WO2006071069A1 - Bactericidal detergent composition - Google Patents

Bactericidal detergent composition Download PDF

Info

Publication number
WO2006071069A1
WO2006071069A1 PCT/KR2005/004599 KR2005004599W WO2006071069A1 WO 2006071069 A1 WO2006071069 A1 WO 2006071069A1 KR 2005004599 W KR2005004599 W KR 2005004599W WO 2006071069 A1 WO2006071069 A1 WO 2006071069A1
Authority
WO
WIPO (PCT)
Prior art keywords
silver
nano
detergent composition
composition
fatty acid
Prior art date
Application number
PCT/KR2005/004599
Other languages
English (en)
French (fr)
Inventor
Hee Cheol Yu
Seong Bae Kim
Seok Kim
Min Young Oh
Yong Hwan Kim
Original Assignee
Gaia Infonet Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gaia Infonet Co., Ltd. filed Critical Gaia Infonet Co., Ltd.
Publication of WO2006071069A1 publication Critical patent/WO2006071069A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/1206Water-insoluble compounds free metals, e.g. aluminium grit or flakes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00Manufacture or treatment of nanostructures
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/667Neutral esters, e.g. sorbitan esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides

Definitions

  • the present invention relates, in general, to a detergent composition for use in washing food, such as vegetables, fruits, fish, etc., cookers, tableware, food processing devices, food cooking machines and so on.
  • the present invention relates to a detergent composition including food and a food additive, which is thus highly safe and has high detergent efficiency, and as well, further including nano-silver, resulting in exhibiting superb bactericidal and germicidal activity while having high storage stability in spite of using nano-silver.
  • the present invention relates to a detergent composition composed mainly of sugar and a food emulsifier as food additives, which is advantageous because of having high biodegradability and harmlessness to human beings, in which the detergent composition further includes nano-silver to manifest superb bactericidal and germicidal activity while being highly stable in spite of using nano-silver.
  • a detergent for use in washing tableware, cookers, food processing devices and food manufacturing machines is composed of an anionic surfactant including aromatic or aliphatic sulfonate, or a nonionic surfactant including sucrose fatty acid ester or polyglycerin fatty acid ester, allowed as a food emulsifier.
  • the detergent consisting mainly of an anionic surfactant of alkylbenzene sulfonate has high detergence, but low rinsability. Also, in cases where such a detergent is adsorbed by food or tableware, it is poisonous to human beings and causes skin irritation. Moreover, the above detergent generates environmental pollution problems, attributed to insufficient biodegradability, therefore being undesirable to use.
  • a detergent consisting essentially of sugar or sucrose fatty acid ester, polyglycerin fatty acid ester, and sorbitan fatty acid ester, having high HLB (Hydrophobic Lipophilic Balance) value, in consideration of emulsification action, washing and solubilization actions of conventional anionic surfactants.
  • HLB Hydrophilic Balance
  • a detergent composition comprises an aqueous germicidal solution of a chlorine compound such as sodium hypochlorate, hydrogen peroxide and ozone.
  • a chlorine compound such as sodium hypochlorate, hydrogen peroxide and ozone.
  • an organic acid of citric acid or sorbic acid, or a salt thereof, or silver ion and silver ion-impregnated zeolite is used as a constitutive component of the above detergent composition, thereby providing bactericidal and germicidal activity to the composition.
  • a silver ion reacts with a chlorine ion or a calcium ion to form an insoluble salt, thus losing bactericidal activity.
  • silver may be immiscible with the detergent composition when stored for a long time, and may cause discoloration by light, or precipitation.
  • silver is known to exhibit bactericidal and germicidal actions, and is reported to have germicidal activity to about 650 species of pathogens. Also, it is known that silver can exhibit high bactericidal and germicidal activity similar to ozone, hydrogen peroxide and chlorine, by producing active oxygen due to a catalytic effect on oxygen.
  • Japanese Patent Laid-open Publication No. Sho. 50-39707 discloses a detergent composition composed mainly of sucrose fatty acid ester and glycerin mono fatty acid ester.
  • Japanese Patent Laid-open Publication No. Hei. 10-158690 discloses a detergent composition including caprylic acid monoglycerin, sucrose fatty acid monoester, and a builder, which is advantageous because of having high safety, detergent efficiency and storage stability.
  • bactericidal activity is not mentioned.
  • Japanese Patent Laid-open Publication No. 2002-294286 discloses a bactericidal detergent composition consisting mainly of an organic acid, a salt thereof, and polyglycerin fatty acid ester, suitable for use in washing food and cookers.
  • Korean Patent Laid-open Publication No. 2003-0051958 discloses a liquid detergent composition for kitchen use including two or more kinds of organic acids to manifest germicidal effects.
  • the above detergent composition is used at a typical dilution ratio, it is difficult to obtain sufficient bactericidal effects.
  • Korean Patent Laid-open Publication No. 2003-0083038 discloses a bactericidal detergent composition containing a solution of silver ions obtained by electrolysis.
  • the composition may be discolored or precipitated by silver ions, depending on the constitutive components thereof.
  • a definite constitutive example for the detergent composition should be provided, nowhere does the above invention mention such an example, so that high stability and desirable bactericidal effects are hardly attained. Disclosure of Invention Technical Problem
  • an object of the present invention is to provide a detergent composition, which is harmless to human beings even when remaining on food, such as vegetables or fruits, cookers, or tableware, and has high foaming power, detergence, rinsability and biodegradability and low skin irritation, and exhibits superb bactericidal and germicidal activity due to nano-silver while being highly stable in spite of using nano-silver.
  • the present invention provides a bactericidal detergent composition, which comprises, based on the total weight of the composition,
  • a weight ratio of the components (b) and (c) to the component (d) is in a range of 200-22,000.
  • the component (b) is a nonionic surfactant including fatty acid alkanol amide, and the component (c) is mono-ester.
  • nano-silver of the component (d) is present in particulate form.
  • nano-silver of the component (d) has an average size of 3-10 nm.
  • the balance wt% that is not given includes water, and typical additives, such as a skin moisturizing agent, a colorant, aromatic agents, etc. Best Mode for Carrying Out the Invention
  • the present invention provides a bactericidal detergent composition, which is composed mainly of three kinds of nonionic surfactants and nano-silver.
  • a first nonionic surfactant includes alkyl glucoside, which is an ester compound composed of a sugar component obtained from corn and an oil component obtained from coconut oil, and is exemplified by lauryl glycoside, decyl glycoside, etc, having a fatty acid moiety of 8-14 carbons.
  • a second nonionic surfactant includes any one selected from among fatty acid alkanol amide, alkyl ethoxylate, and amine oxide.
  • fatty acid alkanol amide is used.
  • a third nonionic surfactant includes sucrose fatty acid ester containing mono- through octa-ester, depending on the degree of esterification of corresponding fatty acid.
  • mono-ester is preferably used.
  • This nonionic surfactant is exemplified by sucrose lauric acid ester, sucrose mono palmitic acid ester, sucrose stearic acid ester, sucrose oleic acid ester, etc.
  • Nano-silver has a particle size of 3-20 nm, and preferably, 3-10 nm, and is used in an amount of 10-100 ppm. As well, nano-silver is used in a colloidal form of metal silver. It is preferable that silver be present in the state of metal nano-particles finely dispersed in the composition, not in its ionic state. The reason why silver ions are not used is that silver ions are highly reactive, and thus, it is difficult to sustain bactericidal activity.
  • Methods of preparing metal nano-silver and a colloidal solution containing the same may be unlimitedly applied to the present invention as if they are widely known in the art. For example, electrolysis, electric reduction, pyrolysis, alcohol reduction, or irradiation methods may be used.
  • the first nonionic surfactant is used in an amount of 5-30 wt%
  • the second and the third nonionic surfactants are used in amounts of 1-10 wt% and 1-10 wt%, respectively, based on the total weight of the detergent composition.
  • a weight ratio of the second and third nonionic surfactants to nano-silver is in a range of 200-22,000, in which the second nonionic surfactant includes any one selected from among fatty acid alkanol amide, alkyl ethoxylate, and amine oxide, and preferably, fatty acid alkanol amide, and the third nonionic surfactant includes sucrose fatty acid ester, and preferably, mono-ester. If the above weight ratio is less than 200, it is difficult to ensure stability of the detergent composition, attributed to discoloration or precipitation by nano-silver. Contrarily, if the weight ratio exceeds 22,000, stability of the detergent composition may be assured, however other effects cannot be expected.
  • nano-silver is used in an amount of 10-100 ppm.
  • desired bactericidal effects cannot be obtained at an actually used dilution ratio.
  • nano-silver is used in an amount larger than 100 ppm, bactericidal effects may increase in proportion to an increase in the amount of nano-silver, but discoloration and precipitation are caused in the detergent composition, thus reducing the stability of the composition, and the preparation costs of the composition increase.
  • nano- silver should have a particle size of 3 to 20 nm, and preferably, 3 to 10 nm.
  • typical additives such as a phase stabilizer, a skin moisturizing agent, a colorant, an aromatic agent, etc., may be used in predetermined amounts, if required, so long as they do not negatively affect bactericidal effects of the detergent composition of the present invention.
  • Tables 1 and 2 was diluted to a 0.25% aqueous detergent composition solution. 20 ml of the aqueous solution were loaded into a glass mass cylinder having an inner diameter of 30 mm, and then, the cylinder was shaken 30 times upward and downward, to produce foam. After 10 sec, the volume of foam was measured. The above experiment was repeated 3 times, and the resultant values were averaged and then classified on the basis of the following categories:
  • [50] x less than 20 ml.
  • a sponge was wet with 2.5 ml of each crude detergent composition and then manually squeezed to generate foam. The number of squeezes required to form sufficient foam was counted. This experiment was repeated 3 times, and the resultant values were averaged and then classified on the basis of the following categories:
  • a sponge was wet with 2.5 ml of each crude detergent composition, and manually squeezed 10 times to generate sufficient foam. Until the generated foam disappeared, the sponge was repeatedly rinsed with the same predetermined amount of water. The number of cycles of the water was counted, and the resultant values were classified on the basis of the following categories:
  • Each crude detergent composition was allowed to stand at 5, 25 and 40 C for 1 month. Thereafter, the outer appearance of the detergent composition, for example, discoloration, separation, precipitation, transparency, etc., was observed, and the results thereof were classified on the basis of the following categories. Further, after each crude detergent composition was allowed to stand under a direct ray of light for 1 month, the outer appearance of the detergent composition was observed, and the results thereof were classified on the basis of the following categories:
  • Bacillus sp. CK-I used as a standard strain, was inoculated into a nutrient meat medium (Difco), and then shake-cultured at 37 C and 150 rpm for 18 hours. If necessary, the number of strains was controlled by dilution. To assay the bactericidal activity of each detergent composition, the detergent composition was diluted 10 times, 50 times and 100 times (v/v) with purified water. 50 ml of a culture of Bacillus sp. CK- 1 was uniformly smeared on the prepared meat nutrient solid medium, after which 20 ml of the diluted detergent composition was quantitatively dropped at regular intervals on the meat nutrient solid medium smeared with Bacillus sp. CK-I, and then cultured at 37 C for 24 hours. Thereby, the sizes of bacterial growth inhibition circles were compared, and then the results thereof were classified on the basis of the following categories:
  • [70] x 50% or less of the bacteria were killed, or there was no bactericidal activity.
  • the bactericidal detergent composition of the present invention has high foaming power, rinsability, stability, and bactericidal activity.
  • the present invention provides a bactericidal detergent composition, which comprises three kinds of nonionic surfactants and nano-silver mixed at a predetermined ratio, thus maximizing the infiltration capacity, emul- sification capacity and dispersibility. Further, nano-silver contained in the detergent composition manifests high bactericidal activity, while the detergent composition can be highly stable without discoloration, precipitation or separation, in spite of using nano-silver. Thereby, the detergent composition of the present invention has high foaming power, detergence, rinsability, stability, harmlessness and bactericidal activity.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Nanotechnology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
PCT/KR2005/004599 2004-12-29 2005-12-28 Bactericidal detergent composition WO2006071069A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-2004-0115225 2004-12-29
KR1020040115225A KR100519889B1 (ko) 2004-12-29 2004-12-29 항균 세정제 조성물

Publications (1)

Publication Number Publication Date
WO2006071069A1 true WO2006071069A1 (en) 2006-07-06

Family

ID=36615151

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2005/004599 WO2006071069A1 (en) 2004-12-29 2005-12-28 Bactericidal detergent composition

Country Status (2)

Country Link
KR (1) KR100519889B1 (ko)
WO (1) WO2006071069A1 (ko)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010084057A1 (de) * 2009-01-22 2010-07-29 Henkel Ag & Co. Kgaa Handgeschirrspülmittel mit antibakterieller wirkung
WO2011046610A1 (en) * 2009-10-14 2011-04-21 S. C. Johnson & Son, Inc. Green compositions containing synergistic blends of surfactants and linkers
WO2011046611A1 (en) * 2009-10-14 2011-04-21 S. C. Johnson & Son, Inc. Green disinfection/sanitization compositions and processes of making thereof
WO2011062647A1 (en) * 2009-11-23 2011-05-26 S. C. Johnson & Son, Inc. Water-activated eco - friendly multi - functional wi pe
CN102895315A (zh) * 2012-09-28 2013-01-30 南昌大学 一种含连翘提取液的纳米银抑菌组合物
CN104046525A (zh) * 2014-04-25 2014-09-17 天津天狮生物发展有限公司 一种塑料餐具洗洁精及其制备方法
CN104327961A (zh) * 2014-10-09 2015-02-04 四川绿洁科技有限公司 一种纯天然型餐具、果蔬洗涤剂及其制备工艺

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100720130B1 (ko) * 2005-10-31 2007-05-18 화인폴리머 주식회사 나노실버가 함유된 항균 세정제 및 그 제조방법
KR100731556B1 (ko) 2005-12-08 2007-06-22 김영남 상자성 은 나노 입자를 함유한 세제 조성물
KR101507763B1 (ko) 2013-04-22 2015-04-08 한국생산기술연구원 수계 세정제 조성물 및 그 조성물을 이용한 세정방법
KR101507766B1 (ko) * 2013-04-22 2015-04-08 한국생산기술연구원 생분해성이 우수한 세정제 조성물
KR101705761B1 (ko) * 2014-11-13 2017-02-22 이주호 무독성 자동식기세척기용 중성 액상 세제 조성물

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001172696A (ja) * 1999-12-17 2001-06-26 Lion Corp 液体洗浄剤組成物
JP2001172697A (ja) * 1999-12-17 2001-06-26 Lion Corp 液体洗浄剤組成物
KR20030044987A (ko) * 2003-05-22 2003-06-09 넵테크놀로지주식회사 나노 크기의 입자가 첨가 된 액상 세탁 세제의 제조 방법
KR20030094978A (ko) * 2002-06-11 2003-12-18 (주)아쿠아렉스 트레할로스와 은을 함유하는 투명비누 조성물

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR960014360B1 (ko) * 1994-10-07 1996-10-15 최승 고기능성 세정 조성물 및 그 제조방법
JPH093492A (ja) * 1995-06-22 1997-01-07 Nichiban Kenkyusho:Kk 洗剤用組成物
JPH09183997A (ja) * 1995-12-28 1997-07-15 Lion Corp 洗浄剤組成物
KR19980087633A (ko) * 1998-09-04 1998-12-05 강남석 은비누 제조방법

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001172696A (ja) * 1999-12-17 2001-06-26 Lion Corp 液体洗浄剤組成物
JP2001172697A (ja) * 1999-12-17 2001-06-26 Lion Corp 液体洗浄剤組成物
KR20030094978A (ko) * 2002-06-11 2003-12-18 (주)아쿠아렉스 트레할로스와 은을 함유하는 투명비누 조성물
KR20030044987A (ko) * 2003-05-22 2003-06-09 넵테크놀로지주식회사 나노 크기의 입자가 첨가 된 액상 세탁 세제의 제조 방법

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010084057A1 (de) * 2009-01-22 2010-07-29 Henkel Ag & Co. Kgaa Handgeschirrspülmittel mit antibakterieller wirkung
WO2011046610A1 (en) * 2009-10-14 2011-04-21 S. C. Johnson & Son, Inc. Green compositions containing synergistic blends of surfactants and linkers
WO2011046611A1 (en) * 2009-10-14 2011-04-21 S. C. Johnson & Son, Inc. Green disinfection/sanitization compositions and processes of making thereof
US8283304B2 (en) 2009-10-14 2012-10-09 S.C. Johnson & Son, Inc. Green compositions containing synergistic blends of surfactants and linkers
US8778860B2 (en) 2009-10-14 2014-07-15 S.C. Johnson & Son, Inc. Green disinfection/sanitization compositions and processes of making thereof
WO2011062647A1 (en) * 2009-11-23 2011-05-26 S. C. Johnson & Son, Inc. Water-activated eco - friendly multi - functional wi pe
CN102834038A (zh) * 2009-11-23 2012-12-19 约翰逊父子公司 水激活环保型多功能抹布
US8541356B2 (en) 2009-11-23 2013-09-24 S.C. Johnson & Son, Inc. Water-activated “green” multi-functional wipe
CN102895315A (zh) * 2012-09-28 2013-01-30 南昌大学 一种含连翘提取液的纳米银抑菌组合物
CN104046525A (zh) * 2014-04-25 2014-09-17 天津天狮生物发展有限公司 一种塑料餐具洗洁精及其制备方法
CN104327961A (zh) * 2014-10-09 2015-02-04 四川绿洁科技有限公司 一种纯天然型餐具、果蔬洗涤剂及其制备工艺
CN104327961B (zh) * 2014-10-09 2017-05-17 四川绿洁科技有限公司 一种餐具、果蔬洗涤剂及其制备工艺

Also Published As

Publication number Publication date
KR100519889B1 (ko) 2005-10-10

Similar Documents

Publication Publication Date Title
WO2006071069A1 (en) Bactericidal detergent composition
EP2718411B1 (en) Sophorolactone compositions and uses thereof
AU665229B2 (en) Composition containing allyl isothiocyanate and its use
CN111569683A (zh) 一种高浓度长效臭氧纳米气泡水溶液及制备方法
KR102066686B1 (ko) 과량의 전해질을 포함하는 액체 세정제 조성물
JP2012020938A (ja) インフルエンザウイルス感染を予防するための泡立性の抗菌手洗い洗浄剤
JP2015078133A (ja) 抗菌性組成物
CA2803574A1 (en) Disinfecting and sterilising solutions
CN105154249B (zh) 一种抑菌杀菌型织物用液体洗涤剂及其制备方法
JP4108067B2 (ja) 泡状殺菌・消毒・清浄剤用の組成物
EP1411892B1 (en) Aqueous narceous concentrate compositions comprising ethoxylated glycerides
KR102488475B1 (ko) 다목적 수계 세정제 조성물
CN114561256B (zh) 一种抑菌洗涤剂组合物
KR102199015B1 (ko) 탈취성 및 살균성이 우수한 소독제 조성물 및 그 제조방법
JP5300759B2 (ja) 抗菌性液体組成物
WO2012153741A1 (ja) ヨウ素-β-シクロデキストリン包接化合物溶液
JP4194977B2 (ja) 殺菌方法及び殺菌用組成物
JP2022502542A (ja) 固体表面の汚染を除去するための組成物
JP2001354506A (ja) 水中油型乳剤
CN1403558A (zh) 杀菌型洗洁精及其生产方法
JP2019156820A (ja) トマト果実の成長促進剤およびトマト果実中の機能性成分含有量向上剤、ならびに、トマト果実の成長促進剤およびトマト果実中の機能性成分含有量向上剤の製造方法
KR101953189B1 (ko) 고형 과채세정제 및 그 제조방법
JP3228563B2 (ja) 水中油型乳剤
JPH0429913A (ja) パール外観を有する化粧料
US20220338476A1 (en) Non-toxic, alcohol-free disinfectant and sanitizing composition

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
NENP Non-entry into the national phase

Ref country code: DE

32PN Ep: public notification in the ep bulletin as address of the adressee cannot be established

Free format text: NOTING LOSS OF RIGHTS PURSUANT TO RULE 112(1)EPC,EPO FORM 1205A DATED 11/09/2007

122 Ep: pct application non-entry in european phase

Ref document number: 05822434

Country of ref document: EP

Kind code of ref document: A1