WO2007083828A1 - セラミックス複合体光変換部材およびそれを用いた発光装置 - Google Patents
セラミックス複合体光変換部材およびそれを用いた発光装置 Download PDFInfo
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- WO2007083828A1 WO2007083828A1 PCT/JP2007/051108 JP2007051108W WO2007083828A1 WO 2007083828 A1 WO2007083828 A1 WO 2007083828A1 JP 2007051108 W JP2007051108 W JP 2007051108W WO 2007083828 A1 WO2007083828 A1 WO 2007083828A1
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Definitions
- the present invention relates to a light-emitting device such as a light-emitting diode that can be used for a display, illumination, backlight light source, and the like.
- a ceramic composite light-converting member that is a light-converting member that obtains fluorescence by using irradiated light
- the present invention relates to a light emitting device using a ceramic composite light converting member.
- white light-emitting diodes using blue light-emitting diodes are light weight, do not use mercury, and have a long service life. Therefore, demand is expected to increase rapidly in the future.
- the most commonly used method for converting blue light of a blue light emitting element into white light is to obtain a pseudo white color by mixing yellow that is complementary to blue. For example, as described in Japanese Patent Application Laid-Open No. 2 0 0 0-2 0 8 8 1 5, fluorescence that emits yellow light by absorbing part of blue light is emitted on the front surface of a light emitting diode that emits blue light.
- a white light emitting diode can be formed by providing a coating layer containing a body and providing a mold layer or the like that mixes blue light from a light source and yellow light from a phosphor.
- a coating layer containing a body As the phosphor, YAG (Y 3 A 1 5 0 1 2 ) (hereinafter YAG: C e) powder activated with cerium is used.
- the present inventors fluoresce, and a plurality of oxide phases including (Y, C e) 3 A 1 5 0 12 phase and A 1 2 0 3 phase are continuously and three-dimensionally entangled with each other.
- a ceramic composite light conversion member made of a solidified body and a white light emitting device composed of a blue to violet light emitting element and this ceramic composite light conversion member.
- This ceramic composite light conversion member can obtain uniform yellow fluorescence because the fluorescent phase is uniformly distributed, and is excellent in heat resistance because it is a ceramic.
- no resin is required for the structure of the white light emitting device, and the fluorescence intensity can be easily controlled by the thickness. For this reason, the white light emitting device has little color unevenness and variation, and is extremely suitable for high output.
- the fluorescence color of the YAG: Ce phosphor that has not been adjusted for the emission wavelength (hereinafter referred to as unadjusted YAG: Ce) is yellow (for example, chromaticity)
- YAG: Ce phosphor is known as a known technology that, for example, by partially replacing the Y element with the Gd element, the peak of the fluorescence wavelength can be shifted to the longer wavelength side (Materials) Integration, ⁇ 6, ⁇ 7 (2003) ⁇ 4 ⁇ 46; and Applied Physics Vol. 7 1 Vol. 12 (2002) P 1518-1522).
- the luminous efficiency of the adjusted YAG: Ce is, for example, as described in the above document (Material Integration, voll6, No7 (2003) p41-46).
- a light conversion material that can emit fluorescence adjusted to the optimum wavelength with respect to the emission wavelength of the blue light emitting element to be combined while maintaining high luminous efficiency. It has been demanded.
- the first object of the present invention is to provide efficient fluorescence and a peak wavelength of 5 4
- Suitable for constructing high-efficiency white light-emitting devices in combination with blue light-emitting elements which can emit light adjusted to 0 to 58 80 nm, and the obtained fluorescence is homogeneous, and has excellent heat resistance and durability. It is to provide a member for light conversion. In addition, it can be adjusted to white using the blue-violet light emitting element and the light conversion material, and the color unevenness / variation is small.
- An object of the present invention is to provide a white light-emitting device that is highly suitable for high output and highly efficient without deterioration because it does not require fat.
- the YAG: Ce phosphor is known as a known technique that the peak of the fluorescence wavelength can be shifted to the longer wavelength side by increasing the amount of Ce in the activator (J. Physicsand C hemistryof S olids, vo 1 6 5 (2 0 0 4) p 8 4 5— 8 5 0). As a result, the peak of the fluorescence wavelength can be moved to around 560 nm.
- the second object of the present invention is that the fluorescence can be emitted efficiently, and the peak wavelength can be adjusted to 5550-560 nm, and that the obtained fluorescence is homogeneous, heat resistance and durability.
- An object of the present invention is to provide a light conversion material suitable for constituting a high-efficiency white light emitting device in combination with an excellent blue light emitting element. Also, it can be adjusted to white color using blue to purple light emitting elements and this light conversion member, and the color unevenness and variation are small. And high The invention is to provide an efficient white light emitting device
- the present inventors have found that when a certain type of ceramic composite is used as a light conversion member, the wavelength of the fluorescence peak can be adjusted and controlled while suppressing a decrease in fluorescence intensity, and the present inventors have reached the present invention.
- the present invention has a structure in which at least two or more oxide phases are continuously and three-dimensionally entangled with each other, and at least one of the oxide phases is a phase emitting fluorescence.
- a solidified body, and the overall composition is
- the present invention provides an oxide of A 1, an oxide of Y, an oxide of Ce, and an oxide of G d,
- the present invention relates to a method for producing a ceramic composite light conversion member.
- the present invention also relates to a light emitting device comprising the ceramic composite light converting member and a light emitting element.
- One embodiment of the light-emitting device includes a light-emitting element that emits light having a peak at a wavelength of 400 nm to 5200 nm, and a peak at a wavelength of 5400 to 5800 nm or 5500 to 5600 nm.
- a white light emitting device comprising the ceramic composite light converting member that emits fluorescence, and one form of the light emitting device is a white light emitting device in which the light emitting element is a light emitting diode element.
- the ceramic composite light conversion member of the present invention By using the ceramic composite light conversion member of the present invention, it is adjusted to a peak wavelength of 5 40 to 5 80 nm or 5 50 to 5 60 nm with excitation light having a wavelength of 400 to 52 O nm.
- the obtained yellow fluorescence can be obtained while maintaining high efficiency without reducing the fluorescence intensity.
- uniform yellow fluorescence with wavelength adjustment can be obtained from the phase that emits uniformly distributed fluorescence, and because it is ceramic, it has excellent heat resistance and durability.
- An optical conversion material suitable for constituting a light emitting device can be provided.
- the light emitting device comprising the blue-violet light emitting element of the present invention and the ceramic composite light conversion member can be adjusted to white, and the color unevenness and variation are small, and the ceramic composite light conversion member itself is a bulk body. Because there is no need for encapsulating resin, it is possible to provide a white light emitting device that is highly suitable for high output and high efficiency without deterioration due to heat and light.
- FIG. 1 is a schematic cross-sectional view showing an embodiment of a light emitting device of the present invention.
- 1 is a ceramic composite light converting member
- 2 is a light emitting element (light emitting diode element)
- 3 is a lead wire
- 4 is a lead electrode.
- FIG. 2 is a photomicrograph of Example 1 showing an example of the structure of the ceramic composite light conversion member of the present invention.
- FIG. 3 is a fluorescence spectrum diagram of Example 1 showing an example of fluorescence characteristics of the ceramic composite light conversion member of the present invention.
- FIG. 4 is an excitation spectrum diagram of Example 1 showing an example of fluorescence characteristics of the ceramic composite light conversion member of the present invention.
- Example 5 is a light emission spectrum diagram of Example 6 showing an example of the light emitting device of the present invention.
- FIG. 6 is a photomicrograph of Example 7 showing an example of the structure of the ceramic composite for light conversion of the present invention.
- FIG. 7 is a fluorescence spectrum diagram of Example 7 showing an example of the fluorescence characteristics of the ceramic composite for light conversion of the present invention.
- FIG. 8 is an excitation spectrum diagram of Example 7 showing an example of fluorescence characteristics of the ceramic composite for light conversion of the present invention.
- FIG. 9 is a light emission spectrum diagram of Example 9 showing an example of the light emitting device of the present invention.
- the ceramic composite light conversion member of the present invention is a solidified body having a structure in which at least two or more oxide phases are continuously and three-dimensionally entangled with each other. Both ones fluoresce Is a phase.
- Fluorescence can be emitted by entering excitation light into the ceramic composite light conversion member.
- the value of X in the composition formula is 0.75 or less, or 0.85 or more, it becomes difficult to obtain a good solidified body without cracks, and is limited to the above range.
- the value of b in the composition formula is limited to the above range because the intensity of the obtained fluorescence decreases when the value is 0.8 or more.
- fluorescence cannot be obtained, and when it is 0.3 or more, it is difficult to obtain a good solidified body without cracks, so the range is limited to the above range. .
- the oxide phase varies depending on the composition and production conditions of the solidified body. 2 0 3 phase, (Y, G d, C e) 3 A l 5 ⁇ 12 phase, (Y, G d, C e) A 1 0 3 phase, (Y, G d, C e) 4 A 1 2 ⁇ 9 phase, C e A l M ⁇ 18 phase, Y 2 0 3 phase, G d 2 ⁇ 3-phase, include C E_ ⁇ 2 equality, such oxide phase contains two phases or more less. At least two of each oxide phase has a structure that is continuously and three-dimensionally intertwined. Some oxide phases may be present in a granular form in an intertwined structure formed by other oxide phases. In either case, the boundary between the phases does not have an amorphous or other boundary layer, and the oxide phases are in direct contact with each other. For this reason, there is little loss of light in the ceramic composite light conversion member, and the light transmittance is also high.
- (Y, G d, C e) 3 A 1 5 0 12 phase, (Y, G d, C e) A 1 0 3 phase, etc. can be mentioned as the phases that emit fluorescence. At least one phase that emits is included. Since the oxide phase containing these fluorescent phases is continuously and three-dimensionally entangled with each other, the oxide phases are distributed uniformly in the ceramic composite light conversion member as a whole. Homogeneous fluorescence with no partial bias can be obtained.
- the ceramic composite light conversion member of the present invention can obtain yellow fluorescent light having a peak wavelength of 5400 to 58 nm with at least blue to purple excitation light having a wavelength of 400 to 52 nm. It is possible to obtain fluorescence with excitation light having an intensity of about 70% of the maximum intensity at a wavelength of 420 to 500 nm, and a strong intensity of about the maximum at a wavelength of 4400 to 4800 nm. Furthermore, fluorescence can be emitted even with near ultraviolet light having a wavelength of 300 to 36 nm.
- the peak wavelength of fluorescence may vary slightly depending on the measurement equipment used, correction conditions, etc., but for fluorescence measurements according to the contents of this claim, a solid FP 6500 manufactured by JASCO is combined with an integrating sphere. A quantum efficiency measuring device was used. The fluorescence correction was performed using a sub-standard light source.
- the peak wavelength of yellow fluorescence emitted from the ceramic composite light conversion member can be controlled by the composition.
- the peak wavelength of yellow fluorescence by incorporating the G D_ ⁇ 3/2 on the composition, it is the this move to the long wavelength side. If C e 0 2 mole fraction is constant, the higher the molar fraction of G D_ ⁇ 3/2, the peak wavelength is more moved to the longer wavelength side.
- the value of X in the composition formula is 0.75 or less, or 0.85 or more, it is difficult to obtain a good solidified body without cracks, and is limited to the above range.
- the value of c in the composition formula is less than 0.125, the peak wavelength of fluorescence is shorter than 5500 nm, and if it is 0.3 or more, it is difficult to obtain a good solid without cracks. Therefore, it is limited to the above range.
- the oxide phase varies depending on the composition and the production conditions of the solidified body, but the A 1 2 0 3 phase, (Y, C e) 3 A l 5 ⁇ 12 phase, (Y, C e) A l ⁇ 3 phase, ( Y, C e) 4 A 1 2 0 9 phase, C e A lu Ou phase, Y 2 0 3 phase, include C E_ ⁇ 2 equality include two or more phases at least the oxide phase was doing. At least two phases of each oxide phase are intertwined with each other continuously and three-dimensionally. Some oxide phases may be present in granular form in an intertwined structure formed by other oxide phases. In any case, the boundary between each phase does not have a boundary layer such as amorphous, and the oxide phases are in direct contact with each other. For this reason, there is little loss of light in the ceramic complex for light conversion, and the light transmittance is also high.
- the fluorescent phase includes (Y, C e) 3 A 1 5 0 12 phase, (Y, C e) C 1 0 3 phase, etc. At least 1 such fluorescent phase is present. Included. Since the oxide phases including these fluorescent phases are intertwined with each other in a three-dimensional manner, the oxide phases as a whole are uniformly distributed in the ceramic composite for light conversion. And uniform fluorescence with no bias.
- the present ceramic composite for light conversion of the present invention can obtain yellow fluorescence having a peak wavelength of 5500 to 5600 nm with at least blue to purple excitation light having a wavelength of 400 to 5200 nm. It is possible to obtain fluorescence with an excitation light having an intensity of about 70% of the maximum intensity at a wavelength of 420 nm to 500 nm and a strong intensity of about 70% at a wavelength of 440 nm to 4800 nm. Furthermore, fluorescence can be emitted even with near ultraviolet light having a wavelength of 300 to 36 nm.
- the peak wavelength of fluorescence may vary slightly depending on the measurement equipment used, correction conditions, etc., but for the fluorescence measurement according to this claim, solid quantum efficiency combining JASCO's FP 6500 with an integrating sphere A measuring device was used. The fluorescence correction was corrected with a sub-standard light source. The peak wavelength of yellow fluorescence emitted by this ceramic composite for light conversion is
- the composition can be controlled.
- the peak wavelength of yellow fluorescence as the molar fraction of C E_ ⁇ 2 is high, more moves to the long wavelength side, can be adjusted up to about 5 6 0 nm.
- the fluorescence intensity increases monotonously, and there is no decrease in fluorescence intensity in this fluorescence peak wavelength range.
- the conventional YAG: Ce phosphor powder increasing the Ce content of the activator can shift the fluorescence peak wavelength to the longer wavelength side, but the peak wavelength is 5500 nm. If it exceeds, the fluorescence intensity decreases due to concentration quenching.
- this ceramic composite for light conversion yellow fluorescent light with high intensity, which can be adjusted arbitrarily within the peak wavelength range of 55-560 nm, which cannot be obtained with conventional YAG: Ce phosphor powder. Can be obtained.
- the solidified body constituting the ceramic composite light converting member of the present invention is produced by solidifying the raw material oxide after melting. For example, it is possible to obtain a solidified body by a simple method of cooling and condensing the melt charged in the crucible held at a predetermined temperature while controlling the cooling temperature. It has been done. This is because unidirectional solidification causes the contained crystal phase to continuously grow in a single crystal state, thereby reducing the attenuation of light in the member.
- One embodiment of a method for producing a ceramic composite light conversion member of the present invention comprises an oxide of A 1, an oxide of Y, an oxide of Ce, and an oxide of G d,
- the solidified body constituting the ceramic composite light conversion member of the present invention has been disclosed in Japanese Patent Application Laid-open No. Hei 7-1 4 9 5 9 except that at least one oxide phase is a fluorescent phase.
- the disclosures of these applications or patents are hereby incorporated by reference.
- each oxide phase including a phase that emits fluorescence is present in a single crystal state continuously and three-dimensionally intertwined, and has a peak wavelength of 5 4 Homogeneous yellow fluorescence adjusted to 0 to 5800 nm or 5500 to 560 nm can be efficiently obtained.
- it since it is composed entirely of inorganic oxide ceramics, it has excellent heat resistance and durability, and is not deteriorated by light.
- each oxide phase exists in a single crystal state, and the boundary between each phase forms a clean interface without a boundary layer. Therefore, light loss in the ceramic composite light conversion member is small, and light transmission is achieved. The rate is also high.
- the light emitting device of the present invention is a device composed of the ceramic composite light conversion member of the present invention and a light emitting element, and irradiates the ceramic composite light conversion member with light from the light emitting element to convert the ceramic composite light.
- the light transmitted through the member and the light from the light emitting element are used in the fluorescence converted by the ceramic composite light converting member.
- FIG. 1 is a schematic cross-sectional view showing an embodiment of a light emitting device of the present invention.
- 1 is a ceramic composite light conversion member
- 2 is a light emitting element (light emitting diode element)
- 3 is a lead wire
- 4 is a lead electrode.
- the bulk (plate-like) ceramic composite light converting member 1 is disposed in front of the light emitting element (light emitting diode element) ′ 2 to form a light emitting device.
- a white light-emitting device which is an embodiment of the light-emitting device of the present invention, has a blue to violet light-emitting element that emits light having a peak at a wavelength of 400 nm to 520 nm, and a peak wavelength of 5 by light emitted from the light-emitting element.
- the ceramic composite light conversion member emits yellow fluorescence of 4 0 to 5 80 nm or 5 5 0 to 5 60 nm. Blue to violet light emitted from the light emitting element is incident on a ceramic composite light conversion member whose fluorescence peak wavelength has been adjusted so that a white color can be obtained in accordance with the wavelength.
- yellow fluorescent light and blue-violet transmitted light from the excited fluorescent phase are uniformly mixed by a structure in which the oxide phase is continuously and three-dimensionally entangled with each other and uniformly distributed. As a result, it is possible to obtain white with small color unevenness.
- the ceramic composite light converting member used in the white light emitting device of the present invention can be obtained by processing the solidified body produced by the above method into an appropriate shape such as a plate shape.
- an appropriate shape such as a plate shape.
- the color tone of the light emitting device can be easily controlled, and the variation in color tone can be easily reduced by maintaining the accuracy of the shape.
- it can be used alone as a member, does not require an encapsulating resin, and does not deteriorate due to heat or light, so it can be used in combination with a high-power light-emitting element, enabling high-power white light-emitting devices. is there.
- the light emitted from the light emitting element used in the white light emitting device of the present invention preferably has a peak at a wavelength of 400 nm to 520 nm. This is because fluorescence excitation can be obtained from the ceramic composite light conversion member at that wavelength. A peak at a wavelength of 420 nm to 500 nm is more preferable because stronger fluorescence excitation can be obtained, and a peak at a wavelength of 4400 nm to 4800 nm is more preferable. This is because the fluorescence excitation efficiency of the ceramic composite light conversion member is high at that wavelength, and efficient light emission is obtained, which is suitable for increasing the efficiency of the white light emitting device.
- Examples of the blue to violet light emitting element used in the white light emitting device of the present invention include a light emitting diode element and an element that emits a single laser beam.
- the light emitting diode element is preferable because it is small and inexpensive.
- the white light-emitting device of the present invention when a light-emitting diode element is used as the light-emitting element is called a white light-emitting diode.
- the white light emitting device of the present invention can provide a white light emitting device that can be adjusted to white, has little color unevenness and parallax, is not deteriorated by heat or light, and is extremely suitable for high output and high efficiency. it can.
- the raw material as it is charged into a molybdenum Ruth Po, and set in one direction coagulation device, 1. 3 3 X 1 0 - to melt the raw material under a pressure of 3 P a (1 0- 5 T orr) .
- the crucible is lowered at a speed of 5 mm in the same atmosphere, and three oxidations of A 1 2 0 3 phase, (Y, G d, C e) 3 A 150 12 phase, and C e A lu Ou phase are performed.
- a solidified body consisting of a physical phase was obtained.
- Figure 2 shows the cross-sectional structure perpendicular to the solidification direction of the solidified body.
- the black part of A is A 1 2 ⁇ 3 phase
- the white part of B is (Y, G d, C e) 3 A 1 5 O, 2 phase
- the gray part of C is C e A 1 u ⁇ 18 phase is there.
- Each oxide phase has a structure that is continuously and three-dimensionally entangled with each other, and is a phase that emits the main fluorescence (Y, G d, C e) 3
- a 1 5 0 12 phase is uniformly distributed You can see that For this reason, uniform fluorescence can be obtained.
- FIG. 3 shows the fluorescence spectrum.
- the wavelength of the excitation light is 460 nm, and the fluorescence intensity is shown with the maximum fluorescence intensity of Comparative Example 1 described later as 100.
- a broad fluorescence spectrum with a peak wavelength at 5 63 nm and a maximum fluorescence intensity of about 120 is obtained. Compared with Comparative Example 1, it can be seen that the peak wavelength shifts by about 20 nm toward the longer wavelength side, and the fluorescence intensity is equal to or greater than that.
- Figure 4 shows the excitation spectrum with a fluorescence wavelength of 56 nm. Fluorescence intensity is maximum fluorescence intensity It is shown as a normalized value with a degree of 100. It can be seen that fluorescence close to the maximum intensity can be obtained in the broad blue excitation wavelength range of 4 40 to 4 80 nm. It can also be seen that fluorescence can be obtained even with excitation light in the violet to blue wavelength range of 400 to 4400 nm, the wavelength range of 480 to 520 ⁇ m, and the near ultraviolet wavelength range of 3600 nm or less. .
- Table 1 shows the fluorescence characteristics.
- the relative fluorescence intensity in Table 1 is shown as a relative value with the maximum fluorescence intensity of Comparative Example 1 described later as 100.
- Each raw material powder is weighed so as to have the molar fraction shown in Table 1, and then has a structure in which a plurality of oxide phases are entangled with each other continuously and three-dimensionally by the same process as in Example 1. A solidified body was obtained. That is, comparative example
- the fluorescence peak wavelength was 5400 nm, and the relative fluorescence intensity was compared with Examples 1 to 5 and Comparative Example 4 with the fluorescence intensity at this time being 100.
- the oxide phase in each example is composed of 2 to 4 phases including Al 2 O 3 phase and (Y, G d, C e) 3 Al 5 O 12 phase.
- the oxide phase including the fluorescent phase is uniformly distributed in the solidified body, and uniform fluorescence can be obtained.
- Table 2 shows the fluorescence characteristics of the obtained phosphor.
- the fluorescence intensity is shown as a relative value with the maximum fluorescence intensity of Comparative Example 7 being 100. It can be seen that the adjusted YAG: Ce powder phosphor is unadjusted and that the relative fluorescence decreases at the same time as the fluorescence peak wavelength shifts to the longer wavelength side compared to the unadjusted YAG: Ce powder phosphor.
- Example 1 The solidified body produced in Example 1 was cut into a predetermined shape and thickness, and the resulting ceramic composite light conversion member was combined with a light emitting diode element emitting blue (46 3 nm) to constitute a white light emitting device.
- the emission spectrum was measured.
- this raw material was directly charged into a molybdenum crucible, set in a unidirectional solidification device, and the raw material was melted under a pressure of 1. 3 3 X 1 0— 3 Pa (1 0 " 5 Torr)
- the crucible is lowered at a speed of 5 mm / hour in the same atmosphere, and three oxidations of A 1 2 0 3 phase, (Y, C e) 3 A 1 5 0 12 phase, and C e A lu O phase
- a cross-sectional structure perpendicular to the solidification direction of the solidified body is shown in Fig. 6.
- the black part of A is A 1 2 0 3 phase and the white part of B is (Y, C e) a A 1 5 0 12 phase,
- the gray part is C e A 1 j! O! 8 phase.
- Each oxide phase has a structure that is continuously and three-dimensionally entangled with each other, and the (Y, C e) a 1 5 0 12 phase, which is the main fluorescent phase, is uniformly distributed I know. For this reason, uniform fluorescence can be obtained.
- FIG. 7 shows the fluorescence spectrum.
- the wavelength of the excitation light is 460 nm, and the fluorescence intensity is shown with the maximum fluorescence intensity of Comparative Example 11 described later as 100.
- a broad fluorescence spectrum with a peak wavelength at 5 58 nm and a maximum fluorescence intensity of about 120 is obtained. Compared to Comparative Example 1 1, it can be seen that the peak wavelength has moved about 10 nm to the longer wavelength side, and the fluorescence intensity has increased.
- Figure 8 shows the excitation spectrum with a fluorescence wavelength of 560 nm.
- the fluorescence intensity is shown as a normalized value with the maximum fluorescence intensity being 100. It can be seen that fluorescence close to the maximum intensity can be obtained in the broad blue excitation wavelength range of 4 40 to 4 80 nm. It can also be seen that fluorescence can be obtained even with excitation light in the violet to blue wavelength range of 4400 to 440 nm, the wavelength range of 480 to 520 nm, and the near ultraviolet wavelength range of 36 Onm or less.
- Table 3 shows the fluorescence characteristics.
- the relative fluorescence intensity in Table 3 is shown as a relative value with the maximum fluorescence intensity of Comparative Example 11 described later as 100.
- Each raw material powder is weighed so as to have the molar fraction shown in Table 3, and then has a structure in which a plurality of oxide phases are entangled with each other continuously and three-dimensionally by the same process as in Example 7. A solidified body was obtained.
- the oxide phase is composed of an A 1 2 0 3 phase, a (Y, C e) 3 A 1 5 0 12 phase and a C e A 1, 0 18 phase.
- the oxide phase including the phase that emits fluorescence is uniformly distributed in the solidified body, and uniform fluorescence can be obtained.
- Each raw material powder is weighed so as to have the molar fraction shown in Table 3, and then has a structure in which a plurality of oxide phases are entangled with each other continuously and three-dimensionally by the same process as in Example 7. An attempt was made to obtain a coagulum. The results are shown in Table 3.
- Comparative Examples 9, 10, and 12 cracks occurred in the obtained solidified body, which was unsuitable as a ceramic composite for light conversion.
- Comparative Example 1 1 when C e 0 2 mole fraction is low as 0.0 3, the peak wavelength of the fluorescence is shorter than 5 5 0 nm, for light conversion ceramic box composite for white light - emitting device It was unsuitable for the body.
- the fluorescence characteristics of Comparative Examples 13 and 14 are summarized in Table 4.
- the fluorescence intensity is shown as a relative value with the maximum fluorescence intensity of Comparative Example 13 being 100.
- Y AG Ce powder phosphor 2 is unadjusted
- YAG Fluorescence peak wavelength is shifted to the long wavelength side by about 10 nm compared to Ce powder phosphor 1, but at the same time relative to It can be seen that the fluorescence intensity is greatly reduced.
- Example 7 The solidified body produced in Example 7 was cut into a predetermined shape and thickness, and the resulting ceramic composite for light conversion and a light emitting diode element emitting blue (46 3 nm) were combined to constitute a white light emitting device to emit light.
- the spectrum was measured.
- the ceramic composite light conversion member and the light-emitting device of the present invention can be used for displays, illumination, backlight light sources and the like.
Abstract
Description
Claims
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EP07707355.9A EP1980606B1 (en) | 2006-01-19 | 2007-01-18 | Ceramic composite light converting member and light emitting device using the same |
CN200780002600XA CN101370908B (zh) | 2006-01-19 | 2007-01-18 | 陶瓷复合体光转换构件和用其的发光装置 |
US12/161,403 US8608978B2 (en) | 2006-01-19 | 2007-01-18 | Ceramic composite light-converting member and light-emitting device using the same |
JP2007555013A JP4957557B2 (ja) | 2006-01-19 | 2007-01-18 | セラミックス複合体光変換部材およびそれを用いた発光装置 |
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JP4957557B2 (ja) | 2012-06-20 |
US8608978B2 (en) | 2013-12-17 |
JPWO2007083828A1 (ja) | 2009-06-18 |
CN101370908B (zh) | 2012-04-18 |
US20100231120A1 (en) | 2010-09-16 |
KR20080077403A (ko) | 2008-08-22 |
EP1980606A1 (en) | 2008-10-15 |
EP1980606A4 (en) | 2012-05-23 |
TWI329935B (en) | 2010-09-01 |
CN101370908A (zh) | 2009-02-18 |
KR101035029B1 (ko) | 2011-05-19 |
WO2007083828A9 (ja) | 2008-10-16 |
EP1980606B1 (en) | 2017-09-06 |
TW200733434A (en) | 2007-09-01 |
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