WO2008018461A1 - Module de cellule solaire amélioré utilisant un absorbant - Google Patents

Module de cellule solaire amélioré utilisant un absorbant Download PDF

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Publication number
WO2008018461A1
WO2008018461A1 PCT/JP2007/065448 JP2007065448W WO2008018461A1 WO 2008018461 A1 WO2008018461 A1 WO 2008018461A1 JP 2007065448 W JP2007065448 W JP 2007065448W WO 2008018461 A1 WO2008018461 A1 WO 2008018461A1
Authority
WO
WIPO (PCT)
Prior art keywords
solar cell
function
cell module
absorption function
adsorbent
Prior art date
Application number
PCT/JP2007/065448
Other languages
English (en)
Japanese (ja)
Inventor
Satoru Kuriyagawa
Katsuya Tabuchi
Tomoo Munakata
Original Assignee
Showa Shell Sekiyu K.K.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Shell Sekiyu K.K. filed Critical Showa Shell Sekiyu K.K.
Publication of WO2008018461A1 publication Critical patent/WO2008018461A1/fr

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Classifications

    • H—ELECTRICITY
    • H02—GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02S—GENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S30/00—Structural details of PV modules other than those related to light conversion
    • H02S30/10—Frame structures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042—PV modules or arrays of single PV cells
    • H01L31/048—Encapsulation of modules
    • H01L31/0488—Double glass encapsulation, e.g. photovoltaic cells arranged between front and rear glass sheets
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00—Energy generation through renewable energy sources
    • Y02E10/50—Photovoltaic [PV] energy
    • Y02E10/541—CuInSe2 material PV cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present invention relates to an improved solar cell module using an adsorbent for moisture (moisture) and / or gas.
  • a general CIS thin film solar cell module 1D without an adsorbent is made up of a CIS thin film solar cell submodule 3 (shown in Fig. 2) formed on a glass substrate 2A.
  • the device 2 is electrically connected by patterning) and the aluminum frame 5 is attached to the peripheral edge of the structure with the cover glass 4 attached (attached) via the filler 8 via the sealant 6
  • the CIS thin-film solar cell submodule 3 that is the most important part for photovoltaic power generation is sandwiched between the cover glass 4 on the upper surface and the glass substrate 2A on the lower surface, and the glass absorbs gases such as moisture and oxygen.
  • a general crystalline Si solar cell module 1E without an adsorbent is sealed with a filler 8 in which a plurality of crystalline Si cells 22 are electrically connected as shown in FIG.
  • a cover glass 4 is mounted on the back surface, and a back sheet 7 is attached to the back surface, and the peripheral edge of the structure is mounted with an aluminum frame 5 via a seal material 6.
  • the upper surface of 22 is covered with glass.
  • the lower surface passes moisture or other gases compared to glass. Since it is covered with a filler 8 and a back sheet (Tedlar film, etc.) 7 that is easy to generate a reactive gas from itself and more than the CIS-based thin film solar cell module 1A, It is necessary to take measures against deterioration of the reaction gas.
  • a translucent material having a function of holding a filler and a function of protecting the solar cell provided between the surface coating material of the solar cell module and the solar cell.
  • a hygroscopic resin molded body for example, Patent Document 3 containing a hygroscopic material that absorbs moisture that has penetrated into batteries, electronic components, or electronic devices other than solar cells.
  • a hygroscopic material that absorbs moisture that has penetrated into batteries, electronic components, or electronic devices other than solar cells.
  • the resin is preferably a fluorine type or a polyolefin type.
  • the shape of the resin is sheet, pellet, plate, film, or granular (granulated body), and if necessary, a gas adsorbent (inorganic porous material such as silica, alumina, synthetic zeolite) in the resin molded body Can be blended.
  • a gas adsorbent inorganic porous material such as silica, alumina, synthetic zeolite
  • the conventional technology using an adsorbent that absorbs moisture and an adsorbent that absorbs a gas such as oxygen is used for a relatively indoor device such as a battery, an electronic component, or an electronic device. Therefore, it is difficult to divert immediately to a device that is used in a harsh environment such as a solar cell and requires a long service life.
  • Patent Document 1 Japanese Patent Application Laid-Open No. 7-288333
  • Patent Document 2 JP 2001-321631 A
  • Patent Document 3 International Publication No. 01/088041 Pamphlet
  • Patent Document 4 Japanese Patent Laid-Open No. 2001-354780
  • Patent Document 5 Japanese Patent Laid-Open No. 2002-124374
  • Patent Document 6 Japanese Patent Laid-Open No. 2002-270366
  • the present invention solves the above problems, and an object of the present invention is to provide a sealing material by virtue of the structure of a solar cell module in which a solar cell device is formed between two upper and lower glass plates.
  • a simple and low-cost structure or manufacturing method that eliminates the use of water, moisture entering the solar cell module from the outside, moisture absorbed during the assembly process, moisture or gas generated by chemical reactions inside the module, etc. It absorbs, prevents the deterioration of the solar cell module, and improves the service life.
  • the present invention is a structure in which a solar cell submodule in which a plurality of solar cell device (or cell) portions are electrically connected by a conductive pattern is sandwiched between two glass plates. Made solar cell module,
  • the peripheral edge of the inner space formed between the two glass plates has a sealing action, and has any of a moisture absorption function, a water absorption function, and a gas absorption function (oxygen absorption function, oxygen supplement function).
  • This is an improved solar cell module using an adsorbent provided with an adsorbent having a function composed of one or a combination thereof.
  • a cover glass is installed on the upper surface of a solar cell submodule in which a plurality of solar cell device (or cell) portions are electrically connected by a conductive pattern, and the solar cell submodule
  • a solar cell module having a structure in which a back sheet is installed on the back surface via a filler
  • a space formed by the lower surface of the peripheral edge of the cover glass and the upper surface of the filler (or backsheet) has a sealing function adjacent to the submodule, and has a moisture absorption function, a water absorption function, and a gas absorption function. It is a solar cell module using an adsorbent characterized by installing an adsorbent having a function consisting of any one of (oxygen absorption function, oxygen supplement function) or a combination thereof.
  • a plurality of layers formed by laminating an alkali barrier layer (which may be omitted), a metal back electrode layer, a CIS light absorption layer, a buffer layer, and a window layer in this order on a glass substrate.
  • a solar cell module having a structure in which a cover glass is installed on the upper surface of a CIS-based thin-film solar cell sub-module in which the CIS-based thin-film solar cell device portions are electrically connected by a conductive pattern.
  • a plurality of layers formed by laminating an alkali barrier layer (which may be omitted), a metal back electrode layer, a CIS light absorption layer, a buffer layer, and a window layer in this order on a glass substrate.
  • an alkali barrier layer which may be omitted
  • a metal back electrode layer which may be omitted
  • a CIS light absorption layer a buffer layer
  • a window layer in this order on a glass substrate.
  • a solar cell module comprising: A space formed by the lower surface of the peripheral edge of the cover glass and the upper surface of the filler (or backsheet) has a sealing function adjacent to the submodule, and has a moisture absorption function, a water absorption function, and a gas absorption function.
  • An improved solar cell that uses an adsorbent with an adsorbent having a function consisting of any one of (oxygen absorbing function, oxygen supplementing function) or a combination of these functions can be used with Monyu Nore.
  • the present invention uses the structure of a solar cell module in which a solar cell device is formed between two upper and lower glass plates, and eliminates the use of a sealing material at the peripheral edge of the glass plate to absorb moisture and / or Or by installing a gas adsorbent, it absorbs moisture or oxygen or other gas generated in the internal space between the two glass plates through the glass plate peripheral edge opening, and has a sealing effect,
  • a simple and low-cost structure or manufacturing method can prevent the deterioration of the solar cell module and improve the service life.
  • FIG. L (a) A configuration diagram (cross-sectional view) of an improved solar cell module (between a CIS-based thin film solar cell module and two glass plates) using the adsorbent of the present invention. (B) Configuration diagram (plan view) of the solar cell module.
  • FIG. 2 is a configuration diagram (cross-sectional view) of a CIS-based thin film solar cell device portion that is a part of the configuration of an improved solar cell module using the adsorbent of the present invention.
  • FIG. 3 is a configuration diagram (cross-sectional view) of another example of the improved solar cell module using the adsorbent of the present invention (CIS-based thin film solar cell module, back surface filler).
  • FIG. 4 is a schematic configuration diagram (cross-sectional view) of another example (non-CIS solar cell module, between two glass plates) of an improved solar cell module using the adsorbent of the present invention.
  • FIG. 5 is a schematic configuration diagram (cross-sectional view) of another embodiment of the improved solar cell module using the adsorbent of the present invention (non-CIS solar cell module, back surface filler).
  • FIG. 6 is a schematic configuration diagram (sectional view) of a conventional CIS-based thin-film solar cell module that does not use an adsorbent.
  • FIG. 7 is a schematic configuration diagram (sectional view) of a conventional crystalline Si solar cell module that does not use an adsorbent. Explanation of symbols
  • Non-CIS solar cell device (or cell)
  • the solar cell module of the present invention is an improved solar cell module that uses an adsorbent that absorbs moisture, oxygen, or other gas. Simplified with only the adsorption that absorbs moisture entering the solar cell module from the outside, moisture absorbed during the assembly process, moisture generated by chemical reaction inside the module or oxygen and other gases at the glass peripheral edge It uses a structure adsorbent.
  • the basic structure of the improved solar cell module 1 using the adsorbent of the present invention is a plurality of CIS-based thin-film solar cell device portions 2 (see Fig. 2).
  • CIS-based thin film solar cell submodule 3 that is electrically connected to each other is heated and crosslinked with EVA resin film, and the cover glass 4 is pasted on the glass substrate 2 A on the back side.
  • the back sheet 7 is attached via an EVA resin film, and an aluminum frame 5 is attached to the outer periphery of the structure via a sealing material 6.
  • the CIS-based thin film solar cell device portion 2 has a basic structure as shown in FIG. 2, and a glass substrate 2A made of soda-lime glass or the like, and an alkali barrier layer 2B (may be omitted). ), Metal back electrode layer (generally, Mo) 2C, p-type CIS light absorption layer 2D, high-resistance buffer layer 2E, n-type window layer (transparent conductive film) 2F It is a stacked pn heterojunction device with a substrate structure.
  • the light absorption layer 2C is a multi-component compound semiconductor thin film, particularly a HII-VI group chalcopyrite semiconductor, for example, copper indium selenide (CuInSe), copper indium selenide, gallium (CuInGaSe), copper diselenide.
  • a HII-VI group chalcopyrite semiconductor for example, copper indium selenide (CuInSe), copper indium selenide, gallium (CuInGaSe), copper diselenide.
  • p-type semiconductor power such as copper indium selenide and gallium (CuInGaSe) having a thin layer of indium diselenide, copper indium gallium gallium (Cu (InGaXSSe)) as a surface layer is also obtained.
  • the CIS thin film solar cell module 1 has an alkali barrier layer 2B (may be omitted), a metal back electrode layer 2C, a p-type CIS light absorption layer 2D, on a glass substrate 2A.
  • High-resistance buffer layer 2E n-type window layer (transparent conductive film) CIS-based thin-film solar cell sub-module 3 in which multiple CIS-based thin-film solar cell device sections 2 stacked in this order are electrically connected by a conductive pattern 3
  • a crosslinked ethylene bulua is heated to cause a polymerization reaction.
  • Cover glass 4 made of white plate semi-strengthened glass, etc.
  • EVA setate resin film
  • an aluminum frame 5 is attached to the peripheral edge of the glass through a sealing material 6.
  • EVA setate
  • an aluminum frame 5 is attached to the peripheral edge of the glass through a sealing material 6.
  • EVA setate resin film
  • an aluminum frame 5 is attached to the peripheral edge of the glass through a sealing material 6.
  • the sealing action at the peripheral edge of the space formed by the cover glass 4 on the upper surface and the glass substrate 2 A on the lower surface, and also has a moisture absorption function, a water absorption function, and a gas absorption function ( It has a structure in which an adsorbent 9 having a function of any one of oxygen absorption function and oxygen supplement function) or a combination thereof is installed.
  • the force using the sealing material 6 and the adsorbing material 9 have a sealing function, so the sealing material 6 can be omitted.
  • the module may have a structure in which a back sheet 7 is attached to the back surface of the glass substrate via a filler.
  • a cover glass 4 is attached to the upper surface of the CIS-based thin film solar cell submodule 3 formed on the glass substrate 2 A, and a filler 8 is attached to the rear surface of the glass substrate.
  • the sub glass is inserted into the space formed by the lower surface of the cover glass peripheral end and the upper surface of the peripheral end of the filler 8 (or back sheet 7)
  • Adsorbent 9 is installed adjacent to module 3 and has a function of any one or combination of moisture absorption function, water absorption function, gas absorption function (oxygen absorption function, oxygen supplement function). By doing so, the moisture (moisture) and / or gas absorption effect is exhibited.
  • the present invention is not limited to the CIS-based thin-film solar cell module, and even solar cell modules such as crystalline (substrate type, super-straight type), amorphous silicon, and tandem, as shown in FIG.
  • a non-CIS solar cell with a structure in which a non-CIS solar cell submodule 3 in which a plurality of solar cell devices (or cells) are electrically connected by a conductive pattern is sandwiched between two glass plates
  • the battery module 1B can be applied.
  • the battery module 1B has a sealing action at the peripheral end portion of the internal space formed between the two glass plates, and has a moisture absorption function, a water absorption function, Moisture (moisture) ⁇ gas absorption by installing an adsorbent with a function consisting of one or a combination of any one of these gas absorption functions (oxygen absorption function, oxygen supplement function) Achieve the results.
  • the present invention provides a crystal system that is not limited to the CIS-based thin film solar cell module. (Substrate type, super straight type), amorphous silicon and other solar cell modules can be applied. Specifically, as shown in Fig.
  • adsorbing material 9 is bonded in advance to the peripheral edge of glass 4 and cover glass 4 is covered by thermocompression bonding (via EVA resin)
  • adsorbing material 9 is simultaneously glass substrate 2A and cover glass 4 It is melt-fixed in the vicinity of the peripheral edge of the.
  • the adsorbent 9 can be attached by the simple method.

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  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Photovoltaic Devices (AREA)

Abstract

La présente invention permet d'éliminer un matériau d'étanchéité au moyen d'un absorbant, d'absorber l'eau et les gaz comme l'oxygène à l'aide d'une structure ou d'un procédé de fabrication simple et économique et d'améliorer la durabilité d'un module de cellule solaire en empêchant sa détérioration. Un absorbant (9) est appliqué à la périphérie de substrats de verre supérieur et inférieur, c'est-à-dire d'un verre de couverture (4) et d'un substrat de verre (2A), un sous-module de cellule solaire (3) (couche génératrice de lumière) étant ainsi formé. Puisque l'absorbant absorbe l'eau ou les gaz comme l'oxygène et similaires entrés par une ouverture à la périphérie du substrat de verre et/ou générés dans un espace à l'intérieur des deux substrats de verre, et que l'absorbant présente des effets d'étanchéité, cela empêche la détérioration du module de cellule solaire. Ce type de dispositif de cellule solaire est applicable à tous les dispositifs, y compris les pellicules minces CIS, qui n'utilisent pas de verre inférieur et comportent une charge sur leur surface arrière.
PCT/JP2007/065448 2006-08-11 2007-08-07 Module de cellule solaire amélioré utilisant un absorbant WO2008018461A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006-219731 2006-08-11
JP2006219731A JP2008047614A (ja) 2006-08-11 2006-08-11 吸着材を利用した改良型太陽電池モジュール

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WO2008018461A1 true WO2008018461A1 (fr) 2008-02-14

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TW (1) TW200818528A (fr)
WO (1) WO2008018461A1 (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6743800B1 (en) 1999-07-02 2004-06-01 Aventis Pharma Deutschland Gmbh Naphthyridine derivatives, processes for their preparation, their use and pharmaceutical compositions comprising them
CN106788189A (zh) * 2016-12-26 2017-05-31 江苏林洋新能源科技有限公司 一种光伏组件固定装置及其安装方法
EP2600426A3 (fr) * 2011-11-29 2017-08-02 LG Innotek Co., Ltd. Appareil à cellule solaire
CN114765226A (zh) * 2021-05-24 2022-07-19 北京劲吾新能源科技有限公司 一种减缓uv油墨降解的彩色光伏组件及其制作方法
CN115427142A (zh) * 2019-12-17 2022-12-02 洛桑联邦理工学院(Epfl) 设置有用于吸附有毒物质的吸附材料的钙钛矿太阳能电池

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CN102931260A (zh) * 2008-10-31 2013-02-13 陶氏康宁公司 光生伏打电池组件和形成方法
JP5340312B2 (ja) * 2008-12-26 2013-11-13 京セラ株式会社 光電変換モジュール
JP2012038956A (ja) * 2010-08-09 2012-02-23 Kaneka Corp 薄膜太陽電池モジュール
KR101231493B1 (ko) * 2011-01-24 2013-02-07 엘지이노텍 주식회사 태양전지 모듈
KR101220060B1 (ko) * 2011-04-08 2013-01-21 엘지이노텍 주식회사 태양전지 및 이의 제조방법
JP5909839B2 (ja) * 2012-03-30 2016-04-27 住友化学株式会社 光電変換装置

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JPH01223778A (ja) * 1988-03-03 1989-09-06 Matsushita Electric Ind Co Ltd 太陽電池モジュール
JPH10271859A (ja) * 1997-03-25 1998-10-09 Taiyo Kogyo Kk 太陽光発電装置
JPH10299353A (ja) * 1997-04-28 1998-11-10 Showa Shell Sekiyu Kk 複層ガラス一体型太陽電池パネル
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JP2003026455A (ja) * 2001-07-13 2003-01-29 Sharp Corp 太陽電池モジュール
US20030079772A1 (en) * 2001-10-23 2003-05-01 Gittings Bruce E. Sealed photovoltaic modules
JP2006165386A (ja) * 2004-12-09 2006-06-22 Showa Shell Sekiyu Kk Ｃｉｓ系薄膜太陽電池及びその作製方法
JP2006179626A (ja) * 2004-12-22 2006-07-06 Showa Shell Sekiyu Kk Ｃｉｓ系薄膜太陽電池モジュール、該太陽電池モジュールの製造方法及び分離方法

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6743800B1 (en) 1999-07-02 2004-06-01 Aventis Pharma Deutschland Gmbh Naphthyridine derivatives, processes for their preparation, their use and pharmaceutical compositions comprising them
EP2600426A3 (fr) * 2011-11-29 2017-08-02 LG Innotek Co., Ltd. Appareil à cellule solaire
CN106788189A (zh) * 2016-12-26 2017-05-31 江苏林洋新能源科技有限公司 一种光伏组件固定装置及其安装方法
CN106788189B (zh) * 2016-12-26 2018-10-12 江苏林洋新能源科技有限公司 一种光伏组件固定装置及其安装方法
CN115427142A (zh) * 2019-12-17 2022-12-02 洛桑联邦理工学院(Epfl) 设置有用于吸附有毒物质的吸附材料的钙钛矿太阳能电池
CN114765226A (zh) * 2021-05-24 2022-07-19 北京劲吾新能源科技有限公司 一种减缓uv油墨降解的彩色光伏组件及其制作方法

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JP2008047614A (ja) 2008-02-28

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