WO2007045217A1 - Verfahren zur beschichtung eines bauteils - Google Patents

Verfahren zur beschichtung eines bauteils Download PDF

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Publication number
WO2007045217A1
WO2007045217A1 PCT/DE2006/001797 DE2006001797W WO2007045217A1 WO 2007045217 A1 WO2007045217 A1 WO 2007045217A1 DE 2006001797 W DE2006001797 W DE 2006001797W WO 2007045217 A1 WO2007045217 A1 WO 2007045217A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
spraying
thermal
intermediate layer
coating
Prior art date
Application number
PCT/DE2006/001797
Other languages
German (de)
English (en)
French (fr)
Inventor
Thorsten Stoltenhoff
Klaus Gorris
Original Assignee
Praxair S.T. Technology, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Praxair S.T. Technology, Inc. filed Critical Praxair S.T. Technology, Inc.
Priority to CA002626427A priority Critical patent/CA2626427A1/en
Priority to JP2008535879A priority patent/JP2009511751A/ja
Priority to BRPI0617642-9A priority patent/BRPI0617642A2/pt
Priority to US12/089,648 priority patent/US20080254227A1/en
Priority to EP06805414.7A priority patent/EP1943369B1/de
Priority to DE112006003449T priority patent/DE112006003449A5/de
Publication of WO2007045217A1 publication Critical patent/WO2007045217A1/de
Priority to NO20082261A priority patent/NO20082261L/no

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/322—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer only coatings of metal elements only
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/32—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer
    • C23C28/324—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one pure metallic layer with at least one metal matrix material layer comprising a mixture of at least two metals or metal phases or a metal-matrix material with hard embedded particles, e.g. WC-Me
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/345—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer
    • C23C28/3455—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with at least one oxide layer with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
    • C23C28/30—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer
    • C23C28/34—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates
    • C23C28/347—Coatings combining at least one metallic layer and at least one inorganic non-metallic layer including at least one inorganic non-metallic material layer, e.g. metal carbide, nitride, boride, silicide layer and their mixtures, enamels, phosphates and sulphates with layers adapted for cutting tools or wear applications
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying

Definitions

  • the invention relates to the production of functional surfaces on fiber-reinforced composite materials using thermal and kinetic spraying, wherein the protection of the component surface against wear, mechanical damage, covering and adhesion, and the improvement in terms of sheet delivery (release behavior) is given a special significance.
  • Fiber reinforced composites can be used to manufacture components having exceptional mechanical and physical properties, e.g. have a low density, a high tensile and torsional strength, and a high elastic modulus or a high stiffness.
  • a variety of high strength fiber materials can be used, including carbon fibers, glass fibers, silicon carbide fibers, and many other oxides, carbides, and other materials.
  • a wide variety of polymeric materials including thermosetting resins, e.g. Phenolic resins, epoxy resins and many other materials.
  • the fibers can be very long and arranged in specific patterns, or they can be relatively short and random.
  • long fibers When arranged in specific patterns, long fibers may be oriented in a single direction or arranged in patterns designed to give the fiber reinforced composite a two- or three-dimensional strength.
  • the mechanical properties of the structure of the fiber reinforced composite material can be tailored to the specific requirements of a component.
  • the surfaces of fiber reinforced composites have low wear resistance, especially to adhesive, abrasive, and erosive wear, and their adhesion and wetting properties are inadequate for many applications, such as in the paper industry.
  • they are often susceptible to oxidation or other forms of corrosion, require heat protection, lack the necessary optical and electrical characteristics, and the like.
  • the insert is fiber reinforced Composite materials in many applications limits or requires the use of metallic or ceramic inserts or coatings in those areas that are exposed to contact with other components or fabrics and thus to increased wear.
  • the use of fiber reinforced composite rolls in the printing, paper and film industries is particularly interesting because they are much lighter and stiffer, and therefore easier and safer to handle than, for example, steel rolls, and thus less energy due to their lower inertia and time for their acceleration and deceleration, allowing for cost savings not only in handling and assembly but also in operation.
  • the rolls in this case have a metallic, ceramic or carbide coating or mixtures thereof with plastics, which provides the required wear resistance and other necessary properties.
  • thermal spray techniques a wide variety of metallic and ceramic layers, cermet layers, i. Carbide particles embedded in a metallic matrix, and some polymer coatings are produced.
  • the family of thermal spraying techniques includes detonation spraying (including Super D-Gun TM), high velocity flame spraying and its variants, e.g. spraying with air-fuel, plasma spraying, flame spraying and electric wire arc spraying.
  • detonation spraying including Super D-Gun TM
  • high velocity flame spraying e.g. spraying with air-fuel, plasma spraying, flame spraying and electric wire arc spraying.
  • the spray material is heated in the form of powder, wire, or rods to a temperature which is at or slightly above its melting point, and droplets or fused particles of the material are accelerated in a gas stream.
  • the droplets are directed against the surface of the substrate to be coated (the portion or component) where they adhere, solidify and form a continuous layer of lamellar structure.
  • the discontinuous detonation spray process the layer of individual overlapping, firmly joined spray marks is formed.
  • Such methods are known in the art and described in detail in numerous publications.
  • EP 0 514 640 B1 An alternative method is shown in EP 0 514 640 B1.
  • a layer is first formed on the surface of a fiber reinforced composite material, which consists of a mixture of a synthetic resin and dispersed therein metallic particles.
  • the surface is mechanically processed to expose the dispersed particles to chemically bond the particulate material to an outer layer material that is thermally sprayed onto the first layer.
  • the mixture of synthetic resin and particulate material can not adhere well to the composite and tends to form globules of material on the surface, rendering it unsuitable for commercial production.
  • a primer is applied to a plastic surface by means of a thermal spraying process, which can be, in particular, zinc, zinc alloys, aluminum alloys and / or exothermically reacting materials in the injection process, such as nickel-aluminum alloys. Subsequently, a functional coating likewise produced by means of a thermal spraying process is applied to the primer.
  • a thermal spraying process which can be, in particular, zinc, zinc alloys, aluminum alloys and / or exothermically reacting materials in the injection process, such as nickel-aluminum alloys.
  • EP 1 129 787 B1 describes a coating method in which a base body made of fiber-reinforced composite material is coated with a first layer which contains only polymer, a second layer made of a polymer / metal mixture and then a thermal spray coating. To one To achieve sufficient bond strength between the layers, suitable polymer materials must be selected for the first two coating layers.
  • the present invention is concerned in particular with the task, by combining two or more thermally or kinetically. sprayed coating systems to improve the wear resistance of fiber-reinforced plastics.
  • a thermally sprayed layer of a composite consisting of organic and metallic components is applied as an adhesive layer; on the adhesive layer, a thermally or kinetically sprayed layer with predominantly metallic portions is applied as an intermediate layer; and to the intermediate layer a thermally or kinetically sprayed functional metal cover layer, CERMET (metal-carbide composite), oxide ceramics or mixtures of the aforementioned materials, or mixtures thereof with plastic is applied.
  • CERMET metal-carbide composite
  • oxide ceramics or mixtures of the aforementioned materials, or mixtures thereof with plastic is applied.
  • the wire or powder spray material itself may consist of the composite material.
  • the purpose of the so-called adhesive layer is to create a better connection to the matrix of the fiber-reinforced base material by the plastic component, and at the same time to ensure a better wetting of exposed fibers, which likewise has a favorable effect on the layer adhesion.
  • the metallic components of the adhesive layer have the purpose of allowing a connection of the subsequently applied metallic intermediate layer.
  • This intermediate layer is essential for the final application of the functional topcoat. It serves as a stable substrate of the usually brittle, wear-resistant cover layer and at the same time brings about a moderate adaptation of the moduli of elasticity of the adhesive layer and cover layer.
  • the metallic intermediate layer ensures uniform distribution and removal of the introduced heat. Without adequate heat dissipation, it can lead to a locally occurring evaporation of the organic binder of the body come, which in turn would result in a replacement of the entire shift system.
  • the method proposed here makes it possible to produce coated components from fiber-reinforced composite materials which are also suitable for strong dynamic loads and components with a large layer area.
  • the proportion of the organic matrix in the adhesion layer e.g. Polyester, between 5 and 60%, more preferably between 20 and 50%, and most preferably between 30 and 40%.
  • the metallic portion of the adhesive layer e.g. Aluminum, copper or nickel is preferably between 40 and 90%, more preferably between 60 and 80%.
  • the thickness of the adhesive layer is preferably 0.1 to 2 mm, more preferably 0.1 to 1 mm, and particularly preferably 0.2 to 0.4 mm.
  • a 0.2 mm thick adhesive layer is applied by plasma spraying and consists of a metal-polyester composite.
  • an approximately 0.1 to 1 mm thick metallic layer is sprayed onto the adhesive layer by a thermal spraying process.
  • the thickness of the intermediate layer is 0.5 to 2 mm.
  • the intermediate layer can be processed before the application of the cover layer, for example by grinding or turning to compensate for unevenness from previous operations.
  • the metallic intermediate layer is applied by a combustion-free method, such as arc spraying, plasma spraying or kinetic spraying, in order to keep the heat input into the base material made of fiber-reinforced plastic as small as possible.
  • the intermediate layer already consists of a metal-hard material composite, for example a kinetically sprayed aluminum-aluminum oxide composite layer, in order to increase the strength.
  • the functional cover layer of the layer system preferably consists of an oxide ceramic (eg chromium oxide) or a CERMET (metal-carbide composite, eg tungsten carbide embedded in a metallic cobalt matrix).

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Ceramic Engineering (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
PCT/DE2006/001797 2005-10-19 2006-10-12 Verfahren zur beschichtung eines bauteils WO2007045217A1 (de)

Priority Applications (7)

Application Number Priority Date Filing Date Title
CA002626427A CA2626427A1 (en) 2005-10-19 2006-10-12 Method for coating a component
JP2008535879A JP2009511751A (ja) 2005-10-19 2006-10-12 部材のコーティング法
BRPI0617642-9A BRPI0617642A2 (pt) 2005-10-19 2006-10-12 processo para revestir um componente de material compósito reforçado com fibra
US12/089,648 US20080254227A1 (en) 2005-10-19 2006-10-12 Method for Coating a Component
EP06805414.7A EP1943369B1 (de) 2005-10-19 2006-10-12 Verfahren zur beschichtung eines bauteils
DE112006003449T DE112006003449A5 (de) 2005-10-19 2006-10-12 Verfahren zur Beschichtung eines Bauteils
NO20082261A NO20082261L (no) 2005-10-19 2008-05-16 Fremgangsmate for belegging av en komponent

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102005050045.5 2005-10-19
DE102005050045A DE102005050045B3 (de) 2005-10-19 2005-10-19 Verfahren zur Beschichtung eines Bauteils

Publications (1)

Publication Number Publication Date
WO2007045217A1 true WO2007045217A1 (de) 2007-04-26

Family

ID=37545323

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE2006/001797 WO2007045217A1 (de) 2005-10-19 2006-10-12 Verfahren zur beschichtung eines bauteils

Country Status (10)

Country Link
US (1) US20080254227A1 (no)
EP (1) EP1943369B1 (no)
JP (1) JP2009511751A (no)
BR (1) BRPI0617642A2 (no)
CA (1) CA2626427A1 (no)
DE (2) DE102005050045B3 (no)
NO (1) NO20082261L (no)
RU (1) RU2423543C2 (no)
WO (1) WO2007045217A1 (no)
ZA (1) ZA200803947B (no)

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US20100239883A1 (en) * 2009-02-11 2010-09-23 Greene, Tweed Of Delaware, Inc. High Performance Thermal Spray Coated Polymer Substrates and Related Methods of Manufacture
WO2011057614A1 (de) * 2009-11-12 2011-05-19 Mtu Aero Engines Gmbh Beschichten von kunststoffbauteilen mittels kinetischen kaltgasspritzens
WO2021191264A1 (en) 2020-03-25 2021-09-30 Basf Se Molded article providing an electromagnetic shielding

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DE102005050045B3 (de) * 2005-10-19 2007-01-04 Praxair Surface Technologies Gmbh Verfahren zur Beschichtung eines Bauteils
DE102007004531A1 (de) * 2007-01-24 2008-07-31 Eads Deutschland Gmbh Faserverbundwerkstoff mit metallischer Matrix und Verfahren zu seiner Herstellung
GB0807261D0 (en) * 2008-04-21 2008-05-28 Accentus Plc An article and a method of making an article
DE102008001468B4 (de) * 2008-04-30 2013-09-19 Airbus Operations Gmbh Verfahren zum Beschichten eines Faserverbundbauteils für ein Luft- oder Raumfahrzeug und durch ein derartiges Verfahren hergestelltes Faserverbundbauteil
EP2337044A1 (fr) * 2009-12-18 2011-06-22 Metalor Technologies International S.A. Procédés de fabrication d'un plot de contact électrique et d'un contact électrique
DE102012108463A1 (de) * 2012-09-11 2014-03-13 Schmid Vacuum Technology Gmbh Folienbeschichtungsanlage und Umlenkwalze hierfür
JPWO2014115251A1 (ja) * 2013-01-23 2017-01-19 株式会社日立製作所 金属被覆樹脂構造体とその製法
FR3008109B1 (fr) * 2013-07-03 2016-12-09 Snecma Procede de preparation a la depose d'un revetement metallique par projection thermique sur un substrat
DE202014000329U1 (de) 2014-01-17 2014-03-12 Balluff Gmbh Beschichtetes Sensor- oder RFlD-Gehäuse
US10064303B2 (en) 2014-05-20 2018-08-28 The Boeing Company Integrated wiring system for composite structures
JP6506926B2 (ja) * 2014-08-08 2019-04-24 ホウムラ産業株式会社 三次元造形物
RU2691356C1 (ru) * 2018-08-09 2019-06-11 Туманов Александр Викторович Способ нанесения антифрикционного слоя на металлическую деталь
JP6730407B2 (ja) 2018-11-16 2020-07-29 三菱重工業株式会社 風車翼およびその製造方法
CN110404751B (zh) * 2019-07-22 2021-12-24 中国航发北京航空材料研究院 一种在树脂基复合材料表面形成抗烧蚀涂层的方法
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CA2626427A1 (en) 2007-04-26
RU2008119486A (ru) 2009-11-27
EP1943369B1 (de) 2013-05-01
RU2423543C2 (ru) 2011-07-10
DE102005050045B3 (de) 2007-01-04
US20080254227A1 (en) 2008-10-16
NO20082261L (no) 2008-05-16
BRPI0617642A2 (pt) 2013-01-01
DE112006003449A5 (de) 2008-09-25
ZA200803947B (en) 2009-09-30
JP2009511751A (ja) 2009-03-19

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