KR101353160B1 - Detergent composition - Google Patents

Abstract

Provides a tablet composition having little irritation to the skin, excellent foaming property, creamy cream, good usability (rinsing property, feeling after washing), and excellent stability.

The following components (A), (B) and (C)

(A) (a ₁ ) The phosphate monoester type surfactant represented by General formula (1), and

(a ₂ ) a phosphoric acid diester surfactant represented by the general formula (2)

As a mixture of phosphate ester-based surfactants whose content ratio is (a ₁ ) / (a ₂ ) = 90/10 to 50/50 by weight ratio:

(B) higher fatty acids or salts thereof represented by General Formula (3);

(C) (C-1) 1 or more types of glyceryl ether which has a C6-C12 linear or branched alkyl group or alkenyl group.

And (C-2) 1 or more types chosen from the group which consists of a compound represented by General formula (4);

And the component (C-1), the content ratio of component (A) and component (B) is component (B) / component (A) = more than 1.5-less than 10, The cleaning composition which is a weight ratio.

Description

Detergent composition {DETERGENT COMPOSITION}

The present invention relates to a cleaning composition having little irritation to the skin and the like, excellent in stability and foaming property, creamy cream, good usability, and excellent stability.

Phosphate ester surfactants have lower irritation to skin and hair than soaps, alkyl ether sulfates, alkyl sulfates, and the like, and are widely applied as skin cleansing components. Moreover, because of its characteristics, it is applied to a wide range of other anionic surfactants and mixing systems with nonionic surfactants.

By the way, generally, a phosphate ester type surfactant is obtained as a mixture of a monoester and a diester, and dialkyl phosphoric acid which is poor in water solubility and inferior in foam generation force is mixed in the alkyl phosphate ester. In the case of using this alone as the main component of the detergent, there are generally problems in foaming force and foaming, and therefore, some methods of further formulating an auxiliary agent have been proposed. Among them, the method of adding higher fatty acid salts as an adjuvant (patent document 1) is an excellent method for enhancing foaming ability, but in this method having a high weight ratio of alkyl phosphate esters and a low proportion of higher fatty acid salts, higher fatty acid salts (soaps) Compared with only, foaming ability, foaming was not yet satisfactory. Moreover, the method of adding a higher fatty acid salt to a polyoxyethylene alkyl ether phosphate ester (patent document 2) is also still unsatisfactory from the point of foam generation force and stability. On the other hand, the method of using glyceryl ether having an alkyl group or an alkenyl group having 6 to 12 carbon atoms as an adjuvant (patent document 3) has some effects in terms of improving foaming ability in the case of monoalkyl phosphate ester salts, but is monoalkyl. When the ratio of the phosphate ester salt / dialkyl phosphate ester salt is less than 95/5, it is also difficult to satisfy both the foaming force and the foam quality as compared with the case where only the higher fatty acid salt is used. In addition, the use of the higher fatty acid salt alone has excellent foaming ability and foaming performance such as foaming as described above, but there are problems in terms of skin irritation such as stiffness during rinsing and wrinkles after washing. In addition, Patent Document 4 discloses a combination of monophosphate, higher fatty acid salts and alkylglyceryl ethers. However, combinations of these having a high ratio of phosphate esters and low proportions of higher fatty acid salts are capable of foaming and foaming. It is not yet satisfactory in that.

Patent Document 1: Japanese Unexamined Patent Publication No. 57-49698

Patent Document 2: Japanese Patent Application Laid-open No. Hei 1-316309

Patent Document 3: Japanese Unexamined Patent Publication No. 2001-107079

Patent Document 4: Japanese Unexamined Patent Publication No. 2005-206804

DISCLOSURE OF INVENTION

The present invention is the following components (A), (B) and (C)

(A) (a ₁ ) The phosphate monoester type surfactant represented by General formula (1), and

(a ₂ ) a phosphoric acid diester surfactant represented by the general formula (2)

As a mixture of phosphate ester-based surfactants whose content ratio is (a ₁ ) / (a ₂ ) = 90/10 to 50/50 by weight ratio:

[Formula 1]

(In formula, R <^1> , R <^2> and R <^3> represent a C8-C18 linear or branched alkyl group or alkenyl group, respectively, and X <^1> , X <^2> and Y respectively represent a hydrogen atom, an alkali metal atom, and an alkaline earth metal atom. , Alkanolamine or ammonium, and mean addition mole number k, m, and n show the number of 0-10, respectively;);

(B) general formula (3)

(Wherein R ⁴ represents a saturated or unsaturated aliphatic hydrocarbon group having 7 to 17 carbon atoms, and M represents a hydrogen atom, an alkali metal atom, an alkanolamine or ammonium)

Higher fatty acids or salts thereof;

(C) (C-1) at least one glyceryl ether having a linear or branched alkyl or alkenyl group having 6 to 12 carbon atoms, and

(C-2) General formula (4)

(In formula, R <^5> represents a C6-C10 linear or branched alkyl group or alkenyl group, R <^6> represents a hydrogen atom or a methyl group, AO represents a C2-C4 alkyleneoxy group, and average addition Mole number q represents the number of 0.5-3)

1 or more types chosen from the group which consists of a compound represented by;

In the case of containing the component (C-1), the content ratio of the component (A) and the component (B) is a component (B) / component (A) = more than 1.5 to less than 10 by weight ratio to provide a cleaning composition It is.

Moreover, this invention provides the washing | cleaning method of a body which applies this washing | cleaning composition to a body.

Moreover, this invention provides the use for the washing | cleaning of the body of this detergent composition.

An object of the present invention is to provide a cleaning composition having little irritation to the skin, excellent foaming property, creamy cream, good usability (rinsing property, feeling after washing) and excellent stability.

MEANS TO SOLVE THE PROBLEM The present inventors mix | blend a higher fatty acid or its salt with a phosphate ester type surfactant, and use glyceryl ether and an alkoxylate together with the cleaning composition which uses the phosphate ester type surfactant, and there is little irritation to skin, etc., It was found that a cleaning composition having excellent stability and foaming properties, creamy creaminess, and good usability was obtained.

The cleaning composition of the present invention is less irritating to the skin, has excellent foaming properties, has a creamy cream, and has a good feeling of use (rinsing property, feeling after washing) at the time of washing and excellent stability.

In the phosphate ester represented by the general formulas (1) and (2) of the component (A) which is a hypoallergenic base used in the present invention, as R ¹ , R ² and R ³ , each having 10 to 16 carbon atoms and 12 to 14 carbon atoms; It is preferable that it is an alkyl group, X <^1> , X <^2> and Y are preferable alkali metal atoms, such as potassium or sodium, and triethanolamine, and potassium is especially preferable at the point of solubility to water. Ethylene oxide average addition mole number k, m, and n are 0-4 mol, 0-2, Furthermore, 0-1 mol is preferable from a viewpoint of foam generation force.

The content ratio of the alkyl phosphate monoester (a ₁ ) and the alkyl phosphate diester (a ₂ ) in the component (A) is, in terms of ease of mixing, the weight ratio (a ₁ ) / (a ₂ ) = 90/10 to 50 / 50, 85/15-60/40 are preferable, and 80/20-70/30 are more preferable. If the weight ratio (a ₁ ) / (a ₂ ) is less than 50/50, foaming properties are inferior, and if the weight ratio (a ₁ ) / (a ₂ ) is more than 90/10, the melting point of the alkyl phosphate ester mixture is high, making it difficult to mix. Become.

1-15 weight% of the cleaning composition of this invention is preferable, and, as for content of the phosphate ester type surfactant of a component (A), from a viewpoint of foaming, cleaning power, and the ease of mixing, 3-10 weight% is more preferable.

Component (A) adds ethylene oxide to the corresponding aliphatic alcohol or the corresponding aliphatic alcohol, for example, and the ethoxylate which became the average addition mole number more than 0-10, phosphoric anhydride, orthophosphoric acid, polyphosphoric acid, or oxychloride It is a phosphate ester obtained by making phosphoric acid esters, such as phosphoric acid, react, or its phosphate ester partially or completely neutralize with alkali, such as sodium hydroxide and potassium hydroxide.

(a ₁ ) / (a ₂ ) can be controlled by the ratio of the water contained in an aliphatic alcohol and a phosphorylating agent.

As a method of obtaining (a ₁ ) / (a ₂ ) = 90/10 to 50/50, for example, orthophosphoric acid containing phosphoric anhydride and water at the time of reaction is used to adjust the ratio of raw alcohol and water. A method of directly controlling the ratio of (a ₁ ) / (a ₂ ), or (a ₁ ) / (a ₂ ) = 100/0 to 95/5 phosphate ester, and (a ₁ ) / (a ₂ ) And a method of mixing a phosphate ester of = 50/50 in an appropriate ratio.

In the higher fatty acid represented by the general formula (3) of the component (B) or a salt thereof, R ⁴ is preferably an alkyl group having 7 to 17 carbon atoms, M is preferably an alkali metal atom, an alkanolamine or an ammonium, and more. Preferably an alkali metal atom such as potassium or sodium.

The higher fatty acid salt may be prepared by neutralizing the higher fatty acid and the base in a mixing tank for producing the cleaning composition. In addition, some of the higher fatty acid salts do not interfere with the effects of the present invention even if salt exchange occurs with counter ions of the phosphate ester salt.

Component (B) brings a foam improving effect, ie, creamy foam, which is absent in component (C), and also improves foaming properties.

The higher fatty acids of the component (B) or salts thereof can be used alone or as a mixture of two or more thereof. As for content of a component (B), 5-35 weight% is preferable, 5-30 weight% is more preferable, 10-25 weight% has the point which provides the washing | cleaning property and foaming property of the cleaning composition of this invention. Even more preferred.

Although the preferable content of a component (A) and a component (B) in the cleaning composition of this invention is as above-mentioned, when it contains a component (C-1), the content rate of a component (A) and a component (B) is further included. It is important in the weight ratio of component (B) / component (A) = more than 1.5 to less than 10 in terms of detergency, foaming force, foaming, texture of the foam and skin irritation, and contains component (C-2). In addition, the content ratio of component (A) and component (B) in terms of weight ratio of component (B) / component (A) = 0.5 to 20 is in terms of cleaning power, foaming ability, foaming, foam texture and skin irritation. desirable. 2-9 are more preferable and, as for component (B) / component (A) weight ratio, 2-5 are still more preferable.

In component (C), the glyceryl ether of component (C-1) has a C6-C12 linear or branched alkyl group or alkenyl group, For example, n-hexyl group, isohexyl group, n It is preferable to have a C6-C12 alkyl group, such as -heptyl group, n-octyl group, 2-ethylhexyl group, n-nonyl group, n-decyl group, and n-lauryl group, Furthermore, it is C6-C11, Furthermore, it is preferable to have 1 or 2, especially 1 alkyl group of 6 to 10 carbon atoms, especially 8 carbon atoms.

In addition, in the alkylene oxide adduct of the alcohol of component (C-2) in component (C), R <^5> is a C6-C10, Preferably it is a C8-C10 linear or branched alkyl group or alkene. And an alkyl group having 8 carbon atoms is more preferable. AO is a C2-C4 alkyleneoxy group, A C2-C3 alkyleneoxy group is more preferable, A C3 alkyleneoxy group is still more preferable. Specifically, an ethyleneoxy group, a propyleneoxy group, a butyleneoxy group, etc. are mentioned, An ethyleneoxy group, a propyleneoxy group is preferable, and a propyleneoxy group is more preferable. Although average added mole number q shows the number of 0.5-3, 1-3 are preferable and 2-3 are more preferable. When the largest component of the added mole number of AO in the component (C) is AO _max , it is preferable that the AO _max is 70% by weight or less of the entire component (C) from the viewpoint of economical efficiency to reduce the load on manufacturing costs such as purification. It is preferable that it is 60 weight% or less, and it is still more preferable that it is 50 weight% or less. It is also preferred if AO is an oxyalkylene group, i.e. an oxyethylene group having a carbon number of 2, AO _max is the component (C) of the total 60 weight%, more than 50% by weight, more than 40% by weight. Further, it is preferable that AO is an oxyalkylene group of a carbon number of 3, i.e., oxypropylene group if, AO _max is component (C) 70% by weight or less of the total, more than 60% by weight, even more 50% by weight or less. R ⁶ represents a hydrogen atom or a methyl group, more preferably a hydrogen atom.

Component (C) can be used 1 or more types.

Component (C) has the effect of maintaining stability and improving foaming force.

0.1-5 weight% is preferable, as for the compounding quantity of a component (C), 0.1-3 weight% is more preferable, 0.2-1 weight% is still more preferable.

Component (C-1) can be obtained, for example, by hydrolyzing the corresponding glycidyl ether and water at 100 to 230 ° C, and component (C-2) is, for example, propylene oxide to the corresponding aliphatic alcohol. And / or after reacting ethylene oxide, the raw material alcohol can be obtained by distilling off.

Using component (A) and (B) in the ratio of component (B) / component (A) = more than 1.5-less than 10 by weight ratio, and using component (C) together, further stimulates a higher fatty acid salt, It is changed to hypoallergenic, such as the use of phosphate ester surfactant alone, and foaming property, which is a drawback of the phosphate ester surfactant, is improved like higher fatty acids. Foaming becomes creamy and is preferred. In addition, despite the high proportion of higher fatty acid salts, it is recognized that the skin, which is unique to the phosphate ester surfactant, is not drawn, and the feeling is good. Furthermore, it originates in this invention, and the compounding at the time of manufacture does not have a raise of a viscosity, and becomes easy.

The cleaning composition of the present invention is a cleaning composition useful as a body cleaning agent such as a skin cleaning agent such as a face wash, a shampoo, a body shampoo or a hair cleaning agent, but is particularly preferably used as a skin cleaning agent such as a face wash or a body shampoo. Arbitrary components can be mix | blended with these detergent compositions according to the objective. Here, as an arbitrary component, the other anionic surfactant, a nonionic surfactant, amphoteric surfactant, cationic surfactant, conditioning components, etc. which are normally mix | blended with these detergents are mentioned.

Other anionic surfactants include alkyl sulfates, polyoxyalkylene alkyl ether sulfates, sulfosuccinic acid surfactants, sulfosuccinamate surfactants, polyoxyalkylene alkylamide ether sulfates, monoglyceride sulfates, and olefin sulfonic acids. Salts, alkanesulfonic acid salts, acyl isethionate salts, acylated amino acid salts, polyoxyalkylene alkyl ether phosphates other than component (A), and the like; Examples of nonionic surfactants include alkyl polyglucosides and sucrose fatty acids. Ester, polyglycerol fatty acid ester, polyoxyalkylene alkyl ether, fatty acid alkanolamide, alkylamine oxide, fatty acid polyhydric alcohol ester and the like. Moreover, as a cationic surfactant, a linear or branched mono or di-chain alkyl quaternary ammonium salt, a mono or di-chain alkyl tertiary amine, etc. are mentioned; As an amphoteric surfactant, an amide amino acid type | system | group active agent is mentioned. And carbobetaine-based activators, sulfobetaine-based activators, amide sulfobetaine-based activators, imidazolinium beta-based activators, amino acid-based betaine activators, and phosphobetaine-based activators.

Conditioning components include higher alcohols, silicones and silicone derivatives, lanolin, squalene, hydrocarbons, protein derivatives, emulsions such as fatty acid esters of polyethylene glycol, cationized cellulose, cationized guar gum and Markot 550 (manufactured by Narco), soft And cation polymers such as Care KG-301W (manufactured by Kao Corporation).

In addition, other components usually used in the cleaning composition, for example, water-soluble polymers such as polysaccharides such as methyl cellulose, hydroxyethyl cellulose, carboxyvinyl polymer and xanthan gum; polyoxyalkylene sorbitan esters, polyoxyethylene glycol Viscosity modifiers such as distearate and ethanol; chelating agents such as ethylenediamine tetraacetic acid (EDTA) and phosphonates; preservatives such as methylparaben and butylparaben; active ingredients such as vitamins and precursors thereof; fauna and flora such as lecithin and gelatin Extracts or derivatives thereof; polymer fine powders such as nylon and polyethylene; anti-inflammatory agents such as dipotassium glycyric acid; bactericides and anti-dandruff agents such as triclosan, trichlorocarban, octopyrox and zinc pyrithione; oxidation of dibutylhydroxytoluene Inhibitors; pearlizing agents, ultraviolet absorbers, pH adjusters, pigments, flavorings, water to reduce the effects of the present invention It can mix | blend as needed in the range which does not harm.

It is preferable that the cleaning composition of this invention is pH 7-11.

The detergent composition of the present invention is preferably used with water having a hardness of 1 to 30 DEG DH.

In addition, it is preferable that pH used here is 4-9.

The cleaning composition of the present invention can be produced according to a conventional method. There is no restriction | limiting in particular about the formulation of the cleaning composition of this invention, It can be set as the conventionally well-known various formulations, for example, liquid body shampoo, cream type face wash. The detergent composition of the present invention is particularly preferable as a detergent for the body such as skin, hair and the like.

Production Example 1

500mL of a reaction vessel under a nitrogen atmosphere, a raw material alcohol (lauryl alcohol) was added to 187.3g (1.0 mole), and expressed as [P ₂ O 85% by weight orthophosphoric acid _{31.9g 5 · nH 2 O P 2} O 5 19.6g (0.14 mol) H ₂ O 12.3 g (0.68 mol)] was added and stirred and mixed at 35 ° C. Furthermore, 62.1 g (0.43 mol) of phosphorus pentaoxide (98.5 weight% of active ingredients) was added gradually for 60 minutes, stirring. The temperature rose to 65 degreeC, it heated up further, and reaction was performed at 80 degreeC for 12 hours. Furthermore, 10.0 g of water was added and hydrolysis was carried out at 80 ° C. for 3 hours to neutralize the phosphate ester with potassium hydroxide to give the lauryl phosphate K salt (monolauryl body / dilauryl body = 80/20) shown in Table 1. Got it.

Production Example 2

In the same manner as in Production Example 1, the amount of water to lauryl alcohol was adjusted and reacted so that monolauryl body / dilauryl body = 60/40, and the lauryl phosphate K salt shown in Table 1 (monolauryl body / Dilauryl body = 60/40).

Production Example 3

In the same manner as in Production Example 1, the amount of water to lauryl alcohol was adjusted and reacted so that the monolauryl body / dilauryl body = 70/30 was reacted, and the obtained phosphate ester was neutralized with triethanolamine and shown in Table 1 Uryl phosphate triethanolamine salt (monolauryl body / dilauryl body = 70/30) was obtained.

Production Example 4

230.4 g (1.0 mole) of raw alcohol (lauryl alcohol, EO = average 1 mole adduct) was added to a 500 mL reaction vessel under a nitrogen atmosphere, and 31.9 g of 85 wt% orthophosphoric acid [P ₂ O ₅ · nH ₂ O expressed as by the addition of P ₂ O ₅ 19.6g (0.14 moles) H ₂ O 12.3g (0.68 moles)] was stirred and mixed at 35 ℃. Furthermore, 62.1 g (0.43 mol) of phosphorus pentaoxide (98.5 weight% of active ingredients) was added gradually for 60 minutes, stirring. The temperature rose to 65 degreeC, it heated up further, and reaction was performed at 80 degreeC for 12 hours. In addition, 10.0 g of water was added and hydrolyzed at 80 ° C. for 3 hours to neutralize the phosphate ester with potassium hydroxide, and the polyoxyethylene (1) lauryl ether phosphate K salt shown in Table 1 (monolauryl body / dilauryl) Sieve = 80/20).

Production Example 5

In the same manner as in Production Example 1, lauryl alcohol and EO = average 1 mole adduct were changed to myristyl alcohol and EO = average 1 mole adduct, so that the monomyristyl / dimyristyl = 85/15. , Myristyl alcohol, EO = polyoxyethylene (1) myristyl ether phosphate K salt shown in Table 1 by controlling the amount of water relative to the average 1 mole adduct and reacting (mono myristyl and dimyristyl) = 85 / 15) was obtained.

Production Example 6

In the same manner as in Production Example 1, lauryl alcohol and EO = average 1 mole adduct are replaced with lauryl alcohol and EO = average 2 mole adduct, so that the monolauryl body / dilauryl body = 75/25, Uryl alcohol, EO = polyoxyethylene (2) lauryl ether phosphate K salt shown in Table 1 by controlling the amount of water relative to the average 2 mole adducts (monolauryl body / dilauryl body = 75/25) Got.

Production Example 7

208 g of 2-ethylhexyl glycidyl ether, 104.8 g of water, 5.82 g of lauric acid and 18.5 g of potassium hydroxide were placed in an autoclave and stirred at 140 DEG C for 5 hours. After dehydration at 100 ° C under reduced pressure (6.67 Pa), 9.7 g of lauric acid and 2.72 g of potassium hydroxide were added and reacted at 160 ° C. for 15 hours, after that, distillation under reduced pressure (53 to 67 Pa, 120 to 123 ° C.) It refine | purified by and obtained 2-ethylhexyl glyceryl ether shown in Table 1.

Production Example 8

In the same manner as in Production Example 7, 2-ethylhexyl glycidyl ether was changed to n-octyl glycidyl ether to obtain n-octyl glyceryl ether shown in Table 1. [

Production Example 9

1615.0 g (12.35 mol) of 1-octanol (Calcohol 0898, manufactured by Cao Co., Ltd.) and 6.9 g (0.12 mol) of potassium hydroxide were charged into an autoclave, dehydrated at 110 ° C and 13.3 Pa, and then propylene at 120 ° C. Addition reaction was performed, pushing 1434 g (24.69 mol) of oxides at 0.3 MPa.

After completion | finish of reaction, after carrying out aging at the same reaction temperature for 6 hours, it cooled to 80 degreeC.

As a post-treatment, 55 g of a synthetic adsorbent (Kyo Ward 600S, Kyowa Chemical Industry Co., Ltd.) was added to the obtained reaction composition, and treated at 4.0 kPa for 1 hour, and then the catalyst was removed by filtration.

Subsequently, 1-octanol was removed by distillation with respect to 1000 g of the obtained filtrate on 130 degreeC and 1.3 kPa conditions. Furthermore, the steam treatment which blows 100 g of steam on conditions of 145 degreeC, 6.0 kPa, and 5 hours was performed, and the dipropylene glycol monooctyl ether shown in Table 2 was obtained.

Production Example 10

In the same manner as in Production Example 9, 1-octanol was replaced with 2-ethylhexyl alcohol and propylene oxide was replaced with ethylene oxide, to obtain diethylene glycol 2-ethylhexyl ether shown in Table 2.

Examples 1-8 and Comparative Examples 1-7

The cleaning composition of the composition shown in Table 1 was manufactured by mixing each component at 70 degreeC (pH was adjusted to 9), and foaming property, foaming property, rinsing property, post-washing texture, hypoallergenicity, and stability were evaluated. . The results are shown in Table 1.

(1) Foaming, foaming, rinsing, feeling after washing and hypoallergenic

The cleaning composition prepared according to the conventional method was applied to 1 g of the cleaning agent on the palm, and the foaming, foaming, rinsing, post-cleaning texture and hypoallergenicity when the hands and arms were washed were evaluated by 10 expert panelists. Evaluation was made according to the standard.

(Bubble occurrence)

4: very large amount of bubbles

3: large amount of bubbles

2: slightly less foam

1: small amount of bubbles

(High quality)

4: Smooth, very creamy and good foam

3: creamy and good foam

2: slightly creamy foam

1: Light and sparse foam

(Rinsing property)

4: rinse property is good without being stiff

3: It is almost stiff and is slightly good rinsing property

2: Slightly stiff, slightly poor rinsing

1: Stiff, poor rinse

(Feel after washing)

4: There is no tension after washing; usability is good

3: There is little pulling feeling after washing; feeling is slightly good

2: There is some pulling feeling after washing, and feeling is slightly bad

1: There is tension after washing, and feeling is bad

Rating

A ： The average rating is 3.5 or more

B: Average rating is 2.5 or more and less than 3.5

C: Average rating is 1.5 or more and less than 2.5

D: Average rating is less than 1.5

(Low irritant)

A ： Everyone did not feel irritated

B ： 1 or more people and 2 or less people felt irritation, but it was an acceptable mild stimulus

C: One or more and two or less people felt irritated, but it was an unacceptable strong stimulus.

D ： More than 3 people felt irritated

(2) Stability

The cleaning composition was placed in a glass bottle and stored at 20 ° C. for 1 month, and then the appearance was visually evaluated based on the following criteria.

◎: Transparent

○: Very cloudy

△: slightly cloudy

×: Settles and separates

Examples 9-11

The face wash and the whole body washing | cleaning agent were manufactured by the following prescription. All are hypoallergenic, and in all the regions where the pH of the water to be used is 4 to 9, and also in all the regions where the hardness of the water to be used is 1 to 30 ° DH, the foaming property is good and the foaming is creamy, The rinsing property and the texture after washing were good and the stability was good.

Example 9 (face wash)

(Component) (wt%)

Lauryl phosphate K salt

(Monolauryl body / dilauryl body = 75/25) 2.0

Polyoxyethylene (1) lauryl ether phosphate K salt a)

(Monolauryl sieve / dilauryl sieve = 75/25) 6.0

Lauric acid K salt 10.0

Myristic acid K salt 7.0

Palmitic acid K salt 7.0

Dipropylene Glycol 10.0

2-ethylhexylglyceryl ether 0.5

Sorbitum 10.0

Sodium chloride0.5

Ethylene Glycol Distearate 2.0

Methylparaben 0.2

Propylparaben 0.1

BHT 0.2

Spices 0.05

Purified Water Balance

          Total 100.00

 a) The compound in () shows the average added mole number of ethylene oxide, and k = m = n = 1 of General formula (1) and (2).

Example 10 (body shampoo)

(Component) (wt%)

Lauryl phosphate K salt

(Monolauryl body / dilauryl body = 75/25) 1.3

Polyoxyethylene (1) lauryl ether phosphate K salt a)

(Monolauryl sieve / dilauryl sieve = 75/25) 3.8

Lauric acid K salt 6.0

Myristic acid K salt 4.5

Palmitic acid K salt 4.5

Dipropylene Glycol 0.7

2-ethylhexylglyceryl ether 0.3

Lauroylhydroxysulfobetaine 10.0

Polyoxyethylene sorbitan triisostearate

(160EO) 2.0

Glycerin 5.0

N, N-dimethylaminoethyl methacrylate diethyl sulfate

N, N-dimethylacrylamide, dimethacrylic acid polyethylene glycol

 Copolymer 4 wt% aqueous solution b) 2.5

Ethylene Glycol Distearate 2.0

Methylparaben 0.1

Propylparaben 0.2

BHT 0.2

Spices 0.05

Purified water                                               balance

          Total 100.00

 a) The compound in () shows the average added mole number of ethylene oxide, and k = m = n = 1 of General formula (1) and (2).

b) Softcare KG-301W; manufactured by Cao

Example 11 (body shampoo)

(Component) (% by weight)

Lauryl phosphate triethanolamine salt

(Monolauryl body / dilauryl body = 75/25) 1.3

Polyoxyethylene (1) lauryl ether phosphate triethanol amine salt a)

(Monolauryl sieve / dilauryl sieve = 75/25) 3.8

Lauric acid triethanol amine salt 6.0

Myristic acid triethanol amine salt 4.5

Palmitic acid triethanolamine salt 4.5

Dipropylene Glycol 0.7

n-octylglyceryl ether 0.3

Lauroylhydroxysulfobetaine 10.0

Polyoxyethylene sorbitan triisostearate

(160EO) 2.0

Glycerin 5.0

N, N-dimethylaminoethyl methacrylate diethyl sulfate

N, N-dimethylacrylamide, dimethacrylic acid polyethylene glycol

 Copolymer 4 wt% aqueous solution b) 2.5

Ethylene Glycol Distearate 2.0

Methylparaben 0.1

Propylparaben 0.2

BHT 0.2

Spices 0.05

Purified water  balance

    Total 100.00

a) The compound in () shows the average added mole number of ethylene oxide, and k = m = n = 1 of General formula (1) and (2).

b) Softcare KG-301W; manufactured by Cao

Examples 12-22 and Comparative Examples 8-11

The cleaning composition of the composition shown in Table 2 was manufactured by mixing each component at 70 degreeC (pH was adjusted to 9), and foaming property, foaming property, rinsing property, a feeling after washing, hypoallergenicity, and stability were mentioned in the said Example. It evaluated by the same evaluation criteria as 1-8 and Comparative Examples 1-7. The results are shown in Table 2.

Example 23 (face wash)

(Component) (% by weight)

Lauryl phosphate K salt

(Monolauryl body / dilauryl body = 75/25) 2.0

Polyoxyethylene (1) lauryl ether phosphate K salt a)

(Monolauryl sieve / dilauryl sieve = 75/25) 6.0

Lauric acid K salt 10.0

Myristic acid K salt 7.0

Palmitic acid K salt 7.0

Dipropylene Glycol 10.0

Dipropylene Glycol Monooctyl Ether 1.0

Sorbitan 10.0

Sodium chloride0.5

Ethylene Glycol Distearate 2.0

Methylparaben 0.2

Propylparaben 0.1

BHT 0.2

Spices 0.05

Purified water                                                 balance

    Total 100.00

a) The compound in () shows the average added mole number of ethylene oxide, and k = m = n = 1 of General formula (1) and (2).

Example 24 (body shampoo)

(Component) (% by weight)

Lauryl phosphate K salt

(Monolauryl body / dilauryl body = 75/25) 1.3

Polyoxyethylene (1) lauryl ether phosphate K salt a)

(Monolauryl sieve / dilauryl sieve = 75/25) 3.8

Lauric acid K salt 6.0

Myristic acid K salt 4.5

Palmitic acid K salt 4.5

Dipropylene Glycol 0.7

Dipropylene Glycol Monooctyl Ether 0.6

Lauroylhydroxysulfobetaine 10.0

Polyoxyethylene sorbitan triisostearate

(160EO) 2.0

Glycerin 5.0

N, N-dimethylaminoethyl methacrylate diethyl sulfate

N, N-dimethylacrylamide, dimethacrylic acid polyethylene glycol

 Copolymer 4 wt% aqueous solution b) 2.5

Ethylene Glycol Distearate 2.0

Methylparaben 0.1

Propylparaben 0.2

BHT 0.2

Spices 0.05

Purified water                                                 balance

          Total 100.00

a) The compound in () shows the average added mole number of ethylene oxide, and k = m = n = 1 of General formula (1) and (2).

b) Softcare KG-301W; manufactured by Cao

Example 25 (body shampoo)

(Component) (% by weight)

Lauryl phosphate triethanolamine salt

(Monolauryl body / dilauryl body = 75/25) 1.3

Polyoxyethylene (1) lauryl ether phosphate

Triethanolamine salt a)

(Monolauryl sieve / dilauryl sieve = 75/25) 3.8

Lauric acid triethanol amine salt 6.0

Myristic acid triethanol amine salt 4.5

Palmitic acid triethanolamine salt 4.5

Dipropylene Glycol 0.7

Diethylene glycol 2-ethylhexyl ether 0.3

Lauroylhydroxysulfobetaine 10.0

Polyoxyethylene sorbitan triisostearate

(160EO) 2.0

Glycerin 5.0

N, N-dimethylaminoethyl methacrylate diethyl sulfate

N, N-dimethylacrylamide, dimethacrylic acid polyethylene glycol

 Copolymer 4 wt% aqueous solution b) 2.5

Ethylene Glycol Distearate 2.0

Methylparaben 0.1

Propylparaben 0.2

BHT 0.2

Spices 0.05

Purified water                                                 balance

          Total 100.00

a) The compound in () shows the average added mole number of ethylene oxide, and k = m = n = 1 of General formula (1) and (2).

b) Softcare KG-301W; manufactured by Cao

All of the face washes or body shampoos of Examples 23 to 25 are hypoallergenic, and foamed in all regions in which the pH of water to be used is 4 to 9, and in all regions in which the hardness of water to be used is 1 to 30 ° DH. It was good in generating property, creamy cream, good rinsing property, good texture after washing, and good stability.

Claims (10)

The following components (A), (B) and (C) (A) (a ₁ ) The phosphate monoester type surfactant represented by General formula (1), and (a ₂ ) a phosphoric acid diester surfactant represented by the general formula (2) As a mixture of phosphate ester-based surfactants whose content ratio is (a ₁ ) / (a ₂ ) = 90/10 to 50/50 by weight ratio: [Formula 1]

(In formula, R <^1> , R <^2> and R <^3> represent a C8-C18 linear or branched alkyl group or alkenyl group, respectively, and X <^1> , X <^2> and Y respectively represent a hydrogen atom, an alkali metal atom, and an alkaline earth metal atom. , Alkanolamine or ammonium, and mean addition mole number k, m, and n show the number of 0-10, respectively;); (B) general formula (3)

(Wherein R ⁴ represents a saturated or unsaturated aliphatic hydrocarbon group having 7 to 17 carbon atoms, and M represents a hydrogen atom, an alkali metal atom, an alkanolamine or ammonium) Higher fatty acids or salts thereof; (C) (C-1) at least one glyceryl ether having a linear or branched alkyl or alkenyl group having 6 to 12 carbon atoms, and (C-2) General formula (4)

(In formula, R <^5> represents a C6-C10 linear or branched alkyl group or alkenyl group, R <^6> represents a hydrogen atom or a methyl group, AO represents a C2-C4 alkyleneoxy group, and average addition Mole number q represents the number of 0.5-3) 1 or more types chosen from the group which consists of a compound represented by; And the component (C-1), the content ratio of component (A) and component (B) is component (B) / component (A) = more than 1.5-less than 10, The cleaning composition which is a weight ratio. The method of claim 1, The component (C) is a component (C-2) whose component ratio (A) and component (B) are component (B) / component (A) = 0.5-20 by weight ratio. 3. The method according to claim 1 or 2, Cleaner composition containing 1-15 weight% of component (A). 3. The method according to claim 1 or 2, Cleaning composition containing 5-35 weight% of component (B). 3. The method according to claim 1 or 2, Cleaner composition containing 0.1-5 weight% of component (C). 3. The method according to claim 1 or 2, Cleaning composition which is pH 7-11. 3. The method according to claim 1 or 2, Is used with water having a hardness of 1 to 30 DEG DH. 3. The method according to claim 1 or 2, is used with water having a pH of 4-9. A method of cleaning a body applying the cleaning composition according to claim 1 or 2 to the body. delete