JP3436745B2 - Makeup cosmetics - Google Patents

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to makeup cosmetics. More specifically, it spreads smoothly when applied, making it easy to apply, smells during application, gloss after application, water resistance,
It is a makeup cosmetic that is extremely excellent in oil resistance, adhesion and makeup lasting, especially in the case of lipstick, a coffee cup,
Does not transfer color to clothing, eyeliner, mascara, eyebrow, nail enamel, foundation,
In the case of eye shadows, it relates to makeup cosmetics that do not lose their makeup due to sweat, tears, swimming, sebum, etc.

[0002]

2. Description of the Related Art Conventionally, makeup cosmetics have been classified according to their compositional classification into emulsion type, film type, oil type,
Oily film type and non-aqueous polymer dispersion type are known.

Although many improvements have been made in terms of usability, these makeup cosmetics satisfy all of the odor during application, gloss after application, water resistance, oil resistance, adhesion and makeup lasting. Things have not been disclosed so far,
It had one of the drawbacks.

For example, in the case of an ordinary oily lipstick, although it has a good gloss, it has a problem that the color is transferred to a coffee cup or clothes and the makeup lasts poor with time.

Various investigations have been made so far in order to solve this problem and improve makeup lasting. As an example thereof, JP-A-5-178722 discloses an oil-based solid cosmetic composition (oil-based makeup cosmetic composition, lipstick, foundation) containing one or more polyoxyalkylene-modified organopolysiloxanes and excellent in makeup lasting. , Eye shadows), Japanese Patent Laid-Open No. 6-199630 discloses an anti-slip cosmetic composition containing a volatile solvent, a silicone resin, a wax, a powder, and an oil component (a makeup cosmetic composition applied to the lips and the skin), JP-A-6-298623 discloses that
Lip care cosmetic composition containing a specific alkylmethyl polysiloxane and having excellent durability and abrasion resistance,
No. 17831 discloses a nonionic surfactant obtained by addition polymerization of ethylene oxide, a liquid oil agent containing a perfluoroalkyl group, a liquid oil, a semisolid fat or solid fat, and an oily cosmetic excellent in makeup lasting containing a pigment. (Lipstick), JP-A-7-33622 discloses a polyoxyalkylene-modified silicone, a liquid oil containing a perfluoroalkyl group, a liquid oil, a semi-solid fat or a solid fat, and an oiliness excellent in makeup lasting containing a pigment. Cosmetics (lipsticks) are disclosed. In addition, Japanese Patent Publication No. 61-12884 discloses a cosmetic composition having a non-aqueous polymer dispersion obtained by dispersing a dispersion polymer in an organic medium in which the dispersion polymer is not dissolved, as a film-forming component. Makeup cosmetics (eyeliner, mascara, eyebrow, nail enamel) are disclosed. On the other hand, Japanese Patent Application No. 7-898
Japanese Patent Laid-Open No. 44-44 discloses a cosmetic containing an alkylphenyl polysiloxane and having durability and water resistance, but it does not particularly mention a makeup cosmetic excellent in makeup lasting.

[0006]

However, although these makeup cosmetics have some functions in smell during application, gloss after application, water resistance, oil resistance, and adhesiveness, for example, the makeup of lipstick In this case, it did not exert an excellent effect of holding makeup so as not to transfer color to a coffee cup or clothes.

When the effect of preventing color transfer is good, the gloss is insufficient. Also mascara,
Even an eyeliner does not exert a sufficient effect on good makeup lasting so as not to lose makeup due to sweat, tears, swimming, sebum, etc.

The inventors of the present invention have conducted extensive studies in view of the above circumstances, and as a result, in a makeup cosmetic composition, a non-aqueous polymer dispersion in which a polymer is dispersed in volatile silicone is contained as a film-forming component, by blending methyl trisiloxane thereto, upon application of the odor, gloss after coating, water resistance, oil resistance, excellent adhesion, in particular a cosmetic having, especially with the case of lipstick is good gloss at the same time , Does not transfer color to coffee cups or clothes, and even with eyeliner, mascara, eyebrow, foundation, eye shadow, does not lose makeup due to sweat, tears, swimming, sebum, etc. Then, they found out the finding and completed the present invention.

[0009]

Means for Solving the Problems That is, the present invention provides a non-aqueous polymer dispersion in which a polymer is dispersed in a volatile silicone, and a methyl represented by the following general formula (1).
The non-aqueous polymer containing phenyltrisiloxane
-Dispersion is the total amount of makeup cosmetics
10 to 60 wt% with respect to the methyl phenyl
The amount of trisiloxane is based on the total amount of makeup cosmetics.
The makeup cosmetic is characterized by being 1 to 50% by mass .

[Chemical formula 1] (1) (In the formula, R1 to R8 represent a methyl group or a phenyl group.
You)

The present invention also provides the makeup cosmetic, wherein the polymer is a polymer of acrylic acid ester or methacrylic acid ester, or a copolymer of acrylic acid ester and methacrylic acid ester. To do.

[0011]

The present invention is also represented by the above general formula (1).
Those methylphenyl trisiloxane, provides the makeup cosmetic which is a tetramethyl tetraphenyl trisiloxane or trimethyl pentaphenyl trisiloxane represented by the following general formula (2) or (3) is there.

[Chemical 7] (2)

[Chemical 8] (3)

Further, the present invention is characterized in that the volatile silicone is one or more volatile silicones represented by the following general formula (4) or (5). Is provided.

[Chemical Formula 9] (4)

[Chemical Formula 10] (5)

Furthermore, the present invention further provides the above-mentioned makeup cosmetic, which further comprises dimethylpolysiloxane.

Further, the present invention is characterized by containing one or more kinds of volatile silicones selected from the group consisting of decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane and dodecamethylcyclohexasiloxane. The makeup cosmetics described above are provided.

Furthermore, the present invention further provides the above-mentioned makeup cosmetic, which further comprises glycerin and / or water.

The present invention also provides the makeup cosmetic, wherein the makeup cosmetic is lipstick.

[0018]

BEST MODE FOR CARRYING OUT THE INVENTION The constitution of the present invention will be described in detail below.

The non-aqueous polymer dispersion referred to in the present invention means a resin liquid in which a volatile silicone is used as a medium and a polymer (polymer) is dispersed in the medium, which is usually in a volatile silicone solvent. Can be produced by polymerizing a polymerizable monomer. Any of the polymerizable monomers referred to herein can be used, but in particular,
A radical-polymerizable monomer is preferable, and it can be produced by radical-polymerizing this in a volatile silicone solvent using a radical initiator. It is also possible to stably disperse a polymer polymerized by any method such as anionic polymerization, cationic polymerization, and radical polymerization in a volatile silicone, but the one prepared by the above-mentioned polymerization method has dispersion stability It is preferable from the aspect. The composition ratio of the polymer and the volatile silicone in the non-aqueous polymer dispersion is arbitrary, but is preferably (polymer) :( volatile silicone) = 1: 25 to 6: 1, and more preferably Is in the range of 1: 7 to 2: 1.

The polymer contained in the non-aqueous polymer dispersion contained in the makeup cosmetic composition of the present invention may be of any kind, for example, an ester of acrylic acid or methacrylic acid and an alcohol having 1 to 10 carbon atoms. Polymers having as a monomer, acrylic acid or methacrylic acid silicone ester polymers, polymers such as styrene, α-methylstyrene, vinyl acetate, vinyl propionate, etc. can be used, and they can be homopolymers or copolymers. Although it is good, it is preferably a polymer of acrylic acid ester or methacrylic acid ester, or a copolymer of acrylic acid ester and methacrylic acid ester.

The non-aqueous polymer dispersion is preferably prepared by dispersing sucrose benzoate together with the above polymer in volatile silicone.

The non-aqueous polymer dispersion contained in the makeup cosmetic of the present invention uses a volatile silicone having excellent odor and skin safety properties as a medium in which the polymer is dispersed. The medium is not particularly limited as long as it is a volatile silicone, but the volatile silicones represented by the general formulas (5) and (6) are preferable.

The amount of the non-aqueous polymer dispersion compounded is 10 to 60% by mass based on the total amount of makeup cosmetics.
By weight, more preferably from 25 to 40 wt%. If the blending amount is less than 10% by mass, water resistance, oil resistance, adhesion, and makeup lasting will be poor. Further, if the blending amount exceeds 60% by mass, the ease of application becomes poor, which is not preferable.

In the present invention, it is represented by the above general formula (1).
Is a newly particularly pronounced effect was made result found that exerted invention when been combining particular methyl trisiloxane and a non-aqueous polymer dispersions of the above table by the general formula (1) Specific
Methylphenyltrisiloxane is more preferably
It is tetramethyltetraphenyltrisiloxane or trimethylpentaphenyltrisiloxane represented by the general formula (2) or (3).

Methylphenyl trisiloxy of the general formula (1)
The amount of sun blended is 1 to the total amount of makeup cosmetics.
The amount is in the range of 50% by mass , more preferably 4 to 30% by mass. If it exceeds 50% by mass, the adhesiveness and the makeup last will be poor, which is not preferable.

In the present invention, it is preferable to add dimethylpolysiloxane as a non-volatile oil component. The blending amount is preferably in the range of 5 to 15 mass% with respect to the total amount of makeup cosmetics. Further, the total amount of all the non-volatile oil components in the total amount of makeup cosmetics is preferably 60% by mass or less. Further, the blending amount of dimethylpolysiloxane is preferably larger than the blending amount of methylphenylpolysiloxane of the nonvolatile oil component.

In the present invention, volatile oil components such as decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane and dodecamethylcyclohexasiloxane are preferably blended. The blending amount is preferably 1 to 50 mass% with respect to the total amount of makeup cosmetics.

In the present invention, it is preferable to add glycerin and / or water. The compounding amount is arbitrary. Glycerin and water are preferably emulsified and blended (both may be emulsified and blended, or may be emulsified in the formulation). Glycerin and water are mixed in the formulation at an arbitrary ratio, and a mass ratio of 1: 1 is preferable.

In addition to the above-mentioned essential components, the makeup cosmetic of the present invention can be produced by a conventional method by blending other components depending on the intended makeup cosmetic. For example, powder component, liquid oil, solid oil, wax,
Hydrocarbons, higher fatty acids, higher alcohols, ester oils,
Silicone oil, anionic surfactant, cationic surfactant, amphoteric surfactant, nonionic surfactant, moisturizer, water-soluble polymer, thickener, film agent, ultraviolet absorber, sequestering agent, lower alcohol , Polyhydric alcohols, sugars, amino acids, organic amines, polymer emulsions, pH adjusting agents, skin nutrition agents, vitamins, antioxidants, antioxidant aids, fragrances, water, etc. are appropriately blended as necessary to achieve the purpose. It can be manufactured by a conventional method depending on the dosage form. Specific ingredients that can be mixed are listed below, and the desired makeup cosmetic can be produced by a conventional method by mixing the above-mentioned essential ingredients and any one or more of the following ingredients.

Examples of powder components include inorganic powders (eg, talc, kaolin, mica, sericite,
Muscovite, phlogopite, synthetic mica, phlogopite, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, tungstate metal salt, magnesium, Silica, zeolite, barium sulfate, calcined calcium sulfate (calculated gypsum), calcium phosphate, fluoroapatite, hydroxyapatite, ceramic powder, metal soap (eg, zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc .; organic Powder (for example, polyamide resin powder (nylon powder), polyethylene powder, polymethylmethacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene powder) Powder, cellulose powder, etc .; inorganic white pigment (eg titanium dioxide, zinc oxide etc.); inorganic red pigment (eg iron oxide (red iron oxide), iron titanate etc.); inorganic brown pigment (eg γ-oxidation) Inorganic yellow pigments (eg yellow iron oxide, ocher etc.); Inorganic black pigments (eg black iron oxide, low order titanium oxide etc.); Inorganic purple pigments (eg mango violet, cobalt violet etc.) ); Inorganic green pigments (for example, chromium oxide,
Chromium hydroxide, cobalt titanate, etc .; Inorganic blue pigments (eg, ultramarine blue, navy blue, etc.); Pearl pigments (eg, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica) , Bismuth oxychloride, fish scale foil, etc.); metal powder pigments (eg, aluminum powder,
Copper powder, etc.); organic pigments such as zirconium, barium, or aluminum lakes (eg, red 201
No. 202, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 228, Red No. 405
No. 203, Orange No. 203, Orange No. 204, Yellow No. 205, Yellow No. 401, Blue No. 404, and other organic pigments, Red 3
Red No. 104, Red No. 106, Red No. 227, Red No. 230, Red No. 401, Red No. 505, Orange No. 205
No., Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203
No. 3, Green No. 3, Blue No. 1, etc.); natural pigments (eg, chlorophyll, β-carotene, etc.) and the like.

Examples of liquid oils and fats include avocado oil,
Camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern oil, castor oil, linseed oil, safflower oil, cottonseed oil, eno oil, Soybean oil, peanut oil, teaseed oil, kaya oil, rice bran oil, cinnamon oil, Japanese tung oil, jojoba oil, germ oil, triglycerin and the like can be mentioned.

Examples of solid fats and oils include cocoa butter, coconut oil, horse fat, hardened coconut oil, palm oil, beef tallow, sheep fat, hardened beef tallow, palm kernel oil, lard, beef bone oil, sorghum kernel oil, and hardened oil. Examples thereof include oil, beef tallow, owl, hydrogenated castor oil, and the like.

Examples of the wax include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax,
Ibotaro, whale wax, montan wax, nukarou, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, P
OE Lanolin alcohol acetate, POE cholesterol ether, Lanolin fatty acid polyethylene glycol, PO
E Hydrogenated lanolin alcohol ether and the like can be mentioned.

Examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax and the like.

Examples of the higher fatty acid include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, tolic acid, isostearic acid, linoleic acid, linoleic acid, eicosapentaenoic acid (EPA), Docosahexaenoic acid (DHA)
Etc.

Examples of higher alcohols include straight chain alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, etc.); branched chain alcohols (eg, monostearyl glycerin ether). (Batyl alcohol), 2-
Decyltetradecinol, lanolin alcohol, cholesterol, phytosterols, hexyldecanol,
(Isostearyl alcohol, octyldodecanol, etc.)
Etc.

As the ester oil, isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyloctanoate,
Cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, dicapric acid Neopentyl glycol, diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexanoate, trimethylolpropane triisostearate, pentaerythritol tetra-2-ethylhexanoate, tri-
Glycerin 2-ethylhexanoate, glyceryl trioctanoate, glyceryl triisopalmitate, trimethylolpropane triisostearate, cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, glyceryl trimyristate, tri-2-heptylundecanoate Glyceride, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid-2-octyldodecyl ester, di-2-heptylundecyl adipate , Ethyl laurate,
Examples include di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, triethyl citrate and the like.

Examples of the silicone oil include linear polysiloxanes (eg, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (eg, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, etc.). Dodecamethylcyclohexasiloxane, etc.) Silicone resin having a three-dimensional network structure, silicone rubber, various modified polysiloxanes (amino modified polysiloxane, polyether modified polysiloxane, alkyl modified polysiloxane, fluorine modified polysiloxane, etc.) Etc.

Examples of the anionic surfactant include fatty acid soap (eg sodium laurate, sodium palmitate etc.); higher alkyl sulfate ester salt (eg sodium lauryl sulfate, potassium lauryl sulfate etc.); alkyl ether sulfate ester salt. (For example,
POE-triethanolamine lauryl sulfate, POE-sodium lauryl sulfate, etc.); N-acyl sarcosinic acid (eg,
Lauroyl sarcosine sodium, etc .; Higher fatty acid amide sulfonate (eg, N-myristoyl-N-methyl taurine sodium, coconut oil fatty acid methyl tauride sodium, lauryl methyl tauride sodium, etc.); Phosphate ester salt (POE-oleyl ether) Sodium phosphate, POE-stearyl ether phosphoric acid, etc.); sulfosuccinate (eg, sodium di-2-ethylhexyl sulfosuccinate, monolauroyl monoethanolamide sodium polyoxyethylene sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, etc.);
Alkylbenzene sulfonates (for example, sodium linear dodecylbenzene sulfonate, triethanolamine linear dodecyl benzene sulfonate, linear dodecyl benzene sulfonic acid, etc.); higher fatty acid ester sulfate ester salts (for example, hardened coconut oil fatty acid glycerin sodium sulfate, etc.); N-acyl glutamate (eg, monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate, N-myristoyl-L-monosodium glutamate, etc.); sulfated oil (eg, funnel oil, etc.); POE-alkyl ether carvone Acid; POE-alkyl allyl ether carboxylate; α-olefin sulfonate; higher fatty acid ester sulfonate; secondary alcohol sulfate ester salt; higher fatty acid alkylolamide sulfate salt; lauroyl mono Ethanolamide sodium succinate; N-palmitoyl aspartic acid ditriethanolamine; sodium caseinate and the like.

Examples of the cationic surfactant include alkyl trimethyl ammonium salts (eg stearyl trimethyl ammonium chloride, lauryl trimethyl ammonium chloride, etc.); alkyl pyridinium salts (eg
Cetylpyridinium chloride, etc.); Distearyldimethylammonium dialkyldimethylammonium chloride; Poly (N, N'-dimethyl-3,5-methylenepiperidinium) chloride;
Alkyl quaternary ammonium salts; Alkyl dimethyl benzyl ammonium salts; Alkyl isoquinolinium salts; Dialkyl morphonium salts; POE-alkyl amines; Alkyl amine salts; Polyamine fatty acid derivatives; Amyl alcohol fatty acid derivatives; Benzalkonium chloride; Benzethonium chloride Etc.

As the amphoteric surfactant, for example, an imidazoline-based amphoteric surfactant (eg, 2-undecyl-N, N, N) is used.
-(Hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide-1-carboxyethyloxy disodium salt, etc .; betaine surfactant (eg, 2-heptadecyl-N- Carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkyl betaine, amidobetaine, sulfobetaine, etc.) and the like.

Examples of lipophilic nonionic surfactants include sorbitan fatty acid esters (eg, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquis). Oleate, sorbitan trioleate, penta-2-ethylhexyl diglycerol sorbitan, tetra-2-ethylhexyl diglycerol sorbitan, etc.); glycerin polyglycerin fatty acids (eg monocotton oil fatty acid glycerin, monoerucic acid glycerin, sesquioleate glycerin) , Glyceryl monostearate, α, α '
-Glycerin oleate pyroglutamate, glyceryl monostearate malic acid, etc.); propylene glycol fatty acid esters (eg, propylene glycol monostearate etc.); hydrogenated castor oil derivative; glycerin alkyl ether and the like.

Examples of hydrophilic nonionic surfactants include POE-sorbitan fatty acid esters (eg, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate). Etc.); POE sorbit fatty acid esters (eg, POE-sorbit monolaurate, POE-sorbit monooleate, POE-sorbit pentaoleate, POE-sorbit monostearate, etc.); POE-glycerin fatty acid esters (eg, POE-glycerin monostearate, POE-glycerin monoisostearate, PO
E-glycerin triisostearate and other POE-monooleates, etc .; POE-fatty acid esters (eg, POE-distearate, POE-monodioleate, ethylene glycol distearate, etc.); POE-alkyl ethers (eg, POE-lauryl ether) , POE-oleyl ether, PO
E-stearyl ether, POE-behenyl ether, POE-2-
Octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic types (eg, Pluronics); POE / POP-alkyl ethers (eg, POE / PO)
P-cetyl ether, POE ・ POP-2-decyl tetradecyl ether, POE ・ POP-monobutyl ether, POE ・ POP-hydrogenated lanolin, POE ・ POP-glycerin ether, etc.); Tetra P
OE / tetra-POP-ethylenediamine condensates (eg, Tetronic); POE-castor oil hydrogenated castor oil derivatives (eg, POE-castor oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE -Cured castor oil triisostearate, POE-cured castor oil monopyroglutamic acid monoisostearate diester, POE-cured castor oil maleic acid, etc .; POE-beeswax lanolin derivative (for example, POE-sorbit beeswax, etc.); alkanolamide (For example, coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid ester; PO
Examples include E-alkylamines; POE-fatty acid amides; sucrose fatty acid esters; alkylethoxydimethylamine oxides; trioleylphosphoric acid.

Examples of moisturizers include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-. Examples thereof include hydroxystearate, sodium lactate, bile salts, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adducts, Isaioba rose extract, Yarrow millet extract, Merrilot extract and the like.

Examples of natural water-soluble polymers include plant-based polymers (eg, gum arabic, tragacanth, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (quince), algecoloid (cassou extract). ), Starch (rice, corn, potato, wheat), glycyrrhizic acid); microbial macromolecules (eg, xanthan gum, dextran, succinoglucan, vullan, etc.); animal macromolecules (eg, collagen, casein,
Albumin, gelatin, etc.) and the like.

As the semi-synthetic water-soluble polymer, for example,
Starch-based polymers (for example, carboxymethyl starch, methyl hydroxypropyl starch, etc.); Cellulose-based polymers (methyl cellulose, ethyl cellulose, methyl hydroxypropyl cellulose, hydroxyethyl cellulose, sodium cellulose sulfate, hydroxypropyl cellulose, carboxymethyl cellulose, carboxymethyl cellulose sodium, Crystalline cellulose,
Cellulose powder, etc.); alginic acid-based polymers (eg, sodium alginate, propylene glycol alginate, etc.) and the like.

As the synthetic water-soluble polymer, for example, vinyl-based polymer (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinylpyrrolidone, carboxyvinyl polymer, etc.); polyoxyethylene-based polymer (eg, polyethylene glycol 20,000, 40,000, 6
Examples include polyoxyethylene-polyoxypropylene copolymers of 0,000); acrylic polymers (eg, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethyleneimine; cationic polymers and the like.

Examples of the thickener include gum arabic,
Carrageenan, karaya gum, tragacanth gum, carob gum, quince seed (quince), casein, dextrin, gelatin, sodium pectate, sodium alginate, methyl cellulose, ethyl cellulose,
CMC, hydroxyethyl cellulose, hydroxypropyl cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, dialkyldimethylammonium sulfate cellulose, xanthan gum, magnesium aluminum silicate, bentonite,
Hectorite, silicic acid A1Mg (veegum), laponite, silicic acid anhydride and the like can be mentioned.

Examples of the ultraviolet absorber include benzoic acid type ultraviolet absorbers (for example, para-aminobenzoic acid (hereinafter, P
Abbreviated as ABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N- Dimethyl PABA ethyl ester, etc.); Anthranilic acid type ultraviolet absorber (eg, homomenthyl-N-acetylanthranilate etc.); Salicylic acid type ultraviolet absorber (eg, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate) , Benzyl salicylate, p-isopropanolphenyl salicylate, etc.); cinnamic acid-based UV absorbers (eg, octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-)
2,5-diisopropylcinnamate, ethyl-2,4-diisopropylcinnamate, methyl-2,4-diisopropylcinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate Mate, octyl-p-methoxycinnamate
(2-ethylhexyl-p-methoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate, cyclohexyl-
p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexanoyl-diparamethoxycinnamate, etc.); benzophenone UV absorbers (for example, 2,4-dihydroxybenzophenone, 2,2'-dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2,2 ', 4,4' -Tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-
Methoxy-4'-methylbenzophenone, 2-hydroxy-4-
Methoxybenzophenone-5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone Etc.); 3- (4'-methylbenzylidene) -d, l-
Camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5-
Methylphenylbenzotriazole; 2- (2'-hydroxy
-5'-t-octylphenyl) benzotriazole; 2- (2'-
Hydroxy-5'-methylphenylbenzotriazole;dibenzalazine;dianisoylmethane;4-methoxy-4'-t-
Butyldibenzoylmethane; 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one and the like can be mentioned.

Examples of the sequestering agent include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, edetate disodium, edetate trisodium, and edet. Tetrasodium acid, sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid,
Examples thereof include ascorbic acid, succinic acid, edetic acid, trisodium ethylenediamine hydroxyethyl triacetate and the like.

Examples of the lower alcohol include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

Examples of the polyhydric alcohol include dihydric alcohols (for example, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-). Butylene glycol, pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trivalent alcohol (eg, glycerin, trimethylolpropane, etc.);
Tetrahydric alcohol (eg, pentaerythritol such as 1,2,6-hexanetriol); pentahydric alcohol (eg, xylitol); hexahydric alcohol (eg, sorbitol, mannitol); polyhydric alcohol polymer (eg, , Diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene glycol, tetraethylene glycol, diglycerin, polyethylene glycol, triglycerin, tetraglycerin, polyglycerin, etc.); divalent alcohol alkyl ethers (for example, ethylene glycol monomethyl ether, Ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol Cole mono 2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, etc .; Dihydric alcohol alkyl ethers (for example, diethylene glycol monomethyl) Ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, pro Pyrene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether,
Dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol butyl ether, etc.); dihydric alcohol ether ester (eg, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl) Ether acetate, ethylene glycol diabate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate , Propylene glycol monophenyl ether acetate); glycerol monoalkyl ethers (e.g., hexyl alcohol, selachyl alcohol, batyl alcohol); sugar alcohols (e.g.,
Sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, starch-decomposing sugar, maltose, xylitose, starch-decomposing sugar reducing alcohol, etc.); Glysolid; Tetrahydrofurfuryl alcohol; POE-Tetrahydrofur Furyl alcohol; POP-butyl ether;
POP / POE-butyl ether; tripolyoxypropylene glycerin ether; POP-glycerin ether; POP-glycerin ether phosphoric acid; POP / POE-pentane erythritol ether, polyglycerin and the like.

As the monosaccharide, for example, tricarbose (for example,
D-glyceryl aldehyde, dihydroxyacetone, etc.);
Four-carbon sugar (for example, D-erythrose, D-erythrulose,
D-threose, erythritol, etc.); pentoses (eg,
L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc .; hexose (eg, D-glucose, D-talose, D- Bucose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose and the like); heptacarbon sugar (for example, aldoheptose, heprose and the like); octose sugar (for example, octulose and the like); deoxy sugar (for example, , 2-deoxy-D-ribose, 6-deoxy-L-
Galactose, 6-deoxy-L-mannose, etc.); Amino sugar (eg, D-glucosamine, D-galactosamine, sialic acid, aminouronic acid, muramic acid, etc.); Uronic acid (eg, D-glucuronic acid, D-mannuronic acid) , L-guluronic acid, D-galacturonic acid, L-iduronic acid, etc.) and the like.

Examples of the oligosaccharides include sucrose, gnthianose, umbelliferose, lactose, planteose, isoliknoses, α, α-trehalose, raffinose, licnose, umbilicin, stachyose verbascose and the like.

Examples of the polysaccharides include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum and dextran. , Keratosulfate, locust bingham, succinoglucan, caronic acid and the like.

Examples of amino acids include neutral amino acids (eg threonine, cysteine etc.); basic amino acids (eg hydroxylysine etc.) and the like. Examples of the amino acid derivative include sodium acyl sarcosine (sodium lauroyl sarcosine), acyl glutamate, sodium β-alanine acyl, glutathione, and pyrrolidone carboxylic acid.

Examples of the organic amine include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-methyl-1. -Propanol and the like can be mentioned.

As the polymer emulsion, for example, acrylic resin emulsion, polyethyl acrylate emulsion, acrylic resin liquid, polyacrylic alkyl ester emulsion, polyvinyl acetate resin emulsion,
Examples thereof include natural rubber latex.

Examples of the pH adjusting agent include lactic acid-sodium lactate, citric acid-sodium citrate, succinic acid-
Examples include buffering agents such as sodium succinate.

Examples of vitamins include vitamins A, B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, biotin and the like.

Examples of the antioxidant include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.

As the antioxidant aid, for example, phosphoric acid,
Examples thereof include citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid and ethylenediaminetetraacetic acid.

Other ingredients that can be mixed are, for example,
Antiseptic (ethyl paraben, butyl paraben, etc.); anti-inflammatory agent (eg, glycyrrhizic acid derivative, glycyrrhetinic acid derivative, salicylic acid derivative, hinokitiol, zinc oxide, allantoin, etc.); whitening agent (eg placenta extract,
Yukinoshita extract, arbutin, etc.); Various extracts (for example, pearl oyster, citrus, peony, cembly, birch, sage, loquat, carrot, aloe, mallow, iris, grape, yokuinin, loofah, lily,
Saffron, Senkyu, Showkyu, Hypericum,
Ononis, garlic, capsicum, chimpi, touki, seaweed, etc.), activator (eg, royal jelly, photosensitizer, cholesterol derivative, etc.); blood circulation promoter (eg, nonyl acid warenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester (Ester, capsaicin, zingerone, cantharisin tincture, ictamol, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthin, γ-oryzanol); Leaks (eg, sulfur, thiantol, etc.); Anti-inflammatory agents (eg, tranexamic acid, thiotaurine, hypotaurine, etc.)
Etc.

The make-up cosmetic composition of the present invention may have any dosage form, for example, a solid form, a semi-solid form or a liquid form, and a W / O emulsion system is also possible.

Especially when the make-up cosmetic composition of the present invention is a lipstick, the make-up cosmetic composition exhibits good gloss and at the same time exhibits an extremely excellent effect of preventing color transfer to a coffee cup or clothes.
Even in the case of eyeliner, mascara, eyebrow, foundation, and eye shadow, it exerts an extremely excellent effect of preventing makeup from being damaged by sweat, tears, swimming, sebum, etc.

[0066]

EXAMPLES The present invention will be described in more detail with reference to Examples and Comparative Examples. The invention is not limited to the examples described below. The unit of the blending amount is% by mass. The non-aqueous polymer dispersion used in Examples and Comparative Examples was manufactured by the following method. the above
Trimethyl pentaphenyl trisiloxa of the general formula (3)
Was used. As the other components, those commercially available as raw materials for cosmetics were used.

Production of "Non-Aqueous Polymer Dispersion A" Methyl methacrylate monomer 15%, ethyl acrylate monomer 25%, polymerization initiator 0.1%, dispersion stabilizer dimethylpolysiloxane graft polymer (molecular weight about 1
50,000) 5% was added to 54.9% of the dispersion medium decamethylcyclopentasiloxane (n = 5 in the general formula (4)).
Polymerization was carried out by stirring at 120 ° C. for 10 hours. Then, after demonomerization is performed under reduced pressure, the mixture is cooled to 25 ° C. and the appearance is milky white and the average particle diameter of the dispersion polymer particles is 1 μm.
A non-aqueous polymer dispersion A having m as a dispersion medium was obtained.

Production of "Non-Aqueous Polymer Dispersion B" Methyl methacrylate monomer 10%, ethyl acrylate monomer 15%, methacrylic acid silicone ester monomer 5%, sucrose benzoate ester (of 8 hydrogen atoms of hydroxyl group of sucrose) A solution of 6.5 to 8 of which substituted by benzoyl groups) in ethyl acetate (weight ratio 1: 1) 1
5%, a polymerization initiator 0.1%, a dispersion stabilizer dimethylpolysiloxane graft polymer (molecular weight about 100,000) 5% as a dispersion medium decamethylcyclopentasiloxane (n = 5 in the general formula (4)) 49 0.99% and added at 120 ° C for 10
Polymerization was carried out by stirring for a time. Then, after demonomerization and deethyl acetate treatment under reduced pressure, the mixture is cooled to 25 ° C. and the appearance is milky white and the average particle size of the dispersion polymer particles is 0.
A non-aqueous polymer dispersion B containing 6 μm of volatile silicone as a dispersion medium was obtained.

Production of "Non-Aqueous Polymer Dispersion C" The dispersion medium decamethylcyclopentasiloxane used in the above non-aqueous polymer dispersion B was changed to octamethylcyclotetrasiloxane (n = 4 in the general formula (4)). A non-aqueous polymer dispersion C was obtained with the same composition and process as B except for the substitution.

[Examples 1 to 16] [Comparative Examples 1 to 7] Each prescription component shown in "Table 1""Table2""Table3" was added at 85 ° C.
The mixture was heated to 1, mixed with stirring, filled in an airtight lipstick container, and cooled at 5 ° C to obtain a lipstick composition. The obtained lipstick composition was subjected to the following tests and evaluated according to the following evaluation criteria.

The lipsticks of Examples and Comparative Examples were subjected to the following tests and evaluated according to the following evaluation criteria.

<Evaluation criteria> ⊚: Evaluation value (average value) of 4.5 or more ◯: Evaluation value (average value) of 3.5 or more and less than 4.5 Δ: Evaluation value (average value) 2.5 or more and less than 3.5 X: Evaluation value (average value) of 1.5 or more and less than 2.5 XX: Evaluation value (average value) of 1.0 or more and less than 1.5

A panel (20 people) specialized in "Tsuya" was asked to use the compositions (samples) for lipstick of each Example and Comparative Example,
The luster (5 minutes to 3 hours after coating) was evaluated functionally on a five-level scale (comprehensive evaluation), and the average value was used for the evaluation. <5-level evaluation> 1: No gloss 2: Less gloss 3: Normal gloss 4: Some gloss 5: Some gloss

A panel (20 persons) specialized in "stickiness" was asked to use the compositions (samples) for lipstick of each Example and Comparative Example, and the stickiness (immediately after application to 3 hours) was evaluated on a sensory level by 5 levels ( (Comprehensive evaluation) and evaluated by the average value. <5-level evaluation> 1: Very sticky 2: Sticky 3: Sticky normal 4: Slightly sticky 5: Not sticky

Special panel for "adhesion to cups" (2
0 people) used the compositions (samples) for lipstick of each Example and Comparative Example, and evaluated the adhesion to the cup (20 minutes after application and 2 hours after application) by sensory evaluation (total evaluation). The average value was evaluated. <5-level evaluation> 1: Sticky 2: Sticky 3: Fairly light 4: Slightly sticky 5: Not sticky

A panel (20 persons) specialized in "makeup mochi" was asked to use the compositions (samples) for lipstick of each of the Examples and Comparative Examples, and the cosmetic mochi was evaluated organoleptically by five levels (comprehensive evaluation), The average value was evaluated. <Evaluation criteria> 1: Bad 2: Slightly bad 3: Normal 4: Fairly good 5: Good

[0077]

[Table 1]

[0078]

[Table 2]

[0079]

[Table 3]

Other examples of the present invention will be described below.
The fluorine-modified methylphenyl polysiloxane has the following general formula (6): a = 2, l = 8, m = 6, n = 40,
Rf = perfluoroalkyl group having 8 carbon atoms was used. The alkoxy-modified silicone used in the following general formula (7) was an alkoxy group having X = 100, Y = 80, and OR = C18.

[Chemical formula 11] (6)

[Chemical 12] (7)

[0081] Example 13 Liquid type lipstick (Ingredients) Trimethylpentaphenyltrisiloxane 10 Non-aqueous polymer dispersion A 30 Decamethylcyclopentasiloxane 35 Glyceryl 2-ethylhexanoate 15 Polyether modified silicone 5 Colorant 5

[0082] Example 14 Cream-type lipstick composition (Ingredients) Trimethylpentaphenyltrisiloxane 10 Fluorine modified methylphenyl polysiloxane 25 Non-aqueous polymer dispersion A 30 Decamethylcyclopentasiloxane 15 Dimethyl polysiloxane 5 Alkoxy-modified silicone 2 Ceresin wax 3 Polyether modified silicone 5 Colorant 5

[0083] Example 15 Eyeliner (Ingredients) Non-aqueous polymer dispersion A 25 Paraffin wax 2 Bentonite 3 Carbon black 2 Extender pigment 30 Octamethylcyclotetrasiloxane 18 Trimethylpentaphenyltrisiloxane 10 Fluorine modified methylphenyl polysiloxane 10 Fragrance suitable amount

[0084] Example 16 Mascara (Ingredients) Non-aqueous polymer dispersion B 42 Paraffin wax 3 Candelilla Row 2 Liquid lanolin 3 Black iron oxide 8 Talc 7 Octamethylcyclotetrasiloxane 13 Trimethylpentaphenyltrisiloxane 10 Fluorine modified methylphenyl polysiloxane 10 Alkoxy-modified silicone 2 Fragrance suitable amount

[0085]

[0086] Example 18 Foundation (Ingredients) Non-aqueous polymer dispersion A 35 Paraffin wax 4 Microcrystalline wax 6 Dimethyl polysiloxane (6CS) 10 Titanium dioxide 10 Red iron oxide 1 Yellow iron oxide 3 Black iron oxide 0.2 Mica 10 Decamethylcyclopentasiloxane 10.8 Trimethylpentaphenyltrisiloxane 5 Fluorine modified methylphenyl polysiloxane 5 Fragrance suitable amount

[0087] Example 19 Eye shadow (Ingredients) Non-aqueous polymer dispersion A 35 Trimethylpentaphenyltrisiloxane 10 Fluorine modified methylphenyl polysiloxane 10 Ceresin wax 10 Candelilla Row 2 Decamethylcyclopentasiloxane 18 Methylphenyl polysiloxane (15CS) 7 Gunjo 5 Titanium dioxide 3 Fragrance suitable amount

Example 20 Stick-shaped lipstick (blending component) trimethylpentaphenyltrisiloxane 5 Non-aqueous polymer emulsion 30 Fluorine-modified methylphenylpolysiloxane 25 Decamethylcyclopentasiloxane 5 Dimethylpolysiloxane 10 Polyether-modified silicone 5 Glycerin 3 Coloring agent 5 Ceresin wax 10 Candelilla wax 2

Example 21 Stick-shaped lipstick (blending component) trimethylpentaphenyltrisiloxane 5 Non-aqueous polymer emulsion 30 Fluorine-modified methylphenylpolysiloxane 25 Decamethylcyclopentasiloxane 5 Dimethylpolysiloxane 10 Polyether-modified silicone 5 Glycerin 1.5 Water 1.5 Coloring agent 5 Ceresin wax 10 Candelilla wax 2

[0090]

The makeup cosmetic of the present invention contains a non-aqueous polymer dispersion in which a polymer is dispersed in a volatile silicone and a specific methylphenyltrisiloxane, so that the gloss, stickiness and adhesion after application are particularly high. It has a particularly remarkable effect on sex and makeup lasting.

─────────────────────────────────────────────────── ─── Continuation of front page (72) Inventor Katsuyuki Kaneko 2-2-1, Hayabuchi, Tsuzuki-ku, Yokohama-shi, Kanagawa Shiseido Research Center (Shin-Yokohama) (72) Fumitaka Sato Hayabuchi, Tsuzuki-ku, Yokohama 2-2-1 Shiseido Research Center (Shin-Yokohama) (72) Inventor Kazunori Yamazaki 2-2-1, Hayabuchi, Tsuzuki-ku, Yokohama-shi, Kanagawa Shiseido Research Center (Shin-Yokohama) (72) Inventor Soyama Miwa 2-2-1, Hayabuchi, Tsuzuki-ku, Yokohama, Kanagawa Prefecture, Shiseido Research Center (Shin-Yokohama) (56) References JP-A-8-269332 (JP, A) JP-A-10-87435 (JP, A) JP-A-10-59827 (JP, A) JP-A-10-218750 (JP, A) (58) Fields investigated (Int. Cl. ⁷ , DB name) A61K 7/00-7 / 050

Claims (8)

(57) [Claims] 1. A non-aqueous polymer dispersion in which a polymer is dispersed in volatile silicone, and the following general formula (1):
Containing methylphenyltrisiloxane represented by
The blending amount of the non-aqueous polymer dispersion is
It is a 10 to 60% by weight, based on the cap the total amount of the cosmetic, before
The amount of methyl phenyl trisiloxane compounded is
The makeup cosmetic is characterized in that it is 1 to 50 mass% with respect to the total amount of the makeup cosmetic. [Chemical formula 1] (1) (In the formula, R1 to R8 represent a methyl group or a phenyl group.
You) 2. The makeup cosmetic according to claim 1, wherein the polymer is a polymer of acrylic acid ester or methacrylic acid ester, or a copolymer of acrylic acid ester and methacrylic acid ester. 3. A methylphene represented by the general formula (1).
Nyltrisiloxane is represented by the following general formula (2) or (3)
The makeup cosmetic according to claim 1 or 2 , which is tetramethyltetraphenyltrisiloxane or trimethylpentaphenyltrisiloxane represented by: [Chemical 2] (2) [Chemical formula 3] (3) Wherein said volatile silicone is represented by the following general formula (4) or (5) according to claim 1 and one or characterized in that two or more kinds of volatile silicone represented until
Or makeup cosmetics described in 3 . [Chemical 4] (4) [Chemical formula 5] (5) 5. Furthermore, according to claim 1, 2, 3 or 4 makeup cosmetic according to characterized in that it contains a dimethylpolysiloxane. 6. Furthermore, claim, characterized in that it contains decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, one or two or more of the volatile silicones selected from the group consisting of dodecamethylcyclohexasiloxane The makeup cosmetic according to 1, 2, 3, 4 or 5 . 7. Furthermore, according to claim 2, 3, 4, 5 or, characterized in that blending of glycerin and / or water
Makeup cosmetics as described in 6 . Wherein said make-up cosmetic, is a lipstick
Claims 1, 2, 3, 4, 5, 6 or
7. Makeup cosmetics described in 7 .