WO2008123267A1 - 成形性に優れた高強度溶融亜鉛めっき鋼板およびその製造方法 - Google Patents
成形性に優れた高強度溶融亜鉛めっき鋼板およびその製造方法 Download PDFInfo
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- WO2008123267A1 WO2008123267A1 PCT/JP2008/055629 JP2008055629W WO2008123267A1 WO 2008123267 A1 WO2008123267 A1 WO 2008123267A1 JP 2008055629 W JP2008055629 W JP 2008055629W WO 2008123267 A1 WO2008123267 A1 WO 2008123267A1
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- steel sheet
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 79
- 239000010959 steel Substances 0.000 title claims abstract description 79
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000011701 zinc Substances 0.000 title claims abstract description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 229910052725 zinc Inorganic materials 0.000 title claims abstract description 9
- 239000000203 mixture Substances 0.000 claims abstract description 29
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 26
- 239000000126 substance Substances 0.000 claims abstract description 11
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 8
- 239000012535 impurity Substances 0.000 claims abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 4
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 72
- 238000007747 plating Methods 0.000 claims description 53
- 238000010438 heat treatment Methods 0.000 claims description 51
- 239000006104 solid solution Substances 0.000 claims description 51
- 229910000734 martensite Inorganic materials 0.000 claims description 33
- 239000002344 surface layer Substances 0.000 claims description 32
- 229910001335 Galvanized steel Inorganic materials 0.000 claims description 31
- 239000008397 galvanized steel Substances 0.000 claims description 31
- 229910052742 iron Inorganic materials 0.000 claims description 31
- 239000010949 copper Substances 0.000 claims description 28
- 229910052802 copper Inorganic materials 0.000 claims description 27
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 26
- 229910000859 α-Fe Inorganic materials 0.000 claims description 23
- 238000001816 cooling Methods 0.000 claims description 22
- 229910001566 austenite Inorganic materials 0.000 claims description 21
- 239000000463 material Substances 0.000 claims description 19
- 238000005246 galvanizing Methods 0.000 claims description 17
- 239000010410 layer Substances 0.000 claims description 16
- 230000009467 reduction Effects 0.000 claims description 13
- 238000000137 annealing Methods 0.000 claims description 12
- 238000005275 alloying Methods 0.000 claims description 11
- 238000005097 cold rolling Methods 0.000 claims description 6
- 230000001590 oxidative effect Effects 0.000 claims description 5
- 238000005098 hot rolling Methods 0.000 claims description 4
- 230000000717 retained effect Effects 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 229910052758 niobium Inorganic materials 0.000 claims description 3
- 239000004071 soot Substances 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims 1
- 239000011159 matrix material Substances 0.000 claims 1
- 230000000694 effects Effects 0.000 description 36
- 229910001563 bainite Inorganic materials 0.000 description 15
- 238000006722 reduction reaction Methods 0.000 description 13
- 239000010953 base metal Substances 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- 230000007423 decrease Effects 0.000 description 8
- 238000007373 indentation Methods 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 229910001562 pearlite Inorganic materials 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 238000005728 strengthening Methods 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 238000002844 melting Methods 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 239000010960 cold rolled steel Substances 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- -1 i.e. Inorganic materials 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 239000010409 thin film Substances 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 150000001247 metal acetylides Chemical class 0.000 description 3
- 238000003303 reheating Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 208000023514 Barrett esophagus Diseases 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005242 forging Methods 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 241000219307 Atriplex rosea Species 0.000 description 1
- 101000634404 Datura stramonium Tropinone reductase 1 Proteins 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 101000848007 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) Thioredoxin-1 Proteins 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- NJFMNPFATSYWHB-UHFFFAOYSA-N ac1l9hgr Chemical compound [Fe].[Fe] NJFMNPFATSYWHB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000007542 hardness measurement Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000002715 modification method Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 210000003462 vein Anatomy 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/003—Apparatus
- C23C2/0038—Apparatus characterised by the pre-treatment chambers located immediately upstream of the bath or occurring locally before the dipping process
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0222—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating in a reactive atmosphere, e.g. oxidising or reducing atmosphere
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
- C23C2/022—Pretreatment of the material to be coated, e.g. for coating on selected surface areas by heating
- C23C2/0224—Two or more thermal pretreatments
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/06—Zinc or cadmium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/26—After-treatment
- C23C2/28—Thermal after-treatment, e.g. treatment in oil bath
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12785—Group IIB metal-base component
- Y10T428/12792—Zn-base component
- Y10T428/12799—Next to Fe-base component [e.g., galvanized]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12951—Fe-base component
- Y10T428/12972—Containing 0.01-1.7% carbon [i.e., steel]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Definitions
- the present invention relates to a high-strength hot-dip galvanized steel sheet excellent in formability for members used in industrial fields such as automobiles and electricity.
- Patent Document 1 proposes a high strength steel sheet with excellent hot-spreading capability
- Patent Documents 2 to 4 provide a high strength steel sheet with excellent hot-plating adhesion and ductility. It has been proposed.
- Patent Documents 2 to 4 include residual austenite, so the elongation characteristics are high, but there are cases where cracking occurs during secondary processing and the shape freezing property of molded parts is inferior to ferrite + martensite steel. is there.
- Non-Patent Document 1 will be described in the [Disclosure of the Invention] section.
- Patent Document 1 Japanese Patent Laid-Open No. 2005-256089
- Patent Document 2 JP 2005-200690
- Patent Document 3 JP 2005-200694
- Patent Document 4 Japanese Unexamined Patent Publication No. 2006-299344
- the problem in the present invention is that it has high formability equal to or higher than that of a conventional high-strength hot-dip galvanized copper sheet, and has the same cost and manufacturability as a conventional high-strength hot-dip galvanized steel sheet. It is to obtain a high-strength molten dumbbell steel plate and its manufacturing method.
- A1 is limited to the level used for normal deoxidation, TS X total elongation ⁇ 1500 OMPa ⁇ %, TSX hole expansion rate It is to obtain a high-strength, fusion-bonded steel sheet having excellent formability of 45000 MPa ⁇ % and a method for producing the same.
- parts for automotive body use have increased in number of complex shapes. Die 3 Total stretch ⁇ 1 500 OMP a ⁇ %, TS X hole expansion rate 45000MPa ⁇ % Satisfying the requirements makes it possible to manufacture many parts using high-tensile steel sheets.
- the inventors first examined the influence of the steel sheet structure on the TSX hole expansion ratio and TSX total elongation for various steel sheets. As a result, there was a correlation between the distribution of nano-hardness of the tissue in the copper plate and the TS X hole expansion rate. In other words, the TSX hole expansion ratio is high when the standard deviation of the nano hardness at the position of the thickness 14 where the structure fraction and hardness are measured as a typical part of the steel sheet structure is 1.50 GPa or less. I found. "Here, nano hardness is the hardness measured using Hy Sitron's TR I BO SCOPE with a load of 1 000 ⁇ . Specifically, 7 points at 5 / zm pitch are measured in 7 rows. Measurements were made around 50 points, and the standard deviation was determined.
- Vickers hardness is a well-known technique for measuring microstructure hardness.
- the minimum value of the applied load is 0.5 gf
- the hard martensite has an indentation size of 1 to 2 m, making it impossible to measure the hardness of fine phases.
- the martensite has a hierarchical structure of packets, blocks, and ras within the organization, and bait Since it has a cocoon layer structure called “subunit”, as clarified in Non-Patent Document 1, the hierarchy that affects the hardness measured by the indentation size is different. For example
- the result of evaluation with an indentation size of 1 ⁇ m or less is different from the result of evaluation with an indentation size of 10 / im or more that can be measured with a Vickers hardness tester, and the correlation between the material and Vickers hardness or nanohardness is not the same. Absent. Under the conditions measured in the present invention, the length of one side of the indentation is 300 to 800 nm, and it has been found that reducing the standard deviation of the nano hardness improves the hole expansion rate.
- the gist of the present invention is as follows.
- the copper plate structure includes ferrite with an area ratio of 20% or more, tempered martensite, tempered bainite, and bait with a total area ratio of 10% or more. Excellent formability, characterized by a total area ratio of tempered martensite, tempered bainite and bainite of 90% or more, and a standard deviation of nano hardness of 1.50 GPa or less High strength hot dip galvanized steel sheet.
- the steel according to any one of (1) to (3) above is selected by mass% from T i: 0.01 to 0.20% and Nb: 0.01 to 0.10% 1
- the copper according to any one of the above (1) to (4) is characterized by further containing, by mass%, B: 0.0002 to 0.00% by weight (1) to (4 Or a high-strength hot-dip galvanized steel sheet having excellent formability. '
- the steel described in any of the above (1) to (5) is one type selected from Ca: 0.001 to 0.005% and REM: 0.001 to 0.005% by mass. Or a high-strength hot-dip galvanized steel sheet excellent in formability according to any one of (1) to (5), further comprising two or more elements.
- the steel sheet structure has a total area ratio of residual austenite and martensite of 5% or less. High strength with excellent formability according to any one of (1) to (6) Hot dip galvanized steel sheet.
- the high-strength hot-dip galvanized steel sheet according to any one of the above (1) to (7), wherein the surface area of the surface layer of the plated steel from the Z-level iron interface to the depth of 0.5 / zm is A high-strength hot-dip galvanized steel sheet excellent in formability, characterized in that both the average solid solution Si amount and the average solid solution Mn amount are 0.5 mass% or less.
- a high-strength galvannealed steel sheet with 7-15% Fe% in the high-strength hot-dip galvanized steel sheet, and a depth of 0.5% from the clasp / steel interface The average solid solution Si amount in the surface layer of the iron steel in the region up to / m is 70 to 90% of the Si amount of the base material average composition, and the average solid solution Mn amount is the Mn amount of the base material average composition. 50-90%
- continuous molten zinc plating having a direct-fired furnace type or non-oxidizing furnace type heating zone
- the heating zone is heated so that the average heating rate from 4003 ⁇ 4 to the heating zone exit side temperature is 10 ° C / s or more and the heating zone exit j3 ⁇ 4 degree is 600 ° C or more, and then the reduction zone
- High formability with high formability characterized by applying hot dip galvanizing after holding to 1 s or longer after heating to below, or alloying treatment of hot dip galvanizing
- the standard deviation of nano hardness is less than 1.50 GPa:
- Nanohardness 1 Thickness 1 When measuring about 50 points near 4 positions, if the standard deviation of nanohardness exceeds 1.5 OGP a, TSX hole expansion ratio ⁇ 4500 OMP a ⁇ % cannot be achieved. 50GP or less. Preferably 1. OGP a or less. The standard deviation ⁇ was obtained from Equation (1) for ⁇ pieces of hardness data X.
- C is an element that stabilizes austenite, and it is easy to generate hard phases other than ferrite, i.e., martensite, bainite, residual austenite, tempered martensite, and tempered bainite. It is an element necessary to increase the strength and improve the TS-elongation balance (TSX elongation) by combining the tissues. If the amount of C is less than 0.05%, even if the production conditions are optimized, it is difficult to secure phases other than ferrite, and TSX elongation decreases. On the other hand, if the C content exceeds 0.30%, the welded part and the heat-affected zone are significantly hardened, and the mechanical properties of the welded part deteriorate. From this point of view, the C content should be in the range of 0.05 to 0.30%. Preferably, it is 0.08% to 0.15%.
- Si is an effective element for strengthening steel.
- Si has the effect of reducing the standard deviation of nanohardness in the composite structure copper.
- details are unknown, it is estimated that Si is unlikely to increase the nanohardness of the hard phase when trying to obtain a steel sheet with the same tensile strength.
- it is a ferrite-forming element, it promotes the concentration of C in the austenite, so that it is a hard phase other than ferrite, that is, martensite, bainite, residual austenite, tempered martensite, and tempered. It is easy to form bainite and improves the TSX elongation of high strength steel by obtaining a composite structure of ferrite + hard phase.
- the solid solution Si in ferrite has the effect of improving the TS X total elongation and hole expandability of the steel sheet. This effect is obtained by addition exceeding 0.60 ° / 0 .
- Si exceeds 2.0% the formability and toughness deteriorate due to the increase in the amount of solid solution in the ferrite, and surface properties and hot-dip plating adhere due to the occurrence of red scale. Cause sexual degradation. Therefore, the Si amount is set to exceed 0.60 to 2.0%. Preferably it is 0.80 to 1.5%.
- Mn 0.50 to 3 50% Mn is an effective element for strengthening steel. It is an element that stabilizes austenite and is necessary for increasing the volume of phases other than ferrite, ensuring strength, and improving TSX elongation. This effect is obtained when Mn is 0.50% or more. On the other hand, when Mn is added in excess of 3.50%, ductility deterioration of the ferrite due to excessive hard phase fraction and solid solution strengthening becomes remarkable, and formability deteriorates. Therefore, 3. 50% or less. The preferred range is 1.5% to 3.0%.
- P is an element effective for strengthening copper, and this effect is obtained when P: 0.003% or more. However, if it is added excessively over 0.100%, it will cause embrittlement due to segregation at the grain boundaries, which will deteriorate the impact resistance. Therefore, the P amount is set to 0.003% to 0.100%.
- Mn S is an inclusion such as Mn S, which may cause deterioration of impact resistance and cracking along the metal flow of the weld. It should be as low as possible. As below, 0.003% or less is preferable because the spreadability is remarkably improved at 0.003% or less.
- a 1 0.010 to 0.06%
- a 1 fixes oxygen in steelmaking and slabs and suppresses the occurrence of defects such as slab cracking. The effect is observed with the addition of 0.010%. However, if added in a large amount, the risk of steel piece cracking during continuous forging increases and productivity decreases. Also, to increase the alloy cost, it is set at 0.06% or less.
- the total amount of N exceeds 0.007%, the coarse A 1 N inside the copper plate increases and the fatigue characteristics deteriorate rapidly. Therefore, it is set to 0.007% or less.
- the above component composition is an essential component and the balance is iron and unavoidable impurities, but the following component composition can be appropriately contained.
- Cr suppresses the formation of pearlite soot when cooled from the annealing temperature, facilitates the formation of martensite, bainite, retained austenite, tempered martensite, and tempered bait, and improves TSX elongation. This effect is obtained at 0.005% or more. However, if it exceeds 2.00%, the effect will saturate, which will increase costs. Therefore, it is specified as 0. 05% to 2.00%.
- V suppresses the formation of pearlite during cooling from the annealing temperature, makes it easier to produce manoletensite, bainite, residual austenite, tempered martensite, and tempered veinite, and improves TS X elongation. .
- This effect is obtained at 0. Q 05% or more. However, if it exceeds 2.00%, the effect will saturate, which will increase costs. Therefore, it is defined as 0.005% to 2.00%.
- Mo suppresses the formation of pearlite when cooled from the annealing temperature, makes it easier to produce martensite, baitite, retained austenite, tempered martensite, and tempered bait, and improves TS X elongation. This effect is obtained at 0.005% or more. However, if it exceeds 2.00%, the effect will saturate, which will increase costs. Therefore, it is defined as 0. 05% to 2.00%.
- Ni suppresses the formation of pearlite during cooling from the annealing temperature, facilitates the formation of martensite, bainite, residual austenite, tempered martensite, and tempered veinite, and improves TSX elongation. .
- This effect is obtained at 0.005% or more. However, if it exceeds 2.0%, the effect will saturate, which will increase the cost. Therefore, it is defined as 0.005% to 2.00%.
- Cu suppresses the formation of pearlite when cooled from the annealing temperature, facilitates the formation of martensite, bainite, residual austenite, tempered martensite, and tempered vein, and improves TSX elongation. This effect is obtained at 0.005% or more. However, if it exceeds 2.00%, the effect will saturate and cause an increase in cost. Therefore, it is specified as 0.0.05% to .2.00%.
- T i 0.01 to 0.2% and Nb: 0.01 to 0.1%
- T i is effective for strengthening steel, and it is possible to deposit carbides and precipitates more evenly and to strengthen ferrite. Therefore, the standard deviation of nano hardness can be reduced, and the TSX hole expansion rate is improved. To do. This effect can be obtained at 0.01% or more, but if it exceeds 0.2%, the effect will be saturated, resulting in a cost increase. Therefore, it is set to 0.01% to 0.2%.
- Nb is effective in strengthening steel, and it can precipitate carbides and precipitates more uniformly and strengthen the ferrite ground, so the standard deviation of nano hardness can be made smaller and the TS X hole expansion rate improved. To do. This effect can be obtained at 0.01% or more, but if it exceeds 0.1%, the effect will be saturated, resulting in a cost increase. Therefore, it is set to 0.0 1% to 0.1%.
- B has the effect of suppressing the formation of ferrite from the austenite grain boundary and increasing the strength.
- the effect is obtained at 0.0002% or more. However, if it exceeds 0.0050%, the effect will be saturated, resulting in a cost increase. Therefore, it is set to 0.0002% to 0.005%.
- C a 0.001 to 0.005% and REM: 0.001 to 0.005% or one or more selected from
- C a 0.001 to 0.005%
- Ca has the effect of improving the elongation and hole expansion ratio, that is, improving the formability by improving the local ductility.
- the effect is obtained at 0.001% or more and saturates at 0.005%. Therefore, it is set to 0.001% to 0.005%.
- REM has the effect of contributing to improvement of elongation and hole expansion rate, that is, improvement of formability by improving local ductility.
- the effect is obtained above 0.001% and saturates at 0.005%. Therefore, it is set to 0.001% to 0.005%.
- Ferrite has an area ratio of 20% or more:
- the area ratio of ferrite is 20% or more, preferably 50% or more.
- Tempered martensite, tempered bainite and bainitic total area ratio is 10% or more:
- the total area ratio of these phases is set to 10% or more. However, if these phases are contained excessively, the TSX elongation decreases, so the total area ratio of the structure is preferably 50% or less.
- the total area ratio of ferrite, tempered martensite, tempered bait and bait is 90% or more:
- the total area ratio of these phases is less than 90%, the TS X hole expansion ratio decreases. For this reason, the total area ratio of these phases is 90% or more, preferably 95% or more.
- the total area ratio of residual austenite and martensite is 5% or less:
- the TS X hole expansion ratio is remarkably improved.
- it is 3% or less.
- High-strength hot-dip galvanized steel sheets that are not alloyed after molten dumbbell plating have an average solid solution S i amount and average solid solution in the surface layer of the steel from 0.5 to // m in depth from the plated iron interface.
- the Mn content is 0.5 mass% or less.
- the area that undergoes internal oxidation in the manufacturing process is sufficient for securing plating characteristics if it is the surface layer of the area from the plating base metal interface to a depth of 0.5 m, so we focused on composition control in this area. .
- Plating that can withstand actual use if the amount of solid solution Si and solid solution Mn is 0.5% by mass or less in the iron and steel in the region from the plating / steel interface to a depth of 0.5 / zm, respectively. Adhesion can be secured and non-plating can be prevented, but if it exceeds 0.5 mass%, non-plating may occur or plating adhesion may deteriorate.
- the average solid solution Si and average solid solution amounts in the surface layer of the iron steel in the region from the plating metal interface to a depth of 0.5 ⁇ Must be 0.5ma ss% or less.
- the base material may be previously surface-modified and internally oxidized before entering the CGL (continuous molten zinc plating line). Any modification method can be used, however, for example, hot-rolled steel sheets are heat-treated, compared to a comparatively high temperature, for example, 650 ° C or higher, and the coil cooling rate after scraping is reduced. It doesn't matter.
- a heat treatment method a method in which a hot rolled coil is heat treated at 65 in a non-reducing atmosphere such as an N 2 atmosphere can be considered.
- the CGL heating zone is made DFF (direct furnace) or NO F (non-oxidizing furnace) type
- the surface layer of the steel is oxidized in the CGL heating zone, and then reduced with oxygen supplied from the iron scale.
- the internal oxidation of the iron surface layer reduces the amount of solute elements in the surface layer of the base metal that can be easily oxidized, and suppresses the surface concentration of Si, Mn, etc. just before the hot galvanizing. I do not care.
- the amount of solid solution Si and solid solution Mn in the surface layer is determined by increasing the steel plate temperature on the heating zone side when reducing in the reduction zone after the oxidation treatment. acid
- the amount of solid solution S i and the amount of solid solution Mn in the surface layer of the steel can be reduced.
- the amount of solid solution Mn can be controlled.
- the presence or absence of oxide is fitted into a resin and polished to obtain a cross-section of the steel sheet, and composition analysis is performed with EPM A to confirm the presence or absence of oxygen and oxidizable elements such as Si and Mn. This can be confirmed by extracting the cross-section replicas or thin-film processed samples with FIB and analyzing the composition with TEM.
- the solid solution amounts of Si and Mn in the base iron can be confirmed by analyzing the composition of the section where oxides are not deposited in the cross section of the sample prepared in the same way.
- a sample processed with a thin film by FIB was measured at a magnification of 20000 times or more for measuring the amount of solid solution.
- the TEM-EDS composition analysis method is preferred.
- the surface layer structure immediately below the plating layer retains the state immediately after annealing immediately before plating, and the Si and Mn solid solution amounts are By keeping it at a low level, the solid solution Si and solid solution Mn content in the surface layer of the plating from the surface of the plating metal to the depth of 0.5 ⁇ can be reduced to 0.5 mass% or less.
- High-strength galvannealed steel sheets with alloyed plating layers are 7 to 15% Fe% in the plating layer, and have a depth of 0.5 im from the surface of the iron surface.
- the average solid solution Si amount and the average solid solution Mn amount in the iron surface layer are 70 to 90% of the average solid solution Si amount and the Si amount of the base material average composition, and the average solid solution Mn amount is It is 50 to 90% of the Mn content of the average base metal composition.
- Fe% in the plating layer is less than 7%, poor appearance such as uneven burning will occur, and if it exceeds 15%, peeling of the plating during bending will become serious, so Fe ° / 0 in the plating layer will be 7 ⁇ 1 Must be 5%.
- a range of Fe ° / ⁇ 8 to l 3% is more preferable.
- the surface layer structure just under the plating layer is slightly different from the state immediately after annealing immediately before staking because the surface layer structure by alloying elutes into the plating layer.
- the amount of Si and Mn solid solution increases compared to the hot-dip galvanized steel sheet that is not alloyed.
- METSUKI The average solid solution Si and average solid solution Mn content in the surface layer of the iron steel in the region up to 0.5 m in depth from the Z iron interface become the Si and Mn amounts of the base material average composition.
- Si is 70 to 90%
- Mn is 50 to 90%, in order to ensure plating adhesion and alloying uniformity.
- the effect of improving the adhesion at the interface after forming the Fe-Zn alloy can be obtained. This is thought to be because Si, Mn, etc., dissolved in the base metal moderately nonuniformize the Fe-Zn alloying reaction and cause an anchor effect at the interface.
- the average solid solution Si content in the surface layer of the iron steel in the region from the Z iron interface to the depth of 0.5 / zm is 70% or more of the Si content of the base metal average composition. This effect is fully manifested when the average solid solution Mn content in the surface layer of the iron steel in the region from 1 to 0.5 / im is 50% or more of the Mn content of the base metal average composition.
- the average solid solution Si amount is less than 70% of the Si content of the base material average composition and the average solid solution Mn amount is less than 50% of the Mn amount of the base material average composition, this effect becomes insufficient. The effect decreases and the plating adhesion deteriorates.
- Plating Z The average solid solution Si content in the surface layer of the iron steel in the region from the depth of 0.5 / xm to the depth of 0.5 / xm exceeds 90% of the Si content of the base material average composition, and the average solid solution Mn content is If the Mn content of the base metal average composition exceeds 90%, the Si and Mn surface concentration during annealing increases, and non-plating occurs, resulting in poor adhesion.
- the P solid solution amount and A 1 solid solution amount in the surface layer of the iron steel in the region from the plating iron interface to a depth of 0.5 ⁇ are not specified, but the P amount and A 1 amount of the base material average composition respectively. Is preferably less than 50%. However, since it is difficult to analyze and confirm if the content of P and A 1 is small, no upper limit is specified for P and A 1.
- Adhesion amount of molten zinc is 20 to 150 gZm 2 per side:
- Adhesion amount of the molten zinc plated is it is difficult to secure the corrosion resistance is less than 20 gZm 2. Also, when the eyes deposition amount exceeds 150 gZm 2, increasing costs. For this reason, the amount of adhesion of molten zinc is 20-150 gZm 2 per side.
- the iron content (Fe% (mass%)) in the plating layer is less than 7%, the alloying unevenness is severe and flaking occurs during bending, which is not preferable. If F e% exceeds 15%, Plating Since a hard ⁇ phase is formed at the iron interface, it is not preferable. Therefore, in the case of alloyed hot dip galvanizing, the Fe% is preferably 7 to 15%.
- a steel slab having the above-mentioned composition is melted and hot rolled and cold rolled to produce a cold rolled steel sheet.
- Slabs can be melted in the same manner as in the past, and ingots, continuous forging slabs or thin slab casters may be used.
- Hot rolling may be performed by cooling the slab and then reheating it, or may be performed immediately after fabrication.
- the finish rolling temperature is preferably Ar 3 or higher, but is not particularly limited.
- Cold rolling may be performed at a cold rolling rate of about 30 to 60%, but is not particularly limited.
- the cold-rolled steel sheet is annealed in a continuous hot-dip galvanizing line having a direct heating furnace or non-oxidizing furnace type heating zone, and then hot-dip galvanizing is applied, or alloying treatment of the hot-dip galvanizing is further performed. Apply.
- the outlet temperature of the heating zone is set to 60 ° C. or higher, and the average heating rate from 400 ° C. to the heating zone outlet temperature in the furnace of the heating zone is 10 ° C. or higher. .
- DFF direct furnace
- NO F non-oxidizing furnace
- the temperature of the copper plate on the heating strip side becomes 6 00 3 ⁇ 4 or more.
- the outlet temperature of the heating zone is less than 600 ° C, the temperature is low, so the amount of oxidation of the iron is small, and when the reduction treatment is performed, the internal oxidation of the surface of the iron iron becomes insufficient, directly below the plating layer.
- the amount of solid solution Si and solid solution Mn in the surface layer of steel cannot be sufficiently reduced.
- the average heating rate from 40 to t in the heating zone furnace is less than 1 O ⁇ Z s, a tight oxide scale is generated and it is difficult to reduce the average heating rate.
- the speed should be at least 10 ° CZ s. If it is less than 40, oxidation hardly accelerates.
- the heating rate below 400 is not limited. In this way, rapid heating in the heating zone not only improves the plateability, but also refines the strength of the steel sheet to reduce nano-hardness variation and improve the hole expansion characteristics. .
- the dew point of the heating zone is preferably more than 0 and 0 2 concentration over 1% 0.1 are preferred.
- the average heating rate from the reduction zone entry side to the maximum temperature is 0.1 to 1 OCs, and the temperature is heated to the maximum temperature 75 or higher and held for 30 seconds or longer.
- Heating at an average heating temperature rate from the reduction zone entry side to the maximum temperature of 0.1 to 10 / s If the average heating rate from the reduction zone entry side to the maximum temperature is less than 0.1 ltZs, the threading speed is reduced. Productivity is inferior because it is necessary to do this. Moreover, when the average heating rate is 1 Ot / s or more, oxygen in the iron scale scale reacts with hydrogen in the reduction zone in the reduction zone to become H 2 0, and Fe-based oxidation of the surface layer The scale is consumed in the reduction reaction, and the amount of oxygen that diffuses from the surface layer of the base metal into the iron and oxidizes Si, Mn, etc. decreases.
- the reduction zone preferably contains 1 to 100% of H 2 in order to reduce the surface.
- the T S X elongation will not improve. This is thought to be due to insufficient reduction of strain after cold rolling.
- the upper limit of the heating temperature and the upper limit of the holding time are not stipulated, but heating over 95 O: or heating or holding for 600 s or more will saturate the effect and lead to increased costs, so the heating temperature is less than 950 and the holding time is 600 Less than s is preferable.
- the steel sheet heated in the heating zone is cooled to less than 350 at an average cooling rate of 75 to 10 and ⁇ s or more. If the average cooling rate is less than 1 OtZs, pearlite is generated in the steel sheet, and the total area of ferrite, tempered martensite, bainite, and tempered bait cannot be increased to 90% or more, and TS X elongation and TS X hole expansion rate does not improve. The faster the cooling rate, the more easily a harder low-temperature transformation phase is generated. In the case of the present invention, tempering as much as possible Therefore, it is preferable to cool at an average cooling rate of 3 O tZ s or more, and an average cooling rate of 100 ° C / s or more is more preferable. . On the other hand, if it exceeds 50 O ⁇ / s, the shape of the copper plate deteriorates, and it becomes very difficult to control the proper amount of adhesion for melting and to ensure uniformity over the entire length of the plate. I like it.
- Cooling temperature conditions are one of the most important points in the present invention. If the temperature reached after cooling exceeds 35 Ot, martensite and residual austenite are generated in the final structure after melting and the residual austenite exceeds 10%, and the T S X hole expansion rate is significantly reduced. For this reason, the cooling ultimate temperature is 3500, which is the following.
- the cooling arrival temperature is preferably 2 200 or less, but the effect is saturated at room temperature or less.
- the time from cooling to the start of reheating is not specified because it does not affect the material. Although it is preferable that the time from the cooling to the start of reheating is shorter, it is preferable because the cost is low. However, after the cooling is completed, the coil may be scraped off and then passed through the mating line again to be heated. In that case, pickling and washing may be performed to remove scales on the second surface of the copper plate before plating.
- the heating is more preferably less than 500 ° C.
- the heating is preferably performed from a temperature before heating to a higher temperature, and it is preferable that the temperature increase is 20 or more, more preferably 25 or more.
- the holding time after heating is less than 1 s, the T S X hole expansion rate will not improve, so it will be 1 s or more.
- the effect is saturated even when the holding time is 6 00 s or more, and from the viewpoint of the characteristics, the holding time is preferably 10 s to 30 s.
- Hot dip galvanizing can be performed by infiltrating into a normal plating bath.
- the alloying treatment of the plating is performed after the molten dumbbell is attached, after being immersed in the plating bath, it is heated to 490 to 550 and held for 1 s to 30 s.
- the slab obtained by melting steel (A ⁇ T) with chemical composition shown in Table 1 by vacuum melting is hot rolled at a finish rolling temperature of 900 to form a hot-rolled copper sheet, which is then pickled and cooled.
- a cold rolled steel sheet having a thickness of 1.6 mm was obtained by cold rolling at a hot rolling rate of 50%.
- This cold-rolled steel sheet was annealed under the conditions shown in Table 2, and then galvanized at 460 and 10 se at 480-580. Alloying treatment was performed by heating, and cooling was performed with l OtZs.
- the plating adhesion amount was 35 to 45 g m 2 in all cases.
- the plating adhesion was evaluated about the obtained plated steel plate. Alloyed (GA) adhesive steel plate is bent 90 ° when the bent part is peeled off with cello tape (registered trademark), and the amount of peeling per unit length is measured by fluorescent X-rays and the Zn count is measured. Based on the following criteria, those with ranks 1 and 2 were evaluated as good ( ⁇ , ⁇ ), and those with 3 or more were evaluated as bad.
- the cross-sectional structure of the steel sheet was revealed with a 3% nital solution, and the position of the plate thickness 14 (position at a depth corresponding to one-fourth of the plate thickness from the surface) was measured.
- the ferrite phase area ratio was quantified from the photographed structure photograph (magnification of the structure was performed using image processing software such as Photo hop manufactured by Adobe, Inc.). Can be)
- the total area ratio of martensite and residual austenite can be determined by taking SEM photographs at an appropriate magnification of 1000 to 3000 times according to the fineness of the tissue and visually confirming that carbides other than ferrite are not precipitated. The determined part was quantified.
- Tempered martensite, tempered bait, and bainite shall be parts other than ferrite, martensite, residual austenite, and pearlite, and the total area ratio of tempered martensite, tempered bait, and bainite Was quantified. Tissue quantification can be performed using the above image processing software.
- Tensile properties were measured using a J I S 5 test piece according to J I S Z 2241.
- TS tensile strength
- T.E 1 total elongation
- the hole expansion test was conducted in accordance with the iron standard J FST 1001, and the average value of three tests was obtained for each sample condition.
- Nano hardness is measured from the surface at a thickness of 14 (position at a depth corresponding to one-fourth of the thickness from the surface).
- Hy si 1; the use Ite 3-5;! ⁇ was measured 49 to 56 points on 7-point X 7 ⁇ 8 points in 1 between the septum.
- the standard deviation ⁇ was obtained from the above equation (1) for ⁇ pieces of hardness data X.
- the depth of the base steel sheet side is 0.5 m from just above the TEM-EDS base metal interface.
- point analysis of Si and Mn was performed on the part without precipitates. Measurement of any 10 points The average value was taken as the evaluation value of the solid solution amount.
- the chemical composition (S i, Mn) shown in Table 1 was used as the average composition of the base material, and the chemical composition shown in Table 1 for the solid solution (average value) obtained above. The ratio to the value was determined and this ratio is listed in Table 3.
- the high-strength hot-dip galvanized steel sheet of the present invention can be used as a high-strength hot-dip galvanized steel sheet used for parts that are required to be thin and have corrosion resistance in the industrial fields such as automobiles and electricity.
- the method for producing a high-strength hot-dip galvanized steel sheet according to the present invention can be used as a method for producing the high-strength hot-dip galvanized steel sheet.
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
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EP08722826.8A EP2128295B1 (en) | 2007-03-22 | 2008-03-18 | High-strength hot dip zinc plated steel sheet having excellent moldability, and method for production thereof |
KR1020097019512A KR101132993B1 (ko) | 2007-03-22 | 2008-03-18 | 성형성이 우수한 고강도 용융 아연 도금 강판 및 그 제조 방법 |
US12/532,452 US8241759B2 (en) | 2007-03-22 | 2008-03-18 | Zinc-plated high-tension steel sheet excellent in press formability |
CN2008800092970A CN101641456B (zh) | 2007-03-22 | 2008-03-18 | 成形性优良的高强度热镀锌钢板及其制造方法 |
CA2679886A CA2679886C (en) | 2007-03-22 | 2008-03-18 | Zinc-plated high tension steel sheet excellent in press formability and method for production thereof |
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JP2007-074656 | 2007-03-22 | ||
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JP2008020772A JP5223360B2 (ja) | 2007-03-22 | 2008-01-31 | 成形性に優れた高強度溶融亜鉛めっき鋼板およびその製造方法 |
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JP (1) | JP5223360B2 (ja) |
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- 2008-03-18 CA CA2679886A patent/CA2679886C/en not_active Expired - Fee Related
- 2008-03-18 EP EP08722826.8A patent/EP2128295B1/en active Active
- 2008-03-18 KR KR1020097019512A patent/KR101132993B1/ko active IP Right Grant
- 2008-03-18 CN CN2008800092970A patent/CN101641456B/zh active Active
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Cited By (16)
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EP2407568A4 (en) * | 2009-03-10 | 2017-05-17 | JFE Steel Corporation | High-strength hot-dip galvanized steel sheet having excellent formability and method for producing same |
EP2436794B1 (en) | 2009-05-29 | 2019-04-03 | Kabushiki Kaisha Kobe Seiko Sho | High strength steel sheet having excellent hydrogen embrittlement resistance |
EP2460897A4 (en) * | 2009-07-29 | 2017-07-12 | JFE Steel Corporation | Process for production of high-strength cold-rolled steel sheet having excellent chemical conversion processability |
JP2013087314A (ja) * | 2011-10-14 | 2013-05-13 | Nippon Steel & Sumitomo Metal Corp | めっき密着性に優れた高強度合金化溶融亜鉛めっき鋼板とその製造方法 |
US9725795B2 (en) | 2012-12-25 | 2017-08-08 | Nippon Steel & Sumitomo Metal Corporation | Galvannealed steel sheet and method of manufacturing the same |
WO2016125461A1 (ja) * | 2015-02-03 | 2016-08-11 | Jfeスチール株式会社 | 高強度鋼板およびその製造方法 |
WO2016125462A1 (ja) * | 2015-02-03 | 2016-08-11 | Jfeスチール株式会社 | 高強度鋼板およびその製造方法 |
WO2016125463A1 (ja) * | 2015-02-03 | 2016-08-11 | Jfeスチール株式会社 | 高強度鋼板およびその製造方法 |
JP2016141857A (ja) * | 2015-02-03 | 2016-08-08 | Jfeスチール株式会社 | 高強度鋼板、高強度めっき鋼板、高強度溶融亜鉛めっき鋼板および高強度合金化溶融亜鉛めっき鋼板、並びにそれらの製造方法 |
JP2016141858A (ja) * | 2015-02-03 | 2016-08-08 | Jfeスチール株式会社 | 高強度鋼板、高強度めっき鋼板、高強度溶融亜鉛めっき鋼板および高強度合金化溶融亜鉛めっき鋼板、並びにそれらの製造方法 |
JP2016141859A (ja) * | 2015-02-03 | 2016-08-08 | Jfeスチール株式会社 | 高強度鋼板、高強度めっき鋼板、高強度溶融亜鉛めっき鋼板および高強度合金化溶融亜鉛めっき鋼板、並びにそれらの製造方法 |
US10472697B2 (en) | 2015-02-03 | 2019-11-12 | Jfe Steel Corporation | High-strength steel sheet and production method therefor |
US10934600B2 (en) | 2015-02-03 | 2021-03-02 | Jfe Steel Corporation | High-strength steel sheet and production method therefor |
US11035019B2 (en) | 2015-02-03 | 2021-06-15 | Jfe Steel Corporation | High-strength steel sheet and production method therefor |
JP7367893B1 (ja) * | 2022-12-08 | 2023-10-24 | Jfeスチール株式会社 | 高強度鋼板、高強度鋼板を用いてなる部材、部材からなる自動車の骨格構造部品用又は自動車の補強部品、ならびに高強度鋼板及び部材の製造方法 |
WO2024122037A1 (ja) * | 2022-12-08 | 2024-06-13 | Jfeスチール株式会社 | 高強度鋼板、高強度鋼板を用いてなる部材、部材からなる自動車の骨格構造部品用又は自動車の補強部品、ならびに高強度鋼板及び部材の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
CN101641456B (zh) | 2011-10-12 |
CA2679886C (en) | 2012-06-05 |
EP2128295A4 (en) | 2014-01-22 |
CN101641456A (zh) | 2010-02-03 |
CA2679886A1 (en) | 2008-10-16 |
EP2128295B1 (en) | 2015-07-15 |
EP2128295A1 (en) | 2009-12-02 |
TW200907074A (en) | 2009-02-16 |
JP2008266778A (ja) | 2008-11-06 |
KR20090115873A (ko) | 2009-11-09 |
US20100104891A1 (en) | 2010-04-29 |
US8241759B2 (en) | 2012-08-14 |
TWI366606B (en) | 2012-06-21 |
KR101132993B1 (ko) | 2012-04-09 |
JP5223360B2 (ja) | 2013-06-26 |
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