WO2006080389A1 - エステル化反応生成物及び化粧料 - Google Patents
エステル化反応生成物及び化粧料 Download PDFInfo
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- WO2006080389A1 WO2006080389A1 PCT/JP2006/301212 JP2006301212W WO2006080389A1 WO 2006080389 A1 WO2006080389 A1 WO 2006080389A1 JP 2006301212 W JP2006301212 W JP 2006301212W WO 2006080389 A1 WO2006080389 A1 WO 2006080389A1
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- reaction product
- esterification reaction
- mixture
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- 229940105125 zinc myristate Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
- C08G63/912—Polymers modified by chemical after-treatment derived from hydroxycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/85—Polyesters
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
- C07C69/33—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with hydroxy compounds having more than three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/67—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids
- C07C69/675—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of saturated acids of saturated hydroxy-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/46—Polyesters chemically modified by esterification
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
- A61Q1/06—Lipsticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/08—Preparations containing skin colorants, e.g. pigments for cheeks, e.g. rouge
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
- A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/12—Face or body powders for grooming, adorning or absorbing
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Definitions
- the present invention relates to an esterification reaction product.
- it relates to an ester wrinkle reaction product having high adhesion to skin and the like, excellent in water-resistant film-forming ability, pigment dispersibility, water retention, non-dyeing property and stability over time.
- this invention relates to the cosmetics containing the said esterification reaction product.
- Cosmetics have been conventionally used to impart an aesthetic appearance to skin and the like. In addition to providing an aesthetic appearance to the skin, cosmetics are used for the purpose of protecting the skin from drying by preventing the transpiration of moisture, and also providing a treatment effect to the skin. ing.
- natural oils such as lanolin and castor oil and synthetic ester oils having water repellency are often used as raw materials.
- the skin surface is coated with an oil film compared to oil-in-water cosmetics and has a high affinity for the skin, so it is used as a cosmetic with anti-drying and treatment effects. Often.
- Lanolin has been widely used as a natural oil. This lanolin is made from wool fat, has a good affinity for skin, adhesion, wettability, etc., and has excellent water-holding and emulsifying power. And many other cosmetics (see, for example, Non-Patent Document 1).
- ester compound described in Patent Documents 8 and 9 is an emulsifier, it does not have a film-forming function that an oil agent has.
- the amount used may be limited depending on the type of cosmetic.
- Patent Document 1 Japanese Patent Laid-Open No. 52- ⁇ 13
- Patent Document 3 Japanese Unexamined Patent Publication No. 55-57509
- Patent Document 4 JP 56-115740 A
- Patent Document 5 JP 56-108739 A
- Patent Document 7 Japanese Patent Laid-Open No. 05-331023
- Patent Document 9 JP 2000-290232 A
- Patent Document 6 Japanese Patent Application Laid-Open No. 64-90025
- Patent Document 8 JP 07-8781 A
- Non-Patent Document 1 Cosmetics Dictionary, Maruzen Co., Ltd. December 15, 2003
- an object of the present invention is to provide an esterification reaction product having high water-resistant film-forming ability, pigment dispersibility, water repellency, non-dyeing property, and stability over time, which has high adhesion to skin and the like. I'll stop.
- Another object of the present invention is to increase the amount of water (and polyhydric alcohols). It is also desirable to provide an esterification reaction product that can be used to produce cosmetics (oil-in-water emulsified cosmetics and water-in-oil emulsified cosmetics) having good water retention stability and stability over time.
- Another object of the present invention is to provide a cosmetic that has good adhesion to the skin and the like, and is excellent in water-resistant film-forming ability, pigment dispersibility, flexibility, moisture retention, water retention, non-dyeing property and stability. There is to be.
- Another object of the present invention is to provide a cosmetic composition that has excellent adhesion to skin, hair, etc., has a good emollient effect, and has an improved makeup.
- the present invention relates to an esterification reaction product obtained by esterifying dipentaerythritol and a 12-hydroxystearic acid polymer, and the esterification reaction product has a hydroxyl value. It provides an esterification reaction product having an acid value of 20 to 70 mgKOHZg and an acid value of 3 mgKOHZg or less.
- this invention provides the cosmetics formed by containing the said esterification reaction product.
- the present invention provides an esterification reaction product having high water retention and good dispersibility of pigments and the like.
- the esterification reaction product has a high water-holding property, and the differential scanning calorimetry was carried out by preparing a water-containing product having a mass ratio of the esterification reaction product to water of 7: 3. In this case, it can be confirmed that no endothermic peak of water is detected at a temperature around 0 ° C.
- the cosmetic of the present invention can embrace water-soluble polyhydric alcohols such as glycerin that is incompatible with water in the same manner as water, in addition to high water-holding properties.
- polyhydric alcohol means glycerin and its polymer, polyethylene glycol, propylene glycol, 1,3-butylene. It means glycols such as glycol, and sugars such as xylitol, sorbitol, maltitol.
- the product using the esterified koji reaction product of the present invention can embrace an aqueous solution in which inorganic salts, organic salts, water-soluble drugs, animal and plant extracts, etc. are dissolved in water to be held in the same manner as water. it can.
- inorganic salts include sodium chloride, sodium chloride, calcium chloride, magnesium chloride, sodium sulfate, magnesium sulfate, sodium carbonate, sodium bicarbonate, and sodium phosphate.
- Organic salts include sodium citrate, sodium malate, sodium dalconate, sodium lactate, sodium succinate, sodium tartrate and the like.
- water-soluble drugs include whitening agents, specifically ascorbic acid and / or its derivatives L-ascorbic acid dalcoside, L-ascorbic acid 2 phosphate esterolate, L-asconolevic acid 3 phosphate esterolate, L-asconoleate phosphate 6 Estenole phosphate, L-ascorenolevate 1-2 Polyphosphate esterole, L-ascorbate 2-sulfate, L-ascorbate 2-palmitate, L-ascorbate 6-palmitate, L-ascorbate 2-stearate ester, Examples include L-asconoleic acid 6-stearate esterol, L-asconoleic acid 2,6-dibutyl ester, L-ascorbic acid 2,6-dipalmitate, and the like.
- salts can also be used.
- the salts include sodium salt, potassium salt, magnesium salt, calcium salt, barium salt, ammonium salt, monoethanolamine salt, diethanolamine salt, triethanolamine salt, monoisopropanolamine salt, triisopropanolamine. Salt.
- other whitening agents include arbutin, kojic acid, and dartathione.
- water-soluble drugs include anti-inflammatory agents, and specific examples include glycyrrhizic acid derivatives and allantoin.
- Animal and plant extracts include, for example, nettle leaf extract, Ezogokogi extract, buckwheat extract, coffee extract, birch extract, sweet potato power extract, thyme extract, chia extract, hamamelis extract, toad extract, grape leaf extract, hop extract, maronier extract, melissa Extract, Acerola extract, Age extract, Kiwi extract, Anole-force extract, Augon extract, Auren extract, Odorikosou extract, Gama spike extract, Forced honey extract, Force wormwood extract, Licorice extract, Gardenia extract, Kumazasa kiss, Gentianana extract, Black tea extract, Confrey Extract, perilla extract, shikon extract, shi Nanoki extract, shimokkeso extract, peonies extract, squirrel extract, sage extract, cicada extract, cicada- ⁇ toco extract, cicada millet extract, sembly kiss, crispy extract, cassava extract, bean clover extract, peach leaf extract, cy
- the above-described inorganic salts, organic salts, water-soluble drugs, animal and plant extracts may be used alone or in combination of two or more.
- adhesion to the skin and the like is high.
- a cosmetic is provided.
- the use of the esterified wrinkle reaction product of the present invention can provide a cosmetic that is excellent in adhesion to skin, hair, etc., has a high emollient effect, and has a long-lasting improvement effect.
- the esterification reaction product of the present invention is an esterification reaction product obtained by esterifying dipentaerythritol and a 12-hydroxy stearic acid polymer, and the hydroxyl value of the esterification reaction product is Is 20 to 70 mgKOHZg, and the acid value is 3 mgKOHZg or less.
- dipentaerythritol used for producing the esterified product of the present invention a commercially available product can be used.
- the product name “Di'Pentalit, manufactured by Guangei Perstove Co., Ltd.” Or the like can be used.
- the 12-hydroxy stearic acid polymer used for producing the esterified koji reaction product of the present invention is a polymer of 12-hydroxy stearic acid having one hydroxyl group in the molecule, such as castor seed oil. It can be obtained by polymerizing 12-hydroxystearic acid obtained by hydrogenating ricinoleic acid obtained by hydrolyzing bisphenol.
- the polymerization reaction of 12-hydroxystearic acid is a reaction in which a hydroxyl group or a carboxyl group in a 12-hydroxystearic acid molecule is esterified with a carboxyl group or a hydroxyl group in another 12-hydroxystearic acid molecule, that is, between molecules. Esterification reaction.
- the polymerization reaction of 12-hydroxystearic acid can be carried out, for example, as follows.
- 12-Hydroxystearic acid is charged into a reaction vessel, and in the presence or absence of acid, alkali, or other metal catalyst, preferably in an organic solvent and Z or gas inert to the reaction, 180 ° C to 220 ° C. Perform esterification (polymerization) with stirring at a temperature of ° C for 5-30 hours.
- 12-hydroxystearic acid a commercially available product can be used.
- “Hydroxystearic acid”, products manufactured by Nippon Oil & Fats Co., Ltd., “castor hardened fatty acid”, and the like can be used.
- the 12-hydroxy stearic acid polymer used for producing the esterified product of the present invention preferably has a polymerization degree of 2-12.
- the degree of polymerization is more preferably 4-12, and most preferably 6-12.
- the average degree of polymerization can be adjusted to the above range by measuring the acid value of the reaction product during the polymerization reaction of 12-hydroxystearic acid. That is, during the polymerization reaction of 12-hydroxystearic acid, the reaction product is sampled, and the acid value is measured to calculate the average polymerization degree. When the desired average polymerization degree is reached, the esterification reaction (polymerization reaction) ) Can be easily implemented.
- the esterification reaction product of the present invention has a hydroxyl value of 20 to 70 mg KOHZg, preferably 20 to 60 mg KOHZg, more preferably 25 to 50 mg KOHZg, and most preferably 30 to 40 mg KOHZg.
- the hydroxyl value is less than 20 mg KOHZg, it is not possible to obtain a product having the desired water repellency and dispersibility. Moreover, it is because manufacture will become difficult when a hydroxyl value exceeds 70 mgKOHZg. On the other hand, when the hydroxyl value is less than 20 mgK OHZg, the production becomes difficult.
- the ratio of dipentaerythritol and 12-hydroxystearic acid polymer can be adjusted.
- the esterification reaction product of the present invention has an acid value of 3 mg KOHZg or less, preferably 0 ⁇ 3mg KOHZg. If the acid value exceeds 3mgKOHZg, odors may occur.
- the reaction product is sampled during the esterification reaction, the acid value is measured, and the esterification reaction is stopped when the desired acid value is reached. Can be implemented.
- the esterification reaction product of the present invention is obtained by esterifying dipentaerythritol and a 12-hydroxystearic acid polymer.
- the amount of 12-hydroxystearic acid polymer used in the esterification reaction is adjusted to the hydroxyl group value within the above range and the amount of unreacted dipentaerythritol remaining is reduced.
- Pentaerythritol is preferably 1 to 6 moles per mole of pentaerythritol, more preferably 1.5 to 5 moles, and most preferably 2 to 4 moles.
- esterification of dipentaerythritol and a 12-hydroxystearic acid polymer is carried out as follows. Esterify dipentaerythritol and 12-hydroxy stearic acid polymer in a reaction vessel in inert organic solvent and Z or gas at a temperature of 200 ° C to 220 ° C for 1 to 20 hours After the reaction, purification treatment is performed to obtain an esterification reaction product of dipentaerythritol and 12-hydroxystearic acid polymer.
- a catalyst may be used as necessary.
- the catalyst include an acid catalyst and an alkaline earth metal alkoxide.
- an acid catalyst or an alkaline earth metal alkoxide is used as a catalyst, the amount used is 0 with respect to the total mass of the reaction raw materials. It is preferably about 001-1. 0% by mass.
- the catalyst and raw material unreacted substances can be removed by performing known purification treatments such as washing with water, alkaline deoxidation, and adsorption treatment. Furthermore, the obtained reaction product can be further purified by performing decolorization and deodorization treatment.
- the resulting esterified soot reaction product is a cosmetic composition described below. It can be used as a component.
- the cosmetic of the present invention contains the esterification reaction product of the present invention.
- the use and dosage form of the cosmetics of the present invention are not particularly limited, for example, lip cosmetics, foundations, emollient creams, emulsions, makeup bases, hair creams, chamboos, rinses, hair conditioning, hand creams, Examples include cosmetics, eyebrows cosmetics, nail cosmetics, and sunscreen cosmetics.
- These cosmetics can be produced by a known method with no particular limitation.
- the cosmetic of the present invention contains the above esterification reaction product, so that makeup such as lip cosmetics, makeup bases, foundations, eyebrows cosmetics, nail cosmetics, etc.
- makeup bases and foundations liquid foundation, powder foundation, stick foundation and cream foundation
- the surface of the skin is made uniform by making use of the ability to form a water-resistant film, and the foundation paste is improved.
- it has the effect of imparting softness and moisturizing effect.
- durability against sebum, sweat, and rubbing is improved, makeup finish can be continued, and it can be applied to sunscreen. is there.
- lip cosmetics lipstick, lip daros, lip balm
- eyebrows cosmetics eyeliner, mascara, eye shadow, eyebrow
- nail cosmetics nail enamel, base coat, top coat
- high pigment dispersibility dye dispersibility
- dyeing with the dyes may cause troubles on the skin and mucous membranes (roughness, dryness, allergies, darkening, etc.).
- the cosmetic composition can be applied to the skin and lips without losing its color, and it is possible to provide cosmetics with less blurring, and it is easy to prepare emulsified lip cosmetics. Become.
- moisturizing effect on the lips by adding moisturizers, inorganic salts, organic salts, water-soluble drugs, animal and plant extracts, etc. , Can give treatment effect.
- a moisturizing agent, inorganic salt, organic salt, water-soluble drug, animal and plant extract, etc. to a powder solid type or an oily type, and to impart a moisturizing effect.
- the esteri koji reaction product of the present invention can be blended in the oil phase of the oil-in-water emulsified cosmetic.
- sunscreen cosmetics water-in-oil (wZo type) cream sunscreen cosmetics, water-in-oil (wZo type) milky sunscreen cosmetics, water-in-oil (wZo type) multilayer emulsions.
- dosage forms such as sunscreen cosmetics, oil-in-water type (oZw type) cream-like sunscreen cosmetics, oil-in-water type (oZw type) milky sunscreen cosmetics, etc.
- the esterification reaction product of the present invention has a high pigment dispersibility
- the inorganic pigment when blended in a sunscreen cosmetic, the inorganic pigment is uniformly dispersed in the cosmetic and applied to the skin. Since a uniform inorganic pigment film can be formed on the top, the UV protection effect can be enhanced. That is, even if the amount of the inorganic pigment in the cosmetic is the same, there is an effect of increasing SPF (SUN PR OTECTION FACTOR).
- SPF SUN PR OTECTION FACTOR
- the esterification reaction product of the present invention has high water retention and has the effect of improving wZo emulsification stability, by incorporating this, the water-in-oil type (wZo type) having excellent stability over time. ) Emulsions can be obtained.
- wZo type water-in-oil type having excellent stability over time.
- the content of the esterification reaction product in the cosmetic of the present invention varies depending on the cosmetic dosage form.
- the cosmetic has a feeling of use such as adhesion, water-resistant film formation, and moisturizing feeling.
- the content of the esterification reaction product of the present invention in the cosmetic is preferably 0.1 to 80% by mass, more preferably 1 to 80% by mass, and still more preferably 1 It is -60 mass%, More preferably, it is 1-40 mass%, Most preferably, it is 5-40 mass%.
- the esterified koji reaction product of the present invention has a high water repellency, and has the effect of improving the WZO emulsification stability.
- the water-in-oil type having excellent temporal stability.
- An emulsion (WZO type) can be obtained.
- WZO type water-in-oil
- examples of such water-in-oil (WZO) emulsions include (a) esterification reaction products, (b) organically modified clay minerals, (c) oil components, and (d) water-containing oils. Water type (WZO type) emulsions may be mentioned.
- the ingredients that depend on the cosmetic application and dosage form include, for example, oily ingredients, aqueous ingredients, polymer emulsions, ionic surfactants, cationic surfactants, amphoteric surfactants, and lipophilic substances.
- oil component examples include liquid paraffin, heavy liquid isoparaffin, solid paraffin, (X-olefin oligomer, squalane, petrolatum, polyisobutylene, polybutene, montan wax, ceresin wax, microcrystalline wax.
- Hydrocarbons such as polyethylene wax and Fischer-Tropsch wax, oils and fats such as olive oil, castor oil, jojoba oil, mink oil, muss power demian nut oil; beeswax, candelilla wax, gay wax, candelilla wax, Waxes such as carnauba, wax, etc .; cetyl 2-ethylhexanoate, cetyl isooctanoate, isopropyl myristate, isopropyl palmitate, octyldodecyl myristate, polyglyceryl diisostearate, polydasyl triisostearate Seryl, diglyceryl triisostearate, polyglyceryl tetraisostearate, diglyceryl tetrisostearate, trioctanoin, diisostearyl malate, dipentyl glycol dioctanoate, propylene glycol didecanoate, cholesterol fatty acid este
- the oily components may be used alone or in combination of two or more.
- aqueous component examples include glycols such as lower alcohols such as ethyl alcohol and butyl alcohol, propylene glycol, 1,3-butylene glycol, dipropylene glycol and polyethylene glycol; glycerin, diglycerin, poly Examples include glyceronoles such as glycerin; plant extracts such as aloe vera, witch hazel nore, cucumber legumes, cucumber, tomato, apple, lemon, lavender and rose.
- the above aqueous components may be used alone or in combination of two or more.
- Examples of the polymer emulsion include alkyl acrylate copolymer emulsion, alkyl methacrylate polymer emulsion, alkyl acrylate copolymer emulsion, alkyl methacrylate copolymer emulsion, and acrylic acid 'acrylic acid.
- Alkyl copolymer emulsion methacrylic acid 'alkyl methacrylate copolymer emulsion, alkyl acrylate, styrene copolymer emulsion, alkyl methacrylate' styrene copolymer emulsion, butyl acetate emulsion, polyacetate emulsion, Emulsion containing butyl acetate, butylpyrrolidone styrene copolymer emulsion And silicone-containing copolymer emulsion.
- Polymer emulsions may be used alone or in combination of two or more.
- surfactants examples include soap bases, fatty acid soaps such as sodium laurate and sodium palmitate, higher alkyl sulfates such as sodium lauryl sulfate and potassium lauryl sulfate, and polyoxy Ethylene (POE) -triethanolamine lauryl sulfate, POE-alkyl ether sulfate ester salts such as sodium lauryl sulfate; N-acyl sarcosine acid such as sodium lauroyl sarcosine; N-myristoyl-N-methyl taurate sodium, palm Higher fatty acid amide sulfonates such as oil fatty acid methyl tauride sodium and lauryl methyl tauride sodium; POE-sodium ether ether phosphate, phosphoric acid ester salt such as POE-stearyl ether phosphoric acid; Sodium xylsulfosuccinate , Sulfosuccinates such as sodium mono
- Higher fatty acid ester sulfate ester salt Sulfated oil such as funnel oil; POE-alkyl ether strength Rubonic acid, POE-alkylaryl ether carboxylate, ⁇ -o Finsulfonic acid salt, higher fatty acid ester sulfonate salt, secondary alcohol sulfate ester salt, higher fatty acid alkylolamide sulfate ester salt, sodium lauroyl monoethanolamide succinate, ⁇ -palmitoylaspartate ditriethanolamine, Casein sodium and the like are listed.
- the above-mentioned surfactants may be used alone or in combination of two or more.
- Examples of the cationic surfactant include alkyltrimethyl ammonium salts such as stearyl chloride trimethyl ammonium and salt lauryl trimethyl ammonium; distearyl dimethyl ammonium chloride and the like. Alkyl salts of dialkyldimethylammonium salts, poly ( ⁇ , N′-dimethyl-3,5-methylenepiberidinium), cetylpyridium chloride, etc.
- Rupyridium salt alkyl quaternary ammonium salt, alkyldimethylbenzyl ammonium salt, alkyl isoquinolium salt, dialkyl morpholine salt, POE—alkylamine, alkylamine salt, polyamine fatty acid derivative Amyl alcohol fatty acid derivatives, salified benzalcoum, and salt benzethonium.
- the cationic surfactants may be used alone or in combination of two or more.
- amphoteric surfactant examples include 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolium hydroxide-1 —Imazoline-based amphoteric surfactants such as carboxyethyloxy disodium salt; 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazo ruthenium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amide Examples include betaine and betaine surfactants such as sulfobetaine. Amphoteric surfactants may be used alone or in combination of two or more.
- lipophilic nonionic surfactant examples include sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate.
- Sorbitan trioleate pentan 2-ethyl hexyl glycerol disorbate sorbitan, tetra-2-ethyl hexyl diglycerol sorbitan, etc .; sucrose fatty acid esters; mono cottonseed oil fatty acid glycerin, monoergic acid glycerin Glycerin fatty acid such as glyceryl sesquioleate, glyceryl monostearate, a, ⁇ '-year-old pyrophosphate glycerin, glyceryl monostearate; diglyceryl monoisostearate, disoterate Propylene glycol fatty acid esters, propylene glycol monostearate; polyglycerin fatty acid esters such as glyceryl hardened castor oil derivatives, and grayed re serine alkyl ether and the like.
- Lipophilic nonionic surfactants may be used alone V, or in combination of two or more
- hydrophilic nonionic surfactant examples include ⁇ -sorbitan monooleate, ⁇ -sorbitan monostearate, ⁇ -sorbitan monooleate, and ⁇ -sorbitan tetraoleate.
- Sorbitan fatty acid esters ⁇ -Sorbit monolaurate, ⁇ —Sorbit monooleate, ⁇ —Sorbit pentaleate, ⁇ POE sorbite fatty acid esters such as OE sorbite monostearate; POE glycerin fatty acid esters such as POE glycerin monostearate, POE glycerin monoisostearate, POE glycerin triisostearate; POE monooleate, POE-distearate, POE POE fatty acid esters such as monodiolates and ethylene glycol distearate; POE alkyl ethers such as POE lauryl ether, POE oleyl ether, POE—stearyl ether, POE beryl ether, POE—2-octyldodecyl ether, POE cholestanol ether, etc.
- POE sorbite fatty acid esters such as OE sorbite
- Pull mouth nick types such as pull mouth nicks; POE ⁇ POP -cetyl ether, POE ⁇ POP— 2-decyltetradecyl ether, ⁇ ⁇ POP monobutyl ether, POE'POP hydrogenated lanolin, POE ⁇ POP -glycerin ether POE ⁇ POP -alkyl ethers such as Telu; Tetra POE 'Tetra POP-ethylenediamine amines such as Tetronic; POE-Castor oil, POE hydrogenated castor oil, POE hydrogenated castor oil monoisostearate, POE hydrogenated castor oil POE castor oil hydrogenated castor oil derivatives such as triisostearate, POE hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, POE hydrogenated castor oil maleic acid, etc .; POE beeswax lanolin derivatives such as POE sorbite beeswax; palm
- Examples of the natural surfactant include lecithins such as soybean phospholipid, hydrogenated soybean phospholipid, egg yolk phospholipid, hydrogenated egg yolk phospholipid; and soybean saponin. Natural surfactants may be used alone or in combination of two or more.
- humectant examples include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caroic acid, and telate.
- Collagen and cholesteryl — 12-hydroxystearate, sodium lactate, urea, bile salt, dl-pyrrolidone carbonate, short-chain soluble collagen, diglycerin (EO) PO adduct, Izayobara extract, sorghum extract, and Merirot extract etc. are mentioned.
- Moisturizers may be used alone or in combination of two or more.
- thickener examples include gum arabic, carrageenan, caraja gum, gum tragacanth, carob gum, quince seed (malt mouth), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethyl cellulose , CMC, hydroxyethyl cellulose, hydroxypropyl cellulose, PVA, PVM, PVP, sodium polyacrylate, carboxybule polymer, locust bean gum, guargam, tamarind gum, dialkyldimethylammonium sulfate cellulose, xanthan gum, caeic acid
- Aluminum magnesium bentonite, hectorite, quaternary ammonium salt type cation-modified bentonite, quaternary ammonium salt type cation modified hectolite and decaglycerin fat Esters eicosane - condensate, and the like.
- Thickeners can be used alone or in combination of two or more
- preservatives examples include methyl paraben, ethyl paraben, and butyl paraben. Preservatives may be used alone or in combination of two or more.
- Examples of the powder component include talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, safmica, biotite, lithia mica, permkyrite, magnesium carbonate, Calcium carbonate, Aluminum silicate, Barium silicate, Calcium silicate, Magnesium silicate, Strontium silicate, Metal tungstate, Magnesium, Silica, Zeolite, Barium sulfate, Calcium sulfate, (Calcined calcium), Calcium phosphate, Fluorine Apatite, hydroxyapatite, ceramic powder, metal sarcophagus (zinc myristate, calcium palmitate, aluminum stearate), inorganic powders such as boron nitride; polyamide resin powder (nylon powder), polyethylene powder, polymethyl methacrylate powder , Polystyrene powder Copolymer ⁇ powder of styrene and acrylic acid, benzogu
- the powder component may be used alone or in combination of two or more.
- the pigment include inorganic white pigments such as titanium dioxide and zinc oxide (fine particle type titanium dioxide used as an ultraviolet scattering agent, zinc oxide, or aluminum stearate with a surface thereof.
- fatty acid soaps such as ginta palmitate, fatty acids such as stearic acid, myristic acid and palmitic acid, and surface-coated inorganic white pigments coated with fatty acid esters such as dextrin palmitate
- inorganic yellow pigments such as yellow iron oxide and ocher
- inorganic black pigments such as black iron oxide, carbon black and low order titanium oxide
- mango Inorganic purple pigments such as violet and cobalt violet
- inorganic green pigments such as acid chrome, chromium hydroxide and cobalt titanate
- Inorganic blue-based pigments Acid-titanium coated my strength, titanium oxide-coated bismuth chloride chloride, titanium oxide-coated talc, colored acid-titanium coated strength, oxysalt-bismuth, fish scale foil, and other pigments; aluminum Metal powder pigments such as powder and kappa powder; Red 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204 No., yellow 205, yellow 401, and blue 404 organic pigments, red 3, red 104, red 106, red 227, red 230, red 401, red 505, orange 205 Zirconium such as Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green No. 3 and Blue No. 1, and organic pigments such as barium or aluminum lake.
- the pigments may be used alone or in combination of two or more.
- Examples of the pH adjuster include edetic acid, disodium edetate, citrate, sodium citrate, sodium hydroxide, potassium hydroxide, and triethanolamine.
- the pH adjuster may be used alone or in combination of two or more.
- anti-oxidation agent examples include vitamin Cs and derivatives thereof, and salts thereof, tocopherols and derivatives thereof, and salts thereof, dibutylhydroxytoluene, butylhydroxyl-sol, and gallic acid. Examples include acid esters. Antioxidants may be used alone or in combination of two or more.
- Examples of the ultraviolet absorber include paraaminobenzoic acid (hereinafter abbreviated as PABA), Benzos such as PABA monoglycerin ester, N, N dipropoxy P ABA ethyl ester, N, N-diethoxy PABA ethyl ester, N, N-dimethyl PABA ethyl ester, N, N-dimethyl P ABA butyl ester, N, N dimethyl PABA octyl ester Acid UV absorbers; Anthracic acid UV absorbers such as homomenthyl-N-acetylacetylate; amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenol salicylate, benzyl salicylate, p Salicylic acid-based UV absorbers such as isopropanol phenol salicylate; octyl cinnamate, ethyl 4-isopropy
- Cinnamic acid UV absorbers 2,4-dihydroxybenzophenone, 2,2, -dihydroxy-4-methoxybenzophenone, 2,2'-dihydroxy 4,4'-dimethoxybenzophenone, 2, 2 ', 4 , 4'-tetrahydroxy benzophenone, 2 hydroxy-4-metho Xylbenzophenone, 2-hydroxy-4-methoxy 4 'methylbenzophenone, 2-hydroxy-4-methoxybenzophenone-5-sulfonate, 4-phenol penzophenone, 2-ethylhexyl 4'-phenol- Benzophenone UV absorbers, such as benzophenone 2-carboxylate, 2-hydroxy-1-4-n-otatoxybenzophenone, 4-hydroxy-1-3-hydroxybenzophenone; 3-(4, 1-methylbenzylidene ) D, 1-camphor, 3-benzylidene d, 1-camphor, urocanic acid, urocanic acid ethyl ester, 2-phenyl-5
- Examples of the pigment include chlorophyll and / 3 strength rotin. Dye may be used alone or in combination of two or more.
- fragrances examples include vegetable fragrances such as rose oil, jasmine oil, and lavender oil, and synthetic fragrances such as limonene, citral, linalool, and eugenol. Perfumes can be used alone or in combination of two or more.
- sequestering agent examples include disodium edetate, edetate, and hydroxyethanediphosphonic acid.
- the sequestering agent may be used alone
- the acid value and hydroxyl value of the esterification reaction product were measured according to the old cosmetic raw material standard.
- a 1 L four-necked flask equipped with a stirrer, thermometer, nitrogen gas blowing tube and moisture separator was charged with 483 g of 12-hydroxystearic acid (trade name: hydroxystearic acid, manufactured by Kawaken Fine Chemical Co., Ltd.) Capable of removing 0.1% of tin chloride as a catalyst and 5% of xylol as a refluxing solvent as a refluxing solvent, and removing water generated in a nitrogen stream. Then, the reaction was carried out for 15 hours to obtain 12 hydroxystearic acid polymer. When the acid value of the obtained polymer was measured, the acid value was 33 mg KOHZg, and the average degree of polymerization calculated from the acid value was 6. Therefore, the resulting product was a 12-hydroxystearic acid hexamer. I understood it.
- the catalyst After completion of the reaction, the catalyst is filtered off, then decolorized using activated clay, and then deodorized by blowing water vapor under reduced pressure to obtain 340 g of a sticky liquid esterified reaction product at room temperature. It was.
- the acid value of the obtained esterification reaction product was 0.5 mgKOHZg, and the hydroxyl value was 35 mgKOH / g.
- 12-hydroxystearic acid As 12-hydroxystearic acid, the same procedure as in Production Example 1 was carried out except that 487 g of the product name “12-hydroacid HP” manufactured by Ogura Gosei Kogyo Co., Ltd. was used and the reaction time was 18 hours. A hydroxystearic acid polymer was obtained. When the acid value of the obtained polymer was measured, the acid value was 19 mgKOHZg, and the average degree of polymerization calculated from the acid value was 10. Thus, it was found to be a 10-mer.
- the catalyst is filtered off, then decolorized using activated clay, deodorized by blowing steam under reduced pressure, and a semi-solid liquid (paste-like) esterification reaction product at room temperature 325 g was obtained.
- the acid value of the obtained ester composition was 1.2 mgKOH, g, and the hydroxyl value was 123 mgKOHZg.
- a 1-L four-necked flask equipped with a stirrer, thermometer, nitrogen gas blowing tube and water separator was placed in a 12-hydroxystearic acid polymer (acid value: 33 mgKOH / g, hexamer) 442 g, and 43 g of dipentaerythritol (product name “Dipentalit”, manufactured by Guangei Harptop Co., Ltd.), and at a temperature of 210 ° C. while removing the generated water under a nitrogen stream, The reaction was continued until the acid value of the product was 1 mgKOHZg or less.
- the amount of 12-hydroxystearic acid polymer (acid value: 33 mg KOH / g, hexamer) obtained by the same production method as in Production Example 1 was 462 g, and dipentaerythritol (manufactured by Guangei Harptop Co., Ltd.)
- the procedure was the same as in Production Example 1 except that the amount used was 29 g (named “di'pentalite”), and 330 g of a viscous liquid estery product was obtained at room temperature.
- the acid value of the obtained esterification reaction product is 0.4 mgKOHZg, and the hydroxyl value is 44 mgKOHZg.
- Example 2 Except that the amount of 12-hydroxystearic acid polymer obtained was 475 g, and the amount of dipentaerythritol (product name “Di'Pentalit” manufactured by Guangei Harptop Co., Ltd.) was 16 g.
- the same operation as in Example 1 was carried out to obtain 338 g of an esterification reaction product of a viscous liquid at room temperature.
- the acid value of the obtained esterification reaction product is 0.9 mgKOH / g
- the hydroxyl value was 52 mg KOHZg.
- liquid lanolin, polyglyceryl triisostearate (manufactured by Nisshin Oillio Group, trade name: Cosmol 43V) and diisostearyl malate (Nisshin Oillio Group) The test was also conducted on the product name, Cosmall 222).
- liquid lanolin, trioctanoin manufactured by Nisshin Oillio Group Co., Ltd., product name: TI 0
- polyglyceryl triisostearate manufactured by Nisshin Oilio Group Co., Ltd., Name: Cosmol 43V
- diisostearyl malate Neshin Oillio Group, product name: Cosmol 222
- the water retention test for the esterification reaction product was conducted as follows with reference to the lanolin water content determination method of the British Pharmacopoeia (BP).
- the measurement sample lg and 9 g of petroleum jelly were mixed and stirred vigorously while dropping purified water in a constant temperature bath at 40 ° C (200 to 300 rpm).
- the point at which water could not enter was the end point, and it was expressed as a percentage of the water mass relative to the mixed sample mass. It can be said that the higher this value is, the higher the water retention of the sample.
- the measurement sample and water were mixed at a mass ratio of 7: 3 and vigorously stirred in a 70 ° C constant temperature bath to obtain a hydrated substance (500 rpm, 3 minutes).
- the obtained hydrate was analyzed by differential scanning calorimetry (manufactured by Seiko Instruments Inc., instrument name “DSC6200”).
- the measurement was performed at a rate of 2 ° C Zl in the range of -15 to 45 ° C, a differential scanning calorimetry curve was created, and the presence or absence of an endothermic peak of water near 0 ° C was confirmed. If this endothermic peak is not present, the water retention is good It can be said.
- Sample force After forming S-cream, apply 10 g of sample uniformly on a petri dish so that the film thickness is 0.5 to 5 mm, and leave the lid open in a constant temperature bath at 40 ° C. I put it.
- the sample was taken out after 24 hours, and the mass after standing was measured, and the decrease mass before and after standing was calculated. The results are expressed as a percentage of the mass decreased with respect to the mass of the coated sample. The lower this value, the better the water retention.
- octyl palmitate (Nisshin Oilio Group Co., Ltd., trade name: Saracos P-8). The point at which flow started when tilted as a whole was taken as the pour point, and the amount of octyl palmitate added to reach each point was measured, and the wet point value and pour point value were obtained.
- a dye mixture was prepared by dissolving a dye (red No. 218) in a sample so that the dye concentration was 0.5 mass%. This dye mixture was applied to the upper arm, and after 3 hours, the applied part was wiped off with a waste cloth and observed with a microscope (X 100 times) to observe the amount of dye remaining on the skin.
- the applied part of the skin was observed with a microscope (X 100 times) and evaluated visually by the following three steps.
- a sample solution was prepared by dissolving the sample in black mouth form to a concentration of 10% by mass. After the obtained sample solution was applied on a cleaned glass plate, the solvent was removed to form a coating film. One drop of distilled water was dropped on the formed coating film, and the contact angle between the water droplets was measured. After measurement, the coating film was washed with running water (25 mLZs, lmin), and the water resistance was evaluated by comparing it with that before washing. The smaller the contact angle difference before and after cleaning, the higher the water resistance.
- the oxidation stability of the sample was evaluated by CDM test (standard oil and fat test method: 120 ° C, Air: 20L / hr). In the test, evaluation was performed by measuring the dielectric constant over time using a Rancimat 743 (manufactured by Metrohm) apparatus. In the CDM test, it can be said that as the time elapses, the dielectric constant does not increase, and the better the acidity stability is.
- FIG. 1 is a graph showing the results of the water retention test 2 of the ester ester reaction product obtained in Production Example 1.
- the endothermic peak of water in the vicinity of 0 ° C. was not detected in the esterified product obtained in Production Example 1. This indicates that the esterification reaction product obtained in Production Example 1 has the ability to include a large amount of water as fine particles and is also stable to heat changes.
- FIG. 2 is a graph showing the results of the water retention test 2 of the esterification reaction product obtained in Production Example 2. As shown in FIG. 2, the esterified soot reaction product obtained in Production Example 2 did not detect the endothermic peak of water near 0 ° C. This indicates that the esterification reaction product obtained in Production Example 2 has the ability to include a large amount of water as fine particles and is also stable to heat changes.
- FIG. 3 is a graph showing the results of the water retention test 2 of the esterification reaction product obtained in Production Example 3. As shown in FIG. 3, the ester end reaction product obtained in Production Example 3 detected an endothermic peak of water near 0 ° C. This indicates that the esteri koji reaction product obtained in Production Example 3 does not have the ability to include a large amount of water as fine particles and is not stable to heat changes.
- FIG. 4, FIG. 5, and FIG. 6 are graphs showing the results of the water retention test 2 for liquid lanolin, cholesteryl hydroxystearate, and diisostearyl malate, respectively. As shown in FIGS. 4 to 6, an endothermic peak of water was detected at around 0 ° C. for the above compound. This indicates that the above compound does not have the ability to include a large amount of water as fine particles and is not stable to heat change.
- the results shown in Table 2 show the following.
- the esterification reaction product obtained in Production Example 1 and Production Example 2 was excellent in non-dyeing properties, and showed the effect of suppressing the dye from staining on the skin.
- the esterification reaction product obtained in Production Examples 1 and 2 has a smaller contact angle difference between the water droplets of the coating film before and after washing compared to liquid lanolin, polyglyceryl triisostearate, and diisostearyl malate. It shows excellent water resistance. That is, the esterification reaction products obtained in Production Examples 1 and 2 are excellent in non-dyeing property and water resistance.
- FIG. 7 shows the evaluation results of oxidation stability.
- FIG. 7 is a graph showing the results of evaluation of oxidation stability (CDM test).
- the horizontal axis represents elapsed time, and the vertical axis represents dielectric constant.
- the esterification reaction product obtained in Production Example 1 has very good acidity stability with little change in dielectric constant over time.
- the thermal stability with no change in hue and odor before and after the test is excellent.
- the dielectric constant increases with time, indicating that the oxidation stability is inferior to the ester reaction product obtained in Production Example 1.
- the esterification reaction product obtained in Production Example 2 also showed the same effect as Production Example 1 in terms of oxidation stability.
- Ten sensory evaluation panelists used each cosmetic and extended (such as skin) The ability to apply cosmetics smoothly to the application site), moisturizing feeling (whether it has a moisturizing effect on the application site such as skin), gloss (natural gloss is applied to the application site such as hair) ), Flexibility (whether to give flexibility to the use site such as skin and hair), film feeling (whether there is a film feeling after use), adhesion (adhesion feeling after use) Feeling of unity (whether or not there is a feeling of unity of hair after use), ease of attachment (whether or not it is easy to stick to wrinkles during use), smoothness ( Smoothness when using), curl feeling (whether there is an effect of curling up the eyelids), stickiness (whether it can force the part to be used), gloss (use Whether the gloss of the part is good or not), sustainability (whether it has a good makeup after use), color developability (whether it is vividly colored at the part used), impact resistance About sensory evaluation such as (determination of whether or not the makeup is maintained by contact with external force) detergency
- Example 1 Comparative Examples 1 and 2
- Raw material 3 5 was added to a part of raw material 11 and processed with a roller to prepare a pigment part.
- Raw material 6 was dissolved in a part of raw material 11 to prepare a dye part.
- the raw material 1 or 2 and the raw material 715 were mixed and dissolved by heating, and then the pigment part and the dye part were added and dispersed uniformly with a homomixer. The dispersion was poured into a mold and then rapidly cooled to obtain a sticky lipstick.
- Table 4 shows the results of sensory evaluation.
- Liquid lanolin 1 1. 0
- Table 4 shows the following.
- the stick-shaped lipstick of Example 1 smoothly extends to the lips and has a natural gloss and moisturizing effect.
- the stick-shaped lipstick of Example 1 is more effective than the stick-shaped lipsticks of Comparative Examples 1 and 2, and does not feel the taste or odor! /.
- the stick-like lipstick of Example 1 was also confirmed to have an effect of suppressing bleeding.
- Paste lipsticks having the composition shown in Table 5 were produced by the following method.
- Heavy fluid isopara 7 7 2 5. 0 2 5. 0
- Table 6 shows the following.
- the pasty lipstick of Example 2 was found to be excellent in pigment color developability, adhesion and film feeling (uniformity of the cosmetic film) and capable of maintaining makeup for a long time.
- the paste-like lipstick of Example 2 is more effective than the paste-like lipstick of Comparative Example 3 in terms of color development, adhesion, and film feeling! It takes a long time and it's a thing.
- a glycerin-containing stick-like lip balm with the formulation shown in Table 7 was produced by the following method. All the raw materials were mixed, dissolved by heating, and then uniformly dispersed with a homomixer to obtain a dispersion. The obtained dispersion was poured into a mold and then rapidly cooled to obtain a glycerin-containing stick-like lip balm.
- the glycerin-containing material is prepared as follows.
- the esterification reaction product and petrolatum obtained in Production Example 1 are mixed so that the mass ratio of the esterification reaction product: petrolatum is 1: 9 (mass ratio), and 10 times the amount of glycerin of this mixture is mixed.
- Table 8 shows the results of sensory evaluation of each.
- Triok Yunoin 1 5. 0 1 5. 0
- Table 8 shows the following.
- the glycerin-containing stick-like lip balm of Example 3 had an excellent moisturizing feeling and had an effect of smoothly extending to the lips and imparting natural gloss.
- the glycerin-containing stick-shaped lip balm of Example 3 is superior to the stick-shaped lip cream of Comparative Example 4 in any of moisturizing feeling, spread, and gloss, and the taste and odor V I could't feel it.
- Vitamin C derivative-containing stick-shaped lipsticks with the composition shown in Table 9 were produced by the following method. All the raw materials were mixed, dissolved by heating, and then uniformly dispersed with a homomixer to obtain a dispersion. The obtained dispersion was poured into a mold and then rapidly cooled to obtain a sticky lipstick containing a vitamin C derivative.
- the vitamin C derivative-containing material was prepared as follows.
- the esterification reaction product and petrolatum obtained in Production Example 1 were combined with the mass ratio of esterification reaction product: petrolatum 1 : 9 (mass ratio) was mixed, and a vitamin C derivative-containing material was obtained by stirring while dropping a 20% aqueous solution of L-ascorbyl magnesium phosphate in 10 times the amount of this mixture.
- Table 10 shows the results of sensory evaluation for each.
- Table 10 shows the following.
- the stick-like lipstick containing vitamin C derivative of Example 4 has an excellent moisturizing feeling, has an effect of smoothly spreading on the lips, imparting natural gloss, and has sufficient hardness.
- the vitamin C derivative-containing stick-shaped lipstick of Example 4 is superior to the stick-shaped lipstick of Comparative Example 5 in any of moisturizing feeling, spread, gloss, and hardness, and taste odor I could't feel it.
- a liquid foundation (OZW type) having the composition shown in Table 11 was produced by the following method. Disperse raw material 18 in raw material 10, add raw materials 19 and 20, add homomixer treatment at a temperature of 70 ° C, add the remaining aqueous components (raw materials 11-12), stir well, and add water phase Was prepared. Next, the sufficiently mixed and pulverized powder components (raw materials 13 to 17) were added to the aqueous phase with stirring, and homomixed at a temperature of 70 ° C.
- the raw material 1 or 2 and the oil component were dissolved by heating at a temperature of 70 to 80 ° C to prepare an oil phase.
- the powder component is added to the aqueous phase and then the oil phase is gradually added, and the mixture is homomixed at a temperature of 70 ° C and cooled to 45 ° C with stirring.
- the raw material 9 was added and cooled to room temperature.
- the cooled product was deaerated and filled into a container to obtain a liquid foundation (OZW type).
- Table 12 shows the results of sensory evaluation.
- Table 12 shows the following.
- Example 6 and Comparative Example 7 adheres to the skin and has a moisturizing effect and flexibility.
- the liquid foundation (OZW type) of Example 5 is more effective than the liquid foundation (OZW type) of Comparative Example 6 even though the film feeling, adhesion, moisturizing feeling and flexibility are not significantly different. It was confirmed that it was excellent.
- Example 6 and Comparative Example 7 are more effective than the liquid foundation (OZW type) of Comparative Example 6 even though the film feeling, adhesion, moisturizing feeling and flexibility are not significantly different. It was confirmed that it was excellent.
- a foundation (WZO type) having the formulation shown in Table 13 was produced by the following method.
- Raw materials 1 to 9 were heated and mixed, cooled to 40 ° C, and then raw materials 10 to 18 were collected and dispersed with a homomixer to obtain a mixture (A).
- the raw materials 19 to 24 were mixed and dissolved uniformly to obtain a mixture (B).
- the mixture (B) was added to the mixture (A) and emulsified with a homomixer to obtain a foundation (WZO type).
- Table 14 shows the results of sensory evaluation for each.
- Titanium oxide 7.0 0 7. 0
- Table 14 shows the following.
- Example 6 The foundation of Example 6 (WZO type) has good adhesion to the skin, spread, and film feeling. It was confirmed that it was excellent in (uniformity of) and long-lasting makeup. In addition, the foundation of Example 6 (WZO type) is superior to the foundation of Comparative Example 7 (WZO type) in all of adhesion, spread and film feeling, and the duration of makeup is long. It was long.
- Solid powdery foundations having the formulations shown in Table 15 were produced by the following method.
- Raw materials 1 to 4 were heated to 50 ° C and mixed to obtain a mixture (A).
- the raw materials 5 to 13 were mixed and dispersed, and the above mixture (A) was added to and mixed with this to obtain a mixture (B).
- the obtained mixture (B) was pulverized and compressed into a dish to obtain a solid powdery foundation.
- Table 16 shows the results of sensory evaluation for each.
- Example 7 was excellent in adhesion to the skin and film feeling (homogeneity of the cosmetic film) and could maintain makeup for a long time.
- the solid powder foundation of Example 7 was more effective in both adhesion and film feeling than the solid powder foundation of Comparative Example 8, and had a long makeup duration. It was.
- Solid powdery white powder having the composition shown in Table 17 was produced by the following method.
- Raw materials 6 to 10 were mixed and dispersed to obtain a mixture ( ⁇ ).
- Raw materials 1 to 5 were added to the obtained mixture ( ⁇ ) and mixed uniformly to obtain a mixture ( ⁇ ).
- the obtained mixture (rice cake) was pulverized and compressed into a dish to obtain a white powdery white powder.
- Table 18 shows the results of sensory evaluation of each.
- the solid powdery white powder of Example 8 was found to be excellent in adhesion to the skin and film feeling (uniformity of the cosmetic film), and capable of maintaining makeup for a long time.
- the solid powdery white powder of Example 8 was more effective than the solid powdery white powder of Comparative Example 9 in both adhesion and film feeling, and the makeup duration was long. It was.
- a solid powder cake foundation having the composition shown in Table 19 was produced by the following method.
- Raw materials 8 to 15 were mixed and dispersed to obtain a mixture (A).
- raw materials 1 to 6 were heated to 50 ° C and mixed to obtain a mixture (B).
- the mixture (B) and the raw material 7 were added to the mixture (A) and mixed uniformly to obtain a mixture (C).
- the obtained mixture C was pulverized and compression molded into a dish to obtain a solid powder cake foundation.
- Table 20 shows the results of sensory evaluation for each!
- Nylon powder 5. 0 5. 0
- Example 9 was excellent in adhesion to the skin and spread, and could continue makeup for a long time.
- the solid powder cake foundation of Example 9 is more effective in both adhesion and spread than the solid powder cake foundation of Comparative Example 10, and the duration of the makeup was long.
- Powdered eye colors having the formulations shown in Table 21 were produced by the following method.
- Raw materials 3 to 8 were mixed and dispersed uniformly to obtain a mixture (A). Subsequently, the mixture obtained by adding the raw materials 1 and 2 to the mixture (A) was pulverized to obtain a powdery eye color. Table 22 shows the results of sensory evaluation of each.
- Table 22 shows the following.
- Example 10 was excellent in adhesion to the skin and spread, and could maintain makeup for a long time.
- the powdered eye color of Example 10 was more effective in adhesion and spread than the powdered eye color of Comparative Example 11, and the duration of makeup was long.
- Raw materials 1 to 6 were dissolved and mixed at 80 ° C. to obtain a mixture (A).
- Raw materials 13 to 18 were heated to 80 ° C., and then raw materials 7 to 12 were added and dispersed with a homomixer to obtain dispersion (B).
- Dispersion B was added to the mixture (A), treated with a homomixer, and cooled to obtain an eye color.
- Table 24 shows the results of sensory evaluation.
- Table 24 shows the following.
- Example 11 was excellent in adhesion and film feeling (uniformity of the decorative film) and could maintain makeup for a long time.
- the eye color of Example 11 was more effective in both adhesion and film feeling than the eye color of Comparative Example 12, and the duration of makeup was long.
- Mascara (OZW type) having the composition shown in Table 25 was produced by the following method.
- Table 26 shows the following.
- the mascara of Example 12 (OZW type) has good adhesion to the skin, film feeling (uniformity of makeup film), It was recognized that it was excellent in impact and could last for a long time. Also
- the mascara of Example 12 (OZW type) is superior to the mascara of Comparative Example 13 (OZW type) in all of adhesion, film feeling and impact resistance, and the duration of makeup is long. It was long.
- Mascara with the formulation shown in Table 27 was produced by the following method.
- Raw material 6 is placed on raw material 9 and dispersed with a homomixer, then raw material 5 is heated and maintained at 70 ° C (phase A). Mix other ingredients and heat to 70 ° C (phase B).
- a mascara was obtained by uniformly emulsifying and dispersing the A phase into the B phase with a homomixer. Table 28 shows the results of sensory evaluation for each.
- Table 28 shows the following.
- Example 13 was smooth and immediately smooth against the eyelashes, and was given a beam and a curl feeling.
- the mascara of Example 13 was more effective than the mascara of Comparative Example 14, and was strong enough that no odor was felt.
- An eyeliner (OZW type) having the formulation shown in Table 29 was produced by the following method.
- Raw material 15 was heated and dissolved, and then raw materials 6 and 7 were added and mixed uniformly to obtain a mixture (A).
- the raw material 814 was uniformly mixed to obtain a mixture (B).
- the mixture (B) was added to the mixture (A) and emulsified to obtain an eyeliner (OZW type).
- Table 30 shows the results of sensory evaluation for each.
- Table 30 shows the following.
- Example 14 It was confirmed that the eyeliner (OZW type) of Example 14 was excellent in the film feeling (uniformity of the decorative film) and the color development, and was able to maintain the makeup for a long time. In addition, the eyeliner of Example 14 (OZW type) is superior to the eyeliner of Comparative Example 15 (OZW type) in terms of film feeling and color development. The duration was long.
- An eye shadow (OZW type) having the composition shown in Table 31 was produced by the following method.
- Raw materials 1 to 7 were heated and dissolved, and then raw materials 8 and 9 were added and mixed uniformly to obtain a mixture (A).
- the raw materials 10 to 15 were uniformly mixed to obtain a mixture (B).
- the mixture (B) was added to the mixture (A) and emulsified to obtain an eye shadow (OZW type).
- Table 32 shows the results of sensory evaluation of each.
- Table 32 shows the following.
- Example 15 It was confirmed that the eye shadow (OZW type) of Example 15 was excellent in film feeling (uniformity of the decorative film) and coloring property, and was able to maintain makeup for a long time. In addition, the eye shadow of Example 15 (OZW type) is superior to the eye shadow of Comparative Example 16 (OZW type) in terms of film feeling and color developability, and it is excellent in terms of makeup. It lasted a long time.
- Eyeplow (OZW type) having the composition shown in Table 33 was produced by the following method.
- Raw materials 1 to 7 were heated and dissolved, and then raw material 8 was added and mixed uniformly to obtain a mixture (A).
- the raw materials 9 to 13 were uniformly mixed to obtain a mixture (B).
- the mixture (B) was added to the mixture (A) and emulsified to obtain eyebrows (OZW type).
- Table 34 shows the results of sensory evaluation of each.
- Example 16 It was confirmed that the eye-plow (OZW type) of Example 16 was excellent in film feeling (uniformity of the decorative film) and coloring property, and could maintain makeup for a long time.
- Idalos (paste) having the composition shown in Table 35 was produced by the following method.
- Raw materials 1 to 10 were uniformly heated, mixed and dissolved to obtain a mixture.
- the obtained mixture was filled in a container to obtain Aidaros (pasty).
- Table 36 shows the results of sensory evaluation of each.
- Table 36 shows the following.
- the Eidaros of Example 17 is excellent in gloss, film feeling (uniformity of makeup film) and long-lasting makeup. It was found that it was possible to last for hours. In addition, the Eidaros of Example 17 was more effective in both gloss and film feel than the Eidaros of Comparative Example 18, and the makeup duration was long.
- Powdered scarlet with the composition shown in Table 37 was produced by the following method.
- Example 18 It was confirmed that the powdered scarlet of Example 18 was excellent in adhesion to the skin and spread, and could maintain makeup for a long time. In addition, the powdered crimson of Example 18 is superior to the powdered crimson of Comparative Example 19 in terms of adhesion, spread, and deviation, and the effect is excellent. Long makeup duration! It was a thing.
- a base coat having the formulation shown in Table 39 was produced by the following method.
- Raw materials 1 to 5 were uniformly mixed to obtain a mixture (A). Subsequently, the raw material 6-8 was added to the obtained mixture (A) and mixed uniformly to obtain a base coat. Table 40 shows the results of sensory evaluation for each.
- Table 40 shows the following.
- the base coat is used before the nail material is applied to the nail, and the unevenness of the nail surface is made uniform and the nail material paste is improved. It was confirmed that the base coat of Example 19 improves the gloss of the nail polish and improves the film feeling, and the effect can be sustained for a long time. In addition, the base coat of Example 19 is Comparative Example 2 Compared with the base coat of 0, it is effective in both gloss and film feeling.
- a top coat having the composition shown in Table 41 was produced by the following method.
- Table 42 shows the following.
- the top coat is applied on the nail polish to improve the gloss of the nail polish and maintain the effect of the nail polish.
- the top coat of Example 20 By applying the top coat of Example 20 on the nail polish, it is possible to improve the gloss of the nail polish and to maintain the effect of the nail polish for a long time. It was recognized.
- the topcoat of Example 20 was improved in gloss and adhesion as compared with the topcoat of Comparative Example 21, and had a long gloss duration.
- Nail enamels with the formulations shown in Table 43 were produced by the following method.
- Example 21 was smooth and immediately smooth on the nails, had a good gloss, filled the groove of the pawl and had good adhesion.
- the nail enamel of Example 21 is easier to stick to the nails than the nail enamel of Comparative Example 22, and has a smoothing effect, improved adhesion, and gloss. It was confirmed that the improvement effect of
- a face wash with the formulation shown in Table 45 was produced by the following method.
- Raw materials 1 to 8 were mixed and dissolved by heating at 70 ° C. to obtain a mixture (A).
- raw materials 9 to 13 were mixed and heated to 70 ° C. to obtain a mixture (B).
- the mixture (A) was gradually added to the mixture (B) with stirring at a temperature of 70 ° C. to carry out a saponification reaction. After the saponification reaction was completed, the mixture was cooled with stirring to obtain a facial cream.
- Table 46 shows the results of sensory evaluation of each.
- Table 46 shows the following.
- the face cream of Example 22 was found to be excellent in detergency and impart softness, moisturizing feeling and smoothness to the skin after use. Further, it was confirmed that the facial cleansing cream of Example 22 was superior to the facial cleansing cream of Comparative Example 23 in that it had excellent flexibility, moisturizing properties, and smoothing effects, as well as excellent cleanability. It was.
- Cleansing oils with the formulation shown in Table 47 were produced by the following method.
- Cleansing oil was obtained by uniformly mixing raw materials 1-7.
- Table 48 shows the results of sensory evaluation for each.
- Table 48 shows the following.
- the cleansing oil of Example 23 was found to be excellent in detergency and impart flexibility, moisture retention and smoothness to the skin after use. In addition, it was confirmed that the cleansing oil of Example 23 was superior to the cleansing oil of Comparative Example 24 in terms of flexibility, moisture retention, and smoothness, as well as excellent cleanability. It was.
- Cleansing creams having the composition shown in Table 49 were produced by the following method.
- Raw materials 1 to 9 were dissolved by heating and mixed uniformly to obtain a mixture (A).
- the raw materials 10 to 15 were heated and mixed uniformly to obtain a mixture (B).
- the mixture (B) was mixed with the mixture (A), emulsified, and cooled to obtain a cleansing cream.
- Table 50 shows the results of sensory evaluation for each.
- Table 50 shows the following.
- the cleansing cream of Example 24 was found to have excellent detergency and impart flexibility, moisture retention and smoothness to the skin after use. In addition, it was confirmed that the cleansing cream of Example 24 was superior to the cleansing cream of Comparative Example 25 in addition to the effects of flexibility, moisture retention, and smoothness, as well as excellent cleanability. .
- Tooth lotion 13 ⁇ 4 A lotion having the composition shown in Table 51 was produced by the following method.
- Table 52 shows the following.
- Example 25 imparted flexibility, moisture retention and smoothness to the skin.
- the lotion of Example 25 was superior to the lotion of Comparative Example 26 in the effects of flexibility, moisture retention and smoothness.
- a serum containing the formulation shown in Table 53 was produced by the following method.
- Table 54 shows the following.
- Example 26 The essence of Example 26 was found to stretch and impart flexibility to the skin and to maintain a moisturizing feeling for a long time. In addition, it was confirmed that the cosmetic liquid of Example 26 was superior in the moisturizing and flexibility effects as compared with the cosmetic liquid of Comparative Example 27.
- Raw materials 1 to 6 were dissolved and mixed at 80 ° C. to obtain a mixture (A).
- raw materials 7 to 12 were mixed, heated to 80 ° C., added to the mixture (A), treated with a homomixer, and then cooled to obtain an emulsion.
- Table 56 shows the results of sensory evaluation for each.
- Table 56 shows the following.
- Example 27 The emulsion of Example 27 was found to stretch and impart flexibility to the skin and to maintain a moisturizing feeling for a long time. In addition, it was confirmed that the emulsion of Example 27 was superior in the effects of spreading, moisture retention and flexibility as compared with the emulsion of Comparative Example 28.
- Example 28 and Comparative Example 29 Emollient cream (WZO type)
- An emollient cream (WZO type) having the composition shown in Table 57 was produced by the following method.
- Raw material 1 and raw material 2 or 3 were mixed at room temperature to obtain a mixture (A).
- the raw materials 4 to 8 were uniformly dissolved while heating to a temperature of 80 ° C., and the mixture (A) was gradually and uniformly dispersed therein to obtain a mixture (B).
- the raw materials 9 and 10 were heated to a temperature of 70 ° C. and emulsified with a homomixer while being added to the mixture (B), then degassed, filtered, cooled, and emollient cream (WZO type).
- Table 58 shows the results of sensory evaluation of the obtained emollient cream.
- Table 58 shows the following.
- the emollient creams of Example 28 and Comparative Example 29 have good spread on the skin. It was recognized that a moisturizing effect and flexibility were imparted. In addition, the emollient cream of Example 28 is more effective than the emollient cream of Comparative Example 29 in terms of spreading, moisturizing feeling and flexibility! /. .
- a vitamin C derivative-containing cream having the composition shown in Table 59 was produced by the following method.
- Raw materials 1 to 3 were uniformly mixed to obtain a mixture (A).
- raw materials 4 to 9 were uniformly mixed to obtain a mixture (B).
- the mixture (B) was added to the mixture (A) and emulsified to obtain a vitamin C derivative-containing cream.
- Table 60 shows the results of sensory evaluation of the resulting vitamin C derivative-containing cream.
- Table 60 shows the following: It was confirmed that the cream containing vitamin C derivative of Example 29 imparted moisturizing feeling, adhesion and flexibility to the skin and maintained the film feeling for a long time. It was confirmed that the vitamin C derivative-containing cream of Example 29 was superior in effect to the vitamin C derivative-containing cream of Comparative Example 30.
- Eye creams having the composition shown in Table 61 were produced by the following method.
- Raw materials 1 to 8 were dissolved and mixed at 80 ° C. to obtain a mixture (A).
- the raw materials 9 to 14 were mixed and heated to 80 ° C., added to the mixture (A), treated with a homomixer and cooled to obtain an eye cream.
- Table 62 shows the results of sensory evaluation for each.
- Example 30 imparted softness to the skin and maintained a moisturizing feeling for a long time. In addition, it was confirmed that the eye cream of Example 30 was superior in effect in terms of spreading, moisturizing feeling and flexibility as compared with the eye cream of Comparative Example 31.
- Conditioning shampoos with the formulations shown in Table 63 were produced by the following method.
- Raw material 8 was added to raw material 12, heated to 70 ° C. with heating and stirring. To this, other ingredients were added, dissolved by stirring, and cooled to obtain a conditioning shampoo. Table 64 shows the results of sensory evaluation of each.
- Table 64 shows the following.
- the conditioning shampoo of Example 31 was found to impart a moisturizing feeling, gloss, flexibility and a feeling of hair unity to the hair. In addition, it was confirmed that the conditioning shampoo of Example 31 was superior to the conditioning shampoo of Comparative Example 32 in any of moisturizing feeling, gloss, flexibility, and unity.
- Cuticle protection jewel steelmaking Cuticle protection jewels having the formulations shown in Table 65 were produced in the following manner.
- Raw materials 1 to 5 were uniformly mixed to obtain a mixture (A).
- the raw materials 6 to 10 and the raw material 12 were uniformly mixed to obtain a mixture (B).
- the mixture (B) was mixed while adding the mixture (A), and then the raw material 11 was added and mixed uniformly to obtain a cuticle protection jewel.
- Table 66 shows the results of sensory evaluation.
- Table 66 shows the following.
- the cuticle protection jewel of Example 32 was found to give the hair flexibility, moisturizing feeling, luster and a feeling of hair cohesion.
- the cuticle protection jewel of Example 32 is more flexible and moisturized than the cuticle protection jewel of Comparative Example 33. It was confirmed that the effect of feeling of unity of gloss and hair was excellent.
- a hair rinse having the composition shown in Table 67 was produced by the following method.
- Raw materials 1 to 5 were uniformly mixed and dissolved to obtain a mixture (A).
- the raw materials 6 to 9 and the raw material 11 were uniformly mixed and dissolved to obtain a mixture (B).
- a mixture (B) By heating the mixture (A) and (B) to 80 ° C and adding and emulsifying the mixture (A) to the mixture (B) at a temperature of 80 ° C, adding the raw material 10 and mixing, A hair rinse was obtained.
- Table 68 shows the results of sensory evaluation of each.
- Table 68 shows the following: The hair rinse of Example 33 was found to give the hair flexibility, moisturizing feeling, gloss, and a feeling of hair unity. In addition, it was confirmed that the hair rinse of Example 33 was superior to the hair rinse of Comparative Example 34 in the effects of flexibility, moisturizing feeling, gloss and hair feeling.
- a hair conditioner having the formulation shown in Table 69 was produced by the following method.
- Raw materials 1 to 7 were mixed and dissolved uniformly to obtain a mixture (A).
- the raw materials 8 to 11 and the raw material 13 were uniformly mixed and dissolved to obtain a mixture (B).
- a mixture (B) By heating the mixture (A) and (B) to 80 ° C and adding and emulsifying the mixture (A) to the mixture (B) at a temperature of 80 ° C, adding the raw material 12 and mixing.
- Got a hair conditioner Table 70 shows the results of sensory evaluation for each.
- Table 70 shows the following.
- the hair conditioner of Example 34 was found to give the hair flexibility, moisturizing feeling, luster and a feeling of hair unity. In addition, it was confirmed that the hair conditioner of Example 34 was superior to the hair conditioner of Comparative Example 35 in terms of the effects of flexibility, moisturizing feeling, gloss, and hair feeling.
- a hair cream having the composition shown in Table 71 was produced by the following method.
- Raw materials 1 to 5 were uniformly mixed and dissolved to obtain a mixture (A).
- Raw materials 6 to 10 and raw material 12 were mixed and dissolved uniformly to obtain a mixture (B).
- the mixture (A) and (B) was heated to 80 ° C, and after the mixture (B) was added to the mixture (A) and emulsified at a temperature of 80 ° C, the raw material 11 was added and cooled to obtain hair. A cream was obtained.
- Table 72 shows the results of sensory evaluation for each.
- Table 72 shows the following.
- Example 35 gave the hair flexibility, moisturizing feeling, gloss, and a feeling of hair unity. In addition, it was confirmed that the hair cream of Example 35 was superior to the hair cream of Comparative Example 36 in the effects of flexibility, moisturizing feeling, gloss and hair feeling.
- Hair waxes having the composition shown in Table 73 were produced by the following method.
- Raw materials 1 to 9 were mixed and dissolved uniformly to obtain a mixture (A).
- the raw materials 10, 11, 13, and 14 were uniformly mixed and dissolved to obtain a mixture (B).
- Mixtures (A) and (B) are heated to 80 ° C, and after mixture (A) is added and emulsified to mixture (B) at a temperature of 80 ° C, raw material 12 is added and mixed. Thus, a hair wax was obtained.
- Table 74 shows the results of sensory evaluation for each.
- Nnic acid condensate 1. 0 1. 0
- Table 74 shows the following.
- the hair wax of Example 36 was found to give the hair flexibility, moisturizing feeling, gloss, and a feeling of hair unity. In addition, the hair wax of Example 36 is superior to the hair wax of Comparative Example 37 in the effects of flexibility, moisturizing feeling, gloss and hair feeling. It was confirmed that
- Multi-layer emulsified sunscreen (W / O type)
- Raw materials 1 to 12 produced by the following method of multilayer emulsion sunscreen (WZO type) having the composition shown in Table 75 were uniformly mixed to obtain a mixture (A).
- the raw materials 13 to 16 were uniformly mixed to obtain a mixture (B).
- the mixture (B) was added to the mixture (A) and emulsified.
- the emulsified product was filled into a resin bottle containing stainless balls to obtain a multilayer emulsified sunscreen (WZO type).
- Table 76 shows the results of sensory evaluation for each.
- Table 76 shows the following.
- the multilayer emulsified sunscreen (WZO type) of Example 37 is excellent in adhesion to the skin and film feeling (uniformity of makeup film), and can maintain makeup for a long time. Admitted.
- the multilayer emulsified sunscreen (WZO type) of Example 37 has a difference in adhesion and film feeling compared to the multilayer emulsified sunscreen (WZO type) of Comparative Example 38! The effect was excellent and the duration of makeup was long.
- a creamy sunscreen (OZW type) with the formulation shown in Table 77 was produced by the following method.
- Raw materials 1 to 11 were heated to 70 ° C and mixed uniformly to obtain a mixture (A).
- the raw materials 13 to 17 were heated to 70 ° C. and mixed uniformly to obtain a mixture (B).
- the mixture (B) is added to the mixture (E) to emulsify, and the resulting emulsion is cooled to room temperature, and then the raw material 12 is added and mixed to form a cream sunscreen (OZW type).
- Got. Table 78 shows the results of sensory evaluation for each.
- Titanium oxide 1 0. 0 1 0. 0
- Table 78 shows the following.
- the creamy sunscreen (OZW type) of Example 38 was excellent in adhesion to the skin and film feeling (uniformity of the makeup film) and could maintain the makeup for a long time. It was.
- the creamy sunscreen (OZW type) of Example 38 is more effective than the creamy sunscreen (OZW type) of Comparative Example 39 in the difference in adhesion and film feeling! It was excellent and the duration of makeup was long.
- Example 39 and Comparative Example 40 Notice of latex sunscreen (w / o type)
- An emulsion sunscreen (WZO type) with the formulation shown in Table 79 was produced by the following method. In order to dissolve the raw material 5, raw materials 1 and 5 were mixed and dissolved by heating. After the raw materials 1 and 5 were heated and dissolved, the raw materials 2 to 4 and 6 to 16 were added and mixed uniformly to obtain a mixture (A). On the other hand, the raw materials 17 and 18 were uniformly mixed to obtain a mixture (B). Next, the mixture (B) was added to the mixture (A) and emulsified to obtain an emulsion sunscreen (WZO type). Table 80 shows the results of sensory evaluation for each.
- Table 80 shows the following.
- the emulsion sunscreen (WZO type) of Example 39 was excellent in adhesion to the skin and film feeling (homogeneity of the cosmetic film) and could maintain makeup for a long time.
- the emulsion sunscreen (WZO type) of Example 39 is superior in both adhesion and film feeling compared to the emulsion sunscreen (WZO type) of Comparative Example 40.
- the makeup time was long.
- the solubility was improved by mixing 4-tert-butyl 4, -methoxydibenzoylmethane, which has poor solubility, with the ester ester reaction product (Production Example 1).
- a creamy sunscreen (WZO type) with the formulation shown in Table 81 was produced by the following method.
- Raw materials 1 to 7 were mixed uniformly to obtain a mixture (A).
- the raw materials 8 to 11 were uniformly mixed to obtain a mixture (B).
- the mixture (B) was added to the mixture (A) and emulsified to obtain a creamy sunscreen (WZO type).
- Table 82 shows the results of sensory evaluation for each.
- the SPF value was measured using UV-1000F manufactured by Labsphere. The measured SPF value was evaluated according to the following evaluation criteria.
- ⁇ : SPF is 20 or more.
- ⁇ : SPF is 10 or more and less than 20.
- X: SPF is less than 10.
- the stability over time was evaluated according to the following criteria by keeping the cream sunscreen at 50 ° C for 1 month and visually observing changes in appearance. A case where the evaluation was ⁇ or ⁇ was considered acceptable.
- Table 82 shows the following.
- the creamy sunscreens of Examples 40, 41 and 42 were found to be excellent in durability, adhesion to the skin, film feeling (uniformity of makeup film) and high SPF value. It was. In addition, the creamy sunscreens (WZO type) of Examples 40, 41 and 42 have better adhesion, film feel, sustainability and SPF value than the creamy sunscreens (WZO type) of Comparative Example 41. The effect is excellent in any case.
- a stick-like oil type concealer having the composition shown in Table 83 was produced by the following method.
- Raw materials 8 to 15 were heated to 70 ° C and mixed uniformly to obtain a mixture (A).
- the raw materials 1 to 7 and the raw material 16 were added to the obtained mixture (A) and mixed uniformly to obtain a mixture (B).
- the resulting mixture (B) was heated again and degassed.
- the defoamed product was filled into a stick container and cooled to room temperature to obtain a stick-like oil-type concealer.
- Table 84 shows the results of sensory evaluation.
- Table 84 shows the following.
- the stick-like oil-type concealer of Example 43 was found to be excellent in color development, adhesion to the skin, and film feeling (uniformity of the makeup film) and capable of maintaining makeup for a long time. It was. In addition, the stick-like oil-type concealer of Example 43 is superior to the stick-like oil-type concealer of Comparative Example 42 in terms of color development, adhesion, and film feeling. The duration of was long.
- a body soap having the formulation shown in Table 85 was produced by the following method.
- Table 86 shows the following.
- the body soap of Example 44 was found to be excellent in cleanability and impart softness, moisturizing feeling and gloss to the skin after use. In addition, it was confirmed that the body soap of Example 44 was superior to the body soap of Comparative Example 43 in terms of flexibility, moisturizing feeling, gloss and cleanability.
- a powdered body powder having the composition shown in Table 87 was produced by the following method.
- Raw materials 3 to 6 were mixed and dispersed uniformly to obtain a mixture (A).
- Table 88 shows the following.
- Example 45 was excellent in adhesion to the skin and spread, and could maintain makeup for a long time.
- the powdery body powder of Example 45 is more effective than the powdery body powder of Comparative Example 44 in terms of adhesion, spread V, and misalignment. It was long.
- Water-in-oil hand creams having the composition shown in Table 89 were produced by the following method.
- Raw material 1 or 2 and raw materials 3 to 7 were mixed, then raw material 8 was added and dispersed with a despa mixer to obtain a mixture (A).
- the remaining ingredients were uniformly mixed and dispersed while being added to the mixture (A) to obtain a water-in-oil type hand cream.
- Table 90 shows the results of sensory evaluation for each.
- Table 90 shows the following.
- Example 46 imparted adhesion, moisturizing feeling and flexibility to the skin and maintained the film feeling for a long time. It was confirmed that the water-in-oil hand cream of Example 46 was superior in effect to the water-in-oil hand cream of Comparative Example 45.
- FIG. 1 is a graph showing the results of a water retention test 2 of the esterification reaction product obtained in Production Example 1.
- FIG. 2 is a graph showing the results of the water retention test 2 of the esterification reaction product obtained in Production Example 2. It is.
- FIG. 4 is a graph showing the results of a water hydration test 2 of liquid lanolin.
- FIG. 5 is a graph showing the results of hydrate test 2 of cholesteryl hydroxystearate.
- FIG. 6 is a graph showing the results of a water retention test 2 of diisostearyl malate.
- FIG. 7 is a graph showing the evaluation results of oxidation stability (CDM test).
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
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ES06712394T ES2400192T3 (es) | 2005-01-28 | 2006-01-26 | Producto de reacción de esterificación y producto cosmético |
EP06712394A EP1857433B1 (en) | 2005-01-28 | 2006-01-26 | Esterification reaction product and cosmetic |
US11/883,116 US7632957B2 (en) | 2005-01-28 | 2006-01-26 | Esterification reaction products and cosmetic products |
CN2006800028829A CN101107214B (zh) | 2005-01-28 | 2006-01-26 | 酯化反应生成物和化妆品 |
JP2006522578A JP5395325B2 (ja) | 2005-01-28 | 2006-01-26 | エステル化反応生成物及び化粧料 |
KR1020077017529A KR101141856B1 (ko) | 2005-01-28 | 2006-01-26 | 에스테르화 반응 생성물 및 화장료 |
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JP2005-021095 | 2005-01-28 | ||
JP2005021095 | 2005-01-28 | ||
JP2005170370 | 2005-06-10 | ||
JP2005-170370 | 2005-06-10 | ||
JP2005-255030 | 2005-09-02 | ||
JP2005255030 | 2005-09-02 | ||
JPPCT/JP2005/018856 | 2005-10-13 | ||
JP2005018856 | 2005-10-13 |
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WO2006080389A1 true WO2006080389A1 (ja) | 2006-08-03 |
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US (1) | US7632957B2 (ja) |
EP (1) | EP1857433B1 (ja) |
JP (2) | JP5395325B2 (ja) |
KR (1) | KR101141856B1 (ja) |
CN (1) | CN101107214B (ja) |
ES (1) | ES2400192T3 (ja) |
WO (1) | WO2006080389A1 (ja) |
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Also Published As
Publication number | Publication date |
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JPWO2006080389A1 (ja) | 2008-06-19 |
JP2013010787A (ja) | 2013-01-17 |
KR20070104374A (ko) | 2007-10-25 |
EP1857433A1 (en) | 2007-11-21 |
CN101107214B (zh) | 2011-01-12 |
CN101107214A (zh) | 2008-01-16 |
KR101141856B1 (ko) | 2012-05-08 |
EP1857433B1 (en) | 2013-01-09 |
ES2400192T3 (es) | 2013-04-08 |
JP5395325B2 (ja) | 2014-01-22 |
JP5584742B2 (ja) | 2014-09-03 |
EP1857433A4 (en) | 2008-05-14 |
US7632957B2 (en) | 2009-12-15 |
US20080260663A1 (en) | 2008-10-23 |
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