WO2007116586A1

WO2007116586A1 - Cleansing composition

Info

Publication number: WO2007116586A1
Application number: PCT/JP2007/000375
Authority: WO
Inventors: Ryosuke Fujii; Yoshinori Tamura
Original assignee: Kao Corporation
Priority date: 2006-04-07
Filing date: 2007-04-06
Publication date: 2007-10-18
Also published as: JPWO2007116586A1; CN101415401B; CN101415401A; KR20080112271A; JP5101493B2; KR101453106B1

Abstract

Disclosed is a cleansing composition which shows little irritation to the skin or the like, has excellent foamability, generate creamy foam, and has good rinsing properties. The cleansing composition comprises the following components (A), (B) and (C): (A) a phosphoric acid ester surfactant mixture of (a1) a phosphoric acid monoester surfactant represented by the general formula (1) and (a2) a phosphoric acid diester surfactant represented by the general formula (2), wherein the content ratio between the components [(a1)/(a2)] is 90/10 to 50/50 by weight;. (B) a sulfuric acid ester surfactant represented by the general formula (3); and (C) (C-1) at least one glyceryl ether having a linear or branched alkyl or alkenyl group having 6 to 12 carbon atoms and (C-2) at least one member selected from compounds represented by the general formula (4).

Description

Specification

Cleaning composition

Technical field

[0001] The present invention relates to a detergent composition having little irritation to skin and the like, excellent foaming properties, creamy quality, and good rinsing properties.

Background art

Conventionally, sulfate surfactants such as alkyl sulfates and polyoxyethylene alkyl sulfates have been widely used as surfactants for cleaning agents. However, such sulfate-based surfactants are not suitable as a cleaning agent for the body because they are light and rough in foam quality, and are not easily rinsed and rinsed.

[0003]-On the other hand, phosphate ester surfactants are known as mild surfactants with low irritation to the skin, etc., but any of them is a mixture of monoester and diester or mono, di, tri. Since it was a mixture of esters, it was poor in solubility in water and foaming power. When this was used alone as a main component of a cleaning agent, there was generally a problem in foaming power.

[0004] In order to improve such foaming problems, a detergent composition containing a sulfate ester surfactant and a phosphate ester surfactant has been disclosed. 1 and Patent Document 2), the foaming power is not satisfactory, and no mention is made of rinsing properties. Further, although a detergent composition containing a phosphate ester surfactant and glyceryl ether has been disclosed (Patent Document 3), the foaming power was not sufficiently satisfactory.

Patent Document 1: Japanese Laid-Open Patent Publication No. 2 2003-3 1 3 5 8 5

Patent Document 2: Japanese Patent Laid-Open No. 2 0 0 6 _ 2 2 1 1 6

Patent Document 3: Japanese Patent Laid-Open No. 2 0 0 5 _ 2 0 6 8 0 4

Disclosure of the invention

[0005] The present invention provides the following components (A), (B) and (C): (A) ( ₃₁ ) — A mixture of a phosphate monoester surfactant represented by general formula (1) and (a ₂ ) — a phosphate diester surfactant represented by general formula (2) there, in its content ratio by weight _{_{(ai) (a 2) =}} 90 1 0 ~50 50 a is a phosphate ester surfactant:

[Chemical 1]

(In the formula, R ¹ , R ² and R ³ each represent a linear or branched alkyl group or alkenyl group having 8 to 18 carbon atoms, and X ¹ , X ² and Y represent a hydrogen atom and an alkali, respectively. A metal atom, an alkaline earth metal atom, an alkanolamine, or an ammonium salt, and the average number of moles added, k, m, and n are each 0 to 10)

(B) — General formula (3)

R ⁴ 0 (CH ₂ CH ₂ 0) _P S 0 ₃ M

(In the formula, R ⁴ represents an alkyl group or alkenyl group having 8 to 18 carbon atoms, M represents an alkali metal atom, an alkaline earth metal atom, an alkanolamine, an ammonium or a basic amino acid, and an average addition. Mole number p shows the number of 0-5.

)

A sulfate ester surfactant represented by:

(C) (C-1) a linear or branched alkyl group having 6 to 12 carbon atoms, wherein <is one or more glyceryl ethers having an alkenyl group, and

(C-2) — General formula (4)

R ⁵ 0 (AO) _q R ⁶ (4)

(In the formula, R ⁵ represents a linear or branched alkyl group or alkyl group having 6 to 10 carbon atoms, R ⁶ represents a hydrogen atom or a methyl group, and AO represents 2 to 4 carbon atoms. The average number of added moles q is a number of 0.5 to 3.

)

One or more selected from the compounds represented by:

The cleaning composition containing this is provided.

[0008] The present invention also provides a method for cleaning the body by applying the cleaning composition to the body.

Furthermore, the present invention provides use of the cleaning composition for body cleaning.

Detailed Description of the Invention

[0009] An object of the present invention is to provide a detergent composition that is less irritating to the skin and the like, is excellent in foaming properties, has a foam quality of creamy, and has good rinsing properties. The cleaning composition of the present invention is less irritating to the skin and the like, has excellent foaming properties, has a creamy quality, and has good rinsing properties.

[0010] In the phosphoric acid ester represented by the general formulas (1) and (2) of the component (A), which is a hypoallergenic base used in the present invention, R ¹ , R ² and R ³ are each a carbon number It is preferably an alkyl group of 10 to 16, more preferably 12 to ¹⁴ , and X ¹ , X ² and Y are preferably an alkali metal atom such as gallium or sodium, or triethanolami, particularly Potassium is preferable from the viewpoint of solubility in water. The average number of moles of ethylene oxide added k, m and n is preferably 0 to 4 moles, more preferably 0 to 2 and even more preferably 0 to 1 mole from the viewpoint of foaming power.

[0011] The content ratio of the alkyl phosphate monoester ( _ai ) and the alkyl phosphate ester (a ₂ ) in the component (A) is determined by weight ratio ( _ai ) (a ₂ ) from the viewpoint of ease of blending. = 90 10 to 50 50, 85 15 to 60 40 is preferable, and 80 20 to 70 30 is more preferable.

When the weight ratio (a / (a ₂ ) is less than 50 50, the foaming property is poor, and when the weight ratio (a / (a ₂ ) is more than 90 10, the melting point of the alkyl phosphate ester mixture becomes high, which makes mixing difficult. Become.

[0012] The content of the phosphoric acid ester-based surfactant of component (A) is foaming, detergency and And 1 to 15% by weight of the cleaning composition of the present invention is preferable, 2 to 10% by weight is more preferable, and 3 to 10% by weight is still more preferable.

[0013] Component (A) is, for example, an ethylene oxide added to a corresponding aliphatic alcohol or a corresponding aliphatic alcohol to obtain an ethoxylate having an average addition mole number of more than 0 to 10; phosphoric anhydride; Phosphoric acid ester obtained by reacting phosphoric acid such as orthophosphoric acid, polyphosphoric acid or oxyphosphoric acid, or the phosphoric acid ester partially or completely with sodium hydroxide, hydroxylated lithium, etc. It is a phosphoric ester salt obtained by neutralization. (A J / (a ₂ ) can be controlled by the ratio between the aliphatic alcohol and the water contained in the phosphorylating agent.

As a method of obtaining (a,) / (a ₂ ) = 90 10 0-50 50, for example, by using orthophosphoric acid containing phosphoric anhydride and water during the reaction, the ratio of the raw alcohol and water is directly adjusted. (A method of controlling the ratio of a J / (a ₂ ), (a J (a ₂ ) = 100-95 5 phosphate ester, (a JZ (a ₂ ) = 50 50 phosphate ester There is a method of mixing

In the sulfate ester surfactant represented by the general formula (3) of component (B), R ⁴ has an average carbon number of 8 to 18, preferably 10 to 16 from the viewpoint of foamability. More preferably, they are 10 to 14 linear or branched alkyl groups or alkenyl groups.

M is preferably an alkali metal such as potassium or sodium, triethanolamine, or ammonium, and more preferably potassium, sodium, or ammonium from the viewpoint of solubility in water and foaming.

[0015] The content of the component (B) is preferably 5 to 40% by weight, more preferably 5 to 35% by weight, from the viewpoint of detergency and foaming property of the cleaning composition of the present invention, 20% by weight is even more preferred.

In the cleaning composition of the present invention, the preferred content of component (A) and component (B) Although the amount is as described above, the content ratio of the component (A) and the component (B) is the weight ratio of the component (B), the component (A) = 0.5 to 20, and “! To 10”. Is preferred from the viewpoints of washing power, foaming power, foam quality and rinsing properties, and 2 to 5 are more preferred.

[0016] The glyceryl ether of the component (C-1) has a linear or branched alkyl group or alkenyl group having 6 to 12 carbon atoms, such as an n-hexyl group, an isohexyl group, Those having an alkyl group having 6 to 12 carbon atoms such as n-heptyl group, n-octyl group, 2_ethylhexyl group, n_nonyl group, n_decyl group, n_lauryl group, and the like are preferable. It is preferable to have 1 or 2 alkyl groups having 6 to 11 carbon atoms, 6 to 10 carbon atoms, especially 8 carbon atoms, and more preferably one.

One or more glyceryl ethers of component (C-1) can be used, and 0.1 to 20% by weight, further 0.1 to 10% by weight, and further 0.1 to 5% by weight in the total composition. % Is preferable in terms of rinsing properties and foaming power.

The component (C_1) can be obtained, for example, by hydrolyzing the corresponding glycidyl ether and water at 100 to 230 ° C.

[0017] In the alkylene oxide adduct of the alcohol represented by the general formula (3) of the component (C_2), R ⁵ is a linear or branched chain having 6 to 10 carbon atoms, preferably 8 to 10 carbon atoms. And an alkyl group having 8 carbon atoms is preferred. AO is an alkyleneoxy group having 2 to 4 carbon atoms, more preferably an alkyleneoxy group having 2 to 3 carbon atoms, and still more preferably an alkyleneoxy group having 3 carbon atoms. Specific examples include an ethyleneoxy group, a propyleneoxy group, and a butyleneoxy group. An ethyleneoxy group and a propyleneoxy group are preferable, and a propyleneoxy group is more preferable. The average added mole number q represents a number of 0.5 to 3, preferably 1 to 3, and more preferably 2 to 3. When the component with the largest number of moles of AO added in component (C_2) is AO _max , AO _max is the total component (C _ 2) from the viewpoint of economy that reduces the burden of manufacturing costs such as refining. 70% by weight or less is preferable, 60% by weight More preferably, it is more preferably 50% by weight or less. Further, when AO is an oxyalkylene group having 2 carbon atoms, that is, an oxyethylene group, AO _max is 60% by weight or less, further 50% by weight or less, and further 40% by weight or less of the total component (C_2). preferable. Further, when AO is an oxyalkylene group having 3 carbon atoms, that is, an oxypropylene group, AO _max is 70% by weight or less, further 60% by weight or less, and further 50% by weight of the total component (C-2). % Or less is preferable. R ⁶ represents a hydrogen atom or a methyl group, more preferably a hydrogen atom. One or more components (C_ 2) can be used, and the total composition is 0.1 to 20% by weight, further 0.1 to 15% by weight ⁰ / o, and further 0.1 to 10% by weight. It is preferable to blend them in terms of rinsing properties and foaming power.

The component (C_2) can be obtained, for example, by reacting propylene oxide and / or ethylene oxide with the corresponding aliphatic alcohol and then distilling the raw material alcohol.

The total amount of component (C) is preferably 0.1 to 20% by weight, more preferably 0.1 to 15% by weight, more preferably 0.1 to 10% by weight in the cleaning composition of the present invention. Even more preferable.

[0018] The cleaning composition of the present invention is a cleaning composition useful as a skin cleaning agent such as a facial cleanser, a shampoo, a body shampoo, or a body cleaner such as a hair cleaner. It is preferably used as a skin cleanser such as body shampoo. These cleaning compositions can contain optional components depending on the purpose. Here, examples of optional components include other anionic surfactants, nonionic surfactants, amphoteric surfactants, force thionic surfactants, and conditioning components that are usually blended in these detergents. .

[0019] Other anionic surfactants include fatty acid salts, sulfosuccinic acid surfactants, sulfosuccinamate surfactants, polyoxyalkylene alkylamide ether sulfates, monoglyceride sulfates, and olefin sulfones. Acid salts, alkane sulfonates, acylated isethionates, acylated amino acid salts, polyoxyalkylene alkyl ether phosphates other than the component (A), etc. Examples of the nonionic surfactant include alkylpolydarcoside, sucrose fatty acid ester, polyglycerin fatty acid ester, fatty acid alcohol amide, alkylamine oxide, and fatty acid polyhydric alcohol ester. Examples of cationic surfactants include linear or branched mono- or di-long chain alkyl quaternary ammonium salts, mono- or di-long chain alkyl tertiary amines, and the like. Amide amino acid-based activator, Carbobetaine-based activator, Sulfobetaine-based activator, Amidosulfobetaine-based activator, Imidazolinium betaine-based activator, Amino acid-based betaine-activator, Phosphobetaine-based activator Etc.

[0020] Examples of conditioning components include higher alcohols, silicone and silicone derivatives, lanolin, squalene, hydrocarbons, protein derivatives, polyethylene glycol fatty acid esters and other oil agents, cationized cellulose, cationized guagam and marcoat. (Naruco Co., Ltd.), Softcare KG-3301 W [manufactured by Kao Corporation], and the like.

[0021] In addition, other components usually used in the detergent composition, for example, water-soluble polymers such as polysaccharides such as methylcellulose, hydroxyethylcellulose, carboxyvinyl polymer, xanthan gum; polyoxyalkylene Viscosity modifiers such as sorbitan ester, polyoxyethylene glycol distearate, ethanol, etc .; Ethylenediamine tetraacetic acid (EDTA), phosphonates and other chelating agents; methylparaben, butylparaben and other preservatives; vitamins and precursors thereof Active ingredients of: Lecithin, animal and plant extracts such as gelatin or derivatives thereof; polymer fine powder such as Nai Nya polyethylene; anti-inflammatory agent such as dipotassium glycyrrhizinate; And anti-dandruff agents; Antioxidants such as dibutylhydroxytoluene; pearlizing agents, ultraviolet absorbers, pH adjusting agents, dyes, fragrances, and water can be blended as necessary within a range not impairing the effects of the present invention.

The detergent composition of the present invention preferably has a pH of 4-8. The cleaning composition of the present invention is used with water having a hardness of 1 to 30 ° DH. Is preferred.

The water used here preferably has a pH of 4 to 9.

[0022] The cleaning composition of the present invention can be produced according to a conventional method. There are no particular limitations on the dosage form of the cleaning composition of the present invention, and various conventionally known dosage forms such as liquid body shampoos, cream facial cleansings, and the like can be used. The cleaning composition of the present invention is particularly suitable as a cleaning agent for body such as skin and hair.

[0023] Production Example 1

50 starting alcohol (lauryl alcohol) under a nitrogen atmosphere in a reaction vessel OmL 1 87. 3 g (1. 0 mol) was added, 85 weight ^_0/0 of orthophosphoric acid 3 1 ■ 9 g [[rho ₂ 0 ₅ · When expressed as n H ₂ 0 Ρ ₂ 0 ₅ 1 9.6 g (0.14 mol) H ₂ 0 1 2.3 g (0.68 mol)] was added and stirred at 35 ° C and mixed . Further, 62.1 g (0.43 mol) of phosphorus pentoxide (effective content: 98.5% by weight) was gradually added over 60 minutes with stirring. The temperature rose to 65 ° C, the temperature was further raised, and the reaction was carried out at 80 ° C for 12 hours. Further, 10 g of water was added, and the phosphoric acid ester obtained by hydrolyzing at 80 ° C for 3 hours was neutralized with potassium hydroxide and lauryl phosphate K salt (monolauryl dilauryl) shown in Table 1. Body = 80 2 0).

[0024] Production Example 2

In the same manner as in Production Example 1, the amount of water with respect to lauryl alcohol was adjusted and reacted so that the monolauryl dilauryl body = 60 40, and the lauryl phosphate K salt (monolauryl dilauryl body = 60 4 0) was obtained.

[0025] Production Example 3

In the same manner as in Production Example 1, the amount of water relative to lauryl alcohol was adjusted and reacted so that the monolauryl dilauryl body = 70 30, and the resulting phosphate ester was neutralized with triethanolamine. The lauryl phosphate triethanolamine salt shown in Table 1 (monolauryl dilauryl = 70 30)

[0026] Production Example 4

Raw material alcohol (lauryl alcohol, 巳 0 = average 1 mol addition product) was added to a 50 OmL reaction vessel under a nitrogen atmosphere, and 23.4 g (1.0 mol) was added, and 39.9 g of 85 wt% orthophosphoric acid was added. Add [P ₂ 0 ₅ ■ n H ₂ 0 and P ₂ 0 ₅ 1 9.6 g (0.14 mol) H ₂ 0 1 2.3 g (0.68 mol)] to 35 ° C Stir and mix. Further, 62.1 g (0.43 mol) of phosphorus pentoxide (effective content 98.5% by weight) was gradually added over 60 minutes with stirring. The temperature rose to 65 ° C, the temperature was further raised, and the reaction was carried out at 80 ° C for 12 hours. Further, 10 g of water was added, and the phosphate ester obtained by hydrolysis at 80 ° C for 3 hours was neutralized with potassium hydroxide, and the polyoxyethylene (1) lauryl ether phosphate K salt shown in Table 1 was obtained. (Monolauryl body dilauryl body = 80 20) was obtained.

[0027] Production Example 5

In the same manner as in Production Example 1, change lauryl alcohol, EO = average 1 mol addition product to myristyl alcohol, EO = average 1 mol addition product, so that monomyristyl dimyristyl = 85 1 5 = Adjusting the amount of water relative to an average 1 mol addition product, reaction was carried out to obtain polyoxyethylene (1) myristyl ether phosphate K salt (monomyristyl dimyristyl = 85 15) shown in Table 1.

[0028] Production Example 6

In the same manner as in Production Example 1, lauryl alcohol, EO = average 1 mol addition product was changed to lauryl alcohol, EO = average 2 mol addition product, so that monolauryl dilauryl product = 75 25, lauryl alcohol, EO = The amount of water relative to the average 2 mol addition product was adjusted and reacted to obtain polyoxyethylene (2) lauryl ether phosphate K salt (monolauryl dilauryl = 75/25) shown in Table 1.

[0029] Production Example 7

2-Ethylhexyl glycidyl ether 208 g, water 104.8 g, laur 5.82 g of phosphoric acid and 18.5 g of potassium hydroxide were placed in an autoclave and stirred at 140 ° C. for 5 hours. After dehydration at 100 ° C under reduced pressure (6.67 k Pa), add 9.7 g of lauric acid and 2.72 g of potassium hydroxide, react at 160 ° C for 15 hours, and then distilled under reduced pressure (53-67 Pa, 120-123 ° C.), 2-ethylhexyl glyceryl ether shown in Table 1 was obtained.

[0030] Production Example 8

In the same manner as in Production Example 7, 2-ethylhexyl glycidyl ether was changed to n-octyl glycidyl ether to obtain n-octyl glyceryl ethers shown in Table 1.

[0031] Production Example 9

1-octanol (Calcoal 0898, manufactured by Kao Corporation) 1 61 5. 0 g (1 2. 35 mo I) and hydroxylated power of 6.9 g (0.12 mo I) were charged into the autoclave, After dehydration at 1 10 ° C and 13.3 kPa, addition reaction was carried out at 120 ° C while injecting 1434 g (24. 69 0 1) of propylene oxide at 0.3 MPa.

After completion of the reaction, after aging at the same reaction temperature for 6 hours, after cooling to 80 ° C, the resulting reaction composition was combined with a synthetic adsorbent (Kyoichi Ward 600 S, Kyowa Chemical Industry Co., Ltd.) After adding 55 g and treating with 4.0 k Pa for 1 hour, the catalyst was removed by filtration.

Subsequently, 1-octanol was distilled off from 1 000 g of the obtained filtrate under the conditions of 130 ° C. and 1.3 kPa. Further, steam treatment was performed by blowing 100 g of steam under the conditions of 145 ° C., 6. O k Pa, and 5 hours to obtain dipropylene glycol monooctyl ether shown in Table 1.

[0032] Production Example 1 0

In the same manner as in Production Example 9, 1-octanol was changed to 2_ethylhexyl alcohol, and propylene oxide was changed to ethylene oxide to obtain the ethylene glycol 2_ethylhexyl ether shown in Table 1. [0033] Examples 1 to 20 and Comparative Examples 1 to 6

A cleaning composition having the composition shown in Table 1 was prepared by mixing each component at 70 ° C according to a conventional method (1 "1 was adjusted to 6-7), and 1 g of this was applied to the palm of the hand and arm. Foaming properties, foam quality and rinsing properties when washed were evaluated by 10 expert panelists according to the following evaluation criteria: Table 1 shows the results.

(Foamability)

4: The amount of foam is very large

3: Large amount of foam

2: Slightly less foam

1: Less foam

(Foam quality)

4: Fine, very creamy and good foam quality

3: Creamy and good foam quality

2: Slightly creamy foam quality

1: Light and rough foam

(Rinse)

4: No slickness, good rinsing

3: Almost no slickness, slightly good rinsing

2 ： Slightly sticky, slightly rinsable

1 ： Slimy, poor rinsing

Rank

A: Average score of 3.5 or higher

B: Average score is 2.5 or more and less than 3.5

C: Average score is 1.5 or more and less than 2.5

D: Average score is less than 1.5

[0034]

[]

S.C000 / .00Zdf / X3d ZY 98S9TI / .00Z OAV

One

, One

One

—,, 1Sfi, 2mDl, .0Sfi%.

[0035] Examples 21 -24

A face wash and whole body cleanser with a pH of 5.0-0.7.0 were prepared with the following formulation. pH was adjusted with citrate and potassium hydroxide. Both are hypoallergenic and the pH of the water used is less than 4-5, less than 5-8, and 8-9, and the hardness of the water used is 1-30 ° In all areas of DH, foaming was good, foam quality was creamy, and rinsing was good.

Example 21 (face wash)

(Ingredient) (Weight ⁰ / o) Lauryl phosphate K salt

(Monolauryl dilauryl = 75 25) 0.5 Polyoxyethylene (1) Lauryl ether phosphate K salt a)

(Monolauryl dilauryl = 75 25) 1.5 Polyoxyethylene (2) Lauryl sulfate N ab) 24.0 Dipropylene glycol 0.5 Dipropylene glycol monooctyl ether 0.4 Lauroyl hydroxysulfobetaine 1. 2 N, N-dimethylaminoethyl jetyl sulfate methacrylate ■ N, N-dimethylacrylamide ■ Polyethylene glycol dimethacrylate copolymer 4% by weight aqueous solution c) 2.5 Alkyl methacrylate copolymer d 0.5 sodium chloride 1.0 sodium sulfate 3.0 ethylene glycol distearate 2.0 methyl paraben 0.2 propyl paraben 0.1

BHT 0. 2 Fragrance 0. 05 賴 Balance Total 1 00. 00 a) In (), the average number of added moles of ethylene oxide is shown, and in the general formulas (1) and (2), k = m = n = 1.

b) The compounds in parentheses indicate the average number of moles of ethylene oxide added, and p = 2 in the general formula (3).

c) Sofcare KG—301 W; manufactured by Kao Corporation

d) Carbopol E T D2020; manufactured by B FGoodric h Example 22 (face wash)

(Ingredient) (Weight ⁰ / o) Lauryl phosphate K salt

(Monolauryl dilauryl = 75 25) 1.5 Polyoxyethylene (1) Ammonium lauryl sulfate b) 24. 0 Dipropylene glycol 1 0. 0

2-Ethylhexyl glyceryl ether 0.2 Lauroyl hydroxysulfobetaine 1.2 N, N-dimethylaminoethyl methacrylate ethyl methacrylate ■ N, N-dimethylacrylamide ■ Polyethylene glycol dimethacrylate copolymer 4 Weight% aqueous solution G) 2.5 Alkyl methacrylate copolymer d) 0.5 Sodium chloride 1. 0 Sodium sulfate 3. 0 Ethylene glycol distearate 2.0 Methyl paraben 0.2 Propropyl paraben 0.1

BHT 0. 2 Fragrance 0. 05 Purified water balance total 1 00. 00 a) In (), the average number of moles added of ethylene oxide is shown, and in the formulas (1) and (2), k = m = n = 1.

b) Compounds in () indicate the average number of added moles of ethylene oxide, and p = 1 in the general formula (3).

c) Sofcare KG—301 W; manufactured by Kao Corporation

d) Carbopol E T D2020; B FGo o dric h Example 23 (Body shampoo)

(Component) (wt%) Lauryl phosphate K salt

(Monolauryl dilauryl = 75 25) 1.3 Polyoxyethylene (1) Lauryl ether phosphate K salt a)

(Monolauryl dilauryl = 75 25) 3.8 Polyoxyethylene (2) Lauryl ether sulfate N ab) 1 5. 0 Dipropylene glycol 0.7 Dipropylene glycol monooctyl ether 0.6 Lauroyl hydroxysulfobetaine 1 0. 0 Polyoxyethylene sorbitan triisostearate

(1 60 EO) 2.0 Sorbite solution 5.0 N, N-dimethylaminoethyl jetyl sulfate methacrylate N, N-dimethylacrylamide Polyethylene glycol dimethacrylate 4 wt% aqueous solution G) 2.5 Ethylene glycol distearate 2.0 Methyl paraben 0.1 Propropyl paraben 0.2

BH 0.2 Perfume 0. 05 Purified water Balance total 1 00. 00 a) () shows the average number of moles of ethylene oxide added, and in the general formulas (1) and (2), k = m = n = 1.

c) Sofcare KG—301 W; manufactured by Kao Corporation

Example 24 (body shampoo)

(Ingredient) (Weight ⁰ / o) Lauryl phosphite triethanolamine salt

(Monolauryl dilauryl = 75 25) 1.3 Polyoxyethylene (1) Lauryl ether phosphate triethanol amine salt a)

(Monolauryl dilauryl = 75Z 25) 3. 8 Polyoxyethylene (2) Lauryl ether sulfate N ab) 1 5. 0 Dipropylene glycol 0.7 Diethylene glycol 2_ethylhexyl ether 0.3 Lauroyl hydroxysulfobetaine 1 0. 0 Polyoxyethylene sorbitan triisostearate

(1 60 EO) 2.0 Sorbite solution 5.0 N, N-dimethylaminoethyl jetyl sulfate methacrylate N, N-dimethylacrylamide Polyethylene glycol dimethacrylate 4 wt% aqueous solution C) 2.5 Ethylene glycol distearate 2.0 Methyl paraben 0.1 Propropyl paraben 0.2 BHT

Fragrance

a) In (), the average number of moles of ethylene oxide added is shown, and in the general formulas (1) and (2), k = m = n = 1.

c) Sofcare KG—301 W; manufactured by Kao Corporation

Claims

Claims The following components (A), (B) and (C) (A) (31) —phosphate monoester surfactant represented by the general formula (1) and (a 2) —general formula ( 2) a phosphate ester surfactant represented by the following formula, the content ratio of which is (ai) (a2) = 90 10-5050:

[Chemical 1]

(In the formula, R ¹ , R ² and R ³ each represent a linear or branched alkyl group or alkenyl group having 8 to 18 carbon atoms, and X ¹ , X ² and Y represent a hydrogen atom and an alkali, respectively. A metal atom, an alkaline earth metal atom, an alkanolamine, or an ammonium, and the average number of moles added, k, m, and n are each 0 to 10)

(B) — General formula (3)

R 0 (CH ₂ CH ₂ 0) _P S 0 ₃ M (3)

(Wherein R ⁴ represents an alkyl group or alkenyl group having 8 to 18 carbon atoms, represents an alkali metal atom, alkaline earth metal atom, alkanolamine, ammonium or basic amino acid, and the average number of moles added. p represents a number from 0 to 5. A sulfate ester surfactant represented by:

(C) (C-1) one or more glyceryl ethers having a linear or branched alkyl or alkenyl group having 6 to 12 carbon atoms, and

(C-2) — General formula (4)

R ^s O (AO) _q R ⁶ (4)

(In the formula, R ⁵ represents a linear or branched alkyl group having 6 to 10 carbon atoms or R ⁶ represents a rukenyl group, R ⁶ represents a hydrogen atom or a methyl group, AO represents an alkyleneoxy group having 2 to 4 carbon atoms, and the average added mole number q represents a number of 0.5 to 3.

)

One or more selected from the compounds represented by:

A cleaning composition comprising:

[2] The content ratio of component (A) to component (B) is the weight ratio of component (B) component (A) =

The cleaning composition according to claim 1, which is 1 to 10.

[3] The cleaning composition according to claim 1 or 2, wherein the component (A) is 1 to 15% by weight.

[4] The cleaning composition according to any one of claims 1 to 3, wherein the component (B) is 5 to 40% by weight.

[5] The cleaning composition according to any one of claims 1 to 4, wherein the component (C) is 0.1 to 20% by weight.

[6] The detergent composition according to any one of claims 1 to 5, which has a pH of 4-8.

[7] The cleaning composition according to any one of [1] to [6], which is used together with water having a hardness of 1 to 30 ° DH.

[8] The method according to any one of claims 1 to 7, wherein the pH is used together with water having a pH of 4 to 9.

The cleaning composition according to claim 1.

[9] A method for cleaning the body, wherein the cleaning composition according to any one of claims 1 to 8 is applied to the body.

[10] Use of the cleaning composition according to any one of claims 1 to 8 for washing the body.