WO2008071905A1 - Chip mounting - Google Patents

Chip mounting Download PDF

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Publication number
WO2008071905A1
WO2008071905A1 PCT/GB2007/004500 GB2007004500W WO2008071905A1 WO 2008071905 A1 WO2008071905 A1 WO 2008071905A1 GB 2007004500 W GB2007004500 W GB 2007004500W WO 2008071905 A1 WO2008071905 A1 WO 2008071905A1
Authority
WO
WIPO (PCT)
Prior art keywords
chip
buffer layers
solder
microns
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2007/004500
Other languages
English (en)
French (fr)
Other versions
WO2008071905B1 (en
Inventor
Simon Johathan Stacey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qualcomm Technologies International Ltd
Original Assignee
Cambridge Silicon Radio Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Cambridge Silicon Radio Ltd filed Critical Cambridge Silicon Radio Ltd
Priority to JP2009540834A priority Critical patent/JP5623080B2/ja
Priority to US12/518,262 priority patent/US9177885B2/en
Publication of WO2008071905A1 publication Critical patent/WO2008071905A1/en
Publication of WO2008071905B1 publication Critical patent/WO2008071905B1/en
Anticipated expiration legal-status Critical
Priority to US14/837,426 priority patent/US9659894B2/en
Ceased legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W20/00Interconnections in chips, wafers or substrates
    • H10W20/40Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W70/00Package substrates; Interposers; Redistribution layers [RDL]
    • H10W70/60Insulating or insulated package substrates; Interposers; Redistribution layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W74/00Encapsulations, e.g. protective coatings
    • H10W74/10Encapsulations, e.g. protective coatings characterised by their shape or disposition
    • H10W74/111Encapsulations, e.g. protective coatings characterised by their shape or disposition the semiconductor body being completely enclosed
    • H10W74/129Encapsulations, e.g. protective coatings characterised by their shape or disposition the semiconductor body being completely enclosed forming a chip-scale package [CSP]
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W74/00Encapsulations, e.g. protective coatings
    • H10W74/10Encapsulations, e.g. protective coatings characterised by their shape or disposition
    • H10W74/131Encapsulations, e.g. protective coatings characterised by their shape or disposition the semiconductor body being only partially enclosed
    • H10W74/147Encapsulations, e.g. protective coatings characterised by their shape or disposition the semiconductor body being only partially enclosed the encapsulations being multilayered
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W20/00Interconnections in chips, wafers or substrates
    • H10W20/40Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes
    • H10W20/45Interconnections external to wafers or substrates, e.g. back-end-of-line [BEOL] metallisations or vias connecting to gate electrodes characterised by their insulating parts
    • H10W20/48Insulating materials thereof
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W70/00Package substrates; Interposers; Redistribution layers [RDL]
    • H10W70/60Insulating or insulated package substrates; Interposers; Redistribution layers
    • H10W70/67Insulating or insulated package substrates; Interposers; Redistribution layers characterised by their insulating layers or insulating parts
    • H10W70/69Insulating materials thereof
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/071Connecting or disconnecting
    • H10W72/072Connecting or disconnecting of bump connectors
    • H10W72/07251Connecting or disconnecting of bump connectors characterised by changes in properties of the bump connectors during connecting
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/20Bump connectors, e.g. solder bumps or copper pillars; Dummy bumps; Thermal bumps
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/20Bump connectors, e.g. solder bumps or copper pillars; Dummy bumps; Thermal bumps
    • H10W72/241Dispositions, e.g. layouts
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/20Bump connectors, e.g. solder bumps or copper pillars; Dummy bumps; Thermal bumps
    • H10W72/241Dispositions, e.g. layouts
    • H10W72/247Dispositions of multiple bumps
    • H10W72/248Top-view layouts, e.g. mirror arrays
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/20Bump connectors, e.g. solder bumps or copper pillars; Dummy bumps; Thermal bumps
    • H10W72/251Materials
    • H10W72/252Materials comprising solid metals or solid metalloids, e.g. PbSn, Ag or Cu
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/20Bump connectors, e.g. solder bumps or copper pillars; Dummy bumps; Thermal bumps
    • H10W72/29Bond pads specially adapted therefor
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W72/00Interconnections or connectors in packages
    • H10W72/90Bond pads, in general
    • H10W72/941Dispositions of bond pads
    • H10W72/9415Dispositions of bond pads relative to the surface, e.g. recessed, protruding
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W74/00Encapsulations, e.g. protective coatings
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W74/00Encapsulations, e.g. protective coatings
    • H10W74/40Encapsulations, e.g. protective coatings characterised by their materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10WGENERIC PACKAGES, INTERCONNECTIONS, CONNECTORS OR OTHER CONSTRUCTIONAL DETAILS OF DEVICES COVERED BY CLASS H10
    • H10W90/00Package configurations
    • H10W90/701Package configurations characterised by the relative positions of pads or connectors relative to package parts
    • H10W90/721Package configurations characterised by the relative positions of pads or connectors relative to package parts of bump connectors
    • H10W90/724Package configurations characterised by the relative positions of pads or connectors relative to package parts of bump connectors between a chip and a stacked insulating package substrate, interposer or RDL

Definitions

  • the present invention relates to a technique for electrically connecting a printed circuit board to a chip defining one or more electronic devices.
  • WLCSP wafer-level chip scale packaging
  • This technique is characterised in that: (a) there is no pre-assembly of the chip on a substrate before mounting onto the printed circuit board; and (b) the chip is ready for surface mounting on a printed circuit board as soon as it is singulated from the wafer.
  • the area that the thus packaged chip occupies when mounted onto a printed circuit board is the size of the silicon die.
  • FIG. 1 One such interconnection between a chip or integrated circuit 6 and a printed circuit board 2 is shown in Figure 1 , where the solder ball is designated by reference numeral 4. Also shown in Figure 1 are the common locations 5 where cracks have been found to develop when the assembly is subject to impact testing, such as drop testing.
  • One aspect of the present invention provides a device comprising a chip including a substrate defining one or more electronic devices and a printed circuit board electrically connected to the chip via one or more solder elements sandwiched between the chip and the printed circuit board, wherein the chip is provided with one or more buffer layers between the substrate and the solder elements, said buffer layers having a Young's Modulus of 2.5GPa or less.
  • Said one or more buffer layers may have a total thickness of more than 3 microns, more preferably - especially but not exclusively in the case of a single buffer layer - in the range of 4 to 8 microns. Said one or more buffer layers may have a total thickness of more than 10 microns, more preferably - especially but not exclusively in the case of multiple buffer layers - in the range of 13 to 20 microns.
  • the chip may be provided with two of said buffer layers. There may then be a patterned conductive layer such as a redistribution layer sandwiched therebetween for electrically connecting said one or more solder elements to said one or more electronic devices.
  • a patterned conductive layer such as a redistribution layer sandwiched therebetween for electrically connecting said one or more solder elements to said one or more electronic devices.
  • only one of those buffer layers is uninterrupted between the entirety of each solder element and the substrate. That may be the one of the layers that lies between the patterned conductive layer and the substrate.
  • the other buffer layer may be interrupted under each solder element to allow the solder element to connect to the patterned conductive layer.
  • Each of said two buffer layers may have a thickness of more than 5 microns, more preferably in the range of about 6.5 microns to about 10 microns, and most preferably of about 7.5 microns.
  • the two buffer layers may have the same composition, or may be different.
  • the two buffer layers each have a Young's
  • the or each buffer layer may be located between each solder element and the substrate, preferably lying uninterruptedly between each solder element and the substrate. Such an uninterrupted buffer layer may conveniently be sandwiched between a patterned conductive layer such as a redistribution layer and the substrate. That buffer layer may have a thickness of more than 5 microns, more preferably in the range of about 6.5 microns to about 10 microns, and most preferably of about 7.5 microns. Preferably the buffer layer has a Young's Modulus of about 2 GPa.
  • the or each layer having a Young's modulus of about 2GPa could have a Young's modulus of 1.6 to 2.4GPa or from 1.7 to 2.3GPa or from 1.8 to 2.2GPa or from 1.9 to 2.1GPa.
  • the device may comprise an array of said solder elements spaced at a pitch of 0.5mm or less, or at a pitch of 0.4mm or less.
  • the one or more solder elements may be tin-based solder elements. They may have a composition including about 4% wt. silver, and about 0.5%wt. copper, although the invention is not limited to use with this composition and the advantages of the invention can be gained when other compositions are used.
  • the solder elements may conveniently be solder balls or solder bumps.
  • the substrate may be a semiconductor wafer.
  • a chip including a substrate defining one or more electronic devices and one or more solder elements located within the area of the chip and electrically connected to said one or more electronic devices, wherein the chip is provided with one or more buffer layers having a Young's Modulus of 2.5GPa or less between the substrate and the solder elements.
  • a device comprising a chip including a substrate defining one or more electronic devices and a printed circuit board electrically connected to the chip via one or more solder elements sandwiched between the chip and the printed circuit board, wherein the chip is provided with one or more buffer layers having a total thickness of more than 5 microns between the substrate and the solder elements.
  • a device comprising a chip including a substrate defining one or more electronic devices and one or more solder elements located within the area of the chip and electrically connected to said one or more electronic devices, wherein the chip is provided with one or more buffer layers having a total thickness of more than 5 microns between the substrate and the solder elements.
  • the total thickness of the buffer layer(s) may preferably be greater than 10 microns.
  • the total thickness of the buffer layer(s) in the zone directly between the substrate and the parts of the solder elements that most closely approach the substrate may preferably be less than 10 microns, e.g. around 7 to 8 microns.
  • a wireless communication device including a device or a chip as set out above. That may be a handheld-portable device such as a mobile phone.
  • Figure 2 illustrates a first WLCSP technique
  • Figure 3 illustrates the results of drop tests for embodiments of the present invention.
  • Figure 4 illustrates a second WLCSP technique.
  • a silicon wafer die 8 has a plurality of electronic devices defined therein. Aluminium pads 10 are then provided in contact with electrodes of the electronic devices. A passivation layer 12 is then provided over the entire area of the wafer die 8, and is then patterned to expose the aluminium pads 10. A first buffer layer 14 is then provided on the passivation layer 12 over the entire area of the wafer die 8, and is patterned to expose portions of the aluminium pads 10 exposed by the patterning of the passivation layer 12. A patterned conductive redistribution layer 16 is then provided on the first buffer layer 14 to provide lateral electrical connections between the locations of the aluminium pads 10 and the desired locations for the respective solder balls 22.
  • a second buffer layer 18 is then provided over the redistribution layer 16, and is patterned to expose portions of the redistribution layer at locations where it is desired to make contact to a solder ball 22.
  • Under-bump metallisation (UBM) 20 is carried out on the thus exposed locations of the redistribution layer 16. Solder balls 22 are then provided in contact with the under-bump metallisations 20.
  • the thus processed/packaged wafer is then cut into chips and each chip is mounted onto a respective printed circuit board in the manner shown in Figure 1 with the solder balls 22 providing the electrical connections between the chip and the printed circuit board.
  • the buffer layers 14, 18 have a Young's Modulus of 2.0 GPa and each have a thickness (t1 and t2) of 5 microns.
  • the buffer layers 14, 18 also have the same Young's Modulus of 2.0GPa and each have a thickness (t1 and t2) of 7.5 microns.
  • each of the buffer layers 14, 18 are provided by spin coating a polyimide precursor sold by HD Microsystems as HD-8820 at a spin speed of 1000-4000rprn and a spin time between 30 and 60 seconds. This is followed by hot plate baking at 123°C for 180 seconds. This is followed by selective exposure of those portions to be removed to reveal the aluminium pads (in the case of the first buffer layer 14) and the redistribution layer (in the case of the second buffer layer 18) at a fluence of 280-500mj/cm 2 , and development using 0.26N Tetra-Methyl Ammonium Hydroxide (TMAH) as a developer. The development step washes away the selectively irradiated portions of the buffer layer.
  • TMAH Tetra-Methyl Ammonium Hydroxide
  • each buffer layer is cured in a furnace in a nitrogen atmosphere at 32O 0 C.
  • the temperature of the furnace is ramped to 320 0 C followed by a period of around 1 hour at 32O 0 C.
  • Changing the final cure temperature and/or the length of time at which the buffer layer is maintained at the final cure temperature can be used to adjust the Young's Modulus of the resultant film.
  • the thicknesses stated above are the thicknesses after curing.
  • the polyimide precursor mentioned above comprises 30-40% polyamide, 45-55% gamma-butyrolactone, 1-10% propylene glycol monomethyl ether acetate, 1 to 5% organo silan compound(s) and 1 to 10% photoinitiator.
  • Figure 3 illustrates the results of a drop test for the first (triangle marker) and second (diamond marker) embodiments. Comparison results of the same drop test for the same construction as the first embodiment but using buffer layers 14, 18 having a Young's Modulus of 3.5GPa (square marker) are also shown. The line to 3.5GPa and thickness of 7.5 microns is a modelled extrapolation. Figure 3 shows how the drop test characteristic life is improved for the first embodiment compared to devices produced in an identical fashion except that the buffer layers 14, 18 have a Young's Modulus of 3.5GPa. Figure 3 also shows how the second embodiment exhibits yet improved drop test performance compared to the first embodiment.
  • solder balls were made from SAC405 (tin-based solder including 4%wt. silver and 0.5%wt. copper). It has been shown experimentally that this solder composition provides better results than other solder compositions in the first and second embodiments described above. However, other compositions may be used if desired.
  • the solder balls had a pitch P of 0.4mm, but it is expected that the same improvements would be exhibited for different pitches, such as 0.5mm and 0.3mm.
  • the buffer layer 14 is located directly between the solder ball 22 and the silicon wafer substrate 8. It is uninterrupted in the region where it underlies the solder ball 22.
  • This physical arrangement of the components promotes the effectiveness of the buffer layer 14 in improving crack resistance.
  • Such a physical arrangement can conveniently by achieved by using a redistribution layer as illustrated in figure 2 to allow a lateral offset between the solder pad 10 and the solder ball 22.
  • connection techniques such as bump-on-IO
  • a via then passes through the polymer layer 14 at a point laterally offset from the pad to connect the second redistribution layer to a redistribution layer analogous to layer 16.
  • the solder ball can then be formed over the pad, with the buffer layer 14 lying between the solder ball and the pad.
  • the pad instead of a second redistribution layer, the pad itself could be laterally extended. This arrangement is illustrated in figure 4, in which analogous components are numbered as in figure 2.
  • the layer 18 could have a higher Young's modulus than layer 14. In some embodiments the layer 18 could be omitted or could not act as a buffer layer.
  • the embodiments described above make use of solder balls. Instead of balls, solder bumps or other forms of discrete solder elements can be used.
  • the buffer layer 14 could be homogeneous or could be formed of a stack of sublayers. Any one or more of those layers could have Young's Modulus of 2.5GPa or less.
  • a Young's modulus of around 2.0GPa is especially advantageous for layer 14 because it provides beneficial results when the layer 14 has a thickness in the range from 5 to 10 microns, more preferably 7 to 8 microns. Outside that range it can become more difficult to form via holes through the layer 14 because the vias extend too far laterally or because it can be difficult to define a reliable contact through the via.
  • the invention is especially suitable for use with chips that are to be incorporated into mobile devices, particularly handheld-portable devices such as mobile phones. Such devices are typically subject to considerable shocks and can particularly benefit from improved shock resistance.
  • the chip conveniently implements mobile communication functionality, such as a radio transmitter and/or receiver.

Landscapes

  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Structures For Mounting Electric Components On Printed Circuit Boards (AREA)
  • Electric Connection Of Electric Components To Printed Circuits (AREA)
  • Wire Bonding (AREA)
  • Production Of Multi-Layered Print Wiring Board (AREA)
PCT/GB2007/004500 2006-12-13 2007-11-26 Chip mounting Ceased WO2008071905A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2009540834A JP5623080B2 (ja) 2006-12-13 2007-11-26 チップ実装
US12/518,262 US9177885B2 (en) 2006-12-13 2007-11-26 Chip mounting
US14/837,426 US9659894B2 (en) 2006-12-13 2015-08-27 Chip mounting

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0624888.4 2006-12-13
GB0624888A GB2444775B (en) 2006-12-13 2006-12-13 Chip mounting

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/518,262 A-371-Of-International US9177885B2 (en) 2006-12-13 2007-11-26 Chip mounting
US14/837,426 Continuation US9659894B2 (en) 2006-12-13 2015-08-27 Chip mounting

Publications (2)

Publication Number Publication Date
WO2008071905A1 true WO2008071905A1 (en) 2008-06-19
WO2008071905B1 WO2008071905B1 (en) 2008-08-21

Family

ID=37712074

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2007/004500 Ceased WO2008071905A1 (en) 2006-12-13 2007-11-26 Chip mounting

Country Status (5)

Country Link
US (2) US9177885B2 (https=)
JP (2) JP5623080B2 (https=)
GB (1) GB2444775B (https=)
TW (1) TWI475621B (https=)
WO (1) WO2008071905A1 (https=)

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GB2444775B (en) * 2006-12-13 2011-06-08 Cambridge Silicon Radio Ltd Chip mounting
GB2482894B (en) 2010-08-18 2014-11-12 Cambridge Silicon Radio Ltd Interconnection structure
US9935038B2 (en) 2012-04-11 2018-04-03 Taiwan Semiconductor Manufacturing Company Semiconductor device packages and methods
US11189538B2 (en) * 2018-09-28 2021-11-30 Taiwan Semiconductor Manufacturing Co., Ltd. Semiconductor structure with polyimide packaging and manufacturing method

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JP5623080B2 (ja) 2014-11-12
GB2444775B (en) 2011-06-08
TW200832577A (en) 2008-08-01
JP2010514148A (ja) 2010-04-30
JP2014112694A (ja) 2014-06-19
US20100013093A1 (en) 2010-01-21
GB0624888D0 (en) 2007-01-24
JP5806286B2 (ja) 2015-11-10
GB2444775A (en) 2008-06-18
WO2008071905B1 (en) 2008-08-21
US20160086907A1 (en) 2016-03-24
US9659894B2 (en) 2017-05-23
TWI475621B (zh) 2015-03-01

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