WO2003104342A1 - Composition de revêtement - Google Patents

Composition de revêtement Download PDF

Info

Publication number
WO2003104342A1
WO2003104342A1 PCT/JP2003/007243 JP0307243W WO03104342A1 WO 2003104342 A1 WO2003104342 A1 WO 2003104342A1 JP 0307243 W JP0307243 W JP 0307243W WO 03104342 A1 WO03104342 A1 WO 03104342A1
Authority
WO
WIPO (PCT)
Prior art keywords
sample
coating composition
test
replacement form
growth
Prior art date
Application number
PCT/JP2003/007243
Other languages
English (en)
Japanese (ja)
Inventor
祐一 山中
敏治 梶
山下　英治
Original Assignee
有限会社セラミック・クラフト
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 有限会社セラミック・クラフト filed Critical 有限会社セラミック・クラフト
Priority to AU2003242040A priority Critical patent/AU2003242040A1/en
Publication of WO2003104342A1 publication Critical patent/WO2003104342A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
    • C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals

Definitions

  • the present invention relates to a coating composition, and more particularly, to a fluororesin composite coating composition containing zirconia.
  • Fluororesin paint is a paint with excellent corrosion resistance, water resistance, acid resistance, alkali resistance, and weather resistance.
  • the present invention provides a coating composition for forming a coating film having improved impact resistance and followability without impairing the merits of a fluororesin coating.
  • the present invention provides a coating composition that forms a coating film while maintaining the performance of charcoal when charcoal is further added.
  • the present invention provides a coating composition that can contain and apply particles of ceramic or other compounds according to the use of the coating.
  • the coating composition according to the present invention is made of a fluororesin as a binder (in this example, a fluororefin vinyl agent). Zirconia having a fluorite structure (ZrO 2 ).
  • a fluororesin as a binder in this example, a fluororefin vinyl agent.
  • Zirconia having a fluorite structure (ZrO 2 ) As a result, the flexibility and elasticity of the fluorite structure improve the followability and impact resistance of the coating film.
  • the gas permeability inherent in the fluorite structure when carbon powder is added, a low molecular gas respiration of the object to be coated and a high molecular gas adsorption effect can be suitably obtained.
  • the particles of the zirconia function as a buffer between the other particles, and the collision between the particles is reduced.
  • the addition of other substances to the fluorite structure of zirconia strengthens the fluorite structure and increases the bonding strength with the fluororesin, thereby strengthening the resin component. This not only improves the durability of the coating film, but also enhances the retention of other particles to be added.
  • said thoria (oxidation Germany tri ⁇ beam, Y 2 0 3) and zirconium two ⁇ ⁇ acme thoria mixture is mixed is used.
  • the replacement of part of the fluorite zirconia with yttria stabilizes the cubic structure. This suppresses cubic crystal transition due to external force.
  • cerium oxide part of the zirconium air fluorite structure is substituted, cubic structure is stabilized, transfer of cubic due to an external force can be suppressed. Further, the UV resistance of the coating is improved.
  • the cerium oxide and the fluororesin a part of the fluororesin is combined with the rare-earth metal oxide to improve the electric conductivity of the resin portion.
  • the electrostatic charge that causes the adhesion is reduced, and the stain resistance of the coating film is improved.
  • yttrium oxide and cerium oxide have a large bonding force with the fluororesin, forming a part of the zirconia structure contributes to uniform mixing of the fluororesin and zirconia and improvement of coating strength. I do.
  • particles of the following substances can be added to the above-mentioned coating composition as an additive, and the respective effects of these substances in the coating film are produced.
  • silica When silica is added, the silica disperses in the coating as ceramic particles. Silica is not required for water or acid, so chemical resistance is improved. It hardly absorbs ultraviolet rays, so that the weather resistance of the coating film is improved.
  • silica Si 2
  • fluorite-structured zircoair some of the silica (Si 2 ) may be replaced by some of the fluorite-structured zircoair.
  • alumina A 1 2 0 3
  • alumina dispersed in the coating as a particulate ceramic element Since alumina is stable to chemicals, chemical resistance is improved.
  • the titanium dioxide When titanium dioxide is added, the titanium dioxide is dispersed as particles in the coating film.
  • rutile-type titanium dioxide When rutile-type titanium dioxide is added, rutile-type titanium dioxide has a small photocatalytic effect, but has a high strength, a high corrosion resistance, and a high resistance to ultraviolet light, so that the corrosion resistance and ultraviolet resistance of the coating film are improved.
  • anatase-type titanium dioxide When anatase-type titanium dioxide is added, anatase-type titanium dioxide has low corrosion resistance and ultraviolet light resistance, but has a very strong photocatalytic effect, so that the coating film can have a photocatalytic effect. Addition of rutile-type and anatase-type titanium dioxide in a balanced manner to obtain a paint composition that forms a coating film with either UV resistance or photocatalytic effect, or both. Can be. PC drawing 3/07243
  • the silver compound When a silver compound is added, the silver compound is dispersed as particles in the coating film.
  • the sulfides of silver can be used to decompose sulfides, which are used as nutrients by microorganisms and bacteria, thereby suppressing the growth of microorganisms. Therefore, an antibacterial effect is added to the coating film.
  • the charcoal powder when charcoal powder is added to the fluororesin, the charcoal powder is dispersed as particles in the coating film.
  • the carbon graphite layer on the surface of the coal powder particles is covalently bonded to a part of the fluororesin, and the cyclohexane type two-dimensional carbon structure layer bonded to the fluororesin is formed on the carbon powder surface.
  • the carbon combined with the fluororesin has a layer structure and high hydrophobicity. Further, the lubricating property is improved by this layer structure.
  • the electric conductivity of the coating film is increased by increasing the hole concentration of the carbon layer by bonding with the fluororesin.
  • the separation of the coal powder and the fluororesin can be suppressed by this layer, but the effect of the coal is maintained.
  • the effects of charcoal include air and water purification, pest resistance, far-infrared radiation, and gas absorption.
  • FIG. 1 shows the molecular structure of fluoroethylene vinyl ether.
  • Figure 2 shows an overview of the structure of the coating.
  • Figure 3 shows an overview of the fluorite structure of zirconia.
  • FIG. 4 shows an overview of the graphite structure.
  • FIG. 5 shows the results of the FRP accelerated weathering test.
  • Figure 6 shows the results of the accelerated weathering test compared with other paints.
  • FIG. 7 shows the results of comparison of the accelerated weathering test with other paints.
  • FIG. 8 shows the results of a comparison between the accelerated weathering test and other paints.
  • Figure 9 shows the results of the ammonia removal test.
  • FIG. 10 shows the results of the trimethylamine removal test.
  • FIG. 11 shows the results of the methyl mercaptan removal test.
  • Figure 12 shows the results of the hydrogen sulfide removal test.
  • FIG. 13 shows the results of the formaldehyde removal test.
  • FIG. 14 shows the results of the acetaldehyde removal test.
  • Figure 15 shows the results of the antibacterial test.
  • Figure 16 shows the conditions for the antibacterial test.
  • Figure 17 shows the results of the mold resistance test.
  • Figure 18 shows how to display the test results visually in the mold resistance test.
  • a fluororesin is used as a resin component of the coating composition of the present invention.
  • a fluoroethylene vinyl ether copolymer is used among the fluoroolefin vinyl ether copolymers.
  • An example of fluoroethylene vinyl ether is shown in FIG. X represents fluorine or chlorine.
  • R 1 and R 2 represent an alkyl group, which contribute to solvent solubility, transparency, gloss, hardness, and leaching property (the property of forming a bridge when binding to other molecules). Each performance can be adjusted by the molecular weight of Rl and R2.
  • R 3 and R 4 represent an alkylene group. OH groups are hardened sites and contribute to basic adhesion. The COOH group contributes to the dispersibility of the pigment and the adhesion to the base.
  • the fluoroethylene vinyl ether copolymer used in this example is as follows. Molecular weight: approximately 20 000, specific gravity: 4, OH value (mg KOH / gr) 52, acid value (mg KOHZ gr) 0, viscosity CPS (25 ° C.) 20 containing xylene / butyl acetate (25 to 35%) as a solvent is used.
  • Fluoroethylene vinyl ether is blended so as to contain 60 to 80 wt% in the coating film (the coating film after coating and drying, the same applies hereinafter).
  • Zirconia is added to the resin component as particles containing yttrium oxide (Y 2 O 3 ).
  • the applicable range is 70 to 90 wt% of zirconium and 10 to 30 wt% of yttrium oxide, but the range of zirconium is approximately 75 to 85 ⁇ %.
  • Particles of zirconium and yttrium oxide can be applied in a particle size of 0.1 to 1.0 m, but generally 0.2 to 1.0 m 0.4 m is preferred.
  • Zirconia and oxide oxide particles can be present in the coating in 5 to 15 watts. Although it is blended so as to be t%, it is preferably about 7 to 12 wt%. If cerium oxide (C E_ ⁇ 2) is added, cerium oxide is formulated such that 1.5 to 3 wt% in the coating film, generally 1.7 to 2. 3 wt% is preferred.
  • Silica is added as particles to the resin component. Silica particles having a diameter of 20 to 50 are applicable, but particles having a diameter of 25 to 35 are preferred.
  • the sili force is blended so as to be 3 to 7 wt% in the coating film, but is preferably about 3 to 5 wt%.
  • Alumina is added as particles to the resin component.
  • Alumina particles having a diameter of 25 to 45 are applicable, but those having a diameter of approximately 30 to 40 / m are preferred.
  • Alumina is blended in the coating in an amount of 5 to 15 wt%, preferably about 5 to 8 wt%.
  • the anatase type titanium dioxide and the rutile type titanium dioxide are added as particles to the resin component.
  • a particle size of 25 to 45 m is applicable, but a particle size of approximately 30 to 40 / zm is preferred.
  • titanium dioxide is used either in the form of an analog-type titanium dioxide or a rutile-type titanium dioxide, or a mixture of two types. Although it is blended so as to be wt%, it is preferably about 5 to 8 wt%.
  • the silver compound is added as a material in which silver and zinc are supported on fine powdered magnesium metasilicate ammonium silicate.
  • the amount added is from 0.5 to 2 wt% in the coating film, but is preferably about 1 wt%.
  • the charcoal powder is blended in the coating film in an amount of 5 to 15 wt%, and preferably about 10% by weight.
  • coal powder those having a particle size of 10 to 50 m are used, and those having a particle size of approximately 20 x m are preferably used.
  • charcoal whose surface is partially coated with a ceramic coating.
  • barium sulfate When barium sulfate is added as a vehicle, it is blended in the coating film in an amount of 0.5 to 0.8 wt%, and preferably about 0.5%.
  • calcium nitrate When calcium nitrate is added for the effect of salt damage resistance, it is blended in a coating film in an amount of 0.5 to 0.8 wt%, but is preferably about 0.5%.
  • the above mixing ratio may vary depending on the mixing and is not limited to the above.
  • xylene or butyl acetate may be added as a solvent to adjust the viscosity of the paint.
  • the above-mentioned paint is applied to the surface of the object after mixing isocyanate as a curing agent before application.
  • the isocyanate is highly reactive, the reaction proceeds without heating, and takes a very stable structure once reacted. This allows drying at room temperature and contributes to improving the solvent resistance of the coating film.
  • the paint dries (solidifies) as the solvent evaporates and the components in the paint undergo addition polymerization.
  • Figure 3 shows an overview of the coating.
  • the coating material of the present invention By applying the coating material of the present invention to an object, a coating film is formed on the object.
  • Zirconia-yttrium oxide particles 3 (including cerium oxide-silicone) are dispersed in the fluororesin coating.
  • particles 4 of ceramic, metal compound, or coal powder are dispersed in the coating film.
  • Zirconia and yttrium oxide particles 3 function as a cushioning material because of their flexibility and elasticity.
  • the yttrium oxide and cerium oxide contained in the zirconium yttrium oxide particles 3 have a strong bonding force with the fluororesin, the ability to retain the ceramic, metal compound, or carbon powder particles 4 in the resin is improved. I do.
  • the zirconium-yttrium oxide particles are composed of yttria-stabilized zirconium in which part of zirconium is replaced with yttrium oxide in some unit crystals of the fluorite structure of zirconium shown in Fig. 3.
  • YSZ Yttria-Stabi 1ized Zirconia
  • YSZ Yttria-Stabi 1ized Zirconia
  • the surface of the charcoal powder has a graphite structure as shown in Fig. 4, and the cyclohexane-type two-dimensional carbon layers are bonded by a weak force (Fandelworth force).
  • a weak force Frndelworth force
  • the carbon layer near the surface and the fluorocarbon resin combine to form a layer with good hydrophobicity and lubricity.
  • test results of the coating components of the present invention using the following components and coating method are shown below.
  • the test items used in the following tests had the following components and application methods.
  • Titanium dioxide (rutile type)
  • test article of the present invention when the test article of the present invention was applied, yellowing occurred after elapse of 400 hours, and whitening occurred before 50,000 hours. This indicates that the test article of the present invention has low transmission of ultraviolet light and protects the object to be coated.
  • test conditions were measured at a black panel temperature of 63 ° C, a humidity of 60% RH, and a water spray of 12 minutes per hour in each test.
  • Figure 6 shows a comparison of the results of accelerated weathering tests between the test product and acrylic silicone-based paint and acrylic urethane-based paint.
  • the gloss retention of the acrylic resin-based paint significantly decreased from the start of the test, and was 80% or less before 1000 hours and 20% or less around 170 hours.
  • Ataryl silicone-based paints remained at the same level as this test sample until 2000 hours, and gradually decreased, but after 2000 hours, decreased and became less than 60% after 300 hours. ing.
  • the test sample maintained 80% or more even after the elapse of 4000 hours.
  • Figure 7 shows a comparison of the results of the accelerated weathering test between the white film test product, the clear paint test product, and a commercially available acrylic urethane paint.
  • the acryl urethane-based paint showed a large decrease in gloss retention from the start of the test and almost lost gloss after 200 hours, whereas the white coated film and the clear coated film tested for 600 hours Good luster is maintained until thereafter. In the clear coating film, 80% or more was maintained until 1000 hours later.
  • Figure 8 shows a comparison of the results of the accelerated weathering test between the test product and the vinylidene fluoride paint, acrylic melanin paint, and silicone polyester paint.
  • Acrylic melanin paints and silicone polyester paints have a greatly reduced gloss retention from the start of the test, reaching about 20% after 2000 hours.
  • Vilinidene fluoride has a gloss retention of 80% or more until after 4000 hours, but the gloss retention is lower than that of this test product.
  • test method is as follows. Sample 1) and sample 2) (one each) are placed in odor bags (25 cm x 35 cm), heat-sealed, filled with 3 L of air, and the gas concentration is targeted. The gas was added to reach the value. After gas addition, the concentration was measured over time.
  • the gas concentrations were about 500 ppm for the ammonia test, about 50 ppm for the trimethylamine test, about 50 ppm for the methyl mercaptan test, about 100 ppm for the hydrogen sulfide test, and the formaldehyde test. The test was performed at about 20 ppm, and in the test for acetoaldehyde at about 20 ppm.
  • Specimen 1 was coated with the paint of the present invention containing charcoal powder, and then further coated with clear paint containing no charcoal powder. One used. In the blank test, the gas concentration was measured without using a sample for a comparative test.
  • Figure 9 shows the results of the ammonia removal test. In both sample 1) and sample 2), the concentration of ammonia decreased. After 180 minutes, both decreased to about 20 ppm A little.
  • FIG. 10 shows the results of the test for removing trimethylamine.
  • concentration of trimethylamine decreased slightly. After 180 minutes, both decreased to about 40 ppm.
  • FIG. 11 shows the results of the methyl mercaptan removal test.
  • concentration of methyl mercaptan decreased. After 180 minutes, both decreased to about 20 ppm.
  • Figure 12 shows the results of the hydrogen sulfide removal test.
  • concentration of hydrogen sulfide decreased.
  • sample 1) decreased to about 50 ppm
  • sample 2) decreased to about 40 ppm.
  • FIG. 13 shows the results of the formaldehyde removal test. Sample 1) Sample
  • FIG. 14 shows the results of the acetoaldehyde removal test.
  • specimen 2 decreased to about 9 ppm.
  • Figure 15 shows the results of the antibacterial test.
  • samples 1) to 3 the numbers of E. coli and staphylococci were reduced to 10 or less.
  • unprocessed polyethylene film With unprocessed polyethylene film, the bacterial count of Escherichia coli increased, while the bacterial count of Staphylococcus aureus remained almost unchanged.
  • Figure 18 shows the method for evaluating the test results by visual inspection of the mold resistance test.
  • Fig. 17 shows the results of the mold resistance test.
  • the growth of the bacteria was "2" in all of the samples 1) to 3).
  • a value of "2" indicates that the hyphal growth is minimal and the area of the growth is no more than 25% of the total area of the specimen.
  • the mycelium on the specimen was covered with the one grown on the surrounding medium, and proliferation of the hypha on the specimen surface was hardly observed.
  • the coating composition of the present invention has high mold resistance.
  • the coating composition of the present invention has excellent weather resistance, flex resistance, impact resistance, scratch strength, chemical resistance, solvent resistance, nonflammability (coating), and thermal dimensional change. It has a high rate, tensile strength, water resistance, gas absorption performance, deodorization performance, antibacterial performance, and mold resistance performance.
  • the coating film has water resistance and gas permeability.
  • the base material when applied to iron, the base material can be covered with a strong coating for a long time, preventing corrosion such as acid rain and salt damage, and extending the durability of the base material.
  • the gas permeability structure of the fluorite structure does not stop the gas respiration of the base material and does not suppress the activity, so that the durability of the base material can be improved.
  • charcoal powder when added, it has a strong retention of particles and is durable, has strong hydrophobicity, and improves the anti-dust effect due to the PH adjustment effect of charcoal. Performance such as improved deodorizing effect, purification of air and water, absorption of polymer gas, and infrared effect can be obtained.
  • the coating composition of the present invention has excellent weather resistance, bending resistance, impact resistance, scratching strength, chemical resistance, solvent resistance, nonflammability (coating), and thermal dimensional change. It has high modulus, tensile strength, and water resistance, and does not impair the merits of fluororesin coatings, while improving the impact resistance and followability of the coatings.
  • the coating composition of the present invention in which carbon powder is further added, The performance of charcoal is maintained.
  • the coating composition of the present invention can be applied by containing ceramic or compound particles according to the use of the coating.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Paints Or Removers (AREA)

Abstract

L'invention concerne une composition de revêtement comprenant une fluororésine (par exemple, un copolymère de fluoro-oléfine-vinyle éther) utilisé comme liant et un zirconium (ZrO2) doté d'une structure de fluorine. Ladite composition de revêtement permet de produire un film de revêtement à caractéristiques de suivi de trajectoire et de résistance aux chocs améliorées du fait des propriétés de souplesse, de contraction et de dilatation inhérentes à une structure de fluorine.
PCT/JP2003/007243 2002-06-11 2003-06-09 Composition de revêtement WO2003104342A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003242040A AU2003242040A1 (en) 2002-06-11 2003-06-09 Coating composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2002170331 2002-06-11
JP2002-170331 2002-06-11

Publications (1)

Publication Number Publication Date
WO2003104342A1 true WO2003104342A1 (fr) 2003-12-18

Family

ID=29727761

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2003/007243 WO2003104342A1 (fr) 2002-06-11 2003-06-09 Composition de revêtement

Country Status (2)

Country Link
AU (1) AU2003242040A1 (fr)
WO (1) WO2003104342A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559522A (zh) * 2014-12-22 2015-04-29 中国人民解放军国防科学技术大学 疏水涂料及其制备方法

Citations (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5525413A (en) * 1978-08-11 1980-02-23 Asahi Glass Co Ltd Coating composition of fluorine-containing copolymer
JPS6462334A (en) * 1987-09-01 1989-03-08 Sekisui Plastics Production of polyolefin resin foamed sheet
JPH037785A (ja) * 1989-06-06 1991-01-14 Toshiba Corp 金属粒子分散樹脂コーティング材料およびこの材料を用いるコーティング方法
JPH05132646A (ja) * 1991-02-07 1993-05-28 Asahi Kagaku Kogyo Kk 無機質塗料組成物
JPH05271609A (ja) * 1992-03-24 1993-10-19 Toray Ind Inc コーティング用樹脂組成物
JPH09295872A (ja) * 1996-02-29 1997-11-18 Kikusui Kagaku Kogyo Kk 焼成治具用のコーティング剤
EP0848077A1 (fr) * 1996-12-12 1998-06-17 United Technologies Corporation Systèmes et matériaux de revêtement comme barrière thermique
JPH10195369A (ja) * 1996-12-28 1998-07-28 Daikin Ind Ltd 塗料組成物及び塗装方法
JPH111659A (ja) * 1997-04-14 1999-01-06 Daikin Ind Ltd 耐候性塗料組成物
JPH11100543A (ja) * 1997-09-29 1999-04-13 Daikin Ind Ltd 塗料組成物
EP0992603A1 (fr) * 1998-10-01 2000-04-12 United Technologies Corporation Systèmes de revêtement de barrière thermique et matériaux
JP2001019895A (ja) * 1999-07-05 2001-01-23 Nakae Bussan Kk フッ素樹脂含有コーティング用組成物
JP2003039839A (ja) * 2001-07-26 2003-02-13 Asahi Kasei Corp 平版印刷原版およびそれを用いた平版印刷版
JP2003155441A (ja) * 2001-11-22 2003-05-30 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料および抗菌性光触媒性部材
JP2003155447A (ja) * 2001-11-21 2003-05-30 Sumitomo Metal Mining Co Ltd 二液型光触媒塗料及び光触媒含有塗膜、光触媒含有塗膜の形成方法
JP2003155448A (ja) * 2001-11-21 2003-05-30 Sumitomo Metal Mining Co Ltd 二液型光触媒塗料及び光触媒含有塗膜、光触媒含有塗膜の形成方法
JP2003155443A (ja) * 2001-11-22 2003-05-30 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料および抗菌性光触媒性部材
JP2003155425A (ja) * 2001-11-21 2003-05-30 Sumitomo Metal Mining Co Ltd 二液型光触媒塗料及び光触媒含有塗膜、光触媒含有塗膜の形成方法
JP2003155442A (ja) * 2001-11-22 2003-05-30 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料および抗菌性光触媒性部材
JP2003171604A (ja) * 2001-12-03 2003-06-20 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料及び抗菌性光触媒部材
JP2003171603A (ja) * 2001-12-03 2003-06-20 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料及び抗菌性光触媒性部材
JP2003171602A (ja) * 2001-12-03 2003-06-20 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料及び抗菌性光触媒性部材
JP2003171601A (ja) * 2001-12-03 2003-06-20 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料及び抗菌性光触媒性部材

Patent Citations (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5525413A (en) * 1978-08-11 1980-02-23 Asahi Glass Co Ltd Coating composition of fluorine-containing copolymer
JPS6462334A (en) * 1987-09-01 1989-03-08 Sekisui Plastics Production of polyolefin resin foamed sheet
JPH037785A (ja) * 1989-06-06 1991-01-14 Toshiba Corp 金属粒子分散樹脂コーティング材料およびこの材料を用いるコーティング方法
JPH05132646A (ja) * 1991-02-07 1993-05-28 Asahi Kagaku Kogyo Kk 無機質塗料組成物
JPH05271609A (ja) * 1992-03-24 1993-10-19 Toray Ind Inc コーティング用樹脂組成物
JPH09295872A (ja) * 1996-02-29 1997-11-18 Kikusui Kagaku Kogyo Kk 焼成治具用のコーティング剤
EP0848077A1 (fr) * 1996-12-12 1998-06-17 United Technologies Corporation Systèmes et matériaux de revêtement comme barrière thermique
JPH10195369A (ja) * 1996-12-28 1998-07-28 Daikin Ind Ltd 塗料組成物及び塗装方法
JPH111659A (ja) * 1997-04-14 1999-01-06 Daikin Ind Ltd 耐候性塗料組成物
JPH11100543A (ja) * 1997-09-29 1999-04-13 Daikin Ind Ltd 塗料組成物
EP0992603A1 (fr) * 1998-10-01 2000-04-12 United Technologies Corporation Systèmes de revêtement de barrière thermique et matériaux
JP2001019895A (ja) * 1999-07-05 2001-01-23 Nakae Bussan Kk フッ素樹脂含有コーティング用組成物
JP2003039839A (ja) * 2001-07-26 2003-02-13 Asahi Kasei Corp 平版印刷原版およびそれを用いた平版印刷版
JP2003155447A (ja) * 2001-11-21 2003-05-30 Sumitomo Metal Mining Co Ltd 二液型光触媒塗料及び光触媒含有塗膜、光触媒含有塗膜の形成方法
JP2003155448A (ja) * 2001-11-21 2003-05-30 Sumitomo Metal Mining Co Ltd 二液型光触媒塗料及び光触媒含有塗膜、光触媒含有塗膜の形成方法
JP2003155425A (ja) * 2001-11-21 2003-05-30 Sumitomo Metal Mining Co Ltd 二液型光触媒塗料及び光触媒含有塗膜、光触媒含有塗膜の形成方法
JP2003155441A (ja) * 2001-11-22 2003-05-30 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料および抗菌性光触媒性部材
JP2003155443A (ja) * 2001-11-22 2003-05-30 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料および抗菌性光触媒性部材
JP2003155442A (ja) * 2001-11-22 2003-05-30 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料および抗菌性光触媒性部材
JP2003171604A (ja) * 2001-12-03 2003-06-20 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料及び抗菌性光触媒部材
JP2003171603A (ja) * 2001-12-03 2003-06-20 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料及び抗菌性光触媒性部材
JP2003171602A (ja) * 2001-12-03 2003-06-20 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料及び抗菌性光触媒性部材
JP2003171601A (ja) * 2001-12-03 2003-06-20 Sumitomo Metal Mining Co Ltd 抗菌性光触媒塗料及び抗菌性光触媒性部材

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559522A (zh) * 2014-12-22 2015-04-29 中国人民解放军国防科学技术大学 疏水涂料及其制备方法

Also Published As

Publication number Publication date
AU2003242040A1 (en) 2003-12-22

Similar Documents

Publication Publication Date Title
TWI481677B (zh) 常溫硬化性近紅外線遮蔽塗佈劑及使用其之近紅外線遮蔽膜以及其製造方法
JP4092434B1 (ja) 光触媒塗装体およびそのための光触媒コーティング液
WO2003102091A1 (fr) Materiau de revetement photocatalytique, materiau composite catalytique et procede de production correspondant. compositions de revetement aqueuses autonettoyantes et element autonettoyant
AU2014237704B2 (en) Superhydrophilic coating composition
CN101525504A (zh) 具有自分层隔离作用的光催化自清洁涂膜剂及其制备方法
US8691376B2 (en) Self-decontaminating inorganic coatings containing semiconductor metal oxide nanoparticles
JP4637656B2 (ja) 塗装仕上げ方法
CN102864884B (zh) 外墙用自清洁隔热涂层体系
JP2003181299A (ja) 光触媒体の製造方法
US9023146B2 (en) Oxidizing agents on pigments
JP2002060651A (ja) 金属酸化物水系ゾル組成物、これを用いた造膜法及び部材
JP2009262153A (ja) 光触媒塗装体およびそのための光触媒コーティング液
JP2009136868A (ja) 光触媒塗装体およびそのための光触媒コーティング液
JPH10298451A (ja) 浄化性コーティング用組成物
JP2009039687A (ja) 光触媒層形成用組成物
JP2009119462A (ja) 光触媒塗装体およびそのための光触媒コーティング液
JP6635329B2 (ja) 光触媒層を有する有機系基材
WO2003104342A1 (fr) Composition de revêtement
JP4695829B2 (ja) 水性塗料組成物
WO2009123135A1 (fr) Composition de revêtement de photocatalyseur
EP3913026A1 (fr) Composition liquide de revêtement à base de silane
JP6797511B2 (ja) 水性赤外線・紫外線遮蔽コーティング剤、及びこれを利用した赤外線・紫外線遮蔽処理方法
JP2002371223A (ja) 水性無機塗料組成物
EP3361020B1 (fr) Agent de revêtement protecteur aqueux pour un sol chimique retardateur d`inflammation; et sol chimique retardateur d`inflammation
WO2011059105A1 (fr) Composition à base d'un agent isolant thermique

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NI NO NZ OM PH PL PT RO RU SC SD SE SG SK SL TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LU MC NL PT SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP

WWW Wipo information: withdrawn in national office

Country of ref document: JP