WO2007099738A1

WO2007099738A1 - Deodorant composition

Info

Publication number: WO2007099738A1
Application number: PCT/JP2007/051963
Authority: WO
Inventors: Hidefumi Araki; Yukiko Kamiya; Norinobu Yoshikawa
Original assignee: Shiseido Company, Ltd.
Priority date: 2006-02-27
Filing date: 2007-02-06
Publication date: 2007-09-07
Also published as: TW200731993A

Abstract

The invention is directed to a deodorant composition and a deodorant cosmetic characterized by containing an antibacterial zeolite and a powder with a specific surface area of 150 m2/g or more and an oil absorption amount of 100 ml/100 g or more. Further, the invention is directed to a deodorant composition and a deodorant cosmetic characterized by containing an antibacterial zeolite and a silicone gum powder. Further, the invention is directed to a deodorant composition and a deodorant cosmetic characterized by containing an antibacterial zeolite, a surfactant and porous silica with a specific surface area of 150 m2/g or more. An object of the invention is to provide a deodorant composition and a deodorant cosmetic capable of removing dirt on clothes efficiently by washing. Further, another object is to provide a deodorant composition which causes less color change and adhesion of dirt, is excellent in a deodorant effect and can be preferably applied particularly as a deodorant cosmetic.

Description

Deodorant composition

Technical field

[0001] [First invention]

The present invention relates to a deodorizing composition. More specifically, it is a deodorant composition used in deodorant cosmetics and the like that contains antibacterial zeolite, has an excellent deodorizing effect, and is used to prevent clothes from being stained due to the antibacterial zeolite. Deodorant composition with improved detergency

The

[0002] [Second Invention]

In addition, it is a deodorant composition for use in deodorant cosmetics and the like that contains antibacterial zeolite, has an excellent deodorizing effect, and has less discoloration and staining caused by the antibacterial zeolite. Related to things.

Background art

[0003] [First and second inventions]

Antibacterial zeolite powder is mainly blended in deodorizing compositions such as deodorant cosmetics as a deodorant.

[0004] For example, antibacterial spray compositions containing antibacterial zeolite (see Patent Document 1) and deodorant cosmetics (see Patent Document 2) have been developed.

Furthermore, as a deodorant cosmetic material with improved discoloration resistance, a technique in which silicone is combined with antibacterial zeolite is disclosed (see Patent Document 3).

[0005] Deodorant cosmetics (also called antiperspirant cosmetics and deodorant cosmetics) are used to prevent or suppress the emission and secretion of unpleasant body odors, or to eliminate the emission and secretion components. Cosmetics. This product form is generally used as a lotion, cream, powder, sticky or aerosol.

[0006] Patent Document 1: Japanese Patent Laid-Open No. 63-250325

Patent Document 2: JP-A-8-26956

Patent Document 3: JP-A-8-92051 Disclosure of the invention

Problems to be solved by the invention

[0007] [First and second inventions]

The deodorant cosmetics disclosed in Patent Documents 1 to 3 are deodorization methods utilizing the bactericidal action of antibacterial zeolite. However, deodorant cosmetics with antibacterial zeolite have the disadvantage that they discolor after application and become soiled on clothes, and stains remain on clothes immediately after washing. Therefore, it is desired to develop a deodorant cosmetic that is excellent in discoloration and antifouling effects, is excellent in use feeling, and has a good deodorization effect.

[0008] [First invention]

As a result of diligent research on the above-mentioned problems of antibacterial zeolite, the present inventors have found that when antibacterial zeolite and a specific powder are combined in a deodorizing composition, the adhesion to clothes is prevented. The present inventors have found that the washing effect of washing is improved and completed the present invention.

[0009] An object of the present invention is to provide a deodorant composition that is excellent in the effect of cleaning and removing stains adhering to clothes and that can be suitably used particularly as a deodorant cosmetic.

[0010] [Second invention]

As a result of intensive studies on the above-mentioned problems of antibacterial zeolite, the present inventors have found that a large discoloration occurs when an antibacterial zeolite and a surfactant coexist, but this is a porous material having a specific surface area. It has been found that when silica is blended, a deodorant composition with less discoloration and contamination and an excellent deodorizing effect can be obtained, and the present invention has been completed.

[0011] An object of the present invention is to provide a deodorizing composition that is excellent in deodorizing effect with less discoloration and staining and that can be suitably used particularly as a deodorizing cosmetic.

Means for solving the problem

[0012] [First invention: Claims 1 to 6]

That is, the present invention provides a deodorizing composition comprising antibacterial zeolite and a powder having a specific surface area of 150 m ² / g or more and an oil absorption of lOOmlZlOOg or more. .

[0013] In addition, the present invention is characterized by containing an antibacterial zeolite and a silicone rubber powder. The present invention provides a deodorizing composition.

[0014] Furthermore, the present invention provides the above-mentioned deodorizing composition further containing zinc oxide.

[0015] Further, the present invention provides the deodorizing method described above, wherein the antibacterial metal ion in the antibacterial zeolite is one or more selected from silver, copper and zinc ions. The composition for use is provided.

[0016] Further, the present invention is characterized in that the antibacterial zeolite has an average particle size of 10 μm or less, and a particle size distribution in which the particle size exceeds 15 m is 20% or less. A deodorant composition is provided.

[0017] The present invention also provides a deodorant cosmetic comprising the deodorant composition described above.

[0018] [Second invention: Claims 7 to: L 1]

That is, the present invention provides a deodorizing composition comprising antibacterial zeolite, a surfactant, and porous silica having a specific surface area of 150 m ² Zg or more.

[0019] The present invention also provides the above deodorizing composition characterized by further containing zinc oxide.

[0020] Further, the present invention provides the deodorizing method described above, wherein the antibacterial metal ions in the antibacterial zeolite are one or more selected from silver, copper and zinc ions. The composition for use is provided.

[0021] Further, the present invention is characterized in that the antibacterial zeolite has an average particle size of 10 μm or less, and a particle size distribution in which the particle size exceeds 15 m is 20% or less. A deodorant composition is provided.

[0022] Further, the present invention provides a deodorant cosmetic characterized by comprising the above-mentioned deodorant composition.

The invention's effect

[0023] [First invention]

The deodorant composition of the present invention is effective for cleaning and removing stains generated when adhering to clothes. It is excellent and can be suitably used particularly as a deodorant cosmetic.

[0024] [Second Invention]

In the deodorant composition of the present invention, discoloration is remarkably suppressed. Therefore, even if it is slightly contaminated with clothes, it can be washed by washing, so that it easily adheres to clothes and can be suitably used as a deodorant cosmetic.

Brief Description of Drawings

FIG. 1 is a photographic diagram showing the cleaning removal effect of the first invention.

FIG. 2 is a photographic diagram showing discoloration of the second invention.

BEST MODE FOR CARRYING OUT THE INVENTION

[0026] Hereinafter, the present invention will be described in detail.

[0027] [First and second inventions]

As the antibacterial zeolite used in the present invention, a zeolite powder holding an antibacterial metal ion in an ion exchangeable portion of the zeolite is used. That is, it is a zeolite powder in which some or all of the ion exchangeable ions of zeolite are substituted with an antibacterial metal. In the present invention, zeolite substituted with ammonia ions together with antibacterial metal ions is also preferred.

[0028] Zeolite may be a shift between natural and synthetic zeolite! /. Zeolite is generally an aluminosilicate with a three-dimensional skeleton structure. The general formula is XM 0-A1

2 / n

O -YSiO · ΖΗ Ο is displayed. In this general formula, Μ is ion-exchangeable

2 3 2 2

It is usually a monovalent or divalent metal ion. η is the valence of the (metal) ion. X and Υ indicate metal oxides and silica coefficients, respectively, and Ζ indicates the number of crystal water.

[0029] Specific examples of zeolite include, for example, soot-type zeolite, X-type zeolite, Y-type zeolite, T-type zeolite, high silica zeolite, sodalite, mordenite, analsim, clinoptite light, and chiabasite. And erionite.

[0030] The ion exchange capacity of these zeolites is A-type zeolite 7meq / g, X-type zeolite 6.4meqZg, Y-type zeolite 5meqZg, T-type zeolite 3.4meqZg, sodalite 11.5meqZg, mordenite 2. 6meqZg, Anal thyme 5meqZg, Clinopti lipstick 2. 6meq / g, Chianosai 5meq / g, Yezi nai night 3.3.8meq / g. Spear They also have sufficient capacity for ion exchange with antibacterial metal ions and ammonia ions.

[0031] The ion-exchangeable ions in the zeolite are, for example, sodium ion, calcium ion, potassium ion, magnesium ion, iron ion and the like. In addition, the antibacterial metal ion substituted by these ions is, for example, silver, copper, zinc, mercury, tin, lead, bismuth, cadmium, chromium, or thallium, and preferably silver, copper, or zinc More preferably, it is a silver ion.

[0032] From the viewpoint of antibacterial properties, the antibacterial metal ions are preferably contained in the zeolite in an amount of 0.1 to 15% by mass. For example, antibacterial zeolite containing 0.1 to 15% silver ions and 0.1 to 8% by mass of copper ions or zinc ions is preferable. On the other hand, ammonium ion is a force that can be contained in zeolite up to 20% by mass. From the viewpoint of effectively preventing discoloration of zeolite, 0.5-5% by mass in zeolite is more preferable. ~ 2% by mass is more preferred. The mass% is the mass percentage in zeolite of 110 ° C dry standard.

In the present invention, a commercially available antibacterial zeolite can be used. As a method for producing the antibacterial zeolite, for example, it is prepared as follows. That is, zeolite is brought into contact with a mixed aqueous solution containing antibacterial metal ions such as silver ions, copper ions, and zinc ions prepared in advance to replace the ions with ion-exchangeable ions in the zeolite. The contact can be carried out at 10 to 70 ° C., preferably 40 to 60 ° C. for 3 to 24 hours, preferably 10 to 24 hours, batchwise or continuously (for example, column method). The pH of the above mixed aqueous solution is suitably adjusted to 3 to: LO, preferably 5 to 7. This adjustment is preferable because precipitation on the zeolite surface or pores such as silver oxide can be prevented. Each ion in the mixed aqueous solution is usually supplied as a salt. For example, silver ions are silver nitrate, silver sulfate, silver perchlorate, silver acetate, diammine silver nitrate, diammine silver sulfate, etc., and copper ions are copper nitrate (11), copper perchlorate, copper acetate, tetraciano. Zinc ions are zinc nitrate (11), zinc sulfate, zinc perchlorate, zinc thiocyanate, zinc acetate, etc., and mercury ions are mercury perchlorate, mercury nitrate, acetic acid. Mercury, tin ion is tin sulfate, etc., lead ion is lead sulfate, lead nitrate, etc., bismuth ion is bis chloride. Cadmium ions are cadmium perchlorate, cadmium sulfate, cadmium nitrate, cadmium acetate, and chromium ions are chromium perchlorate, chromium sulfate, ammonium chromium sulfate, chromium nitrate, etc. Yes, thallium ions such as thallium perchlorate, thallium sulfate, thallium nitrate, and thallium acetate can be used.

[0034] The content of antibacterial metal ions in the zeolite can be appropriately controlled by adjusting the concentration of each ion (salt) in the mixed aqueous solution. For example, when the antibacterial zeolite contains silver ions, the concentration of silver ions in the mixed aqueous solution is set to 0.002 MZ1 to 0.15 MZ1, so that the antibacterial zeolite having a silver ion content of 0.1 to 5% is appropriately selected. Can be obtained. In addition, when the antibacterial zeolite contains further copper ions and zinc ions, the copper ion concentration in the mixed aqueous solution should be 0.1 MZ1 to 0.85 M / U zinc ion concentration 0.15 MZl to l.2 MZ1. As appropriate, an antibacterial zeolite having a copper ion content of 0.1 to 8% and a zinc ion content of 0.1 to 8% can be obtained. In addition to the above mixed aqueous solution, the antibacterial zeolite can be ion-exchanged by sequentially contacting each aqueous solution with zeolite using an aqueous solution containing each ion alone. The concentration of each ion in each aqueous solution can be determined according to the concentration of each ion in the mixed aqueous solution.

[0035] The zeolite after the ion exchange is thoroughly washed and dried. Drying is preferably performed at 105-115 ° C or 70-90 ° C under reduced pressure (l-30 Torr)! /.

[0036] It should be noted that, in the case of appropriate water-soluble salts such as tin and bismuth, ion exchange of ions and organic ions does not cause poorly soluble basic salts to precipitate using an organic solvent solution such as alcohol or acetone. Can be reacted.

[0037] The blending amount of the antibacterial zeolite in the deodorizing composition is not particularly limited. It is determined appropriately depending on the product form of the deodorant composition. Usually, it is 0.1-90 mass% with respect to the deodorant composition whole quantity, Preferably it is 1-70 mass%, More preferably, it is 5-70 mass%. The same applies to the total amount of deodorant cosmetics. When the deodorant cosmetic is a sticky cosmetic, 5 to 20% by mass is particularly preferable.

[0038] The average particle diameter of the antibacterial zeolite is preferably 10 μm or less. More preferably, it is 0.1-5 / ζ πι. In addition, when the average particle size is within this range, the particle size distribution It is preferable that the particle size exceeding 15 μm is 20% or less.

[0039] [First invention]

The powder used in the present invention is a highly oil-absorbing powder (not including silicone rubber powder) having a specific surface area of 150 m ² / g or more and an oil absorption of lOOml / 1 OOg or more.

The specific surface area is calculated by measuring the amount of nitrogen adsorbed on the powder at 77K and analyzing it by the BET method. OMNISORP manufactured by Beckmann Coluter is used as the measuring instrument. The amount of oil absorption is 0.1 g of squalane per 100 g of powder, mixed by manual stirring, the oil absorption limit is judged by visual sensation, and the amount of squalane added up to that point is defined as the oil absorption amount.

Preferably, the powder is porous silica (Carplex # 67, manufactured by Shionogi & Co., Ltd., specific surface area 170 m ² Zg, oil absorption 250 ml Zl00 g), porous silica (Asahi Glass Co., Ltd., Sanfair L-51, specific surface area 300 m ² / g), aluminate metasilicate (Neusilin NFL2N, manufactured by Fuji Chemical Co., Ltd., specific surface area 250 m ² / g, oil absorption 198 ml Zl00 g).

[0040] Further, as the silicone rubber powder used in the present invention, a powder of a three-dimensional crosslinked polymer of silicone that does not limit the specific surface area and the amount of oil absorption may be used. Preferably, (dimethicone Z bur dimethicone Z methicone) crosspolymer (KSP 100 manufactured by Shin-Etsu Chemical Co., Ltd.), methylsiloxane 'dimethylsiloxane' methylhydrogensiloxane 'trimethylsiloxane copolymer (Toray Dow Co., Ltd. Silicone Co., Ltd.) Trefill E

506W).

[0041] The amount of the powder blended into the deodorant composition is not particularly limited. It is determined appropriately depending on the product form of the deodorant composition. Usually, it is 0.1-90 mass% with respect to the deodorant composition whole quantity, Preferably it is 1-20 mass%, More preferably, it is 3-: L0 mass%. The same is applied to the total amount of deodorant cosmetics. In the case of a deodorizing cosmetic power and a ticky cosmetic, 3 to 10% by mass is particularly preferable.

[0042] [Second Invention]

The surfactant used in the present invention is not particularly limited as long as it is a general surfactant used in cosmetics. For example, the following surfactants can be blended. Examples of the surfactants include fatty acid soaps (for example, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (for example, sodium lauryl sulfate, potassium lauryl sulfate); alkyl ether sulfates (Eg, PO E-lauryl sulfate triethanolamine, POE-sodium lauryl sulfate, etc.); N-acyl sarcosine acid (eg, sodium lauroyl sarcosine, etc.); higher fatty acid amide sulfonates (eg, N-myristoyl-N- Methyl taurine sodium, palm oil fatty acid methyl taurine sodium, lauryl methyl taurine sodium, etc .; phosphate ester salts (POE-oleyl ether sodium phosphate, POE-stearyl ether phosphate, etc.); sulfosuccinates (eg di -2-ethylhexylsulfo Sodium succinate, sodium monolauroyl monoethanolamide polyoxyethylene sodium sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, etc.); alkyl benzene sulfonates (for example, sodium linear dodecyl benzene sulfonate, triethanolamine linear dodecyl benzene sulfonate, Linear dodecyl benzene sulfonic acid, etc.); higher fatty acid ester sulfates (eg, hardened coconut oil fatty acid sodium glyceryl sulfate); N-acyl glutamate (eg, monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate) , N-myristoyl-L-glutamate monosodium, etc.); sulfuric acid coconut oil (eg funnel oil, etc.); POE-alkyl ether carboxylic acid; POE-alkylary Α-olefin sulfonate; higher fatty acid ester sulfonate; secondary alcohol sulfate ester; higher fatty acid alkylolamide sulfate ester; lauroyl monoethanolamide sodium succinate; Ν-palmitoylaspartic acid And ditriethanolamine; sodium caseinate and the like.

Cationic surfactants include, for example, alkyltrimethyl ammonium salts (eg, stearyl trimethyl ammonium salts, salt lauryl trimethyl ammonium salts, etc.); alkyl pyridinium salts (eg, salt salts).匕 cetylpyridium, etc.); salt 匕 distearyl dimethylammonium dialkyldimethylammonium salt; poly (Ν, Ν'-dimethyl-3,5-methylenepiveridium); alkyl quaternary ammonium -Um salt; alkyldimethylbenzyl ammonium salt; alkyl isoquinolium salt; dialkyl morpholine salt; POE-alkylamine; alkylamine salt; polyamine fatty acid derivative; amyl alcohol fatty acid derivative; Zarkoum; salted benzetonum.

Examples of amphoteric surfactants include imidazoline-based amphoteric surfactants (for example, 2-undecyl-Ν, Ν, Ν- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2 -Imidazol-hydroxyl-1-carboxyethyloxy disodium salt, etc .; Betaine surfactants (for example, 2-heptadecyl-Ν-carboxymethyl-Ν-hydroxyethyl imidazolidum-mubetaine, lauryldimethylaminoacetic acid) Betaine, alkyl betaine, amide betaine, sulfobetaine, etc.).

Examples of the lipophilic nonionic surfactant include sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquiate). Oleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate); glycerin polyglycerin fatty acids (eg mono-cotton oil fatty acid glycerin, mono-l) Glycerin acid glycerin, glyceryl sesquioleate, glyceryl monostearate, α, α-oleic acid pyroglutamate glycerin, monostearate glycerin malate, etc.); propylene glycol fatty acid esters Propylene glycol stearate, etc.); hardened castor oil derivatives; glyceryl alkyl ether, etc.

Examples of hydrophilic nonionic surfactants include ΡΟΕ-sorbitan fatty acid esters (eg, ΡΟΕ-sorbitan monooleate, ΡΟΕ-sorbitan monostearate, ΡΟΕ-sorbitan monooleate, ΡΟΕ-sorbitan tetraoleate). ΡΟΕ sorbite fatty acid esters (eg, ΡΟΕ-sorbite monolaurate, ΡΟΕ-sorbitol monooleate, ΡΟΕ-sorbitol pentaoleate, ΡΟΕ-sorbitol monostearate, etc.); ΡΟΕ-glycerin fatty acid Esters (eg, ΡΟΕ-glycerol monostearate, ΡΟΕ-glycerol monoisostearate, ΡΟΕ-glycerol monoisostearate, etc.); ΡΟΕ-fatty acid esters (eg, ΡΟΕ-distearate, ΡΟΕ- Monodiolate, ethyl stearateアルキル -alkyl ethers (e.g., ΡΟΕ-lauryl ether, ォ -oleyl ether, ΡΟΕ-stearyl ether, ΡΟΕ-behether ether, ΡΟΕ-2-octyldodecyl ether, ΡΟΕ-cholestanol ether) Etc); Pull mouth nick type (E.g. pull mouth nick); ； · POP-alkyl ethers (eg POE'POP-cetyl ether, POE'POP-2-decyltetradecyl ether, POE'POP-monobutyl ether, POE'POP-hydrogenated) Lanolin, POE'POP-glycerin ether, etc.); Tetra ΡΟΕ Tetra POP-ethylenediamine condensates (eg, Tetronic); POE-castor oil hardened castor oil derivatives (eg, POE-castor oil, POE-hardened castor) POE-hardened castor oil monoisostearate, POE-hardened castor oil triisostearate, POE-hardened castor oil monopyroglutamate monoisostearic acid diester, POE-hardened castor oil maleic acid, etc.); (Eg POE-sorbite beeswax); alkanolamide (eg coconut oil fatty acid diethanolamide, lauric acid monoethanolamide) POE-propylene glycol fatty acid ester; POE-alkylamine; POE-fatty acid amide; sucrose fatty acid ester; alkyl ethoxydimethylamine oxide; trioleyl phosphoric acid and the like.

[0043] The amount of surfactant added to the deodorant composition is not particularly limited. It is determined appropriately depending on the product form of the deodorant composition. Usually, it is 0.01-10 mass% with respect to the deodorant composition whole quantity, Preferably it is 0.1-3 mass%, More preferably, it is 0.3-2 mass%. The same is applied to the total amount of deodorant cosmetics. In the case of a deodorizing cosmetic power and a ticky cosmetic, 0.5 to 3% by mass is particularly preferable.

[0044] The porous silica used in the present invention is a silica having a specific surface area of 150 m ² / g or more, and is a highly oil-absorbing silica. More preferably, the specific surface area is 300 m ² Zg or more. The specific surface area was calculated by measuring the amount of nitrogen adsorbed on the powder at 77 K and analyzing it by the BET method. OMNISORP manufactured by Beckmann Coluter was used as a measuring instrument.

The average pore diameter is preferably 1 nm or more. Particularly preferred is an amorphous porous silica (Sunsphere L-51, manufactured by Asahi Glass Co., Ltd., specific surface area of 300 m ² / g, average pore diameter of 13 nm).

[0045] The amount of porous silica blended into the deodorant composition is not particularly limited. It is determined as appropriate according to the product form of the deodorant composition. Usually, it is 0.1 to 90% by mass, preferably 1 to 20% by mass, and more preferably 3 to 10% by mass with respect to the total amount of the deodorant composition. The same is applied to the total amount of deodorant cosmetics. Deodorant cosmetic power ^ 3-10 for ticky cosmetics Mass% is particularly preferred.

[0046] [First and second inventions]

In applications where a large amount of powder is blended, a finely divided zinc oxide powder that is preferred even if a zinc oxide powder is blended with the composition of the present invention is particularly preferred. The average particle size is preferably 0.5 m or less. The content of the zinc oxide powder is 0.1 to 10% by mass, preferably 0.5 to 5% by mass, and more preferably 2 to 4% by mass with respect to the total amount of the deodorant composition. The same is applied to the total amount of deodorant cosmetics. When the deodorant cosmetic is a sticky cosmetic, 2 to 4% by mass is particularly preferable.

[0047] The use of the deodorant composition of the present invention is not limited, but it is suitably used as a deodorant cosmetic. In addition to the essential constituents described above, other components usually used in cosmetics, for example, one or two or more of the components exemplified below are appropriately blended in the deodorant cosmetic as necessary, and the desired dosage form Can be produced in accordance with conventional methods.

[0048] Examples of powder components other than essential components include, for example, inorganic powders (for example, talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, saucite, biotite, permite, Magnesium carbonate, Calcium carbonate, Aluminum silicate, Barium silicate, Caustic acid Lucium, Magnesium silicate, Strontium silicate, Metal tungstate, Magnesium, Silica, Barium sulfate, Calcined calcium sulfate (calcined gypsum), Calcium phosphate, Fluorine apatite, hydroxyapatite, ceramic powder, metal sarcophagus (for example, zinc myristate, calcium normitate, aluminum stearate), boron nitride, etc .; organic powder (for example, polyamide resin powder (nylon powder), polyethylene Powder, polymethyl methacrylate powder, Nzoguanamine rosin powder, polytetrafluoroethylene powder, cellulose powder, etc.); inorganic white pigments (eg, titanium dioxide, zinc oxide, etc.); inorganic red pigments (eg, iron iron (Bengara), iron titanate, etc.) ); Inorganic brown pigments (eg, y-iron oxide, etc.); Inorganic yellow pigments (eg, yellow iron oxide, ocher, etc.); Inorganic black pigments (eg, black iron oxide, low-order titanium oxide, etc.) Inorganic purple pigments (eg, manganese violet, cobalt violet, etc.); inorganic green pigments (eg, acid chrome, chromium hydroxide, cobalt titanate, etc.); inorganic blue pigments (eg, ultramarine, bitumen, etc.) Pearl pigments (eg titanium oxide coated mica, acid-titanium-coated oxide salt, bismuth, acid-titanium-coated talc, Colored acid, titanium coated my strength, oxysalt, bismuth, fish scale foil, etc.); metal powder pigments (eg, aluminum powder, kappa powder, etc.); organic pigments, such as zirconium, norlium, or aluminum nickel lake (eg, Red 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401, and Organic pigments such as blue 404, red 3, red 104, red 106, red 227, red 230, red 401, red 505, orange 205, yellow 4, yellow 5, yellow 202, yellow 203, green 3 and blue 1); natural pigments (eg chlorofinole, β-strength rotin, etc.).

[0049] Examples of liquid fats include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, barley germ oil, and southern power oil , Castor oil, linseed oil, safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, teaseed oil, cypress oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin, etc. Is mentioned.

[0050] Examples of the solid fat include cacao butter, coconut oil, hardened coconut oil, palm oil, palm kernel oil, owl kernel oil, hardened oil, crowberry, and hardened castor oil.

[0051] Examples of the wax include beeswax, candelilla wax, cotton wax, carnauba wax, beberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, lauric acid Hexyl, reduced lanolin, jojoba wax, hard lanolin, shellac wax, ΡΟΕ lanolin alcohol ether, ΡΟΕ lanolin alcohol acetate, ΡΟΕ cholesterol ether, lanolin fatty acid polyethylene glycol, ΡΟΕ hydrogenated 卩 lanolin alcohol ether, ceresin, microcrystalline wax, etc. Is mentioned.

[0052] Examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalane, pristane, paraffin, squalene, petrolatum and the like.

[0053] Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (ΕΡΑ), Examples include docosahexaenoic acid (DHA).

[0054] Examples of higher alcohols include linear alcohols (for example, lauryl alcohol, Cetino-leanolecole, stearino-leanolecole, behenino-leanolecole, myristino-leanolol, oleyl alcohol, cetostearyl alcohol, etc .; branched chain alcohols (eg monostearyl glycerol ether (batyl alcohol) ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, otatildodecanol, etc.).

Examples of ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate , Myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, di-2-ethylethyl ethylene glycol, dipentaerythritol fatty acid ester, monoisostearate N-alkyl glycol , Neopentyl glycol dicaprate, diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexanoate, triisostearin Trimethylolpropane, tetra-2-ethylhexylhexanoate pentaerythritol, glycerol tri-2-ethylhexylate, glyceryl trioctanoate, glyceryl triisopalmitate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2 -Ethylhexyl palmitate, glyceryl trimyristate, tri-2-heptyl undecanoic acid glyceride, castor oil fatty acid methyl ester, oleate oleyl, acetate glyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-laur Royl-L-glutamic acid-2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate Kishirudeshiru to 2 adipate, diisopropyl sebacate, hexyl succinic acid 2 Echiru, and the like Kuen acid Toryechiru. POE (14) POP (7) dimethyl ether, POE (9) POP (2) dimethyl ether, POE (14) POP (7) dimethyl ether, POE (10) POP (10) dimethyl ether, POE (6) POP (14) Dimethyl ether, POE (15) POP (5) Dimethyl ether, POE (25) POP (25) Dimethyl ether, POE (9) POB (2) Dimethyl ether, POE (14) POB (7) Dimethyl ether, POE (10) P OP (10) Jetyl ether, POE (10) POP (10) Dipropyl ether, POE (10) POP (10) Examples include alkylene oxide derivatives such as dibutyl ether, diethoxyethyl succinate, diethoxyethyl malonate, tripropylene glycol dineopentanoate, propylene glycol dicaprylate, alkyl benzoates such as C8 to C12 alkyl benzoates and dodecyl benzoates. It is done.

[0056] Examples of the silicone oil include linear polysiloxanes (eg, dimethylpolysiloxane, methylphenol polysiloxane, diphenylpolysiloxane, etc.), cyclic polysiloxanes (eg, otatamethylcyclotetrasiloxane, decamethyl). Cyclopentasiloxane, dodecamethylcyclohexasiloxane, etc.), methyltrimethicone, silicone resin that forms a three-dimensional network structure, silicone rubber, various modified polysiloxanes (amino-modified polysiloxanes, polyether-modified) Polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, etc.).

[0057] Examples of the moisturizing agent include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12 -Hydroxy stearate, sodium lactate, bile salt, cQ-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, Isaiba rose extract, Sawflower saw extract, Merilot extract, etc. It is done.

[0058] Natural water-soluble polymers include, for example, plant polymers (for example, gum arabic, gum tragacanth, galactan, guar gum, kilobum gum, cara gum, carrageenan, pectin, agar, quincese (malt mouth), algae Colloid (cuttlefish extract), starch (rice, corn, potato, wheat), glycyrrhizic acid}; microbial polymers (eg, xanthan gum, dextran, succinoglucan, bull run, etc.); other (eg, fish-derived collagen, fish-derived) Gelatin, wheat protein, silk protein, etc.).

[0059] Semi-synthetic water-soluble polymers include, for example, starch polymers (for example, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose polymers (methyl senorelose, ethinorescenellose, methinorehydroxy) Propinoresenorelose, hydroxycellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxymethylenosesylose, sodium carboxymethylcellulose, crystalline cellulose, cellulose And alginic acid polymers (for example, sodium alginate, propylene glycol alginate, etc.) and the like.

[0060] Examples of the synthetic water-soluble polymer include vinyl polymers (for example, polybutyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer, etc.).

); Polyoxyethylene polymer (eg, polyethylene glycol 20,000, 40,000, 60,000 polyoxyethylene polyoxypropylene copolymer, etc.); Acrylic polymer (eg, sodium polyacrylate, polyethylene acrylate) Rate, polyacrylamide and the like); polyethyleneimine; cationic polymer and the like.

[0061] Examples of thickeners include gum arabic, carrageenan, caraja gum, gum tragacanth, carob gum, quince seed (manolemero), casein, dextrin, gelatin, sodium pectate, sodium aradate, methylcellulose, ethylcellulose, CMC, Hydrochichechinole cellulose, hydroxypropinole cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxybule polymer, locust bean gum, guar gum, tamarint gum, dialkyldimethylammonium sulfate cellulose, xanthan gum, aluminum carbonate Examples thereof include magnesium, bentonite, hectorite, silicate AlMg (beegum), laponite, and anhydrous carboxylic acid.

[0062] Examples of the ultraviolet absorber include the following compounds.

(1) Benzoic acid UV absorber

For example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, Ν, Ν-jetoxy PABA ethyl ester, Ν, Ν-dimethyl PABA ethyl ester, Ν, Ν-dimethyl PABA butyl ester , Ν, Ν-dimethyl P ABA ethyl ester and the like.

(2) Anthralic acid UV absorber

For example, homomenthyl-N-acetylethyl anthrate.

(3) Salicylic acid UV absorber

For example, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octenoresalicylate, phenol-noresalicylate, pendinoresalicylate, p-isopropanol phenyl salicylate and the like. (4) Key skin acid UV absorber

For example, octylcinnamate, ethyl-4-isopropylcinnamate, methyl-2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylpropylcinnamate, propyl-p -Methoxycinnamate, isopropyl-p-methoxycinnamate, isamyl-P-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl -p- Methoxycinnamate, Cyclic Hexyl-p-Methoxycinnamate, Ethyl A-Cyanano 13-Fercinnamate, 2-Ethylhexyloo A-Cyano 13-Fercinnamate, Glyceryl Mono-2- Ethylhexanoyl-Diparamethoxycinnamate Such.

(5) Triazine UV absorber

For example, bisresorcyltriazine.

More specifically, bis {[4- (2-ethylhexyloxy) -2-hydroxy] phenol} — 6- (4-methoxyphenol) 1, 3, 5 triazine, 2, 4, 6 tris { 4- (2-ethylhexyloxycarbol) -arino} 1, 3, 5 Triazine.

2,4 Bis {{4- (2-Ethylhexyloxy) 2-2 Hydroxy} 1-phenyl} -6 6- (4-Methoxyphenyl) 1, 3, 5 Triazine.

(6) Other UV absorbers

For example, 3- (4 and methylbenzylidene) -cU-camphor, 3-benzylidene-cU-camphor, 2-phenyl-5-methylbenzoxazole, 2,2'-hydroxy-5-methylphenylbenzotriazole, 2- (2'-hydroxy-5 and t-octylphenol) benzotriazole, 2- (2'-hydroxy-5'-methylphenylbenzotriazole, dibenzalazine, dianisolmethane, 4- Methoxy-4'-t-butyldibenzoylmethane, 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one, etc. Pyridazine derivatives such as dimorpholinopyridazinone. Examples of sequestering agents include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyquichetan-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate. Edetate tetrasodium salt Examples include sodium citrate, sodium polyphosphate, sodium metaphosphate, darconic acid, phosphoric acid, citrate, ascorbic acid, succinic acid, and edetic acid. [0064] Examples of the lower alcohol include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

[0065] Examples of the polyhydric alcohol include divalent alcohols (for example, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3- Butylene glycol, pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trivalent alcohol (eg, glycerin, trimethylolpropane, etc.); tetravalent alcohol (eg, Pentaerythritol such as 1,2,6-hexanetriol, etc .; pentahydric alcohol (eg, xylitol, etc.); hexavalent alcohol (eg, sorbitol, mannitol, etc.); polyhydric alcohol polymer (eg, Diethylene glycol, dipropylene glycol, triethylene glycol, poly Pyrene glycol, tetraethylenedaricol, diglycerin, polyethylene glycol, triglycerin, tetraglycerin, polyglycerin, etc.); dihydric alcohol alkyl ethers (for example, ethylene glycol monomethyl ether, ethylene glycol monoethylenoylate) Tenole, Ethylene glycol monomono butylenoate, Ethylene glycol mononomonophenol-norenoateol, Ethylene glycol monomonohexenoleatenore, Ethylene glycol norenomono 2-Methylenohexenoleatenore, Ethylene glyconorenoaminoatenore Tylene glycol nole venenore etherenole, ethylene glycol isopropylenoate ethere, ethylene glycol dimethyl ether, ethylene glycol jetyl ether, ethylene Diglycol dibutyl ether, etc.); dihydric alcohol alkyl ethers (for example, ethylene glycol monomethino ethenore, diethylene glycol monomethino ethenore, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol dimethyl ether) Ether, diethyleneglycolenobutenoreethenore, diethyleneglycololemethinoleetinoreateore, triethyleneglycololemonomonotinoatenore, triethyleneglycolenolemonotinoreatenore, propyleneglycolenoremonomethinoreatenore, Propylene glycol monoethanolino ether, propylene glycol monobutino ether, propylene glycol isopropyl ether, dipropylene Call methyl ether, dipropylene glycol E chill ether, dipropylene glycol Norev Chino les ether Honoré etc.); dihydric alcohol ether esters (e.g., ethylene glycol monomethyl ether § Se Tate, Ethylene glycol monoethyl ether acetate, Ethylene glycol monobutinoate etherate acetate, Ethylene glycol monophenol enenoate acetate, Ethylene glycol diazinate, Ethylene glycol disuccinate, Diethylene glycol nore Monoethylenoate acetate, diethylene glycol monobutyl ether acetate, propylene glycolenomonomethinoatenoacetate, propylene glycolenomonoenoatenoreacetate, propylene glycolenomonopropenoatenoate acetate, propylene glycol Monophenyl ether acetate, etc.); glycerin monoalkyl ether (eg, chimyl alcohol, seraalkyl alcohol, batyl alcohol, etc.) Ta alcohol (e.g., sorbitol, maltitol, maltotriose, Man - Tall, sucrose

H, erythrose mononole, gnoleose, funolectose, starch |, manolose, xylogase, amylolytic sugar-reduced alcohol, etc.]; glycolide; tetrahydrate-furfuryl alcohol; POE -Tetrahydride furfuryl alcohol; POP-butyl ether; ΡΟΡ · POE-butyl ether; Tripolyoxypropylene glycerol ether; POP-glycerol ether; POP-glycerol ether phosphate; POP · POE-pentaneerythritol ether, polyglycerol, etc. Can be mentioned.

[0066] Examples of monosaccharides include, for example, tricarbon sugars (eg, D-glyceryl aldehyde, dihydroxyacetone); tetracarbon sugars (eg, D-erythrose, D-erythrulose, D-threose, erythritol, etc.) Pentose (eg, L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc.); hexose (eg, D- Glucose, D-talose, D-bucose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc .; hepta sugar (eg, aldoheptose, heptose, etc.); Sugars (eg, octrose); deoxy sugars (eg, 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose, etc.); amino sugars (eg, D-darcosamine) D-galactosamine, sialic acid, aminouronic acid, muramic acid, etc.); uronic acid (eg, D-glucuronic acid, D-mannuronic acid, L-guluronic acid, D-galataturonic acid, L-iduronic acid, etc.) Can be mentioned.

[0067] Examples of the oligosaccharide include sucrose, umbelliferose, ratatose, planteose, isoliquinoses, (X, a-trehalose, raffinose, lycnose, umbilicin, stadium, Examples include the Chios Bell Bus Course.

[0068] Examples of the polysaccharide include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guagam, Examples include dextran, keratosulfuric acid, locust bingham, succinoglucan, and caronic acid.

[0069] Examples of amino acids include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.) and the like. Examples of amino acid derivatives include sodium acylsarcosine (lauroyl sarcosine sodium), acyl acyl glutamate, sodium acyl-β-alanine, dartathione, pyrrolidone carboxylic acid and the like.

[0070] Examples of organic amines include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl 1,3-propanediol, 2-amino-2-methyl. Examples include 1-propanol.

[0071] Examples of the polymer emulsion include acrylic resin emulsion, polyacrylic acid ethyl emulsion, acrylic resin solution, polyacrylic alkyl ester emulsion, poly (acetic acid butyl resin emulsion), and natural rubber latex.

[0072] Examples of the ρΗ preparation agent include buffers such as lactic acid-sodium lactate, succinic acid-sodium succinate, and sodium succinate monosuccinate.

[0073] Examples of vitamins include vitamins A, Bl, B2, B6, C, sputum and derivatives thereof, pantothenic acid and derivatives thereof, and piotin.

[0074] Examples of the anti-oxidation agent include tocopherols, dibutylhydroxytoluene, butyhydroxyl-sol, gallic acid esters and the like.

[0075] Antioxidant aids include, for example, phosphoric acid, citrate, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, ethylendiaminetetrakis ( 2-hydroxyisopropyl) dioleate, ethylenediaminetetrapolyoxypropylene, ethylenediaminehydroxyethyl sodium triacetate (dihydrate), sodium sodium ethylenediaminetetraacetate, edetic acid, trisodium edetate, Examples include dipotassium detoate dihydrate, disodium edetate, tetrasodium edetate, tetrasodium edetate dihydrate, and tetrasodium edetate tetrahydrate.

Other ingredients that can be incorporated include, for example, preservatives (methylparaben, ethylparaben, butylparaben, phenoxyethanol, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, alalane) Whitening agents (eg, Yukinoshita extract, arbutin, tranexamic acid, L-corbic acid, L-corsic acid phosphate magnesium salt, L-corsic acid glucoside, 4-methoxysalicylic acid potassium, etc.); various extracts ( For example, green tea, oolong tea, black tea, puar tea, cucumber, clara, obata, ollen, sicon, peonies, assembly, perch, sage, bean paste, carrot, aloe, zhaoi, iris, grape, yokwon, hechima , Lily, saffron Senkiyu, Shoyuyu, Hypericum, Ononis, Garlic, Pepper, Chimpi, Toki, Seaweed, etc.), Activator (eg, Royal Jelly, Photosensitizer, Cholesterol Derivative, etc.); Blood circulation promoter (eg, nicotinic acid benzyl ester, nicotine) Acid Butoxetyl ester, Capsaicin, Zingerone, Cantalis tincture, Tiktamol, Tannic acid, _α Borneol, Tocopherol nicotinate, Inositol hexa-cotinate, Cyclanderate, Cinnarizine, Trazoline, Acetylcholine, Verapamil, Cephalanthin, γ-Oryzanol Anti seborrheic agents (eg, sulfur, thianthol, etc.); anti-inflammatory agents (eg, thiotaurine, hypotaurine, etc.); bactericides (eg, benzoic acid and its salts, isopropylmethylphenol, union) Decylenic acid and its salts, undecylenic acid monoethanolamide, cetyltrimethylammonium chloride, cetylpyridium chloride, benzalkonium chloride, benzathonium chloride, alkyldiaminoethyldaricin chloride, chlorhexidine chloride, orthophenylphenol , Chlorhexidine dalconate, Tale zonore, Chloramine Τ, Chronoxy lenenore, Chronocrezo mononole, Chronofenesin, Chronobutanol, 5 Chloro-2-methyl-4-isothiazoline-3one, salicylic acid and its salts, 1, 3 Dimethylol-5,5 Dimethylhydantoin, alkylisoquinolinium bromide, domifene bromide, sorbic acid and its salts, thymol, thiram, dehydroacetic acid and its salts, triclosan, trichlorocarbalide, paraoxybenzoic acid Esters, para chrono reflex Hainaut Honoré, Nono Rokanoreno down - Pirogaronore, Kisakuro port Fen Fuenonore to, 2- Methyl-4-isothiazoline-3-one, NN "-methylenebis (Ν'- (3-hydroxymethyl 2.5-dioxo-4-imidazolidi-lurea, lauroyl sarcosine sodium, resorcin, hinokitiol, etc.).

[0077] The product form of the deodorant cosmetic composition of the present invention is not particularly limited. For example, a spray type, a mouth-on type, a powder type, a pressed powder (molded powder) type, a stick type and the like can be mentioned. In the case of the spray type, it is manufactured by filling a spray container such as an aerosol can or a dispenser together with a propellant such as liquid gas or alcohol with a conventional method. In the case of a roll-on type, it is manufactured by filling a roll-on container together with alcohol by a conventional method. In the case of the Noda type and the pressed powder type, they are mixed together with the powder components and oil, and in the case of the powder type, they are produced as they are. In the case of the stick type, it is produced by mixing with oil (solid oil, liquid oil), filling the container in a conventional manner, and molding. A preferable product for the present invention is a stick-shaped diamond product containing a wax or a gelling agent.

Example

Next, the present invention will be described more specifically with reference to examples. The present invention is not limited thereby. A compounding quantity is the mass% with respect to the whole quantity unless there is particular notice.

[0079] [First invention]

A solid antiperspirant stick preparation containing various powders was prepared according to the following formulation. Apply a certain amount (0.06g / cm ² ) of white clothing, artificial sweat (water tol00wt%, sodium chloride 0.8wt%, acetic acid 0.5wt%, disodium phosphate 12hydrate 0.8wt%) After 0.012 g / cm ² was added dropwise, the degree of staining after exposure to sunlight (10 minutes) was evaluated visually. Next, the discolored clothing was washed with a washing machine using a normal laundry detergent, and the degree of staining after washing was visually evaluated. Judgment was made according to the following criteria.

Compared with the above-mentioned staining (discoloration) after exposure to sunlight, it was recognized that the staining (discoloration) was found to have dropped well. The case was determined to be Δ Χ, and the case where it was confirmed that it did not fall at all was judged as X. The evaluation results were written as “

In addition, photographs of these evaluation results are shown in “Figure 1”.

[0080] [Table 1-1]

* 1: Powders listed in Table 1 2

* 2: Silver 'ammonium supported zeolite (Zemic AJ1 ON, Sinanen Zemic Co., Ltd., average particle size approx.1.5 / z m)

* 3: Fine zinc oxide (fine zinc oxide manufactured by Sakai Chemical Industry Co., Ltd.)

* 4: Fine-grain-baked Miyoban (Taime K20 manufactured by Daimei Chemical Industry Co., Ltd.)

* 5: Decamethylcyclopentasiloxane (KF995 manufactured by Shin-Etsu Chemical Co., Ltd.)

* 6: Methylphenol polysiloxane (Shin-Etsu Chemical Co., Ltd., Silicon KF56)

* 7: Polyethylene wax (Performalene PL PO and YETHY and ENE made by New Phase Technologies)

* 8: Hydrogenated jojoba oil (FLORATECH, Flora Ester 70HG)

[0081] [Table 1-2]

Comparative Example Comparative Example Comparative Example Comparative Example Comparative Example Example

1-1 1 1 2 1 1 3 1 1 4 1-5 1-1

Dimethyl

Cell mouth one dichlor

Starch Si 0 ₂ Si0 ₂ Si0 ₂ Composition * 9 S »1 1 Silane treatment * 1 3 * 1 4

* 1 0 Si 0 ₂

* 1 2

Specific surface area m ² / g ― ― 150 110 5. 2 170 Oil absorption ml / IOOg 54 74 63 325 30 250

Evaluation after washing Δ 厶 Δ Δ χ 〇〇

* 9: Starch C (Maize Starch ST-C, manufactured by Nissui Engineering Co., Ltd.)

* 10: Cell mouth flow C-25 (Chisso Corporation)

* 11: Spherical silica P1500 (manufactured by Catalytic Chemical Industry Co., Ltd.)

* 12: Aerosil R972 (manufactured by Nippon Aerosil Co., Ltd.)

* 13: DF silica micro beads (DF silica micro beads FB-10D manufactured by Denki Kagaku Kogyo Co., Ltd.)

* 14: Carplex # 67 (manufactured by Shionogi & Co., Ltd.)

* 15: Gantz Pearl GMX0810 (manufactured by Gantz Kasei Kogyo Co., Ltd.)

* 16: Tospearl 2000B (GE Toshiba Silicone)

* 17: Silicone powder KSP100 (KSP-100 manufactured by Shin-Etsu Chemical Co., Ltd.)

* 18: Talc 15 (Fuji Talc Industrial Co., Ltd. Talc # 15)

* 19: My strength # 5500 (My strength powder # 5500 manufactured by Wakita Banking Co., Ltd.)

* 20: My strength PDM-9L-20 (Tobe Industries, Ltd. My strength PDM-9L-20) * 21: Neusilin NFL2N (Fuji Chemical Industry Co., Ltd.)

[0082] From the above results, Examples 11 to 13 in which specific powders were blended showed the effect of washing and removing dirt due to washing, but the comparative example did not show the washing and removing effect.

[0083] The antiperspirant cosmetics that also have the deodorant composition power of the present invention are listed below. All cosmetics have excellent cleaning and removal effects of stains when attached to clothing, and also have a good feeling of use.

[0084] Example 1 4 Deodorant Spray

Self-synthesis]

(Powder part)

Aluminum hydroxy chloride

Silver ion, ammonia ion supported zeolite 0.

Hydrophobized silver ion supported zeolite 0.

High oil-absorbing silica (specific surface area 300m ² Zg, oil absorption 143ml) 5

(Oil)

Dimethicone 3

Synthetic isoparaffin 2.4

Fragrance 0. 1

(Propellant)

Isopentane 10

Liquefied petroleum gas 80

[Production method]

The powder part is mixed with a kneader, the oil is mixed with a blender, each is sequentially filled into a spray can, and the propellant is filled into a can to obtain a powder spray.

[0085] Example 1-5 Deodorant powder

Self-synthesized] Mass%

Aluminum hydroxychloride 13

Silver ion, dumbbell ion, ammonia ion supported zeolite 5

Metasilicate aluminate Mg (Specific surface area 250m ² / g, oil absorption 198 ml) 10

Synthetic isoparaffin 6

Fragrance 1

Talc residue

[Production method]

The above ingredients are sequentially mixed with a Henschel mixer to obtain a deodorant powder.

[0086] Example 1-6 Deodorant Stick

Self-synthesized] Mass%

Hydrocarbon wax 5

Silicone wax 5

Synthetic isoparaffin 20

Skullan residue

(Dimethicone Z Bul dimethicone Z methicone) Crosspolymer powder 15 Aluminum hydroxy chloride 15

Zinc oxide 5

Silver ion, zinc ion supported zeolite 5

[Production method]

A mixture of the above components is filled in a container to obtain a deodorant stick.

Example 1-7 Deodorant Stick

Self-synthesized] Mass%

Hydrocarbon wax 3

Polyethylene wax 5

Dextrin palmitate 5

Synthetic isoparaffin 20

Dimethicone remaining

Metasilicate aluminate Mg

(Specific surface area ²⁵ Om ² / g, Oil absorption 198ml) 10

Aluminum hydroxychloride 10 Zinc oxide 5

Silver ion and zinc ion supported zeolite 0.5

[Production method]

[0088] Example 1-8 Deodorant Stick

Self-synthesized] Mass%

Silicone wax 3

Polyethylene wax 5

Dextrin palmitate 5

Synthetic isoparaffin 20

Cyclic silicone residue

Metasilicate aluminate Mg (specific surface area 250, oil absorption 198) 5

Oil-absorbing silica (specific surface area 300m ² Zg, oil absorption l ⁴ 3ml) 5

Aluminum hydroxychloride 20

Zinc oxide 3

Silver ion, zinc ion supported zeolite 10

[Production method]

[0089] [Second Invention]

A solid antiperspirant stick preparation containing various powders having the following formulation was prepared, filled in a container and exposed to direct light (sunlight and room light), and left in the room for a week. Compared to the control discoloration in which no powder and surfactant are blended, ◯ indicates no discoloration, ○ △ indicates almost no discoloration, Δ indicates discoloration, and discoloration is large and clear. When the discoloration was divided, it was judged as X, and the result was recorded as a discoloration prevention effect. The photographs of these results are shown in “Figure 2”.

[0090] [Table 2-1] contro l surfactant powder only surfactant material name only + powder various powder "- - 13.8 13.8 Surfactant * ² - 2 - 2

Antibacterial zeolite * ³ 10 10 10 10 Zinc oxide 3 3 3 3

Alum * ⁵ 5 5 5 5

Cyclic silicone * ⁶ 52 50 38. 2 36. 2

Phenyl trimethicone * ⁷ 20 20 20 20

Polyethylene wax * ⁸ 5 5 5 5

Hydrogenated jojoba oil 5 5 5 5

Mouth a \ 100 100 100 100

* 1: Powder listed in “Table 2-2”

* 2: PEG400 glyceryl diisostearate (Nippon Emulsion Co., Ltd. Emaletus tasting 400di—IS (EX))

* 3: Silver-ammonium-supported zeolite (Zemic AJ10 0N, average particle size of about 1.5 / z m, manufactured by Sinanen Zemic Co., Ltd.)

* 4: Fine zinc oxide (fine zinc oxide manufactured by Sakai Chemical Industry Co., Ltd.)

* 5: Fine-grain-baked Miyoban (Taime K20, manufactured by Daimei Chemical Co., Ltd.)

* 6: Decamethylcyclopentasiloxane (KF995 manufactured by Shin-Etsu Chemical Co., Ltd.)

* 7: Methylphenol polysiloxane (Shin-Etsu Chemical Co., Ltd. Silicon KF56)

* 8: Polyethylene wax (Performalene PL PO and YETHY and ENE made by New Phase Technologies)

* 9: Hydrogenated coffee jojoba oil (FLORATECH, Flora ester 70HG)

[Table 2]

* 10: Polymethyl methacrylate cross-linked type (Ganz Pearl GM X-0810, manufactured by Ganz Kasei Kogyo Co., Ltd.)

* 11: Silica (Sansuair L 51 manufactured by Asahi Glass Co., Ltd.) * 12: Silica (Spherical Silica P—1500 manufactured by Catalytic Chemical Industry Co., Ltd.)

* 13: Silica (Chemiselen manufactured by Sumitomo Chemical Co., Ltd.)

[0092] <Discoloration prevention effect>

[Table 2-3]

[0093] The above results indicate that the coexistence of antibacterial zeolite and surfactant causes a large discoloration (vertical 2nd column in Fig. 2). And in the examples of the present invention in which specific powders were blended! Although discoloration was greatly suppressed (horizontal 2 and 3 rows in FIG. 2), in comparative examples (powders that were not porous) The main reason is that discoloration cannot be suppressed (horizontal 1 and 4 in Fig. 2). In particular, Example 1 in which porous silica having a specific surface area of 300 m ² / g in Example 1 was blended showed an extremely remarkable discoloration preventing effect as compared with Example 2 and Comparative Example 1.

[0094] The following are antiperspirant cosmetics that also have the deodorant composition power of the present invention. V and slippery cosmetics are also excellent in anti-discoloration effect and usability.

[0095] Example 2-3 Deodorant Spray

Self-synthesized] Mass%

(Powder part)

Aluminum hydroxychloride 2

Silver ion, amorphous ion supported zeolite 0.5

Hydrophobized silver ion supported zeolite 0.5

Highly oil-absorbing silica (specific surface area 160 m) g 1.5

(Oil)

Dimethicone 3

Synthetic isoparaffin 2.4

Fragrance 0. 1

Sorbitan sesquiisostearate (surfactant) 2 (Propellant)

Isopentane 10

Liquefied petroleum gas 80

[Production method]

The powder part is mixed with a kneader, the oil is mixed with a blender, each is sequentially filled into a spray, and a propellant is filled into a can to obtain a powder spray.

[0096] Example 2-4 Deodorant Powder

Self-synthesized] Mass%

Aluminum hydroxychloride 13

Silver ion, dumbbell ion, ammonium ion supported zeolite 5 High oil-absorbing silica (specific surface area 200m ² Zg) 10

Polyoxyethylene polyoxypropylene decyl tetradecyl ether 1 (surfactant)

Synthetic isoparaffin 6

Fragrance 1

Talc residue

[Production method]

[0097] Example 2-5 Deodorant Stick

Self-synthesized] Mass%

Hydrocarbon wax 5

Polyethylene wax 5

Synthetic isoparaffin 20

Dimethicone remaining

Highly oil-absorbing silica (specific surface area 300m ² / g) 12.5

Diisostearic acid PEG400 glyceryl 2

(Surfactant)

Aluminum hydroxychloride 15 Zinc oxide 5 Silver ion, zinc ion supported zeolite 0.5

[Production method]

[0098] Example 2-6 Deodorant Stick

Self-synthesis] Mass% Hydrocarbon wax 5

Silicone wax 5

Synthetic isoparaffin 20

Skullan residue

Highly oil-absorbing silica (specific surface area 161 mso g) 9 Polyglyceryl diisostearate 2

(Surfactant)

Aluminum hydroxychloride 20

Zinc oxide 5

Silver ion, zinc ion supported zeolite 10

[Production method]

[0099] Example 2-7 Deodorant Stick

Self-synthesized] Mass% Dextrin palmitate 8 Silicone wax 5

Methylphenol silicone 20 Cyclic silicone Residue Highly oil-absorbing silica (specific surface area 254 m ² / g) 12.5 Silicone rubber powder 5

Polyisoethylene stearate polyoxyethylene glyceryl 2 (surfactant) Miyouban 5

Zinc oxide 5

Silver ion, zinc ion supported zeolite 5

[Production method]

[0100] Example 2-8 Deodorant Stick

Self-synthesized] Mass%

Hydroxy stearic acid 5

Silicone wax 5

Synthetic isoparaffin 20

Cyclic silicone residue

Highly oil-absorbing silica (specific surface area 325 m ² / g) 12.5

Polymethyl methacrylate powder 5

Dimethylpolysiloxane PEG20 2

(Surfactant)

Aluminum hydroxychloride 10

Zinc oxide 3

Silver ion and zinc ion supported zeolite 15

[Production method]

Industrial applicability

[0101] [First invention]

The deodorant composition of the present invention can effectively remove stains on clothes by washing and has an excellent deodorizing effect. Therefore, it can be suitably used particularly as a deodorant cosmetic.

[0102] [Second invention]

The deodorant composition of the present invention has an excellent deodorizing effect with less discoloration due to light and less staining on clothes. Therefore, it can be suitably used particularly as a deodorant cosmetic.

Claims

The scope of the claims

[I] A deodorizing composition comprising antibacterial zeolite and a powder having a specific surface area of 150 m ² Zg or more and an oil absorption of lOOmlZlOOg or more.

[2] A deodorizing composition comprising antibacterial zeolite and silicone rubber powder.

[3] The deodorant composition according to claim 1 or 2, further comprising acid zinc oxide.

[4] The antibacterial metal ion in the antibacterial zeolite may be one or more selected from silver, copper, and zinc ions. Deodorant composition.

[5] The average particle diameter of the antibacterial zeolite is 10 μm or less, and the particle size distribution of which the particle diameter exceeds 15 / zm is 20% or less. 4. The deodorant composition as described in any one of 4 above.

[6] An anti-bromide cosmetic comprising the deodorant composition according to any one of claims 1 to 5.

[7] A deodorizing composition comprising antibacterial zeolite, a surfactant, and porous silica having a specific surface area of 150 m ² / g or more.

8. The deodorant composition according to claim 7, further comprising zinc oxide.

[9] The composition for deodorization according to claim 7 or 8, wherein the antibacterial metal ion in the antibacterial zeolite is one or more selected from silver, copper and zinc ions. object.

[10] The force according to any one of claims 7 to 9, wherein the antibacterial zeolite has an average particle size of 10 m or less and a particle size distribution in which the particle size exceeds 15 μm is 20% or less. The deodorizing composition according to item 1.

[II] A deodorant cosmetic, characterized in that it also has a deodorizing composition power according to any one of claims 7 to 10.