WO1999054289A1 - Verfahren zur herstellung von mischungen aus diphenylmethandiisocyanaten und polyphenylen-polymethylen-polyisocyanaten mit vermindertem gehalt an chlorierten nebenprodukten und verminderter jodfarbzahl - Google Patents
Verfahren zur herstellung von mischungen aus diphenylmethandiisocyanaten und polyphenylen-polymethylen-polyisocyanaten mit vermindertem gehalt an chlorierten nebenprodukten und verminderter jodfarbzahl Download PDFInfo
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- WO1999054289A1 WO1999054289A1 PCT/EP1999/002453 EP9902453W WO9954289A1 WO 1999054289 A1 WO1999054289 A1 WO 1999054289A1 EP 9902453 W EP9902453 W EP 9902453W WO 9954289 A1 WO9954289 A1 WO 9954289A1
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/10—Preparation of derivatives of isocyanic acid by reaction of amines with carbonyl halides, e.g. with phosgene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C263/00—Preparation of derivatives of isocyanic acid
- C07C263/18—Separation; Purification; Stabilisation; Use of additives
- C07C263/20—Separation; Purification
Definitions
- the subject of the invention is a process for the preparation of mixtures of diphenylmeti diisocyanates and polyphenylene-poly-methylene-polyisocyanates, so-called PMDI, with a reduced content of chlorinated by-products and a reduced iodine color number by two-stage reaction of the corresponding mixtures of diphenylmethane-diamines and polyphenylene-polymethylene-polyamines, so-called PMDA , with phosgene in the presence of at least one inert organic solvent, the corresponding carbamyl chlorides and amine hydrochlorides formed in the first stage of the phosgenation passing through a residence time apparatus in the second stage of the phosgenation, in which the amine hydrochlorides phosgenate to the corresponding carbamyl chlorides and the carbamyl chlorides to the corresponding isocyanates and hydrogen chloride are split and the mass ratios of phosgene to hydrogen chloride are simultaneously 10
- PMDI is the technically most important isocyanate for the production of polyurethane rigid foams, which are preferably used as insulation material in the construction industry, as insulating foam in the refrigeration cabinet industry and as a sandwich construction material.
- Part of the 4, 4 '-diphenylmethane diisocyanate contained therein, so-called MMDI is usually obtained from the PMDI by a suitable technological operation, such as, for example, distillation or crystallization.
- MMDI is an important component of polyurethane formulations of compact, microcellular and cellular polyurethanes, such as adhesives, coatings, fibers, elastomers and integral foams.
- the term "PMDI" in this document accordingly also defines PMDI mixtures which contain monomeric MDI, for example 4.4 ⁇ -, 2.2 - and / or 2.4 X -MDI.
- PMDI is produced by phosgenation of the corresponding PMDA in the presence of an inert organic solvent.
- PMDA for its part is obtained by an acidic aniline-formaldehyde condensation, which technically can be carried out either continuously or discontinuously.
- aniline, formaldehyde and acid catalyst as well as a suitable temperature and residence time
- the profiles of diphenylmethane diamines and the homologous polyphenylene-polymethylene-polyamines and their positional isomers are controlled in the PMDA using 2 profiles.
- Aniline-formaldehyde condensation process is the formation of undesirable by-products, e.g. the formation of N-methylated and N-formylated compounds and the formation of dihydroquinazolines, together.
- Technical PMDA may also contain residual amounts of non-rearranged aminobenzylanilines, which in turn can be the starting point for further reactions.
- Another disadvantage is that the acidic aniline-formaldehyde condensation forms chromophores which discolor the PMDA. These discolorations are not or only insufficiently reduced after the acidic condensation in the subsequent neutralization of the acidic condensation catalyst and the removal of the aniline used in the condensation in excess, and in the subsequent process stages of PMDI production.
- the PMDA is converted to PMDI with phosgene in an inert organic solvent.
- the unwanted by-products and chromophores in the PMDA can be combined with phosgene to form further compounds, e.g. secondary carbamyl chlorides and chlorination products on the aromatic nucleus and / or on the methylene bridge.
- other chlorine-bearing secondary compounds are formed in the phosgenation stage, e.g. Allophane chlorides and isonitrile dichlorides.
- the chlorine-bearing compounds and chromophores are incorporated both in the low molecular weight fraction, the essential component of which is diphenylmethane diisocyanate, and in the oligomeric fractions of the polyphenylene polymethylene polyisocyanate.
- Chlorine-containing and / or discolored PMDI is undesirable for further processing into polyisocyanate-polyalcohol polyaddition plastics.
- chlorine-containing compounds which can easily form ionic chloride in the sense of the determination method according to ASTM D 1638-74, can considerably disrupt the blowing reaction of the foam production by salt formation with the blowing catalyst.
- Undesired discoloration of the PMDI is also effective in the plastics made from them.
- the inherent color of the polyisocyanate-polyalcohol polyaddition plastics does not adversely affect their mechanical properties, they are bright
- this parameter can be reduced by adding isoureas in an amount of 25-250 mol% to the acidity according to ASTM D 1638-74 of the PMDI.
- the disadvantage here is that an additional agent must be used and the reduction in acidity is only incomplete.
- DD 285.593 proposes the treatment of PMDI with acid amides in an amount of 0.01-0.2% at 100-140 ° C within 0.2-6 hours. After the treatment, the hydrogen chloride formed is driven off by stripping with nitrogen or solvent vapors. The disadvantage of this process is the insufficient action of the acid amides and the formation of additional ones
- DE 2,847,243 proposes phosgene removal by stripping with gaseous hydrogen chloride or nitrogen at 170 ° C. within 2 hours.
- a disadvantage is the considerable amounts of gases loaded with phosgene or with phosgene / hydrogen chloride, which necessitate additional expenditure for the subsequent separation of substances or additional expenditure for the neutralization of the acidic gas components.
- the additional disadvantage of the long dwell time for stripping which is inherent in the process according to DE 2.847.243 is partially eliminated in JP 07.233.136 A by the two-stage stripping with hydrogen chloride after the phosgene removal at 115 ° C./30 minutes and 160 ° C./3 minutes .
- JP 07.233.136 A by the two-stage stripping with hydrogen chloride after the phosgene removal at 115 ° C./30 minutes and 160 ° C./3 minutes .
- organic phosphites are added to the aniline before the aniline-formaldehyde condensation.
- the object of the present invention was, while avoiding the disadvantages mentioned, to reduce the content of chlorinated by-products and the iodine color number of the PMDI in a mixture with MMDI, with the addition of auxiliaries and / or additional apparatus in particular being avoided.
- This object was surprisingly achieved by two-stage reaction of the corresponding mixtures containing diphenylmethane-diamines and polyphenylene-polymethylene-polyamines with phosgene in the presence of at least one inert organic solvent, the corresponding carbamyl chlorides and amine hydrochlorides formed in the first stage of the phosgenation Phosgenation run through a column as a residence apparatus, in which the amine hydrochlorides phosgenate to the corresponding carbamyl chlorides and the carbamyl chlorides 5 ride to the corresponding isocyanates and hydrogen chloride and the mass ratios of phosgene to hydrogen chloride are 10-30: 1 in the liquid phase and 1-10: 1 in the gas phase.
- the invention thus relates to a process for the preparation of mixtures containing diphenylmeti diisocyanates and polyphenylene-polymethylene polyisocyanates with a reduced content of chlorinated by-products and a reduced iodine color number by two-stage reaction of the corresponding mixtures containing diphenylmethane diamines and polyphenylene polymethylene polyamines with phosgene in the presence at least one inert organic solvent, which is characterized in that the carbamyl and a formed in the first stage of the phosgenation minhydrochloride in the second stage of the phosgenation run through a residence time in the phosgenation, the amine hydrochloride to give the corresponding carbamyl and carbamyl chlorides to a column corresponding isocyanates and hydrogen chloride are split and the mass ratios of phosgene to hydrogen chloride are simultaneously 10-30: 1 in the liquid phase and 1-10: 1 in the gas phase.
- 3,544,611 describes a distillation dwell apparatus working at 10-50 bar and 120-150 ° C. with an "extended distillation section"("elongated distillation zone") for splitting the carba- 6 mylchloride and removal of the hydrogen chloride.
- DE 3.744.001 describes a perforated plate column with a flow of from bottom to top with more than 10 perforated plates, a residence time of max. 120 minutes and liquid speeds of 0.05-4 m / s and gas speeds of 2-20 m / s are proposed.
- the drastic conditions in the residence time apparatus and the relatively long residence time of the raw PMDI formed are disadvantageous in the described methods of the prior art. Experience has shown that these processes only allow a very inadequate level of quality in terms of color and chlorine content in the PMDI.
- DE 3.744.001 combines a ring-hole nozzle as a reactor for the reaction of primary amines with phosgene in an inert solvent to give the corresponding carbamyl chlorides and amine hydrochlorides with one or more perforated-plate columns as an apparatus for phosgenating the amine hydrochlorides and carbamyl chloride cleavage.
- No. 3,381,025 carries out the first stage at ⁇ 60 ° C. in an inert solvent with a boiling point of 100-190 ° C.
- a further object of the present invention was therefore to reduce the content of chlorinated by-products and the iodine color number of the PMDI using technological equipment which is simple in terms of safety technology and apparatus.
- This object was surprisingly achieved by two-stage reaction of the PMDA with phosgene in the presence of at least one inert organic solvent, the first stage of the phosgenation being carried out in a static mixer and the second stage of the phosgenation in a column as a residence apparatus and in the column the mass ratios of phosgene to hydrogen chloride are simultaneously 10-30: 1 in the liquid phase and 1-10: 1 in the gas phase.
- the known and above-mentioned devices, in particular nozzles are used as static mixers for the first stage of phosgenation.
- the temperature in the first stage of phosgenation is usually 40 to 150 ° C., preferably 60 to 130 ° C., particularly preferably 90-120 ° C.
- the mixture of the first stage of phosgenation is fed to a column, the mass ratios of phosgene to hydrogen chloride in the column of the second stage of phosgenation being simultaneously in the liquid phase 10-30: 1 and in the gas phase 1-10: 1.
- the product mixture of the first stage of phosgenation is preferably fed into the column in such a way that the PMDI / solvent / phosgene mixture leaves the column through the bottom and a phosgene / hydrogen chloride mixture is drawn off at the top of the column and the hydrogen chloride / phosgene separation is fed .
- the entry temperature of the mixture of the first stage of phosgenation into the column can preferably be 80-120 ° C, particularly preferably 82-117 ° C.
- the bottom temperature of the column is preferably 80-120 ° C, particularly preferably 90-110 ° C.
- the top pressure of the column is preferably 1.0-4.7 at (Ü), particularly preferably 2.0-3.7 at (Ü).
- the hydrogen chloride / phosgene ratio in the column is set and controlled by the excess phosgene in the first stage of the phosgenation, the entry temperature of the reaction product into the column, the column pressure and the bottom temperature of the column.
- the total amount of phosgene can be supplied to the first stage of the phosgenation or only partially, in which case a further amount of phosgene is fed into the residence time apparatus of the second stage of the phosgenation.
- the column used preferably has ⁇ 10 theoretical plates. It is advantageous to preferably use a valve plate column.
- the mixtures of diphenylmethane diisocyanates and polyphenylene-polymethylene polyisocyanates produced by the process according to the invention usually have a diphenylmethane diisocyanate isomer content of 30 to 90% by weight, preferably 30 to 70% by weight, and an NCO content of 29 to 33 % By weight, preferably 30 to 32% by mass, based on the raw MDI weight, and a viscosity, determined in accordance with DIN 51550 at 25 ° C., of at most 2500 mPa.s, preferably from 40 to 2000 mPa. s.
- Crude MDA suitable for the process according to the invention are advantageously obtained by condensation of aniline and formaldehyde in a molar ratio of 6 to 1.6: 1, preferably 4 to 1.9: 1, and a molar ratio of aniline to acidic catalysts of 1: 0.98 to 0.01, preferably 1: 0.8 to 0.1.
- the formaldehyde is preferably in the form of an aqueous solution, e.g. used as a commercially available 30 to 50% by weight solution.
- Proton donors such as e.g. acidic ion exchange resins or strong organic and preferably inorganic acids have proven successful. Strong acids are those with a pKa value of less than 1.5; for polybasic acids, this value applies to the first hydrogen dissociation. Examples include hydrochloric acid, sulfuric acid, phosphoric acid, fluorosulfonic acid and oxalic acid. Hydrogen chloride can also be used in gaseous form. Aqueous hydrochloric acid is preferably used in concentrations of about 25 to 33% by mass.
- Phosgene is used as another starting component for the production of raw MDI.
- the gaseous phosgene can be used as such or in dilution with gases which are inert under the reaction conditions, such as nitrogen, carbon monoxide and others.
- the molar ratio of crude MDA to phosgene is expediently such that 1 to 10 mol, preferably 1.3 to 4 mol, of phosgene are present in the reaction mixture per mol of NH 2 group.
- the amount of phosgene can be fed completely to the first stage of the phosgenation or, in part, can also be added to the residence apparatus of the second stage of the phosgenation.
- Chlorinated, aromatic hydrocarbons for example monochlorobenzene, dichlorobenzenes, such as e.g. o-dichlorobenzene, p-dichlorobenzene, trichlorobenzenes, the corresponding toluenes and xylenes, chloroethylbenzene, monochlorodiphenyl, alpha- and beta-naphthyl chloride and phthalic acid dialkyl esters, such as iso-diethyl phthalate.
- Monochlorobenzene, dichlorobenzenes or mixtures of these chlorobenzenes are used in particular as inert organic solvents. The solvents can be used individually or as mixtures.
- a solvent is advantageously used which has a lower boiling point than the MDI isomers, so that the solvent can easily be separated from the crude MDI by distillation.
- the amount of solvent is expediently such that the reaction mixture has an isocyanate content of 2 to 40% by mass, preferably between 5 and 20% by mass, based on the total weight of the reaction mixture.
- the raw MDA can be used as such or dissolved in organic solvents.
- crude MDA solutions with an amine content of 2 to 45% by mass, preferably 25 to 44% by mass, based on the total weight of the amine solution are used.
- the excess phosgene, the hydrogen chloride and the solvent are preferably separated off from the reaction product.
- the residual content of phosgene after the phosgene removal is ⁇ 10 ppm of phosgene.
- the stabilizers are advantageously in an amount up to max. 1% by mass, preferably from 0.001 to 0.2% by mass.
- antioxidants based on sterically hindered phenols are: styrenated phenols, ie phenols which contain a 1-phenylethyl group bonded in the 2- or 4-position or in the 2- and 4- and / or 6-position, 10
- Tri- (alkylphenyl) phosphites with 1 to 10 carbon atoms in the alkyl radical such as e.g. Tri- (ethylphenyl) -, tri- (ethylphenyl) - tri- (n-propylphenyl) -, tri- (isopropylphenyl) -, tri- (n-butylphenyl) -, tri- (sec-butylphenyl), tri- ( tert.-butylphenyl, tri- (pentylphenyl) -, tri- (hexylphenyl) -, tri- (2-ethylhexylphenyl) -, tri- (octylphenyl) -, ri- (2-ethyl-octylphenyl) -, tri- (decylphenyl) phosphite and preferably tri- (nonylphenyl) phos
- the crude PMDI produced in this way are then usually subjected to a thermal aftertreatment which can be coupled with the removal of the MMDI isomers.
- the PMDI is heated to a temperature of 170-230 ° C, preferably 180-220 ° C, and at this temperature under a pressure of 0.01 to 100 mbar, preferably 0.1 to 20 mbar, for at least 5 minutes and in particular 5 to 45 minutes, optionally with the introduction of an amount of max. 5 Nm3 / t PMDI of an inert gas, e.g. Nitrogen, preferably max. 0.5 Nm3 / t PMDI inert gas, treated.
- an inert gas e.g. Nitrogen, preferably max. 0.5 Nm3 / t PMDI inert gas, treated.
- the PMDI is usually sent to intermediate storage.
- a PMDA of the following composition is used for phosgenation:
- the column is operated at a pressure of 4.3 bar (abs.) And the bottom composition is adjusted by choosing the amount of heating steam so that the phosgene content in the bottom of the column is about 10% by mass, which corresponds to a temperature in the bottom of the column of Corresponds to 95-97 ° C.
- the mass ratios of phosgene to hydrogen chloride are 14.2: 1 in the bottom of the column and 1.6: 1 in the top of the column.
- hydrogen chloride is taken off together with a part of the phosgene used in excess overhead at a temperature of 91 ° C.
- MCB is additionally fed into the top of the column in an amount of 1,350 kg / h.
- the mixture leaving the phosgenation is freed of phosgene and MCB in accordance with the prior art and thermally aftertreated.
- Example 2 For comparison, the same PMDA as in Example 1 is phosgenated in the same angular jet chamber nozzle and the same column. Likewise, 3840 kg / h of this PMDA as a 38.7 mass% solution in monochlorobenzene (MCB) at 26,400 kg / h will be a 42 mass%
- the inlet temperature of the PMDA / MCB stream to the angled jet nozzle is selected so that the temperature of the reaction mixture leaving the nozzle is 96 ° C.
- the reaction mixture enters the valve tray column at 78 ° C.
- the column is operated at a top pressure of 5.2 bar (abs.). With a bottom temperature set to 116 ° C, a head temperature of 76 ° C is set.
- the mass ratios of phosgene to hydrogen chloride are 9.2: 1 in the bottom of the column and 0.95: 1 in the top of the column.
- the PMDI produced as a comparison has the following product properties:
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Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE59907200T DE59907200D1 (de) | 1998-04-21 | 1999-04-12 | Verfahren zur herstellung von mischungen aus diphenylmethandiisocyanaten und polyphenylen-polymethylen-polyisocyanaten mit vermindertem gehalt an chlorierten nebenprodukten und verminderter jodfarbzahl |
US09/673,326 US6576788B1 (en) | 1998-04-21 | 1999-04-12 | Method for producing mixtures consisting of diphenylmethane diisocyanates and polyphenylene-polymethylene-polyisocyanates containing a reduced amount of chlorinated secondary products and with a reduced iodine color index |
JP2000544630A JP4583596B2 (ja) | 1998-04-21 | 1999-04-12 | ジフェニルメタンジイソシアネート及びポリフェニルポリメチレンポリイソシアネートを含み、塩素化副生物含有量及びヨウ素色数が共に低減された混合物の製造方法 |
EP99920644A EP1073628B1 (de) | 1998-04-21 | 1999-04-12 | Verfahren zur herstellung von mischungen aus diphenylmethandiisocyanaten und polyphenylen-polymethylen-polyisocyanaten mit vermindertem gehalt an chlorierten nebenprodukten und verminderter jodfarbzahl |
CA002329655A CA2329655A1 (en) | 1998-04-21 | 1999-04-12 | Method for producing mixtures consisting of diphenylmethane diisocyanates and polyphenylene-polymethylene-polyisocyanates containing a reduced amount of chlorinated secondary products and with a reduced iodine colour index |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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DE19817691.0 | 1998-04-21 | ||
DE19817691A DE19817691A1 (de) | 1998-04-21 | 1998-04-21 | Verfahren zur Herstellung von Mischungen aus Diphenylmehandiisocyanaten und Polyphenylen-polymethylen-polyisocyanaten mit vermindertem Gehalt an chlorierten Nebenprodukten und verminderter Jodfarbzahl |
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WO1999054289A1 true WO1999054289A1 (de) | 1999-10-28 |
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PCT/EP1999/002453 WO1999054289A1 (de) | 1998-04-21 | 1999-04-12 | Verfahren zur herstellung von mischungen aus diphenylmethandiisocyanaten und polyphenylen-polymethylen-polyisocyanaten mit vermindertem gehalt an chlorierten nebenprodukten und verminderter jodfarbzahl |
Country Status (8)
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US (1) | US6576788B1 (de) |
EP (1) | EP1073628B1 (de) |
JP (1) | JP4583596B2 (de) |
KR (1) | KR100601243B1 (de) |
CN (1) | CN1160319C (de) |
CA (1) | CA2329655A1 (de) |
DE (2) | DE19817691A1 (de) |
WO (1) | WO1999054289A1 (de) |
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Cited By (19)
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WO2004056760A1 (de) * | 2002-12-19 | 2004-07-08 | Basf Aktiengesellschaft | Verfahren zur herstellung von (cyclo)aliphatischen isocyanaten |
US7851648B2 (en) | 2002-12-19 | 2010-12-14 | Basf Aktiengesellschaft | Method for the continuous production of isocyanates |
WO2004056756A1 (de) | 2002-12-19 | 2004-07-08 | Basf Aktiengesellschaft | Verfahren zur kontinuierlichen herstellung von isocyanaten |
WO2004058689A1 (de) * | 2002-12-20 | 2004-07-15 | Basf Aktiengesellschaft | Verfahren zur herstellung von isocyanaten |
EP1561745A2 (de) * | 2004-02-04 | 2005-08-10 | Bayer MaterialScience AG | Herstellung von Di- und Polyisocyanaten der Diphenylmethanreihe mit definierter Acidität |
EP1561745A3 (de) * | 2004-02-04 | 2006-03-08 | Bayer MaterialScience AG | Herstellung von Di- und Polyisocyanaten der Diphenylmethanreihe mit definierter Acidität |
EP3181548A1 (de) * | 2004-02-04 | 2017-06-21 | Covestro Deutschland AG | Herstellung von di- und polyisocyanaten der diphenylmethan-reihe mit definiertem gehalt an hydrolysierbarem chlor |
EP1854783A3 (de) * | 2006-05-13 | 2009-06-03 | Bayer MaterialScience AG | Verfahren zur Herstellung von Isocyanaten |
US8329951B2 (en) | 2007-01-08 | 2012-12-11 | Basf Se | Process for preparing diphenylmethanediamine |
US8431746B2 (en) | 2008-05-26 | 2013-04-30 | Basf Se | Method for producing diphenylmethane diamine |
WO2011006807A3 (en) * | 2009-07-14 | 2011-12-22 | Basf Se | Process for preparing light-coloured isocyanates of the diphenylmethane series |
US8748655B2 (en) | 2009-07-14 | 2014-06-10 | Basf Se | Process for preparing light-coloured isocyanates of the diphenylmethane series |
US8759585B2 (en) | 2009-12-18 | 2014-06-24 | Basf Se | Two-stage process for cost-effective deposition of homogeneous catalysts in MDA synthesis |
WO2011080059A1 (de) | 2009-12-18 | 2011-07-07 | Basf Se | Zweistufiges verfahren zur kostengünstigen abscheidung von homogenen katalysatoren bei der mda-synthese |
US10093615B2 (en) | 2014-04-23 | 2018-10-09 | Basf Se | Process for preparing isocyanates in dialkyl carbonates as solvent |
US10435354B2 (en) | 2014-04-23 | 2019-10-08 | Basf Se | Process for preparing isocyanates in dialkyl carbonates as solvent |
WO2017001322A1 (de) | 2015-06-29 | 2017-01-05 | Covestro Deutschland Ag | Verfahren zur herstellung von polyisocyanaten |
WO2020163092A1 (en) | 2019-02-07 | 2020-08-13 | Dow Global Technologies Llc | Phenyl isocyanate conversion process |
WO2022048930A1 (en) | 2020-09-01 | 2022-03-10 | Basf Se | Process for producing isocyanates |
Also Published As
Publication number | Publication date |
---|---|
DE19817691A1 (de) | 1999-10-28 |
CN1160319C (zh) | 2004-08-04 |
JP4583596B2 (ja) | 2010-11-17 |
DE59907200D1 (de) | 2003-11-06 |
CA2329655A1 (en) | 1999-10-28 |
EP1073628A1 (de) | 2001-02-07 |
KR20010034813A (ko) | 2001-04-25 |
JP2003522725A (ja) | 2003-07-29 |
CN1298385A (zh) | 2001-06-06 |
EP1073628B1 (de) | 2003-10-01 |
KR100601243B1 (ko) | 2006-07-19 |
US6576788B1 (en) | 2003-06-10 |
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