重合性液晶組成物、及び光学異方体の製造方法
GB2539346A (en) * 2014-03-04 2016-12-14 Dainippon Ink & Chemicals Polymerizable composition comprising compound having mesogenic group, and polymer thereof
CN106029835B (zh) * 2014-03-04 2022-02-25 Dic株式会社 含有具有介晶基的化合物的混合物
CN106030394A (zh) * 2014-03-04 2016-10-12 Dic株式会社 含有具有介晶基的化合物的聚合性组合物及其聚合物
CN106029835A (zh) * 2014-03-04 2016-10-12 Dic株式会社 含有具有介晶基的化合物的混合物
WO2015133331A1 (ja) * 2014-03-04 2015-09-11 Dic株式会社 メソゲン基を有する化合物を含有する混合物
GB2538689A (en) * 2014-03-04 2016-11-23 Dainippon Ink & Chemicals Mixture that includes compound containing mesogenic group
WO2015133332A1 (ja) * 2014-03-04 2015-09-11 Dic株式会社 メソゲン基を有する化合物を含有する重合性組成物及びその重合体
JPWO2015133331A1 (ja) * 2014-03-04 2017-04-06 Dic株式会社 メソゲン基を有する化合物を含有する混合物
JPWO2015133332A1 (ja) * 2014-03-04 2017-04-06 Dic株式会社 メソゲン基を有する化合物を含有する重合性組成物及びその重合体
WO2016047648A1 (ja) * 2014-09-25 2016-03-31 富士フイルム株式会社 重合性化合物を含む重合性組成物、フィルム、および投映像表示用ハーフミラー
JPWO2016047648A1 (ja) * 2014-09-25 2017-06-22 富士フイルム株式会社 重合性化合物を含む重合性組成物、フィルム、および投映像表示用ハーフミラー
JP2016113555A (ja) * 2014-12-16 2016-06-23 日本ゼオン株式会社 液晶性組成物、円偏光分離素子及びその製造方法、偽造防止用媒体及びその製造方法、輝度向上フィルム並びにセキュリティ媒体
JPWO2019039165A1 (ja) * 2017-08-23 2020-08-20 日本ゼオン株式会社 重合性液晶材料、重合性液晶組成物、高分子、光学フィルム、光学異方体、偏光板、反射防止フィルム、表示装置、並びに、重合性液晶組成物の製造方法
EP3674757A4 (en) * 2017-08-23 2021-05-26 Zeon Corporation POLYMERIZABLE LIQUID CRYSTAL MATERIAL, POLYMERIZABLE LIQUID CRYSTAL COMPOSITION, POLYMER, OPTICAL FILM, OPTICAL ANISOTROPIC BODY, POLARIZER, ANTI-REFLECTIVE FILM, DISPLAY DEVICE, POLISHING DEVICE, AND PROCESSING FACILITIES
WO2019039165A1 (ja) * 2017-08-23 2019-02-28 日本ゼオン株式会社 重合性液晶材料、重合性液晶組成物、高分子、光学フィルム、光学異方体、偏光板、反射防止フィルム、表示装置、並びに、重合性液晶組成物の製造方法
TWI771471B (zh) * 2017-08-23 2022-07-21 日商日本瑞翁股份有限公司 聚合性液晶材料、聚合性液晶組成物、高分子、光學薄膜、光學各向異性體、偏光板、抗反射薄膜、顯示裝置以及聚合性液晶組成物的製造方法
US11492552B2 (en) 2017-08-23 2022-11-08 Zeon Corporation Polymerizable liquid crystal material, polymerizable liquid crystal composition, polymer, optical film, optically anisotropic body, polarizing plate, anti-reflection film, display device, and method of producing polymerizable liquid crystal composition
JP7255484B2 (ja) 2017-08-23 2023-04-11 日本ゼオン株式会社 重合性液晶材料、重合性液晶組成物、高分子、光学フィルム、光学異方体、偏光板、反射防止フィルム、表示装置、並びに、重合性液晶組成物の製造方法
JP2019056069A (ja) * 2017-09-21 2019-04-11 日本ゼオン株式会社 重合性液晶材料、重合性液晶組成物、高分子、光学フィルム、光学異方体、偏光板、反射防止フィルム、表示装置、並びに、重合性液晶組成物の製造方法
CN114890857A (zh) * 2022-06-21 2022-08-12 中节能万润股份有限公司 一种通过分子筛由环醇一步制备环烷烃的方法

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