WO2007142177A1 - メカニカルシール - Google Patents
メカニカルシール Download PDFInfo
- Publication number
- WO2007142177A1 WO2007142177A1 PCT/JP2007/061271 JP2007061271W WO2007142177A1 WO 2007142177 A1 WO2007142177 A1 WO 2007142177A1 JP 2007061271 W JP2007061271 W JP 2007061271W WO 2007142177 A1 WO2007142177 A1 WO 2007142177A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cartridge
- mechanical seal
- back surface
- seal
- deformation
- Prior art date
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J15/00—Sealings
- F16J15/50—Sealings between relatively-movable members, by means of a sealing without relatively-moving surfaces, e.g. fluid-tight sealings for transmitting motion through a wall
- F16J15/52—Sealings between relatively-movable members, by means of a sealing without relatively-moving surfaces, e.g. fluid-tight sealings for transmitting motion through a wall by means of sealing bellows or diaphragms
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J15/00—Sealings
- F16J15/16—Sealings between relatively-moving surfaces
- F16J15/34—Sealings between relatively-moving surfaces with slip-ring pressed against a more or less radial face on one member
- F16J15/3464—Mounting of the seal
- F16J15/348—Pre-assembled seals, e.g. cartridge seals
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16J—PISTONS; CYLINDERS; SEALINGS
- F16J15/00—Sealings
- F16J15/16—Sealings between relatively-moving surfaces
- F16J15/34—Sealings between relatively-moving surfaces with slip-ring pressed against a more or less radial face on one member
- F16J15/36—Sealings between relatively-moving surfaces with slip-ring pressed against a more or less radial face on one member connected by a diaphragm or bellow to the other member
Definitions
- the present invention relates to a mechanical seal for a water pump or the like that is suitable for application to, for example, a cooling water pump of an automobile engine.
- Patent Document 1 As a conventional water pump that is preferably applied to a cooling water pump of an automobile engine, for example, a mechanical seal disclosed in Japanese Patent Application Publication No. 2000-74226 (Patent Document 1) is cited.
- the mechanical seal disclosed in Patent Document 1 has a structure as shown in FIG. That is, the mating ring 11 is fitted and fixed to a sleeve 13 that rotates together with the rotary shaft 2 with a cup gasket 12 interposed therebetween.
- the seal ring 14 that slides facing the mating ring 11 includes a bellows 15 and a case 17. Along with the driving band 19 and the coiled spring 18, it is fitted in a cartridge 96 fitted to the pump housing 3. Then, the seal ring 14 is pressed against the mating ring 11 by the urging force of the bellows 15 and the cold wave spring 18, and an appropriate surface pressure is applied to the sliding surface between them to perform an appropriate seal. Is called.
- Patent Document 1 Japanese Patent Application Publication No. 2000-74226
- the back surface portion 96d of the cartridge 96 is a portion in which material is formed in the radial direction.
- the shape of the cartridge 96 is not easily deformed in the radial direction and easily deformed in the axial direction.
- the conventional cartridge 96 as shown in FIG. 8 has a flat back surface 96d. Easy to transform! Become a shark shape! / Speak.
- the distance between the rotary shaft 2 and the pumping shaft 3 is long, and sometimes the back 96d 'of the cartridge 96' must be extended and fixed in the radial direction.
- the cartridge is easily deformed in the axial direction regardless of the length of the back surface (distance between the rotating shaft and the pump housing).
- the conventional mechanical seal has a problem in that when the cartridge is installed in the pump housing, the back surface of the cartridge is deformed in the axial direction due to the force that receives the pump housing force. It was. If such deformation occurs, the assembly length of the mechanical seal will change, and the assembly load will change accordingly, and it will not be possible to exhibit good sealing performance! .
- the present invention has been made in view of the above-described problems, and an object of the present invention is to make the mechanical seal cartridge deform in the axial direction when the mechanical canore seal is fitted to the pump housing.
- the purpose of the present invention is to provide a mechanical seal that can prevent and prevent a change in the assembly length of the mechanical seal, thereby ensuring good sealing performance.
- a mechanical seal of the present invention includes a mating ring as a sliding member fixed to a rotating shaft and rotating together with the rotating shaft, a cartridge fixed to a housing, A mechanical seal having a seal ring that is mounted on the cartridge and that slides facing the mating ring, wherein the cartridge is disposed around an outer peripheral portion fixed to the housing and the rotation shaft.
- a bent portion in which a member of the back surface portion is bent in the direction of the rotation axis is formed on the back surface in an annular shape around the rotation axis.
- the mechanical seal of the present invention having such a configuration, a portion where the member of the back surface portion is bent in the axial direction of the rotation shaft is formed in the middle of the back surface portion of the cartridge.
- the deformation in the axial direction of the back surface portion of the cartridge caused by the use environment can be absorbed by the bent portion. That is, even if the outer part of the cartridge back part is deformed in the axial direction by the action of the force from the housing, this deformation is absorbed by the bent part, and the inner part of the cartridge back part is deformed, that is, the seal.
- Deformation of the place where the ring, etc. is arranged can be restrained or even if it is deformed, it can be kept to a very small deformation. As a result, the assembly length of the mechanical seal can be prevented from changing, and good sealing performance can be ensured.
- the mechanical seal of the present invention is characterized in that a groove having a concave cross section is formed in an annular shape around the rotation axis in the back surface of the cartridge.
- a groove having a concave cross section is formed in the middle of the back surface of the cartridge, so that the outer portion of the back surface of the cartridge can be deformed. It can absorb properly, and a seal ring etc. can be placed to suppress or suppress deformation inside the cartridge, preventing changes in the assembly length of the mechanical seal, and thus good sealing performance Can be secured.
- the back surface portion of the cartridge is formed such that a position in the rotational axis direction differs between an inner region and an outer region in the radial direction of the rotational shaft.
- the step portion connecting the inner region and the outer region is formed in an annular shape around the rotation axis.
- a step portion is formed in the middle of the back surface portion of the cartridge, thereby appropriately absorbing the deformation of the outer portion of the cartridge back surface portion. It is possible to suppress or suppress the deformation inside the cartridge where the seal ring etc. are arranged, to prevent the mechanical seal assembly length from changing, and to ensure good sealing performance Can do.
- FIG. 1 is a cross-sectional view showing a configuration of a mechanical seal according to an embodiment of the present invention.
- FIG. 2 is a view showing a modification of the mechanical seal cartridge shown in FIG. 1.
- FIG. 3 is a view showing another modified example of the mechanical seal cartridge shown in FIG. 1.
- FIG. 4 is a diagram showing the deformation amount of the force cartridge when the mechanical seal shown in FIG. 1 is fitted to the pump housing.
- FIG. 5 is a view showing the amount of deformation of the cartridge when the mechanical seal having the cartridge shown in FIG. 2 is fitted to the pump housing.
- Fig. 4 is a view showing the deformation amount of the cartridge when the mechanical seal having the cartridge shown in Fig. 3 is fitted to the pump housing.
- FIG. 7 is a view showing the amount of deformation of the cartridge when the conventional mechanical seal is fitted to the pump housing.
- FIG. 8 is a cross-sectional view showing a configuration of a conventional mechanical seal.
- FIG. 9 is a cross-sectional view showing the configuration of another conventional mechanical seal.
- FIG. 1 is a cross-sectional view showing the configuration of the mechanical seal 1.
- the mechanical seal 1 includes a mating ring 11, a cup gasket 12, a sleeve 13, a sheathing ring 14, a bellows 15, a cartridge 16, a case 17, a coinore drive spring 18, and a driving band 19.
- the mating ring 11 is a sliding member that contacts the seal ring 14 on the pump housing 3 side and rotates together with the rotating shaft 2.
- a sleeve 13 fixed to the rotary shaft 2 with a force gasket 12 interposed is used, and the cross-sectional shape of the sleeve 13 is approximately “ko” (Japanese katakana “ko” ) And is press-fitted and fixed to the end 13a.
- the mating ring 11 and the sleeve 13 are provided with one or more cutout portions on the outer periphery of the mating ring 11, and this A claw-shaped portion is provided on the outer peripheral portion of the sleeve 13 so as to respond.
- the seal ring 14 is a member that is fixed to the pump housing 3 and slides toward the mating ring 11.
- the seal ring 14 is disposed adjacent to the bellows 15 and is mounted in the cartridge 16 together with a case 17, a driving band 19 and a coil drive spring 18.
- the seal ring 14 and the bellows 15 are formed by molding the outer peripheral portion 17b of the case 17 into a teno-shaped shape in advance, and after setting the seal ring 14 inside the inner cylindrical portion 15a of the bellows 15, The outer peripheral portion 17b is fixed by applying force on the outer peripheral side.
- rotation stoppers protrusions 14e of the seal ring 14 and convex parts 16e of the cartridge 16 are provided at positions opposite to the inner diameter part of the seal ring 14 and the inner cylindrical surface 16a of the cartridge 16, respectively.
- the structure suppresses the circumferential rotation and torsion of the seal ring 14 caused by torque.
- the bellows 15 is a member for sealing the liquid to be sealed and for applying an appropriate axial pressing force to the seal ring 14, and is generally formed of rubber that is an elastic body.
- the bellows 15 has a case 17 and a driving band 19 attached to the outer peripheral side thereof, and is fixed to an inner cylindrical portion (inner peripheral portion) 16 a of the cartridge 16.
- one end surface 17 a of the case 17 is bent and faces one end surface 19 b of the driving band 19. That is, when the outer peripheral portion 17b of the case 17 is pushed rightward in the figure and a force is applied in the direction in which the coiled wave spring 18 is in close contact, one end surface 17a of the case 17 and one end surface 19b of the driving band 19 are in contact with each other. As a result, the driving band 19 is pushed rightward, and as a result, the bellows 15 is attached to the inner cylinder portion 16a of the cartridge 16 at an appropriate position.
- a coil dwell spring 18 is disposed between the case 17 and the cartridge 16. The cold wave spring 18 urges the bellows 15 in the axial direction toward the seal ring 14.
- the cartridge 16 includes an outer cylinder part (outer peripheral part) 16b fixed to the pump housing 3, an inner cylindrical part (inner peripheral part) disposed around the rotary shaft 2 and provided with a seal ring 14, a bellows 15, and the like. ) 16a and a back surface portion 16d arranged in a direction (radial direction) perpendicular to the axial direction of the rotary shaft 2 so as to connect them, the sectional shape as shown in FIG. It is an annular member formed in a shape like the shape of the Japanese character (“K” in Japanese Katakana).
- the seal ring 14, bellows 15, case 17, coil drive spring 18 and driving band 19 are placed inside the cartridge 16 shaped like the shape of the letter “U”.
- the pump housing 3 side member of Cull seal 1 is arranged. Specifically, the seal ring 14 to the driving band 19 are mounted in the vicinity of the inner cylinder portion 16a of the cartridge 16 and the inner cylinder portion 16a of the back surface portion 16d.
- a part of the inner cylindrical portion 16a of the cartridge 16 is further formed on a convex portion 16e protruding toward the rotating shaft 2, and as described above, the convex portion formed on the inner diameter portion of the seal ring 14 is formed.
- the portion 14e is inserted to provide a detent structure that suppresses torsion of the seal ring 14 in the circumferential direction due to sliding torque.
- the outer cylinder portion 16b is located more in the middle of the back surface portion 16d than the portion where the coil dowel spring 18 is in contact.
- a concave portion (bent portion) 16f having a substantially triangular cross section as shown in the figure is formed in the flat plate region.
- the concave portion 16f is formed to have a certain degree of roundness in the direction of the component member force of the cartridge 16 and to be bent with a certain value of R (curvature).
- the back surface 16d of the cartridge 16 is formed in a ring shape, that is, in a groove shape, centering on 2.
- the concave portion 16f having such a cross-sectional shape in the back surface portion 16d of the cartridge 16, the radial force of the rotary shaft 2 applied to the cartridge 16 when the cartridge 16 is fitted to the pump housing 3 is used.
- the back surface 16d of the cartridge 16 is the axial direction and radial direction of the rotary shaft 2 Even if it is deformed in the direction, the deformation is absorbed by the recess 16f.
- the relative positions of the seal ring 14 and bellows 15 etc. hardly change with respect to the structure of the mating ring 11 etc. on the rotating shaft 2 side.
- the mechanical seal 1 having the above-described configuration is such that the mating ring 1 1 has the letter “C” in which the cross-sectional shape of the sleeve 13 is substantially “ko” via the cup gasket 12 (Japanese force Takana character).
- the inner ring portion 16a or lower end of the cartridge 16 is inserted into the cartridge 16 after the seal ring 14, bellows 15, etc. are fitted to the end portion 13a.
- the inner cylindrical portion 13b of the sleeve 13 is inserted inside the convex portion 16e, and the distal end portion 13c of the inner cylindrical portion 13b of the sleeve 13 is expanded, so that it is integrally manufactured as one mechanical seal device. .
- the back member is bent at the back surface portion 16d of the cartridge 16, and the cross section is formed into a concave shape (substantially triangular in the example shown in Fig. 1). Since the groove 16f is formed in an annular shape, the axial direction and radial direction deformation of the rotary shaft 2 acting on the back surface portion 16d of the cartridge 16 when the cartridge 16 is fitted to the pump housing 3 are absorbed by the concave portion 16f. Is done. As a result, it is difficult for this deformation to be transmitted to the regions near the inner cylindrical portion 16a of the cartridge 16 and the rear cylindrical portion 16a of the cartridge 16 where the seal ring 14, the bellows 15 or the coil dwell spring 18 is mounted.
- the cartridge 16 has a configuration in which a groove portion 16f having a concave cross section is provided in an annular shape around the rotating shaft 2.
- the present invention is achieved by providing a structure in which the constituent members are bent in the axial direction of the rotary shaft 2 on the back surface portion of the cartridge, and may take other forms.
- the cartridge 26 may be configured such that a step 26f is formed on the back surface portion 26d.
- the cartridge 26 shown in FIG. 2 is formed in a stepped shape so that the position in the axial direction of the rotating shaft is different between the inner region 26g and the outer region 26h of the back surface portion 26d.
- the cartridge 26 has a configuration in which an outer region 26h protrudes in an outer direction opposite to the seal ring in the rotation axis direction from an inner region 26g to which a seal ring or the like is attached.
- a connecting portion is formed so as to connect the inner region 26g and the outer region 26h.
- the connecting portion and the region in the vicinity of the connecting portion of the inner region 26g and the outer region 26h are referred to as a stepped portion 26f.
- FIG. 3 the outer region is compared with the inner region 36g where the seal ring or the like is mounted.
- 36h has a shape protruding in the seal ring direction in the rotation axis direction, and a step portion 36f is formed so as to connect the inner region 36g and the outer region 36h.
- the result of the analysis software finding the amount of deformation in the direction of the rotation axis at the position closest to the rotation axis (deformation analysis location) on the back of the cartridge when the cartridge is fitted to the pump nosing is shown.
- FEM analysis software Marc was used, and the tightening margin between the cartridge and the pump housing was set to 0.2 mm.
- the analysis results are shown in Figs. Note that the numerical value of the deformation amount is positive for the deformation analysis portion toward the back side of the cartridge and negative for the deformation side.
- the deformation of the deformation analysis portion of the cartridge 16 in which the groove 16f shown in FIG. 1 is formed in the back surface portion 16d was 0.15 mm in the back surface direction.
- the deformation of the deformation analysis portion of the cartridge 26 in which the step 26f is formed so that the outer region 26h protrudes in the rear direction on the back surface 26d shown in FIG. 2 is opposite to the back surface.
- the direction was 0. Olmm.
- the deformation of the cartridge 36 where the outer region 36h is formed on the back surface 36d shown in FIG. It was 0.27mm in the direction.
- the deformation of the deformation analysis portion of the conventional cartridge 96 having the flat back surface portion 16d shown in FIG. 8 was 0.82 mm in the back surface direction.
- the deformation amount of the back surface portion (strictly speaking, the deformation analysis portion) of the cartridge according to the present invention shown in FIGS. 1 to 3 is the same as that of FIG. Compared to other cartridges, it is significantly less. In particular, almost no deformation is observed in the cartridge in which a step is formed such that the outer region protrudes in the back direction on the back surface as shown in FIG.
- the mechanical seal according to the present invention suppresses the deformation in the rotation axis direction of the cartridge when the mechanical seal is attached to the pump housing, so that a good seal can be achieved by suppressing a change in assembly load. It is a useful mechanical seal that can maintain and exhibit performance, and is particularly useful for a mechanical seal for a water pump such as a cooling water pump of an automobile engine. In addition, the mechanical seal is not limited to this, and is also useful for an arbitrary water pump or a pump for sealing an arbitrary liquid.
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- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Mechanical Sealing (AREA)
- Structures Of Non-Positive Displacement Pumps (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020087029910A KR101420741B1 (ko) | 2006-06-08 | 2007-06-04 | 메카니컬 실링 |
US12/303,905 US8128097B2 (en) | 2006-06-08 | 2007-06-04 | Mechanical seal |
JP2008520554A JP5009909B2 (ja) | 2006-06-08 | 2007-06-04 | メカニカルシール |
EP07767020.6A EP2025976B1 (en) | 2006-06-08 | 2007-06-04 | Mechanical seal |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006-159940 | 2006-06-08 | ||
JP2006159940 | 2006-06-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2007142177A1 true WO2007142177A1 (ja) | 2007-12-13 |
Family
ID=38801428
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2007/061271 WO2007142177A1 (ja) | 2006-06-08 | 2007-06-04 | メカニカルシール |
Country Status (5)
Country | Link |
---|---|
US (1) | US8128097B2 (ja) |
EP (1) | EP2025976B1 (ja) |
JP (1) | JP5009909B2 (ja) |
KR (1) | KR101420741B1 (ja) |
WO (1) | WO2007142177A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105531518A (zh) * | 2014-01-17 | 2016-04-27 | 伊格尔工业股份有限公司 | 机械密封 |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102009049093A1 (de) * | 2009-10-01 | 2011-04-07 | Kaco Gmbh + Co. Kg | Gleitringdichtung |
JP6116575B2 (ja) * | 2012-10-04 | 2017-04-19 | イーグル工業株式会社 | メカニカルシール |
ITTO20130352A1 (it) * | 2013-04-30 | 2014-10-31 | Umbra Meccanotecnica | Tenuta meccanica |
US20150159758A1 (en) * | 2013-12-06 | 2015-06-11 | GM Global Technology Operations LLC | Engine coolant pump seal without internal bellows |
EP2942551A1 (de) * | 2014-05-06 | 2015-11-11 | Aktiebolaget SKF | Dichtungsanordnung für ein drehbar gegenüber einem weiteren Bauteil gelagertes Bauteil und Verfahren |
CN104061328A (zh) * | 2014-05-28 | 2014-09-24 | 宁波东联密封件有限公司 | 一种具有自润滑性能的机械密封 |
KR101894272B1 (ko) * | 2014-08-26 | 2018-09-04 | 이구루코교 가부시기가이샤 | 메커니컬 시일 |
WO2018124252A1 (ja) * | 2016-12-29 | 2018-07-05 | イーグル工業株式会社 | メカニカルシール |
DE102017219190B4 (de) * | 2017-10-26 | 2022-12-29 | Eagleburgmann Germany Gmbh & Co. Kg | Gasgeschmierte Gleitringdichtung mit verbessertem Verschmutzungsschutz |
FR3095847B1 (fr) * | 2019-05-06 | 2021-08-13 | Cyclam | garniture d’étanchéité COMPACTE pour assurer l’étanchéité entre un arbre rotatif et un corps stationnaire d’une machine |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2598886A (en) | 1949-06-09 | 1952-06-03 | Brummer Olin | Cartridge type seal |
JPH06156320A (ja) * | 1992-11-27 | 1994-06-03 | Toyota Motor Corp | 車体前部構造 |
JPH10122185A (ja) * | 1996-10-14 | 1998-05-12 | Aisin Seiki Co Ltd | メカニカルシール |
JP2000074226A (ja) | 1998-08-27 | 2000-03-14 | Eagle Ind Co Ltd | メカニカルシール |
WO2002016810A1 (en) | 2000-08-21 | 2002-02-28 | John Crane Inc. | Improved mechanical face seal |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2554406A (en) * | 1946-12-13 | 1951-05-22 | Crane Packing Co | Rotary fluid seal with "o" ring |
BE769207A (fr) * | 1970-06-30 | 1971-11-03 | Mecanique Ind Int | Bague d'etancheite sans ressort et a coussin de |
GB2080446B (en) * | 1980-07-17 | 1984-08-15 | Fenner Co Ltd J H | Annular fluid seals |
JP4412683B2 (ja) * | 1998-02-13 | 2010-02-10 | 東京自動機工株式会社 | 変速機 |
JP4481690B2 (ja) * | 2004-03-19 | 2010-06-16 | イーグル工業株式会社 | メカニカルシール装置 |
-
2007
- 2007-06-04 EP EP07767020.6A patent/EP2025976B1/en active Active
- 2007-06-04 WO PCT/JP2007/061271 patent/WO2007142177A1/ja active Application Filing
- 2007-06-04 JP JP2008520554A patent/JP5009909B2/ja active Active
- 2007-06-04 KR KR1020087029910A patent/KR101420741B1/ko active IP Right Grant
- 2007-06-04 US US12/303,905 patent/US8128097B2/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2598886A (en) | 1949-06-09 | 1952-06-03 | Brummer Olin | Cartridge type seal |
JPH06156320A (ja) * | 1992-11-27 | 1994-06-03 | Toyota Motor Corp | 車体前部構造 |
JPH10122185A (ja) * | 1996-10-14 | 1998-05-12 | Aisin Seiki Co Ltd | メカニカルシール |
JP2000074226A (ja) | 1998-08-27 | 2000-03-14 | Eagle Ind Co Ltd | メカニカルシール |
WO2002016810A1 (en) | 2000-08-21 | 2002-02-28 | John Crane Inc. | Improved mechanical face seal |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105531518A (zh) * | 2014-01-17 | 2016-04-27 | 伊格尔工业股份有限公司 | 机械密封 |
CN105531518B (zh) * | 2014-01-17 | 2017-07-18 | 伊格尔工业股份有限公司 | 机械密封 |
Also Published As
Publication number | Publication date |
---|---|
KR20090026278A (ko) | 2009-03-12 |
EP2025976A4 (en) | 2013-05-29 |
US20100237564A1 (en) | 2010-09-23 |
US8128097B2 (en) | 2012-03-06 |
JPWO2007142177A1 (ja) | 2009-10-22 |
JP5009909B2 (ja) | 2012-08-29 |
EP2025976A1 (en) | 2009-02-18 |
EP2025976B1 (en) | 2015-03-25 |
KR101420741B1 (ko) | 2014-07-17 |
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