WO1997038038A1 - Copolymeres de terephtalate d'ethylene et de 2,6-naphtalene-dicarboxylate d'ethylene destines a des bouteilles - Google Patents
Copolymeres de terephtalate d'ethylene et de 2,6-naphtalene-dicarboxylate d'ethylene destines a des bouteilles Download PDFInfo
- Publication number
- WO1997038038A1 WO1997038038A1 PCT/JP1997/001127 JP9701127W WO9738038A1 WO 1997038038 A1 WO1997038038 A1 WO 1997038038A1 JP 9701127 W JP9701127 W JP 9701127W WO 9738038 A1 WO9738038 A1 WO 9738038A1
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- WIPO (PCT)
- Prior art keywords
- acid
- ethylene
- copolymer
- dicarboxylic
- glycol
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/185—Acids containing aromatic rings containing two or more aromatic rings
- C08G63/187—Acids containing aromatic rings containing two or more aromatic rings containing condensed aromatic rings
- C08G63/189—Acids containing aromatic rings containing two or more aromatic rings containing condensed aromatic rings containing a naphthalene ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
- Y10T428/1397—Single layer [continuous layer]
Definitions
- the present invention relates to an ethylene terephthalate / ethylene 2,2,6-naphthalene dicarboxylate copolymer for bottles. More specifically, ethylene terephthalene ethylene 1, 2, 6-naphthene is useful as a colorless bottle polymer having excellent gas barrier properties and transparency and having excellent ultraviolet blocking properties. Related to polymers. Background art
- PEN Polyethylene-1,2-naphthalene dicarboxylate
- PET polyethylene terephthalate
- PEN Polyethylene-1,2-naphthalene dicarboxylate
- PET polyethylene terephthalate
- PEN polyethylene terephthalate
- packaging materials as for materials used for beverage bottles such as juice, materials with excellent hue and transparency are strongly demanded from the viewpoint of commercial value.
- PEN can basically be reacted with the same catalyst system as PET, and it is expected that germanium dioxide will be effective particularly as a IB cocatalyst in terms of hue.
- JP-A-67-178828 discloses a process for producing a polyester by a transesterification reaction and a subsequent polycondensation reaction, wherein (a) a catalytic amount of an antimony compound, and (b) a glycol soluble Manganese compounds and / or magnesium compounds, (c) ⁇
- the compound and (d) at least one phosphorous compound selected from phosphorous acid, phosphorous acid and esters thereof are used, and the component (b) and the component (c) are represented by the following formula (1) ⁇ (3):
- M is the amount of component (b) used (mmo 1% total acid component)
- A is the amount of component (c) used (mmo 1% / total acid component).
- Japanese Patent Application Laid-Open No. Hei 7-2223623 discloses that ethylene glycol is an alcohol component containing 85 to 95 mol% of terephthalic acid and 5 to 15 mol% of 2,6-naphthalenedicarboxylic acid as an acid component.
- a heat-resistant bottle comprising a polyester copolymer having a glass transition temperature of 75 ° C. or higher when containing water of 3000 ppm or more is disclosed.
- this publication only discloses the use of calcium acetate as an ester prejudice catalyst. Polyester produced by using an organic acid calcium such as calcium acetate as an ester conversion catalyst has good original color of the polymer, but tends to generate a large amount of large precipitated particles, which causes whitening during bottle blow molding.
- Still another object of the present invention is to provide a bottle comprising the above copolymer of the present invention.
- the molar ratio of the terephthalic acid component to 2.6—naphthene range carboxylic acid component is 80/20 to 95Z5, and the following formulas (1) to (5):
- Mn is the ratio of manganese to all dicarboxylic acid components (mmo 1%) constituting the copolymer
- Mg is the ratio of magnesium to all dicarboxylic acid components (mmo 1%).
- C 0 is the same
- the ratio of cobalt to carboxylic acid (mmo 1%), and the ratio of phosphorus to dicarboxylic acid (mmo 1%) is manganese, magnesium, and phosphorus. This is achieved by an ethylene-terephthalone monoethylene 1,2,6-naphthalenedicarboxylate copolymer for bottles, characterized by optionally containing a cobalt.
- the main dicarboxylic acid of the ethylene terephthalate / ethylene 1,2-naphthylene dicarboxylate copolymer of the present invention (hereinafter sometimes referred to as the ETZ EN copolymer of the present invention) is terephthalic acid.
- 2,6-naphthene dicarboxylic acid is preferably at least 90 mol%, more preferably at least 95 mol%, and particularly preferably at least 98 mol% of the total dicarboxylic acids with terephthalic acid 2, 6 —Naphthene Consists of a range carboxylic acid.
- the copolymerization ratio of terephthalic acid and 2,6-naphthylenedicarboxylic acid is from 800 to 95 Z5 in molar ratio.
- ET / EN copolymers containing less than 5 mol% of 2,6-naphthalenedicarboxylic acid the bottles produced therefrom easily deform when hot water at 95 ° C is brought into contact with the bottle mouth.
- the advantage of heat resistance cannot be obtained because the mouth is loosened.
- the gas barrier properties and ultraviolet shielding properties are not different from PET.
- dicarboxylic acids other than terephthalic acid and 2,6-naphthylenedicarboxylic acid may be any of aliphatic dicarboxylic acids, alicyclic dicarboxylic acids, and aromatic dicarboxylic acids.
- dicarboxylic acids include fatty acids such as oxalic acid, malonic acid, succinic acid, adibic acid, sebacic acid, dodecanedicarboxylic acid, and the like.
- Aromatic dicarboxylic acids such as 4.4'-dicarboxylic acid
- alicyclic dicarboxylic acids such as hexahydroterephthalic acid, decalindicarboxylic acid, and tetralindicarboxylic acid.
- dicarboxylic acid components account for preferably less than 10 mol% of the total dicarboxylic acid components.
- the ET / EN copolymer of the present invention contains ethylen glycol as a main glycol component.
- Ethylene glycol accounts for preferably at least 90 mol%, more preferably at least 95 mol%, particularly preferably at least 98 mol% of the total glycol component.
- glycols other than ethylene glycol may be any of aliphatic group-containing polyols, aromatic diols and alicyclic diols.
- Such other glycols include, for example, aliphatic diols such as tetramethylene glycol, propylene glycol, 1,3-butanediol, neopentyl glycol; cyclohexanedimethanol, trisic Alicyclic diols such as rodecane dimethylol; aromatic diols such as bisphenol A, bisphenol S, bishydroxyethoxy ethoxy bisphenol A, and tetrabromobisphenol A; These other glycols make up preferably less than 10 mol% of the total glycol components.
- the ETEN copolymer of the present invention can further contain an oxyacid component such as p-oxybenzoic acid. These amounts can be substituted for less than 10 mol% of the total dicarboxylic acid component. Further, the ETEN copolymer of the present invention may contain, for example, a trifunctional or higher polyfunctional carboxylic acid or a polyhydroxy compound such as trimethyl acid in an amount of 2 mol% or less based on the total acid components. And pentaerythritol and the like.
- the ETZEN copolymer of the present invention can be produced, for example, by subjecting the corresponding dicarboxylic acid diester and glycol to an ester conversion reaction (hereinafter sometimes referred to as an EI reaction) followed by polycondensation.
- an ester conversion reaction hereinafter sometimes referred to as an EI reaction
- the ET / EN copolymer of the present invention contains manganese (Mn), magnesium (Mg), phosphorus (P) and optionally cobalt (P) at a ratio satisfying the above formulas (1) to (5).
- C o manganese
- Mn, Mg and C0 can be derived from the ester conversion reaction catalyst used in the ester conversion reaction.
- the manganese compound, magnesium compound and cobalt compound used as the ester conversion catalyst include, for example, oxides, chlorides, carbonates and carbonates of manganese, magnesium and cobalt, respectively. Of these, manganese acetate, magnesium acetate and cobalt acetate are particularly preferred.
- the ETZEN copolymer of the present invention contains the above Mn, Mg and Co at a ratio satisfying the following formulas (1) to (4).
- Mn and Mg may be zero (not included), but at least one of them is contained.
- the above formula (4) if the amount of Mn + lZ2Mg is less than 15 mmol% (millimol%) with respect to the total acid components, the EI reaction activity is low and the EI reaction time becomes extremely long. Inconvenience in production.
- the ETZEN copolymer of the present invention produced with a Mn or Mg-based catalyst has the advantage that the coloring of the polymer can be suppressed even when the intrinsic viscosity is relatively high by melt polymerization.
- a Ti-based catalyst is known as an EI catalyst that tends to have a small amount of precipitated particles.However, a polymer produced using a Ti-based catalyst has a too strong yellow tint and is not suitable for bottles. It is.
- the ET / EN copolymer of the present invention has a relatively low melting point, so that solid-state polymerization must be carried out at a relatively low temperature. It is not practical to try to produce the ETZEN copolymer of the present invention with a Ti-based catalyst.
- a C0-based catalyst is known as an EI catalyst that suppresses coloration.
- the force ⁇ C0-based catalyst is hard to dissolve sufficiently in the polymer, so that the precipitated particles act as polymer crystal nuclei, During bottle blow molding, the bottle is crystallized and whitened. Therefore, it is not desirable to use a large amount of a Co-based catalyst as an EI catalyst.
- the ETZEN copolymer of the present invention contains a small amount of C0 so as to satisfy the above formula (3).
- the added amount of the Co compound exceeds 5 mm 01% based on the total acid components, the color of the polymer becomes gray and the color is deteriorated.
- the EEN copolymer of the present invention further contains phosphorus depending on the phosphorus compound added to deactivate the EI catalyst.
- the phosphorus is contained in a range satisfying the above formula (5). If the molar ratio of p // (Mn + Mg + C0) is less than 0.8, the deactivation of the E1 catalyst is not complete, and the resulting polymer is poor in ripening stability and the polymer may be colored. However, there is a disadvantage that the physical properties of the polymer are reduced during molding. On the other hand, if the above molar ratio is more than 1.5, the thermal stability of the obtained polymer is still poor, which is not preferable. A particularly preferred range of the above molar ratio is 1.1 to 1.3.
- the phosphorus compound used for stabilizing the E1 catalyst is, for example, the following formula (6)
- RR and R may be the same or different, and hydrogen
- a compound represented by the following formula: which is an atom, a methyl group, an ethyl group or a hydroxyxyl group is preferable.
- phosphorus compound of the above formula (6) examples include orthophosphoric acid, trimethyl phosphate, monomethyl phosphate, and dimethyl phosphate.
- orthophosphoric acid and trimethyl phosphate are preferred in terms of availability and cost.
- the polycondensation reaction for producing the ET / E ⁇ copolymer of the present invention may use a polycondensation catalyst known to be usable together with the melt polycondensation reaction of polyester, but is preferred.
- a polycondensation catalyst known to be usable together with the melt polycondensation reaction of polyester, but is preferred.
- an antimony compound such as antimony trioxide or antimony acetate or a germanium compound such as germanium dioxide is used.
- germanium dioxide in view of the hue of the polymer.
- amorphous germanium dioxide which does not have a crystal morphology
- polymer precipitation particles are smaller than those having a normal crystal morphology and higher transparency can be obtained. More preferred.
- the term “amorphous” refers to a substance having substantially no beak in Raman spectrum. If the amount of the amorphous germanium dioxide is too small, the polymerization reactivity is low and the productivity is poor.If the amount is too large, the thermal stability of the polymer is inferior and physical properties during molding are deteriorated. It is advisable to add about 20 to 50 mm ⁇ 1% to the total acid component in the polymer, because it may cause hue deterioration.
- R 4 , R-. And R 7 are each independently a hydrogen atom, an alkyl Group, cycloalkyl group, aryl group and substituted derivatives thereof, and R and may form a ring, and A represents an anion residue.
- ammonium compound examples include quaternary ammonium salts, such as hydroxytetramethylammonium, hydroxytraethylammonium, hydroxytrabutylammonium, and tetraethylammonium.
- Tertiary ammonium salt such as hydroxytrimethylammonium
- secondary ammonium salt such as hydroquinidine ammonium salt
- primary ammonium salt such as hydroxymethylammonium.
- ammonium salts such as hydroxyammonium and ammonium chloride.
- the above-mentioned ammonium compounds may be used alone or in combination of two or more.
- Such an ammonium compound can be added after the transesterification reaction is substantially completed and before the intrinsic viscosity reaches 0.2 d 1.
- the order of adding the ammonium compound and the phosphorus compound is not particularly limited, but it is preferable to add the ammonium compound before adding the phosphorus compound.
- the timing of adding the germanium compound is not particularly limited, but it is particularly preferable to add it after 10 minutes or more after the phosphorus compound is added and before the intrinsic viscosity reaches 0.3.
- the atmosphere of the reaction system at the time of addition may be at atmospheric pressure before the start of the polycondensation reaction, or the polycondensation reaction may be started. It may be under reduced pressure after the start.
- the polymer (prepolymer) obtained by the above reaction is preferably subjected to solid-phase polymerization and then used in the range where the intrinsic viscosity is in the range of 0.7 to 0.95.
- the intrinsic viscosity range of the prepolymer is not particularly limited, but is preferably 0.50 to 0.67 (d1 / g) in view of production efficiency and quality.
- part means parts by weight.
- measurement of each characteristic value in the embodiment is performed by the following method.
- the polymer is heat-treated in a drier at 160 ° C for 90 minutes to be crystallized, and then measured with a color machine CM-750 type color machine.
- the temperature of the cylinder was set to 300 using an injection molding machine Dynamometer M-100M manufactured by Meiki Seisakusho. (A 50 g preform was molded in, and this was blow-stretched to obtain a bottle having an internal volume of 1.5 liters and a body thickness of 0.2 mm. Cut off the torso and measure the haze using a haze meter (Kuchimoto Denshoku Industries Model 1001 DP).
- R '', R and 3 are independently of each other H, CH 3 or CH 2 CH 2 OH
- the copolymerization amount of the 2,61-naphthalenedicarboxylic acid component is reduced, the hot water resistance of the mouth of the bottle is deteriorated, and the ultraviolet ray blocking performance and the gas barrier property are not improved. If the naphthalene dicarboxylic acid component is small, the quality is inferior to that of PET (Comparative Example 9). However, if the copolymerization amount of the 2,6-naphthalenedicarboxylic acid component is excessive, the handling during solid-state polymerization becomes extremely difficult, and stable production cannot be performed.
- the copolymerized PET of the present invention is obtained by copolymerizing a predetermined amount of a small amount of 2.6-naphthalenedicarboxylic acid component, thereby improving the gas barrier properties as a molded product, improving the ultraviolet blocking performance, and improving the bottle quality.
- it provides hot water resistance at the mouth, has excellent hue and transparency, has little whitening (cloudiness) when forming the bottle, and can be a bottle product with high commercial value.
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/155,763 US6022603A (en) | 1996-04-05 | 1997-04-01 | Ethylene terephthalate/ethylene-2,6-naphthalene-dicarboxylate copolymers for bottles |
AU21772/97A AU720667B2 (en) | 1996-04-05 | 1997-04-01 | Ethylene terephthalate/ethylene-2,6-naphthalene dicarboxylate copolymer for bottles |
EP97914574A EP0892000B1 (en) | 1996-04-05 | 1997-04-01 | Ethylene terephthalate/ethylene 2,6-naphthalene-dicarboxylate copolymers for bottles |
JP53604297A JP3745776B2 (ja) | 1996-04-05 | 1997-04-01 | ボトル用エチレンテレフタレート/エチレン―2,6―ナフタレンジカルボキシレート共重合体 |
DE69716894T DE69716894T2 (de) | 1996-04-05 | 1997-04-01 | Ethylenterephtalat-ethylen 2,6-naphthalendicarboxylat copolymer für flaschen |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8/83941 | 1996-04-05 | ||
JP8394196 | 1996-04-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997038038A1 true WO1997038038A1 (fr) | 1997-10-16 |
Family
ID=13816622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1997/001127 WO1997038038A1 (fr) | 1996-04-05 | 1997-04-01 | Copolymeres de terephtalate d'ethylene et de 2,6-naphtalene-dicarboxylate d'ethylene destines a des bouteilles |
Country Status (7)
Country | Link |
---|---|
US (1) | US6022603A (ja) |
EP (1) | EP0892000B1 (ja) |
JP (1) | JP3745776B2 (ja) |
AU (1) | AU720667B2 (ja) |
DE (1) | DE69716894T2 (ja) |
TW (1) | TW399070B (ja) |
WO (1) | WO1997038038A1 (ja) |
Cited By (4)
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---|---|---|---|---|
WO1999065987A1 (fr) * | 1997-11-18 | 1999-12-23 | Kuraray Co., Ltd. | Compositions de resine polyester |
CN1127543C (zh) * | 1998-12-14 | 2003-11-12 | 新光合成纤维股份有限公司 | 阻光性聚酯组合物,阻光性聚酯纤维和由其制得的布种及物品 |
JP2013234249A (ja) * | 2012-05-08 | 2013-11-21 | Teijin Ltd | 共重合ポリエステルおよびそれからなる光学シート |
JP2013234248A (ja) * | 2012-05-08 | 2013-11-21 | Teijin Ltd | 共重合ポリエステルおよびそれからなる光学シート |
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TW514583B (en) * | 1997-03-06 | 2002-12-21 | Teijin Ltd | Polyethylene-2, 6-naphthalene dicarboxylate resin and preform and bottle molded thereof |
JP4393004B2 (ja) | 2001-02-06 | 2010-01-06 | 三菱化学株式会社 | ポリエステル樹脂 |
ES2264431T3 (es) * | 2001-05-26 | 2007-01-01 | Nan Ya Plastics Corp. | Un metodo de produccion de un copoliester que contiene unidad de naftalato de etileno y su aplicacion. |
US20060287485A1 (en) * | 2005-06-17 | 2006-12-21 | Crawford Emmett D | Sound barriers comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol |
WO2007053549A1 (en) * | 2005-10-28 | 2007-05-10 | Eastman Chemical Company | Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom |
US20060270773A1 (en) * | 2005-05-26 | 2006-11-30 | Hale Wesley R | Polyester-polycarbonate blends for diffuser sheets with improved luminance |
US20060270806A1 (en) * | 2005-05-26 | 2006-11-30 | Hale Wesley R | Miscible high Tg polyester/polymer blend compositions and films formed therefrom |
US20100298523A1 (en) * | 2005-06-17 | 2010-11-25 | Eastman Chemical Company | Polyester Compositions Which Comprise Cyclobutanediol and at Least One Phosphorus Compound |
US20110144266A1 (en) * | 2005-06-17 | 2011-06-16 | Eastman Chemical Company | Thermoplastic Articles Comprising Cyclobutanediol Having a Decorative Material Embedded Therein |
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US8420868B2 (en) | 2010-12-09 | 2013-04-16 | Eastman Chemical Company | Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols |
US20130217830A1 (en) | 2012-02-16 | 2013-08-22 | Eastman Chemical Company | Clear Semi-Crystalline Articles with Improved Heat Resistance |
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JPH03182523A (ja) * | 1989-12-12 | 1991-08-08 | Toyobo Co Ltd | ポリエステルの製造方法 |
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JPS5183651A (ja) * | 1975-01-20 | 1976-07-22 | Toray Industries | Horiesuteruchukuseikeitai |
JPS535262A (en) * | 1976-07-06 | 1978-01-18 | Toray Industries | Oriented hollow polyester molded article |
JPH062397B2 (ja) * | 1983-11-28 | 1994-01-12 | 三井石油化学工業株式会社 | 共縮合ポリエステル層を有する積層体 |
US4501878A (en) * | 1984-01-30 | 1985-02-26 | Eastman Kodak Company | Process for the preparation of high molecular weight polyesters |
JPS6178828A (ja) * | 1984-09-26 | 1986-04-22 | Teijin Ltd | 曇りのないポリエステルの製造法 |
ZA903202B (en) * | 1989-05-24 | 1991-02-27 | Amoco Corp | Preparation of polyethylene terephthalate |
US5556675A (en) * | 1989-08-31 | 1996-09-17 | Mitsui Petrochemical Industries Ltd. | Blow molded articles |
JP2863570B2 (ja) * | 1989-10-06 | 1999-03-03 | 三井化学株式会社 | 共重合ポリエチレンテレフタレートおよびその用途 |
JPH07223623A (ja) * | 1994-02-07 | 1995-08-22 | Kanebo Ltd | ポリエステル製耐熱ボトル |
JPH07268085A (ja) * | 1994-04-01 | 1995-10-17 | Kanebo Ltd | ポリエステル共重合体およびそれからなるボトル |
US5554720A (en) * | 1994-12-21 | 1996-09-10 | Eastman Chemical Company | Naphthalenedicarboxylic acid polymers containing aryl thioethers and having reduced fluorescene |
JP3581511B2 (ja) * | 1996-12-26 | 2004-10-27 | 帝人ファイバー株式会社 | ボトル用ポリエステル共重合体 |
AU738285B2 (en) * | 1997-08-18 | 2001-09-13 | Teijin Limited | A copolyester for molding a bottle |
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1997
- 1997-04-01 JP JP53604297A patent/JP3745776B2/ja not_active Expired - Fee Related
- 1997-04-01 EP EP97914574A patent/EP0892000B1/en not_active Expired - Lifetime
- 1997-04-01 WO PCT/JP1997/001127 patent/WO1997038038A1/ja active IP Right Grant
- 1997-04-01 AU AU21772/97A patent/AU720667B2/en not_active Ceased
- 1997-04-01 US US09/155,763 patent/US6022603A/en not_active Expired - Lifetime
- 1997-04-01 DE DE69716894T patent/DE69716894T2/de not_active Expired - Lifetime
- 1997-04-03 TW TW086104298A patent/TW399070B/zh not_active IP Right Cessation
Patent Citations (1)
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JPH03182523A (ja) * | 1989-12-12 | 1991-08-08 | Toyobo Co Ltd | ポリエステルの製造方法 |
Non-Patent Citations (1)
Title |
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See also references of EP0892000A4 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999065987A1 (fr) * | 1997-11-18 | 1999-12-23 | Kuraray Co., Ltd. | Compositions de resine polyester |
US6429243B1 (en) | 1998-06-15 | 2002-08-06 | Kuraray Co., Ltd. | Polyester resin composition |
CN1127543C (zh) * | 1998-12-14 | 2003-11-12 | 新光合成纤维股份有限公司 | 阻光性聚酯组合物,阻光性聚酯纤维和由其制得的布种及物品 |
JP2013234249A (ja) * | 2012-05-08 | 2013-11-21 | Teijin Ltd | 共重合ポリエステルおよびそれからなる光学シート |
JP2013234248A (ja) * | 2012-05-08 | 2013-11-21 | Teijin Ltd | 共重合ポリエステルおよびそれからなる光学シート |
Also Published As
Publication number | Publication date |
---|---|
US6022603A (en) | 2000-02-08 |
JP3745776B2 (ja) | 2006-02-15 |
EP0892000B1 (en) | 2002-11-06 |
EP0892000A1 (en) | 1999-01-20 |
AU720667B2 (en) | 2000-06-08 |
DE69716894D1 (de) | 2002-12-12 |
AU2177297A (en) | 1997-10-29 |
EP0892000A4 (en) | 1999-09-01 |
TW399070B (en) | 2000-07-21 |
DE69716894T2 (de) | 2003-07-03 |
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