200818528 九、發明說明： 【發明所屬之技術領域】 本發明係關於利㈣氣（水分）及/或氣體之吸附材的改 良型太陽電池模組。 【先前技術】 解决％保問4之-方法，雖屬於潔淨能源的太陽電池係 :眾主所||^[7潛在有因太陽電池劣化導致財用年限減 广=Η題太陽電池劣化原因之—係由從外部滲入太陽電 池核、、且内的水分造成，將有在模組内部依化學反應等所生 成的水分或氧等生成氣體而造成等情形，為提升太陽電池 的耐用年限’將必需抑制因上述水分或氧等生成氣體，導 致太陽電池裝置、或將該等電氣式轉接的搞接導電膜（導 電體）等，發生腐蝕或變質情形而劣化的情況。 未設置吸附材的一般CIS系薄膜太陽電池模组id，係 如圖6所示，在玻璃基板2AJL所形成的⑴系薄膜太陽 , τ α z所不衣置2施行圖案化而電氣式耦 妾物）中，隔著填充材8貼附（安裝）覆蓋玻璃4，且形成 在該構造體周端部隔著密封材6安装銘框5的構造，光發 電最重要，分的上述Cis系薄膜太陽電池副模組3，心 上面的覆盍玻璃4與下面的玻璃基板2A所包夾，因為破 璃具有未使濕氣、氧等氣體通㉟，且本身不會釋放濕氣的 =質，因而必需採取防止因從2片玻璃周端開放部滲入濕 乳、從玻璃内部空間的構件所產生濕氣或反應氣體，而造 成劣化情形的對策。 312XP/發明說明書(補件)/96·1〇/96129522 200818528 未設置吸附材的一般結晶Si系太陽電池模組1E，係如 圖7所示，將複數結晶Si單元22施行電氣式耦接物，利 用填充，8施行密封，並在其上面安裝覆蓋玻璃4，在背 面貼附著月襯片7，形成在該構造體周端部隔著密封材6 ，裝鋁框5的構造，複數結晶Si單元22上面係由玻璃覆 盖丄而下面則利用相較於玻璃之下，屬於濕氣或其他氣體 較容易通過，且本身亦容易發生反應氣體的填充材8、或 / =襯片（TEDLAR薄膜等)7被覆’因而相較於上述CIS系薄 '膜太陽電池模組1A之下，更必需採取因濕氣或反應氣體 所造成劣化情形的對策。 再者，太陽電池防止水分渗人的對策，係有如將在太陽 電池模組表面被覆材與太陽電池之間，所設置具有填充材 保持機能與太陽電池保護機能的透光性不織布或織布之 尺平方向尺寸縮小，藉由使上述不織布或織布端部位於較 太陽電池模組端部更靠内侧位置處，俾防止水分從不織布 。或織布端部渗人（例如參照專利文獻丨），此技術係在太陽 電池模組内使用不織布或織布的特殊構造，並無法適用於 -般太陽電池模組’防止因水分或氧等生成氣體造成劣化 情形的對策。 再者，除太陽電池以外的電池、電子零件或電子裝置 等，為防止因濕度劣化（例如在組褒步驟中因所吸收的水 分而造成）、或因應外部環境的相對濕度變化而通過密封 =的水分所造成等情形，而内設調濕複合材的技術（例如 多照專利文獻2) ’該調濕複合材的基本組成係乾燥劑（無 312ΧΡ/發明說明書(補件)/96_10/96129522 . 200818528 具夕潮解性與職性祕土族金屬氧㈣）、或氣體吸收劑 /等切、彿石、分子”），並在樹脂表面上將 σ亥等械細粉末狀物質固定化。 、恳=脸的’含有吸濕材的吸濕性樹脂成形體，該吸 人除太陽電池料的電池、電子零件或電子裝 為=ίΓ及收的技術(例如專利文獻3)，吸濕材最好 ，丨、、双奴孟屬虱化物（Ca0、Ba〇、Mg〇、Sr0)及硫酸鹽中至 ^種。樹脂係高分子材料中最好為氟系、聚稀烴系等。 =狀係有：:薄片狀、顆粒狀、板狀、薄膜狀、粒狀(造 "-’可視需要在樹脂成形體内調配入氣體吸附材(二氧 化矽、氧化鋁、合成沸石等無機多孔質材料）。 再者，同樣的，亦有在吸濕性成形體中設置貫通孔，該 吸濕性成形體係將滲入除太陽電池以外的電池、電子零件 或電子裝置等中之水分吸收的技術（例如專利文獻^ 再者，亦有在顯示裝置中，於基板與密封蓋的密封部界 2面附近處，設置將水分或氧中至少—者吸收的吸收劑層， 且依覆蓋該吸收劑層的方式’設置密封層的技術(例如專 利文獻5)。並揭示會吸收水分的吸收劑係有如心〇咄⑹、 Si〇、CaCh、鹼金屬、鹼土族金屬，而會吸收氧的吸收劑 係有如經活性化金屬材料，例如·· Ca、等。然後， 將上述吸收劑層中會吸收水分的吸收劑、會吸收氧的、吸收 劑包裝於微膠囊中的技術（例如專利文獻6)。 如上述，習知使用會吸收水分之吸附材、會吸收氧等氣 體之吸附材的技術，係利用於諸如電池、電子零件或電子 312ΧΡ/發明說明書(補件)/96-10/96129522 η 200818528 裝置等，比較屬於室内使用的裝置，因而較難使用於諸如 太陽電池在戶外嚴苛環境中，且亦頗難直接轉用於200818528 IX. Description of the Invention: [Technical Field of the Invention] The present invention relates to a modified solar cell module for a (four) gas (moisture) and/or gas adsorbing material. [Prior Art] Solving the problem of %Bao 4 - Although it belongs to the solar cell system of clean energy: the mainstay||^[7 Potentially due to the deterioration of the solar cell due to the deterioration of the solar cell = the cause of the deterioration of the solar cell - In the case of infiltration of the solar cell nucleus from the outside, and the inside of the module is caused by the formation of a gas such as moisture or oxygen generated by a chemical reaction inside the module, etc., in order to improve the durability of the solar cell, It is necessary to suppress the formation of a gas by the above-mentioned water, oxygen, or the like, and the solar cell device or the electrically conductive film (conductor) that is electrically transferred may be deteriorated due to corrosion or deterioration. The general CIS-based thin film solar cell module id, in which no adsorbent material is provided, is as shown in Fig. 6. The (1) thin film sun formed by the glass substrate 2AJL, τ α z is not patterned, and is electrically coupled. In the material, the cover glass 4 is attached (mounted) via the filler 8 and the structure in which the frame 5 is attached to the peripheral end portion of the structure via the sealing material 6 is the most important part of the photovoltaic power generation. The solar cell sub-module 3, the cover glass 4 on the upper side of the core and the underlying glass substrate 2A are sandwiched, because the broken glass has a gas that does not allow gas such as moisture or oxygen to pass through, and does not release moisture itself. Therefore, it is necessary to take measures against the occurrence of deterioration due to moisture or a reaction gas generated by the components which penetrate the wet milk from the open end of the two glass ends and from the internal space of the glass. 312XP/Invention Manual (Supplement)/96·1〇/96129522 200818528 A general crystalline Si-based solar cell module 1E in which no adsorbent material is provided, as shown in FIG. 7, an electrical coupling of the plurality of crystalline Si units 22 is performed. By using the filling, 8 is sealed, and the cover glass 4 is attached thereto, and the moon lining sheet 7 is attached to the back surface, and the structure of the aluminum frame 5 is formed at the peripheral end portion of the structure body via the sealing member 6, and the plurality of crystalline Si is formed. The upper part of the unit 22 is covered with glass and the lower part is made of a filler material 8 or a lining sheet (TEDLAR film, etc.) which is relatively easy to pass through moisture or other gases, and which is also prone to reaction gas itself. 7 coating 'and thus it is necessary to take measures against deterioration caused by moisture or reactive gas under the above-mentioned CIS thin thin film solar cell module 1A. In addition, the countermeasure against the infiltration of the solar cell by the solar cell is such that a light-transmitting non-woven fabric or woven fabric having a filler holding function and a solar cell protection function is provided between the surface covering material of the solar cell module and the solar cell. The size of the ruler is reduced in size, and the end of the non-woven fabric or the woven fabric is located at an inner side of the end of the solar battery module to prevent moisture from being woven. Or the end of the woven fabric is infiltrated (for example, refer to the patent document ,), which is a special structure in which a non-woven fabric or a woven fabric is used in a solar cell module, and cannot be applied to a general solar battery module to prevent moisture or oxygen, etc. A countermeasure for generating a gas causing deterioration. In addition, batteries, electronic components, or electronic devices other than solar cells are sealed to prevent deterioration due to humidity (for example, due to moisture absorbed in the stacking step) or in response to changes in relative humidity of the external environment. The technology of the moisture-conducting composite is provided in the case of moisture (for example, Patent Document 2) The basic composition of the humidity-conditioning composite is a desiccant (no 312 ΧΡ / invention manual (supplement) / 96_10/96129522 200818528 The deliquescent and occupationality of the earth metal oxygen (4)), or the gas absorbent / equal cut, the Buddha stone, the molecule"), and the fine powdery substance such as σhai is immobilized on the surface of the resin. = a hygroscopic resin molded body containing a hygroscopic material, which is a battery, an electronic component, or an electronic device that incorporates a solar cell material, such as a technique (for example, Patent Document 3). , 丨, 双 奴 孟 孟 ( ( ( Ca Ca Ca Ca Ca ( ( 。 。 。 。 。 。 。 。 。 。 。 。 。 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂 树脂There are: flake, granular, plate, film Granular (made "-' can be blended into a gas-adsorbing material (inorganic porous material such as ceria, alumina, or synthetic zeolite) in a resin molded body. Further, similarly, it is also formed in hygroscopicity. A through hole is provided in the body, and the hygroscopic molding system penetrates a technique of absorbing moisture in a battery, an electronic component, an electronic device, or the like other than a solar cell (for example, Patent Document), and also in a display device, on a substrate In the vicinity of the two sides of the seal portion boundary of the seal cap, a technique of providing an absorbent layer that absorbs at least one of moisture or oxygen and providing a seal layer so as to cover the absorbent layer (for example, Patent Document 5) is provided. The absorbent which reveals moisture absorption is a heart metal (6), Si〇, CaCh, an alkali metal, an alkaline earth metal, and an absorbent which absorbs oxygen is, for example, an activated metal material such as Ca, etc. Then, An absorbent which absorbs moisture in the absorbent layer and absorbs oxygen and which absorbs the absorbent in a microcapsule (for example, Patent Document 6). As described above, it is known to use an adsorbent which absorbs moisture. A technique that absorbs an adsorbent material such as a gas, such as a battery, an electronic component, or an electronic 312 ΧΡ / invention manual (supplement) / 96-10/96129522 η 200818528 device, etc., is relatively difficult to use for indoor use, and thus is difficult Used in environments such as solar cells that are harsh outdoors, and difficult to use directly
期耐用年限的裝置。 R 專利文獻1:日本專利特開平7-288333號公報 專利文獻2:日本專利特開2001-321631號公報 專利文獻3:國際公開第01/088041號書冊 專利文獻4:日本專利特開200卜354780號公報 專利文獻5:日本專利特開2002-124374號公報 專利文獻6:日本專利特開2002-270366號公報 【發明内容】 (發明所欲解決之問題） 本毛月係為解決上述問題而完成，本發明目的在於活用 於上下板間形成太陽電池裝置的太陽電池模组 構造，省略使用密封材，並依簡單且低成本的構造或製造 方法，將從外部滲人太陽電池模組内的水分、在組褒步驟 中：吸收的水分、在模組内部因化學反應等而生成的水分 或氣體卩及其他氣體吸收，俾防止太陽電池模組發生劣 化f月开>，且提升耐用年限。 (解決問題之手段） 複mm制吸附材之改良型太陽電池模組，係將 的太陽裝置（或單元）部，利用導電圖案電氣式耦接 陽電池模:副:r，挾持設置於2片玻璃板間之構造的太 在上述由2片玻璃板所挾持形成的内部空_端部係 3聰發明說明書(補件)⑽職卿 8 200818528 ’且具有吸濕機 能、氧補充機能） 設有吸附材，該吸附材係具有密封作用 能、吸水機能、氣體吸收機能（氧吸收機 中任一或该荨組合機能。 (2)本發明的利用吸jj付奸士 及附材之太除電池模組，係在將複婁 太陽電池裝置（或單开彳立β $ 一 k飞早几）部，利用導電圖案電氣式耦接的太 陽電池副模組上面，母罟舜葚士 、， b _ σ置復孤玻璃，並在上述太陽電池副 买組为面，隔著填充材設置背襯片之構造的太陽電池模 組；其中， 、 在由上述覆蓋玻璃周端部下面、與填充材（或背觀片） 周而上面所形成的空間内設有吸附#，該吸附材係鄰接 上述副核組’並具有密封作用’且具有吸濕機能、吸水機 能、氣體吸收機能（氧吸收機能、氧補充機能）中任一或該 等組合機能。 ~ (3) 本發明的利用吸附材之改良型太陽電池模組，係將 在玻璃基板上，依序積層著：鹼阻障層（亦可省略）、金屬A device that lasts for a long period of time. R Patent Document 1: Japanese Patent Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. [Patent Document 5: Japanese Patent Laid-Open Publication No. 2002-124374] Patent Document 6: Japanese Patent Laid-Open Publication No. 2002-270366 (Summary of the Invention) The present invention is completed to solve the above problems. The object of the present invention is to use a solar cell module structure for forming a solar cell device between upper and lower plates, omitting the use of a sealing material, and infiltrating the moisture in the solar cell module from the outside according to a simple and low-cost structure or manufacturing method. In the grouping step: the absorbed moisture, the moisture or gas generated by the chemical reaction inside the module, and other gases are absorbed, and the solar cell module is prevented from deteriorating, and the durability is improved. (Means for Solving the Problem) The improved solar cell module of the multi-mm adsorbent material is a solar device (or unit) portion electrically connected to the anode battery module by a conductive pattern: sub: r, held in two pieces The structure between the glass plates is too much in the above-mentioned internal space formed by two glass plates. The invention is supplemented by the manual (supplement) (10), and the system has the functions of moisture absorption and oxygen replenishment. The adsorbent material has a sealing function, a water absorbing function, a gas absorbing function (any one of the oxygen absorbing machine or the hydrazine combination function). (2) The present invention uses the absorbing jj to treat the traitor and the attached material. The module is a solar cell sub-module that is electrically coupled by a conductive pattern, such as a solar cell device (or a single opening). _ σ 复 孤 孤 , , , , , 置 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳 太阳(or a back view) formed on the top of the week The space is provided with adsorption #, which is adjacent to the above-mentioned sub-core group 'and has a sealing function' and has any one or combination of moisture absorption function, water absorption function, gas absorption function (oxygen absorption function, oxygen replenishment function) ~ (3) The improved solar cell module using the adsorbent according to the present invention is laminated on the glass substrate in sequence: an alkali barrier layer (may also be omitted), metal
月面電極層、cis系光吸收層、緩衝層、及窗層的複數cIS 系薄膜太陽電池裝置部，利用導電圖案電氣式耦接而形成 c IS系薄膜太陽電池副模組，並在其上面設置覆蓋玻璃構 造的太陽電池模組； 在由上述上面覆蓋玻璃與下面玻璃基板所挾持形成空 間的周端部係設有吸附材，該吸附材係具有密封作用，且 具有吸濕機能、吸水機能、氣體吸收機能（氧吸收機能、 氧補充機能）中任一或該等組合機能。 (4) 本發明的利用吸附材之改良型太陽電池模組，係將 312XP/發明說明書(補件)/9卜1 ο/% 129522 9 200818528 在玻璃基板上，依序積層著：鹼阻障層（亦可省略 背面電極層、ns系光吸收層、緩衝層、及窗層的複數-屬 糸薄膜太陽電池裝置部’利料電圖案電氣式 CIS系薄膜太陽電池副模組，並在其上面設置：成 且在上述玻璃基板背面隔著填充材設 陽電池模組；其中， 乃稱k的太 在由上述覆蓋玻璃周端部下面、與填充材（或背 周端部上面所形成空間内設有吸附材，該吸附材係鄰接上 述副模組，並具有密封作用，且具有吸濕機能、吸水 氣體吸收機能（氧吸收機能、氧補充機能）中任一或該^^且 (發明效果） 本發明係活用於上下2片玻璃板間形成太陽電池裝置 的太陽電池模組構造，玻璃板周端部將省略使用密封材， 藉由設置吸濕及/或氣體吸附材，便將從玻璃板周Λ端開口 (部滲入的濕氣、或在2片玻璃板間的内部空間中所生成的 或氧及其他氣體吸收，且具有密封效果，藉此便可依 簡單且低成本構造或製造方法，防止太陽電池模組劣化， 並提升耐用年限。 【實施方式】 以下，針對本發明實施形態進行說明。 本發明的太陽電池模組係利用將水分或氧及其他氣體 吸收之吸附材的改良型太陽電池模組，更詳言之，利用在 模組的上下2片玻璃周端部僅設置將從外部滲入太陽電 312ΧΡ/發明說明書(補件)/96^0/9^9522 10 200818528 池模、、且内的水刀、在組裝步驟中所吸收的水分、在模組内 口p依化予反應等所生成水分或氧及其他氣體，吸收並吸附 的屬於簡單構造利用吸附材裝置。 本發明利用吸附材之改良型太陽電池模組1的基本構 造，係如圖1所示，利用圖案化而將複數個CIS系薄膜太 陽電池裝置部2(參照圖2)電氣式㈣的CIS系薄膜太陽 电池田j模組3，利用屬於黏著劑的經加熱、交聯之樹 ^月曰薄膜貼附著覆蓋玻璃4，背面側則在玻璃基板2A上， 、利用經加熱、交聯的EVA樹脂薄膜貼附著背襯片7的構 造，在該構造體外周圍利用密封材6安裝著鋁框5。 上述CIS系薄膜太陽電池裝置部2係如圖2所示基本構 造，在由藍色玻璃板等構成的玻璃基板2A上面，依照鹼 阻障層2B(亦可省略）、金屬背面電極層（一般係M〇)2c、p 形CIS系光吸收層2D、高電阻緩衝層2E、n形窗層（透明 導電膜）2F的順序，依序積層著高品質薄膜層的基板構造 L pn異質接面裝置。上述光吸收層2C係多元化合物半導體 薄膜，特別係由I-ΙΠ—Vh族黃銅礦半導體構成，例如由： 二硒化銅銦（CuInSe〗）、二硒化銅銦•鎵（CuInGaSe2)、二 石西化銅鎵（CuGaSe2)、二硫化硒銅銦•鎵 (Cu(InGa)(SSe)2)、二硫化銅銦（CuInS2)、二硫化銅鎵 (CuGaS2)、二硫化銅銦•鎵（CuInGaS2)、具有薄膜二硫化 石西銅銦•鎵（Cu( InGa)(SSe)2)表面層的二石西化銅銦•鎵 (CuInGaSe2)之類的p形半導體構成。 以下就本發明利用吸附材之改良型太陽電池模組，針對 312XP/發明說明書(補件乂队丨⑽犯松〕 11 200818528 CIS系薄膜太陽電池模組的情況進行說明。 CIS系薄膜太陽電池模組1 ’係如圖1所示，將在玻璃 基板2A上，依照鹼阻障層2β(亦可省略）、金屬背面電極 層2C、p形CIS系光吸收層2D、高電阻緩衝層2E、及n 形窗層（透明導電膜）2F的順序積層的複數CIS系薄膜太 陽電池裝置部2，利用導電圖案電氣式耦接而形成CIS系 薄膜太陽電池副模組3，並在該CIS系薄膜太陽電池副模 〆組3上，利用黏著劑之經加熱而產生聚合反應並交聯的乙 (烯-乙酸乙烯酯（以下稱「EVA」）樹脂薄膜（或薄片），設置 由白板半強化玻璃等構成的覆蓋玻璃4,並在其周端部隔 著密封材6安裝鋁框5的構造，形成由上述上面覆蓋玻璃 4與下面玻璃基板2A所挾持形成的空間周端部，設置具 有密封作用，且具有吸濕機能、吸水機能、氣體吸收機能 (氧吸收機能、氧補充機能）中任一或該等組合機能之吸附 材9的構造。圖丨中，雖使用密封材6,但因為吸附材9 〇具有密封機能，因而將可省略密封材6。 再者，上述模組亦可形成在上述玻璃基板背面隔著填充 材而貼附著背襯片7的構造。 —再者，如圖3所示，當形成於玻璃基板2A上的ns系 薄獏太陽電池副模組3上面，貼附著覆蓋玻璃4，並在上 C破璃基板月面隔著填充材8貼附背襯片7之構造的c I s ^薄膜太陽電池模組U時，利用在由上述覆蓋玻璃周端 部下面、與填充材8(或背襯片7)周端部上面所形成空間 内，设置鄰接上述副模組3，並具有密封作用，且具有吸 312XP/發明說明書(補件)/96-10/96129522 η 200818528 濕機能、吸水機能、氣體吸收機能（氧吸收機能、氧補充 機能）中任一或該等組合機能的吸附材9，便可達濕氣（水 分）及/或氣體的吸收效果。 本發明並不僅適用於上述CIS系薄膜太陽電池模組，即 便結晶系（底層配置式、上層配置式（superstrate type))、非晶矽、豐層等太陽電池模組，只要如圖4所示， 複數太陽電池裝置（或單元）部利用導電圖案電氣式耦接 ^的非ns系太陽電池副模組3,係屬於挾持設置於2片玻 、璃板間之構造的非CIS系太陽電池模組1B的話，則仍可 適應，此情況下，藉由在由上述2片玻璃板挾持形成的内 邛二間周端部，設置具有密封作用，且具有吸濕機能、吸 水機能、氣體吸收機能（氧吸收機能、氧補充機能）中任一 或該等組合機能的吸附材，便可達濕氣（水分）、氣體的吸 收效果。 再者，本發明並不僅侷限於上述CIS系薄膜太陽電池模 I組’、亦可適用於結晶系（底層配置式、上層配置式）、非晶 矽等太陽電池模組，具體而言，如圖5所示，在將複數非 CIS系太陽電池裝置（或單元）21利用導電圖案電氣式耦 接，而形成的太陽電池副模組上面，設置由白板半強化玻 稱等構成的覆蓋玻璃4，並在上述太陽電池副模組背面隔 著填充材8設置背襯片7構造的太陽電池模組1C，藉由 在由上述覆蓋玻璃4周端部下面、與填充材8(或背襯片 Ό周端部上面所形成空間内，設置鄰接上述副模組，並具 有密封作用，且具有吸濕機能、吸水機能、氣體吸收機能 312χΡ/發明說明書(補件)/96-10/96129522 ^ 200818528 (氧吸收機能、氧補右她 材，便可達安壯、1)中任—或該等組合機能的吸附 衣/絲軋（水分）、氣體的吸收效果。 電吸附材9’進行CIS系薄膜太陽 及成本降低下述’將可獲得製造步驟簡略化 二:盍，4盍上的步驟，即，在玻璃基板2A上已形 :cis糸溥膜太陽電池副模組3的構造體 玻璃4的步驟’在此之前，當於上述玻璃基板2a或覆 1 ㈣4周端部’預先黏著上述吸附材9,並（隔著EVA樹 脂）施行加熱壓接，而將覆蓋玻璃4蓋上時m及 附材9亦將在玻璃基板2A與覆蓋玻璃4的周端部附近處 熔融固接。藉由上述簡單的方法，便可安裝吸附材9。 【圖式簡單說明】 圖1中，（a)本發明利用吸附材之改良型太陽電池模組 (CIS系薄膜太陽電池模組、2片玻璃板間）的構造圖（剖視 圖）。（b)同太陽電池模組的構造圖（俯視圖）。 圖2為本發明利用吸附材之改良型太陽電池模組構 造，其中一部分的CIS系薄膜太陽電池裝置部構造圖（剖 視圖）。 圖3為本發明利用吸附材之改良型太陽電池模組，另一 實施例（CIS系薄膜太陽電池模組、背面填充材）構造圖（剖 視圖）。 圖4為本發明利用吸附材之改良型太陽電池模組，另一 實施例（非CIS系太陽電池模組、2片玻璃板間）概略構造 312XP/發明說明書(補件)/96-10/96129522 14 200818528 圖（剖視圖）。 圖5為本發明利用吸附材之改良型太陽電池模組，另一 實施例（非CIS系太陽電池模組、背面填充材）概略構造圖 (剖視圖）。 圖6為習知未利用吸附材的CIS系薄膜太陽電池模 略構造圖（剖視圖）。 '' 圖7為習知未利用吸附材的結晶Si系太陽電池模組 略構造圖（剖視圖）。 Γ【主要元件符號說明】 1 本發明CI s系薄膜太陽電池模組 1A 本發明CIS系薄膜太陽電池模組（另一實施例） 1B 本發明非CIS系薄膜太陽電池模組（另一實施例） 1C 本發明非CIS系薄膜太陽電池模組（另一實施 1D 習知CIS系薄膜太陽電池模組 1E 習知結晶S i系太陽電池模組 r 2 CIS系薄膜太陽電池裝置部 21 非CIS系太陽電池裝置（或單元） 22 結晶Si單元 2A 玻璃基板 2A’ 玻璃板 2B 鹼阻障層 2C 金屬背面電極層 2D p形CIS系光吸收層 2E 高電阻緩衝層 312XP/發明說明書(補件)/96-10/96129522 15 200818528 2F η形窗層（透明導電膜） 3 CIS系薄膜太陽電池副模組 4 覆蓋玻璃 5 鋁框 6 密封材 7 背概片 8 填充材 9 吸附材 312XP/發明說明書(補件)/96-10/96129522 16The cIS-based thin film solar cell device portion of the lunar electrode layer, the cis-based light absorbing layer, the buffer layer, and the window layer is electrically coupled by a conductive pattern to form a cIS-based thin film solar cell sub-module thereon Providing a solar cell module with a cover glass structure; an adsorption material is provided at a peripheral end portion formed by the above-mentioned upper cover glass and the lower glass substrate, and the adsorption material has a sealing function, and has a moisture absorption function and a water absorption function. Any one or combination of gas absorption functions (oxygen absorption function, oxygen replenishment function). (4) The improved solar cell module using the adsorbent according to the present invention is a layer of 312XP/invention specification (supplement)/9b1 ο/% 129522 9 200818528 laminated on a glass substrate: alkali barrier Layer (may also omit the back electrode layer, the ns-type light absorbing layer, the buffer layer, and the window layer - the 糸-type thin film solar cell device part's material electric pattern electric CIS type thin film solar cell sub-module, and Provided above: a solar cell module is disposed on the back surface of the glass substrate via a filler; wherein, k is too much under the peripheral end portion of the cover glass, and the filler material (or the space formed on the back end portion) An adsorbing material is disposed therein, and the adsorbing material is adjacent to the sub-module and has a sealing function, and has any one of the moisture absorption function and the water absorption gas absorption function (oxygen absorption function, oxygen replenishment function) or the like [Effects] The present invention is applied to a solar cell module structure for forming a solar cell device between two upper and lower glass plates, and the sealing member is omitted at the peripheral end portion of the glass plate, and by providing a moisture absorbing and/or gas adsorbing material, Glass plate The opening (the infiltrated moisture, or the oxygen or other gas generated in the internal space between the two glass plates is absorbed, and has a sealing effect, whereby the sun can be prevented by a simple and low-cost construction or manufacturing method. The battery module is deteriorated and the durability is increased. [Embodiment] Hereinafter, an embodiment of the present invention will be described. The solar battery module of the present invention is an improved solar battery module using an adsorbent for absorbing moisture or oxygen and other gases. Group, in more detail, only the solar cell 312 ΧΡ / invention manual (supplement) / 96 ^ 0 / 9 ^ 9522 10 200818528 pool module is used to be infiltrated from the outside of the upper and lower glass ends of the module, and The water knife inside, the water absorbed in the assembly step, and the moisture or oxygen and other gases generated by the reaction in the module port p, and absorbed and adsorbed are simple structures utilizing the adsorbent device. As shown in Fig. 1, the basic structure of the improved solar cell module 1 is a CIS thin film of a plurality of CIS-based thin film solar cell devices 2 (see Fig. 2) by patterning. The solar cell field j module 3 is attached to the cover glass 4 by using a heated and crosslinked tree which is an adhesive, and the back side is on the glass substrate 2A, and the heated and crosslinked EVA resin film is used. The structure of the backing sheet 7 is attached, and the aluminum frame 5 is attached to the periphery of the structure by the sealing member 6. The CIS-based thin film solar battery unit 2 is basically constructed as shown in Fig. 2, and is composed of a blue glass plate or the like. The upper surface of the glass substrate 2A is in accordance with the alkali barrier layer 2B (may also be omitted), the metal back electrode layer (generally M〇) 2c, the p-shaped CIS light absorbing layer 2D, the high-resistance buffer layer 2E, and the n-type window layer ( In the order of the transparent conductive film 2F, a substrate structure L pn heterojunction device of a high-quality thin film layer is sequentially laminated. The light absorbing layer 2C is a multi-component compound semiconductor film, in particular, composed of an I-ΙΠ-Vh group chalcopyrite semiconductor, for example: copper indium diselenide (CuInSe), copper indium diselenide gallium (CuInGaSe2), Two stone copper gallium (CuGaSe2), selenium disulfide, copper indium, gallium (Cu (InGa) (SSe) 2), copper indium disulfide (CuInS2), copper gallium disulfide (CuGaS2), copper indium disulfide / gallium ( CuInGaS2), a p-type semiconductor such as copper indium gallium (CuInGaSe2) having a surface layer of a thin film of disulphide disulphide and a gallium indium gallium (Cu(InGa)(SSe)2). In the following, the modified solar cell module using the adsorbent material of the present invention will be described with respect to the case of the 312XP/invention manual (supplement 乂 丨 (10) smashed] 11 200818528 CIS-based thin film solar cell module. As shown in FIG. 1, the group 1' will be on the glass substrate 2A in accordance with the alkali barrier layer 2β (may also be omitted), the metal back electrode layer 2C, the p-shaped CIS light absorbing layer 2D, and the high-resistance buffer layer 2E. And a plurality of CIS-based thin film solar cell devices 2 laminated in the order of the n-type window layer (transparent conductive film) 2F, electrically connected by a conductive pattern to form a CIS-based thin film solar cell sub-module 3, and in the CIS-based film On the solar cell sub-mold group 3, a B-ene vinyl acetate (hereinafter referred to as "EVA") resin film (or sheet) is produced by heating with an adhesive to be polymerized and crosslinked. The cover glass 4 is configured such that the aluminum frame 5 is attached to the peripheral end portion via the sealing member 6, and the peripheral end portion of the space formed by the upper cover glass 4 and the lower glass substrate 2A is formed to provide a sealing function. , The structure of the adsorbent material 9 having any one of the moisture absorption function, the water absorption function, the gas absorption function (oxygen absorption function, oxygen replenishment function) or the combination function. In the figure, although the sealing material 6 is used, the adsorption material 9 is used. Since the sealing function is provided, the sealing material 6 can be omitted. Further, the module may have a structure in which the backing sheet 7 is adhered to the back surface of the glass substrate via a filler. Further, as shown in FIG. When the ns-based thin solar cell sub-module 3 is formed on the glass substrate 2A, the cover glass 4 is attached, and the backing sheet 7 is attached to the moon surface of the upper C-glass substrate via the filler 8 In the case of the c I s ^ thin film solar cell module U, the sub-module 3 is disposed adjacent to the space formed on the lower surface of the peripheral end portion of the filler 8 (or the backing sheet 7) from the lower end portion of the cover glass. And has a sealing function, and has any combination or combination of wet function, water absorption function, gas absorption function (oxygen absorption function, oxygen replenishment function) of suction 312XP/invention specification (supplement)/96-10/96129522 η 200818528 The function of the adsorbent material 9 can reach moisture (water The present invention is not only applicable to the above-described CIS-based thin film solar cell module, but even a crystal system (a bottom layer type, a superstrate type), an amorphous layer, a high layer, and the like. As shown in FIG. 4, as shown in FIG. 4, the non-ns solar cell sub-module 3 electrically coupled to the solar cell device (or unit) by a conductive pattern is attached to two glass and glass plates. In the case of the non-CIS solar cell module 1B having a structure of between, it is still possible to adapt. In this case, the inner peripheral end portion formed by the two glass plates is provided with a sealing function and has a sealing function. The absorption function of moisture (moisture) and gas can be achieved by any one of the moisture absorption function, the water absorption function, the gas absorption function (oxygen absorption function, oxygen replenishment function) or the combination of these functions. Furthermore, the present invention is not limited to the above-described CIS-based thin film solar cell module I, and can be applied to a solar cell module such as a crystal system (underlayer type, upper layer type) or amorphous germanium, specifically, for example, As shown in FIG. 5, a cover glass 4 made of a whiteboard semi-reinforced glass or the like is provided on a solar cell sub-module formed by electrically coupling a plurality of non-CIS solar cell devices (or cells) 21 by a conductive pattern. And the solar cell module 1C of the backing sheet 7 is disposed on the back surface of the solar cell sub-module via the filler 8 through the underside of the cover glass 4, and the filler 8 (or the backing sheet) Adjacent to the above-mentioned sub-module in the space formed on the upper end of the periorbital end, and having a sealing function, and having a moisture absorption function, a water absorption function, a gas absorption function 312χΡ/invention specification (supplement)/96-10/96129522 ^ 200818528 (Oxygen absorption function, oxygen supplement right material, can reach the strength of the body, 1) - or the absorption function of the combined clothing / silk (water), gas absorption of the combined function. Electro-adsorption material 9' for CIS system Thin film sun and cost reduction The following steps will be made to simplify the manufacturing steps: 盍, 4盍, that is, the step of forming the structural glass 4 of the cis-film solar cell sub-module 3 on the glass substrate 2A Previously, the adsorbent 9 was adhered to the glass substrate 2a or the first (four) end portion of the cover (4), and the pressure-sensitive adhesive 9 was applied (with the EVA resin interposed therebetween). When the cover glass 4 was covered, the m and the attached material 9 were also The glass substrate 2A is melted and fixed in the vicinity of the peripheral end portion of the cover glass 4. The adsorbent material 9 can be attached by the above simple method. [Simplified Schematic] In Fig. 1, (a) the present invention utilizes an adsorbent material. The structural diagram (cross-sectional view) of the improved solar cell module (CIS-based thin-film solar cell module and between two glass plates). (b) The structural diagram (top view) of the solar cell module. Figure 2 is utilized in the present invention. A modified solar cell module structure of an adsorbent material, a part of which is a structural view (cross-sectional view) of a CIS-based thin film solar cell device. Fig. 3 is a modified solar cell module using an adsorbent according to the present invention, and another embodiment (CIS system) Thin film solar cell module, back filling Fig. 4 is a schematic view of a modified solar cell module using an adsorbent material according to the present invention, and another embodiment (a non-CIS solar cell module, between two glass plates), a schematic structure 312XP/invention specification ( Supplement)/96-10/96129522 14 200818528 Figure (cross-sectional view) Figure 5 is a schematic view of an improved solar cell module using an adsorbent material according to the present invention, and another embodiment (non-CIS solar cell module, back filler) Fig. 6 is a schematic structural view (cross-sectional view) of a conventional CIS-based thin film solar cell in which an adsorbent material is not used. '' Fig. 7 is a schematic view of a conventional crystalline Si-based solar cell module without using an adsorbent material. Figure (cross-sectional view). Γ [Main component symbol description] 1 CI s-based thin film solar cell module 1A of the present invention CIS-based thin film solar cell module of the present invention (another embodiment) 1B Non-CIS-based thin film solar cell module of the present invention (another embodiment) 1C Non-CIS thin film solar cell module of the present invention (another embodiment 1D conventional CIS thin film solar cell module 1E conventional crystal solar cell module r 2 CIS thin film solar cell device unit 21 non-CIS system Solar cell device (or unit) 22 Crystalline Si unit 2A Glass substrate 2A' Glass plate 2B Alkali barrier layer 2C Metal back electrode layer 2D P-shaped CIS light absorbing layer 2E High-resistance buffer layer 312XP / Invention manual (supplement) / 96-10/96129522 15 200818528 2F η-shaped window layer (transparent conductive film) 3 CIS-based thin film solar cell sub-module 4 Cover glass 5 Aluminum frame 6 Sealing material 7 Back-battery 8 Filling material 9 Adsorption material 312XP/Invention manual ( Supplement) /96-10/96129522 16