JP5295440B2 - Makeup cosmetics - Google Patents

Abstract

The purpose of the present invention is to provide a makeup cosmetic that does not produce reduced smoothness once applied. This water-in-oil emulsion makeup cosmetic is characterized by comprising (A) 0.1 to 10 mass% of a carboxylic acid-modified silicone having a molecular weight of 800 or lower and including a specific structure, (B) 0.1 to 20 mass% of a non-volatile oil, (C) 1 to 50 mass% of a volatile oil, and (D) 2 to 95 mass% of a powder component.

Description

  The present invention relates to makeup cosmetics, and in particular, to improved usability and scumming.

In makeup cosmetics such as liquid foundation and mascara, a large amount of volatile oil is blended for the purpose of improving skin familiarity when applied to the composition. However, blending a large amount of volatile oil improves skin familiarity during application, but as the volatile oil volatilizes, it may cause scumming (a decrease in smoothness) on the application surface. It was. Therefore, in cosmetics containing a sufficient amount of volatile oil to obtain skin familiarity at the time of application, the volatile oil remains on the skin after volatilization and prevents the occurrence of dusting. Non-volatile oil is blended.
However, when an amount of non-volatile oil sufficient to prevent the above-mentioned scumming is blended into cosmetics, there is a problem that oiliness is generated as the amount of non-volatile oil increases.

JP 2002-80771 A

On the other hand, in cosmetic compositions, a technique for improving the dispersibility of powder components using a dispersant such as organically modified silicone is known. As such an organic modified silicone, for example, a polyether modified silicone is well known, and Patent Document 1 discloses a dispersion stability of a pigment in a liquid oil as a dispersion medium by a carboxylic acid modified silicone having a specific structure. Pigment dispersions and cosmetics with improved properties are disclosed.
Dispersibility improvement of the powder component by the dispersant makes it possible to stably disperse the powder component at a high concentration in a dispersion medium such as oil, so the use of such a dispersant prevents the occurrence of dusting. It was thought that the amount of non-volatile oil necessary for the oil was reduced to such an extent that oiliness did not occur.

However, although the polyether-modified silicone improves the dispersibility of oils and inorganic components as a surfactant, there is a problem that the composition causes a decrease in feeling of use due to stickiness derived from the components in proportion to the blending amount. The carboxylic acid-modified silicone described in Patent Document 1 also improves the dispersion stability of the powder, but at the same time, the viscosity of the composition also increases and the fluidity in the coating film is lacking. I couldn't.
In addition, as another means of suppressing scumming, it is also conceivable to reduce the blending amount of the powder component that causes scumming, but according to the decrease of the powder component, the makeup effect due to the component, The decrease in the feeling of use due to excessive oil content was obvious.
The present invention has been made in view of the above problems, and an object of the present invention is to provide a makeup cosmetic that does not cause dusting after application.

（一般式（１）中、Ｒ^１〜Ｒ^３は、少なくとも１つが−Ｏ−Ｓｉ（Ｒ^４）_３で表される官能基（Ｒ^４は、炭素数１〜６のアルキル基又はフェニル基のいずれかである）であり、その他のＲ^１〜Ｒ^３は同一又は異なっていてもよい置換又は非置換の１価炭化水素基であってもよい。Ａは、Ｃ_ｑＨ_２ｑで表される直鎖状又は分岐鎖状のアルキレン基であり、ｑは０〜２０の整数である。）
（Ｂ）不揮発性油分を０．１〜２０質量％と、
（Ｃ）揮発性油分を１〜５０質量％と、
（Ｄ）粉末成分を２〜９５質量％と、
を含むことを特徴とする。
また、本発明に係るメーキャップ化粧料は、さらに、ＨＬＢが７以下の非イオン性界面活性剤と、水相成分と、を含む油中水型乳化組成物であることが好適である。また、本発明に係るメーキャップ化粧料は、疎水性残留成分量が、粉末成分の配合量に満たないことが好適である。
また、本発明に係るメーキャップ化粧料は、（Ａ）成分が、カルボキシデシルトリシロキサンであることが好適である。 As a result of intensive studies by the inventor in order to achieve the above object, a specific amount of carboxylic acid-modified silicone having a specific structure is blended, so that a small amount of non-volatile oil is blended and a sufficient amount of powder components are blended. Even so, it has been found that generation of dusting accompanying volatilization of the volatile oil can be suppressed, and the present invention has been completed.
That is, the makeup cosmetic according to the present invention is
(A) 0.1 to 10% by mass of a carboxylic acid-modified silicone having a molecular weight of 800 or less represented by the following general formula (1):

(In General Formula (1), at least one of R ^{1 to} R ³ is a functional group represented by —O—Si (R ⁴ ) ₃ (R ⁴ is an alkyl group having 1 to 6 carbon atoms or a phenyl group. The other R ^{1 to} R ³ may be the same or different substituted or unsubstituted monovalent hydrocarbon groups, and A is represented by C _q H _2q. (It is a linear or branched alkylene group, and q is an integer of 0 to 20.)
(B) 0.1-20 mass% of non-volatile oil,
(C) 1-50 mass% of volatile oil,
(D) 2 to 95% by mass of the powder component;
It is characterized by including.
In addition, the makeup cosmetic according to the present invention is preferably a water-in-oil emulsion composition containing a nonionic surfactant having an HLB of 7 or less and an aqueous phase component. Moreover, it is suitable for the makeup cosmetics which concern on this invention that the amount of hydrophobic residual components is less than the compounding quantity of a powder component.
In the makeup cosmetic according to the present invention, the component (A) is preferably carboxydecyltrisiloxane.

  ADVANTAGE OF THE INVENTION According to this invention, the makeup cosmetics without the fear that a scumming will occur after volatilization of a volatile oil can be obtained, without mix | blending a non-volatile oil abundantly. Moreover, since no scumming occurs, a high cosmetic effect can be expected.

In the present invention, “smudge” refers to a squeaky feeling caused by friction when the volatile oil components are volatilized and then brought into direct contact with each other, and means a state lacking smoothness.
First, components (A) to (D) constituting the makeup cosmetic according to the present invention will be described.

上記一般式（１）において、Ｒ^１〜Ｒ^３は、少なくとも１つが−Ｏ−Ｓｉ（Ｒ^４）_３で表される官能基であり、Ｒ^４は、炭素数１〜６のアルキル基又はフェニル基を示す。残りのＲ^１〜Ｒ^３は同一又は異なっていてもよい置換又は非置換の１価炭化水素基を示す。また、Ａは、Ｃ_ｑＨ_２ｑで表される直鎖状又は分岐鎖状のアルキレン基であり、ｑは０〜２０の整数である。
また、上記一般式（１）で表されるカルボン酸変性シリコーンの分子量は８００以下である。 (A) Carboxylic acid-modified silicone The carboxylic acid-modified silicone used in the present invention is represented by the following general formula (1).

In the general formula (1), at least one of R ^{1 to} R ³ is a functional group represented by —O—Si (R ⁴ ) ₃ , and R ⁴ is an alkyl group having 1 to 6 carbon atoms or phenyl Indicates a group. The remaining R ^{1 to} R ³ represent a substituted or unsubstituted monovalent hydrocarbon group which may be the same or different. A is a linear or branched alkylene group represented by C _q H _2q , and q is an integer of 0 to 20.
The molecular weight of the carboxylic acid-modified silicone represented by the general formula (1) is 800 or less.

In the functional group represented by —O—Si (R ⁴ ) ₃ , R ⁴ is either an alkyl group having 1 to 6 carbon atoms or a phenyl group. Examples of the alkyl group having 1 to 6 carbon atoms include methyl, ethyl, n-propyl, i-propyl, n-butyl, i-butyl, s-butyl, t-butyl, pentyl, neopentyl, cyclopentyl, hexyl and the like. Examples include linear, branched or cyclic alkyl groups. Examples of the functional group represented by —O—Si (R ⁴ ) ₃ include —O—Si (CH ₃ ) ₃ , —O—Si (CH ₃ ) ₂ (C ₂ H ₅ ), and —O—Si. (CH ₃ ) ₂ (C ₃ H ₇ ), —O—Si (CH ₃ ) ₂ (C ₄ H ₉ ), —O—Si (CH ₃ ) ₂ (C ₅ H ₁₁ ), —O—Si (CH ₃ ) ₂ (C ₆ H ₁₃ ), —O—Si (CH ₃ ) ₂ (C ₆ H ₅ ), and the like. The functional group is preferably a trialkylsiloxy group, and more preferably a trimethylsiloxy group.
As a more preferable compound, in general formula (1), R ¹ is an alkyl group having 1 to 6 carbon atoms, R ² and R ³ are trialkylsiloxy groups, and q is 4 to 20 Examples include acid-modified silicone. Most preferred is carboxydecyltrisiloxane.

  In the makeup cosmetic according to the present invention, the amount of the carboxylic acid-modified silicone is preferably 0.1 to 10% by mass, more preferably 0.1 to 5% by mass, and still more preferably 0.2 to 2% by mass. If the blending amount is less than 0.1% by mass, the dispersion of the nonvolatile oil may be insufficient and the cosmetic feel may be lowered. Further, even if the blending amount exceeds 10% by mass, the effect of suppressing the scumming of the present invention is obtained, but there is no improvement in the effect according to the increase in the blending amount, and it is used instead by an excessive carboxylic acid-modified silicone. The feeling may be reduced.

  In the makeup cosmetic of the present invention, the molecular weight of the carboxylic acid-modified silicone represented by the general formula (1) is 800 or less, and it is preferable not to use a high molecular weight carboxylic acid-modified silicone having a molecular weight exceeding 800 in combination. . When a high molecular weight carboxylic acid-modified silicone is used in combination, the component may cause an increase in viscosity or stickiness of the composition.

(B) Nonvolatile oil component In this invention, a nonvolatile oil component is an oil component which does not show volatility at room temperature (25 degreeC). The non-volatile oil used in the makeup cosmetic according to the present invention is not particularly limited as long as it is an oil that satisfies the above-described conditions and is usually used in a skin external preparation such as cosmetics and pharmaceuticals. Such non-volatile oils include, for example, avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, sasanca oil, castor oil Oil, flaxseed oil, safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagari oil, Japanese kiri oil, jojoba oil, germ oil, palm oil, palm oil, bird Liquid fats such as glycerin; beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugarcane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced Lanolin, jojoba wax, hard lanolin, shellac wax, POE Waxes such as Norin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether; liquid paraffin, ozokerite, squalane, polybutene, pristane, paraffin, ceresin, squalene, microcrystalline wax, Hydrocarbon oils such as polyethylene wax and hydrogenated olefin oligomers; lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), Higher fatty acids such as docosahexaenoic acid (DHA); linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol) , Behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, etc .; branched chain alcohol (eg monostearyl glycerin ether (batyl alcohol), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyldodecanol, iso Higher alcohols such as stearyl alcohol, octyldodecanol, etc .; glyceryl diisostearate, isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, Hexyldecyl dimethyloctanoate, cetyl lactate, myristyl lactate, lanolin acetate, isocetyl stearate, iso Isocetyl stearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, cetyl 2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, malic acid Diisostearyl, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid trimethylolpropane, triisostearic acid trimethylolpropane, triisostearic acid glyceryl, tri-2-ethylhexanoic acid glyceryl, tetra-2-ethylhexane Acid pentaerythritol, glycerin tri-2-ethylhexanoate, glyceryl trioctanoate, trimethylolpropane trioctanoate, glycerin triisopalmitate Cetyl 2-ethylhexanoate, 2-ethylhexyl palmitate, glyceryl trimyristate, glycerol tri-2-heptylundecanoate, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, adipine Diisobutyl acid, N-lauroyl-L-glutamic acid-2-octyldodecyl, N-lauroyl-L-glutamic acid di (phytostearyl 2-octyldodecyl), di-2-heptylundecyl adipate, ethyl laurate, sebacic acid Synthesis of di-2-ethylhexyl, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyldecyl adipate, diisopropyl sebacate, 2-ethylhexyl succinate, triethyl citrate, etc. Ether oil; it includes ultraviolet absorbers such as benzophenone derivatives; silicone resins such as trimethylsiloxysilicic acid; dimethylpolysiloxane, methylphenyl polysiloxane, linear polysiloxanes such as methyl hydrogen polysiloxane. In the makeup cosmetic according to the present invention, the non-volatile oil can be blended in one or more kinds. In the present invention, it is particularly preferable to use a liquid oil component at room temperature (25 ° C.) as the non-volatile oil component, and it is more preferable to include a liquid silicone oil such as a chain polysiloxane.
Examples of such commercially available silicone oils include KF-96A-6CS, silicone KF-56, KF-96A-20CS, and KF-96A-100CS (all manufactured by Shin-Etsu Chemical Co., Ltd.).

  In the makeup cosmetic according to the present invention, the amount of the non-volatile oil component is preferably 0.1 to 20% by mass, more preferably 1 to 10% by mass, and still more preferably 1 to 5% by mass. It is. If the blending amount is less than 0.1% by mass, dusting may occur as the volatile oil component volatilizes. Moreover, when the said compounding quantity exceeds 20 mass%, oiliness and stickiness may arise in cosmetics.

(C) Volatile oil The volatile oil used in the makeup cosmetic according to the present invention is particularly volatile oil as long as it exhibits volatility at room temperature (25 ° C.) and is usually used in skin external preparations such as cosmetics and pharmaceuticals. Not limited. Examples of such volatile oils include chain polysiloxanes such as decamethyltetrasiloxane, hexamethyldisiloxane, and dodecamethylpentasiloxane, and cyclic polysiloxanes such as octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane. Examples include volatile silicone oils; light liquid isoparaffins (isohexadecane) such as shell sol (shell chemistry) and isopar (esso chemistry). In the makeup cosmetic according to the present invention, the volatile oil can be blended in one or more kinds. In the present invention, it is particularly preferable that the volatile oil contains volatile silicone such as cyclic polysiloxane such as decamethyltetrasiloxane.
Further, in the makeup cosmetic according to the present invention, the blending amount of the volatile oil is preferably 1 to 50% by mass, more preferably 5 to 35% by mass, and further preferably 10 to 30% by mass. . When the blending amount is less than 1% by mass, the feeling of use due to the volatile oil such as skin familiarity during application may be insufficient. Moreover, when the said compounding quantity exceeds 50 mass%, the compounding quantity of the non-volatile oil part which can be mix | blended will reduce relatively, and it may accelerate | stimulate the dust after a volatile oil part volatilizes.

(D) Powder component If the powder component used for the makeup cosmetics which concern on this invention can be used for cosmetics, a pharmaceutical, and a quasi-drug, there will be no restriction | limiting in particular. Such powder components include, for example, talc, kaolin, sericite (sericite), bentonite, organically modified bentonite, muscovite, phlogopite, synthetic mica, red mica, biotite, calcined talc, calcined sericite, calcined Muscovite, calcined phlogopite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, zeolite, barium sulfate, calcined Calcium sulfate (baked gypsum), calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, metal soap (for example, zinc myristate, calcium palmitate, aluminum stearate, etc.), boron nitride, photochromic titanium oxide ( Titanium dioxide with sintered iron), reduced zinc white; organic powder (eg, silicone elastomer powder, silicone powder, silicone resin-coated silicone elastomer powder, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, Polystyrene powder, copolymer resin powder of styrene and acrylic acid, benzoguanamine resin powder, polytetrafluoroethylene powder, cellulose powder, etc.); inorganic white pigment (eg, titanium dioxide, zinc oxide, etc.); inorganic red pigment (eg, , Iron oxide (Bengara), iron titanate, etc.); inorganic brown pigment (for example, γ-iron oxide, etc.); inorganic yellow pigment (for example, yellow iron oxide, loess); inorganic black pigment (for example, black) Iron oxide, low-order titanium oxide, etc.); inorganic purple pigments (eg, mango violet, cobalt bai) Inorganic green pigments (eg, chromium oxide, chromium hydroxide, cobalt titanate, etc.); inorganic blue pigments (eg, ultramarine blue, bitumen, etc.); pearl pigments (eg, bismuth oxychloride, fish scale foil, mica) Titanium, iron oxide-coated mica titanium, low-order titanium oxide-coated mica titanium, photochromic titanium mica, talc, glass, synthetic fluorine phlogopite, silica, bismuth oxychloride, etc. instead of mica as substrate In addition to titanium oxide, low-order titanium oxide, colored titanium oxide, iron oxide, alumina, silica, zirconia, zinc oxide, cobalt oxide, aluminum, etc. coated as a functional pearl pigment, resin particles on the surface of the pearl pigment Coated with aluminum hydroxide particles on the surface of the pearl pigment (JP-A-11-92688) (JP 2002-146238), pearl pigment surface coated with zinc oxide particles (JP 2003-261421), pearl pigment surface coated with barium sulfate particles (JP 2003-61229), etc .; metal Powder pigments (for example, aluminum powder, copper powder, etc.); Organic pigments such as zirconium, barium or aluminum lake (for example, red 201, red 202, red 204, red 205, red 220, red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401, Blue 404, Red 404, Red 104, Red 106, Red 227, Red 230, Red 401 No., Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green 3 And Blue No. 1, etc.); natural colors (e.g., chlorophyll, beta-carotene, etc.) and the like.
In addition, the above powder component has been hydrophobized using a hydrophobizing agent such as silicone, dextrin fatty acid ester, higher alcohol, fatty acid ester, metal soap, amino acid, alkyl phosphoether, or fluorine compound. May be.
In the makeup cosmetic according to the present invention, the powder components can be blended in one or a combination of two or more. In the present invention, it is particularly preferable to use an inorganic powder subjected to a hydrophobic treatment or a hydrophobic organic powder.

  In the makeup cosmetic according to the present invention, the amount of the powder component is preferably 2 to 95% by mass, more preferably 5 to 70% by mass, and further preferably 10 to 50% by mass. If the blending amount is less than 2% by mass, the makeup effect as a makeup cosmetic may be insufficient. Moreover, when the said compounding quantity exceeds 95 mass%, a composition will become powdery by an excess powder component, and it will become easy to produce a scouring.

  In addition to the above essential components, the makeup cosmetics according to the present invention are components that are usually used in skin external preparations such as cosmetics and pharmaceuticals, for example, anionic surfactants and cationic interfaces, within the range not impairing the effects of the present invention. Activators, amphoteric surfactants, nonionic surfactants, humectants, water-soluble polymers, thickeners, film agents, UV absorbers other than those above, sequestering agents, lower alcohols, polyhydric alcohols, sugars , Amino acids, organic amines, polymer emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, antioxidant auxiliaries, fragrances, water, etc., as necessary, can be produced by conventional methods. .

The dosage form of the makeup cosmetic according to the present invention is not limited as long as the above essential components are blended, and it is particularly preferable to use an oily cosmetic or a water-in-oil emulsified cosmetic.
When the water-in-oil emulsified cosmetic is used, the cosmetic of the present invention includes, for example, an oil phase component containing the essential components and a nonionic surfactant having an HLB (hydrophilic / lipophilic balance) of 7 or less. And an aqueous phase component containing water and an optional aqueous component are added and emulsified.

  Examples of the lipophilic nonionic surfactant having an HLB of 7 or less include glyceryl monostearate [HLB3.8], glyceryl monooleate [HLB3.7], glyceryl monoisostearate [HLB5], and sesquiisostearic acid. Glyceryl fatty acid esters such as glyceryl, glyceryl monooleate [HLB3.4], glyceryl dioleate [HLB1.8], glyceryl sesquioleate; polyglyceryl diisostearate [HLB6.0], polyglyceryl triisostearate [HLB4.0], Decaglyceryl pentaisostearate [HLB3.5], decaglyceryl pentaoleate [HLB3.5], diglyceryl monoisostearate [HLB4.7], diglyceryl isostearate [HLB5.5], di Polyglycerin fatty acid esters such as diglyceryl sotearate [HLB3.7], diglyceryl monooleate [HLB5.5], diglyceryl dioleate [HLB3.7]; sorbitan monooleate [HLB4.3], tristearin Sorbitan fatty acids such as sorbitan acid [HLB2.1], sorbitan trioleate [HLB1.7], sorbitan isostearate [HLB5.0], sorbitan sesquiisostearate [HLB4.5], sorbitan sesquioleate [HLB3.7], etc. Esters: POE (5) [HLB 6.0], POE (7.5) [HLB 6.0], POE (10) [HLB 6.5] polyoxyethylene hydrogenated castor oil such as hydrogenated castor oil; dipolyhydroxystearic acid Esters, dipolyhydroxystearin High molecular weight lipophilic active agents such as polyglyceryl-2 (manufactured by Cognis: PGPH), PEG30 dipolyhydroxystearate [HLB5.5] (manufactured by Unikema: Aracel P135); cetyl polyether-modified silicone (for example, manufactured by Goldschmidt) : ABIL EM90), polyether-modified silicone (for example, Shin-Etsu Chemical Co., Ltd .: KF6017), cross-linked polyether-modified silicone (for example, Shin-Etsu Chemical Co., Ltd .: KSG series), and other polyether-based silicones; polyglycerin-modified Examples include silicones and polyglycerin-based silicones such as alkyl co-modified polyglycerin-modified silicones. In the make-up cosmetic according to the present invention, one or more nonionic surfactants having an HLB or less can be blended, and in particular, polyether-modified silicone (for example, manufactured by Shin-Etsu Chemical Co., Ltd .: It is preferable to include KF6017).

  In the makeup cosmetic according to the present invention, the blending amount of the nonionic surfactant is in accordance with the blending amount in a known water-in-oil emulsified cosmetic, but preferably 0.1 to 5% by mass. Preferably it is 1-5 mass%, More preferably, it is 1-3 mass%.

Moreover, in the makeup cosmetics which concern on this invention, it is thought that a volatile oil will volatilize at the time of application | coating of a composition. Therefore, in the composition after application, the powder component is dispersed in the residual oil component other than the volatile oil component, that is, the hydrophobic residual component. Therefore, it is preferable that the hydrophobic residual component, particularly the non-volatile oil component, is blended to such an extent that the powder component can be sufficiently dispersed even in the composition after coating.
As long as each component is used within the above-mentioned blending amount range, the suppression of dusting is sufficient, but in particular, it has a feeling of use such as good skin cosmetics and uniformity of the coating film. In view of this, the amount of the hydrophobic residual component is less than the amount of the powder component, that is,
Hydrophobic residual component amount / powder component amount <1
It is preferable to prepare such that
In addition, as above-mentioned, the hydrophobic residual component in this invention is an oil-based component (oil phase component) which remains on a coating object after application | coating, and means oil-based components other than the volatile oil component in a composition. Accordingly, not only the non-volatile oil component but also, for example, a carboxylic acid-modified silicone and a nonionic surfactant having an HLB of 7 or less are included in this component as an oil component.

The composition of the present invention can take any properties such as liquid, semi-solid, solid, and powder depending on the components to be blended. However, in consideration of the effects of the present invention, the composition is particularly preferably liquid.
Examples of the product form as the makeup cosmetic of the present invention include foundation, makeup base, eye shadow, mascara, lipstick, teak color, face powder, body powder, perfume powder, baby powder, pressed powder, deodorant powder. , Interesting and the like. In the present invention, the form of foundation is particularly preferred, and it can be suitably used as a liquid (liquid) foundation.

  EXAMPLES Hereinafter, although an Example is given and this invention is demonstrated in more detail, this invention is not limited to these. In addition, unless otherwise indicated, the numerical value in each table | surface represents the mass%.

  The composition (liquid foundation) according to the formulation of each test example described in Table 1 below was used by 10 professional panels, and the feeling of use (good skin familiarity during coating, uniformity of coating film, coating 1) An answer was obtained regarding the feeling of squeakiness (no squeaking) after time, and the feeling of use of each composition was evaluated as follows according to the number of people who answered that it was excellent. The results are shown in Table 1.

<Good skin familiarity during application>
A: 9 to 10 people answered that skin familiarity during application was good.
○: Six to eight people answered that skin familiarity during application was good.
(Triangle | delta): 3-5 persons answered that the skin familiarity at the time of application | coating was good.
Δ ×: 1 to 2 persons answered that skin familiarity during application was good.
X: 0 responded that skin familiarity at the time of application was good.

<Uniformity of coating film>
A: 9 to 10 persons answered that the coating film was uniform.
○: Six to eight persons answered that the coating film was uniform.
Δ: 3 to 5 persons answered that the coating film was uniform.
Δ ×: One or two persons answered that the coating film was uniform.
X: 0 responded that the coating film was uniform.

<Lack of squeaking after 1 hour of application>
A: 9 to 10 persons answered that they did not feel squeaky after 1 hour.
○: Six to eight people answered that they did not feel squeaky after 1 hour.
Δ: 3 to 5 persons answered that they did not feel squeaky after 1 hour.
Δ ×: One or two persons answered that they did not feel squeaky after 1 hour.
X: 0 responded that they did not feel squeaky after 1 hour.

＊１ 下記一般式（１）において、Ｒ^１がメチル基、Ｒ^２及びＲ^３がトリメチルシロキシ基、Ａが直鎖状のＣ_８Ｈ_１６であるカルボン酸変性シリコーン（分子量４０６）

＊２ 下記式で表される高分子量のカルボン酸変性シリコーン（分子量１０７２）

* 1 In the following general formula (1), R ¹ is a methyl group, R ² and R ³ are trimethylsiloxy groups, and A is a linear C ₈ H ₁₆ (molecular weight 406)

* 2 High molecular weight carboxylic acid-modified silicone represented by the following formula (molecular weight 1072)

As shown in Table 1 above, in Examples 1-3 to 1-6 in which 0.1 to 10% by mass of carboxydecyltrisiloxane was blended as the specific carboxylic acid-modified silicone of the present invention, all the items were highly evaluated. It became.
On the other hand, in Test Example 1-1 in which carboxydecyltrisiloxane was not blended, and in Test Example 1-2 in which only 0.05% by mass of the component was blended, (B) for the powder component of (D) Since the amount of dimethylpolysiloxane, which is a non-volatile oil component, was small, non-uniformity of the coating film and squeaky sensation due to excessive powder components were recognized. Further, in Test Example 1-7 in which 15% by mass of carboxydecyltrisiloxane was blended, the familiarity of the skin at the time of application with (C) volatile oil was impaired due to the excess of this component.

  Furthermore, in Test Example 1-8 using a high molecular weight carboxylic acid-modified silicone instead of carboxydecyltrisiloxane, the evaluation was low for any item, and Test Example 1 in which the component was used in combination with carboxydecyltrisiloxane. In 9, the evaluation of each item was improved, but the effects were all insufficient. Further, in Test Example 1-10 in which the amount of the polyether-modified silicone used as the surfactant was increased by that amount without using carboxydecyltrisiloxane, compared with the test example using carboxydecyltrisiloxane, The evaluation was low.

  From the above, the carboxylic acid-modified silicone having a specific structure promotes the action of suppressing dusting by an appropriate amount of blending, and on the other hand, does not impair the good usability when applied with volatile oil. it is obvious. Therefore, the present invention blends 0.1 to 10% by mass of the carboxylic acid-modified silicone having the specific structure, so that the non-volatile oil can be ground without using the volatile oil. Can be sufficiently suppressed.

About the composition (liquid foundation) of each test example of Table 2 below, an actual use test was performed in the same manner as described above, and the feeling of use was evaluated according to the same criteria as described above. The results are shown in Table 2.

Comparing Test Examples 2-1 to 2-4 in which carboxydecyltrisiloxane was blended with Test Examples 2-5 to 2-8 in which carboxydecyltrisiloxane was not blended, in the case of the former, dimethylpolysiloxane, which is a non-volatile oil, was reduced to 0. When 1% by mass was added, the squeaky feeling was suppressed, but the latter did not eliminate the squeaky feeling until 20% by mass was added. In addition, as shown in Test Example 2-9, the familiarity of the skin and the uniformity of the coating film considered to be due to decamethylcyclopentasiloxane, which is a volatile oil component, are determined based on the results of other test examples. It is thought that it decreases as the blending amount increases. Therefore, in order to obtain a composition that has good skin conformity and uniformity of the coating film and does not feel squeaky, (A) 0.1 to 10% by mass of carboxylic acid-modified silicone having a specific structure, (C) It is preferable to blend the nonvolatile oil component in an amount of 0.1 to 20% by mass.
In addition, from the results of Test Examples 2-1 to 2-4, in the present invention, the hydrophobic residual component amount and the powder component amount are set so that the hydrophobic residual component amount / powder component amount <1. It is apparent that the makeup cosmetic has (skin-familiar skinness and uniformity of coating film).

Although the formulation example of the makeup cosmetics of this invention is described below, this invention is not limited to these.
<Prescription example 1 makeup foundation (solid type)>
(Compounding ingredients) (mass%)
(1) Hydrophobized talc 25
(2) Mica remaining amount (3) Zinc oxide 3
(4) Fine particle titanium oxide 1
(5) Hydrophobized titanium oxide 11
(6) Hydrophobized yellow iron oxide 2.7
(7) Hydrophobized red iron oxide 1
(8) Hydrophobized black iron oxide 0.25
(9) Barium sulfate 6
(10) Crosslinked dimethicone copolymer 8
(11) Isooctyl methoxycinnamate 1
(12) Hydrogenated olefin oligomer 2.5
(13) Methylphenyl polysiloxane (Shin-Etsu Chemical Co., Ltd. Silicone F-56)
2
(14) Decamethylcyclopentasiloxane 5
(15) Diisostearyl malate 3
(16) Sorbitan sesquiisostearate 1.5
(17) A carboxylic acid-modified silicone in which, in the general formula (1), R ¹ is a methyl group, R ² and R ³ are trimethylsiloxy groups, and A is a linear alkylene group in which q = 8
0.5
(18) Paraben 0.2
Production method: (1) to (10) and (18) were mixed and ground. Thereafter, the oils (11) to (17) warmed to 80 ° C. were added and mixed. The obtained powder was molded to obtain the desired foundation.

<Prescription Example 2 Liquid Foundation>
(Compounding ingredients) (mass%)
(1) Decamethylcyclopentasiloxane 20
(2) Isohexadecane 10
(3) Dimethylpolysiloxane (Shin-Etsu Chemical Co., Ltd. KF-96A-20CS)
5
(4) Polyether-modified silicone 2
(5) Carboxylic acid-modified silicone in which R ¹ is a propyl group, R ² and R ³ are trimethylsiloxy groups, and A is a linear alkylene group with q = 15 in the general formula (1)
1
(6) Organically modified bentonite 1.5
(7) Polymethylmethacrylate spherical powder 5
(8) Hydrophobized yellow iron oxide 2
(9) Hydrophobized red iron oxide 1
(10) Hydrophobized black iron oxide 0.2
(11) Hydrophobized titanium oxide 8
(12) Ion exchange water remaining amount (13) Glycerin 2
(14) 1,3-butylene glycol 5
(15) Phenoxyethanol 0.5
Production method: (1) to (6) were mixed and dispersed, and (7) to (11) were added and dispersed therein. Then, the water phase of (12)-(15) was added and emulsified, and the target liquid foundation was obtained.

<Prescription Example 3 Cosmetic Base>
(Compounding ingredients) (mass%)
(1) Decamethylcyclopentasiloxane 27
(2) Dimethylpolysiloxane (Shin-Etsu Chemical Co., Ltd. KF-96A-6CS)
5
(3) Carboxylic acid-modified silicone 3 wherein R1 is a methyl group, R2 is a trimethylsiloxy group, R3 is an ethyl group, and A is a linear alkylene group with q = 8 in the general formula (1).
(4) Polyether-modified silicone 3
(5) Organically modified bentonite 1.5
(6) Polymethylmethacrylate spherical powder 5
(7) Hydrophobized titanium 2
(8) Organopolysiloxane elastomer spherical powder 5
(9) Hydrophobized black iron oxide 0.2
(10) Hydrophobized talc 5
(11) Remaining ion exchange water (12) Glycerin 2
(13) 1,3-butylene glycol 5
(14) Phenoxyethanol 0.5
Production method: (1) to (5) were mixed and dispersed, and (6) to (10) were added and dispersed therein. Then, the water phase of (11)-(14) was added and emulsified, and the target cosmetic base was obtained.

<Prescription Example 4 Eye Shadow>
(Compounding ingredients) (mass%)
(1) Ceresin 1
(2) Decamethylcyclopentasiloxane Residual amount (3) Polyoxyethylene / methylpolysiloxane copolymer 2
(4) Methylphenylpolysiloxane (Shin-Etsu Chemical Co., Ltd. Silicone KF-56)
5
(5) Macadamia nut oil 1
(6) Sorbitan sesquiisostearate 2
(7) Carboxylic acid-modified silicone in which R1 is a methyl group, R2 and R3 are trimethylsiloxy groups, and A is a branched alkylene group in which q = 8 in the general formula (1)
3
(8) Synthetic phlogopite 0.1
(9) Bengala-coated mica (pearl) 1
(10) Bengala carmine-coated mica titanium (pearl agent) 7
(11) Bengala black iron oxide coated mica titanium (pearl agent) 0.1
(12) Mica 30
(13) Mica titanium (pearl agent) 4
(14) Black iron oxide-coated mica titanium (pearl agent) appropriate amount (15) DL-α-tocopherol acetate 0.1
(16) D-δ-tocopherol appropriate amount (17) ultramarine pink 1
(18) Dimethyl distearyl ammonium hectorite 3
(19) Trimethylsiloxysilicic acid 3
(20) Fragrance Appropriate amount Production method: (8) to (14) and (17) to (19) were mixed and ground. Thereafter, (1) to (7) and (15) to (16) and (20) warmed to 80 ° C. were added and mixed. The obtained powder was molded to obtain the desired eye shadow.

<Prescription Example 5 Lipstick>
(Compounding ingredients) (mass%)
(1) Microcrystalline wax 1
(2) Ceresin 7
(3) Candelilla wax 3
(4) Glyceryl triisostearate 10
(5) Cyclic silicone (tetramer) 5
(6) Diisostearyl malate 2
(7) Glyceryl diisostearate 1
(8) A carboxylic acid-modified silicone in which R1 is a propyl group, R2 and R3 are trimethylsiloxy groups, and A is a linear alkylene group in which q = 15 in the general formula (1)
2
(9) Trimethylolpropane trioctanoate 0.5
(10) Glyceryl tri-2-ethylhexanoate Residue (11) Calcium hydrogen phosphate 1
(12) Silicone-coated pigment (Bengara, titanium oxide, etc.) Appropriate amount (13) Barium sulfate 2
(14) Carmine-coated mica titanium 2
(15) Dye proper amount (16) Heavy liquid isoparaffin 10
Production method: (1) to (10) and (15) to (16) were heated and dissolved at 80 ° C or higher, and when (11) to (14) were added, mixing and stirring were performed. The mixture was filled in a container and then cooled to obtain a desired lipstick.

<Prescription Example 6 Mascara>
(Compounding ingredients) (mass%)
(1) Light isoparaffin 10
(2) Dimethylpolysiloxane (Shin-Etsu Chemical Co., Ltd. KF-96A-100CS)
1
(3) Decamethylcyclopentasiloxane 12
(4) Trimethylsiloxysilicate 12
(5) Carboxylic acid modified silicone in which R1 is a methyl group, R2 is a trimethylsiloxy group, R3 is an ethyl group, and A is a branched alkylene group in which q = 15 in the general formula (1)
2.5
(6) N-lauroyl-L-glutamate di (phytostearyl 2-octyldodecyl)
Appropriate amount (7) polyethylene glycol dioleate 2
(8) Diglyceryl diisostearate 1
(9) Mica titanium 2
(10) Aluminum stearate appropriate amount (11) Sodium bicarbonate 0.1
(12) DL-α-tocopherol acetate 0.1
(13) p-hydroxybenzoate appropriate amount (14) sodium dehydroacetate appropriate amount (15) black iron oxide 10
(16) Dimethyl distearyl ammonium hectorite 5
(17) Polyvinyl acetate emulsion 21
(18) Purified water remaining amount (19) Ethyl alcohol 5
(20) Seaweed extract 0.1
(21) Methyl polysiloxane emulsion Appropriate amount Manufacturing method: Add the aqueous mixture of (17) to (21) previously mixed to the oily mixture in which (1) to (16) are well mixed, and emulsify by stirring. As a result, the target mascara was obtained.

Claims (4)

(A) 0.1 to 10% by mass of a carboxylic acid-modified silicone having a molecular weight of 800 or less represented by the following general formula (1):

(In General Formula (1), at least one of R ^{1 to} R ³ is a functional group represented by —O—Si (R ⁴ ) ₃ (R ⁴ is an alkyl group having 1 to 6 carbon atoms or a phenyl group. And the other R ^{1 to} R ³ represent a substituted or unsubstituted monovalent hydrocarbon group which may be the same or different, and A represents a straight chain represented by C _q H _2q Or a branched alkylene group, and q is an integer of 0 to 20.)
(B) 0.1-20 mass% of non-volatile oil,
(C) 1-50 mass% of volatile oil,
(D) 2 to 95% by mass of the powder component;
Makeup cosmetics characterized by containing.   The makeup cosmetic according to claim 1, which is a water-in-oil emulsion composition comprising a nonionic surfactant having an HLB of 7 or less and an aqueous phase component.   The makeup cosmetic according to claim 1 or 2, wherein the amount of the hydrophobic residual component is less than the blending amount of the powder component.   (A) A component is carboxydecyl trisiloxane, The water-in-oil type emulsion makeup cosmetics in any one of Claims 1-3 characterized by the above-mentioned.