WO2008035554A1 - Nouveau composé complexe squarylium-métal, colorant et composition, toner de couleur, encre, support d'enregistrement optique, filtre de couleur et filtre avant pour dispositif d'affichage contenant le colorant - Google Patents
Nouveau composé complexe squarylium-métal, colorant et composition, toner de couleur, encre, support d'enregistrement optique, filtre de couleur et filtre avant pour dispositif d'affichage contenant le colorant Download PDFInfo
- Publication number
- WO2008035554A1 WO2008035554A1 PCT/JP2007/066879 JP2007066879W WO2008035554A1 WO 2008035554 A1 WO2008035554 A1 WO 2008035554A1 JP 2007066879 W JP2007066879 W JP 2007066879W WO 2008035554 A1 WO2008035554 A1 WO 2008035554A1
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- Prior art keywords
- group
- dye
- metal complex
- complex compound
- present
- Prior art date
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- -1 metal complex compound Chemical class 0.000 title claims abstract description 189
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- 230000003287 optical effect Effects 0.000 title claims abstract description 47
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- 125000001424 substituent group Chemical group 0.000 claims abstract description 44
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- 239000010949 copper Substances 0.000 claims description 20
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- 125000004429 atom Chemical group 0.000 claims description 17
- 125000000623 heterocyclic group Chemical group 0.000 claims description 16
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 13
- 229910052802 copper Inorganic materials 0.000 claims description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 9
- 239000002612 dispersion medium Substances 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 9
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Classifications
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- G03G9/0906—Organic dyes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B23/00—Methine or polymethine dyes, e.g. cyanine dyes
- C09B23/0066—Methine or polymethine dyes, e.g. cyanine dyes the polymethine chain being part of a carbocyclic ring,(e.g. benzene, naphtalene, cyclohexene, cyclobutenene-quadratic acid)
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B57/00—Other synthetic dyes of known constitution
- C09B57/007—Squaraine dyes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/41—Organic pigments; Organic dyes
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- G—PHYSICS
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- G02B5/00—Optical elements other than lenses
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- G02B5/223—Absorbing filters containing organic substances, e.g. dyes, inks or pigments
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- G—PHYSICS
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- G03G9/00—Developers
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- G03G9/08—Developers with toner particles
- G03G9/09—Colouring agents for toner particles
- G03G9/0906—Organic dyes
- G03G9/0924—Dyes characterised by specific substituents
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
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- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/252—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers
- G11B7/258—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers
- G11B7/259—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of layers other than recording layers of reflective layers based on silver
Definitions
- the present invention relates to a novel squarylium metal complex compound, a dye, and a composition containing the same
- Color toner, ink, optical recording medium, color filter, and front filter for display
- Colorants known as dyes and pigments include various dyes such as fiber dyes, resin and paint colorants, photographs, printing, photocopiers, printers, image forming materials, and color filter light absorbers. Widely used in applications.
- various image forming dyes for color hardcopy using inkjet, electrophotography, silver halide photography, thermal transfer, etc. have been proposed, and with the progress of electronics imaging, dyes for filters for solid-state image pickup tubes and color LCD TVs.
- Demand for dyes for optical recording media using semiconductor lasers and the like is increasing, and the field of dye use is expanding. As the use of these dyes expands, the demands on color material materials, especially fastness such as light resistance and chemical resistance, are becoming stricter year by year.
- the present inventors have developed a dye material having a squarylium skeleton.
- Squarium dyes have the advantage that they can be easily adjusted in hue due to the variety of molecular designs and have excellent molecular absorption characteristics.
- it is a useful dye material that exhibits good performance in terms of light resistance, heat resistance, moisture resistance, and the like.
- the squarylium compound has a squaric acid skeleton at the center of the molecule, and has a structure having a substituent composed of an aromatic compound on the carbon atom located on the diagonal line.
- Patent Document 4 discloses a squarylium metal complex structure represented by the following structure A.
- the squarylium compound used here is only a combination of 5-hydroxypyrazole and methylindoline, and the metal is only A1.
- Patent Document 5 discloses a squarylium metal complex represented by the following structure B and structure C.
- a chelate structure is formed between a coordination atom having a 5-membered ring active hydrogen bonded directly to an oxygen atom of a squaric acid skeleton and a squaric acid skeleton, and a metal. It is characteristic to take.
- the squarylium compound is characterized by having the same 6-membered ring and having a dialkylamino group at the P-position of the bond with the squaric acid skeleton. Although this mixture of squarylium compound and metal ion-containing compound shows good color tone, it still has insufficient light resistance, moisture resistance, and heat resistance, and development of a material with excellent fastness has been demanded. .
- Patent Document 1 Japanese Patent Laid-Open No. 2000-265077
- Patent Document 2 JP 2001-342364 A
- Patent Document 3 Japanese Unexamined Patent Publication No. 2000-159776
- Patent Document 4 Pamphlet of International Publication No. 02/50190
- Patent Document 5 International Publication No. 04/7447 Pamphlet
- the present invention has been made in view of the above circumstances, and an object of the present invention is to provide a novel lithium metal complex compound, which has a favorable hue in terms of color reproducibility in the visible range, and weather resistance. It is intended to provide a dye having good fastness such as storage stability, a composition containing the dye, an ink, a toner, an optical recording medium, a color filter, and a front filter for display. Means for solving the problem
- a squarylium metal complex compound having a partial structure represented by the following general formula (1) [0020] 1.
- M represents a metal atom.
- A represents an arbitrary organic group.
- the squarylium metal complex compound having a partial structure represented by the general formula (1) is a squarylium metal complex compound represented by the following general formula (2):
- X is a monodentate or bidentate subcoordination.
- P is an integer from 0 to 2.
- W represents a counter ion and q is an integer from 0 to 3.
- the squarylium metal complex compound having the partial structure represented by the general formula (1) or the squarylium metal complex compound represented by the general formula (2) is represented by the following general formula (3). 3. Said 1 or 2 which is a squarylium metal complex compound The squarylium metal complex compound.
- M represents a metal atom.! ⁇ Is a hydrogen atom or a substituent, A is an arbitrary organic group, and n is 2 or 3.
- the organic group A is an aryl group, a heterocyclic group, or the following general formula (1-A), The squarylium metal complex compound described in 1.
- A represents a 5-membered ring or a 6-membered ring
- 1 represents a hydrogen atom or a substituent.
- the metal atom M is one of copper, nickel, cobalt, aluminum or zinc!
- a composition comprising at least one dye described in 6 above and a dispersion medium.
- a toner comprising at least one dye described in 6 above.
- An ink comprising at least one dye described in 6 above.
- An optical recording medium comprising at least one dye described in 6 above.
- a color filter comprising at least one dye described in 6 above
- a front filter for a display comprising at least one dye described in 6 above.
- a novel squarylium metal complex compound could be provided.
- This compound is a dye having excellent spectral absorption characteristics, weather resistance, and storage stability, and also exhibits high weather resistance and storage stability even when used as a composition with a dispersant.
- Color toner, ink, optical recording Media, color filters and front filters for displays could be provided.
- the dye of the present invention relates to a squarylium metal complex compound having a partial structure represented by the general formula (1), which has an absorption maximum wavelength in a visible light region.
- the squarylium metal complex represented by the general formula (1) has a partial structure, and the general structure of the squarylium metal complex of the present invention is represented by the general formula (2) or the general formula (3).
- the effect that the squarylium metal complex compound of the present invention is more excellent in light resistance and storage stability than the squarylium compound is presumed that stability improvement due to metal chelate formation is one factor.
- the Chelate complexes are characterized by the fact that one ligand is coordinated to a metal ion by multiple coordination sites, and this chelate ring formation provides a thermodynamic and kinetic stabilization effect. . This is generally referred to as the chelate effect, and it is known that the bond energy of metal ligands is 10 to 10 times more stable than ordinary complexes that are not chelate complexes!
- the ratio of the metal and the ligand of the metal chelate complex to be generated can be controlled by using a squarylium compound having a specific structure as a ligand.
- a squarylium compound having a specific structure as a ligand.
- the specific structure means that the adjacent carbon atom of the carbon to which the squaric acid skeleton and the benzene ring are bonded has a hydroxyl group as a substituent as represented by the general formulas (1) to (3).
- the squarylium metal complex compound of the present invention is formed by the oxygen atom of the hydroxyl group and the oxygen atom of the squaric acid skeleton acting as a chelate coordination atom.
- the squarylium metal complex compound of the present invention a coloring matter, a composition using the same, a color toner, an ink, a color filter, and a display front filter will be described, but the present invention is not limited thereto.
- the squarylium metal complex compound in the present invention has a partial structure which is the essence of the invention by the following general formula (1), and the whole structure is represented by the following general formulas (2) and (3).
- M represents a metal atom and bonded to one oxygen atom of the squaric acid skeleton and an oxygen atom derived from a hydroxyl group that is one of the substituents of the benzene ring. It is characterized by forming a chelate ring.
- the metal atom M is not particularly limited as long as it forms a chelate structure with respect to the squarylium compound.
- a chelate structure means that a specific structure of a ligand (here, a squarylium compound) binds to a metal atom M at a plurality of coordination positions and forms a ring structure with the metal and the ligand. Represents that.
- the metal atom M for example, copper, nickel, cobalt, zinc, aluminum, beryllium, iron, silver, chromium, manganese, iridium, vanadium, titanium, norenium, molybdenum, tin, bismuth, osmium, magnesium, canoleum, strontium,
- it can be used for example, norlium, gallium, germanium, platinum, gold, mercury. wear.
- Periodic table 3 to 12 is preferably a group 12 and more preferably a metal ion contained in the periodic table 7 to 12 group.
- the valence is preferably a divalent or trivalent metal.
- manganese, iron, cobalt, nickel, copper, zinc, ruthenium, rhodium, palladium, silver, osmium, iridium or platinum are preferable, and copper, nickel, cobalt are particularly preferable in terms of handling. More preferably, it is selected from aluminum or zinc.
- R represents a substituent
- m represents an integer of 0 to 3.
- the substituent represented by R is not particularly limited, and examples thereof include an alkyl group (for example, a methyl group, an ethyl group, a propyl group, an isopropyl group, a tert butyl group, a pentyl group, a hexyl group, an octyl group, Dodecyl group, trifluoromethyl group, etc.), cycloalkyl group (eg, cyclopentyl group, cyclohexyl group, etc.), aryl group (eg, phenyl group, naphthyl group, etc.), isylamino group (eg, acetylamino group, benzoylamino group, etc.) Group), alkylthio group (for example, methylthio group, ethylthio group, etc.), arylthio group (for example,
- substituents for R include alkyl group, cycloalkyl group, alkenyl group, halogen atom, heterocyclic group, alkylsulfonyl group, arylsulfonyl group, phosphono group, acyl group, sulfonamido group, cyano group, alkoxy group, aryloxy group.
- ⁇ ⁇ represents a hydrogen atom or a substituent, and specific examples thereof include the same as R.
- Preferred substituents for ⁇ ⁇ are alkyl groups, A alkenyl group, an aryleno group, a heteroaryl group, an alkoxy group, an amino group, an amide group, an acetyl group, a cyano group, a nitro group, a hydroxyl group and the like are preferable.
- at least one is preferably a substituent having a long-chain alkyl.
- A represents an arbitrary organic group, and examples of the organic group include the same groups as the substituents represented by R described above, preferably an aryl group and a heterocyclic group. Further, from the viewpoint of fastness, more preferred are aryl groups, heterocyclic groups, and substituents represented by the above general formula (1 A). Further, as the aryl group, it is more preferable to have at least one of an alkyl group, an acylamino group, an amino group, a sulfonamide group, and a hydroxyl group as a substituent. Is more preferable.
- A1 represents a 5-membered ring or a 6-membered ring, and the 5-membered ring represented by A1 includes a virazolidinedione ring
- Examples of the 6-membered ring represented by A1 include a cyclohexagen ring (1,3 cyclohexagen ring, 1,4-cyclohexagen ring), a dihydropyridine ring (1,4-dihydropyridine ring, 3,4-dihydropyrazine ring), 4H-pyran ring, 4H-thiopyran ring, pyridone ring (eg pyridine-2 (3H) -one ring), pyridinethione ring (eg pyridine-2 (3H) — H ON ring), pyridinedione ring (eg, pyridine-2, 4 (3H, 5H) -dione ring), barbyl acid ring, thiobarbituric acid ring, oxazine ring, thiazine ring, dihydropyrimidinedione ring (for example, Dihydropyrimidine 1,4,6 (1H, 5H) -d
- [0053] 1 represents a hydrogen atom or a substituent, and the substituent is a group having the same meaning as the substituent represented by R described above. 1 is preferably a hydrogen atom, an alkyl group or a halogen atom,
- a hydrogen atom, an alkyl group, a halogen atom or an aryl group More preferably a hydrogen atom, an alkyl group, a halogen atom or an aryl group, more preferably a hydrogen atom or an alkyl group, still more preferably a methyl group or an ethyl group, and most preferably a hydrogen atom.
- the general formula (1) is a partial structure in the metal complex of the present invention.
- the above general formula (2) or (3) represents the overall structure of the compound in the present invention, and in order to obtain the effects described in the present invention, the squarylium compound is preferably the main ligand.
- the main ligand and the sub-ligand are explained using the metal complex according to the present invention.
- n ⁇ p in the general formula (2) a partial structure shown in parentheses having n
- a partial structure represented by a tautomer thereof is called a main ligand
- a ligand represented by X in parentheses having p is called a sub-ligand.
- the squarylium compound used in the squarylium metal complex compound of the present invention may be a symmetric squarylium compound or an asymmetric squarylium compound. It is preferable.
- X is a subligand, and the subligand X is not particularly limited.
- the subligand X is not particularly limited.
- the trader has a known ligand as a ligand as necessary. It may be.
- halogen ions e.g., halogen ions, hydroxide ions, ammonia, pyridine, amines (eg, methylamine, jetylamine, tributylamine, etc.) cyanide ions, cyanate ions, thiolate ions, thiocyanate ions, and biviridine
- amines eg, methylamine, jetylamine, tributylamine, etc.
- cyanide ions eg, methylamine, jetylamine, tributylamine, etc.
- cyanate ions eg., methylamine, jetylamine, tributylamine, etc.
- thiolate ions thiolate ions
- biviridine e.g., thiocyanate ions
- chelating ligands such as aminopolycarboxylic acids and 8-hydroxyquinoline.
- the monodentate ligand is coordinated by an acyl group, a carbonyl group, a thiocyanate group, an isocyanate group, a cyanate group, an isocyanate group, a halogen atom, a cyano group, an alkylthio group, an arylthio group, an alkoxy group or an aryloxy group. Preference is given to ligands or ligands consisting of dialkyl ketones or carbonamides.
- the bidentate ligand is an acyloxy group, an oxalylene group, an acylthio group, a thioacyloxy group, a thioacylthio group, an acylaminooxy group, a thiocarbamate group, a dithiocarbamate group, a thiocarbonate group, a dithiocarbonate group.
- a compound represented by the following general formula (4) is more preferable as a ligand.
- E represents a substituent, E is no, and the Met substituent constant (H) is 0.;
- 0.9 represents an electron-withdrawing group, and represents an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, or an amino group, and may have a substituent.
- a substituent or atom having a value of ⁇ ⁇ of 0.10 or more a chlorine atom, a bromine atom, an iodine atom, a carboxyl group, a cyano group, a nitro group, a halogen-substituted alkyl group (for example, , Trichloromethyl, trifluoromethyl, chloromethyl, trifluoromethylthiomethyl, trifluorochloromethanesulfonylmethyl, perfluorobutyl), aliphatic, aromatic or polycyclic acyl groups (for example, formyl, acetyl, Benzoyl), aliphatic, aromatic or bicyclic sulfonyl groups (for example, trifluoromethanesulfonyl, methanesulfonyl, benzensulfonyl), rubamoyl groups (for example, rubamoyl, methylcarbamoyl
- Substituents having a value of ⁇ ⁇ of 0.35 or more include cyano groups, nitro groups, carboxyl groups, fluorine-substituted alkyl groups (for example, trifluoromethyl, perfluoronorolobutyl), aliphatic, aromatic or complex Cyclic isacyl groups (eg, acetyl, benzoyl, formyl), aliphatic, aromatic or heterocyclic sulfonyl groups (eg, trifluoromethanesulfonyl, methanesulfonylonole, benzenesulfonyl), strong rubamoyl groups (eg, strong rubamoyl, methyl canolamoinole, Phenylenorecanomole, 2-chlorophenenorecanolevainole), ananoloxycarbonyl group (eg methoxycarbonyl, ethoxycarbonyl, diphenylmethylcarbonyl), fluor
- Examples of the substituent having a value of ⁇ ⁇ of 0.60 or more include a cyano group, a nitro group, an aliphatic group, an aromatic group or a heterocyclic sulfonyl group (for example, triphenylolomethanesulfonyl, difluoromethanesulfonyl). , Methanesulfonyl, benzenesulfonyl) and the like.
- Examples of such an electron-withdrawing group include an alkyl group, aryl group, heterocyclic group, carbonyl group, cyano group, alkoxycarbonyl group, alkylsulfonyl group, and alkylsulfonyloxy group.
- halogenated alkyl group especially a fluorine-substituted alkyl group
- Examples include a norebonyl group, a cyano group, an alkoxycarbonyl group, an alkylsulfonyl group, and an alkylsulfonyloxy group.
- the type of ligand in the complex is preferably composed of 12 types, and more preferably 1 type.
- W is an arbitrary counter ion
- a typical cation represented by W is an inorganic or organic ammonium ion (for example, a tetraalkylamine).
- n is an integer from ! to 3
- p is an integer from 0 to 2
- q is an integer from 0 to 3.
- the squarylium metal complex compound of the present invention is preferably neutral as a whole, more preferably neutral in the absence of a counter ion, that is, q is 0. Furthermore, it is more preferable that it consists only of a main ligand and a metal ion. In this case, p and q are both 0, and the squarylium metal complex compound of the present invention is represented by the general formula (3).
- the squarylium compounds in the squarylium metal complex compounds represented by the general formulas (1) to (3) according to the present invention are, for example, JP-A Nos. 5-155144, 5-239366, 5 — 339233, JP 2000-345059, 2002-363434, 2004-86133, 2004-238606, Law, KY et al., J. Org. Chem. 1992, 57, 3278 Etc. can be synthesized with reference to conventionally known methods described in the above.
- the squarylium metal complex of the present invention reacts a raw material that gives a metal ion having coordination ability with a squarylium compound at a temperature between room temperature and 120 ° C for 3 to 24 hours. Can be obtained. It is preferable that the raw material providing the metal ion has a ratio of the number of moles of the squarylium compound and the number of moles of the raw material supplying the metal ion of 1.0 to 3.0: 1.0. At this time, an acid or a base may be added to the reaction system.
- raw materials for providing metal ions include bis (acetylacetate) copper, copper acetate, copper bromide, copper nitrate, copper oxalate, copper sulfate, copper chloride, copper perchlorate, and tetrafur.
- the raw material that gives metal ions has an organic substance as a counter salt.
- examples of such a compound include diketonate metal compounds and general formula (4). And the compounds represented.
- Examples of the acid include organic acids such as acetic acid, propionic acid, butyric acid, isobutyric acid, valeric acid, isovaleric acid, and p-toluenesulfonic acid, and inorganic acids such as hydrochloric acid, sulfuric acid, and phosphoric acid.
- organic acids such as acetic acid, propionic acid, butyric acid, isobutyric acid, valeric acid, isovaleric acid, and p-toluenesulfonic acid
- inorganic acids such as hydrochloric acid, sulfuric acid, and phosphoric acid.
- the amount used is preferably 0 ⁇ ;! to 20 ⁇ 20 equivalents (molar ratio) to the squarylium compound.
- Examples of the solvent include halogenated hydrocarbon solvents such as chloroform and dichloromethane, aromatic solvents such as toluene and xylene, ether solvents such as tetrahydrofuran and methyl-tert-butyl ether, and esters such as ethyl acetate. Solvents, alcohol solvents such as methanol and ethanol, water, etc., and the amount used is relative to the squarylium compound. The amount is preferably 1 to 500 times (mass ratio).
- the dye in the present invention refers to a squarylium metal complex represented by the above general formulas (1) to (3) having an absorption maximum wavelength in the visible region (380 to 780 nm). Since the squarylium metal complex of the present invention has good spectral characteristics, the extinction coefficient in a wavelength region shifted by about lOO nm from the absorption maximum wavelength is 1/100 to 1/100 or less of the absorption coefficient of the absorption maximum. In fact, it is characterized by having no absorption in the wavelength range of 60nm longwave or shortwave from the absorption maximum. As described above, the dye in the present invention is preferable in the visible region and has a V ⁇ spectral characteristic.
- the dye of the present invention is preferably used as a composition with a dispersant or a composition in which a solvent is further added to the composition for film-forming stability or the like.
- (meth) acrylate resin polyester resin, polyamide resin, polyimide resin, polystyrene resin, polyepoxy resin, polyester resin, amino resin, fluorine resin, Phenolic resins, polyurethane resins, polyethylene resins, polychlorinated bur resins, polybutyl alcohol resins, polyether resins, polyether ketone resins, polyphenylene sulfide resins, polycarbonate resins, amide resins, etc.
- (meth) acrylate resins, polystyrene resins, polyethylene resins, polychlorinated bur resins, poly butyl alcohol resins, etc. are preferably used, most preferably (meth) acrylate. Resin and polystyrene resin. These copolymers are also preferred.
- (Meth) acrylate resin is synthesized by homopolymerizing or copolymerizing various meta acrylate monomers or acrylate monomers, and by varying the monomer species and monomer composition ratio, The desired (meth) acrylate resin can be obtained. In the present invention, it can be used together with a (meth) acrylate monomer and a copolymerizable monomer having an unsaturated double bond other than the (meth) acrylate monomer, In the present invention, it can be used by mixing a plurality of other resins together with the poly (meth) acrylate resin.
- a monomer component for forming the (meth) acrylate resin used in the present invention are, for example, (meth) acrylic acid, methyl (meth) acrylate, ethyl (meth) acrylate, open pill (meth) acrylate, butyl (meth) acrylate, isopropyl (meth) acrylate, isobutyl ( (Meth) Atylate, t-Butyl (Meth) Atylate, Stearyl (Meth) Atylate, 2-Hydroxyethyl (Meth) Atylate, Acetotaxetyl (Meth) Atylate, Dimethylaminoethyl (Meth) Atylate , 2-Hydroxypropyl (meth) atalylate, Di (ethyleneglycolole) ethinoleethenole (meth) acrylate, Ethyleneglycololemethinolelite Tel (meth) acrylate, Is
- (meth) acryl Acid methyl (meth) acrylate, ethyl (meth) acrylate, propyl (methyl ) Atarylate, butyl (meth) acrylate, stearinole (meth) acrylate, 2-hydroxyethyl (meth) acrylate, acetatetoxetyl (meth) acrylate, benzyl (meth) acrylate, tridecinole (meta) ) Atarylate, dodecinole (meth) acrylate, 2-ethylenohexylate (meth) acrylate.
- a polystyrene resin is a homopolymer of a styrene monomer, a random copolymer or a block copolymer obtained by copolymerizing another monomer having an unsaturated double bond copolymerizable with a styrene monomer, A graft copolymer is mentioned. Furthermore, blends and polymer alloys in which such polymers are blended with other polymers are also included.
- styrene monomer examples include styrene, ⁇ -methyl styrene, ⁇ -ethyl styrene, ⁇ -methyl styrene ⁇ methyl styrene, ⁇ methyl styrene, m-methyl styrene, p-methyl styrene, etc.
- the resin used in the present invention is, for example, a copolymer resin such as benzyl methacrylate / ethyl acrylate or butyl acrylate, or methyl methacrylate.
- Copolymer resin such as ethylhexyl methacrylate, methyl methacrylate / methacrylic acid / stearyl methacrylate / acetoacetoxyxetyl methacrylate copolymer resin, and styrene / acetoxate Copolymer resin of til methacrylate / stearyl methacrylate, styrene / 2-hydroxyethyl methacrylate / stearyl methacrylate copolymer, and 2-ethyl hexyl methacrylate / 2 —Examples include copolymer resins such as hydroxyethyl methacrylate.
- the ink containing at least one of the dyes of the present invention is used for image recording as an ink jet recording liquid, and even if only one kind of the dye of the present invention is used, it is a combination of two or more kinds of dyes. It may also be used in combination with a dye outside the present invention.
- the ink jet recording liquid containing the dye of the present invention can use various solvent systems such as an aqueous solvent, an oil-based solvent, and a solid (phase change) solvent, and particularly exhibits the effects of the present invention when an aqueous solvent is used.
- aqueous solvent water (for example, ion exchange water is preferable) and a water-soluble organic solvent are generally used.
- water-soluble organic solvents include alcohols (eg, methanol, ethanol, propanolol, isopropanol, butanol, isobutanol, sec-butanol, t-butanol, benzyl alcohol, etc.), polyhydric alcohols (eg, , Ethylene glycol, Diethylene glycol, Triethylene glycol, Polyethylene glycol, Propylene glycol, Dipropylene glycol, Polypropylene glycol, Butylene glycol, Hexane dinore, Pentandionol, Glycerin, Hexantrio Nore, Chioji Glico No., etc.), polyhydric alcohol ethers (for example, ethylene glycol monomethyl etherenole, ethylene glycol monoethyl etherenole, ethylene glycol mono nomono mono butenoate ethere, diethylene glycol monomethyl ether, diethylene glycol monomethyl ether, diethylene glycol monomethyl ether, diethylene glyco
- aqueous solvent as described above can be used with a force S that can be used as soon as possible if the dye of the present invention is soluble in the solvent system.
- the dye of the present invention when the dye of the present invention is insoluble in the solvent system as it is, the dye is mixed with various dispersing machines (for example, ball mill, sand mill, attritor, Ronore mill, agitator mill, Henschel mixer, colloid minore, ultrasonic Using a homogenizer, pearl mill, jet mill, ang mill, etc.), or after dissolving the dye in a soluble organic solvent, disperse it in the solvent system together with the polymer dispersant or surfactant.
- dispersing machines for example, ball mill, sand mill, attritor, Ronore mill, agitator mill, Henschel mixer, colloid minore, ultrasonic Using a homogenizer, pearl mill, jet mill, ang mill, etc.
- the dye of the present invention is insoluble in the solvent system, it is preferable to make it fine particles and disperse them in the solvent system.
- S is preferably dispersed in fine particles having an average particle size of 150 nm or less. More preferably.
- the average particle diameter is a volume average particle diameter, and the average particle diameter in terms of a circle obtained from the average value of the projected area (obtained for at least 100 particles) of a transmission electron microscope (TEM) photograph. Is obtained by converting into a spherical shape.
- the coefficient of variation can be obtained by calculating the volume average particle diameter and its standard deviation and dividing the standard deviation by the volume average particle diameter.
- the volume average particle diameter and its standard deviation can be obtained by using a dynamic light scattering method.
- the dye is dissolved in an organic solvent in which the dye of the present invention is soluble, and then dispersed in an aqueous solvent as a fine particle dispersion together with the oil-soluble polymer.
- Specific methods for preparing an aqueous solvent used for such an ink jet recording liquid include, for example, JP-A-5-148436, 5-295312, 7-97541, and 7-82515. Nos. 7-118584, etc. can be referred to.
- the oil-soluble polymer will be described.
- the force bull polymer which can be suitably selected from said dispersing agent group according to the objective is mentioned suitably.
- the bull polymer include conventionally known polymers, and any of a water-insoluble type, a water-dispersed (self-emulsifying) type, and a water-soluble type may be used. In view of the above, a water dispersion type is preferable.
- water-dispersible bull polymer examples include those of an ion dissociation type, a non-ionic dispersible group-containing type, or a mixture type thereof.
- Examples of the ion dissociation type bull polymer include a bull polymer containing a cationic dissociable group such as a tertiary amino group and a bull polymer containing an anionic dissociable group such as carboxylic acid and sulfonic acid.
- Examples of the nonionic dispersible group-containing type bull polymer include a bull polymer containing a nonionic dispersible group such as a polyethyleneoxy chain.
- an ion dissociation type bull polymer containing an anionic dissociable group, a non-ionic dispersible group containing type bull polymer, and a mixed type bull polymer are preferable.
- Examples of the monomer that forms the bull polymer include the following. That is, acrylic acid esters, methacrylic acid esters, bur esters, acrylic amides, methacrylamides, olefins, bur ethers, and the like can be mentioned.
- That Other monomers include butyl crotonate, hexyl crotonate, dimethyl itaconate, dibutyl itaconate, jetyl maleate, dimethyl maleate, dibutyl maleate, jetyl fumarate, dimethyl fumarate, dibutyl fumarate, methyl vinyl Ruketone, phenol vinyl ketone, methoxyethyl vinyl ketone, N-buluoxazolidone, N-burpi mouthlidone, vinylidene mouthride, methylenemalone nitrile, vinylidene, diphenol two-a
- Examples thereof include feto, dibutyl-2-acryloyloxychetyl phosphate, dioctyl-2-methacryloyloxychetyl phosphate, and the like.
- Examples of the monomer having a dissociable group include a monomer having an anionic dissociable group and a monomer having a cationic dissociable group.
- Examples of the monomer having an anionic dissociable group include a carboxylic acid monomer, a sulfonic acid monomer, and a phosphoric acid monomer. Among these, acrylic acid
- Acrylic acid methacrylic acid, styrene sulfonic acid, 2-acrylamido-2-methylpropane sulfonic acid, 2- methacrylic acid, styrene sulfonic acid, vinyl sulfonic acid, acrylamide alkyl sulfonic acid, and methacrylamide alkyl sulfonic acid are preferred.
- Acrylamide
- Examples of the monomer having a cationic dissociable group include monomers having a tertiary amino group such as dialkylaminoethyl methacrylate and dialkylaminoethyl acrylate.
- examples of the monomer containing a nonionic dispersible group include, for example, an ester of a polyethylene glycol monoremonoalkyl ether and a carboxylic acid monomer, a polyethylene glycol monorenoquinoleatenore, and a sulphonic acid monomer. Estenoles of polyethylene glycolenole monoenolequinoleateolene and phosphoric acid monomer, macromolecules containing polybutyl alcohol structure, urethane containing urethane group formed from polyethylene glycolenomonoalkylene ether and isocyanate group-containing monomer And monomers.
- the repeating number of the ethyleneoxy part of the polyethylene glycol monoalkyl ether is preferably 8 to 50 force S, more preferably 10 to 30 force S.
- the number of carbon atoms in the alkyl group of the polyethylene glycol monoalkyl ether is preferably 1-20, more preferably 1-12! /. [0125] These monomers may be used alone to form a bull polymer, or two or more of these monomers may be used in combination to form a bull polymer. , Solubility improvement, dispersion stability, etc.)
- oil-based solvent used in the present invention uses an organic solvent.
- oil solvents include alcohols, esters, ethers, ketones, hydrocarbons, amides, and the like.
- the oil-based solvent as described above can be used by dissolving the dye of the present invention as it is, and can also be used by being dispersed or dissolved in combination with a resinous dispersant or binder. It is more preferable to use in combination with a dispersant from the viewpoint of soil adjustment and the like.
- the solid (phase change) solvent used in the present invention is a phase change solvent that is a solid at room temperature as a solvent and is in a molten liquid state when the ink jet recording liquid is heated and jetted.
- phase change solvents include natural waxes (eg, beeswax, carnauba wax, rice wax, wood wax, jojoba oil, whale wax, candelilla wax, lanolin, montan wax, ozokerite, ceresin, Paraffin wax, microcrystalline wax, petrolatum, etc.), polyethylene wax derivatives, chlorinated hydrocarbons, organic acids (eg palmitic acid, stearic acid, behenic acid, tiglic acid, 2-acetonaphthone behenic acid, 12-hydroxy stearic acid , Dihydroxystearic acid, etc.), organic acid esters (for example, esters of organic acids such as glycerin, diethylene glycolol, and esters with ananolone such as ethylene glycolanol), alcohols (eg, dodecanol, tetradecanol, hexade strength) No , Econosanol, Docosanol, Tetracosanol, Hex
- Reaction products of dimer acid, diamine and fatty acid such as tetramer of acid dimer / ethylene diamine / stearic acid (1: 2: 2 molar ratio), sulfonamide (eg, paratoluene sulphonamide, ethyl) Benzenesulfonamide, butylbenzenesulfonamide, etc.), silicones (eg, silicone SH6018 (Toray Silicone), silicones KR215, 216, 2 20 (Shin-Etsu Silicone), etc.), coumarones (eg, Escron G-90 (Shinichi) ), Cholesterol fatty acid esters (eg, cholesterol stearate, cholesterol palmitate, cholesterol myristate, cholesterol, behenate, cholesterol, laurate cholesterol, etc.), sugar fatty acids Esters (saccharose stearate, palmitate Sucrose behenate, saccharose behenate, saccharose laurate, latatoste
- the solid (phase change) solvent as described above can be used by dissolving the dye of the present invention as it is in a heated molten solvent, and also in combination with a resinous dispersant and a binder. It can be used after dispersing or melting.
- phase change solvents [0133] Specific methods for preparing such phase change solvents are described in JP-A-5-186723 and 7-.
- the ink jet recording liquid of the present invention in which the above-described aqueous, oily, solid (phase change) solvent is used or the dye of the present invention is dissolved or dispersed has a viscosity at the time of flight of 4 X 10 — 2 Pa's or less is preferable, and 3 X 10— 2 Pa ⁇ s or less is more preferable! /.
- the ink jet recording liquid of the present invention is 2 X 10- 4 ⁇ surface tension at the time of flight; 10_ 3
- N / cm is preferred instrument 3 X 10- 4 ⁇ 8 X 10- 4 N / cm.
- the dye of the present invention is preferably used in the range of 0.5% to 25% by mass of the ink jet recording liquid, and more preferably in the range of 0.5% to 10% by mass.
- the resin type dispersant used in the present invention is preferably a high molecular weight compound having a molecular weight of 1,000 to 1,000,000. . ;! ⁇ Five
- the inkjet recording liquid of the present invention includes a viscosity modifier, surface tension, and the like according to the purpose of improving ejection stability, compatibility with print head and ink cartridge, storage stability, image storage stability, and other various performances.
- a regulator, a specific resistance modifier, a film forming agent, a dispersant, a surfactant, an ultraviolet absorber, an antioxidant, an antifading agent, an antifungal agent, an antifungal agent, and the like can also be added.
- the inkjet recording liquid of the present invention is not particularly limited with respect to the recording method used.
- On-demand methods include electromechanical conversion methods (for example, single-cavity type, double-cavity type, bender type, piston type, shear mode type, shared wall type, etc.), electrothermal conversion type (for example, thermal Specific examples include a cjet type, bubble jet (registered trademark) type, electrostatic attraction type (eg, electric field control type, slit jet type, etc.), discharge type (eg, spark jet type). That's the power S.
- electromechanical conversion methods for example, single-cavity type, double-cavity type, bender type, piston type, shear mode type, shared wall type, etc.
- electrothermal conversion type for example, thermal Specific examples include a cjet type, bubble jet (registered trademark) type, electrostatic attraction type (eg, electric field control type, slit jet type, etc.), discharge type (eg, spark jet type). That's the power S.
- electrothermal conversion type for example, thermal Specific examples include a cjet type, bubble jet (registered trademark
- the toner (color toner) of the present invention is characterized by containing the coloring matter of the present invention.
- the content of the coloring matter of the present invention is not particularly limited as long as the toner exhibits sufficient spectral absorption characteristics, but is preferably 2 to 30% by mass in the toner particles.
- the color toner is mainly composed of a binder resin, a release agent, a charge control agent, and an external additive.
- binder resin for forming the matrix all binders generally used for toners can be used. Examples include styrene resins, acrylic resins, styrene / acrylic resins, polyester resins, and the like.
- external additives such as inorganic fine powder and organic fine particles may be added to the toner.
- silica fine particles and titania fine particles whose surface is treated with an alkyl group-containing coupling agent or the like are preferably used.
- the number average primary particle diameter is preferably 10 to 500 nm, and the addition amount thereof is preferably 0.;! To 20% by mass with respect to the toner.
- a release agent added to the toner particles for the purpose of improving the heat fixing property a release agent conventionally used for toner can be used.
- olefins such as low molecular weight polypropylene, low molecular weight polyethylene, and ethylene-propylene copolymer, microcrystalline wax, carnauba wax, sazol wax, and noraffin status. These addition amounts are preferably 1 to 5% by mass in the toner.
- the charge control agent for improving the charging characteristics may be added as necessary, but colorless is preferred from the viewpoint of color development.
- a quaternary ammonium salt structure potassium Examples thereof include those having a xuarene structure.
- the color toner of the present invention is used for a two-component developer, it is used by mixing with a carrier.
- a carrier an uncoated carrier composed only of magnetic material particles such as iron and ferrite, or a resin-coated carrier in which the surface of the magnetic material particle is coated with a resin or the like may be used.
- the average particle size of the carrier is preferably 30 to 150 m in volume average particle size.
- the image forming method to which the color toner of the present invention is applied is not particularly limited. However, for example, a method in which a color image is repeatedly formed on a photoconductor and then transferred to form an image, or an image formed on the photoconductor is sequentially transferred to an intermediate transfer body, etc. And a method of forming a color image by transferring the image to an image forming member such as paper.
- optical recording medium optical information recording medium
- optical information recording method of the present invention will be described in detail.
- the dye of the present invention used for the optical information recording medium of the present invention is a combination of two or more of the dyes of the present invention, even if only one kind of the dye of the present invention is used. Alternatively, it may be used in combination with a dye other than the present invention. Further, the content of the dye of the present invention in the recording layer is 30 to 100% by mass, preferably 60 to 100% by mass, more preferably 90 to 100% by mass, based on the dry mass of the entire recording layer. Most preferred. Further, in the recording layer of the present invention, a dye that can be used for a conventional optical information recording medium as long as it does not affect the effect of the present invention may be used in combination with the dye of the present invention! / ,.
- the optical information recording medium of the present invention includes various configurations.
- the optical information recording medium of the present invention has a configuration in which a recording layer, a light reflecting layer, and a protective layer are arranged in this order on a disc-like substrate on which a pre-loop of a constant track pitch is formed, or a light reflecting layer, a recording layer on the substrate.
- a configuration having a recording layer and a protective layer in this order is preferable.
- two laminates in which a recording layer and a light reflection layer are provided on a transparent disk-like substrate on which a pre-loop of a certain track pitch is formed are joined so that each recording layer is on the inside.
- the configuration is also preferable.
- the optical information recording medium of the present invention can use a substrate on which a pre-loop with a narrower track pitch is formed as compared with CD-R and DVD-R in order to achieve higher recording density.
- the track pitch is preferably in the range of 0.2 to 0.8 ⁇ , and more preferably in the range of 0.2 to 0.5 m. In particular, it is preferably in the range of 0.2-0.4 ⁇ .
- the depth of the predano leve is preferably in the range of 0.01—0.18 in, more preferably in the range of 0.01-0.1.5 m, in particular 0.02-0.1. It is preferably in the range of 5 mm.
- Adjacent predaloop width Is preferably in the range of 0 ⁇ 05—0.4 ⁇ , more preferably in the range of 0.08 to 0.3 ⁇ m, particularly in the range of 0.1 to 0.25 ⁇ m. It is preferable.
- optical information recording medium of the present invention a manufacturing method having a recording layer, a light reflecting layer, and a protective layer in this order on a disc-like substrate will be described below.
- the substrate of the optical information recording medium of the present invention has a wavelength region of laser light used for recording and reproduction (
- the substrate material include acrylic resins such as glass, polycarbonate, and polymethylmethacrylate, chlorinated resins such as polychlorinated bulls and chlorinated copolymers, epoxy resins, amorphous polyolefins, and polyesters. You may use them together. These materials can be used as a film or as a rigid substrate. Among the above materials, polycarbonate is preferable from the viewpoint of moisture resistance, dimensional stability, price, and the like.
- An undercoat layer may be provided on the surface of the substrate on which the recording layer is provided for the purpose of improving flatness, improving adhesive strength, and preventing alteration of the recording layer.
- Materials for the undercoat layer include, for example, polymethyl methacrylate, acrylic acid 'methacrylic acid copolymer, styrene' maleic anhydride copolymer, polybutyl alcohol, N-methylol acrylamide, and styrene 'butanol copolymer.
- the undercoat layer is formed by dissolving or dispersing the above substances in an appropriate solvent to prepare a coating solution, and then applying this coating solution to the substrate surface by a coating method such as spin coating, dip coating, or eta-stretch coating. The power to do S.
- the thickness of the undercoat layer is generally in the range of 0.005 to 20 in, preferably in the range of 0.0;! To 10 m.
- the recording layer can be formed by a method such as vapor deposition, sputtering, CVD, or solvent coating.
- solvent coating is preferred.
- a coating solution is prepared by dissolving the dye, and further, a quencher, a binder, etc., if desired, in a solvent. This can be done by applying it to the substrate surface to form a coating film and then drying it.
- Solvents for the coating solution include esters such as butyl acetate, ethyl lactate and cellosolve acetate; ketones such as methyl ethyl ketone, cyclohexanone and methyl isobutyl ketone; dichloromethane, 1,2-dichloroethane, black mouth Chlorinated hydrocarbons such as form; Amides such as dimethylformamide; Hydrocarbons such as methylcyclohexane; Etherenoles such as dibutyl ether, jetinoreethenole, tetrahydrofuran and dioxane; Ethanol, n-propanol, isopropanol, n-butanol, diacetone Alcohols such as alcohols; Fluorinated solvents such as 2, 2, 3, 3-tetrafluoropropanol; ethylene glycol monomethyl etherenole, ethylene glycol monoethanolino ethere, propylene glycol mono
- the above solvents may be used alone or in combination of two or more in consideration of the solubility of the dye used.
- Various additives such as antioxidants, UV absorbers, plasticizers, and lubricants may be added to the coating solution depending on the purpose.
- binders include gelatin, cellulose derivatives, dextran, rosin, natural organic polymer materials such as rubber; and hydrocarbons such as polyethylene, polypropylene, polystyrene, polyisobutylene, etc.
- Resins poly (vinyl chloride), poly (vinylidene chloride), poly (vinyl chloride), poly (butyl acetate copolymer), etc., acrylic resins such as poly (methyl acrylate) and poly (methyl methacrylate), poly (bull alcohol), chlorinated poly (ethylene) And synthetic organic polymers such as initial condensates of thermosetting resins such as epoxy resins, butyral resins, rubber derivatives, phenol formaldehyde resins, and the like.
- the amount of binder used is generally in the range of 0.0;! To 50 times (mass ratio) with respect to the metal complex, preferably 0.;! ⁇ 5 times the amount (mass ratio).
- the concentration of the dye in the coating solution this way are prepared is generally 0.01 to; the range of 10 mass 0/0, preferably 0.; in the range of 1-5 mass 0/0!.
- Examples of the coating method include a spray method, a spin coating method, a dip method, a roll coating method, a blade coating method, a doctor roll method, and a screen printing method.
- the recording layer may be a single layer or a multilayer.
- the thickness of the recording layer is generally in the range of 0.01-0.5.111, and preferably in the range of 0.015—0.3 mm, more preferably in the range of 0.02—0.1 m. of There are n cars.
- the recording layer constituting the optical recording medium may contain other types of dyes, various resins, surfactants, antistatic agents, dispersants, antioxidants, crosslinking agents, and the like. .
- the recording layer may be formed on one surface of the substrate or on both surfaces of the substrate.
- the recording layer can contain various anti-fading agents.
- a singlet oxygen quencher is generally used as the anti-fading agent.
- the singlet oxygen quencher those described in publications such as known patent specifications can be used. Specific examples thereof include JP-A-58-175693 and 59.
- An example of a preferred singlet oxygen quencher is a compound represented by the following general formula (B).
- R represents an alkyl group which may have a substituent
- Q- represents an anion
- R 1 is generally an optionally substituted alkyl group having 1 to 8 carbon atoms, preferably an unsubstituted alkyl group having 1 to 6 carbon atoms.
- Examples of the substituent for the alkyl group include a halogen atom (for example, F, C1), an alkoxy group (for example, methoxy, ethoxy), an alkylthio group (for example, methylthio, ethylthio), an isyl group (for example, acetyl, propionyl), Acyloxy group (eg, acetoxy, propionyloxy), hydroxy group, alkoxycarbonyl group (eg, methoxycarbonyl, ethoxycarbonyl), alkenyl group (eg, , Bur), and aryl groups (eg, phenyl, naphthyl).
- halogen atoms, alkoxy groups, alkylthio groups, and alkoxycarbonyl groups are preferred.
- Preferred examples of Q—anions include CIO—, AsF—, BF—, and SbF—.
- Table 1 shows examples of the compound represented by formula (B).
- the amount of the anti-fading agent such as the singlet oxygen quencher used is usually in the range of 0.;! To 50% by mass, preferably 0.5 to 0.5%, based on the amount of the metal complex of the present invention.
- the range is 45% by mass, more preferably 0.5 to 40% by mass, particularly preferably 1 to 25% by mass.
- the light-reflecting material that is the material of the light-reflecting layer is a material that has a high reflectivity with respect to laser light. Examples of this are Mg, Se, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, and Mo. , W, Mn, Re, Fe, Co, Ni, Ru, Rh, Pd, Ir, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Si, Ge, Te, Pb, Po, Sn C) Metals such as Bi, semi-metals or stainless steels.
- These substances may be used alone or in combination of two or more kinds or as an alloy.
- Cr, Ni, Pt, Cu, Ag, Au, Al, and stainless steel are preferable.
- Particularly preferred are Au metal, Ag metal, A1 metal or alloys thereof, and most preferred are Ag metal, A1 metal or alloys thereof.
- the light reflecting layer can be formed on the substrate or the recording layer, for example, by vapor deposition, sputtering or ion plating of the light reflecting material.
- the thickness of the light reflecting layer is generally in the range of 0 ⁇ 01—0.3.11, and in the range of 0.05 to 0.2.111. It is preferable.
- a protective layer is preferably provided on the light reflecting layer or the recording layer for the purpose of physically and chemically protecting the recording layer and the like. If a DVD-R type optical information recording medium is manufactured in the same manner, that is, if the recording layer is laminated on the inside using two substrates, it is not always necessary to provide a protective layer. Nare ,.
- Examples of materials used for the protective layer include: Zn—SiO, ZnS, SiO, SiO, MgF, Sn 2 O, Si N, and other inorganic substances, thermoplastic resins, thermosetting resins, UV curable resins, etc.
- the organic compound Zn—SiO, ZnS, SiO, SiO, MgF, Sn 2 O, Si N, and other inorganic substances, thermoplastic resins, thermosetting resins, UV curable resins, etc.
- the protective layer can be formed, for example, by laminating a film obtained by extrusion of plastic on the reflective layer through an adhesive. Or you may provide by methods, such as vacuum evaporation, sputtering, and application
- thermoplastic resin or a thermosetting resin these are dissolved in a suitable solvent to obtain a coating solution.
- the coating solution After preparing the coating solution, it can also be formed by applying this coating solution and drying it.
- a UV curable resin it can also be formed by preparing a coating solution as it is or by dissolving it in an appropriate solvent, and then applying this coating solution and curing it by irradiating with UV light. Can do.
- various additives such as antistatic agents, antioxidants and UV absorbers may be added according to the purpose.
- the thickness of the protective layer is generally 0.1111 to 1 mm (7) fiiH.
- the optical information recording method of the present invention is carried out, for example, as follows using the optical information recording medium.
- the optical information recording medium can be used for recording semiconductor laser light from the substrate side or the protective layer side. Irradiate light.
- the recording layer absorbs the light and the temperature rises locally, and physical or chemical changes (for example, generation of pits) occur to change the optical characteristics, so that information can be obtained. It is considered to be recorded.
- semiconductor laser light having an oscillation wavelength in the range of 300 to 900 nm is used as recording light.
- Examples thereof include a solid-state laser, a gas laser, a dye laser, and a semiconductor laser. Since the metal complex of the present invention has particularly high recording sensitivity, it is suitable for recording and reproduction using a 635 nm or 650 nm semiconductor laser, a 532 nm YAG harmonic laser, or the like.
- the blue-violet SHG laser light is also preferred!
- blue-violet semiconductor laser light is preferably used in terms of recording density.
- various dispersing means such as a two-roll mill, a three-roll mill, a sand mill, and a kneader can be used.
- the resin varnish a varnish used for a conventionally known color filter coloring composition is used.
- the dispersion medium a solvent suitable for the resin varnish or an aqueous medium is used.
- conventionally known additives such as a dispersion aid, a smoothing agent, and an adhesive agent are added and used as necessary.
- the resin varnish a photosensitive resin varnish and a non-photosensitive resin varnish are used.
- the photosensitive resin varnish are photosensitive resin varnishes used for ultraviolet curable inks and electron beam curable inks.
- Non-photosensitive resin varnishes include, for example, relief printing inks, lithographic inks, intaglio inks. Varnishes used for printing inks such as stencil screen ink, varnishes used for electrodeposition coating, varnishes used for developers of electrostatic printing and electrostatic printing, varnishes used for thermal transfer ribbons, etc. can be used .
- Examples of the photosensitive resin varnish include photosensitive cyclized rubber resin, photosensitive phenol resin, photosensitive polymetatalate resin, photosensitive polyamide resin, photosensitive polyimide resin, and the like.
- Polyester resin polyester acrylate resin, polyepoxy Atallate resin, polyurethane acrylate resin, polyether acrylate resin
- a photosensitive coloring composition can be obtained by adding a photopolymerization initiator such as benzoin ether or benzophenone to the metal chelate dye of the present invention and the above varnish and drying by a conventionally known method. Moreover, it can replace with said photoinitiator and can use it as a thermopolymerizable coloring composition using a thermal polymerization initiator.
- a photopolymerization initiator such as benzoin ether or benzophenone
- the photosensitive coloring composition is spin-coated on a transparent substrate, using a low-speed rotary coater, a roll coater, a knife coater, or the like. Apply the entire surface by coating, or print the entire surface by various printing methods or a partial printing that is slightly larger than the pattern! / ⁇ After pre-drying, attach the photomask and expose it using an ultra-high pressure mercury lamp. Burn it. Subsequently, development and washing are performed, and a color filter pattern can be formed by performing post-beta as necessary.
- non-photosensitive resin varnishes examples include cellulose acetate resins, nitrocellulose-based resins, styrene-based (co) polymers, polybutylpropylar resins, aminoalkyd resins, and polyester resins.
- Amino resin-modified polyester resin polyurethane resin, acrylic polyol urethane resin, soluble polyamide resin, soluble polyimide resin, soluble polyamideimide resin, soluble polyesterimide resin, casein, hydroxetyl cellulose, styrene
- Water-soluble salts of maleic acid ester-based copolymers, water-soluble salts of (meth) acrylic acid ester-based (co) polymers, water-soluble amino alkyd resins, water-soluble amino polyester resins, water-soluble polyamide resins Can be used alone or in combination.
- a color filter pattern is formed using the above non-photosensitive coloring composition
- the above-described various types of non-photosensitive coloring composition for example, a color filter printing ink
- a transparent substrate For example, a transparent substrate.
- baking is performed as necessary according to conventional methods, polishing for smoothing the surface, and top coating for protecting the surface.
- a black matrix is formed according to a conventional method to obtain an RGB color filter.
- the front filter for a display of the present invention has the dye of the present invention in the base material or contains at least one kind of the composition. In addition to being contained within the material, it means a state where it is applied to the surface of the base material, a state where it is sandwiched between the base material and the base material, and the like.
- the front filter for a display according to the present invention is disposed in front of a self-luminous display device such as a plasma display or an organic EL display, and is used to correct color tone or block light emission in an unnecessary wavelength region. It is done. Therefore, the display front filter of the present invention is characterized by having an absorption maximum in the visible region.
- the dye of the present invention is characterized by having an absorption maximum in the visible region in a solution state, and more preferably a fluorescent maximum having an absorption maximum at 400 to 620 nm for color tone adjustment. It is preferable to have an absorption maximum in a wavelength region corresponding to the valleys of the blue, green, and red spectra that are emitted from the light body.
- Examples of such a wavelength range include 350 to 400 nm, 480 to 520 nm and the like S.
- Examples of the substrate include a transparent resin plate, a transparent film, transparent glass, and the like, and are not particularly limited as long as the light transmittance at a wavelength of 400 to 7 OOnm is 40% or more.
- a transparent resin plate for example, polyimide, polysulfone (PSF), polyethersulfone (PES), polyethylene terephthalate (PET), polymethylene methacrylate (PMMA), polycarbonate (PC), polyetherol ether ketone (PEEK), polypropylene (PP), triacetyl cellulose (TAC), etc.
- acrylic resins such as polyethylene terephthalate (PET), triacetyl cellulose (TAC), and polymethyl methacrylate (PMMA), and polycarbonate resins are preferably used.
- the thickness of the base material is not particularly limited as long as it has a certain degree of mechanical strength. m ⁇ ; 10 mm, 20 mm ⁇ , preferably 1 mm, 20 mm ⁇ 200 mm, particularly preferred! / ⁇ .
- the method for producing the front filter for a display of the present invention using the dye or the composition thereof is not particularly limited.
- transparent adhesives listed in (1) include acrylic adhesives, silicone adhesives, urethane adhesives, polybutyl petital adhesives (PVB), and ethylene vinyl acetate.
- examples include adhesives (EVA), polybulle ethers, saturated amorphous polyesters, sheet-like or liquid adhesives such as melamine resin, among which acrylic adhesives, urethane adhesives, polybules A petital adhesive is preferred.
- the addition amount of the dye of the present invention is usually 10ppm ⁇ 30 mass 0/0, S preferably 10ppm ⁇ 20 mass 0/0 force, 10p pm ⁇ ; 10 wt% is particularly preferred.
- the method of incorporating the polymer resin molding mentioned in (2) includes (A) a method of kneading a dye mixture into a resin and thermoforming, and (B) a resin or resin monomer in an organic solvent. And a method of producing a polymer molded body by a casting method by dispersing and dissolving a mixture of pigment and dye.
- the resin used in (A) is preferably as transparent as possible when the plate or film is produced.
- PET polyethylene terephthalate
- PES polyether sulfone
- polyethylene Naphthalate polyarylate
- polyetherketone polycarbonate
- polyamide such as polyethylene, polypropylene and nylon 6
- cellulose resin such as polyimide and triacetyl cellulose
- fluorine resin such as polyurethane and polytetrafluoroethylene
- polychlorinated Bull compounds such as Bull, polyacrylic acid, polyacrylate esters, polyacrylonitrile, addition polymers of bur compounds, polymethacrylic acid, polymethacrylic acid esters, vinylidene compounds such as polyvinylidene chloride, vinylidene fluoride / trifluoroethylene
- Polymers copolymers of ethylene / Bulle compound of acetate Bulle copolymer or a fluorine-based compound
- polyether such as polyethylene O dimethylsulfoxide, epoxy resin
- the processing conditions include a method in which a dye mixture is added to and mixed with a base polymer powder or pellet, heated to 150 to 350 ° C, dissolved, and then molded to form a plate, or an extruder.
- additives such as plasticity used for normal resin molding may be added.
- a dye mixture is added and dissolved in an organic solvent solution or an organic solvent of a resin or resin monomer, and if necessary, a plasticizer, a polymerization initiator, and an antioxidant are added,
- a plate or film can be produced by pouring onto a mold or drum having the required surface state, solvent volatilization, drying or polymerization, solvent volatilization and drying.
- Resins used include aliphatic ester resins, acrylic resins, melamine resins, urethane resins, aromatic ester resins, polycarbonate resins, aliphatic polyolefin resins, aromatic polyolefin resins, polybule resins, polyresins. Examples thereof include resin monomers of bulle alcohol resins, polymodified resins (PVA, EVA, etc.) or copolymer resins thereof.
- the solvent include halogen-based, alcohol-based, ketone-based, ester-based, aliphatic hydrocarbon-based, aromatic hydrocarbon-based, ether-based solvents, and mixtures thereof.
- a method for coating the polymer molded body or glass surface mentioned in (3) a method of dissolving the dye of the present invention in a binder resin and an organic solvent to form a composition, and then forming a paint, uncolored And an acrylic emulsion-based water-based paint by dispersing a finely pulverized (50 to 50 Onm) pigment of the present invention in the acrylic emulsion paint.
- additives such as antioxidants used in ordinary coating materials may be added.
- Examples of the noinder include aliphatic ester resins, acrylic resins, melamine resins, urethane resins, aromatic ester resins, polycarbonate resins, aliphatic polyolefin resins, aromatic polyolefin resins, polybule resins, polyresins.
- Examples thereof include a bull alcohol resin, a polyvinyl modified resin (PVB, EVA, etc.) or a copolymer resin thereof.
- Solvents include halogens, alcohols, ketones, esters, and aliphatic hydrocarbons.
- concentration of the composition varies depending on the gram extinction coefficient, coating thickness, desired absorption intensity, desired visible light transmittance, etc.
- the amount is usually 0.1 lpp 111 to 30% by mass with respect to the mass of the binder resin.
- the resin concentration is usually from!
- the paint produced by the above method is applied by forming a thin film on a substrate by a known method such as a bar coder, blade coater, spin coater, reno coater, die coater, or spraying. Can be crafted.
- the front filter for display of the present invention preferably has an electromagnetic wave shielding function or a near-infrared shielding function.
- the electromagnetic wave shield a laminate using a silver thin film or a metal mesh mainly using copper can be used.
- a laminate using a silver thin film is preferably a laminate in which a dielectric such as indium oxide, zinc oxide, titanium oxide and silver are alternately laminated.
- the metal mesh there can be used a fiber mesh obtained by vapor-depositing a metal on a fiber, an etching mesh that forms a pattern by etching using a technique of photolithography, and the like.
- a method of performing battering with an ink containing a metal, a method of applying and developing and fixing silver halide, etc. are also suitably used.
- the near-red ray blocking function when an electromagnetic wave shield using a silver thin film is used, it is possible to simultaneously block near-infrared rays due to scattering by silver free electrons.
- a mesh, ink patterning, or development method when a mesh, ink patterning, or development method is used, a film that absorbs or reflects near infrared rays is used separately.
- a functional transparent layer such as a known antireflection layer, antiglare layer, hard coat layer, antistatic layer or antifouling layer can be added to the display front filter of the present invention.
- UV-blocking acrylic plates may be used as substrates, and UV-blocking acrylic plates may be used as substrates, or UV-absorbing layers may be formed on one or both sides of the substrate.
- the composition for a front film for a display of the present invention may contain an ultraviolet absorber.
- ultraviolet absorbers include salicylic acid derivatives (UV-1), benzophenone derivatives (UV-2), Nzotriazole derivatives (UV-3), acrylonitrile derivatives (UV-4), benzoic acid derivatives (UV-5), or organometallic complex salts (UV-6). Phenyl, 4-tert-phenylsalicylic acid, etc.
- UV-2 such as 2-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, and (UV-3) as 2- (2 (-Hydroxy 1 5 '-methyl phenyl) 1 benzotriazole, 2-(2' -hydroxy 3 '-5-Gipuccino refeninore) 5-black mouth Benzotriazonore etc.
- UV-4 2-ethylhexyl 2 siano 3, 3 '— diphenylatarylate, methyl- ⁇ -cyano ⁇ -( ⁇ methoxyphenyl) acrylate, etc.
- UV —5 include resorcinol monomonobenzoate, 2', 4 '—Di-t-butyl Nitrogen 3,5—t-butyl 4-hydroxybenzoate, etc.
- UV—6 include Nikke Norebisoctylphenylsulfamide, Ethyl 3,5-dibutyltinoleyl 4-hydroxybenzyl phosphate nickel A salt etc. can be mentioned.
- the above-described ultraviolet absorber preferably used in the present invention is a benzotriazole-based ultraviolet absorber or a UV absorber excellent in the effect of preventing deterioration of optical devices such as polarizing plates, liquid crystal elements, and plasma displays having high transparency.
- Nzophenone UV absorbers are preferred and less unwanted coloring! / Benzotriazole UV absorbers are particularly preferred! /.
- a functional transparent layer such as a known antireflection layer, antiglare layer, hard coat layer, antistatic layer or antifouling layer can be added to the display front filter of the present invention.
- any known display device or commercially available display device can be used without any particular limitation. Can do.
- a plasma display panel display device is a device that displays a color image according to the following principle.
- a display electrode pair is provided between the front glass plate and the rear glass plate, and cells corresponding to each pixel (R (red), G (green), B (blue)) provided between the two glass plates are provided.
- Xenon gas or neon gas is sealed in the cell, and a phosphor corresponding to each pixel is applied to the back glass plate side in the cell. Due to the discharge between the display electrodes, xenon gas and neon gas in the cell are excited and emitted, and ultraviolet rays are generated. By irradiating the ultraviolet rays with the ultraviolet rays, visible light corresponding to each pixel is generated.
- An address electrode is provided, and a signal is applied to the address electrode to control which discharge cell is displayed and display a color image.
- the display front filter according to the present invention can be suitably used as a neon cut filter for selectively blocking emission of neon gas in a cell.
- the force of performing color display by the light emission of the phosphor S so-called neon centering around 600 nm (580 to 590 nm) when neon atoms return to the ground state after being excited. It is known to emit orange light (Journal of the Institute of Image Information and Television Engineers, Vol. 51, No. 4, P. 459—463 (1997)).
- the plasma display has a drawback in that a bright red color cannot be obtained by mixing orange with red! In order to eliminate this drawback, it is desired to cut off neon emission.
- the compound of the present invention when used as a composition for a neon emission absorption filter, it is preferable that the compound of the present invention has an absorption maximum at 560 to 620 nm in a solution state at 580 to 605 nm. More preferably, it has an absorption maximum.
- the transmittance of the filter at the absorption maximum in the wavelength region of 560 to 620 nm is preferably in the range of 0.0;! To 80%; and more preferably in the range of! To 70%.
- the absorption waveform in the wavelength region of 560 to 62 Onm is sharp.
- the absorption waveform at 560 to 20 nm is preferably 20 to 70 nm with a half-width value (the width of the wavelength region showing the absorbance at half the absorption maximum) of 15 to 100 nm. Is more preferably 25 to 50 nm.
- a 0.5% dimethoxyethane solution of Exemplified Compound (11) of the present invention was prepared, and coated on a glass substrate with a bar coater and dried to prepare a coated glass.
- This film had a reddish purple color, and it was found that the compound of the present invention effectively absorbs visible light.
- a 1.0% tetrahydrofuran solution of the exemplary compound (11) of the present invention and a 20% dimethoxyethane solution of a polyester resin (dispersion medium) are mixed in a ratio of 2: 8, and coated on a glass substrate with a bar coater and dried.
- a coating film was prepared. This film had a reddish purple color, and the compound of the present invention was able to effectively absorb visible light even in a composition containing a dispersion medium.
- the visible light absorbing filter 2A 11 A 2B 1 IB of the present invention and the comparative visible light absorbing filter 12A 14A 12B 14B were similarly used except that the dye used was changed from the exemplified compound (11) to the dye shown in Table 2.
- the dye of filter 13A and 13B, comparison compound 1 + MS-1 is a mixture of comparison compound 1 and bis (acetylacetate) nickel in dimethoxyethane solution or tetrahydrofuran solution. It was.
- ⁇ Dye remaining rate is less than 80% Practically, a dye residual ratio of 90% or more is preferable.
- AA AEab is less than 1.5, chromaticity change is indistinguishable
- A: AEab is less than 1.5-3.2 and almost no change in chromaticity is felt
- AEab is less than 3.2 to 6.5 and looks the same color sensuously
- the dye of the present invention effectively absorbs visible light and is a visible light absorption filter excellent in light resistance and heat and moisture resistance. Furthermore, by using the dye of the present invention as a mixture with a dispersion medium, it is possible to provide a visible light absorption filter that exhibits superior light resistance and wet heat resistance and is excellent in fastness.
- the light resistance and heat and humidity resistance are the dyes of the present invention.
- the dye of the present invention is excellent in fastness such as light resistance and wet heat resistance, and can provide a visible light absorption filter with little change in dye concentration and color change over a long period of time.
- the coloring composition prepared as described above, respectively, as the finishing Ca ⁇ fin click content of the dye was weighed in an amount of 2 mass 0/0, 15% ethylene glycol, glycerol 15%, Sir Finolhu 465 ( (Manufactured by Nissin Chemical Industry Co., Ltd.) 0.3%, and the remainder was pure water, and further filtered through a 2 m membrane filter to remove dust and coarse particles to obtain an ink composition IJ1. Except that the exemplified compound (13) was replaced with the dyes shown in Table 3, IJ 2 to 10 were obtained in the same manner.
- each ink was printed on Konica Photojet paper Photolike QP glossy paper (manufactured by Konica Minolta Co., Ltd.) using a commercially available Epson inkjet printer (PM-800), and the evaluation of the obtained image was as follows. It went about the item.
- the rate of decrease in the reflection spectral density% at the maximum absorption wavelength in the visible region from the unexploded sample after 72 hours of xenon light (70000 rutus) was calculated. Calculated and evaluated according to the following criteria.
- the pigment remaining rate is less than 80%, and the color appears cloudy visually.
- the pigment residual rate is 85% or more ( ⁇ , ⁇ )!
- Table 3 shows the results of the evaluation.
- the ink of the present invention has a vivid color tone and is superior in light resistance, water resistance and heat and humidity resistance to the comparative example.
- comparative ink IJ 9 using chelate! /, Na! /, And squarylium compounds as dyes is significantly inferior in light resistance and water resistance.
- comparative ink IJ 10 using comparative compound 4, which is a metal chelate dye is superior in terms of color tone and water resistance, but has problems in light resistance and wet heat resistance.
- Comparative ink IJ 11 using a mixture as a pigment does not have excellent color tone, and has light resistance, water resistance and heat and humidity resistance.
- the above dispersion was mixed with 60 g of a low molecular weight polypropylene emulsion dispersion, After adding 220 g of nomer, 40 g of n-butyl acrylate monomer, 12 g of methacrylic acid monomer, and 5.4 g of t-dodecyl mercaptan as a chain transfer agent and 2000 ml of degassed pure water, stirring was performed under a nitrogen stream. While maintaining at 70 ° C for 3 hours, emulsion polymerization was carried out.
- the obtained reaction solution was filtered, washed with water, dried and crushed to obtain colored particles.
- the colored particles and silica fine particles (number average primary particle size 12 nm) 1.0 part by mass were mixed with a Henschel mixer (manufactured by Mitsui Miike Chemical Co., Ltd.) to obtain color toners 10 to 18 by a polymerization method.
- the above color toner and developer are set in the developing machine of a commercially available color image forming device “Koni-Force 9331” (manufactured by Konica Mica Business Technologies Co., Ltd.) that employs an electrophotographic method, and the following evaluation items are evaluated. It was. In order to clarify the difference in color toner performance, the color toner was evaluated so that it could be used in all four color development units. As evaluation samples, reflection images (images on paper) and transmission images (OHP images) were prepared on paper and OHP, respectively. The color toner adhesion amount was adjusted to be in the range of 0.65 to 0.75 mg / cm 2 . Each image sample obtained was evaluated for light resistance, heat and humidity resistance, and transparency of OHP images.
- ⁇ Dye remaining rate is less than 80%, and the color appears slightly cloudy by visual inspection.
- the pigment remaining rate is less than 80%, and the color appears to be cloudy visually.
- the transparency of the OHP image was evaluated based on the spectral transmittance at each of the following wavelengths.
- a 330-type self-recording spectrophotometer manufactured by Hitachi, Ltd.
- the spectral transmittance was measured at Yellow 570 nm, magenta 650 nm, and cyan 500 nm, and evaluated according to the following criteria.
- ⁇ Spectral transmittance is 80% or more and transparency is very good.
- Spectral transmittance is 70% or less, resulting in poor transparency and practical problems.
- Table 4 shows the results of the evaluation.
- the image produced using the color toner of the present invention showed good moisture heat resistance, high res and HP quality, and the color toner of the present invention was used as a full color toner. Is suitable. Furthermore, an image produced using the color toner of the present invention has good light resistance and can be stored for a long time.
- a recording layer (thickness 90 nm) is applied using the dye (16) of the present invention, a reflective layer (Ag, thickness lOOnm), a protective film (ultraviolet hard).
- Acrylic resin having a thickness of 5 ⁇ was sequentially formed according to a conventional method to produce an optical recording medium 1 of the present invention.
- Comparative optical recording media 2 to 5 were produced in the same manner except that the dyes shown in Table 5 below were used instead of the dye (16) used in the production of the optical recording medium 1. However, in optical recording media 2 and 5, a mixture of a dye and 1.0% by mass of an anti-fading agent ( ⁇ -6) was applied as a recording layer. When the reflectances of the optical information recording media 1 to 5 thus produced were measured, they each showed a good value of 70% or more.
- Table 5 shows the results of the evaluation.
- the optical recording medium of the present invention To 3 was able to perform good recording and reproduction satisfying the DVD standard. In addition, it was revealed that the recording and reproducing characteristics were particularly excellent in light resistance.
- the optical recording medium 3 for comparison shows a phenomenon in which the reflectance decreases with the reproduction light of the laser, causing a reproduction failure, and the optical recording media 3 and 4 cannot be recorded even by light exposure with a xenon fade meter. It was. When the residual ratio of the dye was measured, it was found that the comparative optical recording media 3 and 4 significantly decreased the residual ratio after light exposure.
- Example 6 color filter
- a red (R) mosaic pattern, a green (G) mosaic pattern, and a blue (B) mosaic pattern were formed on a glass plate by the following method. Using the components shown below, photosensitive coating agents for color filters of red (R), green (G) and blue (B) were prepared.
- the photosensitive polyimide resin varnish used is a photosensitive polyimide resin varnish containing a photosensitizer.
- Color material B 1 10 parts
- the glass plate treated with the silane coupling agent was set on a spin coater, and the above-mentioned red color filter photosensitive coating agent was first spin-coated at 300 rpm for 5 seconds and then at 20 OOrpm for 5 seconds. Next, pre-beta was performed at 80 ° C. for 15 minutes, a photomask having a mosaic pattern was brought into close contact, and exposure was performed with an ultrahigh pressure mercury lamp at a light amount of 900 mJ / cm 2 .
- the present invention was exactly the same except that the R dye (121), G dye (2-63), and B dye B-1 were changed to the dyes shown in Table 6.
- RGB power filter CF-2 to 4 and comparative RGB color filter CF-5 to 7 were prepared.
- the color tone, heat resistance, and light resistance of the obtained filter were evaluated by the following methods.
- the glass substrate with the undercoat layer on which the pattern was formed was heated with a hot plate at 200 ° C. for 3 hours so as to be in contact with the substrate surface, and the chromaticity change before and after heating, ie, A Eab was measured.
- a color difference meter CR-400 manufactured by Konica Minolta Sensing was used for the measurement of chromaticity. A smaller ⁇ Eab value indicates that the heat resistance is better.
- the glass substrate with the undercoat layer on which the pattern was formed was irradiated with a xenon lamp for 10 days at 70,000 lutas, and then the chromaticity change, that is, the ⁇ Eab value was measured.
- the color difference meter CR-400 manufactured by Konica Minolta Sensing was used for the measurement of chromaticity. A small value of ⁇ Eab value indicates excellent light resistance.
- Table 6 shows the results of the evaluation.
- the color filter CF- ;! to CF-4 of the present invention is a comparative color filter CF
- Example 7 (Front Filter for Display) A polyethylene terephthalate (PET) film (thickness: 100 ⁇ m) was mixed with a 0.4% methyl ethyl ketone / toluene mixed solution (methyl) of the dye (123) of the present invention.
- Ethyl ketone / toluene 1: 1) 0.5 g, 6.5 g of a 20% methyl ethyl ketone / toluene mixed solution of polyester resin, and then coated with a bar coater and dried to give a film thickness of 5 m coating film was obtained.
- the transmittance curve of this coating film has a minimum value at 590 nm.
- the minimum wavelength of visible light transmittance is in the neon emission wavelength region of 580 to 600 nm, so neon light that can effectively absorb neon light emission with high transmittance.
- a UV absorbing coating solution (Sumitomo Osaka Cement Co., Ltd.) containing an isocyanate resin as a binder and zinc oxide as an ultraviolet absorber on the PET resin opposite to the metal complex-containing layer surface of the coating film 1
- the film was coated with a coater and dried to form an ultraviolet absorbing layer having a film thickness of 3 Hm. In the filter, the minimum wavelength of the visible light transmittance did not change.
- cyclohexanone of infrared absorbing dye N, N, N ', N f —tetrakis (p-dibutylaminophenyl) —p-phenylene dimonium hexafluoroantimonate
- 0.5% cyclohexanone of infrared absorbing dye N, N, N ', N f —tetrakis (p-dibutylaminophenyl) —p-phenylene dimonium hexafluoroantimonate
- 0.5% cyclohexane of the above near-infrared absorbing dye (N, N, N ', N'-tetrakis (p-dibutylaminophenol) p-phenol dimonium hexafluoride antimonate)
- N, N, N ', N'-tetrakis (p-dibutylaminophenol) p-phenol dimonium hexafluoride antimonate) Mix 0.5 g of hexanone solution and 0.4 g of 0.4% cyclohexanone solution of the dye (1-23) of the present invention into 6.5 g of 20% cyclohexane solution of polyester resin, and add PET film (thickness 100 m) was coated with a bar coater and dried to obtain a coating film having a thickness of 6 am.
- the coating film contains 2- (2'-hydroxy-5'methylphenyl) monobenzotriazole as an ultraviolet absorber on the surface of the PET resin opposite to the near-infrared absorbing dye and the metal complex-containing surface of the present invention.
- the UV absorbing coating solution was coated with a bar coater and dried to form a 311 m UV absorbing layer.
- a front filter for display having an ultraviolet absorbing layer was obtained in the same manner as the coating film 2 except that the comparative compound 8 was used instead of the compound (123) of the present invention.
- the dye residual ratio% at the maximum absorption wavelength in the visible region from the unexploded sample after 50 hours of xenon light explosion from the ultraviolet absorbing layer surface was calculated. %Met. Further, the dye residual ratio% at the maximum absorption wavelength in the visible region of the sample after being stored at 60 ° C. and 90% RH for 500 hours was calculated to be 85.4%, compared with the case where the dye of the present invention was used. It was found to be inferior in light resistance and heat and humidity resistance.
- a front filter for display having a near-infrared absorbing layer was obtained in the same manner as the coating film 3 except that the comparative compound 8 was used instead of the compound (123) of the present invention.
- the same light resistance test was conducted and the residual pigment ratio (%) was measured. As a result, it was 68.6%.
- the result of the same heat and humidity resistance test was 70.3%.
- a neon emission absorption filter and an ultraviolet ray absorption which can effectively absorb neon emission having excellent light resistance and moist heat resistance and high transmittance.
- Layer, infrared absorption layer, etc.-'could provide a front filter for
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Abstract
L'invention concerne un nouveau composé complexe squarylium-métal; un colorant qui a une teinte préférée pour une reproductivité des couleurs dans la plage visible et présente une excellente solidité telle qu'une résistance aux intempéries et une stabilité au stockage; une composition; une encre; un toner; un support d'enregistrement optique; un filtre de couleur et un filtre avant pour un dispositif d'affichage contenant le colorant. Ce composé complexe squarylium-métal est caractérisé par le fait qu'il présente une structure partielle représentée par la formule générale suivante (1). (Dans la formule, M représente un atome de métal, R, représente un substituant, et m représente un entier de 0 à 3. A représente un groupe organique).
Priority Applications (1)
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JP2008535306A JP5250837B2 (ja) | 2006-09-20 | 2007-08-30 | 新規なスクアリリウム金属錯体化合物、色素及びこれを含有する組成物、カラートナー、インク、光記録媒体、カラーフィルター及びディスプレイ用前面フィルター |
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JP2006254134 | 2006-09-20 | ||
JP2006-254134 | 2006-09-20 |
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WO2008035554A1 true WO2008035554A1 (fr) | 2008-03-27 |
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PCT/JP2007/066879 WO2008035554A1 (fr) | 2006-09-20 | 2007-08-30 | Nouveau composé complexe squarylium-métal, colorant et composition, toner de couleur, encre, support d'enregistrement optique, filtre de couleur et filtre avant pour dispositif d'affichage contenant le colorant |
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WO (1) | WO2008035554A1 (fr) |
Cited By (5)
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WO2016031574A1 (fr) * | 2014-08-29 | 2016-03-03 | 富士フイルム株式会社 | Composition, film durci, procédé de formation de motif, filtre de couleur, procédé de production de filtre de couleur, élément d'imagerie à l'état solide et dispositif d'affichage d'image |
US9310538B2 (en) | 2009-07-06 | 2016-04-12 | Osram Opto Semiconductors Gmbh | Composition for producing a filter material for radiation, method for producing a composition for a filter material, material for filtering radiation, and an optoelectronic device comprising the material |
WO2016208258A1 (fr) * | 2015-06-24 | 2016-12-29 | 富士フイルム株式会社 | Composition absorbant l'infrarouge proche, filtre bloquant l'infrarouge proche, procédé permettant de produire un filtre bloquant l'infrarouge proche, appareil, procédé permettant de produire un polymère contenant du cuivre et polymère contenant du cuivre |
JPWO2017018202A1 (ja) * | 2015-07-29 | 2018-06-28 | 富士フイルム株式会社 | 樹脂組成物、樹脂膜、樹脂膜の製造方法、光学フィルタ、インク、装置、j会合体およびj会合体の製造方法 |
JP2019163233A (ja) * | 2018-03-16 | 2019-09-26 | 東友ファインケム株式会社Dongwoo Fine−Chem Co., Ltd. | 化合物 |
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Cited By (12)
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US9310538B2 (en) | 2009-07-06 | 2016-04-12 | Osram Opto Semiconductors Gmbh | Composition for producing a filter material for radiation, method for producing a composition for a filter material, material for filtering radiation, and an optoelectronic device comprising the material |
EP2452215B1 (fr) * | 2009-07-06 | 2017-08-09 | OSRAM Opto Semiconductors GmbH | Composition pour produire une matière filtrante destinée à un rayonnement, procédé pour préparer une composition pour produire une matière filtrante, matière destinée à filtrer un rayonnement et composant optoélectronique comprenant cette matière |
WO2016031574A1 (fr) * | 2014-08-29 | 2016-03-03 | 富士フイルム株式会社 | Composition, film durci, procédé de formation de motif, filtre de couleur, procédé de production de filtre de couleur, élément d'imagerie à l'état solide et dispositif d'affichage d'image |
CN106661342A (zh) * | 2014-08-29 | 2017-05-10 | 富士胶片株式会社 | 组合物、硬化膜、图案形成方法、彩色滤光器、彩色滤光器的制造方法、固态摄影元件以及图像显示装置 |
JPWO2016031574A1 (ja) * | 2014-08-29 | 2017-07-27 | 富士フイルム株式会社 | 組成物、硬化膜、パターン形成方法、カラーフィルタ、カラーフィルタの製造方法、固体撮像素子および画像表示装置 |
CN106661342B (zh) * | 2014-08-29 | 2019-07-16 | 富士胶片株式会社 | 组合物、硬化膜、图案形成方法、彩色滤光器及其制造方法、固态摄影元件及图像显示装置 |
WO2016208258A1 (fr) * | 2015-06-24 | 2016-12-29 | 富士フイルム株式会社 | Composition absorbant l'infrarouge proche, filtre bloquant l'infrarouge proche, procédé permettant de produire un filtre bloquant l'infrarouge proche, appareil, procédé permettant de produire un polymère contenant du cuivre et polymère contenant du cuivre |
JPWO2016208258A1 (ja) * | 2015-06-24 | 2018-06-07 | 富士フイルム株式会社 | 近赤外線吸収性組成物、近赤外線カットフィルタ、近赤外線カットフィルタの製造方法、装置、銅含有ポリマーの製造方法および銅含有ポリマー |
JPWO2017018202A1 (ja) * | 2015-07-29 | 2018-06-28 | 富士フイルム株式会社 | 樹脂組成物、樹脂膜、樹脂膜の製造方法、光学フィルタ、インク、装置、j会合体およびj会合体の製造方法 |
JP2019163233A (ja) * | 2018-03-16 | 2019-09-26 | 東友ファインケム株式会社Dongwoo Fine−Chem Co., Ltd. | 化合物 |
TWI770368B (zh) * | 2018-03-16 | 2022-07-11 | 南韓商東友精細化工有限公司 | 化合物、著色樹脂組合物、彩色濾光片及顯示裝置 |
JP7101111B2 (ja) | 2018-03-16 | 2022-07-14 | 東友ファインケム株式会社 | 化合物 |
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