JP2014129297A - Water-in-oil type solid emulsion cosmetic - Google Patents
Water-in-oil type solid emulsion cosmetic Download PDFInfo
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- JP2014129297A JP2014129297A JP2012288602A JP2012288602A JP2014129297A JP 2014129297 A JP2014129297 A JP 2014129297A JP 2012288602 A JP2012288602 A JP 2012288602A JP 2012288602 A JP2012288602 A JP 2012288602A JP 2014129297 A JP2014129297 A JP 2014129297A
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- 239000003755 preservative agent Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000001057 purple pigment Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 229940112950 sage extract Drugs 0.000 description 1
- 235000020752 sage extract Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 229910052917 strontium silicate Inorganic materials 0.000 description 1
- QSQXISIULMTHLV-UHFFFAOYSA-N strontium;dioxido(oxo)silane Chemical compound [Sr+2].[O-][Si]([O-])=O QSQXISIULMTHLV-UHFFFAOYSA-N 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- LINXHFKHZLOLEI-UHFFFAOYSA-N trimethyl-[phenyl-bis(trimethylsilyloxy)silyl]oxysilane Chemical compound C[Si](C)(C)O[Si](O[Si](C)(C)C)(O[Si](C)(C)C)C1=CC=CC=C1 LINXHFKHZLOLEI-UHFFFAOYSA-N 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 1
- 229940099259 vaseline Drugs 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Abstract
Description
本発明は、油中水型固形乳化化粧料に関する。 The present invention relates to a water-in-oil solid emulsified cosmetic.
油中水型固形乳化化粧料は、油中水型乳化化粧料の滑らかな感触を備え、固形状であることから使いやすさや持ち運び等の使用性も良好であるため、近年、注目を浴びている剤型である。油中水型乳化化粧料を固形状にするためにワックスが使用されることが多いが（特許文献１〜２）、固形の状態を安定に保つためにワックスの含有量を高めた場合には、表面が固くなりすぎて、使用する際に容器等から化粧料が取れにくくなることがあった。一方、表面を柔らかくするためにワックスの含有量を低くした場合には、保存安定性が不十分となり固形状態を安定に保つことが難しくなることがあった。 In recent years, water-in-oil solid emulsified cosmetics have attracted attention because they have the smooth feel of water-in-oil emulsified cosmetics, and are solid and easy to use and carry. The dosage form. Wax is often used to make water-in-oil emulsified cosmetics solid (Patent Documents 1 and 2), but when the content of wax is increased in order to keep the solid state stable, In some cases, the surface becomes too hard to make it difficult to remove the cosmetic from the container or the like. On the other hand, when the wax content is lowered in order to soften the surface, the storage stability is insufficient and it may be difficult to keep the solid state stable.
そして、油中水型固形乳化化粧料には、ワックスとともに無機粉体や有機粉体が一般に配合されているが、これら粉体の含有量を高めた場合、保存安定性を満足させ、且つ表面を柔らかくし化粧料の「取れ」を良くすることは非常に難しかった。
したがって、本発明は、粉体を高濃度で含むにも拘わらず、保存安定性に優れ、且つ表面が柔らかで「取れ」の良好な油中水型固形乳化化粧料に関する。
And, in water-in-oil solid emulsified cosmetics, inorganic powders and organic powders are generally blended together with wax. When the content of these powders is increased, the storage stability is satisfied, and the surface It was very difficult to soften the skin and improve the cosmetics.
Therefore, the present invention relates to a water-in-oil solid emulsified cosmetic that is excellent in storage stability, has a soft surface, and has good “take off” despite containing a high concentration of powder.
そこで、本発明者は、特定の多価アルコール脂肪酸エステル型界面活性剤、及び架橋型シリコーンエラストマーとともに、特定量の鉱物性ワックスを組み合わせて用いることによって、意外にも、粉体を高濃度で含むにも拘わらず、保存安定性に優れ、且つ表面が柔らかで「取れ」の良好な油中水型固形乳化化粧料が得られることを見出し、本発明を完成した。 Therefore, the inventor unexpectedly contains a high concentration of powder by using a specific amount of mineral wax in combination with a specific polyhydric alcohol fatty acid ester type surfactant and a cross-linked silicone elastomer. Nevertheless, the inventors have found that a water-in-oil solid emulsified cosmetic having excellent storage stability, soft surface and good “take off” can be obtained, and the present invention has been completed.
すなわち、本発明は、以下の成分（Ａ）〜（Ｄ）を含有する油中水型固形乳化化粧料を提供するものである。
（Ａ）ＨＬＢ値６以下であり、２５℃で液状の多価アルコール脂肪酸エステル型界面活性剤
（Ｂ）鉱物性ワックス：１．５〜５質量％
（Ｃ）架橋型シリコーンエラストマー
（Ｄ）粉体：３５〜５５質量％
That is, the present invention provides a water-in-oil type solid emulsified cosmetic containing the following components (A) to (D).
(A) Polyhydric alcohol fatty acid ester type surfactant having an HLB value of 6 or less and liquid at 25 ° C. (B) Mineral wax: 1.5 to 5% by mass
(C) Cross-linked silicone elastomer (D) Powder: 35-55% by mass
本発明の油中水型固形乳化化粧料は、粉体を高濃度で含むにも拘わらず、保存安定性に優れ、且つ表面が柔らかで「取れ」が良好である。 The water-in-oil solid emulsified cosmetic of the present invention is excellent in storage stability, has a soft surface, and has good “take off” despite containing a high concentration of powder.
本発明の油中水型固形乳化化粧料は、成分（Ａ）〜（Ｄ）を含有するものである。 The water-in-oil solid emulsified cosmetic of the present invention contains components (A) to (D).
＜成分（Ａ）＞
本発明の成分（Ａ）は、ＨＬＢ値６以下であり、２５℃で液状の多価アルコール脂肪酸エステル型界面活性剤である。
上記多価アルコール脂肪酸エステル型界面活性剤を構成する多価アルコールは、２価以上のアルコールであればよいが、３〜６価のアルコールが好ましく、３〜５価のアルコールがより好ましい。
上記多価アルコールとしては、ソルビタン、ソルビトール、ショ糖、グリセリン、ポリグリセリン、エチレングリコール、ポリエチレングリコール、プロピレングリコール、ポリプロピレングリコール等が挙げられる。これらの中でも、ソルビタン、グリセリン、ポリグリセリンが好ましく、ソルビタン、グリセリン、ジグリセリンがより好ましく、ソルビタンが更に好ましい。
<Component (A)>
Component (A) of the present invention is a polyhydric alcohol fatty acid ester type surfactant having an HLB value of 6 or less and liquid at 25 ° C.
Although the polyhydric alcohol which comprises the said polyhydric alcohol fatty acid ester type surfactant should just be bivalent or more alcohol, 3-6 valent alcohol is preferable and 3-5 valent alcohol is more preferable.
Examples of the polyhydric alcohol include sorbitan, sorbitol, sucrose, glycerin, polyglycerin, ethylene glycol, polyethylene glycol, propylene glycol, and polypropylene glycol. Among these, sorbitan, glycerol, and polyglycerol are preferable, sorbitan, glycerol, and diglycerol are more preferable, and sorbitan is still more preferable.
上記多価アルコール脂肪酸エステル型界面活性剤を構成する脂肪酸としては、炭素数６〜２２の飽和又は不飽和の脂肪酸が好ましく、炭素数８〜２０の飽和又は不飽和の脂肪酸がより好ましく、１２〜２０の飽和又は不飽和の脂肪酸が更に好ましく、炭素数１４〜２０の飽和又は不飽和の脂肪酸が更に好ましく、炭素数１６〜２０の飽和又は不飽和の脂肪酸が更に好ましい。また、該飽和脂肪酸、不飽和脂肪酸のうち飽和脂肪酸が好ましい。また、該脂肪酸は直鎖脂肪酸でも分岐脂肪酸でもよいが分岐脂肪酸が好ましい。 As a fatty acid which comprises the said polyhydric alcohol fatty acid ester type surfactant, a C6-C22 saturated or unsaturated fatty acid is preferable, a C8-C20 saturated or unsaturated fatty acid is more preferable, 12- A saturated or unsaturated fatty acid having 20 carbon atoms is more preferable, a saturated or unsaturated fatty acid having 14 to 20 carbon atoms is more preferable, and a saturated or unsaturated fatty acid having 16 to 20 carbon atoms is further preferable. Of these saturated fatty acids and unsaturated fatty acids, saturated fatty acids are preferred. The fatty acid may be a linear fatty acid or a branched fatty acid, but a branched fatty acid is preferred.
また、上記多価アルコール脂肪酸エステル型界面活性剤としては、多価アルコールの水酸基の部分エステル化物が好ましく、モノエステル化物、ジエステル化物がより好ましく、表面が柔らかくし「取れ」を良好とする観点から、モノエステル化物が更に好ましい。 The polyhydric alcohol fatty acid ester type surfactant is preferably a partially esterified product of a hydroxyl group of a polyhydric alcohol, more preferably a monoesterified product or a diesterified product, from the viewpoint of softening the surface and improving “removability”. A monoester product is more preferable.
また、本発明の成分（Ａ）のＨＬＢ値は６以下である。該ＨＬＢ値は、好ましくは５．５以下、より好ましくは５以下であり、また、好ましくは１以上、より好ましくは１．５以上、更に好ましくは２以上である。具体的には、１〜６が好ましく、１〜５．５がより好ましく、２〜５が更に好ましい。
なお、本発明におけるＨＬＢ値は下記の川上式（Ｉ）により算出されるものを意味する。
ＨＬＢ＝７＋１１．７ｌｏｇ（Ｍｗ／Ｍｏ） ・・・（Ｉ）
ここで式（Ｉ）においてＭｗは親水性基部の分子量、Ｍｏは親油性基部の分子量をそれぞれ表す。
Moreover, the HLB value of the component (A) of the present invention is 6 or less. The HLB value is preferably 5.5 or less, more preferably 5 or less, preferably 1 or more, more preferably 1.5 or more, and still more preferably 2 or more. Specifically, 1-6 are preferable, 1-5.5 are more preferable, and 2-5 are still more preferable.
In addition, the HLB value in this invention means what is calculated by the following Kawakami formula (I).
HLB = 7 + 11.7 log (Mw / Mo) (I)
Here, in the formula (I), Mw represents the molecular weight of the hydrophilic base and Mo represents the molecular weight of the lipophilic base.
本発明の成分（Ａ）の具体例としては、例えば、モノイソステアリン酸ソルビタン、モノオレイン酸ソルビタン、セスキイソステアリン酸ソルビタン、モノイソステアリン酸ジグリセリル、モノオレイン酸ジグリセリル等が挙げられ、これらのうち１種を単独で又は２種以上を組み合わせて使用してよい。 Specific examples of the component (A) of the present invention include, for example, sorbitan monoisostearate, sorbitan monooleate, sorbitan sesquiisostearate, diglyceryl monoisostearate, diglyceryl monooleate, and the like. You may use a seed | species individually or in combination of 2 or more types.
成分（Ａ）の含有量は、保存安定性の観点、及び塗布時の感触をさっぱりして軽くさせる観点から、本発明の油中水型固形乳化化粧料中、好ましくは０．５質量％、より好ましくは１質量％以上であり、また、好ましくは１０質量％以下、より好ましくは５質量％以下、更に好ましくは３質量％以下である。具体的には、０．５〜１０質量％が好ましく、０．５〜５質量％がより好ましく、１〜３質量％が更に好ましい。 The content of the component (A) is preferably 0.5% by mass in the water-in-oil solid emulsion cosmetic of the present invention, from the viewpoint of storage stability and from the viewpoint of refreshing and lightening the feel during application. More preferably, it is 1 mass% or more, Preferably it is 10 mass% or less, More preferably, it is 5 mass% or less, More preferably, it is 3 mass% or less. Specifically, 0.5-10 mass% is preferable, 0.5-5 mass% is more preferable, and 1-3 mass% is still more preferable.
＜成分（Ｂ）＞
本発明の成分（Ｂ）は、鉱物性ワックスである。鉱物性ワックスとしては、オゾケライト、セレシン、パラフィンワックス、ペトロラタム、マイクロクリスタリンワックス、モンタンワックス等が挙げられ、これらのうち１種を単独で又は２種以上を組み合わせて使用してよい。これらの中でも、保存安定性の観点、及び表面が柔らかくし「取れ」を良好とする観点から、炭化水素系の鉱物性ワックスが好ましく、パラフィンワックス、マイクロクリスタリンワックスがより好ましい。
成分（Ｂ）の市販品としては、パラフィンワックス１５５（日本精鑞社製）等が挙げられる。
<Component (B)>
Component (B) of the present invention is a mineral wax. Examples of the mineral wax include ozokerite, ceresin, paraffin wax, petrolatum, microcrystalline wax, montan wax and the like, and one of these may be used alone or in combination of two or more. Among these, hydrocarbon-based mineral waxes are preferable, and paraffin waxes and microcrystalline waxes are more preferable from the viewpoints of storage stability and softening of the surface and good “removal”.
As a commercial item of a component (B), paraffin wax 155 (made by Nippon Seiki Co., Ltd.) etc. is mentioned.
成分（Ｂ）の含有量は、本発明の油中水型固形乳化化粧料中、１．５〜５質量％である。該含有量は、保存安定性の観点、及び表面が柔らかくし「取れ」を良好とする観点から、好ましくは２質量％以上、より好ましくは２．５質量％以上であり、また、好ましくは４．５質量％以下であり、４質量％以下である。具体的には、２〜４．５質量が好ましく、２．５〜４質量％がより好ましい。 Content of a component (B) is 1.5-5 mass% in the water-in-oil type solid emulsified cosmetics of this invention. The content is preferably 2% by mass or more, more preferably 2.5% by mass or more, and preferably 4% from the viewpoints of storage stability and softening of the surface to improve “removal”. .5% by mass or less, and 4% by mass or less. Specifically, 2-4.5 mass is preferable and 2.5-4 mass% is more preferable.
また、成分（Ａ）と成分（Ｂ）との含有質量比〔（Ａ）／（Ｂ）〕は、好ましくは０．０５以上、より好ましくは０．１以上、更に好ましくは０．２５以上であり、また、好ましくは５以下、より好ましくは１以下、更に好ましくは０．７５以下である。具体的には、０．０５〜５が好ましく、０．１〜１がより好ましく、０．２５〜０．７５が更に好ましい。本発明の油中水型固形乳化化粧料は、斯様な範囲の含有質量比〔（Ａ）／（Ｂ）〕であっても、優れた保存安定性、及び表面の柔らかさが得られる。 The mass ratio [(A) / (B)] of the component (A) and the component (B) is preferably 0.05 or more, more preferably 0.1 or more, and further preferably 0.25 or more. Yes, preferably 5 or less, more preferably 1 or less, still more preferably 0.75 or less. Specifically, 0.05 to 5 is preferable, 0.1 to 1 is more preferable, and 0.25 to 0.75 is still more preferable. The water-in-oil solid emulsified cosmetic of the present invention can provide excellent storage stability and surface softness even in such a content mass ratio [(A) / (B)].
＜成分（Ｃ）＞
本発明の成分（Ｃ）は、架橋型シリコーンエラストマーである。架橋型シリコーンエラストマーとは、モノマーの重合によって得られた架橋構造を有するシリコーン及びその誘導体を意味する。成分（Ｃ）としては、ジメチコン、ビニルジメチコン、フェニルビニルジメチコン、ラウリルジメチコン及びラウリルポリジメチルシロキシエチルジメチコンから選ばれるモノマーを重合又は共重合させて得られるシリコーン及びその誘導体が好ましく、ジメチコンとビニルジメチコンとのクロスポリマーがより好ましい。
<Ingredient (C)>
Component (C) of the present invention is a crosslinked silicone elastomer. The cross-linked silicone elastomer means a silicone having a cross-linked structure obtained by polymerization of monomers and derivatives thereof. Component (C) is preferably a silicone obtained by polymerizing or copolymerizing a monomer selected from dimethicone, vinyl dimethicone, phenyl vinyl dimethicone, lauryl dimethicone, and lauryl polydimethylsiloxyethyl dimethicone, and derivatives thereof. The cross polymer is more preferable.
また、架橋型シリコーンエラストマーとしては粉末状のものが好ましい。なお、この場合であっても斯かる架橋型シリコーンエラストマー粉末は成分（Ｄ）には含まれない。また、架橋型シリコーンエラストマー粉末は分散媒に分散しているものであってもよい。斯かる分散媒としては、シクロペンタシロキサン、メチルトリメチコン、ジメチコン、デカメチルペンタシロキサン、ジフェニルシロキシフェニルトリメチコン、ミネラルオイル、イソドデカン、トリオクタノイン、スクワラン等の油剤や水が挙げられる。 The cross-linked silicone elastomer is preferably in powder form. Even in this case, such a crosslinked silicone elastomer powder is not included in the component (D). The crosslinked silicone elastomer powder may be dispersed in a dispersion medium. Examples of such a dispersion medium include oil agents such as cyclopentasiloxane, methyltrimethicone, dimethicone, decamethylpentasiloxane, diphenylsiloxyphenyltrimethicone, mineral oil, isododecane, trioctanoin, squalane, and water.
成分（Ｃ）の市販品としては、東レ・ダウコーニング社製のトレフィルシリーズ（トレフィルＥ５０５Ｃ、トレフィルＥ５０８等）や、信越化学工業社製のＫＳＰシリーズ（ＫＳＰ−１００、ＫＳＰ−１０１等）等が挙げられる。また、溶媒に予め分散しているものとしては、東レ・ダウコーニング社製のＢＹ２９−１２９や信越化学工業社製のＫＳＧシリーズ（ＫＳＧ−１５、ＫＳＧ−１６、ＫＳＧ−１６１０、ＫＳＧ−１８Ａ、ＫＳＧ−４１、ＫＳＧ−４２、ＫＳＧ−４３、ＫＳＧ−４４等）が挙げられる。また、特許第３６１６２４４号公報に記載の方法で得たものを用いてもよい。 Examples of commercially available components (C) include the Toray Dow Corning trefill series (Trefill E505C, Trefill E508, etc.), the Shin-Etsu Chemical KSP series (KSP-100, KSP-101, etc.), etc. Can be mentioned. Moreover, as what is previously disperse | distributed to a solvent, BY29-129 made by Toray Dow Corning Co., Ltd. and KSG series (KSG-15, KSG-16, KSG-1610, KSG-18A, KSG made by Shin-Etsu Chemical Co., Ltd.) -41, KSG-42, KSG-43, KSG-44, etc.). Moreover, you may use what was obtained by the method of the patent 3616244 gazette.
成分（Ｃ）の含有量は、保存安定性の観点、表面が柔らかくし「取れ」を良好とする観点、及び塗布時の感触をさっぱりして軽くさせる観点から、本発明の油中水型固形乳化化粧料中、好ましくは０．５質量％以上、より好ましくは１質量％以上であり、また、好ましくは３質量％以下、より好ましくは２質量％以下、更に好ましくは１．７５質量％以下である。具体的には、０．５〜３質量％が好ましく、１〜２質量％がより好ましく、１〜１．７５質量％が更に好ましい。 The content of the component (C) is a water-in-oil solid according to the present invention from the viewpoint of storage stability, the viewpoint that the surface is soft and "takes" are good, and the feeling during application is refreshed and lightened. In the emulsified cosmetic, it is preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably 3% by mass or less, more preferably 2% by mass or less, still more preferably 1.75% by mass or less. It is. Specifically, 0.5-3 mass% is preferable, 1-2 mass% is more preferable, and 1-1.75 mass% is still more preferable.
また、成分（Ａ）と成分（Ｃ）との含有質量比〔（Ａ）／（Ｃ）〕は、好ましくは０．５以上、より好ましくは０．７５以上、更に好ましくは１以上であり、また、好ましくは５以下、より好ましくは３以下、更に好ましくは２以下である。具体的には、０．５〜５が好ましく、０．７５〜３がより好ましく、１〜２が更に好ましい。 The content mass ratio [(A) / (C)] of the component (A) and the component (C) is preferably 0.5 or more, more preferably 0.75 or more, and further preferably 1 or more. Moreover, Preferably it is 5 or less, More preferably, it is 3 or less, More preferably, it is 2 or less. Specifically, 0.5-5 is preferable, 0.75-3 is more preferable, and 1-2 is still more preferable.
＜成分（Ｄ）＞
本発明の成分（Ｄ）は粉体である。
成分（Ｄ）の粉体は、通常の化粧料に使用されるものであれば特に限定されず、有機粉体、無機粉体、有色顔料等のいずれでもよく、１種を単独で又は２種以上を組み合わせて使用してよい。また、その形状は、球状、針状、板状のいずれでもよい。また、アルミナ、シリカ、亜鉛等で処理されたものや、シリコーン等で疎水処理したものであってもよい。
<Component (D)>
Component (D) of the present invention is a powder.
The powder of component (D) is not particularly limited as long as it is used in ordinary cosmetics, and may be any of organic powder, inorganic powder, colored pigment and the like, one kind alone or two kinds A combination of the above may be used. Further, the shape may be any of a spherical shape, a needle shape, and a plate shape. Further, it may be treated with alumina, silica, zinc or the like, or treated with silicone or the like.
上記有機粉体としては、ラウロイルリシン、ポリメチルシルセスキオキサンパウダー、ポリアミドパウダー、ポリエステルパウダー、ポリエチレンパウダー、ポリプロピレンパウダー、ポリスチレンパウダー、ポリウレタン、ベンゾグアナミンパウダー、ポリメチルベンゾグアナミンパウダー、テトラフルオロエチレンパウダー等が挙げられる。 Examples of the organic powder include lauroyl lysine, polymethylsilsesquioxane powder, polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyurethane, benzoguanamine powder, polymethylbenzoguanamine powder, and tetrafluoroethylene powder. It is done.
また、上記無機粉体としては、酸化チタン、酸化ジルコニウム、酸化亜鉛、酸化セリウム、酸化マグネシウム、硫酸バリウム、硫酸カルシウム、硫酸マグネシウム、炭酸カルシウム、炭酸マグネシウム、タルク、マイカ、カオリン、セリサイト、白雲母、合成雲母、金雲母、紅雲母、黒雲母、リチア雲母、ケイ酸、無水ケイ酸、ケイ酸アルミニウム、ケイ酸マグネシウム、ケイ酸アルミニウムマグネシウム、ケイ酸カルシウム、ケイ酸バリウム、ケイ酸ストロンチウム、タングステン酸金属塩等が挙げられる。 Examples of the inorganic powder include titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, mica, kaolin, sericite, and muscovite. , Synthetic mica, phlogopite, saucite, biotite, lithia mica, silicic acid, anhydrous silicic acid, aluminum silicate, magnesium silicate, magnesium aluminum silicate, calcium silicate, barium silicate, strontium silicate, tungstic acid A metal salt etc. are mentioned.
また、上記有色顔料としては、酸化鉄、水酸化鉄、チタン酸鉄の無機赤色顔料；γ−酸化鉄等の無機褐色系顔料；黄酸化鉄、黄土等の無機黄色系顔料；黒酸化鉄、カーボンブラック等の無機黒色顔料；マンガンバイオレット、コバルトバイオレット等の無機紫色顔料；水酸化クロム、酸化クロム、酸化コバルト、チタン酸コバルト等の無機緑色顔料；紺青、群青等の無機青色系顔料等が挙げられる。 Examples of the colored pigments include inorganic red pigments such as iron oxide, iron hydroxide and iron titanate; inorganic brown pigments such as γ-iron oxide; inorganic yellow pigments such as yellow iron oxide and ocher; black iron oxide; Inorganic black pigments such as carbon black; inorganic purple pigments such as manganese violet and cobalt violet; inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide and cobalt titanate; inorganic blue pigments such as bitumen and ultramarine It is done.
成分（Ｄ）の含有量は、本発明の油中水型固形乳化化粧料中、３５〜５５質量％である。該含有量は、好ましくは４０質量％以上、より好ましくは４２．５質量％以上であり、また、好ましくは５０質量％以下である。具体的には、４０〜５０質量％が好ましく、４２．５〜５０質量％がより好ましい。本発明の油中水型固形乳化化粧料は、成分（Ｄ）の含有量が斯様な範囲であっても、優れた保存安定性と、及び表面の柔らかさ、良好な「取れ」とが両立される。 Content of a component (D) is 35-55 mass% in the water-in-oil type solid emulsified cosmetics of this invention. The content is preferably 40% by mass or more, more preferably 42.5% by mass or more, and preferably 50% by mass or less. Specifically, 40-50 mass% is preferable and 42.5-50 mass% is more preferable. The water-in-oil solid emulsified cosmetic of the present invention has excellent storage stability, softness of the surface, and good “removal” even if the content of the component (D) is within such a range. It is compatible.
また、成分（Ａ）と成分（Ｄ）との含有質量比〔（Ａ）／（Ｄ）〕は、好ましくは０．００５以上、より好ましくは０．０１以上であり、また、好ましくは１以下、より好ましくは０．１以下、更に好ましくは０．０７５以下である。具体的には、０．００５〜１が好ましく、０．０１〜０．１がより好ましく、０．０１〜０．０７５が更に好ましい。 The mass ratio [(A) / (D)] of component (A) and component (D) is preferably 0.005 or more, more preferably 0.01 or more, and preferably 1 or less. More preferably, it is 0.1 or less, More preferably, it is 0.075 or less. Specifically, 0.005 to 1 is preferable, 0.01 to 0.1 is more preferable, and 0.01 to 0.075 is still more preferable.
また、成分（Ｂ）と成分（Ｄ）との含有質量比〔（Ｂ）／（Ｄ）〕は、好ましくは０．００５以上、より好ましくは０．０１以上であり、また、好ましくは１以下、より好ましくは０．１以下である。具体的には、０．００５〜１が好ましく、０．０１〜０．１がより好ましい。 The mass ratio [(B) / (D)] of component (B) and component (D) is preferably 0.005 or more, more preferably 0.01 or more, and preferably 1 or less. More preferably, it is 0.1 or less. Specifically, 0.005 to 1 is preferable, and 0.01 to 0.1 is more preferable.
また、成分（Ｃ）と成分（Ｄ）との含有質量比〔（Ｃ）／（Ｄ）〕は、好ましくは０．００５以上、より好ましくは０．０１以上であり、また、好ましくは０．５以下、より好ましくは０．１以下である。具体的には、０．００５〜０．５が好ましく、０．０１〜０．１がより好ましい。 The mass ratio [(C) / (D)] of component (C) and component (D) is preferably 0.005 or more, more preferably 0.01 or more, and preferably 0.00. 5 or less, more preferably 0.1 or less. Specifically, 0.005 to 0.5 is preferable, and 0.01 to 0.1 is more preferable.
本発明の油中水型固形乳化化粧料は、上記成分（Ａ）〜（Ｄ）に加え、必要に応じて、ワセリン、メチコン、シクロヘキサシロキサン、デカメチルシクロペンタシロキサン、フェニルメチコン、ジカプリン酸プロピレングリコール等の油剤；１，３−ブチレングリコール、ジプロピレングリコール、マルチトール等の保湿剤；乳化剤；香料；紫外線吸収剤；パラオキシ安息香酸メチル、フェノキシエタノール等の防腐剤；植物エキス等の、成分（Ａ）〜（Ｄ）以外の化粧料に通常配合される成分を含んでいてもよい。
上記成分（Ａ）〜（Ｄ）以外の油剤の含有量としては、１０〜６０質量％が好ましく、１５〜５０質量％がより好ましく、２０〜４０質量％が更に好ましく、２０〜３５質量％が更に好ましい。
The water-in-oil type solid emulsified cosmetic of the present invention includes petrolatum, methicone, cyclohexasiloxane, decamethylcyclopentasiloxane, phenylmethicone, propylene dicaprate, as necessary, in addition to the components (A) to (D). Oil agents such as glycol; moisturizers such as 1,3-butylene glycol, dipropylene glycol and maltitol; emulsifiers; fragrances; ultraviolet absorbers; preservatives such as methyl paraoxybenzoate and phenoxyethanol; The component normally mix | blended with cosmetics other than (D) may be included.
As content of oil agents other than said component (A)-(D), 10-60 mass% is preferable, 15-50 mass% is more preferable, 20-40 mass% is still more preferable, 20-35 mass% is Further preferred.
本発明の油中水型固形乳化化粧料の用途は特に限定されないが、例えば、メーキャップ化粧料、スキンケア化粧料、クレンジング化粧料が挙げられる。本発明の油中水型固形乳化化粧料は、ファンデーション、コンシーラー、化粧下地等のメーキャップ化粧料に特に適している。
また、本発明の油中水型固形乳化化粧料は、常法に従い製造可能である。
The use of the water-in-oil solid emulsified cosmetic of the present invention is not particularly limited, and examples thereof include makeup cosmetics, skin care cosmetics, and cleansing cosmetics. The water-in-oil solid emulsified cosmetic of the present invention is particularly suitable for makeup cosmetics such as foundations, concealers, and makeup bases.
Moreover, the water-in-oil solid emulsified cosmetic of the present invention can be produced according to a conventional method.
そして、本発明の油中水型固形乳化化粧料は、粉体を高濃度で含むにも拘わらず、保存安定性に優れ、且つ表面が柔らかく滑らかで「取れ」が良好である。 The water-in-oil solid emulsified cosmetic of the present invention is excellent in storage stability, has a soft and smooth surface, and has good “take off” despite containing a high concentration of powder.
上述した実施形態に関し、本発明は更に以下の油中水型固形乳化化粧料を開示する。 In relation to the above-described embodiment, the present invention further discloses the following water-in-oil solid emulsified cosmetics.
＜１＞以下の成分（Ａ）〜（Ｄ）を含有する油中水型固形乳化化粧料。
（Ａ）ＨＬＢ値６以下であり、２５℃で液状の多価アルコール脂肪酸エステル型界面活性剤
（Ｂ）鉱物性ワックス：１．５〜５質量％
（Ｃ）架橋型シリコーンエラストマー
（Ｄ）粉体：３５〜５５質量％
<1> A water-in-oil solid emulsified cosmetic containing the following components (A) to (D).
(A) Polyhydric alcohol fatty acid ester type surfactant having an HLB value of 6 or less and liquid at 25 ° C. (B) Mineral wax: 1.5 to 5% by mass
(C) Cross-linked silicone elastomer (D) Powder: 35-55% by mass
＜２＞成分（Ａ）の多価アルコールが、好ましくは３〜６価のアルコールであり、より好ましくは３〜５価のアルコールである＜１＞の油中水型固形乳化化粧料。
＜３＞成分（Ａ）の脂肪酸が、好ましくは炭素数６〜２２の飽和又は不飽和の脂肪酸であり、より好ましくは炭素数８〜２０の飽和又は不飽和の脂肪酸であり、更に好ましくは１２〜２０の飽和又は不飽和の脂肪酸であり、更に好ましくは炭素数１４〜２０の飽和又は不飽和の脂肪酸であり、更に好ましくは炭素数１６〜２０の飽和又は不飽和の脂肪酸である＜１＞又は＜２＞の油中水型固形乳化化粧料。
＜４＞成分（Ａ）が、好ましくは多価アルコールの水酸基の部分エステル化物であり、より好ましくは多価アルコールの水酸基のモノエステル化物及び多価アルコールの水酸基のジエステル化物から選ばれる１種以上であり、更に好ましくは多価アルコールの水酸基のモノエステル化物である＜１＞〜＜３＞のいずれかの油中水型固形乳化化粧料。
＜５＞成分（Ａ）の含有量が、好ましくは０．５質量％、より好ましくは１質量％以上であり、また、好ましくは１０質量％以下、より好ましくは５質量％以下、更に好ましくは３質量％以下である＜１＞〜＜４＞のいずれかの油中水型固形乳化化粧料。
＜６＞成分（Ａ）の含有量が、好ましくは０．５〜１０質量％、より好ましくは０．５〜５質量％、更に好ましくは１〜３質量％である＜１＞〜＜５＞のいずれかの油中水型固形乳化化粧料。
＜７＞成分（Ｂ）が、好ましくは炭化水素系の鉱物性ワックスであり、より好ましくはパラフィンワックス及びマイクロクリスタリンワックスから選ばれるものである＜１＞〜＜６＞のいずれかの油中水型固形乳化化粧料。
＜８＞成分（Ｂ）の含有量が、好ましくは２質量％以上、より好ましくは２．５質量％以上であり、また、好ましくは４．５質量％以下であり、４質量％以下である＜１＞〜＜７＞のいずれかの油中水型固形乳化化粧料。
＜９＞成分（Ｂ）の含有量が、好ましくは２〜４．５質量であり、より好ましくは２．５〜４質量％である＜１＞〜＜８＞のいずれかの油中水型固形乳化化粧料。
＜１０＞成分（Ａ）と成分（Ｂ）との含有質量比〔（Ａ）／（Ｂ）〕が、好ましくは０．０５以上、より好ましくは０．１以上、更に好ましくは０．２５以上であり、また、好ましくは５以下、より好ましくは１以下、更に好ましくは０．７５以下である＜１＞〜＜９＞のいずれかの油中水型固形乳化化粧料。
＜１１＞成分（Ａ）と成分（Ｂ）との含有質量比〔（Ａ）／（Ｂ）〕が、好ましくは０．０５〜５、より好ましくは０．１〜１、更に好ましくは０．２５〜０．７５である＜１＞〜＜１０＞のいずれかの油中水型固形乳化化粧料。
＜１２＞成分（Ｃ）が、好ましくはジメチコン、ビニルジメチコン、フェニルビニルジメチコン、ラウリルジメチコン及びラウリルポリジメチルシロキシエチルジメチコンから選ばれるモノマーを重合又は共重合させて得られるシリコーン及びその誘導体であり、より好ましくはジメチコンとビニルジメチコンとのクロスポリマーである＜１＞〜＜１１＞のいずれかの油中水型固形乳化化粧料。
＜１３＞成分（Ｃ）が、架橋型シリコーンエラストマー粉末である＜１＞〜＜１２＞のいずれかの油中水型固形乳化化粧料。
＜１４＞成分（Ｃ）の含有量が、好ましくは０．５質量％以上、より好ましくは１質量％以上であり、また、好ましくは３質量％以下、より好ましくは２質量％以下、更に好ましくは１．７５質量％以下である＜１＞〜＜１３＞のいずれかの油中水型固形乳化化粧料。
＜１５＞成分（Ｃ）の含有量が、好ましくは０．５〜３質量％、より好ましくは１〜２質量％、更に好ましくは１〜１．７５質量％である＜１＞〜＜１４＞のいずれかの油中水型固形乳化化粧料。
＜１６＞成分（Ａ）と成分（Ｃ）との含有質量比〔（Ａ）／（Ｃ）〕が、好ましくは０．５以上、より好ましくは０．７５以上、更に好ましくは１以上であり、また、好ましくは５以下、より好ましくは３以下、更に好ましくは２以下である＜１＞〜＜１５＞のいずれかの油中水型固形乳化化粧料。
＜１７＞成分（Ａ）と成分（Ｃ）との含有質量比〔（Ａ）／（Ｃ）〕が、好ましくは０．５〜５であり、より好ましくは０．７５〜３であり、更に好ましくは１〜２である＜１＞〜＜１６＞のいずれかの油中水型固形乳化化粧料。
＜１８＞成分（Ｄ）が、有機粉体、無機粉体及び有色顔料から選ばれるものである＜１＞〜＜１７＞のいずれかの油中水型固形乳化化粧料。
＜１９＞成分（Ｄ）の含有量が、好ましくは４０質量％以上、より好ましくは４２．５質量％以上、また、好ましくは５０質量％以下である＜１＞〜＜１８＞のいずれかの油中水型固形乳化化粧料。
＜２０＞成分（Ｄ）の含有量が、好ましくは４０〜５０質量％、より好ましくは４２．５〜５０質量％である＜１＞〜＜１９＞のいずれかの油中水型固形乳化化粧料。
＜２１＞油剤を更に含有する＜１＞〜＜２０＞のいずれかの油中水型固形乳化化粧料。
<2> The water-in-oil solid emulsion cosmetic according to <1>, wherein the polyhydric alcohol of the component (A) is preferably a trivalent to hexavalent alcohol, more preferably a trivalent to pentavalent alcohol.
<3> The fatty acid of component (A) is preferably a saturated or unsaturated fatty acid having 6 to 22 carbon atoms, more preferably a saturated or unsaturated fatty acid having 8 to 20 carbon atoms, and still more preferably 12 <1> Saturated or unsaturated fatty acid having 20 to 20 carbon atoms, more preferably a saturated or unsaturated fatty acid having 14 to 20 carbon atoms, and more preferably a saturated or unsaturated fatty acid having 16 to 20 carbon atoms. Or <2> water-in-oil solid emulsified cosmetics.
<4> Component (A) is preferably a partially esterified product of a hydroxyl group of a polyhydric alcohol, more preferably one or more selected from a monoester product of a hydroxyl group of a polyhydric alcohol and a diester product of a hydroxyl group of a polyhydric alcohol More preferably, the water-in-oil solid emulsified cosmetic according to any one of <1> to <3>, which is a monoesterified product of a hydroxyl group of a polyhydric alcohol.
The content of <5> component (A) is preferably 0.5% by mass, more preferably 1% by mass or more, preferably 10% by mass or less, more preferably 5% by mass or less, still more preferably. The water-in-oil solid emulsified cosmetic according to any one of <1> to <4>, which is 3% by mass or less.
The content of <6> component (A) is preferably 0.5 to 10% by mass, more preferably 0.5 to 5% by mass, and still more preferably 1 to 3% by mass. <1> to <5> Any of the water-in-oil solid emulsified cosmetics.
<7> The water-in-oil according to any one of <1> to <6>, wherein the component (B) is preferably a hydrocarbon mineral wax, more preferably selected from paraffin wax and microcrystalline wax. Type solid emulsified cosmetics.
The content of <8> component (B) is preferably 2% by mass or more, more preferably 2.5% by mass or more, and preferably 4.5% by mass or less, and 4% by mass or less. The water-in-oil solid emulsified cosmetic according to any one of <1> to <7>.
<9> The water-in-oil type according to any one of <1> to <8>, wherein the content of the component (B) is preferably 2 to 4.5 mass%, more preferably 2.5 to 4 mass%. Solid emulsified cosmetic.
<10> The mass ratio [(A) / (B)] of the component (A) and the component (B) is preferably 0.05 or more, more preferably 0.1 or more, still more preferably 0.25 or more. In addition, the water-in-oil solid emulsion cosmetic according to any one of <1> to <9>, which is preferably 5 or less, more preferably 1 or less, and even more preferably 0.75 or less.
<11> The mass ratio [(A) / (B)] of the component (A) and the component (B) is preferably 0.05 to 5, more preferably 0.1 to 1, and still more preferably 0.00. The water-in-oil solid emulsified cosmetic according to any one of <1> to <10>, which is 25 to 0.75.
<12> Component (C) is preferably a silicone obtained by polymerizing or copolymerizing a monomer selected from dimethicone, vinyl dimethicone, phenyl vinyl dimethicone, lauryl dimethicone and lauryl polydimethylsiloxyethyl dimethicone, and more. The water-in-oil solid emulsified cosmetic according to any one of <1> to <11>, which is preferably a cross polymer of dimethicone and vinyl dimethicone.
<13> The water-in-oil solid emulsified cosmetic according to any one of <1> to <12>, wherein the component (C) is a crosslinked silicone elastomer powder.
The content of <14> component (C) is preferably 0.5% by mass or more, more preferably 1% by mass or more, preferably 3% by mass or less, more preferably 2% by mass or less, and still more preferably. Is a water-in-oil solid emulsified cosmetic according to any one of <1> to <13>, which is 1.75% by mass or less.
<15> The content of the component (C) is preferably 0.5 to 3% by mass, more preferably 1 to 2% by mass, and still more preferably 1 to 1.75% by mass. <1> to <14> Any of the water-in-oil solid emulsified cosmetics.
<16> The mass ratio [(A) / (C)] of the component (A) and the component (C) is preferably 0.5 or more, more preferably 0.75 or more, and further preferably 1 or more. The water-in-oil solid emulsified cosmetic according to any one of <1> to <15>, preferably 5 or less, more preferably 3 or less, and still more preferably 2 or less.
<17> The mass ratio [(A) / (C)] of the component (A) and the component (C) is preferably 0.5 to 5, more preferably 0.75 to 3, and further The water-in-oil solid emulsified cosmetic according to any one of <1> to <16>, which is preferably 1-2.
<18> The water-in-oil solid emulsified cosmetic according to any one of <1> to <17>, wherein the component (D) is selected from organic powders, inorganic powders, and colored pigments.
The content of <19> component (D) is preferably 40% by mass or more, more preferably 42.5% by mass or more, and preferably 50% by mass or less, and any one of <1> to <18> Water-in-oil solid emulsified cosmetic.
<20> The water-in-oil solid emulsion makeup according to any one of <1> to <19>, wherein the content of the component (D) is preferably 40 to 50% by mass, more preferably 42.5 to 50% by mass. Fee.
<21> The water-in-oil solid emulsified cosmetic according to any one of <1> to <20>, further containing an oil.
後記実施例及び比較例の油中水型固形乳化化粧料の調製方法及び評価方法を以下に示す。 Preparation methods and evaluation methods of water-in-oil type solid emulsified cosmetics of Examples and Comparative Examples described below are shown below.
＜調製方法＞
油相成分を８０℃に加熱して、これに粉体を分散させ、あらかじめ８０℃に加熱しておいた水相成分を更に添加し、乳化後速やかに容器に充填して、油中水型固形乳化化粧料を得た。
<Preparation method>
The oil phase component is heated to 80 ° C., the powder is dispersed therein, the water phase component heated to 80 ° C. is further added, and after emulsification, the vessel is immediately filled into a water-in-oil type. A solid emulsified cosmetic was obtained.
＜評価方法＞
（１）使用特性
女性パネラー２０名に各化粧料の表面を触ってもらい、「表面が柔らかい」と回答した人数に従って、使用特性を評価した。評価基準は下記のとおりである。
（使用特性の評価基準）
◎：「表面が柔らかい」と回答した人数が１８人以上
○：「表面が柔らかい」と回答した人数が１５〜１７人
△：「表面が柔らかい」と回答した人数が７〜１４人
×：「表面が柔らかい」と回答した人数が６人以下
<Evaluation method>
(1) Use characteristics Twenty female panelists touched the surface of each cosmetic, and the use characteristics were evaluated according to the number of people who answered that the surface was soft. The evaluation criteria are as follows.
(Evaluation criteria for usage characteristics)
◎: 18 or more people who answered “soft surface” ○: 15 to 17 people who answered “soft surface” △: 7 to 14 people who answered “soft surface” ×: “ The number of people who answered that the surface is soft is 6 or less
（２）保存安定性
各化粧料を０℃、２５℃、４５℃の恒温槽内に放置し、３週間後の状態を確認し、保存安定性を下記の基準に従って評価した。
（保存安定性の評価基準）
○：流動性なし
△：わずかに流動性あり
×：流動性あり
(2) Storage stability Each cosmetic was left in a thermostatic bath at 0 ° C, 25 ° C and 45 ° C, the state after 3 weeks was confirmed, and the storage stability was evaluated according to the following criteria.
(Evaluation criteria for storage stability)
○: No fluidity △: Slightly fluidity ×: Fluidity
実施例１〜４及び比較例１〜４ 固形状乳化コンシーラー
下記表１に示す組成の固形状乳化コンシーラーを上記調製方法により製造し、上記各試験を実施した。その結果を併せて表１に示す。
Examples 1 to 4 and Comparative Examples 1 to 4 Solid emulsified concealer Solid emulsified concealers having the compositions shown in Table 1 below were produced by the above preparation methods, and the above tests were performed. The results are also shown in Table 1.
＊１：パラフィンワックス１５５Ｆ（日本精鑞社製）
＊２：特許第３６１６２４４号の実施例１の製法によって得られたもの（純分：３５％、分散媒：デカメチルシクロペンタシロキサン）
＊３：ＫＳＧ−１６（信越化学工業社製、純分：２４％、分散媒：ジメチルポリシロキサン）
＊４：ＳＨ５５６Ｆｌｕｉｄ（東レ・ダウコーニング社製）
＊５：トスパール１４５Ａ（モメンティブ・パフォーマンス・マテリアルズ社製）
* 1: Paraffin wax 155F (Nippon Seiki Co., Ltd.)
* 2: Obtained by the production method of Example 1 of Japanese Patent No. 3616244 (pure content: 35%, dispersion medium: decamethylcyclopentasiloxane)
* 3: KSG-16 (manufactured by Shin-Etsu Chemical Co., Ltd., pure content: 24%, dispersion medium: dimethylpolysiloxane)
* 4: SH556 Fluid (Toray Dow Corning)
* 5: Tospearl 145A (made by Momentive Performance Materials)
表１に示すように実施例１〜４の固形状乳化コンシーラーは、使用特性及び保存安定性に優れたものであった。 As shown in Table 1, the solid emulsified concealers of Examples 1 to 4 were excellent in use characteristics and storage stability.
下記実施例５についても、上記試験において優れた結果を示すものである。
実施例５ 固形状乳化コンシーラー
The following Example 5 also shows excellent results in the above test.
Example 5 Solid emulsified concealer
（油相成分） （質量％）
モノイソステアリン酸ソルビタン ２．０
メトキシケイヒ酸エチルヘキシル ３．０
パラフィンワックス（＊１） ３．０
マイクロクリスタリンワックス ０．５
シクロヘキサシロキサン ２０．０
（ジメチコン／ビニルジメチコン）クロスポリマー分散体（＊２） ４．５
ワセリン ２．０
ジメチコン（＊６） ３．０
ジカプリル酸プロピレングリコール ２．０
フェニルトリメチコン（＊４） １．５
（水相成分）
１，３ブチレングリコール ４．０
ジプロピレングリコール ２．０
マルチトール ２．０
精製水 残量
クロルフェネシン ０．１
フェノキシエタノール ０．１
セージエキス ０．１
加水分解シルク ０．１
（粉体）
酸化チタン ２０．０
酸化鉄 ３．５
タルク １３．０
マイカ ２．０
板状硫酸バリウム ２．０
Ｎ−ラウロイル−Ｌ−リジン ２．０
ポリメチルシルセスキオキサンパウダー（＊５） １．５
(Oil phase component) (mass%)
Sorbitan monoisostearate 2.0
Ethyl hexyl methoxycinnamate 3.0
Paraffin wax (* 1) 3.0
Microcrystalline wax 0.5
Cyclohexasiloxane 20.0
(Dimethicone / vinyl dimethicone) cross-polymer dispersion (* 2) 4.5
Vaseline 2.0
Dimethicone (* 6) 3.0
Propylene glycol dicaprylate 2.0
Phenyltrimethicone (* 4) 1.5
(Aqueous phase component)
1,3 Butylene glycol 4.0
Dipropylene glycol 2.0
Maltitol 2.0
Purified water remaining chlorphenesin 0.1
Phenoxyethanol 0.1
Sage extract 0.1
Hydrolyzed silk 0.1
(powder)
Titanium oxide 20.0
Iron oxide 3.5
Talc 13.0
Mica 2.0
Plate-like barium sulfate 2.0
N-lauroyl-L-lysine 2.0
Polymethylsilsesquioxane powder (* 5) 1.5
＊６：ＫＦ−９６Ａ−６ｃｓ（信越化学工業社製） * 6: KF-96A-6cs (manufactured by Shin-Etsu Chemical Co., Ltd.)
Claims (2)
（Ａ）ＨＬＢ値６以下であり、２５℃で液状の多価アルコール脂肪酸エステル型界面活性剤
（Ｂ）鉱物性ワックス：１．５〜５質量％
（Ｃ）架橋型シリコーンエラストマー
（Ｄ）粉体：３５〜５５質量％ A water-in-oil solid emulsified cosmetic containing the following components (A) to (D).
(A) Polyhydric alcohol fatty acid ester type surfactant having an HLB value of 6 or less and liquid at 25 ° C. (B) Mineral wax: 1.5 to 5% by mass
(C) Cross-linked silicone elastomer (D) Powder: 35-55% by mass
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018104392A (en) * | 2016-12-28 | 2018-07-05 | ポーラ化成工業株式会社 | Method for modifying powder particle surface |
| WO2018199160A1 (en) * | 2017-04-28 | 2018-11-01 | 株式会社 資生堂 | Water-in-oil type emulsification cosmetic makeup preparation |
| JP2021020859A (en) * | 2019-07-24 | 2021-02-18 | 株式会社ファンケル | Water-in-oil emulsion cosmetic |
| WO2022245029A1 (en) * | 2021-05-18 | 2022-11-24 | 주식회사 엘지생활건강 | Emulsion or oil-dispersion cosmetic composition containing high content of powder |
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| JP2005097218A (en) * | 2003-09-26 | 2005-04-14 | Shiseido Co Ltd | Foundation |
| JP2005104854A (en) * | 2003-09-29 | 2005-04-21 | Kanebo Ltd | Waer-in-oil type emulsified cosmetic |
| JP2006056852A (en) * | 2004-08-23 | 2006-03-02 | Shiseido Co Ltd | Water-in-oil type emulsion cosmetic |
| JP2006249049A (en) * | 2005-03-14 | 2006-09-21 | Shiseido Co Ltd | Skin care composition |
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| JP2003534361A (en) * | 2000-06-01 | 2003-11-18 | ザ、プロクター、エンド、ギャンブル、カンパニー | Water-in-oil emulsion make-up composition |
| JP2005097218A (en) * | 2003-09-26 | 2005-04-14 | Shiseido Co Ltd | Foundation |
| JP2005104854A (en) * | 2003-09-29 | 2005-04-21 | Kanebo Ltd | Waer-in-oil type emulsified cosmetic |
| JP2006056852A (en) * | 2004-08-23 | 2006-03-02 | Shiseido Co Ltd | Water-in-oil type emulsion cosmetic |
| JP2006249049A (en) * | 2005-03-14 | 2006-09-21 | Shiseido Co Ltd | Skin care composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2018104392A (en) * | 2016-12-28 | 2018-07-05 | ポーラ化成工業株式会社 | Method for modifying powder particle surface |
| WO2018199160A1 (en) * | 2017-04-28 | 2018-11-01 | 株式会社 資生堂 | Water-in-oil type emulsification cosmetic makeup preparation |
| US11400033B2 (en) | 2017-04-28 | 2022-08-02 | Shiseido Company, Ltd. | Water-in-oil type emulsification cosmetic |
| JP2021020859A (en) * | 2019-07-24 | 2021-02-18 | 株式会社ファンケル | Water-in-oil emulsion cosmetic |
| JP7248533B2 (en) | 2019-07-24 | 2023-03-29 | 株式会社ファンケル | Water-in-oil emulsified cosmetic |
| WO2022245029A1 (en) * | 2021-05-18 | 2022-11-24 | 주식회사 엘지생활건강 | Emulsion or oil-dispersion cosmetic composition containing high content of powder |
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