WO2008143093A1 - 溶剤溶解性の良好な撥水撥油防汚剤 - Google Patents

溶剤溶解性の良好な撥水撥油防汚剤 Download PDF

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Publication number
WO2008143093A1
WO2008143093A1 PCT/JP2008/058857 JP2008058857W WO2008143093A1 WO 2008143093 A1 WO2008143093 A1 WO 2008143093A1 JP 2008058857 W JP2008058857 W JP 2008058857W WO 2008143093 A1 WO2008143093 A1 WO 2008143093A1
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WIPO (PCT)
Prior art keywords
repellent
water
oil
fluorine
antifouling agent
Prior art date
Application number
PCT/JP2008/058857
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English (en)
French (fr)
Inventor
Akihiko Ueda
Masahiko Maeda
Tetsuya Masutani
Original Assignee
Daikin Industries, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daikin Industries, Ltd. filed Critical Daikin Industries, Ltd.
Priority to KR1020137011393A priority Critical patent/KR20130066702A/ko
Priority to US12/599,790 priority patent/US20100227173A1/en
Priority to KR1020157004357A priority patent/KR101630137B1/ko
Priority to AU2008252105A priority patent/AU2008252105B2/en
Priority to JP2009515172A priority patent/JP5625352B2/ja
Priority to EP20080752728 priority patent/EP2154164B1/en
Priority to KR1020147018080A priority patent/KR101554114B1/ko
Priority to CN200880020440A priority patent/CN101707907A/zh
Publication of WO2008143093A1 publication Critical patent/WO2008143093A1/ja

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48Macromolecular compounds
    • C04B41/4838Halogenated polymers
    • C04B41/4842Fluorine-containing polymers
    • C04B41/4846Perfluoro-compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • C08F20/22Esters containing halogen
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10Esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/186Monomers containing fluorine with non-fluorinated comonomers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/22Esters containing halogen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/22Esters containing halogen
    • C08F220/24Esters containing halogen containing perhaloalkyl radicals
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00Materials not provided for elsewhere
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/76Hydrophobic and oleophobic coatings
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/203Oil-proof or grease-repellant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/3154Of fluorinated addition polymer from unsaturated monomers

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Geochemistry & Mineralogy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

 (A)含フッ素アクリレート単量体から誘導された繰り返し単位、ならびに(B)環状炭化水素基を有する単量体(B1)および短鎖炭化水素基を有する単量体(B2)からなる群から選択された少なくとも1種の非フッ素アクリレート単量体から誘導された繰り返し単位を有してなる撥水撥油防汚処理用含フッ素重合体を含む撥水撥油防汚処理剤は、溶剤溶解性が良好であり、種々の基材、特にメーソンリーに優れた効果を示す。
PCT/JP2008/058857 2007-05-15 2008-05-14 溶剤溶解性の良好な撥水撥油防汚剤 WO2008143093A1 (ja)

Priority Applications (8)

Application Number Priority Date Filing Date Title
KR1020137011393A KR20130066702A (ko) 2007-05-15 2008-05-14 용제 용해성이 양호한 발수 발유 방오제
US12/599,790 US20100227173A1 (en) 2007-05-15 2008-05-14 Water-repellent oil-repellent antifouling agent having good solubility in solvent
KR1020157004357A KR101630137B1 (ko) 2007-05-15 2008-05-14 용제 용해성이 양호한 발수 발유 방오제
AU2008252105A AU2008252105B2 (en) 2007-05-15 2008-05-14 Water-repellent oil-repellent antifouling agent having good solubility in solvent
JP2009515172A JP5625352B2 (ja) 2007-05-15 2008-05-14 溶剤溶解性の良好な撥水撥油防汚剤
EP20080752728 EP2154164B1 (en) 2007-05-15 2008-05-14 Water-repellent oil-repellent antifouling agent having good solubility in solvent
KR1020147018080A KR101554114B1 (ko) 2007-05-15 2008-05-14 용제 용해성이 양호한 발수 발유 방오제
CN200880020440A CN101707907A (zh) 2007-05-15 2008-05-14 溶剂溶解性良好的拨水拨油防污剂

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007128854 2007-05-15
JP2007-128854 2007-05-15

Publications (1)

Publication Number Publication Date
WO2008143093A1 true WO2008143093A1 (ja) 2008-11-27

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Application Number Title Priority Date Filing Date
PCT/JP2008/058857 WO2008143093A1 (ja) 2007-05-15 2008-05-14 溶剤溶解性の良好な撥水撥油防汚剤

Country Status (7)

Country Link
US (1) US20100227173A1 (ja)
EP (2) EP2634162A1 (ja)
JP (3) JP5625352B2 (ja)
KR (4) KR101554114B1 (ja)
CN (3) CN101707907A (ja)
AU (1) AU2008252105B2 (ja)
WO (1) WO2008143093A1 (ja)

Cited By (12)

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JP2011099077A (ja) * 2009-11-09 2011-05-19 Noda Screen:Kk フッ素系重合体およびコーティング剤
JPWO2011122442A1 (ja) * 2010-03-30 2013-07-08 ダイキン工業株式会社 α−クロロアクリレートを使用した撥水撥油剤
WO2013151003A1 (ja) * 2012-04-02 2013-10-10 ダイキン工業株式会社 耐久型防水・防湿性コーティング組成物
WO2014030648A1 (ja) * 2012-08-21 2014-02-27 旭硝子株式会社 含フッ素共重合体およびその製造方法、撥水剤組成物、物品
JP2014129532A (ja) * 2008-09-15 2014-07-10 Daikin Ind Ltd 撥水撥油剤組成物
JP2014196432A (ja) * 2013-03-29 2014-10-16 株式会社ネオス フッ素系重合体及びこれを含有する表面処理剤
WO2014208424A1 (ja) 2013-06-28 2014-12-31 ダイキン工業株式会社 表面処理剤
JP2015067679A (ja) * 2013-09-27 2015-04-13 第一工業製薬株式会社 ポリマー組成物及び撥水撥油剤
CN104981444A (zh) * 2012-03-20 2015-10-14 纳幕尔杜邦公司 钙质基底的耐酸蚀性
JP2017128725A (ja) * 2016-01-18 2017-07-27 ダイキン工業株式会社 シーリング材組成物
JP2018095888A (ja) * 2018-02-06 2018-06-21 株式会社ネオス フッ素系重合体及びこれを含有する表面処理剤
WO2020066149A1 (ja) * 2018-09-27 2020-04-02 第一工業製薬株式会社 共重合体および撥水撥油剤

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CN101707907A (zh) * 2007-05-15 2010-05-12 大金工业株式会社 溶剂溶解性良好的拨水拨油防污剂
CN102405549B (zh) 2009-03-04 2014-05-21 株式会社Lg化学 包含酰胺化合物的电解质和含有所述电解质的电化学装置
ES2387430B1 (es) * 2011-02-25 2013-08-02 Quimigama, S.L. Protector de piedra
US10012065B2 (en) 2014-08-15 2018-07-03 Halliburton Energy Services, Inc. Hydrophobic surface treatment for use in subterranean formation operations
KR102536232B1 (ko) * 2016-01-14 2023-05-26 주식회사 케이씨씨 불소계 (메타)아크릴레이트 공중합체를 포함하는 방오도료 조성물
KR102028721B1 (ko) * 2016-10-06 2019-10-07 한국생산기술연구원 공유결합에 의한 종이 코팅용 발수발유 공중합체, 이의 제조방법, 및 이의 용도
WO2019083056A1 (ko) * 2017-10-24 2019-05-02 한국생산기술연구원 공유결합에 의한 종이 코팅용 발수발유 공중합체, 이의 제조방법, 및 이의 용도
KR102166990B1 (ko) * 2017-12-01 2020-10-19 한국생산기술연구원 종이 코팅용 발수발유 코어-쉘 나노입자, 이의 제조방법, 및 이의 용도
KR102468147B1 (ko) * 2020-02-14 2022-11-18 니카코리아 주식회사 발수, 발유 및 방오 성능이 개선된 불소계 가공제 조성물 및 이를 이용한 섬유제품
CN115572539B (zh) * 2022-09-22 2024-01-16 西北工业大学 砖石质文物耐久型超疏水防风化材料及制备方法和涂层制备方法

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See also references of EP2154164A4

Cited By (20)

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JP2014129532A (ja) * 2008-09-15 2014-07-10 Daikin Ind Ltd 撥水撥油剤組成物
JP2011099077A (ja) * 2009-11-09 2011-05-19 Noda Screen:Kk フッ素系重合体およびコーティング剤
JPWO2011122442A1 (ja) * 2010-03-30 2013-07-08 ダイキン工業株式会社 α−クロロアクリレートを使用した撥水撥油剤
JP5626337B2 (ja) * 2010-03-30 2014-11-19 ダイキン工業株式会社 α−クロロアクリレートを使用した撥水撥油剤
CN104981444A (zh) * 2012-03-20 2015-10-14 纳幕尔杜邦公司 钙质基底的耐酸蚀性
WO2013151003A1 (ja) * 2012-04-02 2013-10-10 ダイキン工業株式会社 耐久型防水・防湿性コーティング組成物
JPWO2014030648A1 (ja) * 2012-08-21 2016-07-28 旭硝子株式会社 含フッ素共重合体およびその製造方法、撥水剤組成物、物品
WO2014030648A1 (ja) * 2012-08-21 2014-02-27 旭硝子株式会社 含フッ素共重合体およびその製造方法、撥水剤組成物、物品
KR102019655B1 (ko) 2012-08-21 2019-09-09 에이지씨 가부시키가이샤 함불소 공중합체 및 그 제조 방법, 발수제 조성물, 물품
US9487689B2 (en) 2012-08-21 2016-11-08 Asahi Glass Company, Limited Fluorinated copolymer and process for its production, water repellent composition, and article
KR20150046008A (ko) * 2012-08-21 2015-04-29 아사히 가라스 가부시키가이샤 함불소 공중합체 및 그 제조 방법, 발수제 조성물, 물품
JP2014196432A (ja) * 2013-03-29 2014-10-16 株式会社ネオス フッ素系重合体及びこれを含有する表面処理剤
US9688797B2 (en) 2013-06-28 2017-06-27 Daikin Industries, Ltd. Surface treatment agent
WO2014208424A1 (ja) 2013-06-28 2014-12-31 ダイキン工業株式会社 表面処理剤
JP2015067679A (ja) * 2013-09-27 2015-04-13 第一工業製薬株式会社 ポリマー組成物及び撥水撥油剤
JP2017128725A (ja) * 2016-01-18 2017-07-27 ダイキン工業株式会社 シーリング材組成物
JP2018095888A (ja) * 2018-02-06 2018-06-21 株式会社ネオス フッ素系重合体及びこれを含有する表面処理剤
WO2020066149A1 (ja) * 2018-09-27 2020-04-02 第一工業製薬株式会社 共重合体および撥水撥油剤
JP2020050757A (ja) * 2018-09-27 2020-04-02 第一工業製薬株式会社 共重合体および撥水撥油剤
JP7207922B2 (ja) 2018-09-27 2023-01-18 第一工業製薬株式会社 共重合体および撥水撥油剤

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Publication number Publication date
EP2154164B1 (en) 2014-04-30
EP2154164A4 (en) 2010-08-18
CN104356290A (zh) 2015-02-18
JP5625352B2 (ja) 2014-11-19
JP2015187280A (ja) 2015-10-29
JP6166097B2 (ja) 2017-07-19
JPWO2008143093A1 (ja) 2010-08-05
KR101554114B1 (ko) 2015-09-17
EP2634162A1 (en) 2013-09-04
KR20140090271A (ko) 2014-07-16
CN104311729A (zh) 2015-01-28
KR20130066702A (ko) 2013-06-20
KR20100019514A (ko) 2010-02-18
US20100227173A1 (en) 2010-09-09
EP2154164A1 (en) 2010-02-17
JP2013189641A (ja) 2013-09-26
AU2008252105A1 (en) 2008-11-27
AU2008252105B2 (en) 2011-05-19
KR101630137B1 (ko) 2016-06-13
CN101707907A (zh) 2010-05-12
KR20150038165A (ko) 2015-04-08

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