WO2008081638A1 - α－オレフィン低重合体の製造方法 - Google Patents

α－オレフィン低重合体の製造方法 Download PDF

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Publication number
WO2008081638A1
WO2008081638A1 PCT/JP2007/070572 JP2007070572W WO2008081638A1 WO 2008081638 A1 WO2008081638 A1 WO 2008081638A1 JP 2007070572 W JP2007070572 W JP 2007070572W WO 2008081638 A1 WO2008081638 A1 WO 2008081638A1
Authority
WO
WIPO (PCT)
Prior art keywords
olefin
reactor
gas
inert gas
compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2007/070572
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
Hiroki Emoto
Kei Yoshizuru
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Priority to BRPI0719595-8A priority Critical patent/BRPI0719595B1/pt
Priority to EP07830306A priority patent/EP2098542A4/en
Priority to EA200970640A priority patent/EA024462B1/ru
Priority to CN2007800450285A priority patent/CN101547941B/zh
Priority to US12/520,096 priority patent/US9421534B2/en
Priority to CA2672385A priority patent/CA2672385C/en
Publication of WO2008081638A1 publication Critical patent/WO2008081638A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10—Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12—Olefin polymerisation or copolymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)
  • Polymerization Catalysts (AREA)
PCT/JP2007/070572 2006-12-28 2007-10-22 α－オレフィン低重合体の製造方法 Ceased WO2008081638A1 (ja)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BRPI0719595-8A BRPI0719595B1 (pt) 2006-12-28 2007-10-22 METHOD FOR PRODUCING POLYMERS OF LOWER α-OLEFINE
EP07830306A EP2098542A4 (en) 2006-12-28 2007-10-22 PROCESS FOR THE PRODUCTION OF LOW MOLECULAR WEIGHT POLYMER POLYMERS
EA200970640A EA024462B1 (ru) 2006-12-28 2007-10-22 СПОСОБ ПОЛУЧЕНИЯ НИЗКОМОЛЕКУЛЯРНОГО ПОЛИМЕРА α-ОЛЕФИНА
CN2007800450285A CN101547941B (zh) 2006-12-28 2007-10-22 α-烯烃低聚物的制造方法
US12/520,096 US9421534B2 (en) 2006-12-28 2007-10-22 Production method of α-olefin low polymer
CA2672385A CA2672385C (en) 2006-12-28 2007-10-22 Process for production of .alpha.-olefin low polymers using chromium catalyst

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006354541 2006-12-28
JP2006-354541 2006-12-28

Publications (1)

Publication Number Publication Date
WO2008081638A1 true WO2008081638A1 (ja) 2008-07-10

Family

ID=39588323

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/070572 Ceased WO2008081638A1 (ja) 2006-12-28 2007-10-22 α－オレフィン低重合体の製造方法

Country Status (8)

Country Link
US (1) US9421534B2 (https=)
EP (1) EP2098542A4 (https=)
JP (2) JP5444615B2 (https=)
CN (1) CN101547941B (https=)
BR (1) BRPI0719595B1 (https=)
CA (1) CA2672385C (https=)
EA (1) EA024462B1 (https=)
WO (1) WO2008081638A1 (https=)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2672385C (en) 2006-12-28 2014-10-14 Mitsubishi Chemical Corporation Process for production of .alpha.-olefin low polymers using chromium catalyst
ES2371218T3 (es) * 2009-04-09 2011-12-28 Saudi Basic Industries Corporation Composición de catalizador y procedimiento para la oligomerización de etileno.
CN104926589A (zh) * 2010-03-26 2015-09-23 三菱化学株式会社 α-烯烃低聚物的制造方法
JP5793899B2 (ja) * 2011-03-09 2015-10-14 三菱化学株式会社 １−ヘキセンの製造方法
JP2013231015A (ja) * 2012-05-02 2013-11-14 Idemitsu Kosan Co Ltd オレフィンオリゴマーの製造方法
FR2992962B1 (fr) * 2012-07-04 2015-06-26 Axens Procede de separation de l'hexene-1 a partir d'un melange de produits issus d'une zone de trimerisation de l'ethylene
JP6459587B2 (ja) * 2014-02-25 2019-01-30 三菱ケミカル株式会社 α−オレフィン低重合体の製造方法
JP6733252B2 (ja) * 2015-03-27 2020-07-29 三菱ケミカル株式会社 α−オレフィン低重合体の製造方法
EP3313901B1 (en) * 2015-06-23 2019-04-10 SABIC Global Technologies B.V. Polymerisation of ethylene in the presence of a silylchromate based catalyst
WO2020114745A1 (en) 2018-12-04 2020-06-11 Exxonmobil Chemical Patents Inc. Methods for separating linear alpha olefins from combined product streams
KR102732601B1 (ko) * 2021-01-18 2024-11-19 주식회사 엘지화학 올리고머 제조방법

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0710788A (ja) * 1993-06-21 1995-01-13 Nippon Gosei Arco-Le Kk エチレンの回収方法
JPH0760048A (ja) * 1993-08-26 1995-03-07 Mitsubishi Petrochem Eng Co Ltd 酸化エチレン製造プラント排ガスからのエチレンの回収法
JPH07324047A (ja) * 1994-05-31 1995-12-12 Nippon Gosei Arco-Le Kk エチレン水和反応における不純エチレン流の処理方法
JPH08239419A (ja) 1995-03-02 1996-09-17 Mitsubishi Chem Corp α−オレフイン低重合体の製造方法
JPH1045833A (ja) * 1996-07-30 1998-02-17 Mitsubishi Chem Corp α−オレフイン低重合体の製造方法
JPH10101724A (ja) * 1996-08-08 1998-04-21 Mitsubishi Chem Corp α−オレフイン低重合体の製造方法
JPH1160511A (ja) 1997-08-25 1999-03-02 Mitsubishi Chem Corp α−オレフィン低重合体の製造方法
JPH1171411A (ja) * 1997-06-26 1999-03-16 Mitsui Chem Inc プロピレンの重合方法
JP2002256007A (ja) * 2000-12-26 2002-09-11 Idemitsu Petrochem Co Ltd α−オレフィン低重合体の製造方法
JP2002255863A (ja) * 2001-02-23 2002-09-11 Idemitsu Petrochem Co Ltd α−オレフィン低重合体の製造方法
JP2003064105A (ja) * 2001-08-28 2003-03-05 Idemitsu Petrochem Co Ltd エチレン低重合体の製造方法

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GB855120A (en) 1956-05-07 1960-11-30 Phillips Petroleum Co Method of supplying a catalyst to a reaction zone and apparatus therefor
US3250757A (en) * 1961-05-18 1966-05-10 Phillips Petroleum Co Method and apparatus for controlling feed to a polymerization reaction
US4434313A (en) * 1981-12-14 1984-02-28 Exxon Research And Engineering Co. Preparation of linear olefin products
US5198563A (en) * 1989-08-10 1993-03-30 Phillips Petroleum Company Chromium compounds and uses thereof
CA2110654C (en) * 1992-12-17 2006-03-21 Albert Rossi Dilute process for the polymerization of ethylene/alpha-olefin copolymer using metallocene catalyst systems
CA2134503C (en) * 1994-02-18 2001-04-10 Mark E. Lashier Olefin production
KR100414008B1 (ko) * 1995-03-02 2004-04-29 미쓰비시 가가꾸 가부시키가이샤 α-올레핀올리고머의제조방법
US5856612A (en) * 1996-02-02 1999-01-05 Mitsubishi Chemical Corporation Process for producing α-olefin oligomer
CA2241573A1 (en) 1997-06-26 1998-12-26 Hiroshi Nishikawa Process for propylene polymerization
CN1203925A (zh) * 1997-06-26 1999-01-06 三井化学株式会社 丙烯聚合的方法
US20020182124A1 (en) * 1997-10-14 2002-12-05 William M. Woodard Olefin production process
US6380451B1 (en) * 1999-12-29 2002-04-30 Phillips Petroleum Company Methods for restoring the heat transfer coefficient of an oligomerization reactor
GB0016895D0 (en) 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
US6593506B1 (en) * 2000-10-12 2003-07-15 Exxonmobil Chemical Patents Inc. Olefin recovery in a polyolefin production process
TWI239941B (en) 2000-12-26 2005-09-21 Idemitsu Petrochemical Co Process for producing ethylenic oligomer technical field
DE10211386A1 (de) 2002-03-14 2003-09-25 Basf Ag Verfahren zur Oligomerisierung von Olefinen unter Verwendung eines Cycloalkylalkyl-substituierten Triazacyclohexans
US7449048B2 (en) * 2002-03-29 2008-11-11 Mitsui Chemicals, Inc. Method of reusing exhaust gas in polymer production plant
ES2416314T3 (es) 2004-08-27 2013-07-31 Chevron Phillips Chemical Company Lp Procesos de producción de poliolefinas
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CA2672385C (en) 2006-12-28 2014-10-14 Mitsubishi Chemical Corporation Process for production of .alpha.-olefin low polymers using chromium catalyst

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0710788A (ja) * 1993-06-21 1995-01-13 Nippon Gosei Arco-Le Kk エチレンの回収方法
JPH0760048A (ja) * 1993-08-26 1995-03-07 Mitsubishi Petrochem Eng Co Ltd 酸化エチレン製造プラント排ガスからのエチレンの回収法
JPH07324047A (ja) * 1994-05-31 1995-12-12 Nippon Gosei Arco-Le Kk エチレン水和反応における不純エチレン流の処理方法
JPH08239419A (ja) 1995-03-02 1996-09-17 Mitsubishi Chem Corp α−オレフイン低重合体の製造方法
JPH1045833A (ja) * 1996-07-30 1998-02-17 Mitsubishi Chem Corp α−オレフイン低重合体の製造方法
JPH10101724A (ja) * 1996-08-08 1998-04-21 Mitsubishi Chem Corp α−オレフイン低重合体の製造方法
JPH1171411A (ja) * 1997-06-26 1999-03-16 Mitsui Chem Inc プロピレンの重合方法
JPH1160511A (ja) 1997-08-25 1999-03-02 Mitsubishi Chem Corp α−オレフィン低重合体の製造方法
JP2002256007A (ja) * 2000-12-26 2002-09-11 Idemitsu Petrochem Co Ltd α−オレフィン低重合体の製造方法
JP2002255863A (ja) * 2001-02-23 2002-09-11 Idemitsu Petrochem Co Ltd α−オレフィン低重合体の製造方法
JP2003064105A (ja) * 2001-08-28 2003-03-05 Idemitsu Petrochem Co Ltd エチレン低重合体の製造方法

Non-Patent Citations (1)

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Title
See also references of EP2098542A4 *

Also Published As

Publication number Publication date
CA2672385A1 (en) 2008-07-10
US20090326297A1 (en) 2009-12-31
JP5444615B2 (ja) 2014-03-19
BRPI0719595B1 (pt) 2017-12-26
BRPI0719595A2 (pt) 2013-12-17
US9421534B2 (en) 2016-08-23
EA024462B1 (ru) 2016-09-30
EP2098542A1 (en) 2009-09-09
CN101547941A (zh) 2009-09-30
EA200970640A1 (ru) 2010-02-26
CA2672385C (en) 2014-10-14
CN101547941B (zh) 2011-12-28
JP2009102363A (ja) 2009-05-14
JP2008179631A (ja) 2008-08-07
EP2098542A4 (en) 2011-03-09

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