WO2009004187A3 - Procède de fabrication de nanoparti cules d'oxyde de métal de transition enrobées de carbone - Google Patents

Procède de fabrication de nanoparti cules d'oxyde de métal de transition enrobées de carbone Download PDF

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Publication number
WO2009004187A3
WO2009004187A3 PCT/FR2008/000765 FR2008000765W WO2009004187A3 WO 2009004187 A3 WO2009004187 A3 WO 2009004187A3 FR 2008000765 W FR2008000765 W FR 2008000765W WO 2009004187 A3 WO2009004187 A3 WO 2009004187A3
Authority
WO
WIPO (PCT)
Prior art keywords
transition metal
nanoparticles
freeze
aqueous solution
dried
Prior art date
Application number
PCT/FR2008/000765
Other languages
English (en)
Other versions
WO2009004187A2 (fr
Inventor
Christine Bogicevic
Fabienne Karolak
Gianguido Baldinozzi
Mickael Dolle
Dominique Gosset
David Simeone
Original Assignee
Commissariat Energie Atomique
Ecole Centrale De Paris Ecp
Christine Bogicevic
Fabienne Karolak
Gianguido Baldinozzi
Mickael Dolle
Dominique Gosset
David Simeone
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Commissariat Energie Atomique, Ecole Centrale De Paris Ecp, Christine Bogicevic, Fabienne Karolak, Gianguido Baldinozzi, Mickael Dolle, Dominique Gosset, David Simeone filed Critical Commissariat Energie Atomique
Priority to RU2009148871/02A priority Critical patent/RU2485052C2/ru
Priority to CN2008800191834A priority patent/CN101743201B/zh
Priority to CA2690121A priority patent/CA2690121C/fr
Priority to EP08805653A priority patent/EP2155612A2/fr
Priority to KR1020107000254A priority patent/KR101427247B1/ko
Priority to JP2010510843A priority patent/JP2010528967A/ja
Priority to US12/663,352 priority patent/US8337799B2/en
Priority to BRPI0811962-7A2A priority patent/BRPI0811962A2/pt
Publication of WO2009004187A2 publication Critical patent/WO2009004187A2/fr
Publication of WO2009004187A3 publication Critical patent/WO2009004187A3/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/10—Treatment with macromolecular organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/90—Carbides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B32/00—Carbon; Compounds thereof
    • C01B32/90—Carbides
    • C01B32/914—Carbides of single elements
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/04—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3653—Treatment with inorganic compounds
    • C09C1/3661—Coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3669—Treatment with low-molecular organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3607—Titanium dioxide
    • C09C1/3676—Treatment with macro-molecular organic compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/36—Compounds of titanium
    • C09C1/3692—Combinations of treatments provided for in groups C09C1/3615 - C09C1/3684
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06—Treatment with inorganic compounds
    • C09C3/063—Coating
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/08—Treatment with low-molecular-weight non-polymer organic compounds
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Nanotechnology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Composite Materials (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Manufacturing & Machinery (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)

Abstract

Procédé de fabrication de nanoparticules d'au moins un oxyde de métal de transition choisi parmi Ti, Zr, Hf, V, Nb et Ta enrobées de carbone amorphe, le procédé comprenant les étapes successives suivantes : (i) un mélange liquide contenant en tant que précurseurs au moins un alkoxyde du métal de transition, un alcool, de l'acide acétique en excès vis à vis du métal de transition est préparé puis dilué dans de l'eau afin de former une solution aqueuse, les précurseurs étant présents dans la solution aqueuse selon un rapport molaire tel qu'il prévient ou limite suffisamment la formation d'un sol pour que la solution aqueuse soit lyophilisable et tel que le métal de transition, le carbone et l'oxygène sont présents selon le rapport stœchiométrique dans lequel ils se trouvent dans les nanoparticules, (ii) la solution aqueuse est soumise à une lyophilisation, (iii) le lyophilisât obtenu à l'étape précédente est pyrolyse sous vide ou sous atmosphère inerte afin d'obtenir les nanoparticules. L'invention concerne également l'application du procédé à la fabrication de carbure de métal de transition.
PCT/FR2008/000765 2007-06-06 2008-06-06 Procède de fabrication de nanoparti cules d'oxyde de métal de transition enrobées de carbone WO2009004187A2 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
RU2009148871/02A RU2485052C2 (ru) 2007-06-06 2008-06-06 Способ получения покрытых аморфным углеродом наночастиц и способ получения карбида переходного металла в форме нанокристаллитов
CN2008800191834A CN101743201B (zh) 2007-06-06 2008-06-06 用于制造带有碳涂层的过渡金属氧化物纳米颗粒的方法
CA2690121A CA2690121C (fr) 2007-06-06 2008-06-06 Procede de fabrication de nanoparticules d'oxyde de metal de transition enrobees de carbone
EP08805653A EP2155612A2 (fr) 2007-06-06 2008-06-06 Procède de fabrication de nanoparti cules d'oxyde de métal de transition enrobées de carbone.
KR1020107000254A KR101427247B1 (ko) 2007-06-06 2008-06-06 전이금속산화물의 탄소코팅된 나노입자 제조방법
JP2010510843A JP2010528967A (ja) 2007-06-06 2008-06-06 遷移金属酸化物のカーボンコーティングされたナノ粒子の製造方法
US12/663,352 US8337799B2 (en) 2007-06-06 2008-06-06 Process for manufacturing carbon coated nanoparticles of a transition metal oxide
BRPI0811962-7A2A BRPI0811962A2 (pt) 2007-06-06 2008-06-06 Processo para a fabricação de nanopartículas revestidas de carbono de um óxido de metal de transição.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0704031A FR2917080B1 (fr) 2007-06-06 2007-06-06 Procede de fabrication de nanoparticules d'oxyde de metal de transition enrobees de carbone
FR0704031 2007-06-06

Publications (2)

Publication Number Publication Date
WO2009004187A2 WO2009004187A2 (fr) 2009-01-08
WO2009004187A3 true WO2009004187A3 (fr) 2009-03-12

Family

ID=38983483

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2008/000765 WO2009004187A2 (fr) 2007-06-06 2008-06-06 Procède de fabrication de nanoparti cules d'oxyde de métal de transition enrobées de carbone

Country Status (10)

Country Link
US (1) US8337799B2 (fr)
EP (1) EP2155612A2 (fr)
JP (1) JP2010528967A (fr)
KR (1) KR101427247B1 (fr)
CN (1) CN101743201B (fr)
BR (1) BRPI0811962A2 (fr)
CA (1) CA2690121C (fr)
FR (1) FR2917080B1 (fr)
RU (1) RU2485052C2 (fr)
WO (1) WO2009004187A2 (fr)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102596814B (zh) * 2010-08-02 2014-05-14 昭和电工株式会社 氧化钛溶胶、其制造方法、超微粒状氧化钛、其制造方法及用途
US8932513B2 (en) 2011-06-10 2015-01-13 South Dakota Board Of Regents Process of making titanium carbide (TiC) nano-fibrous felts
CN103570066A (zh) * 2013-11-13 2014-02-12 沈阳大学 一种氧化锆纳米粉的制备方法
WO2015196039A1 (fr) * 2014-06-19 2015-12-23 The University Of Massachusetts Nanostructures à rapport d'aspect élevé et procédés de préparation
JP5926868B1 (ja) * 2014-09-22 2016-05-25 積水化学工業株式会社 カーボン被覆二酸化バナジウム粒子
US9725803B2 (en) 2015-07-02 2017-08-08 Goodrich Corporation Method of forming borides in carbon composites
US9970497B2 (en) 2015-12-18 2018-05-15 Goodrich Corporation Systems and methods for carbon-carbon materials incorporating yttrium and zirconium compounds
US9919973B1 (en) * 2017-03-31 2018-03-20 The Florida International University Board Of Trustees Synthesis of high temperature ceramic powders
US10786803B2 (en) 2018-04-23 2020-09-29 King Abdulaziz University Multi-walled carbon nanotube nanocomposite for hydrogen production
CN110104648B (zh) * 2019-05-10 2022-11-01 东华大学 一种高熵碳化物纳米粉体及其制备方法

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US4948573A (en) * 1986-12-02 1990-08-14 Alcan International Limited Process for producing silicon carbide and metal carbides
JPH06298533A (ja) * 1993-04-13 1994-10-25 Agency Of Ind Science & Technol 酸化チタンコロイドの製造方法
WO2006061367A1 (fr) * 2004-12-06 2006-06-15 Colorobbia Italia S.P.A. Procede de preparation de dispersions de tio2 sous forme de nanoparticules, dispersions obtenues a l'aide du procede et fonctionnalisation de surfaces par l'application de dispersions de tio2

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JPH0243943A (ja) * 1988-04-12 1990-02-14 Mitsuboshi:Kk 超微粉体の製造法
JPH02204319A (ja) * 1989-02-03 1990-08-14 Japan Atom Energy Res Inst 高融点炭化物超微粉の製造方法
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US3301790A (en) * 1964-09-24 1967-01-31 Grace W R & Co Metal oxide-carbon organosol process and product
US4948573A (en) * 1986-12-02 1990-08-14 Alcan International Limited Process for producing silicon carbide and metal carbides
JPH06298533A (ja) * 1993-04-13 1994-10-25 Agency Of Ind Science & Technol 酸化チタンコロイドの製造方法
WO2006061367A1 (fr) * 2004-12-06 2006-06-15 Colorobbia Italia S.P.A. Procede de preparation de dispersions de tio2 sous forme de nanoparticules, dispersions obtenues a l'aide du procede et fonctionnalisation de surfaces par l'application de dispersions de tio2

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Also Published As

Publication number Publication date
BRPI0811962A2 (pt) 2014-11-11
FR2917080B1 (fr) 2009-09-04
CA2690121C (fr) 2014-02-04
KR101427247B1 (ko) 2014-08-06
CN101743201B (zh) 2012-12-26
US20100202956A1 (en) 2010-08-12
KR20100062989A (ko) 2010-06-10
JP2010528967A (ja) 2010-08-26
RU2009148871A (ru) 2011-07-20
CA2690121A1 (fr) 2009-01-08
WO2009004187A2 (fr) 2009-01-08
RU2485052C2 (ru) 2013-06-20
FR2917080A1 (fr) 2008-12-12
US8337799B2 (en) 2012-12-25
CN101743201A (zh) 2010-06-16
EP2155612A2 (fr) 2010-02-24

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