WO2002033039A1 - Reinigungsmaterial - Google Patents

Reinigungsmaterial Download PDF

Info

Publication number
WO2002033039A1
WO2002033039A1 PCT/EP2001/011549 EP0111549W WO0233039A1 WO 2002033039 A1 WO2002033039 A1 WO 2002033039A1 EP 0111549 W EP0111549 W EP 0111549W WO 0233039 A1 WO0233039 A1 WO 0233039A1
Authority
WO
WIPO (PCT)
Prior art keywords
cleaning
cleaning material
material according
substances
textile
Prior art date
Application number
PCT/EP2001/011549
Other languages
German (de)
English (en)
French (fr)
Inventor
Ulrich Pegelow
Bernhard Guckenbiehl
Jürgen HILSMANN
Original Assignee
Henkel Kommanditgesellschaft Auf Aktien
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel Kommanditgesellschaft Auf Aktien filed Critical Henkel Kommanditgesellschaft Auf Aktien
Priority to EP01987788A priority Critical patent/EP1326956B1/de
Priority to US10/399,388 priority patent/US20040031107A1/en
Priority to AU2002223597A priority patent/AU2002223597A1/en
Priority to DE50105259T priority patent/DE50105259D1/de
Priority to AT01987788T priority patent/ATE288473T1/de
Priority to JP2002536409A priority patent/JP4342177B2/ja
Publication of WO2002033039A1 publication Critical patent/WO2002033039A1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/047—Arrangements specially adapted for dry cleaning or laundry dryer related applications
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces

Definitions

  • the present invention relates to a cleaning material in the form of a sheet-like structure on the surface of which one or more host substances are applied, which can contain and release one or more active components, a method for producing this cleaning material and the use of the cleaning material as a cleaning cloth for dry cleaning hard surfaces and as a cleaning cloth for dry cleaning textiles.
  • aqueous solutions are not always desirable, particularly in the case of substrates sensitive to water.
  • aqueous application solutions is also associated with the fact that the appropriate cleaning liquors must first be prepared and then removed from the substrate again. This involves a longer drying process, particularly for textiles and textile surfaces.
  • agents are also known which are applied to the substrate to be cleaned without further addition of water and removed again with the aid of a cloth.
  • wipes are usually used that are equipped with an antistatic agent or that have long fibers. Examples of such cloths are the commercially available dusters or linen cloths, such as those used for polishing glass, etc. They usually do not contain any active substances.
  • the cleaning kit contains a container in which the textile to be cleaned and the carrier material impregnated with the cleaning composition can be placed. The filled container is then placed in a household dryer.
  • the carrier materials used release cleaning-active substances, but they are not able to bind the loosened dirt.
  • the object of the present invention was to provide a cleaning material which can be used for dry cleaning substrates, such as textiles and also hard surfaces, without the use of aqueous solutions, namely wash liquors, being necessary.
  • the present invention accordingly relates to a textile cleaning material in the form of a sheet-like structure, on the surface of which one or more host substances are applied which contain one or more active components and can release, the host substances being chemically and / or physically bound to the surface of the sheet-like structure.
  • soiling of any substrates can be removed without the use of aqueous alkalis.
  • Soiling in the sense of the present invention is the usual soiling, which is visible as stains, and odorous substances, such as tobacco smoke, perfume residues, sweat or sweat breakdown products, mustiness, etc.
  • odorous substances such as tobacco smoke, perfume residues, sweat or sweat breakdown products, mustiness, etc.
  • cleaning used in this application includes both the removal of visible and invisible soiling and the removal of odorous substances.
  • the cleaning material according to the invention is a sheet-like structure on the surface of which one or more host substances are bound, which contain and can release one or more active components.
  • the structure has a two-dimensional shape and can also be called a cloth in common usage.
  • the host substances are preferably bound to the surface of the sheet-like structure via a bond such that they are not dissolved during the manufacturing process of the cleaning material, during storage or during use. Bonds with binding energies above 5 kJ / mol, preferably above 10 kJ / mol, particularly preferably above 30 kJ / mol and in particular above 50 kJ / mol are particularly suitable.
  • the bond between the host substances and the surface of the textile fabric can be covalent or ionic or based on van der Waals interactions.
  • the bond between the surface of the sheet-like structure and the host substance has the advantage that the active component is present in complexed form before the cleaning material is used and is thus protected from premature release and that the complexing substance, ie the host substance, does not or only to a lesser extent Amount is solved during the application.
  • the host substance can complex complexed impurities. Any substances can be used as host substances for the active components that are able to absorb the active components or bind them complexly and also release these components again.
  • the host substances preferably have polar groups or functional groups. Examples of functional groups are OH, COOH, NH 2 - or other acidic or basic groups.
  • the sorbent is preferably bound to the sheet-like structure via a covalent bond.
  • Examples of preferred host substances that can be bound to the sheet-like tissue are cyclodextrins and / or cyclodextrin derivatives.
  • Cyclodextrins are cyclic compounds that are made up of 1,4-linked glucose units.
  • the cyclodextrins or cyclodextrin derivatives are composed of 5 to 12 glucose units.
  • a mixture of cyclodextrins or cyclodextrin derivatives can also be used, which consists of ⁇ -, ⁇ - and / or ⁇ -cyclodextrins or the corresponding cyclodextrin derivatives.
  • Fibrous or cellular flexible materials are suitable as sheet-like structures which can be used for the production of the cleaning material according to the invention, which have sufficient thermal and mechanical stability when used and whose surface is designed in such a way that the host substances can be bound to them physically or chemically.
  • suitable materials are textile fabrics, or cloths of woven and non-woven synthetic and / or natural fibers, such as wool, cotton, silk, jute, hemp, linen, sisal, Rami, rayon, cellulose esters, polyvinyl derivatives, polyolefins, polyamides and / or polyester, felt, paper or foam, such as hydrophilic polyurethane foam, so-called nonwoven based on viscose or cellulose acetate.
  • the surface of the carrier material preferably has functional groups via which the host substances via chemical bonds, optionally via so-called Spacers, preferably bifunctional compounds or polymeric compounds, can be bound.
  • suitable functional groups are OH, NH, NH 2 , COOH, CHO, SO 3 H, epoxy or other acidic and / or basic groups, and triazine. These free functional groups generally react with the free functional groups of the host substances by addition or condensation reactions.
  • spacers are linear and / or branched alkyl groups, aryl groups, linear and / or branched alkyl aryl groups and / or oligomeric ethylene glycol terephthalate groups and polymeric groups
  • the host substances are bound to the ingredient as a spacer via a polymeric group.
  • Suitable monomeric compounds for forming the polymeric groups are, in particular, triazine and / or halogenated triazine derivatives, such as monochlorotriazine, and also dimethylol urea (DMU), dimethoxymethyl urea (DMUMe 2 ), methoxymethyl melamine, in particular trimethoxymethyl melamine to hexamethoxymethyl melamine, dimethylol alkanediol-diurethanes, dimethylolethylene urea (DMDHEU), dimethylol-propylene urea (DMPU), dimethylol-4-methoxy-5,5-dimethyl-propylene urea, dimethylol-5-hydroxypropylene urea, dimethylol-hexahydrotriazione, dimethoxymethyluron, tetramethylamethyl-acrylate, and / or t
  • the amount of host substances that the sheet-like structure contains depends on the particular area of use of the cleaning material according to the invention.
  • the cleaning material according to the invention usually has between 0.1 and 15% by weight, preferably between 1 and 5% by weight, based on the cleaning material, of host substances, the host substances preferably being statistically distributed over the textile fabric.
  • the Host substances can also be concentrated locally on the textile fabric, for example in the center or in the outer regions.
  • the size of the sheet-like structure can be any and depends on the respective application. However, the structure should be of sufficient size to be able to accommodate the required amount of active components.
  • the structures preferably have a size of 5 cm ⁇ 5 cm up to approximately 50 cm ⁇ 50 cm.
  • the active components contained according to the invention can be selected depending on the respective application.
  • active components are surfactants, solvents, fragrances, antimicrobial active ingredients, fungicides, nourishing components for surfaces, insect repellents and any mixtures thereof.
  • the cleaning process can be referred to as an exchange reaction.
  • An example of an exchange reaction is the exchange of water or moisture from the surface to be cleaned for active substance from the cleaning material.
  • nonionic, anionic, cationic and amphoteric surfactants may be mentioned as surfactants, with the nonionic and amphoteric surfactants being preferred.
  • Cationic surfactants and also anionic surfactants can also be present.
  • the nonionic surfactants used are preferably alkoxylated, advantageously ethoxylated, in particular primary alcohols having preferably 8 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linear or preferably methyl-branched in the 2-position or may contain linear and methyl branched radicals in the mixture, as are usually present in oxo alcohol radicals.
  • EO ethylene oxide
  • alcohol ethoxylates with linear residues of alcohols of native origin with 12 to 18 carbon atoms, for example from coconut, palm, tallow or oleyl alcohol, and an average of 2 to 8 EO per mole of alcohol are particularly preferred.
  • the preferred ethoxylated alcohols include, for example, C 12 . 14 - alcohols with 3 EO to 7 EO, C 9 -n alcohol with 7 EO, C 13 - ⁇ 5 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 2 -i 8 alcohols with 3 EO, 5 EO or 7 EO and mixtures of these, such as mixtures of C ⁇ . 2 14 alcohol with 3 EO and C 12 . 18 alcohol with 7 EO.
  • the degrees of ethoxylation given represent statistical averages, which can be an integer or a fraction for a specific product.
  • Preferred alcohol ethoxylates have a narrow homolog distribution (narrow range ethoxylates, NRE).
  • fatty alcohols with more than 12 EO can also be used. Examples include tallow fat alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • Nonionic surfactants which contain EO and PO groups together in the molecule can also be used according to the invention.
  • block copolymers with EO-PO block units or PO-EO block units can be used, but also EO-PO-EO copolymers or PO-EO-PO copolymers.
  • mixed alkoxylated nonionic surfactants can also be used, in which EO and PO units are not distributed in blocks but statistically. Such products can be obtained from the simultaneous exposure to fatty alcohol of ethylene and propylene oxide.
  • nonionic surfactants which cause water to run off well on hard surfaces are the fatty alcohol polyethylene glycol ethers, fatty alcohol polyethylene / polypropylene glycol ethers and mixed ethers, which can optionally be end group capped.
  • fatty alcohol polyethylene glycol ethers are those of the formula (I)
  • R a is a linear or branched alkyl and / or alkenyl radical having 6 to 22, preferably 12 to 18 carbon atoms and n1 is a number from 1 to 50.
  • the substances mentioned are known commercial products. Typical examples are adducts of on average 2 or 4 moles of ethylene oxide with technical C 12 14 coconut oil fatty alcohol (Dehydol ® LS-2 and LS-4, Cognis), or adducts of an average of 4 moles of ethylene oxide and C 14/15 oxo alcohols (Dobanol ® 45-4, Shell).
  • the products can have a conventional or narrowed homolog distribution.
  • Fatty alcohol polyethylene / polypropylene glycol ethers are to be understood as meaning nonionic surfactants of the formula (II)
  • R b represents a linear or branched alkyl and / or alkenyl radical having 6 to 22, preferably 12 to 18 carbon atoms
  • n2 stands for numbers from 1 to 10
  • m2 stands for numbers from 1 to 4.
  • Typical examples are addition products of an average of 5 moles of ethylene oxide and 4 moles of propylene oxide with technical C 12 / ⁇ coconut oil alcohol (Dehydol ® LS-54, Cognis), or 6.4 moles of ethylene oxide and 1.2 moles Propylene oxide on technical C 10 14 coconut fatty alcohol (Dehydol ® LS-980, Cognis).
  • n3 stands for numbers from 1 to 10
  • m3 for numbers from 0 to 4
  • R d for an alkyl radical with 1 to 4 carbon atoms or a benzyl radical.
  • Typical examples are mixed ethers of the formula (III) in which R c stands for an industrial C 12 / ⁇ 4 cocoalkyl radical, n3 for 5 or 10, m3 for 0 and R d for a butyl group (Dehypon ® LS-54 or LS-104, Cognis).
  • R c stands for an industrial C 12 / ⁇ 4 cocoalkyl radical
  • n3 for 5 or 10
  • R d for a butyl group
  • R d for a butyl group
  • Hydroxyalkyl polyethylene glycol ethers are compounds with the general formula (IV)
  • R e represents hydrogen or a straight-chain alkyl radical having 1 to 16 carbon atoms
  • R f represents a straight-chain or branched alkyl radical having 4 to 8 carbon atoms
  • R 9 represents hydrogen or an alkyl radical having 1 to 16 carbon atoms and n4 stand for a number from 7 to 30, with the proviso that the total number of carbon atoms contained in R e and R 9 is 6 to 16.
  • alkyl glycosides of the general formula RO (G) x can also be used as further nonionic surfactants, in which R denotes a primary straight-chain or methyl-branched, in particular methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18, C atoms and G is the symbol which stands for a glycose unit with 5 or 6 carbon atoms, preferably for glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10; x is preferably 1.2 to 1.4.
  • nonionic surfactants which are used in particular in solid compositions, are alkoxylated, preferably ethoxylated or ethoxylated / propoxylated, fatty acid alkyl esters, preferably having 1 to 4 carbon atoms in the alkyl chain.
  • Nonionic surfactants of the amine oxide type for example N-coconut alkyl-N, N-dimethylamine oxide and N-tallow alkyl-N, N-dihydroxyethylamine oxide, and the fatty acid alkanolamides can also be suitable.
  • the amount of these nonionic surfactants is preferably not more than that of the ethoxylated fatty alcohols, in particular not more than half of them.
  • Suitable surfactants are polyhydroxy fatty acid amides of the formula (V), R 1
  • R h CO is an aliphatic acyl radical having 6 to 22 carbon atoms
  • R ' is hydrogen, an alkyl or hydroxyalkyl radical having 1 to 4 carbon atoms
  • [Z 1 ] is a linear or branched polyhydroxyalkyl radical having 3 to 10 carbon atoms and 3 to 10 Hydroxyl groups.
  • the polyhydroxy fatty acid amides are known substances which can usually be obtained by reductive amination of a reducing sugar with ammonia, an alkylamine or an alkanolamine and subsequent acylation with a fatty acid, a fatty acid alkyl ester or a fatty acid chloride.
  • the group of polyhydroxy fatty acid amides also includes compounds of the formula (VI)
  • R k is a linear or branched alkyl or alkenyl radical having 7 to 12 carbon atoms
  • R 1 is a linear, branched or cyclic alkyl radical or an aryl radical is 2 to 8 carbon atoms
  • R p is a linear, branched or cyclic alkyl radical or Aryl radical or an oxy-alkyl radical having 1 to 8 carbon atoms, C 1 -C 4 -alkyl or phenyl radicals being preferred and [Z 2 ] representing a linear polyhydroxyalkyl radical whose alkyl chain is substituted by at least two hydroxyl groups, or alkoxylated, preferably ethoxylated or propoxylated Derivatives of this rest.
  • [Z 2 ] is preferably obtained by reductive amination of a sugar, for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • a sugar for example glucose, fructose, maltose, lactose, galactose, mannose or xylose.
  • the N-alkoxy- or N-aryloxy-substituted compounds can then, for example, according to the teaching of international application WO 95/07331, by reaction with Fatty acid methyl esters can be converted into the desired polyhydroxy fatty acid amides in the presence of an alkoxide as catalyst.
  • Ampholytic surfactants are surface-active compounds which, in addition to a C 8 -C 8 alkyl or acyl group, contain at least one free amino group and at least one COOH or SO 3 H group in the molecule and are capable of forming internal salts.
  • ampholytic surfactants are N-alkylglycines, N-alkylpropionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, N-alkyltaurines, N-alkylsarcosines, 2-alkylaminopropionic acids and alkylaminoacetic acids each with about 8 to 18 carbon atoms in the alkyl group.
  • Particularly preferred ampholytic surfactants are the N-cocoalkylaminopropionate, the cocoacylaminoethylaminopropionate and the C ⁇ 2 - ⁇ 8 - acylsarcosine.
  • Zwitterionic surfactants are surface-active compounds that contain at least one quaternary ammonium group and at least one COO (_) or SOs ⁇ group in the molecule.
  • Particularly suitable zwitterionic surfactants are the so-called betaines such as the N-alkyl-N, N-dimethylammonium glycinate, for example the coconut alkyl dimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinate, for example the coconut acylaminopropyl dimethylammonium glycinate, and 2 -Alkyl-3-carboxymethyl-3-hydroxyethyl-imidazolines each having 8 to 18 carbon atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known under the CTFA name
  • Suitable cationic surfactants are quaternary. Ammonium compounds of the formulas (VII) and (VIII),
  • R and R 1 is an acyclic alkyl radical having 12 to 24 carbon atoms
  • R 2 is a saturated C 1 -C 4 alkyl or hydroxyalkyl radical
  • R 3 is either R, R 1 or R 2 or is aromatic Rest stands.
  • X ⁇ stands for either a halide, methosulfate, methophosphate or phosphate ion as well as mixtures of these.
  • Examples of cationic compounds of the formula (VII) are didecyldimethylammonium chloride, ditallow dimethylammonium chloride or
  • R 4 represents an aliphatic acyl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds
  • R 5 stands for H, OH or O (CO)
  • R 7 stands for H, OH or O (CO)
  • R 8 independently of R 5 stands for H, OH or O (CO)
  • R 7 and R 8 each independently represent an aliphatic acyl radical with 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds
  • m, n and p can each independently have the value 1, 2 or 3.
  • X " can be either a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof.
  • Compounds in which R 6 is also OH are particularly preferred, and examples of compounds of the formula (VIII) are methyl-N- (2-hydroxyethyl) -N, N-di (tallow acyl-oxyethyl) ammonium methosulfate, bis - (palmitoyl) -ethyl-hydroxyethyl-methyl-ammonium-methosulfate or methyl-N, N-bis (acyloxyethyl) -N- (2-hydroxyethyl) ammonium-methosulfate, quaternized compounds of formula (VIII) are used, the unsaturated alkyl chains are preferred, the acyl groups whose corresponding fatty acids have an iodine number between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45 and which have a cis /
  • methylhydroxyalkyldialkoyloxyalkylammonium methosulfates sold by Stepan under the trademark Stepantex ® or the products known under Dehyquart ® from Cognis or the products from Goldschmidt-Witco known under Rewoquat.
  • Further preferred compounds are the diesterquats of the formula (IX), which are available under the name Rewoquat® W 222 LM or CR 3099 and, in addition to the softness, also ensure stability and color protection.
  • R 9 and R 10 each independently represent an aliphatic acyl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds.
  • R 11 is H or a saturated alkyl radical with 1 to 4 carbon atoms
  • R 1Z and R 13 independently of one another, each for an aliphatic, saturated or unsaturated alkyl radical with 12 to 18 carbon atoms
  • R 12 alternatively also for O (CO)
  • R 14 where R 14 is an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms
  • Z is an NH group or oxygen
  • q Can have integer values between 1 and 4.
  • R 15, R 16 and R 17 independently represents a C ⁇ alkyl, alkenyl or hydroxyalkyl group
  • R 18 and R 19 are each independently selected a C 8 _ 28 - alkyl group and r is a number between 0 and 5, ,
  • short-chain, water-soluble, quaternary ammonium compounds such as trihydroxyethylmethylammonium methosulfate or the alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride.
  • Protonated alkylamine compounds which have a softening effect and the non-quaternized, protonated precursors of the cationic emulsifiers are also suitable.
  • the quaternized protein hydrolyzates are further cationic compounds which can be used according to the invention.
  • cationic silicone oils such as, for example, the commercially available products Q2-7224 (manufacturer: Dow Corning; a stabilized trimethylsilylamodimethicone), Dow Coming 929 emulsion (containing a hydroxylamino-modified silicone, which is also referred to as amodimethicone), SM -2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker) Abil ® -Quat 3270 and 3272 (manufacturer: Goldschmidt-Rewo; diquartary polydimethylsiloxanes, Quaternium-80), and silicone quat Rewoquat ® SQ 1 (Tegopren ® 6922, Manufacturer: Goldschmidt-Rewo).
  • Q2-7224 commercially available products
  • Dow Corning a stabilized trimethylsilylamodimethicone
  • Dow Coming 929 emulsion containing a hydroxylamino-modified silicone, which is also
  • the alkylamidoamines can be in their non-quaternized or, as shown, their quaternized form.
  • R 20 can be an aliphatic acyl radical with 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds, s can take on values between 0 and 5.
  • R 21 and R 22 each independently represent H, C 1-4 alkyl or hydroxyalkyl.
  • Preferred compounds are fatty acid amidoamines such as the stearylamidopropyldimethylamine available under the name Tego Amid ® S 18 or the 3-tallowamidopropyl trimethylammonium methosulfate available under the name Stepantex ® X 9124, which, in addition to having a good conditioning effect, are also characterized by an ink transfer inhibiting action and especially by their good effect distinguish biodegradability.
  • detergents or cleaning agents can contain antimicrobial agents.
  • antimicrobial agents Depending on the antimicrobial spectrum and mechanism of action, a distinction is made between bacteriostatics and bactericides, fungistatics and fungicides etc.
  • Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, halophenols and phenol mercuric acetate.
  • antimicrobial activity and antimicrobial active substance have the customary meaning, as used, for example, by KH Wall conferencecher in "Practice of Sterilization, Disinfection - Preservation: Germ Identification - Industrial Hygiene" (5th ed.
  • Suitable antimicrobial agents are preferably selected from the groups of alcohols, amines, aldehydes, antimicrobial acids or their salts, carboxylic acid esters, acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes , Urea derivatives, oxygen, nitrogen acetals and formals, benzamidines, isothiazolines, phthalimide derivatives, pyridine derivatives, antimicrobial surface-active compounds, guanidines, antimicrobial amphoteric compounds, quinolines, 1,2-dibromo-2,4-dicyanobutane, iodo-2-propyl butyl- carbamate, iodine, iodophores, peroxo compounds, halogen compounds and any mixtures of the foregoing.
  • the antimicrobial active ingredient can be selected from ethanol, n-propanol, i-propanol, 1,3-butanediol, phenoxyethanol, 1, 2-propylene glycol, glycerin, undecylenic acid, benzoic acid, salicylic acid, dihydracetic acid, o-phenylphenol, N-methylmorpholine acetonitrile (MMA), 2-benzyl-4-chlorophenol, 2,2'-methylene-bis- (6-bromo-4-chlorophenol), 4,4'-dichloro-2'-hydroxydiphenyl ether (dichlosan), 2.4 , 4'-trichloro-2'-hydroxydiphenyl ether (trichlosan), chlorhexidine, N- (4-chlorophenyl) -N- (3,4-dichlorophenyl) urea, N, N '- (1, 10-decanediyldi- 1-pyridinyl-4-yliden
  • Halogenated xylene and cresol derivatives such as p-chlorometacresol or p-chlorometaxylene, as well as natural antimicrobial agents of plant origin (e.g. from spices or herbs), animal and microbial origin are also suitable.
  • antimicrobial surface-active quaternary compounds a natural antimicrobial active ingredient of plant origin and / or a natural antimicrobial active ingredient of animal origin, most preferably at least one natural antimicrobial active ingredient of plant origin from the group comprising caffeine, theobromine and theophylline as well as essential oils such as eugenol, thymol and geraniol, and / or at least one natural antimicrobial active ingredient of animal origin from the group comprising enzymes such as protein from milk, lysozyme and lactoperoxidase, and / or at least one antimicrobial surface-active quaternary compound with an ammonium, sulfonium, phosphonium, iodonium - Or arsonium group, peroxo compounds and chlorine compounds are used.
  • Substances of microbial origin so-called bacteriocins, can also be used.
  • the quaternary ammonium compounds (QAV) suitable as antimicrobial active ingredients have the general formula (R 1 ) (R 2 ) (R 3 ) (R 4 ) N + X " , in which R 1 to R 4 are identical or different CrC 22 alkyl radicals , C 7 -C 28 -aralkyl radicals, or heterocyclic radicals, or in the case of an aromatic compound such as pyridine-even together with the nitrogen atom forming the heterocycle, for example a pyridinium or imidazolinium compound three radicals, and X "halide ions, sulfate ions, Are hydroxide ions or similar anions.
  • At least one of the residues preferably has a chain length of 8 to 18, in particular 12 to 16, carbon atoms.
  • QAV can be prepared by reacting tertiary amines with alkylating agents such as methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide.
  • alkylating agents such as methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide.
  • alkylation of tertiary amines with a long alkyl radical and two methyl groups is particularly easy, and the quaternization of tertiary amines with two long radicals and one methyl group can also be carried out using methyl chloride under mild conditions.
  • Amines which have three long alkyl radicals or hydroxy-substituted alkyl radicals are not very reactive and are preferably quaternized with dimethyl sulfate.
  • Suitable QACs are, for example, benzalkonium chloride (N-alkyl-N, N-dimethyl-benzylammonium chloride, CAS No. 8001-54-5), benzalkon B (77, p-dichlorobenzyldimethyl-C12-alkylammonium chloride, CAS No. 58390- 78-6), benzoxonium chloride (benzyl-dodecyl-bis (2-hydroxyethyl) ammonium chloride), cetrimonium bromide (N-hexadecyl-N, N-trimethyl-ammonium bromide, CAS No.
  • benzetonium chloride N, N-DimethyI-N- [2- [2- [p- (1, 1, 3,3-tetramethylbutyl) phenoxy] ethoxy] ethyl] benzylammonium chloride, CAS No. 121-54-0
  • Dialkyldimethylammonium chloride such as di-n-decyldimethylammonium chloride (CAS No. 7173-51-5-5), didecyldimethylammonium bromide (CAS No. 2390-68-3), dioctyldimethylammoniumchloric, 1-cetylpyridinium chloride ( CAS No.
  • QAV thiazoline iodide
  • Particularly preferred QAV are the benzalkonium chlorides with C 8 -C 18 -alkyl radicals, in particular C 12 -C 1 -alkyl-benzyl-dimethyl-a monium chloride.
  • Benzalkonium halides and / or substituted benzalkonium halides are for example commercially available as Barquat ® ex Lonza, Marquat® ® ex Mason, Variquat ® ex Witco / Sherex and Hyamine ® ex Lonza and as Bardac ® ex Lonza.
  • N- (3-chloroallyl) hexaminium chloride such as Dowicide ® and Dowicil ® ex Dow
  • benzethonium chloride such as Hyamine ® 1622 ex Rohm & Haas
  • methylbenzethonium chloride such as Hyamine ® 10X ex Rohm & Haas
  • cetylpyridinium chloride such as Cepacolchlorid ex Merrell
  • the antimicrobial active ingredients are used in amounts of from 0.0001% by weight to 1% by weight, preferably from 0.001% by weight to 0.8% by weight, particularly preferably from 0.005% by weight to 0.3% by weight .-% and in particular from 0.01 to 0.2 wt .-% used.
  • the nourishing components are particularly contained in materials that are used to treat surfaces in the home. These surfaces are hard surfaces as well as the surfaces of home textiles and upholstery, including leather. Examples of suitable care components are in particular waxes and silicone oils and waxes.
  • “Waxing” is understood to mean a number of natural or artificially obtained substances which generally melt above 40 ° C. without decomposition and which are relatively low-viscosity and not stringy even a little above the melting point. They have a strongly temperature-dependent consistency and solubility.
  • the waxes are divided into three groups according to their origin, natural waxes, chemically modified waxes and synthetic waxes.
  • Natural waxes include, for example, vegetable waxes such as candelilla wax, carnauba wax, japan wax, esparto grass wax, cork wax, guaruma wax, rice germ oil wax, sugar cane wax, ouricury wax, or montan wax, animal waxes such as beeswax, shellac wax, walnut, lanolin (wool wax), or broom wax, mineral wax or ozokerite (earth wax), or petrochemical waxes such as petrolatum, paraffin waxes or micro waxes.
  • vegetable waxes such as candelilla wax, carnauba wax, japan wax, esparto grass wax, cork wax, guaruma wax, rice germ oil wax, sugar cane wax, ouricury wax, or montan wax
  • animal waxes such as beeswax, shellac wax, walnut, lanolin (wool wax), or broom wax, mineral wax or ozokerite (earth wax), or
  • the chemically modified waxes include hard waxes such as montan ester waxes, Sassol waxes or hydrogenated jojoba waxes.
  • Synthetic waxes are generally understood to mean polyalkylene waxes or polyalkylene glycol waxes.
  • suitable synthetic compounds have, for example, higher esters of phthalic acid, in particular dicyclohexyl, which is commercially available under the name Unimoll 66 ® (Bayer AG), proved.
  • suitable Synthetic waxes of lower carboxylic acids and fatty alcohols such as dimyristyl tartrate, sold under the name Cosmacol ® ETLP (Condea).
  • synthetic or partially synthetic esters from lower alcohols with fatty acids from native sources can also be used.
  • Tegin ® 90 Goldschmidt
  • a glycerol monostearate palmitate falls into this class of substances.
  • Shellac can also be used as a care component in the present invention.
  • the so-called wax alcohols are also included in the waxes in the context of the present invention, for example.
  • Wax alcohols are higher molecular weight, water-insoluble fatty alcohols with usually about 22 to 40 carbon atoms.
  • the wax alcohols occur, for example, in the form of wax esters of higher molecular fatty acids (wax acids) as the main component of many natural waxes.
  • wax alcohols are lignoceryl alcohol (1-tetracosanol), cetyl alcohol, myristyl alcohol or melissyl alcohol.
  • the coating of the present invention the solid particles coated can optionally also contain wool wax alcohols which are understood to be triterpenoid and steroid alcohols, for example lanolin understood, which is obtainable for example under the trade name Argowax ® (Pamentier & Co).
  • wool wax alcohols which are understood to be triterpenoid and steroid alcohols, for example lanolin understood, which is obtainable for example under the trade name Argowax ® (Pamentier & Co).
  • Fatty acid glycerol esters or fatty acid alkanolamides can also be used in the context of the present invention, but optionally also water-insoluble or only slightly water-soluble polyalkylene glycol compounds.
  • fragrance compounds e.g. the synthetic products of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are used.
  • Fragrance compounds of the ester type are e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate, phenylethyl acetate, linalylbenzoate, benzyl formate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallyl propylate and benzylsalpionate.
  • the ethers include, for example, benzyl ethyl ether, the aldehydes e.g. the linear alkanals with 8-18 C atoms, citral, citronellal,
  • the ketones include, for example, the jonones, ⁇ -isomethylionone and methylcedryl ketone, the alcohols anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol and terpineol, and the hydrocarbons, in particular, belong to the hydrocarbons such as hydrocarbons pinene.
  • Perfume oils of this type may also contain natural fragrances such as are obtainable from plant sources, for example pine, citrus, jasmine, patchouly, rose or ylang-ylang oil, as well as cedar oil and lavender. Also suitable are muscatel, sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, linden blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil as well as orange blossom oil, neroliol, Orange peel oil and sandalwood oil.
  • the fragrances mentioned, such as cedar oil or lavender can also be used as agents for repelling insects (insect repellents).
  • Another object of the present invention is a method for producing the textile cleaning material described above, in which one or more host substances, which can contain and release one or more active components, are chemically and / or physically bound to a textile fabric, the host substances optionally applied to the textile fabric together with other substances and then subjected to a thermal treatment.
  • the thermal treatment causes the host substances and the textile fabric to react with one another, either in an addition or a condensation reaction. If appropriate, the host substances can be applied together with condensable monomers, so that a thermal compound forms a two-dimensional or three-dimensional crosslinking during the thermal treatment. In this embodiment, there is a chemical integration into the crosslinked monomer and a chemical connection to the textile material.
  • the thermal treatment for binding the host substances to the textile fabric preferably takes place in a temperature range between 130 ° C. and 190 ° C. over a period of time sufficient for the reaction, usually over a period of between one minute and 8 minutes.
  • the host substances are fixed to the textile fabric via spacers, then they are preferably dissolved or dispersed in a suitable solvent, and the textile material is then preferably at a temperature between 60 ° C. and 140 ° C., in particular between 80 ° C. and 130 ° C, treated with the solution or dispersion prepared.
  • the monomeric compounds used in one possible embodiment are preferably condensable monomeric compounds.
  • cyclodextrins or cyclodextrin derivatives are used as host substances and cellulose or cellulose derivatives are used as textile fabrics.
  • the compounds already mentioned above have proven to be particularly suitable as condensable monomers.
  • Such monomers are preferably in an amount between 1 and 10% by weight, in particular between 2 and 6% by weight, based on the weight of the textile material.
  • Another object of the present invention relates to the use of the textile cleaning material according to the invention as a cleaning cloth for dry cleaning hard surfaces.
  • hard surfaces e.g. Surfaces made of plastic, wood and metal as well as ceramic, which are common in the household, are cleaned, for example dust can be removed.
  • the cloth with one or more active components binds the dirt on the surface and at the same time releases the corresponding active components.
  • active components which can be contained in the host substances are surfactants, antibacterial active substances, fragrances, water and any mixtures of the above.
  • Another object of the present invention relates to the use of the textile cleaning material as a cleaning cloth for dry cleaning of textiles.
  • Textiles or textile objects are not only to be understood as clothing items but also other articles that usually have to be dry-cleaned, such as sheets, curtains, carpets and runners, upholstery covers, towels and the like.
  • dryer used below refers to a conventional domestic hot air dryer, in which the items of clothing are circulated in a drum with warm or hot air, usually at temperatures of 40 to 95 ° C., preferably at 50 to 90 ° C., usually above one Period of 15 to 45 minutes.
  • the host substances bound to the textile fabric are loaded with a liquid component selected from water, a water-miscible organic solvent and mixtures thereof and at least one surfactant.
  • the textile cleaning material according to the invention is used as a component in a so-called cleaning kit for dry cleaning, which comprises the textile cleaning material described above and a closable container for holding the cleaning material which is not affected by the action of the Movement of the dryer drum and the elevated temperature, which causes the release of the active components from the host substances, is destroyed.
  • these can be bound by the textile cleaning material and also by the host substances. Unwanted odorants in particular can be complexed by the host substances.
  • a method of cleaning contaminated textile articles comprising the steps of: placing the contaminated textile in the container of the cleaning kit described above, which also contains the textile cleaning material, sealing the container and agitating the sealed container and its contents, preferably in a dryer, at a temperature high enough to release the active components from the active substance in liquid and / or gaseous form and for a period sufficient to contain an effective amount of the active components to bring the contaminated textile into contact and thereby clean it.
  • stained or soiled areas of the textile are preferably pretreated manually with the textile cleaning material before they and the textile cleaning material are added to the container, so as to bring the soiled areas into contact with the dry cleaning composition and to loosen the contaminants.
  • the loosened / removed dirt particles can be absorbed by the textile cleaning material i.e. are adsorbed by the host substances.
  • the kit can also contain a second cleaning material which is not necessarily equipped according to the invention and which contains water or moisture as the active component. Is still a second water-containing Containing cleaning material, the water wets the textile surface and makes cleaning easier.
  • a cleaning material according to the invention which is used for dry cleaning of textiles preferably contains as active components a solvent system which additionally contains organic cosolvents or solvent systems.
  • the solvent or solvent mixture is preferably non-toxic and miscible with water.
  • a cleaning material for cleaning textiles contains an effective amount of one or more surfactants that serve as cleaning enhancers to facilitate the removal of contaminants.
  • the surfactants are preferably present in the dry cleaning composition used in an amount of 1 to 10% by weight, particularly preferably 3 to 7% by weight, based on the total active components.
  • Fragrances, deodorants, preservatives, insect repellants and insect repellants (antimidants, insect repellents) and / or dyes and other suitable additives which also improve the handling of the cleaning material according to the invention can be present as further active components.
  • the amount of such additives is preferably between about 0.25 and 5% by weight, based on the total amount of active components.
  • the container is a closed container, which should be made of a material that is not permeable to the liquid and gaseous active components.
  • a closed container which should be made of a material that is not permeable to the liquid and gaseous active components.
  • the container can be made of polyethylene, polypropylene, polyamide or a multi-layer composite material. It is also important that the container is not damaged under the application conditions in the dryer.
  • the container After use, the container can be discarded or, if necessary, reused.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Emergency Medicine (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Detergent Compositions (AREA)
  • Glass Compositions (AREA)
  • Valve Device For Special Equipments (AREA)
  • Mechanical Treatment Of Semiconductor (AREA)
  • Registering, Tensioning, Guiding Webs, And Rollers Therefor (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
PCT/EP2001/011549 2000-10-17 2001-10-06 Reinigungsmaterial WO2002033039A1 (de)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP01987788A EP1326956B1 (de) 2000-10-17 2001-10-06 Reinigungsmaterial
US10/399,388 US20040031107A1 (en) 2000-10-17 2001-10-06 Cleaning material
AU2002223597A AU2002223597A1 (en) 2000-10-17 2001-10-06 Cleaning material
DE50105259T DE50105259D1 (de) 2000-10-17 2001-10-06 Reinigungsmaterial
AT01987788T ATE288473T1 (de) 2000-10-17 2001-10-06 Reinigungsmaterial
JP2002536409A JP4342177B2 (ja) 2000-10-17 2001-10-06 クリーニング材

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10051350A DE10051350A1 (de) 2000-10-17 2000-10-17 Reinigungsmaterial
DE10051350.6 2000-10-17

Publications (1)

Publication Number Publication Date
WO2002033039A1 true WO2002033039A1 (de) 2002-04-25

Family

ID=7660039

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2001/011549 WO2002033039A1 (de) 2000-10-17 2001-10-06 Reinigungsmaterial

Country Status (8)

Country Link
US (1) US20040031107A1 (ja)
EP (1) EP1326956B1 (ja)
JP (1) JP4342177B2 (ja)
AT (1) ATE288473T1 (ja)
AU (1) AU2002223597A1 (ja)
DE (2) DE10051350A1 (ja)
ES (1) ES2236337T3 (ja)
WO (1) WO2002033039A1 (ja)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7481893B2 (en) 2002-06-24 2009-01-27 Croda International Plc Cleaning textiles
US7621965B2 (en) 2003-04-29 2009-11-24 Croda International Plc Dry cleaning textiles with a composition containing one or more alcohol polyoxyalkylene derivatives and/or one or more benzoate or phenyl alkylcarboxylate esters
US8003591B2 (en) 2002-08-20 2011-08-23 Croda International Plc Method for conditioning textiles

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20060029145A (ko) * 2003-06-26 2006-04-04 시바 스페셜티 케미칼스 홀딩 인크. 사이클로덱스트린 또는 사이클로덱스트린 유도체의 수성액체 조성물 및 당해 조성물을 이용하는 공정
WO2007112916A1 (en) * 2006-04-01 2007-10-11 Sca Hygiene Products Gmbh Lather-forming tissue paper product
EP1918306A3 (en) * 2006-10-31 2008-05-14 The University of New Brunswick Antimicrobial and Bacteriostatic-Modified Polysaccharides
US7696145B2 (en) * 2007-06-20 2010-04-13 The Clorox Company Natural cleaning compositions
US7465700B1 (en) * 2007-06-20 2008-12-16 The Clorox Company Natural cleaning compositions
JP5061295B2 (ja) * 2007-07-09 2012-10-31 独立行政法人科学技術振興機構 機能性布帛処理剤及びこれを用いた機能性布帛の製造方法、並びに機能性布帛
US20090318321A1 (en) * 2008-06-20 2009-12-24 Hood Ryan K Natural Cleaning Compositions
DE102012004024A1 (de) * 2012-03-02 2013-09-05 Hawest Research AG Wundauflage
US10961487B2 (en) 2017-11-30 2021-03-30 Taiwan Semiconductor Manufacturing Company, Ltd. Semiconductor device cleaning solution, method of use, and method of manufacture
CN113748192B (zh) 2019-04-12 2023-08-29 埃科莱布美国股份有限公司 抗微生物多用途清洁剂及其制备和使用方法

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0033134A1 (de) * 1980-01-30 1981-08-05 Henkel Kommanditgesellschaft auf Aktien Mittel zum Nachbehandeln gewaschener Wäsche in einem Wäschetrockner
EP0273594A1 (en) * 1986-12-04 1988-07-06 Reckitt & Colman Inc. Disposable semi-moist wipes
DE4035378A1 (de) * 1990-11-07 1992-05-14 Oeffentliche Pruefstelle Und T Textiles material sowie verfahren zur herstellung eines derartigen textilen materials
US5630848A (en) * 1995-05-25 1997-05-20 The Procter & Gamble Company Dry cleaning process with hydroentangled carrier substrate
WO1998058114A1 (en) * 1997-06-16 1998-12-23 The Procter & Gamble Company Rolled dry cleaning article
WO1999055815A1 (en) * 1998-04-27 1999-11-04 The Procter & Gamble Company Improved uncomplexed cyclodextrin compositions for odor control
FR2789704A1 (fr) * 1999-02-15 2000-08-18 Univ Lille Sciences Tech Procede de traitement d'une fibre ou d'un materiau a base de fibres en vue d'ameliorer ses proprietes adsorbantes et fibre ou materiau a base de fibres presentant des proprietes adsorbantes ameliorees
WO2001048025A1 (en) * 1999-12-28 2001-07-05 Kimberly-Clark Worldwide, Inc. Cyclodextrins covalently bound to polysaccharides

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE124422T1 (de) * 1989-04-12 1995-07-15 Procter & Gamble Festes verbraucherprodukt, welches feinteilige cyclodextrin-komplexe enthält.
US5238587A (en) * 1991-03-20 1993-08-24 Creative Products Resource Associates, Ltd. Dry-cleaning kit for in-dryer use
DE4429229A1 (de) * 1994-08-18 1996-02-22 Consortium Elektrochem Ind Cyclodextrinderivate mit mindestens einem stickstoffhaltigen Heterozyklus, ihre Herstellung und Verwendung
DE19520967A1 (de) * 1995-06-08 1996-12-12 Consortium Elektrochem Ind Textiles Material oder Leder, welches mit Cyclodextrinderivaten mit mindestens einem stickstoffhaltigen Heterozyklus ausgerüstet ist
DE19810951B4 (de) * 1998-03-13 2005-09-29 Ciba Speciality Chemicals Holding Inc. Verwendung eines textilen Materials als transdermales Abgabesystem sowie Verfahren zu seiner Herstellung
US6842936B2 (en) * 1998-12-01 2005-01-18 The Procter & Gamble Company Adapter plates for cleaning implement
US6691536B2 (en) * 2000-06-05 2004-02-17 The Procter & Gamble Company Washing apparatus

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0033134A1 (de) * 1980-01-30 1981-08-05 Henkel Kommanditgesellschaft auf Aktien Mittel zum Nachbehandeln gewaschener Wäsche in einem Wäschetrockner
EP0273594A1 (en) * 1986-12-04 1988-07-06 Reckitt & Colman Inc. Disposable semi-moist wipes
DE4035378A1 (de) * 1990-11-07 1992-05-14 Oeffentliche Pruefstelle Und T Textiles material sowie verfahren zur herstellung eines derartigen textilen materials
US5630848A (en) * 1995-05-25 1997-05-20 The Procter & Gamble Company Dry cleaning process with hydroentangled carrier substrate
WO1998058114A1 (en) * 1997-06-16 1998-12-23 The Procter & Gamble Company Rolled dry cleaning article
WO1999055815A1 (en) * 1998-04-27 1999-11-04 The Procter & Gamble Company Improved uncomplexed cyclodextrin compositions for odor control
FR2789704A1 (fr) * 1999-02-15 2000-08-18 Univ Lille Sciences Tech Procede de traitement d'une fibre ou d'un materiau a base de fibres en vue d'ameliorer ses proprietes adsorbantes et fibre ou materiau a base de fibres presentant des proprietes adsorbantes ameliorees
WO2001048025A1 (en) * 1999-12-28 2001-07-05 Kimberly-Clark Worldwide, Inc. Cyclodextrins covalently bound to polysaccharides

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7481893B2 (en) 2002-06-24 2009-01-27 Croda International Plc Cleaning textiles
US7514396B2 (en) 2002-06-24 2009-04-07 Croda International Plc Method for cleaning textiles
US8003591B2 (en) 2002-08-20 2011-08-23 Croda International Plc Method for conditioning textiles
US7621965B2 (en) 2003-04-29 2009-11-24 Croda International Plc Dry cleaning textiles with a composition containing one or more alcohol polyoxyalkylene derivatives and/or one or more benzoate or phenyl alkylcarboxylate esters

Also Published As

Publication number Publication date
JP4342177B2 (ja) 2009-10-14
EP1326956B1 (de) 2005-02-02
DE50105259D1 (de) 2005-03-10
DE10051350A1 (de) 2002-04-25
JP2004517977A (ja) 2004-06-17
EP1326956A1 (de) 2003-07-16
AU2002223597A1 (en) 2002-04-29
ES2236337T3 (es) 2005-07-16
ATE288473T1 (de) 2005-02-15
US20040031107A1 (en) 2004-02-19

Similar Documents

Publication Publication Date Title
EP2212465B1 (de) Biozides textilbehandlungsmittel
EP1326956B1 (de) Reinigungsmaterial
DE102007056525A1 (de) Polyoxyalkylenamine zur verbesserten Duftausbeute
EP1812542A1 (de) Duftstoffkombination enthaltend 3, 7-dymethyl-6-en-nitril (citronellyl nitril) als genanoritril-substitut
EP1660621B1 (de) Auf substratoberflächen aufziehende mittel
EP2331671A1 (de) Textilspülmittel
WO2008135333A1 (de) Froststabiler weichspüler
EP1366141A1 (de) Konditioniermittel
EP1468068B1 (de) Konditioniermittel zur textilschonung
DE10039100A1 (de) Desodorierendes Textilbehandlungsmittel
WO2012016829A1 (de) Textilbehandlungsmittel zur entfernung von deodorant-flecken
EP3420063B1 (de) Wasch- oder reinigungsmittel mit verbesserter antimikrobieller wirkung
DE10203192A1 (de) Konditioniermittel zur Textilschonung
EP3636734A1 (de) Polyorganosiloxan-beschichteter und/oder mit amorphen siliziumdioxidbeschichteter textiler waschartikel
DE102009027047A1 (de) Waschtuch mit Farbfängereigenschaften
DE102009027046A1 (de) Waschtuch mit Schmutzfängereigenschaften
DE102009027048A1 (de) Waschtuch mit Wirkstoffdepot
DE102014203865A1 (de) Rohstoff und seine Verwendung
EP1948772A1 (de) Textilbehandlungsmittel mit einem milcherzeugnis
DE10159000A1 (de) Konditioniermittel mit verbesserter Wiederbenetzbarkeit
WO2002099179A2 (de) Bügelwasser
DE102006020383A1 (de) Textilbehandlungsmittel mit einem Milchprotein
DE102009002026A1 (de) Flüssige, Textil-pflegende Zusammensetzung mit Harnstoff

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU BR CA CN CZ DZ HU ID IL IN JP KR MX PL RO RU SG SI SK UA US ZA

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR

DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
121 Ep: the epo has been informed by wipo that ep was designated in this application
WWE Wipo information: entry into national phase

Ref document number: 2001987788

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 10399388

Country of ref document: US

Ref document number: 2002536409

Country of ref document: JP

WWP Wipo information: published in national office

Ref document number: 2001987788

Country of ref document: EP

WWG Wipo information: grant in national office

Ref document number: 2001987788

Country of ref document: EP