WO2003022812A1 - Organische sulfate als ionische flüssigkeiten - Google Patents

Organische sulfate als ionische flüssigkeiten Download PDF

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Publication number
WO2003022812A1
WO2003022812A1 PCT/EP2002/010206 EP0210206W WO03022812A1 WO 2003022812 A1 WO2003022812 A1 WO 2003022812A1 EP 0210206 W EP0210206 W EP 0210206W WO 03022812 A1 WO03022812 A1 WO 03022812A1
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WO
WIPO (PCT)
Prior art keywords
ionic liquid
aryl
group
alkyl groups
reactions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2002/010206
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German (de)
English (en)
French (fr)
Inventor
Peter Wasserscheid
Andreas BÖSMANN
Roy Van Hal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Solvent Innovation GmbH
Original Assignee
Solvent Innovation GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7699290&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2003022812(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Solvent Innovation GmbH filed Critical Solvent Innovation GmbH
Priority to EP02797984A priority Critical patent/EP1425268B2/de
Priority to DE50211793T priority patent/DE50211793D1/de
Priority to JP2003526888A priority patent/JP4698945B2/ja
Publication of WO2003022812A1 publication Critical patent/WO2003022812A1/de
Priority to US10/798,796 priority patent/US7252791B2/en
Anticipated expiration legal-status Critical
Priority to US11/833,529 priority patent/US7544807B2/en
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D231/00Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/12Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D233/00Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/54Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C07D233/56Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with only hydrogen atoms or radicals containing only hydrogen and carbon atoms, attached to ring carbon atoms
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D249/00Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
    • C07D249/02Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
    • C07D249/081,2,4-Triazoles; Hydrogenated 1,2,4-triazoles

Definitions

  • This invention relates to novel ionic liquids of the general formula [cation] [R'-S04] where R 'is a branched or linear, saturated or unsaturated, aliphatic or alicyclic, functionalized or unfunctionalized hydrocarbon chain with 3-36 carbon atoms.
  • novel ionic liquids can e.g. B. as a solvent or solvent additives in chemical reactions, as an extractant or as a heat transfer medium.
  • Ionic liquids are generally understood to mean salts or mixtures of salts whose melting points are below 100 ° C. (P. Wasserscheid, W. Keim, Angew. Chem. 2001, 112, 3926).
  • Known salts of this type consist of anions such as. B. halogenostannates, halogenoaluminates, hexafluorophosphates or tetrafluoroborates combined with substituted ammonium, phosphonium, pyridinium or imidazolium cations.
  • ionic liquids as solvents for chemical reactions (T. Welton, Chem. Rev. 1999, 99, 2071, P. Wasserscheid, W. Keim, Angew.
  • ionic liquid Even if the definition for ionic liquid also includes salts whose melting points are between room temperature and 100 ° C., it is nevertheless necessary or desirable for many applications that the ionic liquids are already liquid at temperatures below room temperature.
  • ionic liquids such as F “ , CI “ , Br “ or I " or those anions which contain halogen atoms.
  • Typical representatives of the latter anions are - without claiming to be complete - [BF 4 ] “ , [PF 6 ] “ , [CF 3 COO] -, [CF3SO3] “ , [(CF 3 S0 2 ) 2N] ' , [AICI4] “ , [AI2CI7] " or [SnCI 3 ] “ .
  • ionic liquids which consist of a combination of a suitable organic cations - with imidazolium, pyridinium, phosphonium or ammonium cations being particularly suitable examples - with
  • R-SO4 Anions of the general formula [R-SO4] exist - where R is a linear or branched, saturated or unsaturated, aliphatic or alicyclic, functionalized or unfunctionalized alkyl radical with 3-36
  • the invention has melting points or glass points below 25
  • R-SO4 where R is a linear or branched, functionalized or unfunctionalized, saturated or unsaturated, aliphatic or alicyclic alkyl radical with 3-36 carbon atoms - technically readily available raw materials for detergents and for
  • Such ionic liquids can also be particularly preferably of this invention manufacture and use which contain mixtures of different anions of the general formula [RSO] - where R is a linear or branched, saturated or unsaturated, aliphatic or alicyclic, functionalized or unfunctionalized
  • Example 2 In-butyl-3-methylimidazolium octyl sulfate ([BMIM] [OcSO 4 ])

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Pyridine Compounds (AREA)
PCT/EP2002/010206 2001-09-12 2002-09-11 Organische sulfate als ionische flüssigkeiten Ceased WO2003022812A1 (de)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP02797984A EP1425268B2 (de) 2001-09-17 2002-09-11 Organische sulfate als ionische flüssigkeiten
DE50211793T DE50211793D1 (enExample) 2001-09-17 2002-09-11
JP2003526888A JP4698945B2 (ja) 2001-09-17 2002-09-11 イオン液体
US10/798,796 US7252791B2 (en) 2001-09-17 2004-03-11 Ionic liquids
US11/833,529 US7544807B2 (en) 2001-09-17 2007-08-03 Ionic liquids

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10145747.2 2001-09-12
DE10145747A DE10145747A1 (de) 2001-09-17 2001-09-17 Ionische Flüssigkeiten

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US10/798,796 Continuation-In-Part US7252791B2 (en) 2001-09-17 2004-03-11 Ionic liquids

Publications (1)

Publication Number Publication Date
WO2003022812A1 true WO2003022812A1 (de) 2003-03-20

Family

ID=7699290

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/010206 Ceased WO2003022812A1 (de) 2001-09-12 2002-09-11 Organische sulfate als ionische flüssigkeiten

Country Status (6)

Country Link
US (2) US7252791B2 (enExample)
EP (1) EP1425268B2 (enExample)
JP (1) JP4698945B2 (enExample)
AT (1) ATE387427T1 (enExample)
DE (2) DE10145747A1 (enExample)
WO (1) WO2003022812A1 (enExample)

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EP1400504A1 (de) * 2002-09-19 2004-03-24 Celanese Chemicals Europe GmbH Verfahren zur Herstellung von Aldehyden
WO2005019185A1 (en) * 2003-08-26 2005-03-03 Ecole Polytechnique Federale De Lausanne (Epfl) Ionic liquids based on imidazolium salts incorporating a nitrile functionality
WO2005007657A3 (de) * 2003-07-11 2005-04-14 Solvay Fluor & Derivate Verwendung von dbn und dbu-salzen als ionische flüssigkeiten
WO2005021484A3 (de) * 2003-08-27 2005-05-26 Roland Kalb Verfahren zur herstellung ionischer flüssigkeiten, ionischer feststoffe oder gemische derselben
JP2005314332A (ja) * 2004-04-30 2005-11-10 Kaneka Corp イオン性液体およびその製造方法
WO2006136529A1 (de) * 2005-06-18 2006-12-28 Basf Aktiengesellschaft Pyrazolium alkylsulfates as ionic liquids
JP2008526822A (ja) * 2005-01-04 2008-07-24 ザ クィーンズ ユニヴァーシティー オブ ベルファスト 塩基安定性イオン液体
JP2008533232A (ja) * 2005-03-11 2008-08-21 ザ クィーンズ ユニヴァーシティー オブ ベルファスト バイオディーゼルの製造
WO2009077452A1 (de) * 2007-12-14 2009-06-25 Basf Se Verfahren zur verbesserung der hydrolysestabilität ionischer flüssigkeiten
WO2011012687A2 (de) 2009-07-31 2011-02-03 Basf Se Imidazolgruppenhaltige phosphinoboran-verbindungen und verfahren zur herstellung von imidazolgruppenhaltige phosphorverbindungen
JP2015110594A (ja) * 2004-04-07 2015-06-18 イノビア フィルムズ リミティド 液体
WO2016040629A1 (en) 2014-09-10 2016-03-17 Basf Se Encapsulated cleaning composition
WO2017156141A1 (en) 2016-03-09 2017-09-14 Basf Se Encapsulated laundry cleaning composition
CN114606508A (zh) * 2022-03-16 2022-06-10 四川大学 一种环保型离子液体脱脂液及其使用方法

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US20080033178A1 (en) 2008-02-07
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ATE387427T1 (de) 2008-03-15
US7544807B2 (en) 2009-06-09

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