WO2007099738A1 - Composition de deodorant - Google Patents

Composition de deodorant Download PDF

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Publication number
WO2007099738A1
WO2007099738A1 PCT/JP2007/051963 JP2007051963W WO2007099738A1 WO 2007099738 A1 WO2007099738 A1 WO 2007099738A1 JP 2007051963 W JP2007051963 W JP 2007051963W WO 2007099738 A1 WO2007099738 A1 WO 2007099738A1
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WO
WIPO (PCT)
Prior art keywords
deodorant
acid
zeolite
oil
powder
Prior art date
Application number
PCT/JP2007/051963
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English (en)
Japanese (ja)
Inventor
Hidefumi Araki
Yukiko Kamiya
Norinobu Yoshikawa
Original Assignee
Shiseido Company, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP2006050067A external-priority patent/JP5019348B2/ja
Priority claimed from JP2006050068A external-priority patent/JP5036025B2/ja
Application filed by Shiseido Company, Ltd. filed Critical Shiseido Company, Ltd.
Publication of WO2007099738A1 publication Critical patent/WO2007099738A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25—Silicon; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants

Definitions

  • the present invention relates to a deodorizing composition. More specifically, it is a deodorant composition used in deodorant cosmetics and the like that contains antibacterial zeolite, has an excellent deodorizing effect, and is used to prevent clothes from being stained due to the antibacterial zeolite. Deodorant composition with improved detergency
  • deodorant composition for use in deodorant cosmetics and the like that contains antibacterial zeolite, has an excellent deodorizing effect, and has less discoloration and staining caused by the antibacterial zeolite.
  • Antibacterial zeolite powder is mainly blended in deodorizing compositions such as deodorant cosmetics as a deodorant.
  • Patent Document 1 antibacterial spray compositions containing antibacterial zeolite (see Patent Document 1) and deodorant cosmetics (see Patent Document 2) have been developed.
  • Deodorant cosmetics also called antiperspirant cosmetics and deodorant cosmetics
  • Cosmetics are used to prevent or suppress the emission and secretion of unpleasant body odors, or to eliminate the emission and secretion components.
  • Cosmetics. This product form is generally used as a lotion, cream, powder, sticky or aerosol.
  • Patent Document 1 Japanese Patent Laid-Open No. 63-250325
  • Patent Document 2 JP-A-8-26956
  • Patent Document 3 JP-A-8-92051 Disclosure of the invention
  • the deodorant cosmetics disclosed in Patent Documents 1 to 3 are deodorization methods utilizing the bactericidal action of antibacterial zeolite.
  • deodorant cosmetics with antibacterial zeolite have the disadvantage that they discolor after application and become soiled on clothes, and stains remain on clothes immediately after washing. Therefore, it is desired to develop a deodorant cosmetic that is excellent in discoloration and antifouling effects, is excellent in use feeling, and has a good deodorization effect.
  • the present inventors have found that when antibacterial zeolite and a specific powder are combined in a deodorizing composition, the adhesion to clothes is prevented. The present inventors have found that the washing effect of washing is improved and completed the present invention.
  • An object of the present invention is to provide a deodorant composition that is excellent in the effect of cleaning and removing stains adhering to clothes and that can be suitably used particularly as a deodorant cosmetic.
  • An object of the present invention is to provide a deodorizing composition that is excellent in deodorizing effect with less discoloration and staining and that can be suitably used particularly as a deodorizing cosmetic.
  • the present invention provides a deodorizing composition
  • a deodorizing composition comprising antibacterial zeolite and a powder having a specific surface area of 150 m 2 / g or more and an oil absorption of lOOmlZlOOg or more. .
  • the present invention is characterized by containing an antibacterial zeolite and a silicone rubber powder.
  • the present invention provides a deodorizing composition.
  • the present invention provides the above-mentioned deodorizing composition further containing zinc oxide.
  • the present invention provides the deodorizing method described above, wherein the antibacterial metal ion in the antibacterial zeolite is one or more selected from silver, copper and zinc ions.
  • the composition for use is provided.
  • the present invention is characterized in that the antibacterial zeolite has an average particle size of 10 ⁇ m or less, and a particle size distribution in which the particle size exceeds 15 m is 20% or less.
  • a deodorant composition is provided.
  • the present invention also provides a deodorant cosmetic comprising the deodorant composition described above.
  • the present invention provides a deodorizing composition
  • a deodorizing composition comprising antibacterial zeolite, a surfactant, and porous silica having a specific surface area of 150 m 2 Zg or more.
  • the present invention also provides the above deodorizing composition characterized by further containing zinc oxide.
  • the present invention provides the deodorizing method described above, wherein the antibacterial metal ions in the antibacterial zeolite are one or more selected from silver, copper and zinc ions.
  • the composition for use is provided.
  • the present invention is characterized in that the antibacterial zeolite has an average particle size of 10 ⁇ m or less, and a particle size distribution in which the particle size exceeds 15 m is 20% or less.
  • a deodorant composition is provided.
  • the present invention provides a deodorant cosmetic characterized by comprising the above-mentioned deodorant composition.
  • the deodorant composition of the present invention is effective for cleaning and removing stains generated when adhering to clothes. It is excellent and can be suitably used particularly as a deodorant cosmetic.
  • the deodorant composition of the present invention discoloration is remarkably suppressed. Therefore, even if it is slightly contaminated with clothes, it can be washed by washing, so that it easily adheres to clothes and can be suitably used as a deodorant cosmetic.
  • FIG. 1 is a photographic diagram showing the cleaning removal effect of the first invention.
  • FIG. 2 is a photographic diagram showing discoloration of the second invention.
  • a zeolite powder holding an antibacterial metal ion in an ion exchangeable portion of the zeolite is used. That is, it is a zeolite powder in which some or all of the ion exchangeable ions of zeolite are substituted with an antibacterial metal.
  • zeolite substituted with ammonia ions together with antibacterial metal ions is also preferred.
  • Zeolite may be a shift between natural and synthetic zeolite! /.
  • Zeolite is generally an aluminosilicate with a three-dimensional skeleton structure.
  • the general formula is XM 0-A1
  • ⁇ is the valence of the (metal) ion.
  • X and ⁇ indicate metal oxides and silica coefficients, respectively, and ⁇ indicates the number of crystal water.
  • zeolite examples include, for example, soot-type zeolite, X-type zeolite, Y-type zeolite, T-type zeolite, high silica zeolite, sodalite, mordenite, analsim, clinoptite light, and chiabasite. And erionite.
  • the ion exchange capacity of these zeolites is A-type zeolite 7meq / g, X-type zeolite 6.4meqZg, Y-type zeolite 5meqZg, T-type zeolite 3.4meqZg, sodalite 11.5meqZg, mordenite 2. 6meqZg, Anal thyme 5meqZg, Clinopti lipstick 2. 6meq / g, Chianosai 5meq / g, Yezi nai night 3.3.8meq / g. Spear They also have sufficient capacity for ion exchange with antibacterial metal ions and ammonia ions.
  • the ion-exchangeable ions in the zeolite are, for example, sodium ion, calcium ion, potassium ion, magnesium ion, iron ion and the like.
  • the antibacterial metal ion substituted by these ions is, for example, silver, copper, zinc, mercury, tin, lead, bismuth, cadmium, chromium, or thallium, and preferably silver, copper, or zinc More preferably, it is a silver ion.
  • the antibacterial metal ions are preferably contained in the zeolite in an amount of 0.1 to 15% by mass.
  • antibacterial zeolite containing 0.1 to 15% silver ions and 0.1 to 8% by mass of copper ions or zinc ions is preferable.
  • ammonium ion is a force that can be contained in zeolite up to 20% by mass.
  • 0.5-5% by mass in zeolite is more preferable.
  • ⁇ 2% by mass is more preferred.
  • the mass% is the mass percentage in zeolite of 110 ° C dry standard.
  • a commercially available antibacterial zeolite can be used.
  • a method for producing the antibacterial zeolite for example, it is prepared as follows. That is, zeolite is brought into contact with a mixed aqueous solution containing antibacterial metal ions such as silver ions, copper ions, and zinc ions prepared in advance to replace the ions with ion-exchangeable ions in the zeolite.
  • the contact can be carried out at 10 to 70 ° C., preferably 40 to 60 ° C. for 3 to 24 hours, preferably 10 to 24 hours, batchwise or continuously (for example, column method).
  • the pH of the above mixed aqueous solution is suitably adjusted to 3 to: LO, preferably 5 to 7.
  • Each ion in the mixed aqueous solution is usually supplied as a salt.
  • silver ions are silver nitrate, silver sulfate, silver perchlorate, silver acetate, diammine silver nitrate, diammine silver sulfate, etc.
  • copper ions are copper nitrate (11), copper perchlorate, copper acetate, tetraciano.
  • Zinc ions are zinc nitrate (11), zinc sulfate, zinc perchlorate, zinc thiocyanate, zinc acetate, etc.
  • mercury ions are mercury perchlorate, mercury nitrate, acetic acid.
  • Mercury, tin ion is tin sulfate, etc.
  • lead ion is lead sulfate, lead nitrate, etc.
  • bismuth ion is bis chloride.
  • Cadmium ions are cadmium perchlorate, cadmium sulfate, cadmium nitrate, cadmium acetate
  • chromium ions are chromium perchlorate, chromium sulfate, ammonium chromium sulfate, chromium nitrate, etc.
  • thallium ions such as thallium perchlorate, thallium sulfate, thallium nitrate, and thallium acetate can be used.
  • the content of antibacterial metal ions in the zeolite can be appropriately controlled by adjusting the concentration of each ion (salt) in the mixed aqueous solution.
  • concentration of silver ions in the mixed aqueous solution is set to 0.002 MZ1 to 0.15 MZ1, so that the antibacterial zeolite having a silver ion content of 0.1 to 5% is appropriately selected. Can be obtained.
  • the copper ion concentration in the mixed aqueous solution should be 0.1 MZ1 to 0.85 M / U zinc ion concentration 0.15 MZl to l.2 MZ1.
  • an antibacterial zeolite having a copper ion content of 0.1 to 8% and a zinc ion content of 0.1 to 8% can be obtained.
  • the antibacterial zeolite can be ion-exchanged by sequentially contacting each aqueous solution with zeolite using an aqueous solution containing each ion alone.
  • the concentration of each ion in each aqueous solution can be determined according to the concentration of each ion in the mixed aqueous solution.
  • the zeolite after the ion exchange is thoroughly washed and dried. Drying is preferably performed at 105-115 ° C or 70-90 ° C under reduced pressure (l-30 Torr)! /.
  • the blending amount of the antibacterial zeolite in the deodorizing composition is not particularly limited. It is determined appropriately depending on the product form of the deodorant composition. Usually, it is 0.1-90 mass% with respect to the deodorant composition whole quantity, Preferably it is 1-70 mass%, More preferably, it is 5-70 mass%. The same applies to the total amount of deodorant cosmetics. When the deodorant cosmetic is a sticky cosmetic, 5 to 20% by mass is particularly preferable.
  • the average particle diameter of the antibacterial zeolite is preferably 10 ⁇ m or less. More preferably, it is 0.1-5 / ⁇ ⁇ . In addition, when the average particle size is within this range, the particle size distribution It is preferable that the particle size exceeding 15 ⁇ m is 20% or less.
  • the powder used in the present invention is a highly oil-absorbing powder (not including silicone rubber powder) having a specific surface area of 150 m 2 / g or more and an oil absorption of lOOml / 1 OOg or more.
  • the specific surface area is calculated by measuring the amount of nitrogen adsorbed on the powder at 77K and analyzing it by the BET method.
  • OMNISORP manufactured by Beckmann Coluter is used as the measuring instrument.
  • the amount of oil absorption is 0.1 g of squalane per 100 g of powder, mixed by manual stirring, the oil absorption limit is judged by visual sensation, and the amount of squalane added up to that point is defined as the oil absorption amount.
  • the powder is porous silica (Carplex # 67, manufactured by Shionogi & Co., Ltd., specific surface area 170 m 2 Zg, oil absorption 250 ml Zl00 g), porous silica (Asahi Glass Co., Ltd., Sanfair L-51, specific surface area 300 m 2 / g), aluminate metasilicate (Neusilin NFL2N, manufactured by Fuji Chemical Co., Ltd., specific surface area 250 m 2 / g, oil absorption 198 ml Zl00 g).
  • porous silica Carplex # 67, manufactured by Shionogi & Co., Ltd., specific surface area 170 m 2 Zg, oil absorption 250 ml Zl00 g
  • porous silica Asahi Glass Co., Ltd., Sanfair L-51, specific surface area 300 m 2 / g
  • aluminate metasilicate Nesilin NFL2N, manufactured by Fuji Chemical Co.,
  • silicone rubber powder used in the present invention a powder of a three-dimensional crosslinked polymer of silicone that does not limit the specific surface area and the amount of oil absorption may be used.
  • a powder of a three-dimensional crosslinked polymer of silicone that does not limit the specific surface area and the amount of oil absorption
  • (dimethicone Z bur dimethicone Z methicone) crosspolymer KSP 100 manufactured by Shin-Etsu Chemical Co., Ltd.
  • methylsiloxane 'dimethylsiloxane' methylhydrogensiloxane 'trimethylsiloxane copolymer Toray Dow Co., Ltd. Silicone Co., Ltd.
  • the amount of the powder blended into the deodorant composition is not particularly limited. It is determined appropriately depending on the product form of the deodorant composition. Usually, it is 0.1-90 mass% with respect to the deodorant composition whole quantity, Preferably it is 1-20 mass%, More preferably, it is 3-: L0 mass%. The same is applied to the total amount of deodorant cosmetics. In the case of a deodorizing cosmetic power and a ticky cosmetic, 3 to 10% by mass is particularly preferable.
  • the surfactant used in the present invention is not particularly limited as long as it is a general surfactant used in cosmetics.
  • the following surfactants can be blended.
  • the surfactants include fatty acid soaps (for example, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (for example, sodium lauryl sulfate, potassium lauryl sulfate); alkyl ether sulfates (Eg, PO E-lauryl sulfate triethanolamine, POE-sodium lauryl sulfate, etc.); N-acyl sarcosine acid (eg, sodium lauroyl sarcosine, etc.); higher fatty acid amide sulfonates (eg, N-myristoyl-N- Methyl taurine sodium, palm oil fatty acid methyl taurine sodium, lauryl methyl taurine sodium, etc .; phosphate ester salts (POE-oleyl ether sodium phosphat
  • Cationic surfactants include, for example, alkyltrimethyl ammonium salts (eg, stearyl trimethyl ammonium salts, salt lauryl trimethyl ammonium salts, etc.); alkyl pyridinium salts (eg, salt salts). ⁇ cetylpyridium, etc.); salt ⁇ distearyl dimethylammonium dialkyldimethylammonium salt; poly ( ⁇ , ⁇ '-dimethyl-3,5-methylenepiveridium); alkyl quaternary ammonium -Um salt; alkyldimethylbenzyl ammonium salt; alkyl isoquinolium salt; dialkyl morpholine salt; POE-alkylamine; alkylamine salt; polyamine fatty acid derivative; amyl alcohol fatty acid derivative; Zarkoum; salted benzetonum.
  • alkyltrimethyl ammonium salts eg, stearyl trimethyl ammonium salts, salt lauryl trimethyl ammoni
  • amphoteric surfactants examples include imidazoline-based amphoteric surfactants (for example, 2-undecyl- ⁇ , ⁇ , ⁇ - (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2 -Imidazol-hydroxyl-1-carboxyethyloxy disodium salt, etc .; Betaine surfactants (for example, 2-heptadecyl- ⁇ -carboxymethyl- ⁇ -hydroxyethyl imidazolidum-mubetaine, lauryldimethylaminoacetic acid) Betaine, alkyl betaine, amide betaine, sulfobetaine, etc.).
  • imidazoline-based amphoteric surfactants for example, 2-undecyl- ⁇ , ⁇ , ⁇ - (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2 -Imidazol-hydroxyl-1-carboxyethyloxy
  • lipophilic nonionic surfactant examples include sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquiate).
  • sorbitan fatty acid esters for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquiate.
  • hydrophilic nonionic surfactants include ⁇ -sorbitan fatty acid esters (eg, ⁇ -sorbitan monooleate, ⁇ -sorbitan monostearate, ⁇ -sorbitan monooleate, ⁇ -sorbitan tetraoleate).
  • ⁇ -sorbitan fatty acid esters eg, ⁇ -sorbitan monooleate, ⁇ -sorbitan monostearate, ⁇ -sorbitan monooleate, ⁇ -sorbitan tetraoleate.
  • ⁇ sorbite fatty acid esters eg, ⁇ -sorbite monolaurate, ⁇ -sorbitol monooleate, ⁇ -sorbitol pentaoleate, ⁇ -sorbitol monostearate, etc.
  • ⁇ -glycerin fatty acid Esters eg, ⁇ -glycerol monostearate, ⁇ -glycerol monoisostearate, ⁇ -glycerol monoisostearate, etc.
  • ⁇ -fatty acid esters eg, ⁇ -distearate, ⁇ - Monodiolate, ethyl stearate ⁇ ⁇ ⁇ ⁇ -alkyl ethers (e.g., ⁇ -lauryl ether, ⁇ -oleyl ether, ⁇ -stearyl ether, ⁇ -behether ether, ⁇ -2-octyldodecyl ether, ⁇ -cholestanol ether) Etc); Pull
  • the amount of surfactant added to the deodorant composition is not particularly limited. It is determined appropriately depending on the product form of the deodorant composition. Usually, it is 0.01-10 mass% with respect to the deodorant composition whole quantity, Preferably it is 0.1-3 mass%, More preferably, it is 0.3-2 mass%. The same is applied to the total amount of deodorant cosmetics. In the case of a deodorizing cosmetic power and a ticky cosmetic, 0.5 to 3% by mass is particularly preferable.
  • the porous silica used in the present invention is a silica having a specific surface area of 150 m 2 / g or more, and is a highly oil-absorbing silica. More preferably, the specific surface area is 300 m 2 Zg or more.
  • the specific surface area was calculated by measuring the amount of nitrogen adsorbed on the powder at 77 K and analyzing it by the BET method. OMNISORP manufactured by Beckmann Coluter was used as a measuring instrument.
  • the average pore diameter is preferably 1 nm or more. Particularly preferred is an amorphous porous silica (Sunsphere L-51, manufactured by Asahi Glass Co., Ltd., specific surface area of 300 m 2 / g, average pore diameter of 13 nm).
  • the amount of porous silica blended into the deodorant composition is not particularly limited. It is determined as appropriate according to the product form of the deodorant composition. Usually, it is 0.1 to 90% by mass, preferably 1 to 20% by mass, and more preferably 3 to 10% by mass with respect to the total amount of the deodorant composition. The same is applied to the total amount of deodorant cosmetics. Deodorant cosmetic power ⁇ 3-10 for ticky cosmetics Mass% is particularly preferred.
  • a finely divided zinc oxide powder that is preferred even if a zinc oxide powder is blended with the composition of the present invention is particularly preferred.
  • the average particle size is preferably 0.5 m or less.
  • the content of the zinc oxide powder is 0.1 to 10% by mass, preferably 0.5 to 5% by mass, and more preferably 2 to 4% by mass with respect to the total amount of the deodorant composition. The same is applied to the total amount of deodorant cosmetics. When the deodorant cosmetic is a sticky cosmetic, 2 to 4% by mass is particularly preferable.
  • the use of the deodorant composition of the present invention is not limited, but it is suitably used as a deodorant cosmetic.
  • a deodorant cosmetic In addition to the essential constituents described above, other components usually used in cosmetics, for example, one or two or more of the components exemplified below are appropriately blended in the deodorant cosmetic as necessary, and the desired dosage form Can be produced in accordance with conventional methods.
  • powder components other than essential components include, for example, inorganic powders (for example, talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, saucite, biotite, permite, Magnesium carbonate, Calcium carbonate, Aluminum silicate, Barium silicate, Caustic acid Lucium, Magnesium silicate, Strontium silicate, Metal tungstate, Magnesium, Silica, Barium sulfate, Calcined calcium sulfate (calcined gypsum), Calcium phosphate, Fluorine apatite, hydroxyapatite, ceramic powder, metal sarcophagus (for example, zinc myristate, calcium normitate, aluminum stearate), boron nitride, etc .; organic powder (for example, polyamide resin powder (nylon powder), polyethylene Powder, polymethyl methacrylate powder, Nzoguanamine rosin powder, polyt
  • liquid fats examples include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, barley germ oil, and southern power oil , Castor oil, linseed oil, safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, teaseed oil, cypress oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin, etc. Is mentioned.
  • Examples of the solid fat include cacao butter, coconut oil, hardened coconut oil, palm oil, palm kernel oil, owl kernel oil, hardened oil, crowberry, and hardened castor oil.
  • Examples of the wax include beeswax, candelilla wax, cotton wax, carnauba wax, beberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, lauric acid Hexyl, reduced lanolin, jojoba wax, hard lanolin, shellac wax, ⁇ lanolin alcohol ether, ⁇ lanolin alcohol acetate, ⁇ cholesterol ether, lanolin fatty acid polyethylene glycol, ⁇ hydrogenated ⁇ lanolin alcohol ether, ceresin, microcrystalline wax, etc. Is mentioned.
  • hydrocarbon oil examples include liquid paraffin, ozokerite, squalane, pristane, paraffin, squalene, petrolatum and the like.
  • Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid ( ⁇ ), Examples include docosahexaenoic acid (DHA).
  • DHA docosahexaenoic acid
  • Examples of higher alcohols include linear alcohols (for example, lauryl alcohol, Cetino-leanolecole, stearino-leanolecole, behenino-leanolecole, myristino-leanolol, oleyl alcohol, cetostearyl alcohol, etc .; branched chain alcohols (eg monostearyl glycerol ether (batyl alcohol) ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, otatildodecanol, etc.).
  • linear alcohols for example, lauryl alcohol, Cetino-leanolecole, stearino-leanolecole, behenino-leanolecole, myristino-leanolol, oleyl alcohol, cetostearyl alcohol, etc .
  • branched chain alcohols eg
  • ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate , Myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, di-2-ethylethyl ethylene glycol, dipentaerythritol fatty acid ester, monoisostearate N-alkyl glycol , Neopentyl glycol dicaprate, diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhe
  • silicone oil examples include linear polysiloxanes (eg, dimethylpolysiloxane, methylphenol polysiloxane, diphenylpolysiloxane, etc.), cyclic polysiloxanes (eg, otatamethylcyclotetrasiloxane, decamethyl).
  • linear polysiloxanes eg, dimethylpolysiloxane, methylphenol polysiloxane, diphenylpolysiloxane, etc.
  • cyclic polysiloxanes eg, otatamethylcyclotetrasiloxane, decamethyl
  • Examples of the moisturizing agent include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12 -Hydroxy stearate, sodium lactate, bile salt, cQ-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, Isaiba rose extract, Sawflower saw extract, Merilot extract, etc. It is done.
  • EO diglycerin
  • Natural water-soluble polymers include, for example, plant polymers (for example, gum arabic, gum tragacanth, galactan, guar gum, kilobum gum, cara gum, carrageenan, pectin, agar, quincese (malt mouth), algae Colloid (cuttlefish extract), starch (rice, corn, potato, wheat), glycyrrhizic acid ⁇ ; microbial polymers (eg, xanthan gum, dextran, succinoglucan, bull run, etc.); other (eg, fish-derived collagen, fish-derived) Gelatin, wheat protein, silk protein, etc.).
  • plant polymers for example, gum arabic, gum tragacanth, galactan, guar gum, kilobum gum, cara gum, carrageenan, pectin, agar, quincese (malt mouth), algae Colloid (cuttlefish extract), starch (rice, corn, potato, wheat), glycyrrhizic acid ⁇ ;
  • Semi-synthetic water-soluble polymers include, for example, starch polymers (for example, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose polymers (methyl senorelose, ethinorescenellose, methinorehydroxy) Propinoresenorelose, hydroxycellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxymethylenosesylose, sodium carboxymethylcellulose, crystalline cellulose, cellulose And alginic acid polymers (for example, sodium alginate, propylene glycol alginate, etc.) and the like.
  • starch polymers for example, carboxymethyl starch, methylhydroxypropyl starch, etc.
  • cellulose polymers methyl senorelose, ethinorescenellose, methinorehydroxy
  • Propinoresenorelose hydroxycellulose
  • sodium cellulose sulfate hydroxypropylcellulose
  • carboxymethylenosesylose sodium carboxymethylcellulose
  • Examples of the synthetic water-soluble polymer include vinyl polymers (for example, polybutyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer, etc.).
  • Polyoxyethylene polymer eg, polyethylene glycol 20,000, 40,000, 60,000 polyoxyethylene polyoxypropylene copolymer, etc.
  • Acrylic polymer eg, sodium polyacrylate, polyethylene acrylate) Rate, polyacrylamide and the like
  • polyethyleneimine cationic polymer and the like.
  • thickeners examples include gum arabic, carrageenan, caraja gum, gum tragacanth, carob gum, quince seed (manolemero), casein, dextrin, gelatin, sodium pectate, sodium aradate, methylcellulose, ethylcellulose, CMC, Hydrochichechinole cellulose, hydroxypropinole cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxybule polymer, locust bean gum, guar gum, tamarint gum, dialkyldimethylammonium sulfate cellulose, xanthan gum, aluminum carbonate
  • examples thereof include magnesium, bentonite, hectorite, silicate AlMg (beegum), laponite, and anhydrous carboxylic acid.
  • Examples of the ultraviolet absorber include the following compounds.
  • paraaminobenzoic acid hereinafter abbreviated as PABA
  • PABA monoglycerin ester N, N-dipropoxy PABA ethyl ester, ⁇ , ⁇ -jetoxy PABA ethyl ester, ⁇ , ⁇ -dimethyl PABA ethyl ester, ⁇ , ⁇ -dimethyl PABA butyl ester , ⁇ , ⁇ -dimethyl P ABA ethyl ester and the like.
  • homomenthyl-N-acetylethyl anthrate For example, homomenthyl-N-acetylethyl anthrate.
  • octylcinnamate ethyl-4-isopropylcinnamate, methyl-2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylpropylcinnamate, propyl-p -Methoxycinnamate, isopropyl-p-methoxycinnamate, isamyl-P-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl -p- Methoxycinnamate, Cyclic Hexyl-p-Methoxycinnamate, Ethyl A-Cyanano 13-Fercinnamate, 2-Ethylhexyloo A-Cyano 13-Fercinnamate
  • Pyridazine derivatives such as dimorpholinopyridazinone.
  • sequestering agents include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyquiginan-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate.
  • Edetate tetrasodium salt examples include sodium citrate, sodium polyphosphate, sodium metaphosphate, darconic acid, phosphoric acid, citrate, ascorbic acid, succinic acid, and edetic acid.
  • the lower alcohol include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.
  • polyhydric alcohol examples include divalent alcohols (for example, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3- Butylene glycol, pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trivalent alcohol (eg, glycerin, trimethylolpropane, etc.); tetravalent alcohol (eg, Pentaerythritol such as 1,2,6-hexanetriol, etc .; pentahydric alcohol (eg, xylitol, etc.); hexavalent alcohol (eg, sorbitol, mannitol, etc.); polyhydric alcohol polymer (eg, Diethylene glycol, dipropylene glycol, triethylene glycol, poly Pyrene glycol, tetraethylened
  • H erythrose mononole, gnoleose, funolectose, starch
  • glycolide tetrahydrate-furfuryl alcohol; POE -Tetrahydride furfuryl alcohol; POP-butyl ether; ⁇ ⁇ POE-butyl ether; Tripolyoxypropylene glycerol ether; POP-glycerol ether; POP-glycerol ether phosphate; POP ⁇ POE-pentaneerythritol ether, polyglycerol, etc. Can be mentioned.
  • Examples of monosaccharides include, for example, tricarbon sugars (eg, D-glyceryl aldehyde, dihydroxyacetone); tetracarbon sugars (eg, D-erythrose, D-erythrulose, D-threose, erythritol, etc.) Pentose (eg, L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc.); hexose (eg, D- Glucose, D-talose, D-bucose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc .; hepta sugar (eg, aldoheptose, heptose, etc.); Sugars (eg, al
  • oligosaccharide examples include sucrose, umbelliferose, ratatose, planteose, isoliquinoses, (X, a-trehalose, raffinose, lycnose, umbilicin, stadium, Examples include the Chios Bell Bus Course.
  • polysaccharide examples include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guagam, Examples include dextran, keratosulfuric acid, locust bingham, succinoglucan, and caronic acid.
  • amino acids examples include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.) and the like.
  • amino acid derivatives include sodium acylsarcosine (lauroyl sarcosine sodium), acyl acyl glutamate, sodium acyl- ⁇ -alanine, dartathione, pyrrolidone carboxylic acid and the like.
  • organic amines examples include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl 1,3-propanediol, 2-amino-2-methyl.
  • examples include 1-propanol.
  • polymer emulsion examples include acrylic resin emulsion, polyacrylic acid ethyl emulsion, acrylic resin solution, polyacrylic alkyl ester emulsion, poly (acetic acid butyl resin emulsion), and natural rubber latex.
  • Examples of the ⁇ preparation agent include buffers such as lactic acid-sodium lactate, succinic acid-sodium succinate, and sodium succinate monosuccinate.
  • vitamins include vitamins A, Bl, B2, B6, C, sputum and derivatives thereof, pantothenic acid and derivatives thereof, and piotin.
  • anti-oxidation agent examples include tocopherols, dibutylhydroxytoluene, butyhydroxyl-sol, gallic acid esters and the like.
  • Antioxidant aids include, for example, phosphoric acid, citrate, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, ethylendiaminetetrakis ( 2-hydroxyisopropyl) dioleate, ethylenediaminetetrapolyoxypropylene, ethylenediaminehydroxyethyl sodium triacetate (dihydrate), sodium sodium ethylenediaminetetraacetate, edetic acid, trisodium edetate, Examples include dipotassium detoate dihydrate, disodium edetate, tetrasodium edetate, tetrasodium edetate dihydrate, and tetrasodium edetate tetrahydrate.
  • ingredients that can be incorporated include, for example, preservatives (methylparaben, ethylparaben, butylparaben, phenoxyethanol, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, alalane) Whitening agents (eg, Yukinoshita extract, arbutin, tranexamic acid, L-corbic acid, L-corsic acid phosphate magnesium salt, L-corsic acid glucoside, 4-methoxysalicylic acid potassium, etc.); various extracts ( For example, green tea, oolong tea, black tea, puar tea, cucumber, clara, obata, ollen, sicon, peonies, assembly, perch, sage, bean paste, carrot, aloe, zhaoi, iris, grape, yokwon,
  • the product form of the deodorant cosmetic composition of the present invention is not particularly limited.
  • a spray type, a mouth-on type, a powder type, a pressed powder (molded powder) type, a stick type and the like can be mentioned.
  • the spray type it is manufactured by filling a spray container such as an aerosol can or a dispenser together with a propellant such as liquid gas or alcohol with a conventional method.
  • a roll-on type it is manufactured by filling a roll-on container together with alcohol by a conventional method.
  • the Noda type and the pressed powder type they are mixed together with the powder components and oil, and in the case of the powder type, they are produced as they are.
  • the stick type it is produced by mixing with oil (solid oil, liquid oil), filling the container in a conventional manner, and molding.
  • a preferable product for the present invention is a stick-shaped diamond product containing a wax or a gelling agent.
  • a compounding quantity is the mass% with respect to the whole quantity unless there is particular notice.
  • a solid antiperspirant stick preparation containing various powders was prepared according to the following formulation. Apply a certain amount (0.06g / cm 2 ) of white clothing, artificial sweat (water tol00wt%, sodium chloride 0.8wt%, acetic acid 0.5wt%, disodium phosphate 12hydrate 0.8wt%) After 0.012 g / cm 2 was added dropwise, the degree of staining after exposure to sunlight (10 minutes) was evaluated visually. Next, the discolored clothing was washed with a washing machine using a normal laundry detergent, and the degree of staining after washing was visually evaluated. Judgment was made according to the following criteria.
  • Aerosil R972 manufactured by Nippon Aerosil Co., Ltd.
  • Gantz Pearl GMX0810 manufactured by Gantz Kasei Kogyo Co., Ltd.
  • My strength # 5500 My strength powder # 5500 manufactured by Wakita Banking Co., Ltd.
  • the antiperspirant cosmetics that also have the deodorant composition power of the present invention are listed below. All cosmetics have excellent cleaning and removal effects of stains when attached to clothing, and also have a good feeling of use.
  • Example 1 Deodorant Spray
  • the powder part is mixed with a kneader, the oil is mixed with a blender, each is sequentially filled into a spray can, and the propellant is filled into a can to obtain a powder spray.
  • Example 1-5 Deodorant powder
  • Metasilicate aluminate Mg (Specific surface area 250m 2 / g, oil absorption 198 ml) 10
  • the above ingredients are sequentially mixed with a Henschel mixer to obtain a deodorant powder.
  • Example 1-6 Deodorant Stick
  • a mixture of the above components is filled in a container to obtain a deodorant stick.
  • a mixture of the above components is filled in a container to obtain a deodorant stick.
  • Metasilicate aluminate Mg (specific surface area 250, oil absorption 198) 5
  • Oil-absorbing silica (specific surface area 300m 2 Zg, oil absorption l 4 3ml) 5
  • a mixture of the above components is filled in a container to obtain a deodorant stick.
  • a solid antiperspirant stick preparation containing various powders having the following formulation was prepared, filled in a container and exposed to direct light (sunlight and room light), and left in the room for a week.
  • ⁇ indicates no discoloration
  • ⁇ ⁇ indicates almost no discoloration
  • ⁇ indicates discoloration
  • discoloration is large and clear.
  • antiperspirant cosmetics that also have the deodorant composition power of the present invention.
  • V and slippery cosmetics are also excellent in anti-discoloration effect and usability.
  • the powder part is mixed with a kneader, the oil is mixed with a blender, each is sequentially filled into a spray, and a propellant is filled into a can to obtain a powder spray.
  • Example 2-4 Deodorant Powder
  • the above ingredients are sequentially mixed with a Henschel mixer to obtain a deodorant powder.
  • a mixture of the above components is filled in a container to obtain a deodorant stick.
  • a mixture of the above components is filled in a container to obtain a deodorant stick.
  • Methylphenol silicone 20 Cyclic silicone Residue Highly oil-absorbing silica (specific surface area 254 m 2 / g) 12.5 Silicone rubber powder 5
  • a mixture of the above components is filled in a container to obtain a deodorant stick.
  • a mixture of the above components is filled in a container to obtain a deodorant stick.
  • the deodorant composition of the present invention can effectively remove stains on clothes by washing and has an excellent deodorizing effect. Therefore, it can be suitably used particularly as a deodorant cosmetic.
  • the deodorant composition of the present invention has an excellent deodorizing effect with less discoloration due to light and less staining on clothes. Therefore, it can be suitably used particularly as a deodorant cosmetic.

Abstract

La présente invention concerne une composition de déodorant et un cosmétique déodorant caractérisés en ce qu'ils contiennent une zéolithe à activité antibactérienne et une poudre dotée d'une surface spécifique de 150 m²/g ou plus et d'une capacité d'absorption d'huile de 100 ml/100 g ou plus. En outre, cette invention concerne une composition de déodorant et un cosmétique déodorant caractérisés en ce qu'ils contiennent une zéolithe à activité antibactérienne et une poudre à base de gomme de silicone. En outre, l'invention concerne une composition de déodorant et un cosmétique déodorant caractérisés en ce qu'ils contiennent une zéolithe à activité antibactérienne, un tensioactif et du silicium poreux présentant une surface spécifique de 150 m²/g ou plus. L'invention a pour objectif de proposer une composition de déodorant et un cosmétique déodorant en mesure de supprimer efficacement au lavage la saleté de vêtements. De plus, un autre objectif de l'invention est de proposer une composition de déodorant qui réduit l'altération des couleurs et l'adhérence de la saleté, qui présente d'excellentes qualités déodorantes et qui peut, de préférence, être utilisée notamment comme déodorant cosmétique.
PCT/JP2007/051963 2006-02-27 2007-02-06 Composition de deodorant WO2007099738A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2006-050068 2006-02-27
JP2006050067A JP5019348B2 (ja) 2006-02-27 2006-02-27 消臭用組成物
JP2006050068A JP5036025B2 (ja) 2006-02-27 2006-02-27 消臭用組成物
JP2006-050067 2006-02-27

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US9687425B2 (en) 2014-06-30 2017-06-27 The Procter & Gamble Company Personal care compositions and methods
US9717930B2 (en) 2013-03-12 2017-08-01 The Procter & Gamble Company Antiperspirant compositions
US9877909B2 (en) 2014-06-30 2018-01-30 The Procter & Gamble Company Personal care compositions and methods
JP2018065800A (ja) * 2016-10-18 2018-04-26 花王株式会社 皮膚化粧料
US10016343B2 (en) 2013-03-12 2018-07-10 The Procter & Gamble Company Solid stick antiperspirant compositions
CN108430438A (zh) * 2015-12-09 2018-08-21 爱因斯有限公司 除臭用化妆品组合物及其制备方法
CN112334160A (zh) * 2018-06-22 2021-02-05 狮王株式会社 粉末除臭剂组合物、粉末除臭剂组合物制品和除臭方法
EP3831904A4 (fr) * 2019-10-08 2022-07-13 Koyo Corporation Composition d'adhésif sensible à la pression, procédé de production d'une composition adhésive sensible à la pression, et article contenant une composition adhésive sensible à la pression

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CN109943901B (zh) * 2017-12-20 2022-03-22 财团法人纺织产业综合研究所 消臭纤维及其制造方法

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US10052271B2 (en) 2013-03-12 2018-08-21 The Procter & Gamble Company Antiperspirant compositions
US9937113B2 (en) 2013-03-12 2018-04-10 The Procter & Gamble Company Antiperspirant compositions
US9717930B2 (en) 2013-03-12 2017-08-01 The Procter & Gamble Company Antiperspirant compositions
US10016343B2 (en) 2013-03-12 2018-07-10 The Procter & Gamble Company Solid stick antiperspirant compositions
US10716743B2 (en) 2014-06-30 2020-07-21 The Procter & Gamble Company Personal care compositions and methods
US10154949B2 (en) 2014-06-30 2018-12-18 The Procter & Gamble Company Personal care compositions and methods
US9687425B2 (en) 2014-06-30 2017-06-27 The Procter & Gamble Company Personal care compositions and methods
US9750671B2 (en) 2014-06-30 2017-09-05 The Procter & Gamble Company Personal care compositions and methods
US9877909B2 (en) 2014-06-30 2018-01-30 The Procter & Gamble Company Personal care compositions and methods
US10413493B2 (en) 2014-06-30 2019-09-17 The Procter & Gamble Company Personal care composition and methods
CN108430438A (zh) * 2015-12-09 2018-08-21 爱因斯有限公司 除臭用化妆品组合物及其制备方法
CN109862877B (zh) * 2016-10-18 2022-04-29 花王株式会社 皮肤化妆品
WO2018074440A1 (fr) * 2016-10-18 2018-04-26 花王株式会社 Produit cosmétique pour la peau
CN109862877A (zh) * 2016-10-18 2019-06-07 花王株式会社 皮肤化妆品
JP2018065800A (ja) * 2016-10-18 2018-04-26 花王株式会社 皮膚化粧料
TWI744393B (zh) * 2016-10-18 2021-11-01 日商花王股份有限公司 皮膚化妝料
CN112334160A (zh) * 2018-06-22 2021-02-05 狮王株式会社 粉末除臭剂组合物、粉末除臭剂组合物制品和除臭方法
EP3831904A4 (fr) * 2019-10-08 2022-07-13 Koyo Corporation Composition d'adhésif sensible à la pression, procédé de production d'une composition adhésive sensible à la pression, et article contenant une composition adhésive sensible à la pression

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