JP2007070273A - Deodorizing cosmetic - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a deodorizing cosmetic compounded with an antibacterial zeolite and having excellent deodorizing effect, odor eliminating effect, preparation stability and feeling in use. <P>SOLUTION: The deodorizing cosmetic contains an antibacterial zeolite and nano-porous silica or an antibacterial zeolite, nano-porous silica and zinc oxide. <P>COPYRIGHT: (C)2007,JPO&INPIT

Description

  The present invention relates to a deodorant cosmetic. More specifically, it is a deodorant cosmetic compounded with an antibacterial zeolite, has an excellent deodorizing effect compared with conventional deodorant cosmetics, and is excellent in formulation stability such as dispersibility and discoloration resistance of powder components, Further, the present invention relates to a deodorant cosmetic material that is extremely excellent in use feeling.

  The deodorant cosmetic composition of the present invention is an external preparation for the purpose of deodorization, and is preferably used as a deodorant cosmetic composition, an antiperspirant cosmetic composition, a deodorizing cosmetic composition or the like.

  The deodorant cosmetic is a cosmetic used to prevent, suppress, or eliminate unpleasant body odor emission and secretion. As the product form, generally, lotion, cream, powder, stick, aerosol, and the like are used.

  In general, unpleasant body odor, which is the object of deodorization, is the cause of odor due to decomposition of sweat. The following methods are known for preventing body odor caused by sweat.

(1) Deodorizing method by astringent action It suppresses the generation of sweat with a strong astringent action and indirectly prevents body odor. For example, astringents such as zinc sulfocolate, citric acid, or various aluminum compounds are often used. In addition, ethyl alcohol has an astringent action. Among these, an aluminum compound (aluminum hydroxychloride) is often used, and in the case of an aerosol type, a complex with propylene glycol having excellent compatibility with freon gas has been developed.

(2) Deodorizing method by masking action Normal body odor can be removed by masking with perfume or eau de cologne. There is also a method of promoting the deodorizing effect by blending the above-mentioned disinfectant with perfume or eau de cologne.
Antibacterial zeolite powder is blended in skin preparations such as cosmetics and quasi-drugs as preservatives and deodorants.

(3) Deodorizing method by bactericidal action It is due to the decomposition action of bacteria that sweat decomposes and generates odor. Therefore, the germicide prevents the growth of bacteria, and directly prevents sweat decomposition and odor. For example, TMTD (tetramethylthiuram disulfide), benzalkonium chloride, halocarban and the like are well known. In addition, zinc white, essential oils, fragrances, chlorophyll compounds, etc. also have antibacterial action and exert deodorizing effect.

And as a deodorizing method by the bactericidal action of the above (3), an antibacterial spray composition using a bactericidal action of antibacterial zeolite (see Patent Document 1) and a deodorizing cosmetic (see Patent Document 2) have been developed. .
Moreover, the technique which mix | blended silicone with the antibacterial zeolite is disclosed as a deodorant cosmetics which improved discoloration resistance (refer patent document 3).
JP-A-63-250325 JP-A-8-26956 JP-A-8-92051

However, deodorant cosmetics using antibacterial zeolite have a problem that when metal compounds such as zinc oxide are used, discoloration occurs and it is difficult to maintain the stability of the preparation. In addition, there is a problem that the usability becomes white on the skin and stands out (white residue).
Therefore, development of deodorant cosmetics that have excellent formulation stability, excellent usability, and a good deodorizing effect is desired.

  In order to solve the above-mentioned problems, the inventors have conducted intensive research on the second component to be blended in combination with the antibacterial zeolite. It has been found that an excellent deodorant cosmetic can be obtained. Furthermore, it has also been found that a deodorizing effect superior to conventional ones can be obtained by combining zinc oxide with antibacterial zeolite and specific nanoporous silica, and the present invention has been completed.

  An object of the present invention is to provide a deodorant cosmetic that is excellent in formulation stability and usability and has an excellent deodorizing effect.

  That is, the present invention provides an anti-odor cosmetic comprising an antibacterial zeolite and nanoporous silica having a hexagonal crystal structure.

  The present invention also provides a deodorizing cosmetic comprising antibacterial zeolite, nanoporous silica having a hexagonal crystal structure, and zinc oxide.

  Furthermore, the present invention provides the above deodorant cosmetic, wherein the nanoporous silica has a pore diameter of 1 to 7 nm.

  The present invention also provides the above deodorant cosmetic, wherein the content of the antibacterial zeolite is 0.1 to 90% by mass with respect to the total amount of the deodorant cosmetic.

  Furthermore, the present invention provides the above deodorant cosmetic, wherein the content of the nanoporous silica is 0.1 or more by mass ratio with respect to the content of the antibacterial zeolite. .

  Moreover, this invention provides said deodorant cosmetics whose content of the said zinc oxide is 0.1-90 mass% with respect to the deodorant cosmetics whole quantity.

  Furthermore, the present invention provides the deodorant cosmetic described above, wherein the antibacterial metal ion in the antibacterial zeolite is one or more selected from silver, copper and zinc ions. Is.

  In the present invention, the average particle diameter of the antibacterial zeolite is 10 μm or less, and the particle size distribution of which the particle diameter exceeds 15 μm is 20% or less, and the average particle diameter of the nanoporous silica is 0.01 to The deodorant cosmetic composition described above is provided having a thickness of 50 μm.

The deodorant cosmetic composition of the present invention is excellent in deodorization effect, usability, and light resistance. In particular, since the dispersibility of powders such as antibacterial zeolite, nanoporous silica, and zinc oxide is good, the powders do not aggregate and are excellent in usability (no roughness). Excellent resistance to discoloration.
In addition, although antibacterial zeolite has an effect of suppressing the generation of odor due to an antibacterial action, it has not been satisfactory with respect to the deodorizing effect of eliminating the odor originally present. The deodorant cosmetic composition of the present invention is particularly excellent in deodorizing effect. Furthermore, when the deodorant cosmetic composition of the present invention is applied to a powder spray, a particularly excellent feeling of use can be obtained.

  Hereinafter, the present invention will be described in detail.

  As the antibacterial zeolite used in the present invention, a zeolite powder holding an antibacterial metal ion in an ion-exchangeable portion of the zeolite is used. That is, it is a zeolite powder in which some or all of the ion-exchangeable ions of the zeolite are substituted with an antibacterial metal. In the present invention, zeolites substituted with ammonium ions together with antibacterial metal ions are also preferred.

The zeolite may be either natural zeolite or synthetic zeolite. Zeolites is generally an aluminosilicate having a three-dimensional skeleton structure, the formula is displayed in _{XM 2 / n O · Al 2} O 3 · YSiO 2 · ZH 2 O. In this general formula, M represents an ion-exchangeable ion, and is usually a monovalent or divalent metal ion. n is the valence of the (metal) ion. X and Y are the metal oxide and silica coefficient, respectively, and Z is the number of crystal water.

  Specific examples of the zeolite include, for example, A-type zeolite, X-type zeolite, Y-type zeolite, T-type zeolite, high silica zeolite, sodalite, mordenite, analcym, clinoptilolite, chabasite, erionite. Etc. The ion exchange capacities of these zeolites are as follows: A-type zeolite 7 meq / g, X-type zeolite 6.4 meq / g, Y-type zeolite 5 meq / g, T-type zeolite 3.4 meq / g, Sodalite 11.5 meq / G, mordenite 2.6 meq / g, analsim 5 meq / g, clinoptilolite 2.6 meq / g, chabasite 5 meq / g, erionite 3.8 meq / g. Both have sufficient capacity for ion exchange with antibacterial metal ions and ammonium ions.

  Examples of ion-exchangeable ions in the zeolite include sodium ions, calcium ions, potassium ions, magnesium ions, and iron ions. In addition, the antibacterial metal ion substituted with these ions is, for example, silver, copper, zinc, mercury, tin, lead, bismuth, cadmium, chromium, or thallium, and preferably silver, copper, or zinc Ions, more preferably silver ions.

  The antibacterial metal ion is preferably contained in the zeolite in an amount of 0.1 to 15% by mass from the viewpoint of antibacterial properties. For example, an antibacterial zeolite containing 0.1 to 15% by mass of silver ions and 0.1 to 8% by mass of copper ions or zinc ions is preferable. On the other hand, ammonium ion can be contained in the zeolite up to 20% by mass, but from the viewpoint of effectively preventing discoloration of the zeolite, 0.5 to 5% by mass in the zeolite is more preferable, 2% by mass is more preferable. In addition, the mass% is a mass percentage in the zeolite on the basis of 110 ° C. drying.

  In the present invention, commercially available antibacterial zeolite can be used. For example, the antibacterial zeolite is prepared as follows. That is, the zeolite is brought into contact with a mixed aqueous solution containing antibacterial metal ions such as silver ions, copper ions, and zinc ions prepared in advance to replace the ions capable of ion exchange in the zeolite with the ions. The contact can be carried out at 10 to 70 ° C., preferably 40 to 60 ° C. for 3 to 24 hours, preferably 10 to 24 hours by a batch method or a continuous method (for example, a column method). In addition, it is appropriate to adjust the pH of the mixed aqueous solution to 3 to 10, preferably 5 to 7. This adjustment is preferable because precipitation of silver oxide or the like on the zeolite surface or pores can be prevented. Each ion in the mixed aqueous solution is usually supplied as a salt. For example, silver ions are silver nitrate, silver sulfate, silver perchlorate, silver acetate, diammine silver nitrate, diammine silver sulfate, etc., and copper ions are copper (II) nitrate, copper perchlorate, copper acetate, tetracyano. Examples include potassium copperate and copper sulfate. Zinc ions include zinc nitrate (II), zinc sulfate, zinc perchlorate, zinc thiocyanate, and zinc acetate. Mercury ions include mercury perchlorate, mercury nitrate, and acetic acid. Mercury, tin ions such as tin sulfate, lead ions such as lead sulfate and lead nitrate, bismuth ions such as bismuth chloride and bismuth iodide, cadmium ions include cadmium perchlorate, cadmium sulfate, Cadmium nitrate and cadmium acetate. Chromium ions are chromium perchlorate, chromium sulfate, ammonium sulfate, chromium nitrate, etc., and thallium ions are thallium perchlorate. It can be used thallium sulfate, thallium nitrate, thallium acetate, and the like.

  The content of antibacterial metal ions in the zeolite can be appropriately controlled by adjusting the concentration of each ion (salt) in the mixed aqueous solution. For example, when the antibacterial zeolite contains silver ions, the silver ion content in the mixed aqueous solution is adjusted to 0.002 M / l to 0.15 M / l, so that the silver ion content is appropriately 0.1 to 5 mass. % Antibacterial zeolite can be obtained. When the antibacterial zeolite further contains copper ions and zinc ions, the copper ion concentration in the mixed aqueous solution is 0.1 M / l to 0.85 M / l, and the zinc ion concentration is 0.15 M / l to 1. By setting it to 2 M / l, an antibacterial zeolite having a copper ion content of 0.1 to 8% and a zinc ion content of 0.1 to 8% by mass can be obtained as appropriate. In addition to the above mixed aqueous solution, the antibacterial zeolite can be ion-exchanged by using an aqueous solution containing each ion alone and sequentially contacting each aqueous solution with the zeolite. The concentration of each ion in each aqueous solution can be determined according to the concentration of each ion in the mixed aqueous solution.

  The zeolite after ion exchange is thoroughly washed and dried. Drying is preferably performed at 105 to 115 ° C. or 70 to 90 ° C. under reduced pressure (1 to 30 Torr).

  It should be noted that ion exchange of ions and organic ions without suitable water-soluble salts such as tin and bismuth can be carried out using an organic solvent solution such as alcohol or acetone so that hardly soluble basic salts do not precipitate.

  The blending amount of the antibacterial zeolite is not particularly limited. It is determined appropriately depending on the product form of the deodorant cosmetic. Usually, 0.1 to 90% by mass, preferably 1 to 70% by mass, and more preferably 5 to 70% by mass with respect to the total amount of the deodorant cosmetic is blended depending on the product form.

  The average particle size of the antibacterial zeolite is preferably 10 μm or less. More preferably, it is 0.1-5 micrometers. Further, when the average particle diameter is within this range, the particle size distribution preferably having a particle diameter exceeding 1 μm is 20% or less.

  The nanoporous silica used in the present invention refers to hexagonal silica having a pore diameter of 1 to 50 nm obtained by forming a surfactant micelle between layers of a layered silicate compound and removing the surfactant therefrom. The method for producing nanoporous silica in the present invention is not particularly limited. For example, an organic material in which an inorganic material is formed as a template by mixing and reacting an inorganic material with an organic material and reacting it. And a method of removing an organic substance from the obtained composite after forming a composite of an inorganic substance.

The inorganic raw material is not particularly limited as long as it is a substance containing silicon. Examples of the substance containing silicon include substances containing silicates such as layered silicates and non-layered silicates, and substances containing silicon other than silicates. Examples of layered silicates include kanemite (NaHSi ₂ O ₅ .3H ₂ O), sodium disilicate crystal (Na ₂ Si ₂ O ₅ ), macatite (NaHSi ₄ O ₉ .5H ₂ O), and Iraite (NaHSi ₈ O _17. XH ₂ O), magadiite (Na ₂ HSi ₁₄ O ₂₉ .XH ₂ O), Kenyaite (Na ₂ HSi ₂₀ O ₄₁ .XH ₂ O) and the like. Non-layered silicates include water glass (sodium silicate). ), Glass, amorphous sodium silicate, tetraethoxysilane (TEOS), tetramethylammonium (TMA) silicate, silicon alkoxide such as tetraethylorthosilicate, and the like. Examples of the substance containing silicon other than silicate include silica, silica oxide, and silica-metal composite oxide. These may be used alone or in admixture of two or more.

  Examples of the organic raw material include cationic, anionic, amphoteric and nonionic surfactants, polymer polymers and the like, and these can be used alone or in admixture of two or more.

  Examples of the cationic surfactant include primary amine salts, secondary amine salts, tertiary amine salts, and quaternary ammonium salts. Among these, quaternary ammonium salts are preferable. Amine salts have poor dispersibility in the alkaline region, so that the synthesis conditions are used only in the acidic range, but the quaternary ammonium salts can be used in both cases where the synthesis conditions are acidic and alkaline. .

  Quaternary ammonium salts include octyltrimethylammonium chloride, octyltrimethylammonium bromide, octyltrimethylammonium hydroxide, decyltrimethylammonium chloride, decyltrimethylammonium bromide, decyltrimethylammonium hydroxide, dodecyltrimethylammonium chloride, dodecyltrimethylammonium bromide, Dodecyltrimethylammonium hydroxide, hexadecyltrimethylammonium chloride, hexadecyltrimethylammonium bromide, hexadecyltrimethylammonium hydroxide, octadecyltrimethylammonium chloride, octadecyltrimethylammonium bromide, octadecyltrimethylammonium hydroxide Behenyltrimethylammonium chloride, behenyltrimethylammonium bromide, behenyltrimethylammonium hydroxide, tetradecyltrimethylammonium chloride, tetradecyltrimethylammonium bromide, tetradecyltrimethylammonium hydroxide, benzyltrimethylammonium chloride, benzyltrimethylammonium bromide, benzyltrimethylammonium hydroxide And alkyl (8 to 22 carbon atoms) trimethylammonium salt. You may use these individually or in mixture of 2 or more types.

  Examples of the anionic surfactant include carboxylate, sulfate ester salt, sulfonate salt, and phosphate ester salt. Among them, soap, higher alcohol sulfate ester salt, higher alkyl ether sulfate ester salt, sulfate Oils, sulfated fatty acid esters, sulfated olefins, alkyl benzene sulfonates, alkyl naphthalene sulfonates, paraffin sulfonates, higher alcohol phosphate esters, etc. are preferred, which are used alone or in admixture of two or more. May be.

  As the amphoteric surfactant, sodium laurylaminopropionate, stearyldimethylbetaine, lauryldihydroxyethylbetaine and the like are preferable, and these may be used alone or in admixture of two or more.

  Nonionic surfactants include polyoxyethylene alkyl ether, polyoxyethylene secondary alcohol ether, polyoxyethylene alkylphenyl ether, polyoxyethylene sterol ether, polyoxyethylene lanolinic acid derivative, polyoxyethylene polyoxypropylene alkyl ether Ether-type ones such as polypropylene glycol and polyethylene glycol and nitrogen-containing ones such as polyoxyethylene alkylamine are preferred, and these may be used alone or in admixture of two or more.

  When a surfactant is used as the organic raw material and pores are formed using the surfactant as a template, micelles can be used as the template. Also, by controlling the alkyl chain length of the surfactant, the diameter of the template can be changed and the diameter of the pores to be formed can be controlled. Further, by adding a relatively hydrophobic molecule such as trimethylbenzene or tripropylbenzene together with the surfactant, the micelles expand and larger pores can be formed. By using these methods, pores having an optimal size can be formed.

When mixing an inorganic raw material and an organic raw material, an appropriate solvent may be used. Although it does not specifically limit as a solvent, Water, alcohol, etc. are mentioned.
The mixing method of the inorganic raw material and the organic raw material is not particularly limited, but after adding ion exchange water twice or more by weight to the inorganic raw material, the mixture is stirred at 40 ° C. to 80 ° C. for 1 hour or longer, and then the organic raw material is mixed. A method of adding and mixing the raw materials is preferable.

  The mixing ratio of the inorganic raw material and the organic raw material is not particularly limited, but the ratio of the inorganic raw material to the organic raw material is preferably 0.1: 1 to 5: 1 by weight, more preferably 0.1: 1. ~ 3: 1.

  The pH condition for reacting the inorganic raw material and the organic raw material is not particularly limited. Preferably, the pH is 11 or more for 1 hour or more by stirring to adjust the pH to 8.0 to 9.0, and then mixing for 1 hour or more. It is preferable to react.

  As a method for removing the organic substance from the complex of the organic substance and the inorganic substance, there are a method in which the complex is collected by filtration, washed with water and dried, then baked at 400 ° C. to 800 ° C., and extracted with an organic solvent or the like. Can be mentioned.

  The pore diameter of the nanoporous silica is most preferably 1 to 7 nm from the viewpoint of the deodorizing effect. The pore diameter is obtained by measuring the adsorption isotherm of nitrogen gas and calculating the capacity of the adsorbed nitrogen gas.

  The average particle size of the nanoporous silica is preferably 0.01 to 50 μm because the usability is good.

  The compounding quantity of nanoporous silica is not specifically limited. It is determined appropriately depending on the product form of the deodorant cosmetic. Usually, 0.1 to 90% by mass, preferably 1 to 80% by mass, and more preferably 5 to 70% by mass with respect to the total amount of the deodorant cosmetic is blended depending on the product form.

  In addition, it is preferable that content of nanoporous silica is 0.1 or more by mass ratio with respect to content of antimicrobial zeolite. When the product form is an aerosol spray type, 0.1-80% by mass of antibacterial zeolite and 0.1-80% by mass of nanoporous silica are preferable, and more preferably 0.5-70% by mass, respectively. In the case of the stick type, 0.1 to 70% by mass of antibacterial zeolite and 0.1 to 70% by mass of nanoporous silica are preferable, and more preferably 0.5 to 60% by mass, respectively. When a product form is a powder type, 0.1-99.9 mass% of antimicrobial zeolite and 0.1-99.9 mass% of nanoporous silica are preferable, More preferably, they are 50-95 mass%, respectively. When the product form is a lotion type, it is 0.1 to 30% by mass of antibacterial zeolite and 0.1 to 30% by mass of nanoporous silica, and more preferably 0.5 to 20% by mass, respectively.

The zinc oxide used in the present invention is preferably fine particle zinc oxide powder. The average particle size is preferably 0.5 μm or less.
Content of a zinc oxide powder is 0.1-90 mass% with respect to the deodorant cosmetics whole quantity, Preferably it is 0.1-10 mass%.

  In addition to the essential components described above, the deodorant cosmetic composition of the present invention is appropriately blended with other components usually used in a skin external preparation, for example, one or more of the components exemplified below as required. Depending on the dosage form, it can be produced by a conventional method. Preferable products are deodorant cosmetics and antiperspirant cosmetics which are deodorant skin external preparations.

  Examples of the powder component include inorganic powders (for example, talc, kaolin, mica, sericite, muscovite, phlogopite, synthetic mica, saucite, biotite, permiculite, magnesium carbonate, calcium carbonate, silicic acid. Aluminum, barium silicate, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, silica, barium sulfate, calcined calcium sulfate (baked gypsum), calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, metal Soap (for example, zinc myristate, calcium palmitate, aluminum stearate), boron nitride, etc .; Organic powder (for example, polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder, benzoguanamine resin powder Polytetrafluoroethylene powder, cellulose powder, etc.); inorganic white pigments (eg, titanium dioxide, zinc oxide, etc.); inorganic red pigments (eg, iron oxide (Bengara), iron titanate, etc.); inorganic brown pigments (eg, For example, γ-iron oxide, etc.); inorganic yellow pigments (for example, yellow iron oxide, ocher, etc.); inorganic black pigments (for example, black iron oxide, low-order titanium oxide, etc.); inorganic purple pigments (for example, manganese) Violet, cobalt violet, etc.); inorganic green pigments (eg, chromium oxide, chromium hydroxide, cobalt titanate, etc.); inorganic blue pigments (eg, ultramarine blue, bitumen, etc.); pearl pigments (eg, titanium oxide coated mica, Titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, etc.); metal powder pigment For example, aluminum powder, copper powder, etc.); organic pigments such as zirconium, barium or aluminum lake (for example, red 201, red 202, red 204, red 205, red 220, red 226, red 228) Organic pigments such as red 405, orange 203, orange 204, yellow 205, yellow 401, and blue 404, red 3, red 104, red 106, red 227, red 230, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green No. 3 and Blue No. 1); natural pigments (eg, chlorophyll, β-carotene, etc.) Etc.

  Examples of liquid oils include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern castor oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin and the like.

  Examples of the solid fat include cacao butter, coconut oil, hardened coconut oil, palm oil, palm kernel oil, owl kernel oil, hardened oil, owl, and hardened castor oil.

  Examples of the wax include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, Examples include jojoba wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, ceresin, and microcrystalline wax.

  Examples of the hydrocarbon oil include liquid paraffin, ozokerite, squalane, pristane, paraffin, squalene, petrolatum and the like.

  Examples of higher fatty acids include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid (DHA), and the like. Is mentioned.

  Examples of higher alcohols include linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol); branched chain alcohols (eg, monostearyl glycerin ether (batyl alcohol) ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyl decanol, isostearyl alcohol, octyldodecanol and the like.

  Examples of ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, lactic acid Myristyl, lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, monoisostearate N-alkyl glycol, neopentyl glycol dicaprate, Diisostearyl malate, glycerin di-2-heptylundecanoate, trimethylolpropane tri-2-ethylhexanoate, trime triisostearate Roll propane, tetra-2-ethylhexanoic acid pentaerythritol, tri-2-ethylhexanoic acid glycerin, trioctanoic acid glycerin, triisopalmitic acid glycerin, triisostearic acid trimethylolpropane, cetyl 2-ethylhexanoate, 2-ethylhexyl Palmitate, glyceryl trimyristate, glyceride tri-2-heptylundecanoate, castor oil fatty acid methyl ester, oleyl oleate, acetoglyceride, 2-heptylundecyl palmitate, diisobutyl adipate, N-lauroyl-L-glutamic acid 2-octyldodecyl ester, di-2-heptylundecyl adipate, ethyl laurate, di-2-ethylhexyl sebacate, 2-hexyldecyl myristate, 2-hexyldecyl palmitate, 2-hexyl adipate Decyl, diisopropyl sebacate, 2-ethylhexyl succinate, and triethyl citrate. Also, POE (14) POP (7) dimethyl ether, POE (9) POP (2) dimethyl ether, POE (14) POP (7) dimethyl ether, POE (10) POP (10) dimethyl ether, POE (6) POP (14) Dimethyl ether, POE (15) POP (5) Dimethyl ether, POE (25) POP (25) Dimethyl ether, POE (9) POB (2) Dimethyl ether, POE (14) POB (7) Dimethyl ether, POE (10) POP (10) Alkylene oxide derivatives such as diethyl ether, POE (10) POP (10) dipropyl ether, POE (10) POP (10) dibutyl ether, diethoxyethyl succinate, diethoxyethyl malonate, tripropylene glycol dineopentanoate, dicapryl Examples include propylene glycol acid, alkyl benzoates such as C8 to C12 alkyl benzoates and dodecyl benzoates.

  Examples of the silicone oil include chain polysiloxanes (for example, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.), cyclic polysiloxanes (for example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexane). Satrisiloxane, etc.), methyl trimethicone, silicone resin forming a three-dimensional network structure, silicone rubber, various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, etc.) ) And the like.

  Anionic surfactants include, for example, fatty acid soaps (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (eg, sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfates (eg, POE-lauryl sulfate triethanolamine, POE-sodium lauryl sulfate, etc.); N-acyl sarcosine acids (eg, sodium lauroyl sarcosine, etc.); higher fatty acid amide sulfonates (eg, sodium N-myristoyl-N-methyl taurate, palm Oil fatty acid methyl taurine sodium, lauryl methyl taurine sodium, etc .; phosphate ester salts (POE-oleyl ether sodium phosphate, POE-stearyl ether phosphate, etc.); sulfosuccinates (eg, di-2-ethylhexyl sulfosuccinate) Sodium salt, monolauroyl monoethanolamide polyoxyethylene sodium sulfosuccinate, sodium lauryl polypropylene glycol sulfosuccinate, etc.); alkylbenzene sulfonate (eg, sodium lineardodecylbenzenesulfonate, triethanolamine lineardodecylbenzenesulfonate, lineardodecylbenzene) Sulfonic acid, etc.); higher fatty acid ester sulfate (eg, hydrogenated coconut oil fatty acid sodium glycerol sulfate, etc.); N-acyl glutamate (eg, monosodium N-lauroyl glutamate, disodium N-stearoyl glutamate, N-myristoyl- L-glutamate monosodium etc.); sulfated oil (eg funnel oil etc.); POE-alkyl ether carboxylic acid; POE-alkyl allyl ether cal Α-olefin sulfonates; higher fatty acid ester sulfonates; secondary alcohol sulfates; higher fatty acid alkylolamide sulfates; lauroyl monoethanolamide sodium succinate; N-palmitoyl aspartate ditriethanolamine ; Sodium caseinate and the like.

  Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (eg, cetylpyridinium chloride, etc.); distearyldimethylammonium dialkyldimethylammonium chloride; Poly (N, N'-dimethyl-3,5-methylenepiperidinium chloride); alkyl quaternary ammonium salt; alkyldimethylbenzylammonium salt; alkylisoquinolinium salt; dialkyl morpholinium salt; POE-alkylamine; Examples include alkylamine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride and the like.

  Examples of amphoteric surfactants include imidazoline-based amphoteric surfactants (eg, 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide). Side-1-carboxyethyloxy disodium salt, etc.); betaine surfactants (for example, 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amide betaine) , Sulfobetaine, etc.).

  Examples of the lipophilic nonionic surfactant include sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, Sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate); glycerin polyglycerin fatty acids (eg mono cottonseed oil fatty acid glycerin, monoerucic acid glycerin, sesquioleate glycerin, monostearin) Glycerin acid, α, α'-oleic acid pyroglutamate glycerin, monostearic acid glycerin malic acid, etc.); propylene glycol fatty acid esters (eg monostearies) Propylene glycolate, etc.); hardened castor oil derivative; glycerin alkyl ether, etc.

  Examples of hydrophilic nonionic surfactants include POE-sorbitan fatty acid esters (for example, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate, etc.); POE sorbite fatty acid esters (eg, POE-sorbite monolaurate, POE-sorbite monooleate, POE-sorbite pentaoleate, POE-sorbite monostearate, etc.); POE-glycerin fatty acid esters (eg, POE-glycerin) Monostearate, POE-glycerol monoisostearate, POE-monooleate such as POE-glycerol triisostearate, etc.); POE-fatty acid esters (for example, POE-distearate, POE-monodiolate, ethylene glycol distearate, etc.); POE-alkyl ethers (eg POE- Uril ether, POE-oleyl ether, POE-stearyl ether, POE-behenyl ether, POE-2-octyldodecyl ether, POE-cholestanol ether, etc.); Pluronic type (for example, Pluronic, etc.); POE / POP-alkyl ether (For example, POE / POP-cetyl ether, POE / POP-2-decyltetradecyl ether, POE / POP-monobutyl ether, POE / POP-hydrogenated lanolin, POE / POP-glycerin ether, etc.); Tetra POE / tetra POP-ethylenediamine condensates (eg Tetronic, etc.); POE-castor oil hardened castor oil derivatives (eg POE-castor oil, POE-hardened castor oil, POE-hardened castor oil monoisostearate, POE-hardened castor Oil triisostearate, POE-hardened castor oil monopyroglutamic acid monoisostearic acid diester, POE-hardened castor oil maleic acid, etc.); PO E-beeswax lanolin derivatives (eg POE-sorbite beeswax); alkanolamides (eg coconut oil fatty acid diethanolamide, lauric acid monoethanolamide, fatty acid isopropanolamide, etc.); POE-propylene glycol fatty acid ester; POE-alkylamine POE-fatty acid amide; sucrose fatty acid ester; alkyl ethoxydimethylamine oxide; trioleyl phosphate and the like.

  Examples of the humectant include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-hydroxystearate Sodium lactate, bile salt, dl-pyrrolidone carboxylate, short-chain soluble collagen, diglycerin (EO) PO adduct, Izayoi rose extract, yarrow extract, merirot extract and the like.

  Examples of natural water-soluble polymers include plant-based polymers (for example, gum arabic, gum tragacanth, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (guckweed extract), starch (Rice, corn, potato, wheat), glycyrrhizic acid}; microbial polymers (eg, xanthan gum, dextran, succinoglucan, bull run); others (eg, fish-derived collagen, fish-derived gelatin, wheat protein, silk protein) Etc.).

  Semi-synthetic water-soluble polymers include, for example, starch polymers (eg, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate) Hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder and the like); alginic acid polymers (for example, sodium alginate, propylene glycol alginate, etc.) and the like.

  Synthetic water-soluble polymers include, for example, vinyl polymers (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer); polyoxyethylene polymers (eg, polyethylene glycol 20,000, 40,000, 60,000). Polyoxyethylene polyoxypropylene copolymer, etc.); acrylic polymers (for example, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethyleneimine; cationic polymers, and the like.

  Examples of the thickener include gum arabic, carrageenan, caraya gum, gum tragacanth, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, CMC, hydroxyethylcellulose, hydroxypropyl Cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxyvinyl polymer, locust bean gum, guar gum, tamarind gum, cellulose dialkyldimethylammonium sulfate, xanthan gum, magnesium aluminum silicate, bentonite, hectorite, AlMg silicate (Beegum), Examples thereof include laponite and silicic anhydride.

Examples of the ultraviolet absorber include the following compounds.
(1) Benzoic acid ultraviolet absorbers For example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N-dimethyl PABA ethyl ester, N, N-dimethyl PABA butyl ester, N, N-dimethyl PABA ethyl ester and the like.
(2) Anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate.
(3) Salicylic acid ultraviolet absorbers such as amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate, and the like.
(4) Cinnamic acid UV absorbers For example, octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4- Diisopropyl cinnamate, propyl-p-methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, octyl-p-methoxycinnamate (2-ethylhexyl-p-methoxycinnamate), 2-ethoxy Ethyl-p-methoxycinnamate, cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl-α-cyano-β-phenylcinnamate, glyceryl mono-2-ethylhexanoyl -Diparamethoxycinnamate.
(5) Triazine-based ultraviolet absorber, for example, bisresorcinyl triazine.
More specifically, bis {[4- (2-ethylhexyloxy) -2-hydroxy] phenyl} -6- (4-methoxyphenyl) 1,3,5-triazine, 2,4,6-tris { 4- (2-Ethylhexyloxycarbonyl) anilino} 1,3,5-triazine.
2,4-bis-{[4- (2-ethylhexyloxy) -2-2hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine.
(6) Other UV absorbers For example, 3- (4'-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor, 2-phenyl-5-methylbenzoxazole, 2,2 '-Hydroxy-5-methylphenylbenzotriazole, 2- (2'-hydroxy-5'-t-octylphenyl) benzotriazole, 2- (2'-hydroxy-5'-methylphenylbenzotriazole, dibenzalazine, dianisoyl Methane, 4-methoxy-4'-t-butyldibenzoylmethane, 5- (3,3-dimethyl-2-norbornylidene) -3-pentan-2-one, etc. Pyridazine derivatives such as dimorpholinopyridazinone Octocrylene .

  Examples of the sequestering agent include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, and tetrasodium edetate. Sodium citrate, sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, citric acid, ascorbic acid, succinic acid, edetic acid and the like.

  Examples of the lower alcohol include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.

  Examples of the polyhydric alcohol include divalent alcohols (for example, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, Pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trivalent alcohol (eg, glycerin, trimethylolpropane, etc.); tetravalent alcohol (eg, 1,2,6) Pentaerythritol such as hexanetriol); pentahydric alcohol (eg, xylitol, etc.); hexavalent alcohol (eg, sorbitol, mannitol, etc.); polyhydric alcohol polymer (eg, diethylene glycol, dipropylene glycol, triethylene glycol, polypropylene Glycol, tetraethylene glycol, diglycerin, polyethylene glycol, triglycerin, tetraglycerin, polyglycerin, etc.); divalent alcohol alkyl ethers (for example, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, ethylene) Glycol monophenyl ether, ethylene glycol monohexyl ether, ethylene glycol mono 2-methylhexyl ether, ethylene glycol isoamyl ether, ethylene glycol benzyl ether, ethylene glycol isopropyl ether, ethylene glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, etc.) ; Dihydric alcohol alkyl ester Tellurium (for example, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol butyl ether, diethylene glycol methyl ethyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether , Propylene glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol isopropyl ether, dipropylene glycol methyl ether, dipropylene glycol ethyl ether, dipropylene glycol butyl ether, etc.); divalent alcohol Ether esters (eg, ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether acetate, ethylene glycol monophenyl ether acetate, ethylene glycol diazinate, ethylene glycol disuccinate, diethylene glycol monoethyl ether acetate, diethylene glycol) Monobutyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate, propylene glycol monophenyl ether acetate, etc .; glycerin monoalkyl ethers (for example, Kimyl alcohol, Serakir al Sugar alcohol (for example, sorbitol, maltitol, maltotriose, mannitol, sucrose, erythritol, glucose, fructose, amylolytic sugar, maltose, xylitolose, amylolytic sugar reducing alcohol, etc.); Solid; Tetrahydrofurfuryl alcohol; POE-Tetrahydrofurfuryl alcohol; POP-Butyl ether; POP / POE-Butyl ether; Tripolyoxypropylene glycerin ether; POP-glycerin ether; POP-glycerin ether phosphate; POP / POE-pentane erythritol Examples include ether and polyglycerin.

  Monosaccharides include, for example, tricarbon sugars (eg, D-glyceryl aldehyde, dihydroxyacetone, etc.); tetracarbon sugars (eg, D-erythrose, D-erythrulose, D-treose, erythritol, etc.); pentose sugars (eg, , L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc .; hexose (eg, D-glucose, D-talose, D) -Bucicose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc.); pentose sugar (eg, aldheptose, heproose, etc.); octose sugar (eg, octulose, etc.); For example, 2-deoxy-D-ribose, 6-deoxy-L-galactose, 6-deoxy-L-mannose, etc .; amino sugar (eg, D-glucosamine, D-galactosamine, shea Acid, Aminouron acid, muramic acid); uronic acid (e.g., D- glucuronic acid, D- mannuronic acid, L- guluronic acid, D- galacturonic acid, L- iduronic acid) and the like.

  Examples of the oligosaccharide include sucrose, umbelliferose, lactose, planteose, isolicnose, α, α-trehalose, raffinose, lycnose, umbilicin, stachyose verbus course, and the like.

  Examples of the polysaccharide include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum, dextran, kerato sulfate. , Locust bingham, succinoglucan, caronic acid and the like.

  Examples of amino acids include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.) and the like. Examples of amino acid derivatives include acyl sarcosine sodium (lauroyl sarcosine sodium), acyl glutamate, acyl β-alanine sodium, glutathione, and pyrrolidone carboxylic acid.

  Examples of the organic amine include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol. Is mentioned.

  Examples of the polymer emulsion include an acrylic resin emulsion, a polyethyl acrylate emulsion, an acrylic resin liquid, a polyacryl alkyl ester emulsion, a polyvinyl acetate resin emulsion, and a natural rubber latex.

  Examples of the pH adjuster include buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate.

  Examples of vitamins include vitamins A, B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, biotin and the like.

  Examples of the antioxidant include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.

  Examples of the antioxidant assistant include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, ethylenediaminetetrakis (2-hydroxyisopropyl) dioleic acid Salt, ethylenediaminetetrapolyoxypropylene, sodium ethylenediaminehydroxyethyl triacetate (dihydrate), sodium calcium ethylenediaminetetraacetate, edetic acid, trisodium edetate, dipotassium edetate, disodium edetate, edetate tetra Examples thereof include sodium, edetate tetrasodium dihydrate, edetate tetrasodium tetrahydrate, and the like.

  Examples of other components that can be blended include, for example, preservatives (methyl paraben, ethyl paraben, butyl paraben, phenoxyethanol, etc.); Whitening agents (eg, Yukinosita extract, arbutin, tranexamic acid, L-ascorbic acid, L-ascorbic acid phosphate magnesium salt, L-ascorbic acid glucoside, potassium 4-methoxysalicylate, etc.); various extracts (eg, green tea , Oolong tea, black tea, pu-erh tea, mulberry, clara, amber, auren, shikon, peonies, assembly, birch, sage, loquat, carrot, aloe, mallow, iris, grape, yokuinin, loofah, lily, saffron Senkyu, Shokyu, Hypericum, Onis, Garlic, Pepper, Chimpi, Toki, Seaweed, etc.), Activator (eg, Royal Jelly, Photosensitizer, Cholesterol Derivative, etc.); Blood circulation promoter (eg, nicotinic acid benzyl ester, nicotinic acid β -Butoxyethyl ester, capsaicin, gingerone, cantalis tincture, ictamol, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandrate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, γ-oryzanol, etc.) Antiseborrheic agents (eg, sulfur, thianthol, etc.); anti-inflammatory agents (eg, thiotaurine, hypotaurine, etc.); bactericides (eg, benzoic acid and its salts, isopropylmethylphenol, Ndecylenic acid and its salts, undecylenic acid monoethanolamide, cetyltrimethylammonium chloride, cetylpyridinium chloride, benzalkonium chloride, benzathonium chloride, alkyldiaminoethylglycine chloride, chlorhexidine chloride, orthophenylphenol, chlorhexidine gluconate, cresol, chloramine T , Chlorxylenol, chlorcresol, chlorphenesin, chlorobutanol, 5-chloro-2-methyl-4-isothiazolin-3-one, salicylic acid and its salts, 1,3-dimethylol-5,5-dimethylhydantoin, bromide Alkylisoquinolinium, domifene bromide, sorbic acid and its salts, thymol, thiram, dehydroacetic acid and its salts, triclosan, trichlorocarbanilide, paraoxy Benzoic acid ester, parachlorophenol, halocarban, pyrogallol, phenol, hexachlorophene, 2-methyl-4-isothiazolin-3-one, NN "-methylenebis (N '-(3-hydroxymethyl-2.5-dioxo- 4-imidazolidinyl urea, sodium lauroyl sarcosine, resorcin, hinokitiol, etc.).

  The product form of the deodorant cosmetic composition of the present invention is not particularly limited. Examples thereof include a spray type, a roll-on type, a powder type, a pressed powder (molded powder) type, and a stick type. In the case of the spray type, it is manufactured by filling a spray container such as an aerosol can or a dispenser together with a propellant such as a liquefied gas and alcohol by a conventional method. In the case of a roll-on type, it is manufactured by filling a roll-on container together with alcohol by a conventional method. In the case of the powder type and the pressed powder type, they are mixed together with the powder component and the oil. In the case of the powder type, they are produced as they are. In the case of the stick type, it is produced by mixing together with oil (solid oil, liquid oil), filling the container by a conventional method, and molding.

  Next, the present invention will be described more specifically with reference to examples. The present invention is not limited thereby. A compounding quantity is the mass% with respect to the whole quantity unless there is particular notice.

<Example of production of nanoporous silica>
“Production Example 1 of Nanoporous Silica”
50 g of water glass No. 1 (SiO ₂ / Na ₂ O = 2.00) was dispersed in 1000 ml of a 0.1M solution of behenyltrimethylammonium chloride [C ₂₂ H ₄₅ N (CH ₃ ) ₃ ] Cl as a surfactant, Heated at 70 ° C. with stirring for 3 hours.
Thereafter, 2N hydrochloric acid was added while heating and stirring at 70 ° C., the pH of the dispersion was lowered to pH 8.5, and the mixture was further heated and stirred at 70 ° C. for 3 hours. The solid product was once filtered, dispersed again in 1000 ml of ion exchange water, and stirred. This filtration / dispersion stirring was repeated 5 times, followed by drying at 40 ° C. for 24 hours. The dried solid product was heated in nitrogen gas at 450 ° C. for 3 hours, and then calcined in air at 550 ° C. for 6 hours to obtain nanoporous silica A. (Pore diameter 7nm)

"Production example 2 of nanoporous silica"
50 g of water glass No. 1 (SiO ₂ / Na ₂ O = 2.00) was dispersed in 1000 ml of a 0.1M solution of cetyltrimethylammonium chloride [C ₁₆ H ₃₃ N (CH ₃ ) ₃ ] Cl as a surfactant, Heated at 70 ° C. with stirring for 3 hours.
Thereafter, 2N hydrochloric acid was added while heating and stirring at 70 ° C., the pH of the dispersion was lowered to pH 8.5, and the mixture was further heated and stirred at 70 ° C. for 3 hours. The solid product was once filtered, dispersed again in 1000 ml of ion exchange water, and stirred. This filtration / dispersion stirring was repeated 5 times, followed by drying at 40 ° C. for 24 hours. The dried solid product was heated in nitrogen gas at 450 ° C. for 3 hours, and then calcined in air at 550 ° C. for 6 hours to obtain nanoporous silica B. (Pore diameter 4nm)

“Production Example 3 of Nanoporous Silica”
Disperse 50 g of water glass No. 1 (SiO ₂ / Na ₂ O = 2.00) in 1000 ml of a 0.1M solution of n-decyltrimethylammonium chloride [C ₁₀ H ₂₁ N (CH ₃ ) ₃ ] Cl as a surfactant. And heated at 70 ° C. with stirring for 3 hours.
Thereafter, 2N hydrochloric acid was added while heating and stirring at 70 ° C., the pH of the dispersion was lowered to pH 8.5, and the mixture was further heated and stirred at 70 ° C. for 3 hours. The solid product was once filtered, dispersed again in 1000 ml of ion exchange water, and stirred. This filtration / dispersion stirring was repeated 5 times, followed by drying at 40 ° C. for 24 hours. The dried solid product was heated in nitrogen gas at 450 ° C. for 3 hours, and then calcined in air at 550 ° C. for 6 hours to obtain nanoporous silica C. (Pore size 1.5nm)

"Examples 1-2, Comparative Examples 1-4"
[Deodorant powder spray]
The deodorant powder spray was manufactured by the following manufacturing method with the composition of Examples 1 to 3 and Comparative Examples 1 to 4 shown in Table 1, and the following methods were used for usability, deodorizing effect, and stability (discoloration resistance) of the preparation. evaluated. The evaluation results are shown in Table 1.

"Production method"
The powder component is mixed well with a Henschel mixer to prepare a powder part. Further, an oil component and a surfactant are mixed and dissolved in a blender to obtain an oil phase part. An aluminum aerosol can having an internal volume of 80 mL is filled with 5.3 g of a powder part and 2.9 g of an oil phase part, clinched, and then filled with a propellant (LPG 0.18 MPa / 20 ° C.) to obtain a powder spray.

(1) Usability (white balance)
The following tests were performed using a deodorant spray that had been left at room temperature for 6 months. Ten test subjects sprayed the Example and Comparative Example to the left or right axilla from a distance of 10 cm for 3 seconds, and visually evaluated the whiteness of the area where the sample was applied. The white residue is considered to be due to the difference in refractive index between the powder and the oil.
<Evaluation criteria>
Evaluation was made by the 5-point method according to the following criteria, and the judgment results were shown using the average value of 10 male panels. The higher the value, the less white is left.
0 point: 1 point that remains white: 2 points that remain slightly white: 3 points that are neither white: 4 points that do not leave white slightly: Judgment result that does not remain white ×: 0 point or more and less than 1 point Δ: 1 point or more and less than 3 points ○: 3 points or more

(2) Deodorizing effect (pseudo odor)
Since the odor components of sweat odor and foot odor are lower fatty acids such as acetic acid and isovaleric acid, a “pseudo odor” containing 15 ppm of isovaleric acid is adjusted as a odor model of odor, and the deodorizing effect against this odor odor is gasified. This is a method of evaluation by a detector. After injecting isovaleric acid (manufactured by Tokyo Chemical Industry Co., Ltd.) so that the gas phase concentration becomes 15 ppm in a 500 ml Erlenmeyer flask, put 200 mg of filter paper coated with the sample, and let the gas phase concentration after standing for 30 minutes be the gas detector It was measured with a gas detector (GV-100S manufactured by Gastec) equipped with (81L manufactured by Gastech).

(3) Deodorizing effect (bitter odor)
This is a method in which a judge who has been trained in odor evaluation performs sensory evaluation using a panel of 10 males who are aware of the odor in the summer when sweat is likely to occur. The test samples were assigned randomly by left and right, and a double blind test was conducted in which one person other than the panel and the judge assigned samples and stored their key codes. The axilla of the panel was wiped with 70% ethanol until there was no odor and the sample was used for 3 seconds from a distance of 10 cm. Each panel was prohibited from bathing, showering, and washing under the armpit. After 24 hours, the assessor evaluated the degree of odor in the left and right armpits of the panel according to the following criteria.
<Evaluation criteria>
Evaluation was made by the 5-point method according to the following criteria, and the judgment results were shown using the average value of 10 male panels. The higher the value, the better the deodorizing effect.
Evaluation 0 points: Strongly smelling 1 point: Slightly smelling 2 points: Neither of them 3 points: Not smelling 4 points: Not smelling at all X: 0 point or more and less than 1 point Δ: 1 point or more and less than 3 points ○: 3 points more than

(4) Discoloration resistance The following tests were conducted using a deodorant spray that had been left at room temperature for 6 months. A deodorant powder spray filled in an aerosol container is sprayed on white paper from a distance of about 10 cm for 3 seconds, and this is used as a sample for 3 hours in the sun. Whether the change occurred or not was evaluated visually by a specialist researcher. The evaluation criteria were evaluated according to the following criteria. It can be said that the smaller the color change, the better the product and the stability of the preparation.
<Evaluation criteria>
○: Color change is not felt at all △: Color change is felt slightly ×: Color change is clearly felt

粉末成分
A：銀・亜鉛・アンモニウム担持ゼオライト
（シナネンゼオミック株式会社製ゼオミックＡＪ１０Ｎ、平均粒径約１．５μｍであって粒径１５μｍを超えるものは０．５％以下）
B：酸化亜鉛（堺化学工業株式会社製 微細酸化亜鉛 平均粒径０．３μｍ）
C：多孔質シリカ（アモルファス構造：旭硝子株式会社製 サンスフェアＬ−５１、細孔径１３ｎｍ）
D：製造例３のナノポーラスシリカＣ（細孔径１．５ｎｍ）
E：デンプン
F：球状アルギン酸カルシウム
G：クロルヒドロキシアルミニウム
H：カルシウムステアレート
I：メタケイ酸アルミン酸マグネシウム
J：球状ポリエチレン粉末（平均粒径１２μｍ）

油性成分及び界面活性剤
K：オクタン酸セチル
L：ジメチルポリシロキサン（６ｍＰａ・ｓ，２５℃）
M：メチルフェニルポリシロキサン（１３ｍＰａ・ｓ，２５℃）
N：セスキイソステアリン酸ソルビタン
O：ＰＰＧ−１０デシルテトラデセス−２４
P：天然型ビタミンＥ

Powder component
A: Zeolite supported on silver, zinc, and ammonium (Zeomic AJ10N manufactured by Sinanen Zeomic Co., Ltd., average particle size of about 1.5 μm, and particle size exceeding 15 μm is 0.5% or less)
B: Zinc oxide (manufactured by Sakai Chemical Industry Co., Ltd. Fine zinc oxide, average particle size 0.3 μm)
C: porous silica (amorphous structure: Asahi Glass Co., Ltd. Sunsphere L-51, pore size 13 nm)
D: Nanoporous silica C of Production Example 3 (pore diameter: 1.5 nm)
E: Starch
F: Spherical calcium alginate
G: Chlorhydroxyaluminum
H: Calcium stearate
I: Magnesium aluminate metasilicate
J: Spherical polyethylene powder (average particle size 12 μm)

Oil component and surfactant
K: Cetyl octanoate
L: Dimethylpolysiloxane (6 mPa · s, 25 ° C.)
M: methylphenylpolysiloxane (13 mPa · s, 25 ° C.)
N: Sorbitan sesquiisostearate
O: PPG-10 decyltetradeces-24
P: Natural vitamin E

From the above Examples and Comparative Examples, it can be seen that the deodorant powder spray of the present invention is superior in deodorizing properties, usability, and discoloration resistance as compared with Comparative Examples. In addition, the deodorant powder sprays of the examples did not agglomerate and were excellent in dispersibility.
Similar results can be obtained even when the nanoporous silicas A and B of Production Examples 1 and 2 are used.

  Below, other examples of the deodorant cosmetic composition of the present invention are listed.

Example 4
[Pressed powder type deodorant cosmetic]
(Powder part)
Silver ion / ammonium ion-supported zeolite (average particle size is about 3 μm, and particle size exceeding 15 μm is 0.5% or less) 4.0% by mass
Nanoporous silica C (pore size 1.5 nm) 1.5
Aluminum hydroxychloride 0.5
Zinc oxide 3.0
Talc 87.0
(Oil)
Methylphenylpolysiloxane (13 mPa · s, 25 ° C.) 3.0
Liquid paraffin 1.0
(Additive)
Perfume appropriate amount

(Manufacturing method) The powder part is mixed with a Henschel mixer, oil and additives are added to this mixture, and then pulverized with a 5HP pulverizer (manufactured by Hosokawa Micron Co., Ltd.). Get a deodorant cosmetic.
The obtained pressed powder type deodorant cosmetic does not have caking during use, has good usability (non-roughness), and has sufficient deodorant effect and discoloration resistance.

"Example 5"
[Deodorant powder]
Nanoporous silica C (pore diameter: 1.5 nm) 13.0% by mass
Silver ion / ammonium ion-supported zeolite (average particle size is about 2 μm, and particle size exceeding 15 μm is 1% or less) 7.0
Spherical nylon powder 5.0
Dimethylpolysiloxane (molecular weight 450,000) 1.0
Synthetic isoparaffin 1.0
Perfume proper amount talc 73.0

(Manufacturing method) The said component is mixed sequentially with a Henschel mixer, and deodorant powder is obtained. The obtained deodorant powder is excellent in usability (no roughness), deodorizing effect, and discoloration resistance.

"Example 6"
[Powder spray]
(Powder part)
Nanoporous silica A (pore diameter 7 nm) 4.0% by mass
Aluminum hydroxychloride 2.0
Silver ion, copper ion, ammonium ion-supported zeolite (average particle size is about 1.5 μm, and particle size exceeding 15 μm is 0.5% or less) 1.0
Talc 0.5
(Oil)
Decamethylcyclopentasiloxane 1.5
Fragrance 0.2
(Propellant)
Isopentane 10.0
Liquefied petroleum gas 80.8

(Manufacturing method) A powder part is mixed with a kneader, an oil component is mixed with a blender, each is sequentially filled into a spray can, and a propellant is sprayed onto the can to obtain a powder spray.
The obtained powder spray has good dispersibility in the propellant, has no clogging of the nozzle at the time of injection, and has excellent deodorizing effect and discoloration resistance.

"Example 7"
[Powder spray]
(Powder part)
Nanoporous silica B (pore diameter 4 nm) 3.0% by mass
Silver ion, zinc ion, ammonium ion-supported zeolite (average particle size is about 5 μm, and particle size exceeding 15 μm is 1% or less) 2.0
Zinc oxide 0.2
Silica 1.5
(Oil)
Polyoxyethylene nonylphenyl ether 0.5
Dimethylpolysiloxane (20 mPa · s, 25 ° C.) 0.1
Isopropyl myristate 0.5
(Additive)
Polyoxyethylene sorbitan monooleate 0.1
Fragrance 0.1
(Propellant)
Liquefied petroleum gas 92.0

(Manufacturing method) A powder part is mixed with a kneader, an oil component is mixed with a blender, an additive is added, each is sequentially filled in a spray can, and further a propellant is filled in a can to obtain a powder spray.
The obtained powder spray has good dispersibility in the propellant, has no clogging of the nozzle at the time of injection, and has excellent deodorizing effect and discoloration resistance.

"Example 8"
[Compact deodorant powder]
(Powder part)
Nanoporous silica A (pore diameter 7 nm) 10.0% by mass
Copper ion, zinc ion, ammonium ion-supported zeolite (average particle size is about 1.5 μm, and the particle size exceeding 15 μm is 0.1% or less) 10.0
Talc 60.0
(Oil)
Methylphenylpolysiloxane (13 mPa · s, 25 ° C.) 10.0
Liquid paraffin 10.0

(Manufacturing method) The powder part is mixed with a Henschel mixer, oil is added to the mixture, and then pulverized with a 5HP pulperizer (manufactured by Hosokawa Micron Co., Ltd.), and pressed into an inner plate to obtain a compact deodorant powder.
The resulting compact deodorant powder has sufficient usability (non-roughness), deodorizing effect, and discoloration resistance.

"Example 9"
[Odor control spray]
(Powder part)
Nanoporous silica B (pore diameter 4nm) 1.0% by mass
Zinc ion and ammonium ion-supported zeolite (average particle size is about 5 μm, and particle size exceeding 15 μm is 5% or less) 3.0
Zinc oxide 2.0
(Oil)
Decamethylcyclopentasiloxane 5.0
(Additive)
Isopropyl myristate 0.5
Tetra-2-ethylhexanoic acid diglycerol sorbitan 0.5
(Propellant)
n-Butane 75.0
i-Butane 13.0

(Manufacturing method) After mixing a powder part with a kneader and mixing an oil component and an additive with a blender, it fills a spray can sequentially, and also fills a propellant, and obtains a deodorizing spray.
The resulting deodorant spray is excellent in the dispersibility of the powder in the propellant, and excellent in usability (no roughness), deodorizing effect, and discoloration resistance.

"Example 10"
[Baby powder]
(Powder part)
Nanoporous silica B (pore diameter 4 nm) 15.0 mass%
Talc 65.3
Calcium carbonate 17.0
Silver ion and ammonium ion-supported zeolite (average particle size is about 8 μm, and particle size exceeding 15 μm is 1% or less) 2.0
(Oil)
Methylphenylpolysiloxane (13 mPa · s, 25 ° C.) 0.4
Dimethylpolysiloxane / polyethylene glycol copolymer 0.1
(Additive)
Preservative 0.2

(Manufacturing method) The above ingredients are thoroughly mixed with a blender to obtain a baby powder.
The resulting baby powder has excellent usability (no roughness), deodorization effect, and discoloration resistance.

"Example 11"
[Deodorant Stick]
Methyl trimethicone 60.0% by mass
Squalane 10.0
Hydrocarbon wax 10.0
Nanoporous silica B (pore size 4 nm) 5.0
Zinc ion and ammonium ion-supported zeolite (average particle size is about 10 μm, and the particle size exceeding 15 μm is 20% or less) 15.0

(Manufacturing method) A mixture of the above components is filled in a container to obtain a deodorant stick.
The obtained deodorant stick is excellent in usability (non-roughness), deodorizing effect, and discoloration resistance when applied to the armpit.

"Example 12"
[Roll-on deodorant]
Dodecamethylcyclohexasiloxane 67.0% by mass
Ethanol 20.0
Sorbit 4.0
Nanoporous silica C (pore diameter 1.5 nm) 1.0
Aluminum chloride 1.0
Magnesium oxide 2.0
Silver ion, copper ion, ammonium ion-supported zeolite (average particle size is about 2 μm, and particle size exceeding 15 μm is 3% or less) 5.0

(Manufacturing method) The said component is mixed, it puts into a roll-on container, and roll-on deodorant cosmetics are obtained.
The obtained roll-on deodorant cosmetic has no powder agglomeration and is excellent in usability (no roughness), deodorization effect, and discoloration resistance.

"Example 13"
[Powder spray]
(Powder part)
Nanoporous silica B (pore diameter 4nm) 2.0% by mass
Aluminum hydroxychloride 0.5
Zinc ion, copper ion, ammonium ion-supported zeolite (average particle size is about 1.5 μm, and particle size exceeding 15 μm is 0.5% or less) 1.0
Talc 0.5
(Oil)
Decamethylcyclopentasiloxane 1.5
Fragrance 0.2
(Propellant)
Isopentane 10.0
Liquefied petroleum gas 83.3

(Manufacturing method) The powder part is mixed with a kneader, the oil is mixed with a blender, each is sequentially filled in a spray can, and further, a propellant is filled to obtain a powder spray.
The resulting powder spray has good dispersibility in the probelant, no clogging of the nozzle during spraying, good elongation on the skin, and excellent antiperspirant, deodorizing effect, and discoloration resistance.

"Example 14"
[Powder spray]
(Powder part)
Nanoporous silica (pore size 1.5nm) 0.5% by mass
Silver ion, copper ion, ammonium ion-supported zeolite (average particle size is about 1.0 μm, and particle size exceeding 15 μm is 0.05% or less) 1.5
Zinc oxide 0.2
Silica 1.5
(Oil)
Polyoxyethylene nonylphenyl ether 0.5
Dimethylpolysiloxane (1.5 mPa · s, 25 ° C.) 0.1
Isopropyl myristate 0.5
(Additive)
Polyoxyethylene sorbitan monooleate 0.1
Fragrance 0.1
(Propellant)
Liquefied petroleum gas 95.0

(Manufacturing method) The powder part is mixed with a kneader, the oil is mixed with a blender, each is sequentially filled in a spray can, and further, a propellant is filled to obtain a powder spray.
The obtained powder spray has a good feeling of use without being agglomerated for long-term storage, and exhibits a deodorizing effect and discoloration resistance sufficiently.

"Example 15"
[Compact deodorant powder]
(Powder part)
Nanoporous silica B (pore diameter 4 nm) 30.0% by mass
Silver ion, zinc ion, ammonium ion-supported zeolite (average particle size is about 1.5 μm, and particle size exceeding 15 μm is 1% or less) 20.0
Talc 30.0
(Oil)
Methylphenylpolysiloxane (13 mPa · s, 25 ° C.) 10.0
Liquid paraffin 10.0

(Manufacturing method) A powder part is mixed with a Henschel mixer, and after adding oil to this mixture, it grind | pulverizes with a 5HP pulperizer (Hosokawa micron), this is press-molded to a medium plate, and compact deodorant powder is obtained.
The obtained compact deodorant powder had no caking during use, had a good feeling on the skin, and had sufficient deodorizing effect and discoloration resistance.

"Example 16"
[Odor control spray]
(Propellant)
n-butane 76.0% by mass
i-Butane 15.0
(Oil)
Dimethylpolysiloxane (1.5 mPa · s, 25 ° C.) 5.0
(Powder part)
Nanoporous silica A (pore diameter 7 nm) 2.5
Zinc ion and ammonium ion-supported zeolite (average particle size is about 0.5 μm, and the particle size exceeds 15 μm is 1% or less) 0.5
(Additive)
Isopropyl myristate 0.5
Tetra-2-ethylhexanoic acid diglycerol sorbitan 0.5

(Manufacturing method) After mixing a powder part with a kneader and mixing an oil component and an additive with a blender, it fills in a spray can, and also fills with a propellant, and obtains a deodorizing spray.
The obtained deodorant spray has good dispersibility in the propellant of the powder part, has a smooth and pleasant feel, and sufficiently exhibits the deodorizing effect and discoloration resistance.

"Example 17"
[Baby powder]
(Powder part)
Talc 55.0% by mass
Nanoporous silica B (pore size 4 nm) 25.0
Calcium carbonate 17.0
Silver ion, copper / ammonium ion-supported zeolite (average particle size is about 8 μm, and particle size exceeding 15 μm is 20% or less) 2.3
(Oil)
Methylphenylpolysiloxane (13 mPa · s, 25 ° C.) 0.4
Dimethylpolysiloxane / polyethylene glycol copolymer 0.1
(Additive)
Preservative 0.2

(Manufacturing method) The above ingredients are thoroughly mixed with a blender to obtain a baby powder.
The resulting baby powder does not agglomerate, has a smooth use feeling, and is excellent in deodorizing effect and discoloration resistance.

"Example 18"
[Deodorant Stick]
Methyl trimethicone 60.0% by mass
Squalane 10.0
Hydrocarbon wax 10.0
Silver ion, copper ion, zinc ion, ammonium ion-supported zeolite (average particle size is about 1.5 μm, and particle size exceeding 15 μm is 1.5% or less)
10.0
Nanoporous silica A (pore diameter 7 nm) 9.0
Aluminum, Zirconium, Hydrochloride 1.0

(Manufacturing method) What mixed the said component is filled in a container and a deodorant stick is obtained.
When the obtained deodorant stick is applied under the armpit, it has a smooth and good feel and is excellent in deodorizing effect and discoloration resistance.

"Example 19"
[Roll-on deodorant cosmetic]
Dodecamethylcyclohexasiloxane 51.0% by mass
Ethanol 20.0
Sorbit 4.0
Copper ion, ammonium ion-supported zeolite (average particle size is about 10 μm, and particle size exceeding 15 μm is 10% or less) 5.0
Nanoporous silica A (pore diameter 7 nm) 15.0
Aluminum ・ Zirconium ・ Hydroxychloride 5.0

(Manufacturing method) The said component is mixed, it puts into a roll-on container, and roll-on deodorant cosmetics are obtained.
The obtained roll-on deodorant cosmetic is free from agglomeration of the powder part, makes the skin dry with a refreshed feeling of use, and is excellent in deodorization effect and discoloration resistance.

"Example 20"
[Body washing fee]
N-lauryl-L glutamic acid triethanolamine 6.0% by mass
N-laurylmethyl taurine sodium 3.0
Lauric acid triethanolamine 9.5
Myristic acid triethanolamine 9.5
Lauryl imidazolinium betaine 5.0
Lauryl diethanolamide 5.0
Propylene glycol 7.0
Silver ion / ammonium ion-supported zeolite (average particle size is about 5 μm, and particle size exceeding 15 μm is 5% or less) 0.5
Nanoporous silica A (pore diameter 7 nm) 1.0
Aluminum chloride 0.3
Aluminum hydroxide 0.2
Methylphenylpolysiloxane (13 mPa · s, 25 ° C.) 1.0
Purified water Residual fragrance 0.01
Preservative 0.1
Ethylenediaminetetraacetic acid sodium salt 0.01

(Manufacturing method) Purified water is heated to 70 ° C., and other components are sequentially added and dissolved by stirring. Cool to room temperature and fill a resin bottle with a stirring sphere to obtain a body wash.
The resulting body cleansing agent has a detergency and discoloration resistance as well as a good system stability and usability (no roughness) while having detergency and foaming power.

"Example 21"
[Carmine lotion]
Ethanol 12.5% by mass
(Oil)
Methyltrimethicone 2.0
(Humectant)
Glycerin 2.0
1,3-butylene glycol 2.0
(Powder)
Iron oxide (Bengara) 0.15
Zinc oxide 0.5
Silver ion and ammonium ion-supported zeolite (average particle size is about 1.5 μm, and the particle size exceeding 15 μm is 0.2% or less) 0.5
Nanoporous silica C (pore size 1.5 nm) 0.5
Kaolin 1.5
(Drug)
Camphor 0.2
Phenol 0.02
Fragrance 0.01
Anti-fading agent 0.01
Purified water residue

(Manufacturing method) A fragrance was added to ethanol, a humectant, and an oil to dissolve. Camphor and phenol were dissolved in purified water, and the powder agent, anti-fading agent and the above-mentioned ethanol moisturizer phase were added and stirred, and the powder agent was wet dispersed. A carmine lotion was obtained by filtering through about 160 mesh.
The carmine lotion has an effect of calming hot flashes after sunburn, and is excellent in usability without rust, deodorizing effect, and discoloration resistance.

"Example 22"
[Essence oil]
(Oil)
Olive oil 39.69% by mass
Liquid paraffin 25.0
Squalane 20.0
(Powder)
Dimethylpolysiloxane (6 mPa · s, 25 ° C.) 3.0
Silver ion, zinc ion, ammonium ion-supported zeolite (average particle size is about 5 μm, and particle size exceeding 15 μm is 20% or less) 2.0
Nanoporous silica B (pore diameter 4 nm) 10.0
(Other)
Vitamin E acetate 0.2
Antioxidant 0.1
Fragrance 0.01

(Manufacturing method) Oil obtained by carbonizing a powdered drug, antioxidant, and fragrance into oil and stirring the mixture is filled in a resin bottle containing a stirring sphere to obtain an essence oil.
The essence oil has good usability (non-roughness) and is excellent in deodorizing effect and discoloration resistance.

"Example 23"
〔Facial wash〕
(fatty acid)
Stearic acid 10.0% by mass
Palmitic acid 10.0
Myristic acid 10.0
Lauric acid 4.0
(Oil)
Methylphenyl polysiloxane (13 mPa · s, 25 ° C.) 2.0
(alkali)
Potassium hydroxide 6.0
(Humectant)
PEG 1500 10.0
Glycerin 15.0
(Surfactant)
Glycerol monostearate ester 2.0
POE (20) sorbitan monostearic acid 2.0
(Powder)
Silver ion / ammonium ion-supported zeolite (average particle size is about 10 μm, and particle size exceeding 15 μm is 20% or less) 2.0
Nanoporous silica A (pore diameter 7 nm) 2.0
Preservative 0.1
Sodium ethylenediaminetetraacetate 0.05
Fragrance 0.01
Purified water residue

(Manufacturing method) Fatty acids, oils, moisturizers and preservatives are dissolved by heating and kept at 70 ° C. Purified water, in which the alkali has been dissolved in advance, is added to the stirring oil phase. After the addition, the temperature is kept at 70 ° C. for a while to complete the neutralization reaction. Next, a melted surfactant, chelating agent, fragrance, and powder are added, followed by stirring, mixing, deaeration, and filtration, followed by cooling to obtain a facial cleanser.
The face wash has excellent detergency and foaming properties, has good usability without roughness, and is also excellent in deodorizing effect and discoloration resistance.

"Example 24"
[Pack (Peel-off type)]
(Coating agent)
Polyvinyl acetate emulsion 15.0% by mass
Polyvinyl alcohol 10.0
(Humectant)
Sorbitol 5.0
PEG400 5.0
(Oil)
Jojoba oil 2.0
Methylphenylpolysiloxane (13 mPa · s, 25 ° C.) 1.0
Squalane 1.0
(Surfactant)
POE sorbitan monostearate ester 1.0
(Powder)
Titanium oxide 4.0
Silver ion and ammonium ion-supported zeolite (average particle size is about 1.5 μm, and particle size exceeding 15 μm is 2% or less) 3.0
Nanoporous silica B (pore size 4 nm) 4.0
Talc 4.0
(alcohol)
Ethanol 8.0
Fragrance 0.01
Preservative 0.1
Purified water residue

(Manufacturing method) Powder is added to purified water and dispersed sufficiently, and then a moisturizing agent is added. After heating to 70 to 80 ° C, the coating agent is added and dissolved. Add fragrances, preservatives, surfactants and oils to ethanol. This was added to the aqueous phase and mixed. Degas, filter and cool to get pack.
The pack has excellent usability (no roughness), deodorization effect, and discoloration resistance.

"Example 25"
[Pressed powder]
(Powder)
Nanoporous silica A (pore diameter 7 nm) 50.0% by mass
Aluminum hydroxychloride 1.0
Silver ion, zinc ion, ammonium ion-supported zeolite (average particle size is about 6 μm, and particle size exceeding 15 μm is 15% or less) 5.0
Talc 37.0
(Oil)
Liquid paraffin 2.0
Methylphenylpolysiloxane (13 mPa · s, 25 ° C.) 1.0
Perfume appropriate amount

(Manufacturing method) After sufficiently mixing the powder components, the fragrance dissolved in the oil is uniformly sprayed and mixed. After this powder is pulverized, compression molding is performed to obtain a pressed powder.
The pressed powder is excellent in usability (no roughness), deodorizing effect, and discoloration resistance.

"Example 26"
〔Soap〕
Sodium lauric acid monoglyceride sulfate residue Residual sodium lauryl sulfate ester 10.0% by mass
Coconut oil fatty acid sodium 30.0
Cetyl alcohol 3.5
Methylphenylpolysiloxane (13 mPa · s, 25 ° C.) 0.5
Silver ion and ammonium ion-supported zeolite (average particle size is about 1.5 μm, and particle size exceeding 15 μm is 1% or less) 1.0
Nanoporous silica B (pore size 4 nm) 4.0
Fragrance 0.01
Dye 0.01
Antioxidant 0.1
Ethylenediaminetetraacetic acid sodium salt 0.01

(Manufacturing method) The above components are added to a mixer, mixed and stirred, then applied to a roll and a plotter, kneaded and compressed, molded into a rod shape, extruded, and stamped to obtain soap.
The soap has excellent usability (no roughness), deodorization effect, and discoloration resistance.

"Example 27"
[Emollient lotion]
(Oil)
Cetyl alcohol 1.0 mass%
Beeslow 0.5
Vaseline 2.0
Squalane 6.0
Dimethylpolysiloxane (1.5 mPa · s, 25 ° C.) 2.0
(alcohol)
Ethanol 5.0
(Humectant)
Glycerin 4.0
1,3 Butylene glycol 4.0
(Surfactant)
POE (10) monooleate 1.0
Glycerol monostearate ester 1.0
(Mucus)
Quince seed extract (5% aqueous solution) 20.0
(Powder)
Silver ion, copper ion, zinc ion, ammonium ion-supported zeolite (average particle size is 3.5 μm, and particle size exceeding 15 μm is 5% or less) 2.0
Nanoporous silica B (pore size 4 nm) 1.0
Phenoxyethanol 0.05
Colorant 0.01
Fragrance 0.01
Purified water residue

(Manufacturing method) A moisturizing agent and a colorant are added to purified water, and the mixture is heated to 70 ° C. Surfactant and preservative are added to the oil and heated to 70 ° C. This is added to the previous aqueous phase and pre-emulsified. To this, a quince seed extract, powder and ethanol are added, stirred, and the emulsified particles are homogenized with a homomixer, followed by deaeration, filtration and cooling to obtain an emollient lotion.
The above emollient lotion is excellent in usability (no roughness), deodorizing effect, and discoloration resistance.

"Example 28"
[Oil-based gel (emulsification type)]
(Oil)
Liquid paraffin 10.0% by mass
Glycerol tri-2-ethylhexanoate 48.0
Decamethylcyclopentasiloxane 2.0
(Humectant)
Sorbitol 10.0
PEG400 5.0
(Surfactant)
Lauroylmethyl taurine sodium 5.0
POE octyldodecyl alcohol ether 10.0
(Powder)
Silver ion, zinc ion ammonium ion-supported zeolite (average particle size is about 2.0 μm, and particle size exceeding 15 μm is 3% or less) 2.0
Nanoporous silica B (pore diameter 4 nm) 2.0
Fragrance 0.01
Purified water residue

(Manufacturing method) A moisturizing agent and acylmethyl taurine are added to purified water and heated to 70 ° C. Add POE octyldodecyl ether and fragrance to oil and heat to 70 ° C. Gradually add this and the powder to the previous aqueous phase. After homogenizing the emulsified particles with a homomixer, deaeration, filtration and cooling are performed to obtain an oily gel.
The oily gel has excellent usability (no roughness), deodorizing effect, and discoloration resistance.

"Example 29"
〔cream〕
(Oil)
Cetyl alcohol 5.0% by mass
Stearic acid 3.0
Methylphenylpolysiloxane (13 mPa · s, 25 ° C.) 1.0
Vaseline 4.0
Squalane 9.0
Glycerol tri-2-ethylhexanoate 7.0
(Humectant)
Dipropylene glycol 5.0
Glycerin 5.0
(Surfactant)
Propylene glycol monostearate 3.0
POE (20) cetyl alcohol ether 3.0
(alkali)
Triethanolamine 1.0
(Powder)
Silver ion and ammonium ion-supported zeolite (average particle size is about 1.5 μm, and particle size exceeding 15 μm is 1.5% or less) 1.0
Nanoporous silica C (pore size 1.5 nm) 0.1
Preservative 0.1
Antioxidant 0.05
Fragrance 0.01
Purified water residue

(Manufacturing method) A moisturizer and an alkali are added to purified water, and it adjusts to 70 degreeC. After heating and dissolving the oil, a surfactant, preservative, antioxidant, and fragrance are added and adjusted to 70 ° C. This is added to the previous aqueous phase and pre-emulsified. After adding powder and making the emulsified particles uniform with a homomixer, deaeration, filtration, and cooling are performed.
The cream is excellent in usability (no roughness), deodorizing effect, and discoloration resistance.

"Example 30"
[Wet sheet]
Ion-exchanged water 65.38% by mass
Ethanol 30.00
Silver / zinc / ammonium-supported zeolite (average particle size is 3 μm, and particle size exceeding 15 μm is 1% or less) 1.0
Nanoporous silica A (pore size 7 nm) 3.0
Polyoxyethylene polyoxypropylene decyl tetradecyl ether
0.4
Citric acid 0.04
Sodium citrate 0.04
Adenine 0.05
Ethylenediamine hydroxyethyl triacetic acid trisodium 0.05
Camphor 0.01
Menthol 0.03

(Manufacturing method) It is obtained by dissolving a water-soluble component well in ion-exchanged water, then immersing it in a non-woven fabric while adding and dispersing well an insoluble component, and then filling it in an aluminum pouch pack.
The wet sheet is excellent in usability (no roughness), deodorizing effect, and discoloration resistance.

"Example 31"
[Powder Impuff]
Talc 69.66% by mass
Polymethylsilsesquioxane spherical powder 10.0
Spherical calcium alginate powder 3.0
Silver / zinc / ammonium supported zeolite (average particle size is 10 μm, 18% or less is more than 15 μm) 2.0
Nanoporous silica C (pore size 1.5 nm) 5.0
Ethylparaben 0.1
Salicylic acid 0.2
Fine zinc oxide (average particle size 60 nm) 5.0
Zinc oxide coated spherical polyethylene powder 5.0
Iron oxide (yellow) 0.015
Iron oxide (red) 0.025

(Manufacturing method) The above components are mixed well in a Henschel mixer, and then pulverized with a pulverizer is filled into a non-woven bag, and this is built into a puff.
The powder impuff is excellent in usability (no roughness), deodorizing effect, and discoloration resistance.

"Example 32"
[Deodorant Stick (Wax)]
Decamethylcyclopentasiloxane 0.1% by mass
Dimethylpolysiloxane (1.5 mPa · s, 25 ° C.) 10.0
Stearyl alcohol 8.0
Polyoxypropylene (40) butyl ether 7.0
Sorbitan sesquiisostearate 2.5
Hardened castor oil 1.5
Nanoporous silica C (pore size 1.5 nm) 20.0
Silver / zinc / ammonium-supported zeolite (average particle size is 3.0 μm, and particle size exceeding 15 μm is 10% or less) 18.0
Talc 10.7
Fine zinc oxide (average particle size 60 nm) 1.0
Hydroxypropyl-β-cyclodextrin 0.1
Zinc oxide coated spherical nylon 12 1.0
Calcium disodium ethylenediaminetetraacetate 0.1

(Manufacturing method) The oil component is heated and melted and mixed well, and then the powder component is added and dispersed and mixed uniformly with a homomixer while heating, and poured into a mold, and cooled to obtain a stick.
The deodorant stick is excellent in usability (no roughness), deodorizing effect, and discoloration resistance.

"Example 33"
[Deodorant stick (non-oil type)]
Talc 49.0% by mass
Sericite 20.0
(Dimethicone / vinyl dimethicone) cross-polymer spherical powder 5.0
Nanoporous silica C (pore size 1.5 nm) 10.0
Polymethylsilsesquioxane spherical powder 5.0
Silver / zinc / ammonium-supported zeolite (average particle size is 0.9 μm, and particle size exceeding 15 μm is 0.3% or less) 10.0
Aluminum magnesium silicate 1.0

(Manufacturing method) After mixing 20 parts of ion-exchanged water with 1 part of the weight of magnesium aluminum silicate well into a gel, thoroughly mix and disperse other ingredients to form a slurry, then pour into a mold Then, this is put in a dryer to evaporate the moisture and cooled to obtain a stick.
The deodorant stick is excellent in usability (no roughness), deodorizing effect, and discoloration resistance.

"Example 34"
[Water-based gel]
POE (14) POP (7) Dimethyl ether 7.0% by mass
PEG1500 8.0
Silver / copper / ammonium supported zeolite (average particle size is 5 μm, 20% or less if the particle size exceeds 15 μm) 1.0
Nanoporous silica B (pore size 4 nm) 3.0
Carboxyvinyl polymer 0.4
Methylcellulose 0.2
POE (15) oleyl alcohol ether 1.0
Potassium hydroxide 0.1
ε-polylysine 0.2
Edetate tetrasodium 0.05
Fragrance 0.1
Purified water 78.95

(Production method) After water-soluble polymer is uniformly dissolved in purified water, ε-polylysine and tetrasodium edetate are dissolved, a surfactant is added to POE (14) POP (7) dimethyl ether, and dissolved by heating. Add fragrance to this. The aqueous phase prepared previously is gradually added, and finally an aqueous potassium hydroxide solution is added, followed by sufficient stirring for neutralization.
The aqueous gel is excellent in usability (no roughness), deodorizing effect, and discoloration resistance.

"Example 35"
[Medical body cleaning fee]
Lauryl sulfate triethanolamine salt (40% aqueous solution)
40.0% by mass
Lauryl polyoxyethylene (3 mol) sodium sulfate salt (30% aqueous solution)
20.0
Lauryl diethanolamide 5.0
Silver / zinc / ammonium supported zeolite (average particle size is 3.5 μm, and particle size exceeding 15 μm is 1% or less) 2.0
Nanoporous silica C (pore size 1.5 nm) 2.0
Glycerin monopalmitate 1.0
Lanolin derivative 2.0
Propylene glycol 5.0
Purified water Residual fragrance Appropriate dye Appropriate amount Ethylenediaminehydroxyethyl triacetate trisodium salt (dihydrate)
Appropriate amount

(Manufacturing method) It is obtained by thoroughly mixing water-soluble components and then filling a container while adding and mixing well with powder components. Shake well when using.
The body cleaning material has excellent usability (no roughness), deodorizing effect, and discoloration resistance.

According to the present invention, since a deodorant cosmetic having an excellent deodorizing effect and excellent dispersibility and discoloration resistance of the powder component is provided, the deodorant cosmetic is intended for deodorization or deodorization, It is preferably used as antiperspirant cosmetics, deodorant cosmetics and the like.

Claims (8)

  A deodorizing cosmetic comprising antibacterial zeolite and nanoporous silica having a hexagonal crystal structure.   An anti-odor cosmetic comprising an antibacterial zeolite, nanoporous silica having a hexagonal crystal structure, and zinc oxide.   The deodorant cosmetic according to claim 1 or 2, wherein the nanoporous silica has a pore diameter of 1 to 7 nm.   The deodorant cosmetic according to any one of claims 1 to 3, wherein the content of the antibacterial zeolite is 0.1 to 90 mass% with respect to the total amount of the deodorant cosmetic.   5. The deodorant cosmetic according to claim 1, wherein a content of the nanoporous silica is 0.1 or more by mass ratio with respect to a content of the antibacterial zeolite.   The deodorant cosmetic according to any one of claims 2 to 5, wherein a content of the zinc oxide is 0.1 to 90% by mass with respect to a total amount of the deodorant cosmetic.   The antibacterial cosmetic ion according to any one of claims 1 to 6, wherein the antibacterial metal ion in the antibacterial zeolite is one or more selected from silver, copper and zinc ions. . The antibacterial zeolite has an average particle size of 10 μm or less, a particle size distribution in which the particle size exceeds 15 μm is 20% or less, and the nanoporous silica has an average particle size of 0.01 to 50 μm. The deodorant cosmetic according to any one of claims 1 to 7.