WO2008084703A1 - ノンハロゲン難燃性樹脂組成物およびそれを用いた電線・ケーブル - Google Patents

ノンハロゲン難燃性樹脂組成物およびそれを用いた電線・ケーブル Download PDF

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WO2008084703A1
WO2008084703A1 PCT/JP2007/075056 JP2007075056W WO2008084703A1 WO 2008084703 A1 WO2008084703 A1 WO 2008084703A1 JP 2007075056 W JP2007075056 W JP 2007075056W WO 2008084703 A1 WO2008084703 A1 WO 2008084703A1
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flame retardant
mass
parts
resin composition
electric wire
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PCT/JP2007/075056
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English (en)
French (fr)
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Satoshi Hashimoto
Hiroshi Hayami
Tsunenori Morioka
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Sumitomo Electric Industries, Ltd.
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Priority to CN2007800495642A priority Critical patent/CN101578334B/zh
Priority to TW097100647A priority patent/TWI409322B/zh
Publication of WO2008084703A1 publication Critical patent/WO2008084703A1/ja

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C08L71/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08L71/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08L71/12—Polyphenylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D153/02—Vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D177/00—Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Coating compositions based on derivatives of such polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/303—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups H01B3/38 or H01B3/302
    • H01B3/305—Polyamides or polyesteramides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/42—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes polyesters; polyethers; polyacetals
    • H01B3/421—Polyesters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/42—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes polyesters; polyethers; polyacetals
    • H01B3/427—Polyethers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/442—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from aromatic vinyl compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00—Insulated conductors or cables characterised by their form
    • H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29—Protection against damage caused by extremes of temperature or by flame
    • H01B7/295—Protection against damage caused by extremes of temperature or by flame using material resistant to flame
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3477—Six-membered rings
    • C08K5/3492—Triazines
    • C08K5/34924—Triazines containing cyanurate groups; Tautomers thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Physics & Mathematics (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)
  • Insulated Conductors (AREA)

Abstract

　ハロゲン系難燃剤を含有することなく、ＰＶＣ電線と同等の難燃性を示し、かつ、機械的物性、耐熱性、耐加熱変形性などに優れた被覆層を形成することができると共に加熱巻き付け試験にも適合する難燃性樹脂組成物及びこの難燃性樹脂組成物を被覆層として用いた電線・ケーブルを提供する。本組成物は、樹脂成分１００質量部に対して窒素系難燃剤を５～７０質量部含有するノンハロゲン難燃性樹脂組成物であって、前記樹脂成分１００質量部中に、ポリアミド樹脂又はポリエステル樹脂又はこれらの混合物が２０～５０質量部、ポリフェニレンエーテル系樹脂２０～５０質量部、及びスチレン系エラストマー３０～６０質量部を含有する。
PCT/JP2007/075056 2007-01-09 2007-12-27 ノンハロゲン難燃性樹脂組成物およびそれを用いた電線・ケーブル WO2008084703A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2007800495642A CN101578334B (zh) 2007-01-09 2007-12-27 无卤阻燃树脂复合材料以及采用该复合材料的电线和电缆
TW097100647A TWI409322B (zh) 2007-01-09 2008-01-08 無鹵素難燃性樹脂組成物及使用它之電線／電纜

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JP2007-000891 2007-01-09
JP2007000891A JP5481770B2 (ja) 2007-01-09 2007-01-09 ノンハロゲン難燃性樹脂組成物およびそれを用いた電線・ケーブル

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JP (1) JP5481770B2 (ja)
KR (1) KR20090096714A (ja)
CN (1) CN101578334B (ja)
TW (1) TWI409322B (ja)
WO (1) WO2008084703A1 (ja)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102471558A (zh) * 2009-08-10 2012-05-23 矢崎总业株式会社 热塑性弹性体树脂组合物和连接器
CN102516742A (zh) * 2011-11-30 2012-06-27 中国蓝星（集团）股份有限公司 一种调节硬度的聚苯醚电缆料复合物及其制备方法
CN101928453B (zh) * 2009-06-26 2012-10-17 深圳市华力兴工程塑料有限公司 用于电线电缆的阻燃聚苯醚组合物及利用所述组合物制备阻燃聚苯醚树脂的方法
WO2012173190A1 (ja) 2011-06-14 2012-12-20 三菱レイヨン株式会社 光ファイバ被覆用組成物及び光ファイバケーブル
CN104051056A (zh) * 2014-05-30 2014-09-17 安徽三和电力技术有限公司 电网设备用绝缘材料
WO2014148609A1 (ja) * 2013-03-22 2014-09-25 三菱レイヨン株式会社 光ファイバケーブル及び移動媒体
US9162948B2 (en) 2008-05-15 2015-10-20 Mexichem Amanco Holding S.A. De C.V. Process for the preparation of 2, 3, 3, 3-tetrafluoropropene
CN109679266A (zh) * 2018-12-29 2019-04-26 无锡鑫宏业特塑线缆有限公司 低烟耐高温光伏电缆的制备工艺
CN113773631A (zh) * 2021-08-11 2021-12-10 江苏泰祥电线电缆有限公司 一种耐极寒电线电缆用辐照交联聚烯烃绝缘组合物及其制备方法

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JP5182580B2 (ja) * 2008-10-28 2013-04-17 住友電気工業株式会社 ハロゲンフリー難燃絶縁電線
JP5387944B2 (ja) * 2008-11-12 2014-01-15 住友電気工業株式会社 ハロゲンフリー難燃絶縁電線
CN101831144B (zh) * 2010-05-19 2011-12-21 广东生益科技股份有限公司 无卤环氧树脂组合物以及使用其制备的高柔性挠性覆铜板
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JP5631408B2 (ja) * 2010-10-08 2014-11-26 矢崎総業株式会社 耐熱電線用樹脂組成物及び耐熱電線
JP2013149425A (ja) * 2012-01-18 2013-08-01 Sumitomo Electric Ind Ltd ハロゲンフリー難燃絶縁電線
JP5494688B2 (ja) 2012-02-03 2014-05-21 住友電気工業株式会社 ハロゲンフリー難燃絶縁電線
JP6010352B2 (ja) 2012-06-07 2016-10-19 株式会社オートネットワーク技術研究所 硬化性増感剤、光硬化材料、硬化物及びワイヤーハーネス材料
CN102816405B (zh) * 2012-08-30 2014-12-24 宁波聚泰新材料科技有限公司 一种低烟无卤阻燃热塑性弹性体及其制备方法
CN104200903B (zh) * 2014-08-19 2017-04-05 安徽蒙特尔电缆集团有限公司 一种耐撕裂耐拉伸高效阻燃电缆
JP6756690B2 (ja) * 2017-11-07 2020-09-16 日立金属株式会社 絶縁電線
CN110626028B (zh) * 2019-09-27 2021-07-16 厦门长塑实业有限公司 一种耐高温阻燃聚酰胺薄膜及其制备方法

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JP2007197619A (ja) * 2006-01-30 2007-08-09 Sumitomo Electric Ind Ltd ノンハロゲン難燃性樹脂組成物およびそれを用いた電線・ケーブル

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9162948B2 (en) 2008-05-15 2015-10-20 Mexichem Amanco Holding S.A. De C.V. Process for the preparation of 2, 3, 3, 3-tetrafluoropropene
US11267772B2 (en) 2008-05-15 2022-03-08 Mexichem Amanco Holding S.A. De C.V. Process for the preparation of 2,3,3,3-tetrafluoropropene
US10683248B2 (en) 2008-05-15 2020-06-16 Mexichem Amanco Holding S.A. De C.V. Process for the preparation of 2,3,3,3-tetrafluoropropene
US9957210B2 (en) 2008-05-15 2018-05-01 Mexichem Amanco Holdings S.A. De C.V. Process for the preparation of 2,3,3,3-tetrafluoropropene
CN101928453B (zh) * 2009-06-26 2012-10-17 深圳市华力兴工程塑料有限公司 用于电线电缆的阻燃聚苯醚组合物及利用所述组合物制备阻燃聚苯醚树脂的方法
CN102471558A (zh) * 2009-08-10 2012-05-23 矢崎总业株式会社 热塑性弹性体树脂组合物和连接器
WO2012173190A1 (ja) 2011-06-14 2012-12-20 三菱レイヨン株式会社 光ファイバ被覆用組成物及び光ファイバケーブル
CN102516742B (zh) * 2011-11-30 2013-12-11 中国蓝星（集团）股份有限公司 一种调节硬度的聚苯醚电缆料复合物及其制备方法
CN102516742A (zh) * 2011-11-30 2012-06-27 中国蓝星（集团）股份有限公司 一种调节硬度的聚苯醚电缆料复合物及其制备方法
WO2014148609A1 (ja) * 2013-03-22 2014-09-25 三菱レイヨン株式会社 光ファイバケーブル及び移動媒体
JPWO2014148609A1 (ja) * 2013-03-22 2017-02-16 三菱レイヨン株式会社 光ファイバケーブル及び移動媒体
CN104051056A (zh) * 2014-05-30 2014-09-17 安徽三和电力技术有限公司 电网设备用绝缘材料
CN109679266A (zh) * 2018-12-29 2019-04-26 无锡鑫宏业特塑线缆有限公司 低烟耐高温光伏电缆的制备工艺
CN113773631A (zh) * 2021-08-11 2021-12-10 江苏泰祥电线电缆有限公司 一种耐极寒电线电缆用辐照交联聚烯烃绝缘组合物及其制备方法

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Publication number Publication date
TWI409322B (zh) 2013-09-21
JP2008169234A (ja) 2008-07-24
KR20090096714A (ko) 2009-09-14
CN101578334B (zh) 2011-05-18
CN101578334A (zh) 2009-11-11
JP5481770B2 (ja) 2014-04-23
TW200838993A (en) 2008-10-01

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