WO2005031063A1 - ゴム補強用コードおよびその製造方法ならびにそれを用いたゴム製品 - Google Patents
ゴム補強用コードおよびその製造方法ならびにそれを用いたゴム製品 Download PDFInfo
- Publication number
- WO2005031063A1 WO2005031063A1 PCT/JP2004/013795 JP2004013795W WO2005031063A1 WO 2005031063 A1 WO2005031063 A1 WO 2005031063A1 JP 2004013795 W JP2004013795 W JP 2004013795W WO 2005031063 A1 WO2005031063 A1 WO 2005031063A1
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- WIPO (PCT)
- Prior art keywords
- cord
- strands
- rubber
- strand
- twisting
- Prior art date
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Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/48—Tyre cords
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B1/00—Constructional features of ropes or cables
- D07B1/06—Ropes or cables built-up from metal wires, e.g. of section wires around a hemp core
- D07B1/0606—Reinforcing cords for rubber or plastic articles
- D07B1/062—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration
- D07B1/064—Reinforcing cords for rubber or plastic articles the reinforcing cords being characterised by the strand configuration the reinforcing cords being twisted and with at least one wire exchanging place with another wire
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/10—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres
- B29C70/16—Fibrous reinforcements only characterised by the structure of fibrous reinforcements, e.g. hollow fibres using fibres of substantial or continuous length
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/16—Yarns or threads made from mineral substances
- D02G3/18—Yarns or threads made from mineral substances from glass or the like
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/10—Rope or cable structures
- D07B2201/104—Rope or cable structures twisted
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2201/00—Ropes or cables
- D07B2201/10—Rope or cable structures
- D07B2201/104—Rope or cable structures twisted
- D07B2201/1044—Rope or cable structures twisted characterised by a value or range of the pitch parameter given
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2205/00—Rope or cable materials
- D07B2205/30—Inorganic materials
- D07B2205/3003—Glass
-
- D—TEXTILES; PAPER
- D07—ROPES; CABLES OTHER THAN ELECTRIC
- D07B—ROPES OR CABLES IN GENERAL
- D07B2501/00—Application field
- D07B2501/20—Application field related to ropes or cables
- D07B2501/2046—Tire cords
Definitions
- the present invention relates to a rubber reinforcing cord, a method of manufacturing the same, and a rubber product using the same.
- the present invention relates to a reinforcing cord for reinforcing rubber, a method for manufacturing the same, and a rubber product using the same.
- reinforcing cords using reinforcing fibers such as glass fiber peramide fibers are used.
- Rubber reinforcement cords are required to have bending fatigue resistance (flexibility to bending), high strength and dimensional stability.
- rubber products such as rubber belts are repeatedly subjected to bending stress, and their performance is likely to deteriorate due to bending fatigue.
- Such a decrease in performance causes peeling between the reinforcing material and the rubber matrix, a decrease in strength due to abrasion of the reinforcing fibers, and a decrease in mastication. Therefore, bending fatigue resistance is important for the rubber reinforcing cord.
- twisting methods There are two types of twisting methods, namely, Moro twisting and Lang twisting, as a method of adding a bottom twist and a top twist to a strand.
- Moro twist the direction of the lower twist and the direction of the upper twist are different.
- Lang twist the direction of the lower twist and the direction of the upper twist are the same.
- Lang twist has the advantage that the resistance to bending is low and the flexibility is high compared to Moro twist, so that the bending fatigue resistance of the cord is improved! For this reason, Lang twist is often used for twist cords using organic fibers and the like.
- the bending fatigue resistance is greatly improved, but since the twisting directions of the lower twist and the upper twist are the same, the untwisting of the cord and the self-twisting are performed. Involvement of spontaneous codes is likely to occur.
- the twisting of the cord means that, for example, when the cord is buried in the shape of a coil in an endless belt-shaped rubber, the twist of the cord returns near both ends thereof, and the strands are loosened.
- spontaneous entanglement of cords means that cords are entangled to form a knot in a single cord.
- Twisting or spontaneous entanglement of the cord creates gaps between the strands and shifts the appropriate position strands where each strand should be.
- the load concentrates on the part during use of the product, causing localized wear and causing breakage of the filaments, strands and cords.
- the glass fiber cord twisted with rungs does not actually exhibit high bending fatigue resistance, and is not suitable for use in rubber products such as rubber belts subjected to strong and bending stress. Was thought.
- one of the objects of the present invention is to provide a rung-reinforced rubber reinforcement having excellent tensile strength and resistance to bending fatigue with less twisting and spontaneous entanglement of the cord. And a method for manufacturing the same.
- Another object of the present invention is to provide a rubber product using the rubber reinforcing cord of the present invention.
- a method for producing a rubber reinforcing cord of the present invention comprises:
- the rubber reinforcing cord of the present invention is a cord manufactured by the manufacturing method of the present invention.
- the rubber product of the present invention is a rubber product reinforced with the rubber reinforcing cord of the present invention.
- a rubber reinforcing cord excellent in tensile strength and bending fatigue resistance, which can prevent untwisting and spontaneous entanglement peculiar to a Lang-twisted glass fiber cord. can get. Further, since the rubber product of the present invention uses the rubber reinforcing cord of the present invention, it has excellent bow I tension strength and flex fatigue resistance.
- FIG. 1 is a perspective view schematically showing one example of a rubber product of the present invention.
- FIG. 2 is a cross-sectional view schematically showing a rubber reinforcing cord produced in an example.
- FIG. 3 is a diagram schematically showing a method of a bending test performed in an example.
- a second strand is formed by twisting a plurality of first strands in a first direction. That is, the second strand is formed by twisting the plurality of first strands in a predetermined direction.
- the first strand contains glass filaments as reinforcing fibers.
- the first direction is the S direction or the Z direction.
- a cord including a plurality of second strands twisted in the same direction as the first direction and an unsolidified treatment agent applied to the second strands is formed. That is, the plurality of second strands are ply-twisted in the same direction as the ply-twist.
- This cord may be formed by twisting a plurality of second strands in the same direction as the first direction, and then applying an unsolidified treatment agent. Further, the cord may be formed by twisting a plurality of second strands coated with an unsolidified treatment agent in the same direction as the first direction.
- the second strands are bonded to each other by solidifying the treating agent while applying a tensile load of 40 to 800 N per 1 mm 2 of the cross-sectional area of the glass filament to the cord.
- a glass fiber strand is used as the first strand.
- the reinforcing fibers included in the first strand are typically made of glass fibers, but may include fibers made of other materials as long as the effects of the present invention can be obtained.
- a fiber strand of a material other than glass fiber may be used in combination.
- strands of aramide fiber, PBO (polyparaphenylenebenzobisoxazole) fiber or carbon fiber are arranged in the core.
- a plurality of glass fiber strands arranged around the hybrid cord In this case, the present invention is applied to a plurality of glass fiber strands.
- Examples of the glass fiber used for the glass fiber strand include E glass filament and high-strength glass filament.
- the diameter of the glass filament and the number of glass filaments constituting the glass fiber are not particularly limited. Particularly high-flexibility reinforcement by using glass fiber strands with a count of 5 to 64 Og / lOOOOm formed by bundling and twisting 100 to 2,400 glass filaments with a diameter of 5 to 11 m Code is obtained.
- the production method of the present invention may include a step of coating the glass filament of the first strand with a pretreatment agent.
- the solid content weight of the pretreatment agent is preferably in the range of 5.0 to 35.0% with respect to the sum of the weight of the glass filament and the solid content weight of the pretreatment agent.
- a glass filament constituting the first strand is usually coated with a pretreatment agent (adhesive) to improve heat resistance, water resistance, adhesion, and the like, and to prevent fraying.
- a pretreatment agent adheresive
- the pretreatment agent is not particularly limited, but a resorcinol-formalin-rubber latex mixture (hereinafter sometimes referred to as “RFL treatment liquid”), an epoxy conjugate, an isocyanate conjugate, and the like can be used. .
- the rubber latex used in the RFL treatment solution includes acrylic rubber-based latex, urethane-based latex, styrene-butadiene-based rubber latex, nitrile rubber-based latex, chlorosulfonated polyethylene-based latex, modified latex of these, and mixtures thereof. Is exemplified.
- Examples of preferred pretreatment agents include resorcinol formaldehyde water-soluble condensate, carboxylated butylpyridine butadiene styrene copolymer latex, dicarboxyl butadiene styrene copolymer latex, and chlorosulfonated polyethylene latex, and Are 2 to 15% by weight, 15 to 80% by weight, 7 to 50% by weight, and 10 to 60% by weight, respectively, in terms of solid content.
- the number of twists of the first strand is 0.5-9.0.0 turns / 25m m (0.5-9.0 times per 25mm) force ⁇ preferred, 1.0-4.0 times / 25mm force ⁇ preferred! / ⁇ .
- a plurality of (preferably 2 to 24) first strands are bundled and twisted to form a second strand.
- the second strand count (tex) is typically in the range of 5-640 gZl000 m.
- a plurality of second strands are bundled and given a top twist in the same direction as the bottom twist. That is, when the direction of the bottom twist is the S direction, the direction of the top twist is also the S direction, and when the direction of the bottom twist is the Z direction, the direction of the top twist is also the Z direction.
- the number of twists in the first twist is preferably 0.5-9.0 times Z25mm for the same reason as described for the first twist, and more preferably 1.0-4.0 times Z25mm. That is, a plurality of first strands are twisted 0.5-9.0 times at a rate of Z25 mm, and a plurality of second strands are twisted 0.5-
- a cord is formed by ply-twisting a plurality (preferably 3 to 30) of second strands.
- the count (tex) of the resulting twisted cord is usually in the range of 15-6000gZl000m.
- yarn twisting device and twisting device of the fiber strand there are no particular limitations on the yarn twisting device and twisting device of the fiber strand, but a ring twisting machine, a flat yarn twisting machine, a stranded wire machine, or the like can be used.
- a treatment agent for fixing the second strands to each other is applied to the second strands.
- a cord composed of a plurality of second strands on which a treating agent is applied and twisted is subjected to a tensile load in the length direction.
- a tensile load is applied to the cord in the length direction
- the strands constituting the cord and the filaments constituting the cord are arranged in an aligned manner, so that the cord is untwisted or spontaneous. Is in a released state.
- the treatment agent is solidified in such a state, the alignment state is fixed, and thereafter, even if the tensile load is released, the movement of the filament or the strand is suppressed.
- the treatment agent is solidified in a state where a predetermined tensile load is applied to the cord to which the untwisted treatment agent is applied by the rung twist. In this way, the twisted state is maintained. Also, by solidifying the treating agent, untwisting and entanglement can be prevented.
- the tensile load may be applied not only when the treatment agent applied to the fiber cord is solidified but also in a step before that. For example, from the step of aligning and twisting a plurality of second strands and the step of applying a treating agent to the twisted second strand, a tensile load is continuously applied.
- the rubber reinforcing cord of the present invention has no movement of filaments and strands even when embedded and heated and compressed in a rubber composition to produce a rubber product such as a rubber belt. Twisting and spontaneous entanglement of the cord do not occur.
- the tensile load applied to the cord is selected within a range smaller than the tensile strength of the cord.
- the tensile load per 1 mm 2 of the cross-sectional area of the glass filament is expressed in units of [NZmm 2 ].
- Tensile load is more preferably in the range of 50- 500NZmm 2.
- a cord using a filament having a composition of E glass is preferably 50 to 300 N / mm 2
- a cord using a filament having a high strength glass composition is preferably 50 to 500 NZmm 2 .
- the cross-sectional area of the glass filament in the cross section of the cord is calculated based on the diameter and the number of glass filaments constituting the cord.
- a plurality of second strands are twisted to form a cord, and wound around a bobbin.
- the cord is continuously drawn out of the bobbin and passed through the bath so as to be immersed in the treatment agent in the bath, and the treatment agent is applied.
- the cord is passed through a drying oven to dry and solidify the treating agent, and wound around a bobbin.
- a pair of driving rolls are arranged before and after the drying oven, and the rotation speed of one driving roll is controlled so that a predetermined tensile load is applied to the cord passing through the drying oven.
- a predetermined tensile load may be applied to the fiber cord through the steps of coating, drying and solidifying, or pulling out and winding up the cord.
- a cord is continuously formed by twist-twisting the second strand with a twisting machine, and this cord is immersed in a treatment agent in a tank in the same manner as in (1) above. Pass through the tank as needed. Next, the cord is passed through a drying oven to dry and solidify the treating agent, and wound around a bobbin. At this time, a predetermined tensile load is applied to the cord passing through the drying oven in the same manner as in (1) above.
- the treatment agent applied to the second strand is preferably one that firmly solidifies the cord.
- known adhesives such as an RFL treating solution, an epoxy compound, and an isocyanate compound can be used.
- This treating agent is preferably selected according to the type of matrix rubber of the rubber product in which the reinforcing cord is embedded.
- a treating agent containing a halogen-containing polymer-based adhesive is preferable in that it has high adhesiveness to a hydrogenated-tolyl rubber-based rubber.
- the halogen-containing polymer-based adhesive those containing an organic disocyanate, chlorosulfonated polyethylene and an aromatic-troso compound are preferably used.
- a preferred example of the adhesive expressed as solid weight, the organic di Isoshianeto 10-50 wt 0/0, the chlorosulfonated polyethylene 10 60 weight 0/0, you And 11 to 20% by weight of an aromatic-troso compound.
- a commercially available product for example, “Chemrock 402” (trade name) manufactured by Road Corporation may be used.
- the solid content weight of the treating agent applied to the second strand is in the range of 1.0 to 15.0% with respect to the sum of the weight of the second strand and the solid content weight of the treating agent. Preferably, there is.
- the method of solidifying the treatment agent is selected according to the type of treatment agent used. Usually, the treatment agent is solidified by removing the solvent by drying or by heat treatment.
- the rubber product of the present invention is a product mainly composed of rubber, and is reinforced by the rubber reinforcing cord of the present invention.
- the rubber product of the present invention is not particularly limited, and examples thereof include a rubber belt and a rubber tire.
- FIG. 1 schematically shows a perspective view of an example of the toothed belt.
- the toothed belt 10 includes a main body 11 and a plurality of cords 12 embedded in the main body 11.
- the main body 11 is made of rubber, or rubber and other materials.
- the cord 12 is a reinforcing cord of the present invention.
- Known members can be applied to portions other than the code 12.
- a first strand was prepared by bundling 200 glass filaments (diameter 9 ⁇ m) of E glass composition.
- the three first strands are bundled to form a strand having an outer diameter of about 0.15 mm, and the strand is immersed in an RFL treatment solution, and then dried in a drying furnace to form a strand (about 130 te X).
- Tensile strength: 80 NZ strand) was formed.
- the adhesion amount of the RFL treatment liquid was set to 20% by weight in terms of solid content.
- resorcinol Z-formaldehyde 1Z1.5, solid content 8% by weight
- Example 1 Code count: 1440gZl00 Om
- a treating agent a product obtained by diluting “Chemrock 402” (trade name, manufactured by Road Corporation, solid content: 14.5% by weight) with toluene was used.
- the amount of the treatment agent attached to the cord was 3.5% by weight (solid content). Drying was performed at 80-150 ° C for about 1 minute. The tensile load was adjusted by the roll on the sending side and the roll on the winding side.
- FIG. 2 schematically shows a cross-sectional view of the obtained reinforcing cord.
- the reinforcing cord 20 is composed of 11 twisted second strands 21 and a solidified treatment agent 22.
- Each second strand 21 is constituted by three first strands 24 that are twisted and bonded with a pretreatment agent 23.
- the tensile strength of the reinforcing cord of Example 1 was measured, the tensile strength per cord was 880 N.
- the cord was cut and the degree of untwist was evaluated. Specifically, the diameter (major axis) of the cord cross section was measured before and 5 minutes after the cord was cut. As a result, the cord had a diameter of 1.02 mm before and after cutting, and almost no twisting occurred.
- a rubber reinforcing cord with a length of 300 mm is arranged on a matrix rubber sheet (width 10 mm, length 300 mm, thickness lmm) composed of the components shown in Table 1, and the same
- the matrix rubber sheets were stacked.
- the laminate was press-vulcanized from above and below at 150 ° C for 20 minutes to produce a strip-shaped test piece.
- this test piece (test piece 33) was connected to one flat pulley 31 having a diameter of 25 mm, a motor (not shown), and four guide pulleys 32.
- the bending tester 30 was set. Then, with a weight attached to one end 33a of the test piece 33 and an initial tension of 9.8 N applied to the test piece 33, the other end 33b of the test piece 33 is reciprocated a distance of 10 cm in the direction of the arrow in the figure by a motor. Exercise. Thus, the test piece 33 was repeatedly bent at the flat pulley 31.
- the tensile strength after the bending test was measured to evaluate the bending fatigue resistance. Then, the ratio of the tensile strength (per cord) after the bending test to the tensile strength (per cord) before the bending test was calculated as a tensile strength retention (%). The higher the value of the tensile strength retention ratio, the better the flex fatigue resistance. With the reinforcing cord of Example 1, the tensile strength retention after the bending test was 97%.
- a rubber reinforcing cord was produced in the same manner as in Example 1 except that the tensile load for applying and drying the treatment agent on the second strand was changed to 250 NZmm 2 . Then, for the obtained reinforcing cord, measurement of tensile strength, preparation of a strip-shaped test piece, and measurement of tensile strength retention were performed in the same manner as in Example 1.
- the diameter (major axis) of the cut surface was measured in the same manner as in Example 1 to evaluate the degree of untwisting. As a result, the cord diameter is 0 before and after cutting. It was 98 mm, and almost no twisting occurred.
- a rubber reinforcing cord was prepared in the same manner as in Example 1, except that the treatment was not applied to the second strand. Then, for the obtained reinforcing cord, the tensile strength was measured, a strip-shaped test piece was prepared, and the tensile strength retention was measured in the same manner as in Example 1.
- the diameter (major axis) of the cut surface was measured in the same manner as in Example 1 to evaluate the degree of untwisting.
- the diameter of the cord was 1. OO mm before cutting and 1.56 mm after cutting.
- a large amount of untwisting occurred.
- a rubber reinforcing cord was produced in the same manner as in Example 1, except that the direction of the first twist of the three first strands was changed to the S direction.
- the measurement of the tensile strength, the production of a strip-shaped test piece, and the measurement of the tensile strength retention were performed in the same manner as in Example 1.
- the diameter (major axis) of the cut surface was measured in the same manner as in Example 1 to evaluate the degree of untwisting.
- the cord had a diameter of 1.05 mm before and after cutting, and almost no twisting occurred.
- a rubber reinforcing cord was produced in the same manner as in Example 1, except that the direction of the first twist of the three first strands was set to the S direction, and the treatment was not applied to the second strands. Then, for the obtained reinforcing cord, the tensile strength was measured, a strip-shaped test piece was prepared, and the tensile strength retention was measured in the same manner as in Example 1.
- the diameter (major axis) of the cut surface was measured in the same manner as in Example 1 to evaluate the degree of untwisting. As a result, the diameter of the cord was 0.98 mm before cutting and 1. OO mm after cutting. As described above, in the reinforcing cord of Comparative Example 3, twisting slightly occurred.
- Example 4 A rubber reinforcing cord was produced in the same manner as in Example 1 except that the treatment load was applied to the second strand and then the tensile load at the time of drying was changed to 30 NZmm 2 . Then, for the obtained reinforcing cord, measurement of tensile strength, preparation of a strip-shaped test piece, and measurement of tensile strength retention were performed in the same manner as in Example 1.
- the diameter (major axis) of the cut surface was measured in the same manner as in Example 1 to evaluate the degree of untwisting.
- the cord had a diameter of 1.05 mm before and after cutting, and almost no twisting occurred.
- Table 2 shows the configurations and evaluation results of the reinforcing cords of Examples 1-2 and Comparative Examples 1-4.
- the reinforcing cord of Example 1-2 had an initial tensile strength as high as 880-930NZ cord and a high tensile strength retention rate after the bending test as high as 97-99.5%.
- the reinforcement cords of Comparative Examples 2 and 3 in which the direction of the first twist and the direction of the first twist are different have an initial tensile strength of 880-890 NZ cord, which is high, but the tensile strength retention rate after the bending test is 48-51. % Was low.
- the reinforcing cord of Comparative Example 4 was produced tensile load during coating 'drying treatment agent as 30NZmm 2 is the also the tensile strength retention rate after bending test is 95% higher, the initial tensile strength 850N / Cord and low strength vine. Further, the reinforcing cord of Comparative Example 1 without applying the treatment agent had an initial tensile strength of 870 NZ cord, which was high, but the tensile strength retention after the bending test was lower than that of the cords of Examples 1 and 2. I got low strength. Industrial potential
- the present invention relates to a rubber reinforcing cord, a method for manufacturing the same, and a rubber product using the same. Applicable to
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- Chemical & Material Sciences (AREA)
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Abstract
Description
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Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04787978A EP1686212A4 (en) | 2003-09-25 | 2004-09-22 | RUBBER REINFORCING CORD, METHOD FOR MANUFACTURING THE CORD AND RUBBER PRODUCT USING THE CORD |
US10/571,240 US20070028583A1 (en) | 2003-09-25 | 2004-09-22 | Rubber reinforcing cord, method of producing the cord, and rubber product using the cord |
CA002539616A CA2539616A1 (en) | 2003-09-25 | 2004-09-22 | Reinforcing cord for rubber reinforcement, method of manufacturing the same, and rubber product including the same |
JP2005514193A JP4396945B2 (ja) | 2003-09-25 | 2004-09-22 | ゴム補強用コードおよびその製造方法ならびにそれを用いたゴム製品 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2003332988 | 2003-09-25 | ||
JP2003-332988 | 2003-09-25 |
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WO2005031063A1 true WO2005031063A1 (ja) | 2005-04-07 |
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PCT/JP2004/013795 WO2005031063A1 (ja) | 2003-09-25 | 2004-09-22 | ゴム補強用コードおよびその製造方法ならびにそれを用いたゴム製品 |
Country Status (7)
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US (1) | US20070028583A1 (ja) |
EP (1) | EP1686212A4 (ja) |
JP (1) | JP4396945B2 (ja) |
KR (1) | KR20060088884A (ja) |
CN (1) | CN1856615A (ja) |
CA (1) | CA2539616A1 (ja) |
WO (1) | WO2005031063A1 (ja) |
Cited By (2)
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JP2010173612A (ja) * | 2009-02-02 | 2010-08-12 | Yokohama Rubber Co Ltd:The | 空気入りラジアルタイヤ |
CN109982869A (zh) * | 2016-11-25 | 2019-07-05 | 大陆轮胎德国有限公司 | 包括具有钢增强构件的带束层的车辆充气轮胎 |
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KR100635355B1 (ko) * | 2003-04-09 | 2006-10-18 | 니혼 이타가라스 가부시키가이샤 | 고무를 보강하기 위한 보강용 코드 및 그것을 이용한 고무제품 |
FR2938558B1 (fr) * | 2008-11-17 | 2010-12-31 | Michelin Soc Tech | Procede et dispositif de fabrication d'un cable a trois couches du type gomme in situ. |
WO2012002750A2 (ko) * | 2010-06-30 | 2012-01-05 | 코오롱인더스트리 주식회사 | 타이어 이너라이너용 필름 및 그의 제조 방법 |
EP2719824B1 (en) * | 2011-06-10 | 2017-02-22 | Nippon Sheet Glass Company, Limited | Reinforcement cord for reinforcing rubber product, and rubber product using same |
CN102995201B (zh) * | 2012-12-19 | 2016-04-13 | 江苏九鼎新材料股份有限公司 | 一种特种玻璃纤维捻线工艺 |
Citations (2)
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JPS5935056A (ja) * | 1982-08-19 | 1984-02-25 | 帝人株式会社 | コンクリ−ト用筋材及びその製造方法 |
JPH04352889A (ja) * | 1991-05-28 | 1992-12-07 | Kawasaki Steel Corp | 複合材料強化用チョップの製造装置 |
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US2930105A (en) * | 1953-07-31 | 1960-03-29 | Goodrich Co B F | Glass fiber material |
US3029590A (en) * | 1958-12-30 | 1962-04-17 | Owens Corning Fiberglass Corp | Extensible fibrous glass textile strand structure and method of making same |
GB1095557A (ja) * | 1964-04-01 | 1900-01-01 | ||
US4356219A (en) * | 1980-12-03 | 1982-10-26 | The Goodyear Tire & Rubber Company | Treated yarn, method of preparation and rubber/cord composite |
JPS58118332U (ja) * | 1982-02-05 | 1983-08-12 | 三ツ星ベルト株式会社 | 動力伝動用ベルト |
ATE25115T1 (de) * | 1982-11-02 | 1987-02-15 | Akzo Nv | Mit klebemittel beschichtetes multifilamentgarn aus aromatischem polyamid sowie verfahren zur herstellung dieses garns. |
JPH09296378A (ja) * | 1996-04-26 | 1997-11-18 | Toyota Motor Corp | ゴム部品の補強用心線及びその製造方法 |
JP2002004139A (ja) * | 2000-06-23 | 2002-01-09 | Nippon Sheet Glass Co Ltd | ゴム補強用ガラス繊維コードの製造方法およびそのガラス繊維コードを含有するゴム製品 |
JP4018460B2 (ja) * | 2002-06-10 | 2007-12-05 | 日本板硝子株式会社 | ゴム補強用コードおよびそれを含有するゴム製品 |
-
2004
- 2004-09-22 WO PCT/JP2004/013795 patent/WO2005031063A1/ja active Application Filing
- 2004-09-22 EP EP04787978A patent/EP1686212A4/en not_active Withdrawn
- 2004-09-22 CA CA002539616A patent/CA2539616A1/en not_active Abandoned
- 2004-09-22 JP JP2005514193A patent/JP4396945B2/ja active Active
- 2004-09-22 CN CNA2004800272570A patent/CN1856615A/zh active Pending
- 2004-09-22 KR KR1020067005853A patent/KR20060088884A/ko not_active Application Discontinuation
- 2004-09-22 US US10/571,240 patent/US20070028583A1/en not_active Abandoned
Patent Citations (2)
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JPS5935056A (ja) * | 1982-08-19 | 1984-02-25 | 帝人株式会社 | コンクリ−ト用筋材及びその製造方法 |
JPH04352889A (ja) * | 1991-05-28 | 1992-12-07 | Kawasaki Steel Corp | 複合材料強化用チョップの製造装置 |
Non-Patent Citations (1)
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010173612A (ja) * | 2009-02-02 | 2010-08-12 | Yokohama Rubber Co Ltd:The | 空気入りラジアルタイヤ |
CN109982869A (zh) * | 2016-11-25 | 2019-07-05 | 大陆轮胎德国有限公司 | 包括具有钢增强构件的带束层的车辆充气轮胎 |
Also Published As
Publication number | Publication date |
---|---|
CN1856615A (zh) | 2006-11-01 |
KR20060088884A (ko) | 2006-08-07 |
US20070028583A1 (en) | 2007-02-08 |
JPWO2005031063A1 (ja) | 2007-11-15 |
EP1686212A1 (en) | 2006-08-02 |
EP1686212A4 (en) | 2007-10-10 |
CA2539616A1 (en) | 2005-04-07 |
JP4396945B2 (ja) | 2010-01-13 |
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