WO2007116586A1 - Composition de nettoyage - Google Patents

Composition de nettoyage Download PDF

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Publication number
WO2007116586A1
WO2007116586A1 PCT/JP2007/000375 JP2007000375W WO2007116586A1 WO 2007116586 A1 WO2007116586 A1 WO 2007116586A1 JP 2007000375 W JP2007000375 W JP 2007000375W WO 2007116586 A1 WO2007116586 A1 WO 2007116586A1
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WO
WIPO (PCT)
Prior art keywords
component
cleaning composition
composition according
weight
general formula
Prior art date
Application number
PCT/JP2007/000375
Other languages
English (en)
Japanese (ja)
Inventor
Ryosuke Fujii
Yoshinori Tamura
Original Assignee
Kao Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corporation filed Critical Kao Corporation
Priority to JP2008509698A priority Critical patent/JP5101493B2/ja
Priority to KR1020087024421A priority patent/KR101453106B1/ko
Priority to CN2007800125486A priority patent/CN101415401B/zh
Publication of WO2007116586A1 publication Critical patent/WO2007116586A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/55—Phosphorus compounds
    • A61K8/556—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/34—Derivatives of acids of phosphorus
    • C11D1/342—Phosphonates; Phosphinates or phosphonites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups

Definitions

  • the present invention relates to a detergent composition having little irritation to skin and the like, excellent foaming properties, creamy quality, and good rinsing properties.
  • sulfate surfactants such as alkyl sulfates and polyoxyethylene alkyl sulfates have been widely used as surfactants for cleaning agents.
  • sulfate-based surfactants are not suitable as a cleaning agent for the body because they are light and rough in foam quality, and are not easily rinsed and rinsed.
  • phosphate ester surfactants are known as mild surfactants with low irritation to the skin, etc., but any of them is a mixture of monoester and diester or mono, di, tri. Since it was a mixture of esters, it was poor in solubility in water and foaming power. When this was used alone as a main component of a cleaning agent, there was generally a problem in foaming power.
  • Patent Document 1 Japanese Laid-Open Patent Publication No. 2 2003-3 1 3 5 8 5
  • Patent Document 2 Japanese Patent Laid-Open No. 2 0 0 6 _ 2 2 1 1 6
  • Patent Document 3 Japanese Patent Laid-Open No. 2 0 0 5 _ 2 0 6 8 0 4
  • R 1 , R 2 and R 3 each represent a linear or branched alkyl group or alkenyl group having 8 to 18 carbon atoms, and X 1 , X 2 and Y represent a hydrogen atom and an alkali, respectively.
  • a metal atom, an alkaline earth metal atom, an alkanolamine, or an ammonium salt, and the average number of moles added, k, m, and n are each 0 to 10.
  • R 4 represents an alkyl group or alkenyl group having 8 to 18 carbon atoms
  • M represents an alkali metal atom, an alkaline earth metal atom, an alkanolamine, an ammonium or a basic amino acid, and an average addition.
  • Mole number p shows the number of 0-5.
  • (C) (C-1) a linear or branched alkyl group having 6 to 12 carbon atoms, wherein ⁇ is one or more glyceryl ethers having an alkenyl group, and
  • R 5 represents a linear or branched alkyl group or alkyl group having 6 to 10 carbon atoms
  • R 6 represents a hydrogen atom or a methyl group
  • AO represents 2 to 4 carbon atoms.
  • the average number of added moles q is a number of 0.5 to 3.
  • the cleaning composition containing this is provided.
  • the present invention also provides a method for cleaning the body by applying the cleaning composition to the body.
  • the present invention provides use of the cleaning composition for body cleaning.
  • An object of the present invention is to provide a detergent composition that is less irritating to the skin and the like, is excellent in foaming properties, has a foam quality of creamy, and has good rinsing properties.
  • the cleaning composition of the present invention is less irritating to the skin and the like, has excellent foaming properties, has a creamy quality, and has good rinsing properties.
  • R 1 , R 2 and R 3 are each a carbon number It is preferably an alkyl group of 10 to 16, more preferably 12 to 14 , and X 1 , X 2 and Y are preferably an alkali metal atom such as gallium or sodium, or triethanolami, particularly Potassium is preferable from the viewpoint of solubility in water.
  • the average number of moles of ethylene oxide added k, m and n is preferably 0 to 4 moles, more preferably 0 to 2 and even more preferably 0 to 1 mole from the viewpoint of foaming power.
  • the content of the phosphoric acid ester-based surfactant of component (A) is foaming, detergency and And 1 to 15% by weight of the cleaning composition of the present invention is preferable, 2 to 10% by weight is more preferable, and 3 to 10% by weight is still more preferable.
  • Component (A) is, for example, an ethylene oxide added to a corresponding aliphatic alcohol or a corresponding aliphatic alcohol to obtain an ethoxylate having an average addition mole number of more than 0 to 10; phosphoric anhydride; Phosphoric acid ester obtained by reacting phosphoric acid such as orthophosphoric acid, polyphosphoric acid or oxyphosphoric acid, or the phosphoric acid ester partially or completely with sodium hydroxide, hydroxylated lithium, etc. It is a phosphoric ester salt obtained by neutralization.
  • a J / (a 2 ) can be controlled by the ratio between the aliphatic alcohol and the water contained in the phosphorylating agent.
  • R 4 has an average carbon number of 8 to 18, preferably 10 to 16 from the viewpoint of foamability. More preferably, they are 10 to 14 linear or branched alkyl groups or alkenyl groups.
  • M is preferably an alkali metal such as potassium or sodium, triethanolamine, or ammonium, and more preferably potassium, sodium, or ammonium from the viewpoint of solubility in water and foaming.
  • the content of the component (B) is preferably 5 to 40% by weight, more preferably 5 to 35% by weight, from the viewpoint of detergency and foaming property of the cleaning composition of the present invention, 20% by weight is even more preferred.
  • the glyceryl ether of the component (C-1) has a linear or branched alkyl group or alkenyl group having 6 to 12 carbon atoms, such as an n-hexyl group, an isohexyl group, Those having an alkyl group having 6 to 12 carbon atoms such as n-heptyl group, n-octyl group, 2_ethylhexyl group, n_nonyl group, n_decyl group, n_lauryl group, and the like are preferable. It is preferable to have 1 or 2 alkyl groups having 6 to 11 carbon atoms, 6 to 10 carbon atoms, especially 8 carbon atoms, and more preferably one.
  • One or more glyceryl ethers of component (C-1) can be used, and 0.1 to 20% by weight, further 0.1 to 10% by weight, and further 0.1 to 5% by weight in the total composition.
  • % Is preferable in terms of rinsing properties and foaming power.
  • the component (C_1) can be obtained, for example, by hydrolyzing the corresponding glycidyl ether and water at 100 to 230 ° C.
  • R 5 is a linear or branched chain having 6 to 10 carbon atoms, preferably 8 to 10 carbon atoms. And an alkyl group having 8 carbon atoms is preferred.
  • AO is an alkyleneoxy group having 2 to 4 carbon atoms, more preferably an alkyleneoxy group having 2 to 3 carbon atoms, and still more preferably an alkyleneoxy group having 3 carbon atoms. Specific examples include an ethyleneoxy group, a propyleneoxy group, and a butyleneoxy group. An ethyleneoxy group and a propyleneoxy group are preferable, and a propyleneoxy group is more preferable.
  • the average added mole number q represents a number of 0.5 to 3, preferably 1 to 3, and more preferably 2 to 3.
  • AO max is the total component (C _ 2) from the viewpoint of economy that reduces the burden of manufacturing costs such as refining. 70% by weight or less is preferable, 60% by weight More preferably, it is more preferably 50% by weight or less.
  • AO max is 60% by weight or less, further 50% by weight or less, and further 40% by weight or less of the total component (C_2). preferable.
  • AO max is 70% by weight or less, further 60% by weight or less, and further 50% by weight of the total component (C-2). % Or less is preferable.
  • R 6 represents a hydrogen atom or a methyl group, more preferably a hydrogen atom.
  • One or more components (C_ 2) can be used, and the total composition is 0.1 to 20% by weight, further 0.1 to 15% by weight 0 / o, and further 0.1 to 10% by weight. It is preferable to blend them in terms of rinsing properties and foaming power.
  • the component (C_2) can be obtained, for example, by reacting propylene oxide and / or ethylene oxide with the corresponding aliphatic alcohol and then distilling the raw material alcohol.
  • the total amount of component (C) is preferably 0.1 to 20% by weight, more preferably 0.1 to 15% by weight, more preferably 0.1 to 10% by weight in the cleaning composition of the present invention. Even more preferable.
  • the cleaning composition of the present invention is a cleaning composition useful as a skin cleaning agent such as a facial cleanser, a shampoo, a body shampoo, or a body cleaner such as a hair cleaner. It is preferably used as a skin cleanser such as body shampoo.
  • These cleaning compositions can contain optional components depending on the purpose.
  • optional components include other anionic surfactants, nonionic surfactants, amphoteric surfactants, force thionic surfactants, and conditioning components that are usually blended in these detergents. .
  • anionic surfactants include fatty acid salts, sulfosuccinic acid surfactants, sulfosuccinamate surfactants, polyoxyalkylene alkylamide ether sulfates, monoglyceride sulfates, and olefin sulfones. Acid salts, alkane sulfonates, acylated isethionates, acylated amino acid salts, polyoxyalkylene alkyl ether phosphates other than the component (A), etc.
  • nonionic surfactant examples include alkylpolydarcoside, sucrose fatty acid ester, polyglycerin fatty acid ester, fatty acid alcohol amide, alkylamine oxide, and fatty acid polyhydric alcohol ester.
  • cationic surfactants include linear or branched mono- or di-long chain alkyl quaternary ammonium salts, mono- or di-long chain alkyl tertiary amines, and the like.
  • Amide amino acid-based activator Carbobetaine-based activator, Sulfobetaine-based activator, Amidosulfobetaine-based activator, Imidazolinium betaine-based activator, Amino acid-based betaine-activator, Phosphobetaine-based activator Etc.
  • conditioning components include higher alcohols, silicone and silicone derivatives, lanolin, squalene, hydrocarbons, protein derivatives, polyethylene glycol fatty acid esters and other oil agents, cationized cellulose, cationized guagam and marcoat. (Naruco Co., Ltd.), Softcare KG-3301 W [manufactured by Kao Corporation], and the like.
  • water-soluble polymers such as polysaccharides such as methylcellulose, hydroxyethylcellulose, carboxyvinyl polymer, xanthan gum; polyoxyalkylene Viscosity modifiers such as sorbitan ester, polyoxyethylene glycol distearate, ethanol, etc .; Ethylenediamine tetraacetic acid (EDTA), phosphonates and other chelating agents; methylparaben, butylparaben and other preservatives; vitamins and precursors thereof Active ingredients of: Lecithin, animal and plant extracts such as gelatin or derivatives thereof; polymer fine powder such as Nai Nya polyethylene; anti-inflammatory agent such as dipotassium glycyrrhizinate; And anti-dandruff agents; Antioxidants such as dibutylhydroxytoluene; pearlizing agents, ultraviolet absorbers, pH adjusting agents, dyes, fragrances, and water can be
  • the detergent composition of the present invention preferably has a pH of 4-8.
  • the cleaning composition of the present invention is used with water having a hardness of 1 to 30 ° DH. Is preferred.
  • the water used here preferably has a pH of 4 to 9.
  • the cleaning composition of the present invention can be produced according to a conventional method. There are no particular limitations on the dosage form of the cleaning composition of the present invention, and various conventionally known dosage forms such as liquid body shampoos, cream facial cleansings, and the like can be used.
  • the cleaning composition of the present invention is particularly suitable as a cleaning agent for body such as skin and hair.
  • Add [P 2 0 5 ⁇ n H 2 0 and P 2 0 5 1 9.6 g (0.14 mol) H 2 0 1 2.3 g (0.68 mol)] to 35 ° C Stir and mix. Further, 62.1 g (0.43 mol) of phosphorus pentoxide (effective content 98.5% by weight) was gradually added over 60 minutes with stirring.
  • 2-Ethylhexyl glycidyl ether 208 g, water 104.8 g, laur 5.82 g of phosphoric acid and 18.5 g of potassium hydroxide were placed in an autoclave and stirred at 140 ° C. for 5 hours. After dehydration at 100 ° C under reduced pressure (6.67 k Pa), add 9.7 g of lauric acid and 2.72 g of potassium hydroxide, react at 160 ° C for 15 hours, and then distilled under reduced pressure (53-67 Pa, 120-123 ° C.), 2-ethylhexyl glyceryl ether shown in Table 1 was obtained.
  • 1-octanol (Calcoal 0898, manufactured by Kao Corporation) 1 61 5. 0 g (1 2. 35 mo I) and hydroxylated power of 6.9 g (0.12 mo I) were charged into the autoclave, After dehydration at 1 10 ° C and 13.3 kPa, addition reaction was carried out at 120 ° C while injecting 1434 g (24. 69 0 1) of propylene oxide at 0.3 MPa.
  • 1-octanol was distilled off from 1 000 g of the obtained filtrate under the conditions of 130 ° C. and 1.3 kPa. Further, steam treatment was performed by blowing 100 g of steam under the conditions of 145 ° C., 6. O k Pa, and 5 hours to obtain dipropylene glycol monooctyl ether shown in Table 1.
  • a cleaning composition having the composition shown in Table 1 was prepared by mixing each component at 70 ° C according to a conventional method (1 "1 was adjusted to 6-7), and 1 g of this was applied to the palm of the hand and arm. Foaming properties, foam quality and rinsing properties when washed were evaluated by 10 expert panelists according to the following evaluation criteria: Table 1 shows the results.
  • a face wash and whole body cleanser with a pH of 5.0-0.7.0 were prepared with the following formulation. pH was adjusted with citrate and potassium hydroxide. Both are hypoallergenic and the pH of the water used is less than 4-5, less than 5-8, and 8-9, and the hardness of the water used is 1-30 ° In all areas of DH, foaming was good, foam quality was creamy, and rinsing was good.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

La présente invention concerne une composition de nettoyage qui présente peu d'irritation sur la peau ou analogues, a une excellente capacité d'expansion, produit de la mousse crémeuse et a de bonnes propriétés de rinçage. La composition de nettoyage comprend les composants suivants (A), (B) et (C) : (A) un mélange d'agents tensioactifs de type ester d'acide phosphorique composé (a1) d'un agent tensioactif de type monoester d'acide phosphorique représenté par la formule générale (1) et (a2) d'un agent tensioactif de type diester d'acide phosphorique représenté par la formule générale (2), le rapport de concentration entre les composants (a1) et (a2) [(a1)/(a2)] allant de 90/10 à 50/50 en poids; (B) un agent tensioactif de type ester d'acide sulfurique représenté par la formule générale (3); et (C) (C-1) au moins un éther de glycéryle possédant un groupe alkyle ou alcényle linéaire ou ramifié ayant de 6 à 12 atomes de carbone et (C-2) au moins un élément choisi parmi les composés représentés par la formule générale (4).
PCT/JP2007/000375 2006-04-07 2007-04-06 Composition de nettoyage WO2007116586A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2008509698A JP5101493B2 (ja) 2006-04-07 2007-04-06 洗浄剤組成物
KR1020087024421A KR101453106B1 (ko) 2006-04-07 2007-04-06 세정제 조성물
CN2007800125486A CN101415401B (zh) 2006-04-07 2007-04-06 洗涤剂组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006106939 2006-04-07
JP2006-106939 2006-04-07

Publications (1)

Publication Number Publication Date
WO2007116586A1 true WO2007116586A1 (fr) 2007-10-18

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ID=38580888

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/000375 WO2007116586A1 (fr) 2006-04-07 2007-04-06 Composition de nettoyage

Country Status (4)

Country Link
JP (1) JP5101493B2 (fr)
KR (1) KR101453106B1 (fr)
CN (1) CN101415401B (fr)
WO (1) WO2007116586A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009275010A (ja) * 2008-05-16 2009-11-26 Kao Corp 皮膚洗浄剤組成物
JP2009275012A (ja) * 2008-05-16 2009-11-26 Kao Corp 皮膚洗浄剤組成物
JP2009275009A (ja) * 2008-05-16 2009-11-26 Kao Corp 皮膚洗浄剤組成物
WO2011158483A1 (fr) * 2010-06-18 2011-12-22 花王株式会社 Agent aqueux de lavage pour cheveux

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5730507B2 (ja) 2010-07-08 2015-06-10 花王株式会社 毛髪化粧料

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03285996A (ja) * 1990-04-02 1991-12-17 Kao Corp 洗浄剤組成物
JP2004168951A (ja) * 2002-11-21 2004-06-17 Kao Corp 洗浄剤組成物
JP2005206804A (ja) * 2003-12-26 2005-08-04 Kao Corp 洗浄剤組成物
JP2006022116A (ja) * 2003-04-14 2006-01-26 Kao Corp 洗浄剤組成物

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3093981B2 (ja) * 1996-04-05 2000-10-03 花王株式会社 洗浄剤組成物
WO2004092315A1 (fr) * 2003-04-14 2004-10-28 Kao Corporation Composition d'agent de nettoyage
US7183244B2 (en) * 2003-12-26 2007-02-27 Kao Corporation Detergent compositions comprising a mixture of phosphate esters

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03285996A (ja) * 1990-04-02 1991-12-17 Kao Corp 洗浄剤組成物
JP2004168951A (ja) * 2002-11-21 2004-06-17 Kao Corp 洗浄剤組成物
JP2006022116A (ja) * 2003-04-14 2006-01-26 Kao Corp 洗浄剤組成物
JP2005206804A (ja) * 2003-12-26 2005-08-04 Kao Corp 洗浄剤組成物

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009275010A (ja) * 2008-05-16 2009-11-26 Kao Corp 皮膚洗浄剤組成物
JP2009275012A (ja) * 2008-05-16 2009-11-26 Kao Corp 皮膚洗浄剤組成物
JP2009275009A (ja) * 2008-05-16 2009-11-26 Kao Corp 皮膚洗浄剤組成物
WO2011158483A1 (fr) * 2010-06-18 2011-12-22 花王株式会社 Agent aqueux de lavage pour cheveux
US8530398B2 (en) 2010-06-18 2013-09-10 Kao Corporation Aqueous hair cleansing agent
TWI465255B (zh) * 2010-06-18 2014-12-21 Kao Corp 水性毛髮洗淨劑

Also Published As

Publication number Publication date
JPWO2007116586A1 (ja) 2009-08-20
CN101415401B (zh) 2011-05-04
KR20080112271A (ko) 2008-12-24
JP5101493B2 (ja) 2012-12-19
KR101453106B1 (ko) 2014-10-27
CN101415401A (zh) 2009-04-22

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