JP2006249049A - Skin care composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a skin care composition like a cosmetic, which considerably rarely stimulates a skin, has sufficient preservative efficacy, shows no temporal decrease of preservative efficacy, is not affected by pH or salt in a preparation line, has no problem in stability such as separation, aggregating or the like, and has substantially high usability, stability and safety. <P>SOLUTION: The skin care composition characteristically comprises 2-phenoxyethanol and 2-ethyl-1, 3-hexanediol. Particularly, parabens are not added, and the composition comprises alcohols of 5.0 wt% or less, wherein 2-phenoxyethanol is 0.01-1.0 wt% and 2-ethyl-1, 3-hexanediol is 0.1-5.0 wt%. <P>COPYRIGHT: (C)2006,JPO&NCIPI

Description

The present invention relates to an external composition for skin such as cosmetics. In particular, the present invention relates to a composition for external use on skin, such as various cosmetics, which has sufficient antiseptic properties and maintains excellent antiseptic properties, but has low skin irritation and significantly improved usability, safety and stability.

In recent years, there has been a demand for a safe external composition for skin. On the other hand, the composition for external use of the skin must emphasize the preservability, and it is necessary to consider antiseptic and antifungal properties. Many compositions for external use of the skin contain paraoxybenzoic acid esters, commonly called parabens, as preservatives. The fact is that the antiseptic power is secured.

However, when parabens are blended as preservatives, rarely some sensitive users may experience skin irritation such as spotting during use, and the usability is also unsatisfactory. Naturally, it is also possible to prepare a composition for external use without blending parabens. In that case, however, in order to ensure antiseptic properties, a sub-container for each use can be used, or a tube container can be backed. Other complicated means such as providing a less mechanism were required, and the versatility was lacking.

Therefore, attempts have been made in recent years to increase the amount of ethanol blended and ensure antiseptic power. However, when the blending amount of ethanol is increased, there is a problem that the usability is remarkably lowered, and further, some people with ethanol hypersensitivity cause irritation.

Therefore, attempts have been made to use preservatives other than parabens, but in the first place, many of the preservatives other than parabens are salicylic acids, dehydroacetic acids, benzoic acids, resorcinol and the like. Thus, there is a problem of stability that it is a solid and precipitates at a low temperature depending on its solubility. In addition, these preservatives have a polar group such as a cationic group, a carboxyl group, and a phenolic hydroxyl group, and there are problems that the preservative power is reduced by the pH and salt of the preparation system, and the preparation of the preparation cannot be performed. Therefore, by adding a liquid preservative that does not have a polar group such as 2-phenoxyethanol, an anti-skin power composition that is not affected by the pH and salt of the preparation system and that is easy to construct a preparation. It has come to use.

However, although 2-phenoxyethanol is weak to some people, it may cause irritation, and there may be a problem in securing antiseptic properties at a concentration at which blending is possible. In addition, due to the familiarity between 2-phenoxyethanol and powders, oils, etc., there has been a formulation in which blending is restricted due to stability because aggregation and separation occur in the blended preparation. Furthermore, since 2-phenoxyethanol is easily volatilized, there is a problem that the preservative power of the preparation cannot be maintained over time. For this reason, we tried complex means such as using highly confidential containers that do not volatilize, but even if temporarily ensuring antiseptic properties, they will volatilize by opening the container during use, so the antiseptic power over time There was a problem that decreased.

2-ethyl-1,3-hexanediol is commonly used as a pest repellent (Patent Documents 1, 2, and 3).
US2407205 WO89 / 03639 JP-A-5-294828

Therefore, it is excellent in safety, has no stability problems such as separation and agglomeration, has excellent formulation stability, is not affected by the pH and salt of the formulation system, and has antiseptic effects over time while having a sufficient antiseptic effect. There has been a demand for a composition for external use on the skin in which the strength does not decrease.

  As a result of intensive studies by the present inventors in order to achieve the above object, by blending 2-phenoxyethanol and 2-ethyl-1,3-hexanediol, it has a sufficient antiseptic effect and is excellent. The inventors have found that a composition for external use of skin having a low skin irritation and a significantly improved usability, safety and stability can be obtained while maintaining antiseptic power, and the present invention has been completed.

That is, the present invention has extremely low skin irritation containing 2-phenoxyethanol and 2-ethyl-1,3-hexanediol, is not affected by the pH and salt of the preparation system, and has a sufficient antiseptic effect. The present invention relates to a composition for external use on the skin, in which preservative power does not decrease with time, and there is no problem such as separation / aggregation in a formulated preparation, and the usability, stability and safety are remarkably high.

The present invention also relates to a composition for external use on the skin, wherein the cosmetic is any one of a basic cosmetic, a makeup cosmetic, and a body cosmetic.
Further, the present invention is characterized in that no parabens are blended in these external compositions for skin.
In addition, the present invention is characterized in that the proportion of alcohol in the composition for external use in skin is 5.0% by mass or less.
Further, the present invention is characterized in that the ratio of 2-phenoxyethanol in the composition for external use in skin is 0.01 to 1.0% by mass.
In addition, the present invention is characterized in that the ratio of 2-ethyl-1,3-hexanediol in the composition for external use in skin is 0.1 to 5.0% by mass.

In the composition for external use of the present invention, by adding 2-phenoxyethanol and 2-ethyl-1,3-hexanediol, the antiseptic power does not decrease over time while ensuring sufficient antiseptic properties, It is possible to provide a composition for external use that is extremely low in irritation to the skin, is not affected by pH and salt, has no stability problems such as separation / aggregation, and has improved usability, safety and stability. .

Hereinafter, embodiments of the present invention will be described in more detail.
2-ethyl-1,3-hexanediol used in the present invention is a known substance, and 2-phenoxyethanol is known as a preservative, but by blending these, skin irritation is extremely low, safety is high, It is novel that a composition for external use of skin having high preparation stability, not affected by the pH and salt of the preparation, sufficiently ensuring antiseptic properties and capable of preventing the antiseptic power from decreasing with time can be provided.

2-phenoxyethanol used in the present invention can be produced by a general synthesis method, and 2-phenoxyethanol is commercially available from Tokyo Chemical Industry Co., Ltd. and can be easily obtained.

2-ethyl-1,3-hexanediol used in the present invention can be produced by a general synthesis method, and 2-ethyl-1,3-hexanediol is commercially available from Tokyo Chemical Industry Co., Ltd. And can be easily obtained.

The 2-ethyl-1,3-hexanediol used in the present invention has stereoisomerism due to its structure, but in the present invention, it may be a single compound or a mixture thereof, and the mixing ratio thereof is also It doesn't matter. Further, although optical isomerism occurs, it may be optically active, racemic, or a mixture thereof, or may be a single or a mixture of their stereoisomerism, and their mixing ratio is not limited.

2-Ethyl-1,3-hexanediol according to the present invention is a transparent liquid substance having a high boiling point, and does not precipitate crystals at a low temperature after blending. The familiarity is good, and at the same time, the familiarity between the components is improved, and the stability of the prescription system is improved. Further, even when combined with 2-phenoxyethanol, there is no problem of separation and aggregation of the preparation, sufficient antiseptic power is ensured, and the antiseptic power does not decrease with time, and the antiseptic power is sustained.

  The amount of 2-phenoxyethanol according to the present invention needs to be 0.001% by mass or more in view of antiseptic properties, but a desired amount can be appropriately added depending on the properties of the composition for external use on the skin. The upper limit of blending is not limited as long as a composition for external use on skin can be formed, but it is desirable that the amount is as small as possible in consideration of some users who are sensitive to 2-phenoxyethanol. Is preferable.

  The amount of 2-ethyl-1,3-hexanediol according to the present invention needs to be 0.01% by mass or more, preferably 0.1% by mass or more, in relation to the contribution of the present invention. The upper limit of blending is not limited as long as a composition for external use on the skin can be formed, but blending of 5.0% by mass or less is preferable because deterioration in usability such as stickiness is manifested when it is excessively blended.

  The blending ratio of 2-phenoxyethanol and 2-ethyl-1,3-hexanediol according to the present invention can be appropriately combined with a desired amount depending on the formulation, and the blending ratio is limited as long as the composition for external skin can be formed. Not.

  The composition for external use of the skin containing 2-phenoxyethanol and 2-ethyl-1,3-hexanediol according to the present invention can provide sufficient antiseptic properties without adding high ethanol or parabens. Can be provided, and the composition for external use of skin can be provided with extremely low irritation to skin, excellent usability and high safety. Furthermore, it is not affected by the pH and salt of the formulation system, the antiseptic property does not decrease with time, the excellent antiseptic property lasts, there is no problem of aggregation and separation, and the stability of the composition for external use on the skin Will improve.

As the external composition base for skin, characterized by blending 2-phenoxyethanol and 2-ethyl-1,3-hexanediol of the present invention, any normal external composition base can be used. That is, liquids, gels, pastes, emulsions, creams, powders, solids, sticks, and the like can be used. In addition, components usually blended into the composition for external use of skin, for example, powder components, liquid fats, solid fats, waxes, hydrocarbon oils, higher fatty acids, higher alcohols, ester oils, silicone oils, anionic surfactants, cationic surfactants Agent, amphoteric surfactant, nonionic surfactant, moisturizer, water-soluble polymer, thickener, film agent, UV absorber, sequestering agent, lower alcohol, polyhydric alcohol, sugar, amino acid, organic amine Needless to say, polymer emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, antioxidant aids, other drugs, pigments, fragrances, water and the like can be used in combination.

  Ingredients that can be blended in the composition for external use of the skin, characterized by blending 2-phenoxyethanol and 2-ethyl-1,3-hexanediol of the present invention, are specifically listed below. A composition for external use on skin can be prepared by blending with seeds or more.

  Examples of the powder component include inorganic powders (for example, talc, kaolin, mica, sericite, muscovite, phlogopite, synthetic mica, saucite, biotite, permiculite, magnesium carbonate, calcium carbonate, silicic acid. Aluminum, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined calcium sulfate (baked gypsum), calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder , Metal soap (eg, zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc .; organic powder (eg, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, benzoguana Resin powder, polytetrafluoroethylene powder, cellulose powder, etc.); inorganic white pigments (eg, titanium dioxide, zinc oxide, etc.); inorganic red pigments (eg, iron oxide (Bengara), iron titanate, etc.); inorganic Brown pigment (for example, γ-iron oxide, etc.); Inorganic yellow pigment (for example, yellow iron oxide, ocher, etc.); Inorganic black pigment (for example, black iron oxide, low-order titanium oxide, etc.); Inorganic purple pigment (Eg, mango violet, cobalt violet, etc.); inorganic green pigments (eg, chromium oxide, chromium hydroxide, cobalt titanate, etc.); inorganic blue pigments (eg, ultramarine blue, bitumen, etc.); pearl pigments (eg, oxidized) Titanium coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, etc.); gold Powder pigments (for example, aluminum powder, copper powder, etc.); Organic pigments such as zirconium, barium or aluminum lake (for example, red 201, red 202, red 204, red 205, red 220, red 226, Organic pigments such as red 228, red 405, orange 203, orange 204, yellow 205, yellow 401, and blue 404, red 3, red 104, red 106, red 227, red 230, red 401, red 505, orange 205, yellow 4, yellow 5, yellow 202, yellow 203, green 3 and blue 1); natural pigments (eg chlorophyll, β- Carotene and the like).

  Examples of liquid oils include avocado oil, camellia oil, macadamia nut oil, corn oil, olive oil, rapeseed oil, sesame oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil, soybean oil, peanut oil , Tea seed oil, rice bran oil, jojoba oil, germ oil, triglycerin and the like.

  Examples of the solid fat include cacao butter, coconut oil, hardened coconut oil, palm oil, palm kernel oil, owl kernel oil, hardened oil, owl, and hardened castor oil.

  Examples of the wax include beeswax, candelilla wax, carnauba wax, lanolin, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojo wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol Examples include acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, and the like.

  Examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax, and Fischer-Trops wax.

  Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), and the like. Is mentioned.

  Examples of higher alcohols include linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol); branched chain alcohols (eg, monostearyl glycerin ether (batyl alcohol) ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, isostearyl alcohol, octyldodecanol and the like.

  Ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate, Lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, monoisostearic acid N-alkyl glycol, neopentyl glycol dicaprate, malic acid Diisostearyl, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid trimethylolpropane, triisostearyl Acid trimethylolpropane, tetra-2-ethylhexanoic acid pentaerythritol, tri-2-ethylhexanoic acid glycerin, trioctanoic acid glycerin, triisopalmitic acid glycerin, triisostearic acid trimethylolpropane, cetyl 2-ethylhexanoate, 2 -Ethylhexyl palmitate, glyceryl trimyristate, tri-2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleic acid oleyl, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L- Glutamic acid-2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate , Palmitic acid 2-hexyl decyl, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, and triethyl citrate.

  Examples of the silicone oil include linear polysiloxanes (for example, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (for example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexyl). Satrisiloxane, etc.), methyl trimethicone, silicone resin forming a three-dimensional network structure, silicone rubber, various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, etc.) ) And the like.

  Anionic surfactants include, for example, fatty acid soaps (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (eg, sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfates (eg, POE-lauryl sulfate triethanolamine, POE-sodium lauryl sulfate, etc.); N-acyl sarcosine acid (eg, sodium lauroyl sarcosine, etc.); higher fatty acid amide sulfonates (eg, sodium N-myristoyl-N-methyl taurate, palm Oil fatty acid methyl taurine sodium, palm oil fatty acid methyl taurine taurine sodium, lauryl methyl taurine sodium, lauryl methyl taurine methyl taurine sodium, etc .; sulfosuccinate (for example di- Sodium 2-ethylhexyl sulfosuccinate, sodium monolauroyl monoethanolamide polyoxyethylene sodium sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, etc .; alkylbenzene sulfonates (for example, sodium lineardodecylbenzenesulfonate, triethanolamine lineardodecylbenzenesulfonate) Higher fatty acid ester sulfate (for example, hydrogenated coconut oil fatty acid sodium glyceryl sulfate, etc.); N-acyl glutamate (for example, monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate, N-myristoyl-L-glutamate monosodium, etc.); POE-alkyl ether carboxylic acid; POE-a Kill allyl ether carboxylate; alpha-olefin sulfonate; lauroyl sodium monoethanolamide succinate; N- palmitoyl aspartate ditriethanolamine; and the like.

  Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (eg, cetylpyridinium chloride, etc.); distearyldimethylammonium dialkyldimethylammonium chloride; Poly (N, N′-dimethyl-3,5-methylenepiperidinium chloride); alkyl quaternary ammonium salt; alkyldimethylbenzylammonium salt; alkylisoquinolinium salt; dialkyl morpholinium salt; benzalkonium chloride; Examples thereof include benzethonium chloride.

  Examples of amphoteric surfactants include imidazoline-based amphoteric surfactants (eg, 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide). Side-1-carboxyethyloxy disodium salt, etc.); betaine surfactant (for example, 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, amidoamine type amphoteric surfactant, lauryldimethylaminoacetic acid) Betaine, alkyl betaine, amide betaine, sulfobetaine and the like).

  Examples of the lipophilic nonionic surfactant include sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, Sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexyl); glycerin polyglycerin fatty acids (for example, mono-cotton oil fatty acid glycerin, mono-erucic acid glycerin, sesquioleate glycerin, monostearin) Glycerin acid, α, α′-oleic acid pyroglutamate glycerin, monostearate glycerin malate, etc.); propylene glycol fatty acid esters (for example, And propylene glycol monostearate); hardened castor oil derivatives; glycerin alkyl ethers and the like.

  Examples of the hydrophilic nonionic surfactant include POE-sorbitan fatty acid esters (for example, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate, etc.); POE sorbite fatty acid esters (eg, POE-sorbite monolaurate, POE-sorbite monooleate, POE-sorbite pentaoleate, POE-sorbite monostearate, etc.); POE-glycerin fatty acid esters (eg, POE-glycerin) Monostearate, POE-glycerol monoisostearate, POE-monooleate such as POE-glycerol triisostearate, etc.); POE-fatty acid esters (for example, POE-distearate, PO Monodioleate, ethylene glycol distearate, etc .; POE-alkyl ethers (eg POE-lauryl ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol) Ethers, etc .; Pluronic types (eg, Pluronics, etc.); POE • POP-alkyl ethers (eg, POE • POP-cetyl ether, POE • POP-2-decyltetradecyl ether, POE • POP-monobutyl ether, POE) POP-hydrogenated lanolin, POE / POP-glycerin ether, etc.) Tetra POE / tetra-POP-ethylenediamine condensates (eg, Tetronic etc.); POE-castor oil hydrogenated castor oil derivative ( For example, POE-castor oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE-hardened castor oil triisostearate, POE-hardened castor oil monopyroglutamic acid monoisostearic acid diester, POE-hardened castor Alkanolamide (for example, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); sucrose fatty acid ester; alkyl ethoxydimethylamine oxide; trioleyl phosphoric acid and the like.

  Examples of the humectant include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, acetylated hyaluronic acid, mucoitin sulfate, and salts thereof, and the like. Examples thereof include cholesteryl-12-hydroxystearate, lactic acid, sodium lactate, dl-pyrrolidone carboxylate, trimethylglycine, diglycerin (EO) PO adduct, Izayoi rose extract, yarrow extract, and merirot extract.

  Examples of natural water-soluble polymers include plant-based polymers (for example, gum arabic, gum tragacanth, galactan, guar gum, carrageenan, pectin, agar, locust bin gum, quince seed (malmello), alge colloid (gypsum extract), starch ( Rice, corn, potato, wheat); microbial polymers (eg, xanthan gum, dextran, succinoglucan, gellan gum, pullulan, etc.).

  Semi-synthetic water-soluble polymers include, for example, starch polymers (eg, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate) Hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder and the like); alginic acid polymers (for example, sodium alginate, propylene glycol alginate, etc.) and the like.

  Synthetic water-soluble polymers include, for example, vinyl polymers (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer, alkyl-modified carboxyvinyl polymer, etc.); polyoxyethylene polymers (eg, polyethylene) Glycol 20,000, 40,000, 60,000 polyoxyethylene polyoxypropylene copolymers, etc.); acrylic polymers (for example, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethyleneimine; cationic polymers, etc.

  Examples of the thickener other than the water-soluble polymer include aluminum magnesium silicate, bentonite, organically modified bentonite, hectorite, silicate A1Mg (beegum), laponite, and anhydrous silicic acid.

  Examples of the ultraviolet absorber include benzoic acid-based ultraviolet absorbers (for example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester. N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester, etc.); salicylic acid ultraviolet absorbers (for example, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate) , Phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, etc.); cinnamic acid-based ultraviolet absorbers (for example, octylcinnamate, ethyl-4-isopropylcinnamate, methyl-2,5) Diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl- p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate Etc.); 3- (4′-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2′-hydroxy-5-methyl Phenylbenzotriazol 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole; 2- (2'-hydroxy-5'-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 4-methoxy-4'- t-butyldibenzoylmethane; 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one; bis-ethylhexyloxyphenol-methoxyphenyl-triazine; 2,4,6-tris [4- (2-ethylhexyloxycarbonyl) anilino] 1,3,5-triazine and the like.

  Examples of the sequestering agent include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, and tetrasodium edetate. Sodium hexametaphosphate, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid, trisodium ethylenediaminehydroxyethyl triacetate, and the like.

  Examples of the lower alcohol include ethanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

  Examples of the polyhydric alcohol include divalent alcohols (for example, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, Pentamethylene glycol, 2,2,4-trimethyl-1,3-pentanediol, 2,2-dimethyl-1,3-propanediol, 2,2-diethyl-1,3-propanediol, 2,2-di Methylol pentane, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trivalent alcohols (eg, glycerin, trimethylol propane, etc.); tetravalent alcohols (eg, 1,2,6- Pentaerythritol such as hexanetriol); pentavalent alcohol (E.g., xylitol); hexavalent alcohol (e.g., sorbitol, mannitol, etc.); polyhydric alcohol polymer (e.g., diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene glycol, tetraethylene glycol, diglycerin, polyethylene glycol) , Triglycerin, tetraglycerin, polyglycerin, etc.); divalent alcohol alkyl ethers (for example, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, Ethylene glycol mono 2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene Recall benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, etc.); dihydric alcohol alkyl ethers (for example, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, Diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene Glycol monobutyl ether, propylene glycol isopropyl ether, dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol butyl ether, etc.); dihydric alcohol ether esters (for example, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, Ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl ether acetate, ethylene glycol diazinate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol mono Chill ether acetate, propylene glycol monopropyl ether acetate, propylene glycol monophenyl ether acetate, etc.); glycerin monoalkyl ether (eg, xyl alcohol, ceralkyl alcohol, batyl alcohol, etc.); sugar alcohol (eg, sorbitol, maltitol, malto) Triose, mannitol, sucrose, erythritol, glucose, fructose, amylolytic sugar, maltose, xylitolose, amylolytic sugar reducing alcohol, etc.); glycolide; tetrahydrofurfuryl alcohol; POE-tetrahydrofurfuryl alcohol; POP-butyl ether POP · POE-butyl ether; Tripolyoxypropylene glycerin ether; POP-glycerin ether; P P- glycerol ether phosphoric acid; POP · POE- pentane erythritol ether, polyglycerol and the like.

  Examples of monosaccharides include tricarbon sugars (eg, D-glyceryl aldehyde, dihydroxyacetone, etc.); tetracarbon sugars (eg, D-erythrose, D-erythrulose, D-treose, erythritol, etc.); pentose sugars (eg, L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc .; hexose (eg, D-glucose, D-talose, D) -Bucicose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc.); pentose sugar (eg, aldheptose, heproose, etc.); octose sugar (eg, octulose, etc.); For example, 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L Mannose, etc.]; amino sugars (eg, D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, muramic acid, etc.); uronic acids (eg, D-glucuronic acid, D-mannuronic acid, L-guluronic acid, D- Galacturonic acid, L-iduronic acid, etc.).

  Examples of oligosaccharides include sucrose, gunthianose, umbelliferose, lactose, planteose, isoliquinoses, α, α-trehalose, and raffinose.

  Examples of amino acids include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.) and the like. Examples of amino acid derivatives include trimethyl glycine, glycyl glycine, glutathione, sarcosine, and pyrrolidone carboxylic acid.

  Examples of the organic amine include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-methyl-1-propanol, and the like. Is mentioned.

  Examples of the polymer emulsion include an acrylic resin emulsion, a polyethyl acrylate emulsion, an acrylic resin liquid, a polyacryl alkyl ester emulsion, a polyvinyl acetate resin emulsion, and a natural rubber latex.

  Examples of the pH adjusting agent include buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate.

  Examples of vitamins include vitamin A, B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, biotin and the like.

  Examples of the antioxidant include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.

  Examples of the antioxidant assistant include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, and ethylenediaminetetraacetic acid.

  Other ingredients that can be blended include, for example, anti-inflammatory agents (for example, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.); whitening agents (for example, placenta extract, yukinoshita extract, arbutin, Tranexamic acid, potassium 4-methoxysalicylate, etc .; various extracts (eg, buckwheat, auren, shikon, peonies, assembly, birch, sage, loquat, carrot, aloe, mallow, iris, grape, yokoinin, loofah, lily, saffron , Senkyu, Shokyu, Hypericum, Onis, Garlic, Pepper, Chimpi, Toki, Seaweed, etc.), Activator (eg, Royal Jelly, Photosensitizer, Cholesterol derivative, etc.); Blood circulation promoter (eg, Nonylate Wallenylamide, Nicotine) Benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin , Γ-oryzanol, etc.); antiseborrheic agents (eg, sulfur, thianthol, etc.); anti-inflammatory agents (eg, thiotaurine, hypotaurine, etc.); stabilizers (4,5-dimorpholino-3-hydroxypyridazine), etc. It is done.

The embodiment of the present invention may be any of those described above, and is not limited thereto. Specifically, for example, a cosmetic is selected as the external composition for skin of the present invention, but the present invention is not limited thereto.
The cosmetic is specifically a basic cosmetic, makeup cosmetic, or body cosmetic, but the present invention is not limited to this.
In addition, the basic cosmetic can be specifically selected in any form such as lotion, milky lotion, cream, gel, facial cleanser, cosmetic liquid, pack, mask, shaving cosmetic, etc. The invention is not limited to this.
In addition, the makeup cosmetic is specifically any one of foundation, white powder and dusting powder, lipstick, blusher, makeup base, eyeliner, mascara, eye shadow, eyebrow, nail enamel, enamel remover, nail treatment, etc. The form can be selected, but the present invention is not limited to this.
Further, the body cosmetics specifically include, for example, cleaning agents, bathing agents, lotions, emulsions, creams, fragrances, sun care cosmetics (sunscreen, sun oil, after sun lotion, etc.), deodorant cosmetics, decolorizing / Any form such as a hair remover, soft cosmetic (keratin softening lotion, gommage, etc.) can be selected, but the present invention is not limited to this.

  Next, the present invention will be described more specifically with reference to examples. The present invention is not limited thereby. A compounding quantity is the mass%.

[Use test and antiseptic test]
A lotion having the formulation shown in Table 1 was prepared according to the following production method, and a use test and an antiseptic test were conducted.
<Manufacturing method for lotion>
Dissolve citric acid, trisodium citrate, and trisodium edetate in purified water (aqueous phase). Each test sample is dissolved in an ethanol, glycerin, 1,3-butylene glycol, POE (60) hydrogenated castor oil dissolved (alcohol phase). Mix the aqueous and alcohol phases.
<Use test method>

In the past, 10 panelists with sensitive skin who had felt irritation when using a topical skin composition containing parabens were used twice a day for 1 week. I was declared. The evaluation of feeling of use was classified into the following four criteria, and the number of people who complained of irritation was confirmed.
A: Eight or more panelists recognized as having good feeling B: Five or more to less than eight panelists recognized as having good feeling C: Three or more to less than five panelists recognized as having good feeling D: Less than 3 panelists recognized as having a good feeling of use <Preservation test method>

After inoculating the bacterial solution into 30 g of the samples of Examples and Comparative Examples, the change in the number of bacteria was examined by a smearing method. The inoculum is mold (strain name: Aspergillus niger ATCC16404; inoculum 10 ⁴ cfu (colony forming unit) / g), yeast (strain name: Candida albicans ATCC10231; inoculum 10 ⁵ cfu / g), bacteria (E. coli: strain name) : Escherichia coli
ATCC8739; inoculum 10 ⁶ cfu / g, Staphylococcus aureus: strain name: Staphylococcus aureus ATCC6538; inoculum 10 ⁶ cfu / g, Pseudomonas aeruginosa: strain name: Pseudomonas aeruginosa ATCC 15442; inoculum 10 ⁶ cfu / g) The antibacterial activity was evaluated based on the change in the number of bacteria until the lapse of 2 weeks, and the obtained effects were classified according to the following four criteria.
A: All of mold, yeast, and bacteria are reduced to 100 cfu / g or less within one week B; All of mold, yeast, and bacteria are reduced to 100 cfu / g or less within two weeks C; , Yeast or bacteria remain at 100 cfu / g or more D; molds, yeast, and bacteria all remain at 100 cfu / g or more after 2 weeks. To do. Table 1 shows the results of the use test and the antiseptic test.
<Temperature test>
50 g of the samples of Examples and Comparative Examples were placed in a 50 mL screw tube, and three of each were stored in a high temperature bath at 50 ° C. for 30 days.
<Stability test>
The stability of the sample subjected to the temperature test was evaluated according to the following criteria.
A: Good formulation stability, no change in appearance, no phenomena such as discoloration, separation, aggregation, and crystal precipitation.
○: The stability of the preparation is almost good, and there is no significant change in appearance that causes a problem, but some changes are observed.
Δ: Slightly problematic in formulation stability, and phenomena such as partial discoloration, separation, aggregation, and precipitation of crystals are observed.
X: There is a problem in the stability of the preparation, and appearance change, discoloration, separation, aggregation, crystal precipitation, etc. are observed.
In addition, ◎ and ○ are acceptable as preparations.
<Anti-preserving power retention test method>
The samples subjected to the temperature test were evaluated for preservative power by the same method as the above-described preservative power determination test method, and evaluated for preserving power of the preservative power. Table 1 shows the results of the stability test and the antiseptic retention test.

In Examples 1 to 4, there was no person who complained of skin irritation, and the percentage of those who were satisfied with usability was high, and antiseptic power was also ensured. This is an effect according to the present invention. On the other hand, Comparative Example 1 has a high proportion of those who have little skin irritation and are satisfied with usability, but have poor antiseptic power. In Comparative Example 2, the percentage of those who were satisfied with usability with little skin irritation was high, but the antiseptic power was poor. In Comparative Example 3, there was no problem with antiseptic power, but the satisfaction with usability was low, and there were two people who complained of skin irritation. In Comparative Example 4, there was no problem with antiseptic power, but there was one person who complained of skin irritation that was considered to be due to low satisfaction of usability and a large amount of ethanol. Although Comparative Example 5 was excellent in usability and antiseptic power, many people complained of skin irritation and had problems with skin irritation.
Moreover, about what gave the temperature test for 30 days at 50 degreeC, in Examples 1-4, stability is favorable and antiseptic power is also hold | maintained. This is an effect according to the present invention. On the other hand, although the stability was favorable in Comparative Example 1, the antiseptic power was inferior even after the test. In Comparative Examples 2 and 3, the stability was good, but the antiseptic power was reduced. In Comparative Examples 4 and 5, the stability was good and the antiseptic power was maintained.

Were prepared according to the following production methods, and a use test, an antiseptic test, a stability test, and an antiseptic retention test were carried out in the same manner as described above. Table 2 shows the results of these use test and antiseptic test, as well as the stability test and antiseptic retention test.
<Production method of emulsion>

1,3-butylene glycol, polyethylene glycol 1500, trisodium edetate, triethanolamine, and purified water are added to each test sample and heated to 70 ° C. (aqueous phase). Stearic acid, cetyl alcohol, petrolatum, and squalane are dissolved, and sorbitan monooleate is added thereto and adjusted to 70 ° C. (oil phase). The oil phase is added to the aqueous phase, pre-emulsified, and uniformly emulsified with a homomixer, and then cooled.

実施例５〜７では防腐力が十分確保されていながら、皮膚刺激を訴えた者はなく、また使用性に満足した者の割合が多い。これは本発明に係る効果である。一方、比較例６では、皮膚刺激が少なく使用性に満足した者の割合も多いが、防腐力が劣っている。比較例７では、刺激を訴えた者はなく、使用性に満足する者の割合が多いが、防腐力にやや劣っている。比較例８では、防腐力に問題はなかったが、使用性の満足度が低く、皮膚刺激を訴えた者が２名いた。比較例９は使用性、防腐力に問題はなかったが、皮膚刺激を訴えた者が多く皮膚刺激に課題があった。
また、５０℃３０日間の温度試験を施したものについて、実施例５〜７では安定性が良好で防腐力も保持されている。これは本発明に係る効果である。一方、比較例６では安定性は良好であったが、試験後も防腐力が劣っている。比較例７ではやや分離がおきており、更には防腐力が低下していた。比較例８では分離がおきており、更には防腐力が低下していた。比較例９では安定性は良好であり、防腐力が保持されていた。

In Examples 5 to 7, there is no person who complained of skin irritation while the antiseptic power is sufficiently secured, and there are many persons who are satisfied with usability. This is an effect according to the present invention. On the other hand, in Comparative Example 6, the percentage of those who had little skin irritation and satisfied usability was high, but the antiseptic power was inferior. In Comparative Example 7, there was no person who complained of irritation and there was a large proportion of those who were satisfied with usability, but it was slightly inferior in antiseptic power. In Comparative Example 8, there was no problem with antiseptic power, but the satisfaction with usability was low, and there were two people who complained of skin irritation. In Comparative Example 9, there was no problem in usability and antiseptic power, but many people complained of skin irritation and there was a problem in skin irritation.
Moreover, about what gave the temperature test for 30 days at 50 degreeC, in Examples 5-7, stability is favorable and antiseptic power is also hold | maintained. This is an effect according to the present invention. On the other hand, in Comparative Example 6, the stability was good, but the antiseptic power was inferior even after the test. In Comparative Example 7, some separation occurred, and the antiseptic power was further reduced. In Comparative Example 8, separation occurred and the antiseptic power was further reduced. In Comparative Example 9, the stability was good and the antiseptic power was maintained.

Was prepared according to the following production method, and a use test, an antiseptic power test, and an antiseptic power retention test were carried out in the same manner as described above. Moreover, the temperature stability test was performed by the method shown below, and the evaluation was performed according to the same criteria as described above. Table 3 shows the results of these use test and antiseptic test, as well as the stability test and antiseptic test.
<Production method of water-in-oil cream foundation>

1,3-butylene glycol and a dispersant are added to each test sample, and the mixture is heated and adjusted to 70 ° C. (aqueous phase). Sericite, kaolin, titanium dioxide, bengara, yellow iron oxide, and black iron oxide are sufficiently mixed and ground (powder part), and added to the aqueous phase at 70 ° C. using a homomixer. To this, a stabilizer dissolved in a part of purified water is added and stirred. Further, liquid paraffin, decamethylcyclopentanesiloxane, and polyoxyethylene-modified dimethylpolysiloxane are heated to 70 ° C. (oil phase). In addition to this, the mixture is uniformly emulsified with a homomixer and then cooled.
<Temperature test>

50 g of each of the samples of Examples and Comparative Examples were placed in 50 mL screw tubes, and each was stored in a high temperature bath at 0 ° C. and 50 ° C. for 30 days.

実施例８〜１０では皮膚刺激を訴えた者はなく、また使用性に満足した者の割合が多く防腐力も確保されている。これは本発明に係る効果である。一方、比較例１０では、皮膚刺激が少なく使用性に満足した者の割合も多いが、防腐力が劣っている。比較例１１では、刺激を訴えた者はなく、使用性に満足した者の割合が多いが、防腐力がやや劣っている。比較例１２では、防腐力に問題はなかったが、使用性の満足度が低く、皮膚刺激を訴えた者が３名いた。比較例１３は防腐力に問題はなかったが、使用性の満足度が低く、皮膚刺激を訴えた者が多く皮膚刺激に課題があった。比較例１４では、皮膚刺激を訴えた者はなく、使用性に満足した者の割合が多く、防腐力も確保されている。
また、０℃及び５０℃各３０日間の温度試験を施したものについて、実施例８〜１０ではいずれの温度でも安定性が良好で防腐力も保持されている。これは本発明に係る効果である。一方比較例１０ではいずれの温度でも安定性が良好であったが、いずれも防腐力が劣っている。比較例１１ではいずれの温度であってもやや分離・凝集がおきており、５０℃保存品については防腐力が低下していた。比較例１２ではいずれの温度であっても分離・凝集がおきており、５０℃保存品については防腐力が低下していた。比較例１３では５０℃保存品についての安定性は良好であり、防腐力も保持されていたが、０℃保存品について白い固体の析出がみられ、防腐力が低下していた。比較例１４は製剤調整直後から着色がみられ、５０℃保存品では更に着色していた。５０℃保存品の防腐力は保持されていたものの、０℃保存品については白い固体の析出がみられ、防腐力が低下していた。

In Examples 8 to 10, there was no person who complained of skin irritation, and the percentage of those who were satisfied with usability was high, and antiseptic power was also ensured. This is an effect according to the present invention. On the other hand, in Comparative Example 10, although the percentage of those who are satisfied with usability with little skin irritation is high, the antiseptic power is inferior. In Comparative Example 11, there was no person who complained of irritation, and there were many persons who were satisfied with usability, but the antiseptic power was slightly inferior. In Comparative Example 12, there was no problem with antiseptic power, but the satisfaction with usability was low, and there were three people who complained of skin irritation. In Comparative Example 13, there was no problem with antiseptic power, but the satisfaction with usability was low, and many people complained of skin irritation and had problems with skin irritation. In Comparative Example 14, there was no person who complained of skin irritation, a large proportion of those who were satisfied with usability, and antiseptic power was ensured.
Moreover, about what performed the temperature test for 30 degreeC each at 0 degreeC and 50 degreeC, in Examples 8-10, stability is favorable at any temperature, and antiseptic power is also hold | maintained. This is an effect according to the present invention. On the other hand, in Comparative Example 10, the stability was good at any temperature, but all were poor in antiseptic power. In Comparative Example 11, separation / aggregation occurred somewhat at any temperature, and the antiseptic power of the product stored at 50 ° C. was reduced. In Comparative Example 12, separation / aggregation occurred at any temperature, and the antiseptic power of the product stored at 50 ° C. was reduced. In Comparative Example 13, the stability of the product stored at 50 ° C. was good and the antiseptic power was maintained, but precipitation of a white solid was observed for the product stored at 0 ° C., and the antiseptic power was reduced. In Comparative Example 14, coloring was observed immediately after preparation preparation, and coloring was further performed in the product stored at 50 ° C. Although the preservative power of the 50 ° C. preserved product was retained, the white preserved precipitate was observed in the 0 ° C. preserved product, and the antiseptic power was reduced.

Were prepared according to the following production method, and a use test, a preservative test, a stability test, and a preservative test were conducted in the same manner as described above. Table 4 shows the results of these use test and antiseptic test, as well as the stability test and antiseptic retention test.
<Clay mask manufacturing method>

L-arginine-L-aspartic acid and EDTA trisodium are dissolved in water, and bentonite wetted with glycerin is added and dissolved (aqueous phase). Add 1,3-butylene glycol, dipropylene glycol, stearyl alcohol, behenyl alcohol, self-emulsifying glyceryl monostearate, polyoxyethylene glyceryl monosterate, betaine lauryldimethylaminoacetate, vitamin E acetate to each sample and heat at 80 ° C. Dissolve (oil phase), keep the whole at 55 ° C., add the oil phase to the aqueous phase and emulsify. Titanium oxide, kaolin, and zinc oxide (powder part) are mixed, added to the emulsified phase, and cooled.

In Examples 11 to 13, there was no person who complained of skin irritation, and the percentage of those who were satisfied with usability was large, and antiseptic power was secured. This is an effect according to the present invention. On the other hand, in Comparative Example 15, the percentage of those who were satisfied with usability with little skin irritation was high, but the antiseptic power was inferior. In Comparative Example 16, there was no person who complained of irritation and there was a large proportion of those who were satisfied with usability, but it was slightly inferior in antiseptic power. In Comparative Example 17, there was no problem with antiseptic power, but the satisfaction with usability was low, and there were two people who complained of skin irritation. In Comparative Example 18, the satisfaction of usability was low, the antiseptic power was inferior, and there were many people who complained of skin irritation and had problems with skin irritation.
Moreover, about what gave the temperature test for 30 degreeC each at 0 degreeC and 50 degreeC, in Examples 11-13, stability is favorable at any temperature, and antiseptic power is also hold | maintained. This is an effect according to the present invention. On the other hand, in Comparative Example 15, the stability was good at any temperature, but all were poor in antiseptic power. In Comparative Example 16, separation / aggregation occurred somewhat at any temperature, and the antiseptic power of the product stored at 50 ° C. was reduced. In Comparative Example 17, separation / aggregation occurred at any temperature, and the antiseptic power of the product stored at 50 ° C. was reduced. In Comparative Example 18, the pH decreased immediately after preparation preparation, coloring was observed for the 50 ° C. stored product, and the antiseptic power was poor. Further, a white solid was deposited on the 0 ° C. stored product, and the antiseptic power was inferior.

Hereinafter, various compositions for external use of the skin of the present invention will be exemplified. In any of the examples, while maintaining excellent antiseptic power, skin irritation was low, and usability and stability were good. In addition, the manufacturing method of the external composition for skin in these Examples followed the method generally used as a manufacturing method in each.

Toner lotion mass%
Ethanol 5.0
1,3-butylene glycol 6.0
Glycerin 5.0
Oleyl alcohol 0.1
2-Ethyl-1,3-hexanediol 0.8
POE (20) sorbitan monolaurate 0.5
POE (15) lauryl ether 0.5
2-Phenoxyethanol 0.2
Perfume Appropriate amount of purified water

Toner lotion mass%
Sorbit 4.0
1,3-butylene glycol 6.0
Glycerin 2.0
POE (20) oleyl alcohol ether 0.5
Methylcellulose 0.2
Quince Seed 0.1
2-Ethyl-1,3-hexanediol 1.2
2-phenoxyethanol 0.1
Perfume Appropriate amount of purified water

Toner lotion mass%
(Alcohol phase)
Ethanol 5.0
Oleyl alcohol 0.2
2-Ethyl-1.3-hexanediol 1.0
POE (20) sorbitan monolaurate 0.5
POE (15) lauryl ether 0.5
4,5-Dimorpholino-3-hydroxypyridazine 0.1
2-Phenoxyethanol 0.2
Perfume appropriate amount (water phase)
1,3-butylene glycol 6.0
1,2-pentanediol 1.0
Glycerin 5.0
Purified water residue

Toner lotion mass%
(Alcohol phase)
Ethanol 5.0
POE (20) oleyl ether 0.5
2-Ethyl-1.3-hexanediol 0.2
2-phenoxyethanol 0.1
Perfume appropriate amount (water phase)
Dipropylene glycol 6.0
Sorbit 4.0
PEG 1500 5.0
Methylcellulose 0.2
Quince Seed 0.1
Purified water residue

Toner lotion mass%
Ethanol 5.0
2-Ethyl-1.3-hexanediol 0.3
Glycerin 2.0
Dipropylene glycol 1.0
Isostearic acid 0.1
Poly (oxyethylene oxypropylene) 1.0
・ Methylpolysiloxane copolymer lauryldimethylaminoacetic acid betaine 0.1
Citric acid 0.02
Sodium citrate 0.08
Sodium hexametaphosphate 0.01
Hipotaurine 0.1
Chamomile extract 0.1
Lavender oil 0.001
2-phenoxyethanol 1.0
Active hydrogen water 1.0
Purified water residue

Milk mass%
Glycerin 3.0
2-Ethyl-1,3-hexanediol 1.0
Cetanol 1.5
Stearyl alcohol 1.8
Dimethylpolysiloxane (20cs) 1.5
Squalane 2.0
Vaseline 2.0
Isopropyl myristate 2.5
Glyceryl monostearate 1.8
Polyoxyethylene (POE = 5) glyceryl monostearate 1.8
Polyoxyethylene (POE = 20) cetyl ether 1.5
Carboxyvinyl polymer 0.25
Potassium hydroxide 0.05
L-Arginine 0.2
Dipropylene glycol 5.0
1,3-butylene glycol 3.0
1,2-pentanediol 0.1
Edetate trisodium 0.2
2-Phenoxyethanol 0.01
Purified water remaining

Milk mass%
Stearic acid 2.5
Cetyl alcohol 1.5
2-Ethyl-1,3-hexanediol 1.0
Vaseline 5.0
Liquid paraffin 10.0
POE (10) monooleate 2.0
PEG 1500 3.0
Triethanolamine 1.0
2-Phenoxyethanol 0.2
Sodium bisulfite 0.01
Carboxyvinyl polymer 0.05
Perfume Appropriate amount of purified water

Milk mass%
Liquid paraffin 7.0
Vaseline 3.0
Decamethylcyclopentasiloxane 2.0
Behenyl alcohol 1.0
Glycerin 5.0
Dipropylene glycol 7.0
Polyethylene glycol 1500 2.0
2-Ethyl-1,3-hexanediol 1.8
2-phenoxyethanol 0.1
Jojoba oil 1.0
Isostearic acid 0.5
Stearic acid 0.5
Behenic acid 0.5
Tetra-2-ethylhexanoic acid pentaerythritol 3.0
Cetyl 2-ethylhexanoate 3.0
Glycerol monostearate 1.0
Polyoxyethylene glycerol monostearate 1.0
Potassium hydroxide 0.1
Sodium hexametaphosphate 0.05
Stearyl glycyrrhetinate 0.05
L-Arginine 0.1
Royal Jelly Extract 0.1
Tocopherol acetate 0.1
Acetylated sodium hyaluronate 0.1
Edetate trisodium 0.05
4-t-butyl-4'-methoxydibenzoylmethane 0.1
2-Ethylhexyl paramethoxycinnamate 0.1
Carboxyvinyl polymer 0.15
Purified water residue

Milk mass%
Decamethylcyclopentasiloxane 3.0
Methylphenylpolysiloxane 3.0
Behenyl alcohol 1.0
1,3-butylene glycol 5.0
2-Ethyl-1,3-hexanediol 2.5
Polyoxyethylene glyceryl isostearate 1.5
Polyoxyethylene glycerol monostearate 1.0
Dipotassium glycyrrhizinate 0.05
Trimethylglycine 1.0
L-ascorbic acid 2-glucoside 2.0
Edetate trisodium 0.1
2-Ethylhexyl paramethoxycinnamate 7.0
Xanthan gum 0.1
Carboxyvinyl polymer 0.3
Phenoxyethanol 0.3
Purified water Residual fragrance

Milk mass%
Cetanol 1.0
Glycerin 5.0
2-Ethyl-1,3-hexanediol 0.8
1,3-butylene glycol 5.0
Polyethylene glycol 20000 2.0
Tetra (2-ethylhexanoic acid / paramethoxycinnamic acid) 3.0
Pentaerislit di-2-ethylhexyl succinate 3.0
Potassium hydroxide 0.1
Edetate trisodium 0.1
Methyl bis (trimethylsiloxy) trimethoxycinnamate 2.0
Silylisopentyl 4-t-butyl-4′-methoxydibenzoylmethane 2.0
2-Ethylhexyl paramethoxycinnamate 2.0
Diparamethoxycinnamate mono-2-ethylhexanoate glyceryl 2.0
Carboxyvinyl polymer 0.15
Acrylic acid / alkyl methacrylate copolymer 0.1
(Pemulen TR-1)
2-phenoxyethanol 0.3
Purified water Residual fragrance

Gel mass%
95% ethanol 5.0
Dipropylene glycol 15.0
1,2-octanediol 2.0
2-Ethyl-1,3-hexanediol 2.0
POE (50) oleyl ether 2.0
Carboxyvinyl polymer 1.0
Sodium hydroxide 0.15
2-phenoxyethanol 0.1
Perfume Appropriate amount of purified water

Essence mass%
95% ethanol 5.0
POE (20) Octyldodecanol 1.0
Pantothenyl ethyl ether 0.1
2-Ethyl-1,3-hexanediol 0.1
Potassium hydroxide 0.1
Glycerin 5.0
Dipropylene glycol 10.0
Sodium bisulfite 0.03
Carboxyvinyl polymer 0.2
2-phenoxyethanol 0.1
Purified water residue

Pack mass%
(Phase A)
Dipropylene glycol 5.0
POE (60) hydrogenated castor oil 5.0
(Phase B)
Olive oil 5.0
2-Ethyl-1,3-hexanediol 0.8
Tocopherol acetate 0.2
Fragrance 0.2
(Phase C)
Sodium bisulfite 0.03
Polyvinyl alcohol
(Degree of saponification 90, degree of polymerization 2000) 13.0
Ethanol 5.0
2-Phenoxyethanol 0.15
Purified water residue

Cream mass%
2-Ethyl-1,3-hexanediol 1.0
Stearyl alcohol 3.5
Stearic acid 2.0
Squalane 10.5
Isopropyl myristate 7.5
Polyoxyethylene (POE = 25) cetyl alcohol ether 3.0
Glycerol monostearate 2.0
Tocopherol acetate 0.2
Monoammonium glycyrrhizinate 0.05
Glycerin 3.0
Dipropylene glycol 5.0
1,2-pentanediol 0.1
1,3-butylene glycol 3.0
2-phenoxyethanol 0.1
Edetate trisodium 0.01
Purified water remaining

Cream mass%
Stearic acid 6.0
Sorbitan monostearate ester 2.0
POE (20) sorbitan monostearate ester 1.5
Ethylhexanediol 2.0
Propylene glycol 10.0
Glycerin trioctanoate 10.0
Squalene 5.0
Sodium bisulfite 0.01
2-Ethyl-1,3-hexanediol 3.0
2-phenoxyethanol 0.1
Perfume Appropriate amount of purified water

Cream mass%
Liquid paraffin 10.0
Dimethylpolysiloxane 2.0
Glycerin 10.0
1,3-butylene glycol 2.0
Erythritol 1.0
2-Ethyl-1,3-hexanediol 2.1
Polyethylene glycol 1500 5.0
Squalane 15.0
Tetra-2-ethylhexanoic acid pentaerythrit 5.0
Potassium hydroxide 0.1
Sodium hexametaphosphate 0.05
Tocopherol acetate 0.05
2-phenoxyethanol 0.1
Hydroxypropyl methylcellulose 0.3
Polyvinyl alcohol 0.1
Carboxyvinyl polymer 0.2
Acrylic acid / alkyl methacrylate copolymer (Pemulene TR-2) 0.1

Cream mass%
Vaseline 2.0
Dimethylpolysiloxane (6mPa.s) 2.0
Ethanol 5.0
Behenyl alcohol 0.5
Batyl alcohol 0.2
Glycerin 7.0
1,3-butylene glycol 5.0
Polyethylene glycol 20000 0.5
Jojoba oil 3.0
Squalane 2.0
Phytosteryl hydroxystearate 0.5
Tetra-2-ethylhexanoic acid pentaerythrit 1.0
Polyoxyethylene (60) hydrogenated castor oil 1.0
Potassium hydroxide 0.1
Sodium pyrosulfite 0.01
Sodium hexametaphosphate 0.05
Stearyl glycyrrhetinate 0.1
Pantothenyl ethyl ether 0.1
Arbutin 7.0
Tranexamic acid 1.0
Tocopherol acetate 0.1
Sodium hyaluronate 0.05
Edetate trisodium 0.05
2-Ethyl-1,3-hexanediol 5.0
4-t-butyl-4'-methoxydibenzoylmethane 0.1
Diparamethoxycinnamic acid mono-2-ethylhexanoate glyceryl 0.1
2-phenoxyethanol 0.1
Yellow iron oxide xanthane gum 0.1
Carboxyvinyl polymer 0.2
Purified water residue

Cream mass%
Decamethylcyclopentasiloxane 30.0
Polyoxyethylene / methylpolysiloxane copolymer (molecular weight 6000) 1.5
Trimethylsiloxysilicate 0.5
Glycerin 2.0
2-Ethyl-1,3-hexanediol 1.0
Dipropylene glycol 5.0
Talc 5.0
Spherical silica 0.5
Palmitic acid dextrin coated fine particle titanium oxide (30nm) 7.0
Spherical polyethylene powder 2.0
Poly (oxyethylene / oxypropylene) / methylpolysiloxane copolymer (molecular weight 55000) 1.0
2-Phenoxyethanol 0.2
Edetate trisodium 0.02
Dimethyl distearyl ammonium hectorite 0.5
Purified water residue

Face wash
2-Ethyl-1,3-hexanediol 0.3
1,2-pentanediol 0.1
Stearic acid 8.0
Palmitic acid 6.0
Myristic acid 6.0
Lauric acid 4.0
Potassium hydroxide 5.2
Glyceryl monostearate 2.0
Propylene glycol 1.0
Bees wax 1.5
Polyethylene glycol 1500 5.0
Glycerin 10.0
2-Phenoxyethanol 0.01
Purified water remaining

Jelly pack mass%
Polyoxyethylene oleyl alcohol ether 0.5
Monoammonium glycyrrhizinate 0.05
Carboxymethylcellulose 5.0
Ethanol 12.0
Polyvinyl alcohol 12.0
1,3-butylene glycol 5.0
1,2-pentanediol 0.3
2-Ethyl-1,3-hexanediol 0.3
2-phenoxyethanol 0.1
Edetate trisodium 0.01
Purified water balance

Solid powder foundation mass%
Talc 15.0
Sericite 10.0
Spherical nylon powder 10.0
Porous silicic acid powder 15.0
Boron nitride 5.0
Titanium dioxide 5.0
Iron oxide 3.0
Zinc stearate 5.0
Liquid paraffin Residual glycerin triisooctanoate 15.0
Sorbitan sesquioleate 1.5
2-Ethyl-1,3-hexanediol 5.0
2-Phenoxyethanol 0.15
Perfume

Water-in-oil emulsification foundation Mass%
Spherical nylon 10.0
Porous silica powder 8.0
Mica titanium 2.0
Silicone-treated sericite 2.0
Silicone-treated mica 12.0
Silicone-treated titanium dioxide 5.0
Silicone-treated iron oxide 2.0
Purified water Residual 2-ethyl-1,3-hexanediol 5.0
Decamethylcyclopentasiloxane 18.0
Dimethylpolysiloxane 5.0
Squalane 1.0
Polyoxyethylene-modified dimethylpolysiloxane 2.0
2-Phenoxyethanol 0.05
Perfume

White powder
Talc Residual sericite 10.0
Spherical nylon powder 10.0
Boron nitride 5.0
Iron oxide 3.0
Magnesium carbonate 5.0
Squalane 3.0
Glycerin triisooctanoate 2.0
Sorbitan sesquioleate 2.0
Ethylhexanediol 0.5
2-phenoxyethanol 0.1
Perfume

Eyeliner mass%
Iron oxide (black) 14.0
Isopropyl myristate 1.5
Polyoxyethylene sorbitan monooleate 1.0
Vinyl acetate resin emulsion 45.0
Monoammonium glycyrrhizinate 0.05
Carboxyvinyl polymer 1.5
Acetyltributyl citrate 1.0
Dipropylene glycol 4.0
Isopropyl alcohol 1.0
2-Ethyl-1,3-hexanediol 1.0
1,2-pentanediol 3.0
Phenoxyethanol 0.1
Edetate trisodium 0.01
Purified water remaining

Eye shadow-mass%
Talc Residual Mica 15.0
Spherical nylon powder 10.0
Boron nitride 5.0
Iron oxide 3.0
Titanium oxide coated mica 5.0
Squalane 3.0
Glycerin triisooctanoate 2.0
Sorbitan sesquioleate 2.0
2-Ethyl-1,3-hexanediol 4.0
2-Phenoxyethanol 0.2
Perfume

Lipstick mass%
Carnavalo 0.5
Candelilla Row 5.0
Ceresin 10.0
Squalane Residual glycerin triisostearate 10.0
Glycerin diisostearate 20.0
2-Ethyl-1,3-hexanediol 1.0
2-Phenoxyethanol 0.2
Macadamia nut oil fatty acid cholesteryl 4.0
Synthetic sodium silicate-magnesium 0.5
Hydrophobic silica 0.5
Purified water 2.0
Colorant Appropriate amount of perfume Appropriate amount

Bath agent mass%
Sodium bicarbonate 64.5
Anhydrous sodium sulfate 35.0
2-Ethyl-1,3-hexanediol 0.5
2-Phenoxyethanol 0.01

Water-in-oil emulsification foundation Mass%
Spherical nylon 10.0
Porous silica powder 8.0
Mica titanium 2.0
Silicone-treated sericite 2.0
Silicone-treated mica 12.0
Silicone-treated titanium dioxide 5.0
Silicone-treated iron oxide 2.0
Purified water Residual 2-ethyl-1,3-hexanediol 1.0
3-phenoxy-1,2-propanediol 1.0
Decamethylcyclopentasiloxane 18.0
Dimethylpolysiloxane 5.0
Squalane 1.0
Polyoxyethylene-modified dimethylpolysiloxane 2.0
Phenoxyethanol 0.1
Perfume

Water-in-oil emulsified solid foundation Mass%
Microcrystalline wax 5.0
Dimethylpolysiloxane 10
Decamethylcyclopentasiloxane 30
Polyoxyethylene / methylpolysiloxane copolymer 2.0
Dipropylene glycol 3.0
Palmitic acid 0.5
Sorbitan sesquiisostearate 1.0
2-Ethyl-1,3-hexanediol 1.0
3-phenoxy-1,2-propanediol 3.0
Alkyl-modified silicone resin coated yellow iron oxide 3.0
Alkyl modified silicone resin coated bengara 1.0
Alkyl-modified silicone resin-coated black iron oxide Appropriate amount of alkyl-modified silicone resin-coated silicic acid 2.0
Alkyl-modified silicone resin coated titanium oxide 15
Alkyl modified silicone resin coated sericite 10
Titanium oxide Bengala coated mica 3.0
Cross-linked silicone powder (Trefil E-506) 3.0
N-lauroyl-L-lysine 0.1
Tocopherol acetate 0.1
δ-tocopherol 0.1
Phenoxyethanol 0.3
Merirot Extract 2.0
Purified water residue

Oil-in-water emulsified solid foundation Mass%
Microcrystalline wax 1.0
Dimethylpolysiloxane 15
Decamethylcyclopentasiloxane 2.0
1,3-butylene glycol 6.0
3-phenoxy-1,2-propanediol 4.0
2-Ethyl-1,3-hexanediol 1.0
Candelilla Row 3.0
Isostearic acid 1.0
Ethylene glycol fatty acid ester 0.1
Lanolin fatty acid octyldodecyl 0.5
2-Alkyl-N-carboxymethyl 4.0
-N-hydroxyethylimidazolinium betaine titanium oxide 7.5
Barium sulfate 5.0
Titanium oxide 7.0
Talc 3.0
Silicic anhydride 4.0
Cross-linked silicone powder (Trefil E-506) 0.1
Sodium metaphosphate 0.1
Hydroxypropyl-β-cyclodextrin 0.1
DL-α-tocopherol acetate 0.1
Hamamelis extract 0.1
Peonies extract 0.1
Sodium chondroitin sulfate 0.1
Sodium hyaluronate 0.1
Phenoxyethanol 0.3
Bengala appropriate amount yellow iron oxide appropriate amount black iron oxide appropriate amount xanthan gum 0.2
Sodium carboxymethylcellulose 0.2
Merirot Extract 2.0
Purified water residue

Solid foundation mass%
Dimethylpolysiloxane 5.0
Isostearic acid 0.5
Diisostearyl malate 3.0
Tri-2-ethylhexane sanglyceryl 1.0
Sorbitan sesquiisostearate 1.0
2-Ethyl-1,3-hexanediol 1.0
3-phenoxy-1,2-propanediol 1.0
Spherical PMMA-coated mica 6.0
Prism tone powder YR 1.0
Fine zinc oxide 0.5
Fine particle titanium oxide 2.0
Synthetic phlogopite 2.0
Metal soap treated talc 8.0
Spherical silica 5.0
Vitamin E acetate 0.1
δ Tocopherol 0.1
Phenoxyethanol 0.1
Methyl trimethoxycinnamate 1.0
Bis (trimethylsiloxy) silylisopentyl
2-methoxyhexyl paramethoxycinnamate 3.0
Spherical polyalkyl acrylate powder 6.0
Methyl hydrogen polysiloxane coated talc
Methyl hydrogen polysiloxane-coated sericite 20
Methyl hydrogen polysiloxane-coated titanium oxide 15
Methyl hydrogen polysiloxane coated pigment (colorant) 5.0

Stick foundation mass%
Ceresin 5.0
Dimethylpolysiloxane 10
Decamethylcyclopentasiloxane 10
Dodecamethylcyclohexasiloxane 20
Carnauba 0.5
Candelilla wax 0.5
Tri-2-ethylhexane sanglyceryl residual sesquiisostearate sorbitan 1.5
3-phenoxy-1,2-propanediol 2.0
2-Ethyl-1,3-hexanediol 1.0
Titanium oxide 8.0
Kaolin 10
Mica 12
Mica titanium / polyalkyl acrylate composite powder 1.0
Polyalkyl acrylate coated mica titanium 1.0
Titanium oxide MT-014TV 5.0
Black iron oxide coated mica titanium 0.5
Tocopherol acetate 0.1
Phenoxyethanol 0.3
δ-tocopherol 0.1
Bengala
Appropriate amount of yellow iron oxide
Appropriate amount of zinc oxide treated ultramarine
Appropriate amount of black iron oxide
Proper amount of fragrance
Appropriate amount

Water-in-oil cream foundation mass%
Dimethylpolysiloxane 3.0
Decamethylcyclopentasiloxane 10
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Dodecamethylcyclohexasiloxane 5.0
Glycerin 4.0
1,3-butylene glycol 5.0
3-phenoxy-1,2-propanediol 2.0
2-Ethyl-1,3-hexanediol 0.5
Palmitic acid 0.5
Distearyldimethylammonium chloride 0.2
Metal soap treated talc 2.0
Cross-linked silicone powder (Trefil E-506) 0.1
Bengala-coated mica titanium 0.5
N-lauroyl-L-lysine 2.0
Sodium L-glutamate 2.0
Tocopherol acetate 0.1
δ-tocopherol 0.1
Methylparaben 0.1
Phenoxyethanol 0.2
Spherical nylon powder 1.0
Spherical polyalkyl acrylate powder 3.0
Merirot Extract 2.0
Purified water Residual dextrin fatty acid-treated talc 3.0
Dextrin fatty acid-treated titanium dioxide 15
Dextrin fatty acid-treated yellow iron oxide 3.0
Dextrin fatty acid-treated black iron oxide 0.5

Oil-in-water cream foundation by mass
Behenyl alcohol 0.5
Dipropylene glycol 6.0
Stearic acid 1.0
Glycerol monostearate 1.0
3-phenoxy-1,2-propanediol 2.0
2-Ethyl-1,3-hexanediol 3.0
Potassium hydroxide 0.2
Triethanolamine 0.8
DL-α-tocopherol acetate 0.1
Yellow iron oxide 1.0
α-olefin oligomer 3.0
Dimethylpolysiloxane (6 mPa.s) 2.0
Dimethylpolysiloxane (100 mPa.s) 5.0
Batyl alcohol 0.5
Isostearic acid 1.0
Behenic acid 0.5
Cetyl 2-ethylhexanoate 10
Polyoxyethylene glycerol monostearate 1.0
Titanium oxide 3.0
Mica titanium / polyalkyl acrylate composite powder 0.5
Surface-treated titanium oxide (MT-062) 10
Polyacrylic acid alkyl coated mica titanium 0.5
Black iron oxide coated mica titanium 0.5
Silica anhydride 6.0
2-Ethylhexyl paramethoxycinnamate 2.0
Bengala appropriate amount
Ultramarine blue
Black iron oxide
Legal dye Appropriate amount
Xanthan gum 0.1
Bentonite 1.0
Sodium carboxymethylcellulose 0.1
Phenoxyethanol 0.3
Purified water residue
Perfume

Oil-in-water emulsion foundation mass%
Dimethylpolysiloxane 8.0
Behenyl alcohol 0.5
Batyl alcohol 0.5
1,3-butylene glycol 5.0
Macadamia nut oil 0.1
Isostearic acid 1.5
Stearic acid 1.0
Behenic acid 0.5
Cetyl 2-ethylhexanoate 5.0
Polyoxyethylene glycerol monostearate 1.0
Self-emulsifying glyceryl monostearate 1.0
Yellow iron oxide coated mica titanium 2.0
Titanium oxide 4.0
Talc 0.5
Kaolin 3.0
Synthetic phlogopite 0.1
Cross-linked silicone powder 0.1
Silicic anhydride 5.0
Potassium hydroxide 0.2
Triethanolamine 0.8
DL-α-tocopherol acetate 0.1
Sodium hyaluronate 0.1
Phenoxyethanol 0.3
2-Ethylhexyl paramethoxycinnamate 1.0
3-phenoxy-1,2-propanediol 1.0
2-Ethyl-1,3-hexanediol 1.0
Bengala appropriate amount yellow iron oxide appropriate amount black iron oxide appropriate amount xanthan gum 0.1
Bentonite 1.0
Sodium carboxymethylcellulose 0.1
Purified water Residual fragrance

Concealer mass%
Dimethylpolysiloxane 2.0
Decamethylcyclopentasiloxane 15
Polyoxyethylene / methylpolysiloxane copolymer 3.0
Glycerin 5.0
1,3-butylene glycol 6.0
D-man knit 1.0
3-phenoxy-1,2-propanediol 0.3
2-Ethyl-1,3-hexanediol 0.2
Squalane 0.5
Dextrin fatty acid coated titanium oxide 10
Dextrin fatty acid coated talc 10
Spherical polymethylsilsesquioxane powder 0.1
Bengala-coated mica titanium 0.5
Sodium L-glutamate 2.0
Wild rose extract 0.1
Phenoxyethanol 0.3
Bengala-coated mica titanium 0.5
Dextrin fatty acid coated yellow iron oxide 1.5
Dextrin fatty acid coated black iron oxide 0.5
Purified water residue

Eyeliner mass%
Iron oxide (black) 14.0
Isopropyl myristate 1.5
Polyoxyethylene sorbitan monooleate 1.0
Vinyl acetate resin emulsion 45.0
Monoammonium glycyrrhizinate 0.05
Carboxyvinyl polymer 1.5
Acetyltributyl citrate 1.0
Dipropylene glycol 4.0
Isopropyl alcohol 1.0
3-phenoxy-1,2-propanediol 1.0
2-Ethyl-1,3-hexanediol 1.0
1,2-pentanediol 3.0
Phenoxyethanol 0.1
Edetate trisodium 0.01
Purified water remaining

Eyeliner (water-based film type)
1,3-butylene glycol 7.0
Polyethylene glycol 300 3.0
3-phenoxy-1,2-propanediol 1.0
2-Ethyl-1,3-hexanediol 1.0
Polyoxyethylene (30) behenyl ether 2.0
P-Hydroxybenzoate ester 0.01
Sodium dehydroacetate 0.01
Phenoxyethanol 0.1
Carbon black 7.0
Alkyl acrylate copolymer emulsion 6.0
Purified water Remaining fragrance Appropriate amount Black iron oxide Appropriate amount

Eyeliner (Quick-drying type) Mass%
Liquid paraffin 5.0
Methyl polysiloxane emulsion Appropriate amount Glycerin 3.0
1,3-butylene glycol 6.0
3-phenoxy-1,2-propanediol 1.0
2-Ethyl-1,3-hexanediol 0.2
Polyoxyethylene sorbitan monolaurate (20E.O.) 2.0
Isobutylene / sodium maleate copolymer liquid 1.0
Titanium oxide Appropriate amount Plate-like barium sulfate Appropriate amount Kaolin 8.0
Black iron oxide-coated mica titanium (pearl agent) 3.0
Black iron oxide 9.0
DL-α-tocopherol acetate 0.1
Phenoxyethanol 0.3
Bentonite 1.0
Sodium carboxymethylcellulose 2.0
Alkyl acrylate copolymer emulsion 7.0
Purified water remaining

Eyeliner (waterproof type)
Decamethylcyclopentasiloxane 30
Polyoxyethylene / methylpolysiloxane copolymer 3.0
1,3-butylene glycol 2.0
3-phenoxy-1,2-propanediol 0.5
2-Ethyl-1,3-hexanediol 1.5
Isostearic acid 1.0
N-laureuil L-glutamic acid 0.1
Di (phytostearyl 2-octyldodecyl)
Sorbitan sesquiisostearate 15
Alkyl modified silicone resin coated black iron oxide 5.0
Alkyl modified silicone resin coated talc 3.0
Mica titanium (pearl agent) 5.0
Sodium hydroxide 0.05
Sodium chloride 0.2
Glycine 0.3
DL-α-tocopherol acetate 0.05
Phenoxyethanol 0.2
Dimethyl distearyl ammonium hectorite 1.5
Trimethylsiloxysilicic acid 10
Purified water remaining

Eyeliner / eyebrow mass%
Liquid paraffin 1.0
Vaseline 4.0
Dimethylpolysiloxane
7.0
3-phenoxy-1,2-propanediol 0.5
2-Ethyl-1,3-hexanediol 0.5
1,3-butylene glycol 0.1
Phytoteryl hydroxystearate 0.1
Sorbitan monoisostearate 1.0
Hydroxyapatite 1.0
Sericite 20
Mica Residual tocopherol acetate 0.02
δ-tocopherol 0.02
Phenoxyethanol 0.3
4-tert-butyl-4'-methoxydibenzoylmethane 0.1
Diparamethoxycinnamate mono-2-ethylhexanoate glyceryl 0.1
Bengala 2.0
Yellow iron oxide 7.0
Black iron oxide 10
Heavy liquid isoparaffin 2.0
Spherical nylon powder 0.5
Polyalkyl acrylate powder 2.0
Perfume

Eye shadow-mass%
Decamethylcyclopentasiloxane 16
Methylphenylpolysiloxane 1.0
Batyl alcohol 1.0
1,3-butylene glycol 5.0
3-phenoxy-1,2-propanediol 0.3
2-Ethyl-1,3-hexanediol 0.3
Macadamia nut oil 0.1
Stearic acid 1.0
Palmitic acid 1.0
Self-emulsifying glyceryl monostearate 1.0
Self-emulsifying propylene glycol stearate 1.0
Bengala-coated mica titanium (pearl agent) 13
Synthetic phlogopite 0.1
Silica anhydride 2.0
Triethanolamine 1.0
DL-α-tocopherol acetate 0.1
Phenoxyethanol 0.2
Xanthan gum 0.1
Bentonite 1.0
Sodium carboxymethylcellulose 0.1
Trimethylsiloxysilicate 5.0
Purified water Residual stearyl alcohol 0.5
Behenyl alcohol 0.5

Aishad- / Hot Red Mass%
Ethanol 6.0
Glycerin 4.0
1,3-butylene glycol 5.0
3-phenoxy-1,2-propanediol 0.5
2-Ethyl-1,3-hexanediol 0.7
Zinc oxide 0.01
Barium sulfate 3.0
Mica 1.0
Bengala-coated mica titanium 4.0
Mica titanium 8.0
Sodium chloride 1.0
Methylparaben 0.2
Phenoxyethanol 0.1
Ultramarine 0.1
Cellulose powder 3.0
Bentonite 1.0
Purified water residue

Water-in-oil mascara mass%
Light isoparaffin 7.0
Dimethylpolysiloxane 2.0
Decamethylcyclopentasiloxane 10
Trimethylsiloxysilicic acid 10
Methyl polysiloxane emulsion Appropriate amount 1,3-butylene glycol 4.0
3-phenoxy-1,2-propanediol 0.1
Dioleic acid polyethylene glycol 2.0
Diglyceryl diisostearate 2.0
Sodium bicarbonate 0.2
Sodium metaphosphate appropriate amount DL-α-tocopherol acetate
0.1
Sodium dehydroacetate 0.2
Black iron oxide 7.0
Seaweed extract 0.1
Bentonite 1.0
Dimethyl distearyl ammonium hectorite 6.0
Nylon fiber (1-2mm) 3.0
Heavy liquid isoparaffin 4.0
Polyvinyl acetate emulsion 30
Purified water remaining

Water-in-oil mascara (eyeliner type)
Decamethylcyclopentasiloxane 20
Polyoxyethylene / methylpolysiloxane copolymer 2.0
Methylphenylpolysiloxane 2.0
1,3-butylene glycol 2.0
3-phenoxy-1,2-propanediol 0.3
Macadamia nut oil 0.1
Oleic acid 1.0
Sorbitan sesquiisostearate 2.0
Alkyl modified silicone resin coated talc 5.0
Carmine coated mica titanium (pearl agent) 17
Bengala Carmine-coated mica titanium (pearl agent) 3.0
Sodium hydroxide 0.1
Sodium chloride 0.2
Glycine 0.3
D-δ-Tocopherol Appropriate amount Phenoxyethanol 0.3
Dimethyl distearyl ammonium hectorite 3.0
Trimethylsiloxysilicic acid 10
Purified water remaining

Oil-in-water mascara mass%
Light isoparaffin 6.0
Dimethylpolysiloxane 1.0
Decamethylcyclopentasiloxane 5.0
Trimethylsiloxysilicate 5.0
Methyl polysiloxane emulsion Suitable amount Isopropanol 3.0
1,3-butylene glycol 6.0
3-phenoxy-1,2-propanediol 3.5
Polyoxyethylene hydrogenated castor oil 1.0
Sucrose fatty acid ester 0.6
Diglyceryl diisostearate 1.0
Sodium bicarbonate 0.01
DL-α-tocopherol acetate 0.1
Acetylated sodium hyaluronate 0.1
Phenoxyethanol 0.3
Black iron oxide 8.0
Bentonite 1.0
Dimethyl distearyl ammonium hectorite 4.0
Polyvinyl alcohol 4.0
Alkyl acrylate copolymer emulsion 12
Polyvinyl acetate emulsion 12
Nylon fiber (1-2mm) 6.0
Purified water Residual amount Silicic anhydride 0.5
Titanium oxide 1.0
Perfume

Makeup base mass%
Dimethylpolysiloxane 6mPas 5.0
Decamethylcyclopentasiloxane Residual ethyl alcohol 8.0
Bitumen coated mica titanium 0.5
Methylsiloxane network polymer 5.0
Cross-linked silicone powder (Trefil E-506) 15
Citric acid 0.02
Sodium citrate 0.08
Tocopherol acetate 0.1
δ-tocopherol 0.1
Merirot Extract 3.0
3-phenoxy-1,2-propanediol 0.5
Purified water 1.0
Poly (oxyethylene oxypropylene) 5.0
・
Methyl polysiloxy acid copolymer

Lipstick mass%
Liquid paraffin 20
Polyoxyethylene / methylpolysiloxane copolymer 0.5
Methylphenyl polysiloxane 0.5
Glycerin 1.0
1,3-butylene glycol 3.0
3-phenoxy-1,2-propanediol 0.01
2-Ethyl-1,3-hexanediol 1.0
Diisostearyl phosphate, residual pigment 1.0
Pantothenyl ethyl ether 0.01
Arginine hydrochloride 0.01
Sodium hyaluronate 0.01
Dye proper amount Phenoxyethanol 0.3
Synthetic sodium silicate and magnesium 1.5
Dextrin palmitate 2.5
Heavy liquid isoparaffin 20
Purified water 1.0

Lipstick mass%
Microcrystalline wax 2.0
Ceresin 8.0
Glycerin 0.2
3-phenoxy-1,2-propanediol 0.03
2-ethyl-1,3-hexanediol 0.02
Squalane 1.0
Glyceryl triisostearate 1.5
Macadamia nut oil fatty acid cholesteryl 1.5
Diisostearyl malate 5.0
Glyceryl diisostearate3.0
Trimethylol propane trioctanoate 2.0
Tri-2-ethylhexane sangglyceryl Remaining silicone coating pigment (Bengara, iron oxide, titanium oxide, etc.) 10
Barium sulfate 4.0
Citric acid 0.05
Potassium hydroxide 0.05
Hydroxypropyl-β-cyclodextrin 0.5
Pantothenyl ethyl ether 0.02
Arginine hydrochloride 0.01
Sodium hyaluronate 0.05
Dye proper amount Phenoxyethanol 0.3
Safflower red-treated cellulose powder 0.01
Heavy liquid isoparaffin 5.0
Purified water 0.5
Perfume

Lip liner mass%
Hardened oil 20
Macadamia nut oil 2.0
Owl 6.0
Behenic acid 10
Glyceryl tri-2-ethylhexanoate Residual 3-phenoxy-1,2-propanediol 0.01
2-Ethyl-1,3-hexanediol 0.1
Sucrose fatty acid ester 5.0
Titanium oxide 10
Mica 10
D-δ-tocopherol 0.04
Phenoxyethanol 0.1
Bengala 13
Yellow iron oxide 5.0
Black iron oxide 2.0
Sorbitan sesquiisostearate 1.0

Claims (7)

A composition for external use on skin, comprising 2-phenoxyethanol and 2-ethyl-1,3-hexanediol. The composition for external skin according to claim 1, wherein the composition for external skin is a cosmetic. An external composition for skin, wherein the cosmetic according to claim 2 is any one of basic cosmetics, makeup cosmetics, and body cosmetics. A composition for external use on the skin, which does not contain parabens in the composition for external use on skin according to claims 1 to 3. The composition for external use of the skin according to any one of claims 1 to 4, wherein the proportion of alcohol in the composition of the skin is 5.0% by mass or less. The composition for external use of the skin according to claim 1, wherein the proportion of 2-phenoxyethanol in the composition is 0.01 to 1.0% by mass. The composition for external use according to claim 1, wherein the proportion of 2-ethyl-1,3-hexanediol in the composition is 0.1 to 5.0% by mass. .