WO2008102509A1 - 水素精製方法、水素分離膜、及び水素精製装置 - Google Patents

水素精製方法、水素分離膜、及び水素精製装置 Download PDF

Info

Publication number
WO2008102509A1
WO2008102509A1 PCT/JP2007/074302 JP2007074302W WO2008102509A1 WO 2008102509 A1 WO2008102509 A1 WO 2008102509A1 JP 2007074302 W JP2007074302 W JP 2007074302W WO 2008102509 A1 WO2008102509 A1 WO 2008102509A1
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen
separation membrane
hydrogen purification
purification apparatus
membrane
Prior art date
Application number
PCT/JP2007/074302
Other languages
English (en)
French (fr)
Inventor
Eiji Okada
Jun Yoshihara
Futoshi Ikoma
Noboru Takemasa
Tatsunori Tayama
Kenji Otsuka
Original Assignee
Mitsubishi Gas Chemical Company, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Gas Chemical Company, Inc. filed Critical Mitsubishi Gas Chemical Company, Inc.
Priority to US12/525,990 priority Critical patent/US20100313754A1/en
Priority to JP2009500073A priority patent/JP5229503B2/ja
Priority to KR1020097016659A priority patent/KR20090110897A/ko
Priority to EP07850788A priority patent/EP2128082A4/en
Publication of WO2008102509A1 publication Critical patent/WO2008102509A1/ja

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0044—Inorganic membrane manufacture by chemical reaction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0069—Inorganic membrane manufacture by deposition from the liquid phase, e.g. electrochemical deposition
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0072—Inorganic membrane manufacture by deposition from the gaseous phase, e.g. sputtering, CVD, PVD
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/022—Metals
    • B01D71/0223—Group 8, 9 or 10 metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
    • C01B3/505—Membranes containing palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/102—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/502—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702—Hydrocarbons
    • B01D2257/7022—Aliphatic hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/80—Water
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/06—Surface irregularities
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0244—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being an autothermal reforming step, e.g. secondary reforming processes
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405—Purification by membrane separation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/047—Composition of the impurity the impurity being carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/048—Composition of the impurity the impurity being an organic compound
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Electrochemistry (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

 水素以外に水、一酸化炭素、二酸化炭素、メタン、窒素の少なくともひとつの成分を１％以上含む水素含有ガスから、高い水素透過能を保持しながら高効率に水素を分離・精製する方法、これに用いる水素分離膜、及び水素精製装置を提供する。  パラジウム合金膜の表面にパラジウムの微粒子を付着させた水素分離膜を用いて、水、一酸化炭素、二酸化炭素、メタン及び窒素のうち少なくとも１つの成分を１％以上含む水素含有ガスから水素を分離・精製することを特徴とする水素精製方法、これに用いる水素分離膜、及び水素精製装置。
PCT/JP2007/074302 2007-02-19 2007-12-18 水素精製方法、水素分離膜、及び水素精製装置 WO2008102509A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US12/525,990 US20100313754A1 (en) 2007-02-19 2007-12-18 Hydrogen purification method, hydrogen separation membrane, and hydrogen purification apparatus
JP2009500073A JP5229503B2 (ja) 2007-02-19 2007-12-18 水素精製方法、水素分離膜、及び水素精製装置
KR1020097016659A KR20090110897A (ko) 2007-02-19 2007-12-18 수소 정제 방법, 수소 분리막 및 수소 정제 장치
EP07850788A EP2128082A4 (en) 2007-02-19 2007-12-18 HYDROGEN PURIFICATION METHOD, HYDROGEN SEPARATION MEMBRANE, AND HYDROGEN PURIFICATION APPARATUS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-037840 2007-02-19
JP2007037840 2007-02-19

Publications (1)

Publication Number Publication Date
WO2008102509A1 true WO2008102509A1 (ja) 2008-08-28

Family

ID=39709791

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/074302 WO2008102509A1 (ja) 2007-02-19 2007-12-18 水素精製方法、水素分離膜、及び水素精製装置

Country Status (7)

Country Link
US (1) US20100313754A1 (ja)
EP (1) EP2128082A4 (ja)
JP (1) JP5229503B2 (ja)
KR (1) KR20090110897A (ja)
CN (1) CN101610975A (ja)
TW (1) TW200844044A (ja)
WO (1) WO2008102509A1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103269768A (zh) * 2010-12-24 2013-08-28 株式会社新生能源研究 气体分离装置、膜反应器、制氢装置
JP2016533882A (ja) * 2013-08-14 2016-11-04 コモンウェルス サイエンティフィック アンド インダストリアル リサーチ オーガナイゼーション 選択的透過性の膜を利用するプロセス
JP2018062602A (ja) * 2016-10-14 2018-04-19 日本特殊陶業株式会社 有機化合物の還元装置
JP2018145103A (ja) * 2017-03-01 2018-09-20 日本特殊陶業株式会社 水素添加方法、及び有機化合物の製造方法

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8721773B2 (en) * 2011-10-26 2014-05-13 Shell Oil Company Method for preparing a palladium-gold alloy gas separation membrane system
CN103373705B (zh) * 2012-04-17 2015-03-25 中国科学院工程热物理研究所 中低温太阳热能品位提升与co2一体化分离的方法和装置
KR101388649B1 (ko) * 2013-07-25 2014-04-24 한국에너지기술연구원 수소 분리막의 제조방법
US9616379B2 (en) 2013-07-25 2017-04-11 Korea Institute Of Energy Research Method for preparing hydrogen separation membrane and device for preparing hydrogen separation membrane
EP2896595A1 (en) * 2014-01-16 2015-07-22 Japan Pionics Co., Ltd. Palladium alloy membrane unit, storage structure thereof, and method of purifying hydrogen by using the same
WO2017210728A1 (en) * 2016-06-06 2017-12-14 Commonwealth Scientific And Industrial Research Organisation Method of forming a pd-au alloy layer on a substrate
KR101969200B1 (ko) * 2016-06-17 2019-04-16 한국화학연구원 메탄 함유 혼합가스를 이용한 수소 농축가스, 아세틸렌 농축가스, 에틸렌 농축가스 및 용접용 가스 제조방법 및 이의 장치
TWI674143B (zh) * 2018-06-21 2019-10-11 國立成功大學 一種促進氣體混合物之分離方法
US11339104B2 (en) * 2019-03-29 2022-05-24 Purdue Research Foundation Process for upgrading natural gas liquids from shale gas without front-end demethanizer
CN115806272A (zh) * 2021-09-16 2023-03-17 镫锋绿能科技股份有限公司 高分子膜结合钯膜的氢纯化系统以及氢纯化方法

Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62121616A (ja) 1985-11-21 1987-06-02 Ngk Insulators Ltd 水素ガス分離膜
JPS63171617A (ja) 1987-01-09 1988-07-15 Shozaburo Saito 水素選択透過性に優れた複合膜およびその製造法
JPS644216A (en) 1987-06-26 1989-01-09 Agency Ind Science Techn Production of thin membrane for separating gas
JPH01262924A (ja) 1988-04-12 1989-10-19 Natl Res Inst For Metals 水素分離膜
JPH02265631A (ja) 1989-04-05 1990-10-30 Natl Res Inst For Metals 水素分離用合金膜
JPH0352630A (ja) 1989-07-18 1991-03-06 Mitsubishi Heavy Ind Ltd 水素分離膜
JPH03288534A (ja) 1990-04-04 1991-12-18 Ebara Corp 無電解Ｐｄ―Ａｇ合金メッキ膜を有する水素分離膜及びその製造方法
JPH0698281B2 (ja) 1990-05-25 1994-12-07 科学技術庁金属材料技術研究所長 水素分離用合金膜
JPH10330992A (ja) 1997-06-04 1998-12-15 Mitsubishi Heavy Ind Ltd Ｐｄ合金箔の製造方法
JP2000042388A (ja) * 1998-07-30 2000-02-15 Mitsubishi Heavy Ind Ltd 水素精製膜及び水素製造方法
JP2002308605A (ja) * 2001-04-11 2002-10-23 Japan Pionics Co Ltd 水素ガスの精製方法
JP3373006B2 (ja) 1993-09-17 2003-02-04 エヌオーケー株式会社 水素分離膜の製造法
JP2003225544A (ja) * 2002-02-04 2003-08-12 Toyota Motor Corp 水素透過膜およびその製造方法
JP2004008966A (ja) 2002-06-07 2004-01-15 Mitsubishi Heavy Ind Ltd 水素分離膜、水素分離ユニット、水素分離膜の製造方法
JP2004113950A (ja) * 2002-09-26 2004-04-15 Kobe Steel Ltd 水素透過体とその製造方法

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6461408B2 (en) * 1995-11-06 2002-10-08 Robert E. Buxbaum Hydrogen generator
NO304220B1 (no) * 1996-04-30 1998-11-16 Sintef FremgangsmÕte til fremstilling av tynne metallmembraner
DE10135390A1 (de) * 2001-07-25 2003-02-20 Fraunhofer Ges Forschung Metallische Lösungs-Diffusions-Membran sowie Verfahren zur Herstellung
AU2004224371B2 (en) * 2003-03-21 2008-07-31 Worcester Polytechnic Institute Method for fabricating composite gas separation modules
US7749305B1 (en) * 2003-06-04 2010-07-06 Bossard Peter R Composite structure for high efficiency hydrogen separation containing preformed nano-particles in a bonded layer
JP4429318B2 (ja) * 2004-02-02 2010-03-10 ピーター・アール・ボサード 高効率で水素を分離するための複合構造を有する水素ガス分離器、ならびにその製造および使用方法
US7771520B1 (en) * 2006-09-06 2010-08-10 Bossard Peter R System and method for forming a membrane that is super-permeable to hydrogen

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62121616A (ja) 1985-11-21 1987-06-02 Ngk Insulators Ltd 水素ガス分離膜
JPS63171617A (ja) 1987-01-09 1988-07-15 Shozaburo Saito 水素選択透過性に優れた複合膜およびその製造法
JPS644216A (en) 1987-06-26 1989-01-09 Agency Ind Science Techn Production of thin membrane for separating gas
JPH01262924A (ja) 1988-04-12 1989-10-19 Natl Res Inst For Metals 水素分離膜
JPH02265631A (ja) 1989-04-05 1990-10-30 Natl Res Inst For Metals 水素分離用合金膜
JPH0352630A (ja) 1989-07-18 1991-03-06 Mitsubishi Heavy Ind Ltd 水素分離膜
JPH03288534A (ja) 1990-04-04 1991-12-18 Ebara Corp 無電解Ｐｄ―Ａｇ合金メッキ膜を有する水素分離膜及びその製造方法
JPH0698281B2 (ja) 1990-05-25 1994-12-07 科学技術庁金属材料技術研究所長 水素分離用合金膜
JP3373006B2 (ja) 1993-09-17 2003-02-04 エヌオーケー株式会社 水素分離膜の製造法
JPH10330992A (ja) 1997-06-04 1998-12-15 Mitsubishi Heavy Ind Ltd Ｐｄ合金箔の製造方法
JP2000042388A (ja) * 1998-07-30 2000-02-15 Mitsubishi Heavy Ind Ltd 水素精製膜及び水素製造方法
JP2002308605A (ja) * 2001-04-11 2002-10-23 Japan Pionics Co Ltd 水素ガスの精製方法
JP2003225544A (ja) * 2002-02-04 2003-08-12 Toyota Motor Corp 水素透過膜およびその製造方法
JP2004008966A (ja) 2002-06-07 2004-01-15 Mitsubishi Heavy Ind Ltd 水素分離膜、水素分離ユニット、水素分離膜の製造方法
JP2004113950A (ja) * 2002-09-26 2004-04-15 Kobe Steel Ltd 水素透過体とその製造方法

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
26TH GRAND MEETING OF THE HYDROGEN ENERGY ASSOCIATION OF JAPAN, pages 117 - 120
See also references of EP2128082A4

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103269768A (zh) * 2010-12-24 2013-08-28 株式会社新生能源研究 气体分离装置、膜反应器、制氢装置
CN103269768B (zh) * 2010-12-24 2015-05-13 株式会社新生能源研究 气体分离装置、膜反应器、制氢装置
JP2016533882A (ja) * 2013-08-14 2016-11-04 コモンウェルス サイエンティフィック アンド インダストリアル リサーチ オーガナイゼーション 選択的透過性の膜を利用するプロセス
JP2018062602A (ja) * 2016-10-14 2018-04-19 日本特殊陶業株式会社 有機化合物の還元装置
JP2018145103A (ja) * 2017-03-01 2018-09-20 日本特殊陶業株式会社 水素添加方法、及び有機化合物の製造方法

Also Published As

Publication number Publication date
JP5229503B2 (ja) 2013-07-03
EP2128082A4 (en) 2011-09-07
CN101610975A (zh) 2009-12-23
KR20090110897A (ko) 2009-10-23
US20100313754A1 (en) 2010-12-16
TW200844044A (en) 2008-11-16
EP2128082A1 (en) 2009-12-02
JPWO2008102509A1 (ja) 2010-05-27

Similar Documents

Publication Publication Date Title
WO2008102509A1 (ja) 水素精製方法、水素分離膜、及び水素精製装置
MY140997A (en) Process for the removal of cos from a synthesis gas stream comprising h2s and cos
SG144835A1 (en) Purification of carbon dioxide
EP1762294A3 (en) Gas purification
WO2008127379A3 (en) Methods and systems of producing molecular hydrogen using a plasma system
WO2010014774A3 (en) Modular membrane reactor and process for carbon dioxide extraction
WO2010088054A3 (en) Hybrid carbon dioxide separation process and system
WO2004104160A8 (en) Methods, apparatuses, and reactors for gas separation
WO2009017054A1 (ja) 水素製造および二酸化炭素回収方法ならびに装置
WO2010037109A3 (en) Process for accelerated capture of carbon dioxide
WO2009010690A3 (fr) Procede de purification d'un gaz contenant du co2
WO2009010691A3 (fr) Procede de purification d'un gaz contenant du co2 par integration d'unite de purification par adsorption
MY147051A (en) Molecular sieve and membrane system to purify natural gas
WO2011149724A3 (en) Treatment of natural gas feeds
EP2404658A3 (en) Removal of NO2 by selective adsorption from oxyfuel derived flue gas
ZA200802365B (en) Process and apparatus for the purification of methane rich gas streams
PT1725320E (pt) Processo para a remoção de dióxido de carbono de correntes gasosas com baixas pressões parciais de dióxido de carbono
WO2012012129A3 (en) Flexible system to remove carbon dioxide from a feed natural gas
WO2009145851A3 (en) Systems and methods for removing impurities from a feed fluid
WO2007001417A3 (en) Systems and methods for air purificiation using supercritical water oxidation
SG155925A1 (en) Method for purifying and concentrating dinitrogen monoxide
PL2002877T3 (pl) Sposób oddzielania wodoru ze strumieni gazu za pomocą procesu adsorpcji pod zmiennym ciśnieniem
WO2007019515A3 (en) Method for enabling the provision of purified carbon dioxide
WO2012012647A3 (en) Denitrification and ph control using bio-electrochemical systems
WO2006012296A3 (en) Separation of water from a fischer-tropsch product

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200780051214.X

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07850788

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2009500073

Country of ref document: JP

Kind code of ref document: A

WWE Wipo information: entry into national phase

Ref document number: 12525990

Country of ref document: US

Ref document number: 2007850788

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 1020097016659

Country of ref document: KR

NENP Non-entry into the national phase

Ref country code: DE