WO2007032435A1 - Composition détergente liquide pour vêtements - Google Patents

Composition détergente liquide pour vêtements Download PDF

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Publication number
WO2007032435A1
WO2007032435A1 PCT/JP2006/318260 JP2006318260W WO2007032435A1 WO 2007032435 A1 WO2007032435 A1 WO 2007032435A1 JP 2006318260 W JP2006318260 W JP 2006318260W WO 2007032435 A1 WO2007032435 A1 WO 2007032435A1
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WIPO (PCT)
Prior art keywords
group
component
acid
carbon atoms
liquid detergent
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PCT/JP2006/318260
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English (en)
Japanese (ja)
Inventor
Izumi Onuki
Toshihiko Tachikawa
Megumu Ono
Takahiro Okamoto
Tetsuya Katagi
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Lion Corporation
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Application filed by Lion Corporation filed Critical Lion Corporation
Priority to KR1020087004046A priority Critical patent/KR101240698B1/ko
Publication of WO2007032435A1 publication Critical patent/WO2007032435A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/34—Organic compounds containing sulfur
    • C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/08—Liquid soap, e.g. for dispensers; capsuled
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/42—Amino alcohols or amino ethers
    • C11D1/44—Ethers of polyoxyalkylenes with amino alcohols; Condensation products of epoxyalkanes with amines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds

Definitions

  • the present invention relates to a liquid detergent composition for clothing.
  • Patent Documents 1 and 2 mainly include one or more surfactants selected from amine oxides and amphoteric surfactants for the purpose of cleaning dark stains.
  • An acidic laundry pretreatment composition and an acidic coating detergent composition, which are various components, are disclosed.
  • Patent Document 3 is intended for cleaning dark stains, and includes one or more surfactants selected from amine oxides and amphoteric surfactants, and organic acids and inorganic acids of pKa2.0 to 6.8.
  • a laundry pre-treatment composition containing the same is disclosed.
  • Patent Document 4 describes a liquid detergent composition for clothing containing a specific amphoteric surfactant and a nonionic surfactant.
  • Patent Document 5 describes a pretreatment agent for mud soil comprising an acidic composition containing a compound having a phosphonic acid group! Speak.
  • Patent Document 6 discloses a cleaning composition combining a plurality of types of specific surfactants for the purpose of cleaning stubborn dirt! Speak.
  • Patent Document 7 discloses a liquid detergent composition for clothing that uses a specific non-ionic surfactant for the purpose of satisfying both a texture and a detergency with a squeaky feeling! Speak.
  • a polyoxyethylene alkyl ether having an alkyl group of 10 to 20 carbon atoms and an average added mole number of ethylene oxide of 8 to 26 hereinafter, this component is referred to as “specific nonionic surfactant”.
  • Patent Document 1 Japanese Patent Laid-Open No. 2000-109889
  • Patent Document 2 JP 2000-109893 A
  • Patent Document 3 Japanese Unexamined Patent Publication No. 2000-109890
  • Patent Document 4 Japanese Patent Laid-Open No. 08 157870
  • Patent Document 5 Japanese Patent Laid-Open No. 3-26797
  • Patent Document 6 Japanese Patent No. 3556806
  • Patent Document 7 Japanese Patent No. 2813112
  • Patent Document 8 Japanese Patent Laid-Open No. 2004-210961
  • composition described in Patent Document 3 may not have a sufficient mud dirt cleaning effect.
  • an object of the present invention is to provide a liquid detergent composition for clothing having good detergency against mud dirt and sebum dirt.
  • polyoxyethylene alkyl ethers from 2 to 50 mass carbon number of the hydrophobic groups is the average number of added moles force ⁇ to 26 Echirenokishido at 10 ⁇ 20 0/0;
  • B The following general formula (I):
  • X, Y and ⁇ are each independently a hydrogen atom, C ⁇ ⁇ or (CH) CH (where ⁇ is ⁇ 2 ⁇ + 1 3 2
  • ⁇ represents a hydrogen atom, an alkaline metal atom, an alkaline earth metal atom, ⁇ 4+, or an anoreno-norenoamine
  • R 12 are each independently a linear or branched alkyl group or a alkenyl group having 1 to 20 carbon atoms, a linear hydroxyalkyl group, a tolyl group, a phenyl group, a benzyl group
  • R 13 represents any one of a linear or branched alkyl group or a alkenyl group having 8 to 20 carbon atoms, a linear hydroxyalkyl group, a tolyl group, a phenyl group, or a benzyl group.
  • EO represents an ethylene oxide group
  • a and b are each 0 or more
  • a + b is 10 or more, and (in other words, represents an anion).
  • a liquid detergent composition for clothing comprising: at least one selected compound; and (D) l-hydroxyethane-1,1-diphosphonic acid or a salt thereof.
  • the liquid detergent composition for clothing can further contain (E) monoethanolamine.
  • a liquid detergent composition for clothing having good detergency against mud dirt can be provided.
  • (A) component is a polyoxyethylene alkyl ether from 2 to 50 mass 0/0 of the average Tsukeka ⁇ mole number 3-26 of Echirenokishido is at 10 to 20 carbon atoms in the hydrophobic groups (alkyl group).
  • the lower limit of the number of carbon atoms in the alkyl group is preferably 11 or more, more preferably 12 or more, and the upper limit is preferably 18 or less, particularly 15 or less, from the viewpoint of mud dirt cleaning power.
  • the average number of added moles of ethylene oxide is preferably 5 or more, more preferably 8 or more, and the upper limit is preferably 20 or less in 1 mol of component (A). More preferably, it is 18 or less.
  • Component (A) is a non-ionic surfactant, which can be obtained by addition reaction of ethylene oxide with a higher alcohol by a conventional method using an alkali catalyst or the like, or using a commercially available product. I'll do it.
  • higher alcohols examples include linear primary alcohols, branched primary alcohols, linear secondary alcohols, and the like.
  • the component (A) can be used alone or in combination of two or more.
  • the amount of component (A) is 2 to 50% by mass in the liquid detergent composition for clothing. Preferably rather it is 10 to 50 mass%, more preferably from 15 to 45 weight 0/0, particularly preferably in the range of 20 to 40 wt%.
  • Ingredient strength of component If it is within this range, the detergency of mud dirt is improved. In addition, the detergency of the sebum stain and the liquid stability (characteristics that do not cause gelling or the like and can maintain a stable state) are improved.
  • Component (B) is a compound represented by general formula (I).
  • X, ⁇ and Z are each independently H, C H or (CH) CH (where n is 1 to
  • M represents a hydrogen atom; an alkali metal atom such as sodium or potassium; an alkaline earth metal atom such as magnesium or calcium; NH 4+ ; or an alkanolamine such as monoethanolamine, diethanolamine or triethanolamine. Of these, sodium, monotamine, and diethanolamine are preferable.
  • the compound include benzene sulfonic acid, sodium benzene sulfonate, potassium benzene sulfonate, ammonium benzene sulfonate, magnesium benzene sulfonate, calcium benzene sulfonate, benzene Sulfonic acid monoethanolamine salt, benzenesulfonic acid diethanolamine salt, benzenesulfonic acid triethanolamine salt, p toluenesulfonic acid, p toluenesulfonic acid sodium salt, p toluenesulfonic acid potassium salt, p-toluenesulfonic acid ammonium Salt, magnesium p-toluenesulfonate, calcium p-toluenesulfonate, monoethanolamine p-toluenesulfonate, diethanolamine p-toluenesulfonate, triethanolamine p
  • Component (B) may be used alone or in combination of two or more.
  • the blending amount of component (B) is preferably 1 to 15% by mass, more preferably 3 to 10% by mass, and particularly preferably 3 to 6% by mass in the liquid detergent composition for clothing. It is a range. When the component (B) is within this range, the detergency of mud dirt is improved. Further, it is preferable because of excellent storage stability.
  • Component (C) is a semipolar surfactant, amphoteric surfactant, general formula ( ⁇ ): And the general formula ( ⁇ ): '(E0) a H
  • (E0) b group is a group force that also has a compound power represented by at least one compound selected.
  • Examples of the semipolar surfactant include amine oxide surfactants represented by the following general formula (IV).
  • R 1 is a linear or branched alkyl group or a alkenyl group having 8 to 18, preferably 8 to 16, and more preferably 10 to 14 carbon atoms; 2 and R 3 are each independently an alkyl or hydroxyalkyl group having 1 to 3 carbon atoms, R 4 is an alkyl group having 1 to 4 carbon atoms, and A is —CO—NH—, —NHCO— , —COO—, —OCO—, or —O—power is also a group selected, and n ′ is 0 or 1.
  • alkyldimethylamine oxide examples include alkyldimethylamine oxide, alkylamidopropyldimethylaminooxide, and the like, and preferably n-dodecyldimethylamine, where alkyldimethylamine oxide is desirable for the detergency of the detergency. Oxide is preferred. n-dodecyldimethylamine oxide is commercially available, for example, from Lionaxo Corporation.
  • amphoteric surfactants include N-alkyl or alkyl amino acids or salts thereof, and betaines.
  • N-alkyl or alkylamino acid has an alkyl group or an alkyl group bonded to a nitrogen atom, and one or two “one R—COOH” (where R is a divalent hydrocarbon). Group, preferably an alkylene group, particularly preferably having 1 to 2 carbon atoms). “One R—a compound with one COOHJ bonded! /, In which a hydrogen atom is bonded to a nitrogen atom.
  • the alkyl group and the alkenyl group preferably have 10 to 20 carbon atoms, and these may be linear or branched.
  • the salt is preferably a sodium salt that is preferably an alkali metal salt such as sodium or potassium.
  • Preferable examples include alkyl or alk-laminopropionic acid or a salt thereof, and laurylaminopropionic acid or a sodium salt thereof is more preferable.
  • Examples of commercially available products include Naurylaminopropionic acid Na (manufactured by Hokata Oil and Fat Co., Ltd.). This is a 90% by weight: 10% by weight mixture of mono and di.
  • betaines include alkyl betaines, carbobetaines, amide betaines, sulfobetaines, amide sulfobetaines, imidazole betaines, phosphobetaines, and the like. Specific examples include amidepropyl betaine laurate. Examples include fatty acid amidopropyl betaine, 2-alkyl N carboxymethyl N hydroxyethyl imidazolium betaine, alkyldimethylaminoacetic acid betaine, alkylhydroxysulfobetaine, and alkyldimethylbedine such as lauryldimethylbedine.
  • amidopropyl betaine laurate (trade name “Softazoline LPB”; manufactured by Kawaken Fine Chemicals Co., Ltd.), lauryl dimethyl betaine (trade name “Amphitol 24B”; manufactured by Kao Co., Ltd.), and the like. .
  • alkylbedine alkylbedine, amidebedine, and sulfobedine are preferred.
  • Amidopropylbetaine and lauryldimethylbetaine are particularly preferred.
  • amphoteric surfactants N-alkyl or alkaryl amino acids or salts thereof, alkylbedines, amidebedines, and sulfobedines are particularly preferable.
  • R 11 and R 12 are each independently a linear or branched alkyl or alkyl group having 1 to 20 carbon atoms, a long-chain hydroxyalkyl group, a tolyl group, Hue It represents either a nyl group or a benzyl group.
  • the number of carbon atoms of the alkyl group is more preferably 10-18.
  • the carbon number of the alkenyl group is particularly preferably 10-18.
  • the alkyl group preferably has 10 to 20 carbon atoms, particularly 10 to 18 carbon atoms.
  • the number of hydroxy groups is, for example, 1 to 3, and preferably 1.
  • one of R 1 and R 12 is a combination of a straight-chain or branched alkyl group or alkyl group having 10 to 18 carbon atoms, the other is a acetyl group, a tolyl group or a benzyl group.
  • EO represents an ethylene oxide group.
  • a and b each independently represent an average number of moles of addition of the ethylene oxide group, and each independently represents 0 or more.
  • a + b is 10 mol or more, preferably 10 to 50 mol.
  • a + b is 10 mol or more, the effect of dispersing organic substances in the mud is improved, and the detergency against mud dirt is improved.
  • X— is an anion, such as a halogen atom ion such as chlorine ion, bromine ion, iodine ion, or the general formula R 5 SO— (where R 5 is an alkyl group having 1 to 3 carbon atoms (methyl group, Yetil
  • R 13 represents a linear or branched alkyl group or a alkenyl group having 8 to 20 carbon atoms, a long-chain hydroxyalkyl group, a tolyl group, a phenol. Group or benzyl group.
  • the number of carbon atoms of the alkyl group is more preferably 10-18.
  • the carbon number of the alkenyl group is particularly preferably 10-18.
  • the alkyl group preferably has 10 to 20 carbon atoms, particularly 10 to 18 carbon atoms.
  • the number of hydroxy groups is, for example, 1 to 3, and preferably one.
  • R 13 is particularly preferably a linear or branched alkyl group or a alkenyl group having 10 to 18 carbon atoms.
  • EO represents an ethylene oxide group.
  • a and b are the average number of moles of ethylene oxide groups, and each independently represents 0 or more.
  • a + b is 10 mol or more, preferably 10 to 50 mol. When a + b is 10 or more, the effect of dispersing organic substances in the mud is improved, and the detergency against mud dirt is improved.
  • the component (C) can be used alone or in combination.
  • the content of the component (C) is preferably 0.5 to 10% by mass, more preferably 0.5 to 5% by mass in the liquid detergent composition for clothing, from the viewpoint of improving the detergency of mud soil. . In this range, the detergency against sebum dirt is also improved.
  • the amount By setting the amount to 10% by mass or less, the rinsing time is shortened, and preparation becomes easier, which is more preferable.
  • Component (D) is 1-hydroxyethane-1,1-diphosphonic acid and Z or a salt thereof.
  • the salt include alkali metal salts such as sodium salt and potassium salt, and alkanolamine salts such as monoethanolamine salt and diethanolamine salt.
  • Component (D) can be used alone or in combination.
  • the content of the component (D) is, from the viewpoint of mud dirt cleaning power, in the liquid detergent composition for clothing, Preferably it is 0.1-10 mass%, More preferably, it is 0.1-5 mass%.
  • the content is 0.1% by mass or more, the detergency of mud soil is improved, and when the content is 10% by mass or less, the component (D) can be blended more stably. It is also preferable in terms of improving the detergency of sebum dirt.
  • Component (E) is monoethanolamine.
  • the blending amount of monoethanolamine is 0.1 to 20% by mass, preferably 0.5 to 8% by mass, more preferably 1 to 5% by mass in the liquid detergent composition for clothing.
  • the sebum dirt and mud dirt cleaning power is improved.
  • Examples of monoethanolamine are commercially available from Nippon Shokubai Co., Ltd. and Mitsui Chemicals.
  • a non-ionic surfactant or a cationic surfactant other than the component (A) can be blended.
  • the non-ionic surfactant has an alkyl group having 8 to 18 carbon atoms, an alkyl polydarcoside having an average number of moles of 1 to 10 glucose glucose, and an alkyl group having 8 to 18 carbon atoms.
  • the glycerin unit has an average number of moles of alkyl glyceryl ether having 1 to 3 carbon atoms, a fatty acid diethanolamide having 10 to 20 carbon atoms, an alkyl group having 10 to 18 carbon atoms, and an average mole number of ethylene oxide. Examples thereof include methoxypolyoxyethylene alkanoates having a number of 1 to 30.
  • the amount of the nonionic surfactant other than the component (A) is preferably in the range of 0 to 10% by mass in the liquid detergent composition for clothing.
  • Examples of the ionic surfactant include alkylbenzene sulfonates having an alkyl group having 8 to 16 carbon atoms, alkyl sulfates having an alkyl group having 10 to 20 carbon atoms, and alkyl having 10 to 20 carbon atoms.
  • Polyoxyethylene having an average number of moles of ethylene oxide of 1 to 10 Ethylene alkyl ether sulfate, a-olefin sulfonate having an alkyl group having 10 to 20 carbon atoms, alkane sulfonate having an alkyl group having 10 to 20 carbon atoms, ⁇ - having an alkyl group having 10 to 20 carbon atoms
  • Examples thereof include sulfo fatty acid methyl ester salts, polyoxyethylene alkyl ether carboxylates having an alkyl group having 10 to 20 carbon atoms and an average number of moles of ethylene oxide of 1 to 10.
  • the amount of these key-on surfactants is preferably in the range of 0 to 10% by mass in the liquid detergent composition for clothing.
  • liquid cleaning composition for clothing of the present invention may contain other optional components as necessary.
  • examples of the hydrotrope include glycol solvents such as ethylene glycol, propylene glycol, polyethylene glycol, and polypropylene glycol, and alcohols such as ethanol.
  • glycol solvents such as ethylene glycol, propylene glycol, polyethylene glycol, and polypropylene glycol
  • alcohols such as ethanol.
  • polyethylene glycol and ethanol having a mass average molecular weight of 400 to 5000 are preferable.
  • alkali agent examples include alkanolamine.
  • alkanolamine examples include monoethanolamine, diethanolamine, triethanolamine and the like, and the alkanolamine may be used alone or in combination of two or more.
  • the blending amount of these hydrotropes and alkaline agents is preferably 0.1 to L0 mass%, more preferably 1 to 5 mass% in the liquid detergent composition for clothing.
  • the liquid cleaning composition for clothing may contain 0 to 1% by mass of a fatty acid having 8 to 22 carbon atoms as a foam suppressant.
  • Fatty acids having a carbon number in the range of 8 to 22 are preferably saturated fatty acids such as cabrylic acid, strong puric acid, lauric acid, myristic acid, palmitic acid and stearic acid, or oleic acid and linoleic acid. Any of unsaturated fatty acids such as linolenic acid may be used. Of these, palmitic acid is most preferred.
  • a recontamination inhibitor such as polybulurpyrrolidone and carboxymethylcellulose
  • enzymes such as lipase, cellulase, amylase and protease are used.
  • fragrance for aroma examples include a fragrance composition containing a fragrance component, a solvent and a stabilizer described in JP-A-2002-146399, and the liquid detergent composition for clothing of the present invention. In the product, 0.01 to 1 mass% can be blended.
  • inorganic acids and inorganic bases such as sulfuric acid, sodium hydroxide, potassium hydroxide and the like can be blended. From the viewpoint of maintaining detergency after storage, 7.0 to 11.0 is preferable, and 9.0 to 10.5 is more preferable.
  • the amount of component (E) can be set so that the pH falls within this range.
  • the liquid detergent composition for clothing of the present invention can be prepared based on a conventional method, preferably using water as a solvent.
  • the usage method is a normal usage method, that is, a method of pouring water together with the laundry at the time of washing, a method of directly applying the liquid cleaning composition for clothing to mud and sebum soil, and a liquid cleaning composition for clothing to water.
  • a method of immersing clothing by dissolving it in Also preferred is a method in which the liquid cleaning composition for clothing is applied to the laundry and then allowed to stand as appropriate, followed by normal washing using a laundry liquid containing a cation surfactant.
  • liquid detergent composition for clothing having good detergency against mud dirt can be provided.
  • the liquid detergent composition for clothing of the present invention exhibits a high detergency even against sebum dirt.
  • a liquid detergent composition for clothing having the composition shown in the table was prepared as follows.
  • the unit of the blending amount in the table is mass%, and the amount of water was adjusted so that the total amount would be 100 mass%. Cooled to below 40 ° C. All subsequent steps were performed between room temperature and 40 ° C. Thereafter, the component (B) and the component (E) or diethanolamine were added and stirred. Thereafter, 90% of the mass of purified water (norrance) was added, and a fragrance was added and stirred. Furthermore, after adding (C) component, (D) component, other arbitrary components, and the pigment
  • the pH was adjusted by adding a pH adjuster (sodium hydroxide or sulfuric acid) so that the pH at 25 ° C of the adjusted liquid detergent composition for clothing would be the value shown in the table. . And it evaluated by the following method and evaluation criteria, and the result was shown according to the table.
  • a pH adjuster sodium hydroxide or sulfuric acid
  • dehydration was performed at a temperature of 100 ° C and a pressure of 2. OkPa or less for 30 minutes, and then the temperature was raised to 160 ° C. While stirring the alcohol, 763.6 g of ethylene oxide (gaseous) was gradually added to the alcohol liquid while adjusting the addition rate so that the reaction temperature did not exceed 180 ° C using a blowing tube.
  • Branching rate indicates the ratio of the number of carbon atoms constituting the branched chain to the total number of carbon atoms.
  • A-4 C H O (EO) H (Branched chain content, Dyadol 13, branching rate "50%) (Mitsubishi
  • A-5 C H O (EO) H (C chain length, branched type), (BASF, product name: Lutenzol TO
  • B-l p-toluenesulfonic acid: manufactured by Kyowa Hakko Kogyo Co., Ltd.
  • E-1 Monoethanolamine: manufactured by Nippon Shokubai Co., Ltd.
  • Diethanolamine Made by Nippon Shokubai Co., Ltd.
  • Palmitic acid manufactured by Nippon Oil & Fats Co., Ltd.
  • Polyethylene glycol PEG # 1000 (mass average molecular weight 1000) Perfume composition manufactured by Nippon Oil & Fats Co., Ltd .: Perfume compositions A to D described in Tables 11 to 18 described in JP-A-2002-146399
  • Dye A Green 201, manufactured by Hagi Kasei Co., Ltd.
  • Dye B Yellow 201, manufactured by Hagi Kasei Co., Ltd.
  • Dye C Green No. 3, manufactured by Hagi Kasei Co., Ltd.
  • Dye D Kirin Yellow—WG—G CONC, manufactured by Chuo Synthetic Chemical Co., Ltd.
  • Horticultural black soil (kyotochiya) 15g was weighed and put into 500g of tap water, and dispersed for 5 minutes at 8 Orpm with homogenizer 1 (trade name Polytron Type PT 10/35) manufactured by KINEMATICA ⁇ Iss. I let you.
  • homogenizer 1 trade name Polytron Type PT 10/35 manufactured by KINEMATICA ⁇ Iss. I let you.
  • 15 pieces of cotton knitted fabric cut into 10cm x 25cm (dyeing material made by Tanigami Shoten Co., Ltd., unstained cotton knit) is immersed, and the cloth is thoroughly rubbed by hand.
  • the mud dispersion was uniformly contained throughout.
  • the cloth was taken out and lightly squeezed with a roller. After naturally drying for 1 hour, it was further dried for 1 hour in a thermostatic bath at 105 ° C. Finally, the surface of the cloth was rubbed with a urethane sponge, and excess mud particles were removed as a model mud soil cloth for
  • the following method was applied as the cleaning method.
  • Terg-O-Tomete r cleaning test machine 25 ° C tap water (hardness 3DH) 0.9L was added and stirred for 10 minutes at 120rpm, then transferred to a two-tank washing machine (Mitsubishi Electric Corp., product number: CW—C30A1—HI) and dehydrated for 1 minute. did. Thereafter, it was rinsed with running water
  • the Z value was measured using a colorimetric color difference meter (manufactured by Nippon Denshoku Co., Ltd .: trade name SE2000) and evaluated as a cleaning rate of the following formula. The average value of 10 sheets was used for each evaluation.
  • Cleaning rate (%) (Z value after cleaning—z value before cleaning) Z (z value of raw fabric—Z value before cleaning) X 10
  • the mud dirt cleaning power was evaluated according to the following criteria.
  • Component (D) D-1 0.5 0.5 0.5 0.5 0.5 1.0 0.5
  • Component (D) D-1 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5
  • Fragrance composition A B C D Fragrance content 0.2 0.2 0.1 0.2 Dye A 0.0006 0.0006 0.0006 Dye B 0.0001 0.0001 0.0001 Dye! 0.0002 Sodium hydroxide
  • A-1 30 30 30 30 1 A-1 30 30 30 1
  • Component (D) D-1 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 distribution
  • Fragrance composition A B C A Fragrance content 0.2 0.2 0.1 0.2 Dye C 0.0002 0.0003 0.0006 0.0002 Purified water Balance balance balance pH 9.5 9.5 9.5 10.0 Sebum dirt cleaning power B B B A Mud dirt cleaning power C C C
  • Component (D) D-1 0.5 0.5 0.5 0.5 0.5 1 0.5

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  • Detergent Compositions (AREA)

Abstract

La présente invention concerne une composition détergente liquide pour vêtements caractérisée en ce qu’elle contient (A) un éther d’alkyle de polyoxyéthylène, (B) un composé représenté par la formule générale (I) ci-dessous, (C) un agent tensioactif semi-polaire, un agent tensioactif amphotère ou un composé représenté par la formule générale (II) ou (III) ci-dessous, et (D) l’acide 1-hydroxyéthane-1,1-diphosphonique ou un sel de celui-ci. (I) (Dans la formule (I), X, Y et Z représentent respectivement un atome d'hydrogène, CnH2n+1 ou (CH3)2CH (n étant un nombre entier de 1 à 3) ; et M représente un atome d'hydrogène, un atome de métal alcalin, un atome de métal alcalinoterreux, NH4+ ou une alcanolamine.) (II) (III) (Dans les formules (II) et (III), R11, R12 et R13 représentent respectivement un groupe alkyle, un groupe alcényle, un groupe hydroxyalkyle à chaîne linéaire, un groupe tolyle, un groupe phényle ou un groupe benzyle ; EO représente un groupe oxyde d'éthylène ; a et b représentent respectivement un nombre non inférieur à 0 et a + b n'est pas inférieur à 10 ; et X- représente un anion.)
PCT/JP2006/318260 2005-09-16 2006-09-14 Composition détergente liquide pour vêtements WO2007032435A1 (fr)

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JP2005-269972 2005-09-16
JP2005269972A JP4896475B2 (ja) 2005-09-16 2005-09-16 衣料用液体洗浄剤組成物

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JP4991199B2 (ja) * 2006-07-27 2012-08-01 ライオン株式会社 衣料用液体洗浄剤組成物
JP2009191128A (ja) * 2008-02-13 2009-08-27 Lion Corp 液体洗浄剤組成物
JP5520029B2 (ja) * 2009-12-15 2014-06-11 花王株式会社 液体洗浄剤組成物
JP7450428B2 (ja) * 2020-03-25 2024-03-15 花王株式会社 洗浄剤組成物の製造方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002517548A (ja) * 1998-05-29 2002-06-18 ザ、プロクター、エンド、ギャンブル、カンパニー 液状漂白剤組成物
JP2003147394A (ja) * 2001-11-15 2003-05-21 Kao Corp 衣料用漂白剤組成物
JP2005171195A (ja) * 2003-12-15 2005-06-30 Lion Corp 衣料用液体洗浄剤組成物

Family Cites Families (3)

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KR0121327B1 (ko) * 1990-01-03 1997-11-15 이원송 복합계면활성제 제조법
TW349994B (en) * 1996-12-02 1999-01-11 Kao Corp Surface activator composition
JP3751556B2 (ja) * 2001-11-15 2006-03-01 花王株式会社 衣料用洗浄剤組成物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002517548A (ja) * 1998-05-29 2002-06-18 ザ、プロクター、エンド、ギャンブル、カンパニー 液状漂白剤組成物
JP2003147394A (ja) * 2001-11-15 2003-05-21 Kao Corp 衣料用漂白剤組成物
JP2005171195A (ja) * 2003-12-15 2005-06-30 Lion Corp 衣料用液体洗浄剤組成物

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JP4896475B2 (ja) 2012-03-14
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JP2007077352A (ja) 2007-03-29

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