WO2009008246A1 - 車両用塗膜面接着用粘着シート - Google Patents

車両用塗膜面接着用粘着シート Download PDF

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Publication number
WO2009008246A1
WO2009008246A1 PCT/JP2008/060883 JP2008060883W WO2009008246A1 WO 2009008246 A1 WO2009008246 A1 WO 2009008246A1 JP 2008060883 W JP2008060883 W JP 2008060883W WO 2009008246 A1 WO2009008246 A1 WO 2009008246A1
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WO
WIPO (PCT)
Prior art keywords
sensitive adhesive
pressure
meth
coating film
weight
Prior art date
Application number
PCT/JP2008/060883
Other languages
English (en)
French (fr)
Inventor
Masanori Uesugi
Mitsuyoshi Shirai
Takashi Kondou
Masayuki Okamoto
Masahito Niwa
Original Assignee
Nitto Denko Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nitto Denko Corporation filed Critical Nitto Denko Corporation
Priority to EP08765593.2A priority Critical patent/EP2166052A4/en
Priority to US12/452,387 priority patent/US20100136321A1/en
Priority to CN2008800236695A priority patent/CN101688089B/zh
Publication of WO2009008246A1 publication Critical patent/WO2009008246A1/ja

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/04—External Ornamental or guard strips; Ornamental inscriptive devices thereon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/10—Homopolymers or copolymers of methacrylic acid esters
    • C09J133/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385—Acrylic polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/52—Amides or imides
    • C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F220/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine
    • C08F220/585—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-(meth)acryloylmorpholine and containing other heteroatoms, e.g. 2-acrylamido-2-methylpropane sulfonic acid [AMPS]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
    • C09J2203/306—Applications of adhesives in processes or use of adhesives in the form of films or foils for protecting painted surfaces, e.g. of cars
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/41—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the carrier layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/412—Additional features of adhesives in the form of films or foils characterized by the presence of essential components presence of microspheres
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/249921—Web or sheet containing structurally defined element or component
    • Y10T428/249953—Composite having voids in a component [e.g., porous, cellular, etc.]
    • Y10T428/249982—With component specified as adhesive or bonding agent
    • Y10T428/249983—As outermost component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles

Abstract

　本発明の粘着シートは、表面調整剤が表面に存在する車両用塗膜面に使用する粘着シートであり、車両用塗膜面に接触する粘着剤層が、炭素数２～１４個のアルキル基を有するアルキル（メタ）アクリレート（ａ１）を主成分とするビニル系モノマーまたはその部分重合物（ａ）、活性エネルギー線重合開始剤（ｂ）、多官能（メタ）アクリレート（ｃ）、および、ロジン変性（メタ）アクリレート（ｄ１）を全モノマー成分１００重量部に対して１～５０重量部含有する重量平均分子量１０００～３００００である（メタ）アクリル酸エステルオリゴマー（ｄ）を含有するアクリル系粘着剤組成物を活性エネルギー線照射して重合して形成されたアクリル系粘着剤層（Ｙ）であることを特徴としている。本発明の粘着シートは、表面調整剤が表面に存在する自動車塗膜に対しても、表面調整剤による接着力低下の影響を受けずに、優れた接着力を発揮する。
PCT/JP2008/060883 2007-07-06 2008-06-13 車両用塗膜面接着用粘着シート WO2009008246A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP08765593.2A EP2166052A4 (en) 2007-07-06 2008-06-13 PRESSURE-SENSITIVE ADHESIVE SHEET FOR APPLICATION TO VEHICLE COATING FILM
US12/452,387 US20100136321A1 (en) 2007-07-06 2008-06-13 Pressure-sensitive adhesive sheet for application to vehicle coatings
CN2008800236695A CN101688089B (zh) 2007-07-06 2008-06-13 用于粘接车辆用涂膜面的粘合片

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007178081A JP5095279B2 (ja) 2007-07-06 2007-07-06 車両用塗膜面接着用粘着シート
JP2007-178081 2007-07-06

Publications (1)

Publication Number Publication Date
WO2009008246A1 true WO2009008246A1 (ja) 2009-01-15

Family

ID=40228425

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/060883 WO2009008246A1 (ja) 2007-07-06 2008-06-13 車両用塗膜面接着用粘着シート

Country Status (5)

Country Link
US (1) US20100136321A1 (ja)
EP (1) EP2166052A4 (ja)
JP (1) JP5095279B2 (ja)
CN (1) CN101688089B (ja)
WO (1) WO2009008246A1 (ja)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2228419A1 (en) * 2009-03-11 2010-09-15 Nitto Denko Corporation Acrylic pressure-sensitive adhesive sheet
EP2228418A1 (en) 2009-03-11 2010-09-15 Nitto Denko Corporation Acrylic pressure-sensitive adhesive sheet
US20120288710A1 (en) * 2010-01-07 2012-11-15 Nitto Denko Corporation Pressure-sensitive adhesive composition and pressure-sensitive adhesive sheet
CN102822292A (zh) * 2010-03-25 2012-12-12 日东电工株式会社 丙烯酸类粘合带
JPWO2011118181A1 (ja) * 2010-03-25 2013-07-04 日東電工株式会社 アクリル系粘着剤組成物およびアクリル系粘着テープ
WO2017154660A1 (ja) * 2016-03-09 2017-09-14 株式会社カネカ ラジカル硬化性組成物およびその硬化物

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009215489A (ja) * 2008-03-12 2009-09-24 Nitto Denko Corp 縁止めテープおよびその利用
JP5606725B2 (ja) * 2009-11-27 2014-10-15 日東電工株式会社 塗膜保護シート
JP5748952B2 (ja) * 2009-11-27 2015-07-15 日東電工株式会社 塗膜保護シート
JP2011202012A (ja) * 2010-03-25 2011-10-13 Nitto Denko Corp アクリル系粘着剤組成物およびアクリル系粘着テープ
EP2573149A1 (en) * 2011-09-26 2013-03-27 3M Innovative Properties Company Multilayer pressure-sensitive adhesive films with a (meth)acrylic-based elastomeric material
CN104093806B (zh) 2011-11-18 2017-04-05 3M创新有限公司 压敏粘合剂组合物
CN105247003B (zh) 2013-05-14 2017-03-29 3M创新有限公司 粘合剂组合物
EP3020776A4 (en) * 2013-07-09 2017-01-11 Nitto Denko Corporation Adhesive sheet and use thereof
JP6323041B2 (ja) * 2014-02-13 2018-05-16 東亞合成株式会社 粘着剤組成物およびその用途
WO2015143649A1 (en) 2014-03-26 2015-10-01 3M Innovative Properties Company Ultraviolet cured (meth)acrylate pressure-sensitive adhesive composition and process for producing thereof
JP6429679B2 (ja) * 2015-03-03 2018-11-28 積水フーラー株式会社 紫外線硬化型接着剤組成物
CN106928865B (zh) 2015-12-31 2021-01-12 3M创新有限公司 可固化的粘合剂组合物、压敏粘合剂和制备压敏粘合剂的方法
US10780668B2 (en) 2016-03-14 2020-09-22 3M Innovative Properties Company Surface protection film and related methods
JP6897334B2 (ja) * 2017-05-31 2021-06-30 王子ホールディングス株式会社 粘着シート
US11760073B2 (en) * 2019-06-20 2023-09-19 Craig Greiner Vehicle sheet coating
CN110396370B (zh) * 2019-08-07 2021-06-04 济南北方泰和新材料有限公司 一种uv-led固化改性丙烯酸酯压敏胶及其制备方法
CN113528065B (zh) * 2020-04-16 2023-02-17 3M创新有限公司 丙烯酸系压敏胶组合物、其制品及相关制备方法

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Publication number Priority date Publication date Assignee Title
JPH04114079A (ja) * 1990-09-03 1992-04-15 Nitto Denko Corp 感圧性接着剤組成物
JPH0812727A (ja) * 1994-07-04 1996-01-16 Shinnakamura Kagaku Kogyo Kk ビニル系共重合体および水分散型粘着剤
JPH08333550A (ja) * 1995-06-08 1996-12-17 New Oji Paper Co Ltd 粘着シート
JP2000248241A (ja) 1999-03-02 2000-09-12 Sliontec Corp 感圧性両面接着テープ及びその製造方法
JP2001049200A (ja) 1999-08-11 2001-02-20 Soken Chem & Eng Co Ltd アクリル系粘着剤組成物、該組成物を用いた粘着テープの製造方法および粘着テープ
JP2002003796A (ja) * 2000-06-27 2002-01-09 Nitto Denko Corp 接着剤組成物とこれを用いた感圧性接着剤およびその接着シート類
JP2002066206A (ja) 2000-08-25 2002-03-05 Kusumoto Kasei Kk クリアー塗料用消泡剤及び平滑剤
JP2003226834A (ja) 2002-02-07 2003-08-15 Kusumoto Kasei Kk 非水塗料用平滑剤

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US5130375A (en) * 1989-11-01 1992-07-14 Avery Dennison Corporation Vinyl functional reactive tackifiers for pressure-sensitive adhesives
JP3622289B2 (ja) * 1995-09-28 2005-02-23 王子製紙株式会社 再剥離性粘着シート
DE69723454T2 (de) * 1996-10-23 2004-05-13 Minnesota Mining And Manufacturing Co., Saint Paul Gegenstand umfassend eine retroreflektierende folie
JP4969036B2 (ja) * 2004-11-30 2012-07-04 日東電工株式会社 粘着シート類
CN1821333A (zh) * 2005-02-14 2006-08-23 日东电工株式会社 粘合带以及粘合剂组合物
JP4744172B2 (ja) * 2005-03-24 2011-08-10 日東電工株式会社 アクリル系粘着シートおよびその製造方法

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04114079A (ja) * 1990-09-03 1992-04-15 Nitto Denko Corp 感圧性接着剤組成物
JPH0812727A (ja) * 1994-07-04 1996-01-16 Shinnakamura Kagaku Kogyo Kk ビニル系共重合体および水分散型粘着剤
JPH08333550A (ja) * 1995-06-08 1996-12-17 New Oji Paper Co Ltd 粘着シート
JP2000248241A (ja) 1999-03-02 2000-09-12 Sliontec Corp 感圧性両面接着テープ及びその製造方法
JP2001049200A (ja) 1999-08-11 2001-02-20 Soken Chem & Eng Co Ltd アクリル系粘着剤組成物、該組成物を用いた粘着テープの製造方法および粘着テープ
JP2002003796A (ja) * 2000-06-27 2002-01-09 Nitto Denko Corp 接着剤組成物とこれを用いた感圧性接着剤およびその接着シート類
JP2002066206A (ja) 2000-08-25 2002-03-05 Kusumoto Kasei Kk クリアー塗料用消泡剤及び平滑剤
JP2003226834A (ja) 2002-02-07 2003-08-15 Kusumoto Kasei Kk 非水塗料用平滑剤

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2166052A4

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2228419A1 (en) * 2009-03-11 2010-09-15 Nitto Denko Corporation Acrylic pressure-sensitive adhesive sheet
EP2228418A1 (en) 2009-03-11 2010-09-15 Nitto Denko Corporation Acrylic pressure-sensitive adhesive sheet
US20120288710A1 (en) * 2010-01-07 2012-11-15 Nitto Denko Corporation Pressure-sensitive adhesive composition and pressure-sensitive adhesive sheet
CN102822292A (zh) * 2010-03-25 2012-12-12 日东电工株式会社 丙烯酸类粘合带
JPWO2011118181A1 (ja) * 2010-03-25 2013-07-04 日東電工株式会社 アクリル系粘着剤組成物およびアクリル系粘着テープ
WO2017154660A1 (ja) * 2016-03-09 2017-09-14 株式会社カネカ ラジカル硬化性組成物およびその硬化物

Also Published As

Publication number Publication date
EP2166052A1 (en) 2010-03-24
CN101688089A (zh) 2010-03-31
JP5095279B2 (ja) 2012-12-12
CN101688089B (zh) 2013-08-07
JP2009013322A (ja) 2009-01-22
US20100136321A1 (en) 2010-06-03
EP2166052A4 (en) 2013-11-06

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