WO1999000108A1 - Improved cosmetic composition containing ferulic acid esters - Google Patents

Improved cosmetic composition containing ferulic acid esters Download PDF

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Publication number
WO1999000108A1
WO1999000108A1 PCT/EP1998/003187 EP9803187W WO9900108A1 WO 1999000108 A1 WO1999000108 A1 WO 1999000108A1 EP 9803187 W EP9803187 W EP 9803187W WO 9900108 A1 WO9900108 A1 WO 9900108A1
Authority
WO
WIPO (PCT)
Prior art keywords
ferulic acid
composition according
weight
glycol
esters
Prior art date
Application number
PCT/EP1998/003187
Other languages
English (en)
French (fr)
Inventor
Brian Andrew Crotty
Alexander Paul Znaiden
Anthony William Johnson
Original Assignee
Unilever Plc
Unilever N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever Plc, Unilever N.V. filed Critical Unilever Plc
Priority to BR9810307-5A priority Critical patent/BR9810307A/pt
Priority to CA002293800A priority patent/CA2293800A1/en
Priority to EP98929397A priority patent/EP0975323B1/en
Priority to AU79168/98A priority patent/AU726832B2/en
Priority to DE69813540T priority patent/DE69813540T2/de
Priority to JP50524099A priority patent/JP2002507970A/ja
Publication of WO1999000108A1 publication Critical patent/WO1999000108A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/894—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a polyoxyalkylene group, e.g. cetyl dimethicone copolyol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/895—Polysiloxanes containing silicon bound to unsaturated aliphatic groups, e.g. vinyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin

Definitions

  • the invention relates to enhancing the activity of ferulic acid in cosmetic compositions.
  • Oryzanol esters of ferulic acid reports the oryzanol esters of ferulic acid as being active against dry skin, as well as suppressing dandruff and itchiness.
  • Oryzanol is a triterpene alcohol.
  • Oryzanol ferulate esters have been reported in JP 52/55037 (Eisai) as naturally deepening the black color tone of hair and skin.
  • JP 59/067213 (Suga) describes ferulate esters as having antioxidant properties, especially for alleviating effects of ultraviolet rays on polyunsaturated fatty acids.
  • JP 53/10526 (Eisai) connects both the acid and the oryzanol esters to the prevention of skin aging and wrinkling.
  • Another object of the present invention is to provide cosmetic compositions containing ferulic acid or its esters which function to lighten skin and provide an antioxidant effect .
  • a cosmetic composition includes:
  • ferulic acid or its C 1 -C 30 esters can have their skin lightening, antioxidant and other skin activities enhanced through use of dimethylisosorbide in a pharmaceutically acceptable carrier.
  • Dimethyl isosorbide is known in Chemical Abstracts as 1,4:3,6 dianhydro-2 , 5-di-o-methyl-D-glucitol .
  • Ferulic acid is available from several sources including Seltzer Chemicals, Inc., Carlsbad, California.
  • Esters of ferulic acid are derived from esterification with a C 1 -C 30 alcohol. Examples include methyl ferulate, ethyl ferulate, isopropyl ferulate, octyl ferulate and oryzanyl ferulate.
  • Amounts of ferulic acid or its esters may range from 0.01 to 5%, preferably from 0.1 to 3%, optimally from 1 to 2% by weight of the cosmetic composition.
  • compositions of this invention usually require a pharmaceutically acceptable carrier.
  • the carrier will be an ingredient present in highest amounts in the cosmetic composition. These amounts may range from 10 to 99.9%, preferably from 25 to 90%, optimally from 50 to 85% by weight of the cosmetic composition.
  • Carriers typically include polyols, silicones, carboxylic esters and combinations thereof.
  • Polyols are particularly suitable as carriers in the compositions of this invention.
  • Illustrative are propylene glycol, dipropylene glycol, polypropylene glycol, polyethylene glycol, sorbitol, hydroxypropyl sorbitol, hexylene glycol, 1,3-butylene glycol, 1 , 2 , 6-hexanetriol , glycerin, ethoxylated glycerin, propoxylated glycerin and mixtures thereof.
  • the polyol is a mixture of polyethylene glycol, molecular weight ranging from 200 to 2,000, and propylene glycol.
  • Preferred weight ratios of polyethylene glycol to propylene glycol range from 5:1 to 1:10, preferably from 2:1 to 1:5, optimally 1:1 to 1:2. Amounts of the polyol may range from 1 to 50%, preferably from 10 to 40%, optimally from 25 to 35% by weight of the cosmetic composition. Silicone oils may also be included as carriers in the compositions of this invention. These oils may be either volatile or nonvolatile. The term "volatile" as used herein refers to those materials which have a measurable vapor pressure at ambient temperature. Volatile silicone oils are preferably chosen from cyclic or linear polydimethyl- siloxanes containing from about 3 to about 9, preferably from about 4 to about 5, silicon atoms.
  • Cyclomethicone is the common name of the preferred volatile silicone oil and is available as a tetramer or pentamer. Amounts of the volatile siloxane will range from 10 to 80%, preferably from 20 to 70%, optimally from 30 to 65% by weight of the composition.
  • Linear volatile silicone materials generally have viscosities less than about 5 centistokes at 25°C while cyclic materials typically have viscosities of less than about 10 centistokes.
  • Examples of preferred volatile silicone oils useful herein include: DC 344, DC 345, DC 244 and DC 245 (manufactured by Dow Corning Corp.); Silicone 7207 and Silicone 7158 (manufactured by the Union Carbide Corp.); SF 1202 (manufactured by General Electric) ; and S S-03314 (manufactured by SWS Silicones, Inc.).
  • the nonvolatile silicone oils useful in compositions of this invention are exemplified by the polyalkyl siloxanes, polyalklyaryl siloxanes and polyether siloxane copolymers .
  • the essentially nonvolatile polyalkyl siloxanes useful herein include, for example, polydimethylsiloxanes with viscosities of from about 5 to about 100,000 centistokes at 25°C.
  • the preferred nonvolatile silicones useful in the present compositions are the polydimethylsiloxanes having viscosities from about 10 to about 400 centistokes at 25°C.
  • polyalkyl siloxanes include the Viscasil series (sold by General Electric Company) and the Dow Corning 200 series (sold by Dow Corning Corporation) .
  • Polyalkylaryl siloxanes include poly (methylphenyl ) siloxanes having viscosities of from about 15 to about 65 centistokes at 25°C. These are available, for example, as SF 1075 methylphenyl fluid (sold by General Electric Company) and 556 Cosmetic Grade Fluid (sold by Dow Corning Corporation) .
  • Useful polyether siloxane copolymers include, for example, a polyoxyalkylene ether copolymer having a viscosity of about 1200 to 1500 centistokes at 25°C.
  • Such a fluid is available as SF-1066 organosilicone surfactant (sold by General Electric Company) .
  • Cetyl dimethicone copolyol and cetyl dimethicone are especially preferred because these materials also function as emulsifiers and emollients.
  • the former material is available from Goldschmidt AG under the trademark Abil EM-90.
  • Amounts of the nonvolatile siloxane may range from 0.1 to 40%, preferably from 0.5 to 25% by weight of the composition.
  • Esters may also be incorporated into the cosmetic compositions as pharmaceutically acceptable carriers. Amounts may range from 0.1 to 50% by weight of the composition. Among the esters are:
  • Alkyl esters of fatty acids having 10 to 20 carbon atoms are useful herein. Examples include hexyl laurate, isohexyl laurate, isohexyl palmitate, isopropyl palmitate, decyl oleate, isodecyl oleate, hexadecyl stearate, decyl stearate, isopropyl isostearate, diisopropyl adipate, diisohexyl adipate, dihexyldecyl adipate, diisopropyl sebacate, lauryl lactate, myristyl lactate, and cetyl lactate. Particularly preferred are C 12 -C 15 alcohol benzoate esters .
  • Alkenyl esters of fatty acids having 10 to 20 carbon atoms examples thereof include oleyl myristate, oleyl stearate, and oleyl oleate.
  • Ether-esters such as fatty acid esters of ethoxylated fatty alcohols.
  • Ethylene glycol mono and di-fatty acid esters diethylene glycol mono- and di-fatty acid esters, polyethylene glycol (200-6000) mono- and di-fatty acid esters, propylene glycol mono- and di-fatty acid esters, polypropylene glycol 2000 monooleate, polypropylene glycol 2000 monostearate, ethoxylated propylene glycol monostearate, glyceryl mono- and di-fatty acid esters, polyglycerol poly-fatty esters, ethoxylated glyceryl monostearate, 1,3-butylene glycol monostearate, 1,3-butylene glycol distearate, polyoxyethylene polyol fatty acid ester, sorbitan fatty acid esters, and polyoxyethylene sorbitan fatty acid esters are satisfactory polyhydric alcohol esters.
  • Wax esters such as beeswax, spermaceti, myristyl myristate, stearyl stearate.
  • Sterols esters of which cholesterol fatty acid esters are examples thereof.
  • Aesthetic properties and stabilization of emulsions incorporating ferulic acid or its esters and dimethylisosorbide combination may be improved through addition of a crosslinked non-emulsifying siloxane elastomer.
  • Average number molecular weight of these elastomers should be in excess of 1,000, preferably in excess of 1 million and optimally will range from 10,000 to 20 million.
  • non-emulsifying defines a siloxane from which polyoxyalkylene units are absent.
  • the elastomers are formed from a divinyl compound, particularly a polymer with at least two free vinyl groups, reacting with Si-H linkages of a polysiloxane backbone such as a molecularly spherical MQ resin.
  • Elastomer compositions are commercially available from the General Electric Company under product designation General Electric Silicone 1229 with proposed CTFA name of Cyclomethicone and Vinyl Dimethicone/Methicone Cross Polymer, delivered as 20-35% elastomer in a cyclomethicone carrier.
  • a related elastomer composition under the CTFA name of Crosslinked Stearyl Methyl Dimethyl Siloxane Copolymer is available as Gransil SR-CYC (25-35% elastomer in cyclomethicone) from Grant Industries, Inc., Elmwood Park, New Jersey.
  • Amounts of the elastomer may range from 0.1 to 30%, optimally from 1 to 25%, most preferably from 10 to 20% by weight of the composition.
  • Minor adjunct ingredients may also be included in cosmetic compositions of this invention. These ingredients may be selected from preservatives, fragrances, anti-foam agents, opacifiers, colorants and mixtures thereof, each in their effective amounts to accomplish their respective functions.
  • Formula B Base + 0.5% Ferulic acid
  • Formula C Base + 0.5% Ferulic acid + 10% Dimethyl isosorbide. Evaluations were conducted with a Rapid In-Vivo Screening test. Approximately 20 subjects participated. The test involved the radiation of a selected area covered with test product on an individual's skin for approximately two minutes. Observation of the exposed area was then performed at 72 hours, 120 hours and 160 hours. The following scale was employed.
  • the present evaluation reflects anti-oxidant activity which interferes with the skin tanning response. In essence this test measures a material's biological tanning preventative activity.
  • the present invention and its materials should not be considered limited by the aforementioned mechanistic theory; other mechanistic pathways may be operative.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
PCT/EP1998/003187 1997-06-27 1998-05-27 Improved cosmetic composition containing ferulic acid esters WO1999000108A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BR9810307-5A BR9810307A (pt) 1997-06-27 1998-05-27 Composição cosmética.
CA002293800A CA2293800A1 (en) 1997-06-27 1998-05-27 Improved cosmetic composition containing ferulic acid esters
EP98929397A EP0975323B1 (en) 1997-06-27 1998-05-27 Improved cosmetic composition containing ferulic acid esters
AU79168/98A AU726832B2 (en) 1997-06-27 1998-05-27 Improved cosmetic composition containing ferulic acid esters
DE69813540T DE69813540T2 (de) 1997-06-27 1998-05-27 Kosmetische zusammensetzung enthaltend ferulasäureester
JP50524099A JP2002507970A (ja) 1997-06-27 1998-05-27 フェルラ酸エステルを含む改良された化粧品組成物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/884,177 1997-06-27
US08/884,177 US5824326A (en) 1997-06-27 1997-06-27 Activity enhancement of ferulic acid with dimethyl isosorbride in cosmetic compositions

Publications (1)

Publication Number Publication Date
WO1999000108A1 true WO1999000108A1 (en) 1999-01-07

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PCT/EP1998/003187 WO1999000108A1 (en) 1997-06-27 1998-05-27 Improved cosmetic composition containing ferulic acid esters

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US (1) US5824326A (US06559137-20030506-C00182.png)
EP (1) EP0975323B1 (US06559137-20030506-C00182.png)
JP (1) JP2002507970A (US06559137-20030506-C00182.png)
CN (1) CN1101179C (US06559137-20030506-C00182.png)
AU (1) AU726832B2 (US06559137-20030506-C00182.png)
BR (1) BR9810307A (US06559137-20030506-C00182.png)
CA (1) CA2293800A1 (US06559137-20030506-C00182.png)
DE (1) DE69813540T2 (US06559137-20030506-C00182.png)
ES (1) ES2196569T3 (US06559137-20030506-C00182.png)
IN (1) IN190070B (US06559137-20030506-C00182.png)
WO (1) WO1999000108A1 (US06559137-20030506-C00182.png)
ZA (1) ZA984029B (US06559137-20030506-C00182.png)

Cited By (9)

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DE10113053A1 (de) * 2001-03-15 2002-09-19 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen mit anorganischen Gelbildnern und organischen Hydrololloiden
DE10113048A1 (de) * 2001-03-15 2002-09-19 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen mit partikulären hydrophoben und/oder hydrophobisierten und/oder ölabsorbierenden Festkörpersubstanzen
DE10113051A1 (de) * 2001-03-15 2002-09-19 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen mit anorganischen Gelbildnern und partikulären hydrophoben und/oder hydrophobisierten und/oder ölabsorbierenden Festkörpersubstanzen
DE10113050A1 (de) * 2001-03-15 2002-09-19 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen organischen Hydrokolloiden
DE10113047A1 (de) * 2001-03-15 2002-09-26 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen mit anorganischen Gelbildnern
DE10113054A1 (de) * 2001-03-15 2002-09-26 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen mit anorganischen Gelbildnern, organischen Hydrokolloiden und partikulären hydrophoben und/oder hydrophobisierten und/oder ölabsorbierenden Festkörpersubstanzen
DE10113046A1 (de) * 2001-03-15 2002-09-26 Beiersdorf Ag Selbstschäumende schaumförmige Zubereitungen mit organischen Hydrokolliden und partikulären hydrophobisierten und/oder ölabsorbierenden Festkörpersubstanzen
EP1067901B1 (en) * 1998-04-03 2003-01-02 Colgate-Palmolive Company Low residue cosmetic composition
WO2022139458A1 (ko) * 2020-12-23 2022-06-30 주식회사 엘지생활건강 피부 개선용 조성물

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FR2900048B1 (fr) * 2006-04-21 2012-11-16 Oreal Compositions comprenant un derive diphenyl-methane hydroxyle
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EP2200573B1 (en) * 2007-09-08 2017-08-23 ELC Management LLC Resveratrol ferulate compounds, compositions containing the compounds, and methods of using the same
EP2060261B1 (en) * 2007-11-13 2016-03-09 Athenion AG C-19 steroids for cosmetic uses
DK2500062T3 (en) 2007-11-13 2015-09-21 Curadis Gmbh C-19 steroids to specific therapeutic applications,
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CN102353572A (zh) * 2011-06-30 2012-02-15 上海相宜本草化妆品股份有限公司 用于检测化妆品中阿魏酸的标准物质的配制方法
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CN112120952A (zh) * 2019-06-25 2020-12-25 上海家化联合股份有限公司 高含量阿魏酸的水包水组合物
EP4084775A4 (en) * 2019-12-30 2023-10-11 L'oreal WATER-FREE COMPOSITION FOR CARE OF KERATIN MATERIALS
CN116437894A (zh) 2020-08-31 2023-07-14 莱雅公司 用于护理角蛋白材料的组合物
CN114869790B (zh) * 2022-06-08 2023-09-15 上海上水和肌生物科技有限公司 包含阿魏酸的抗氧化组合物及其护肤品和应用
CN116370328B (zh) * 2023-06-05 2023-07-28 深圳市护家科技有限公司 一种皮肤护理组合物和外用皮肤制剂

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Cited By (9)

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Publication number Priority date Publication date Assignee Title
EP1067901B1 (en) * 1998-04-03 2003-01-02 Colgate-Palmolive Company Low residue cosmetic composition
DE10113053A1 (de) * 2001-03-15 2002-09-19 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen mit anorganischen Gelbildnern und organischen Hydrololloiden
DE10113048A1 (de) * 2001-03-15 2002-09-19 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen mit partikulären hydrophoben und/oder hydrophobisierten und/oder ölabsorbierenden Festkörpersubstanzen
DE10113051A1 (de) * 2001-03-15 2002-09-19 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen mit anorganischen Gelbildnern und partikulären hydrophoben und/oder hydrophobisierten und/oder ölabsorbierenden Festkörpersubstanzen
DE10113050A1 (de) * 2001-03-15 2002-09-19 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen organischen Hydrokolloiden
DE10113047A1 (de) * 2001-03-15 2002-09-26 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen mit anorganischen Gelbildnern
DE10113054A1 (de) * 2001-03-15 2002-09-26 Beiersdorf Ag Selbstschäumende oder schaumförmige Zubereitungen mit anorganischen Gelbildnern, organischen Hydrokolloiden und partikulären hydrophoben und/oder hydrophobisierten und/oder ölabsorbierenden Festkörpersubstanzen
DE10113046A1 (de) * 2001-03-15 2002-09-26 Beiersdorf Ag Selbstschäumende schaumförmige Zubereitungen mit organischen Hydrokolliden und partikulären hydrophobisierten und/oder ölabsorbierenden Festkörpersubstanzen
WO2022139458A1 (ko) * 2020-12-23 2022-06-30 주식회사 엘지생활건강 피부 개선용 조성물

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BR9810307A (pt) 2000-09-19
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US5824326A (en) 1998-10-20
CA2293800A1 (en) 1999-01-07
ZA984029B (en) 1999-11-15
EP0975323A1 (en) 2000-02-02
ES2196569T3 (es) 2003-12-16
EP0975323B1 (en) 2003-04-16
AU726832B2 (en) 2000-11-23
DE69813540D1 (de) 2003-05-22
IN190070B (US06559137-20030506-C00182.png) 2003-06-07
CN1101179C (zh) 2003-02-12

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