WO1995012622A1 - Supported olefin polymerization catalyst, its preparation and use - Google Patents

Supported olefin polymerization catalyst, its preparation and use Download PDF

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Publication number
WO1995012622A1
WO1995012622A1 PCT/FI1994/000499 FI9400499W WO9512622A1 WO 1995012622 A1 WO1995012622 A1 WO 1995012622A1 FI 9400499 W FI9400499 W FI 9400499W WO 9512622 A1 WO9512622 A1 WO 9512622A1
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
support
metallocene
formula
process according
Prior art date
Application number
PCT/FI1994/000499
Other languages
English (en)
French (fr)
Inventor
Kalle Kallio
Ove Andell
Hilkka Knuuttila
Ulf Palmqvist
Original Assignee
Borealis Holding A/S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=8538908&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1995012622(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to CA002175702A priority Critical patent/CA2175702C/en
Priority to AT95900146T priority patent/ATE195325T1/de
Priority to AU81078/94A priority patent/AU685870B2/en
Priority to EP95900146A priority patent/EP0678103B2/en
Priority to US08/481,336 priority patent/US6291611B1/en
Application filed by Borealis Holding A/S filed Critical Borealis Holding A/S
Priority to BR9407968A priority patent/BR9407968A/pt
Priority to DE69425485T priority patent/DE69425485T3/de
Priority to JP7513040A priority patent/JP2990299B2/ja
Priority to SK560-96A priority patent/SK281632B6/sk
Priority to KR1019960702313A priority patent/KR100262245B1/ko
Publication of WO1995012622A1 publication Critical patent/WO1995012622A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
PCT/FI1994/000499 1993-11-05 1994-11-04 Supported olefin polymerization catalyst, its preparation and use WO1995012622A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
KR1019960702313A KR100262245B1 (ko) 1993-11-05 1994-11-04 지지된 올레핀 중합촉매, 그의 제법 및 용도
AT95900146T ATE195325T1 (de) 1993-11-05 1994-11-04 Trägerkatalysator zur olefinpolymerisation, seine herstellung und verwendung
AU81078/94A AU685870B2 (en) 1993-11-05 1994-11-04 Supported olefin polymerization catalyst, its preparation and use
EP95900146A EP0678103B2 (en) 1993-11-05 1994-11-04 Supported olefin polymerization catalyst, its preparation and use
US08/481,336 US6291611B1 (en) 1993-11-05 1994-11-04 Supported olefin polymerization catalyst, its preparation and use
CA002175702A CA2175702C (en) 1993-11-05 1994-11-04 Supported olefin polymerization catalyst, its preparation and use
BR9407968A BR9407968A (pt) 1993-11-05 1994-11-04 Processo para a preparaçao de um catalisador suportado para a polimerizaçao de olefina catalisador suportado para a polimerizaçao de olefina uso de um catalisador suportado para a polimerizaçao de olefina e processo para a preparaçao de polietileno possuindo uma densidade aparente elevada
DE69425485T DE69425485T3 (de) 1993-11-05 1994-11-04 Trägerkatalysator zur olefinpolymerisation, seine herstellung und verwendung
JP7513040A JP2990299B2 (ja) 1993-11-05 1994-11-04 担持オレフィン重合触媒、その製造法および使用
SK560-96A SK281632B6 (sk) 1993-11-05 1994-11-04 Spôsob prípravy nosičového katalyzátora polymerizácie olefínov

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FI934917 1993-11-05
FI934917A FI96866C (fi) 1993-11-05 1993-11-05 Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö

Publications (1)

Publication Number Publication Date
WO1995012622A1 true WO1995012622A1 (en) 1995-05-11

Family

ID=8538908

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FI1994/000499 WO1995012622A1 (en) 1993-11-05 1994-11-04 Supported olefin polymerization catalyst, its preparation and use

Country Status (19)

Country Link
US (1) US6291611B1 (US06291611-20010918-C00003.png)
EP (1) EP0678103B2 (US06291611-20010918-C00003.png)
JP (1) JP2990299B2 (US06291611-20010918-C00003.png)
KR (1) KR100262245B1 (US06291611-20010918-C00003.png)
CN (1) CN1044481C (US06291611-20010918-C00003.png)
AT (1) ATE195325T1 (US06291611-20010918-C00003.png)
AU (1) AU685870B2 (US06291611-20010918-C00003.png)
BR (1) BR9407968A (US06291611-20010918-C00003.png)
CA (1) CA2175702C (US06291611-20010918-C00003.png)
CZ (1) CZ284859B6 (US06291611-20010918-C00003.png)
DE (1) DE69425485T3 (US06291611-20010918-C00003.png)
ES (1) ES2149950T5 (US06291611-20010918-C00003.png)
FI (1) FI96866C (US06291611-20010918-C00003.png)
HU (1) HU216545B (US06291611-20010918-C00003.png)
IL (1) IL111532A (US06291611-20010918-C00003.png)
MY (1) MY131681A (US06291611-20010918-C00003.png)
SK (1) SK281632B6 (US06291611-20010918-C00003.png)
TW (1) TW341578B (US06291611-20010918-C00003.png)
WO (1) WO1995012622A1 (US06291611-20010918-C00003.png)

Cited By (218)

* Cited by examiner, † Cited by third party
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EP0724603A1 (en) * 1993-10-22 1996-08-07 Mobil Oil Corporation An olefin polymerization or copolymerization catalyst
WO1996016093A3 (en) * 1994-11-23 1996-08-22 Exxon Chemical Patents Inc Method for making supported catalyst systems, and catalyst systems therefrom
WO1996032423A1 (en) * 1995-04-12 1996-10-17 Borealis A/S Method of preparing catalyst components
WO1997002297A1 (en) * 1995-07-06 1997-01-23 Exxon Chemical Patents Inc. Method for producing prepolymerized, supported metallocene catalyst systems
EP0780402A1 (de) * 1995-12-22 1997-06-25 Hoechst Aktiengesellschaft Geträgertes Katalysatorensystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
WO1997022633A1 (en) * 1995-12-19 1997-06-26 Borealis A/S Procatalyst, procatalyst precursor, and process for the preparation of a multimodal ethylene polymer
WO1997024375A1 (en) * 1995-12-29 1997-07-10 Exxon Chemical Patents Inc. Slurry polymerization process
WO1998013393A1 (en) * 1996-09-24 1998-04-02 Exxon Chemical Patents Inc. Improved method for preparing supported metallocene catalyst systems
US5786291A (en) * 1996-02-23 1998-07-28 Exxon Chemical Patents, Inc. Engineered catalyst systems and methods for their production and use
WO1998040416A1 (de) * 1997-03-07 1998-09-17 Targor Gmbh Geträgertes katalysatorsystem, verfahren zu seiner herstellung und seine verwendung zur polymerisation von olefinen
US5891814A (en) * 1993-05-25 1999-04-06 Exxon Chemical Patents Inc. Nonwoven fabrics
DE19758306A1 (de) * 1997-12-31 1999-07-15 Elenac Gmbh Katalysator für die Polyolefinsynthese
US5952430A (en) * 1996-09-24 1999-09-14 Shell Oil Company Process for selective hydrogenation of poly(monovinyl aromatic)-poly(conjugated diene) block copolymers
US6043180A (en) * 1994-11-17 2000-03-28 The Dow Chemical Company Supported catalyst component, supported catalyst, their preparation, and addition polymerization process
US6087291A (en) * 1994-06-24 2000-07-11 Exxon Chemical Patents, Inc. Polymerization catalyst systems
US6180736B1 (en) 1996-12-20 2001-01-30 Exxon Chemical Patents Inc High activity metallocene polymerization process
WO2001062847A1 (en) 2000-02-21 2001-08-30 Borealis Technology Oy Process for producing a polyethylene coating on a substrate
US6294625B1 (en) * 1990-03-20 2001-09-25 Exxonmobil Chemical Patents Inc. Catalyst system of enhanced productivity and its use in polymerization process
US6437063B1 (en) 1997-11-07 2002-08-20 Borealis Technology Oy Process for preparing polypropylene
US6451725B1 (en) 1995-04-12 2002-09-17 Borealis Technology Oy Method for preparing catalyst components
US6455643B1 (en) 1997-06-24 2002-09-24 Borealis Technology Oy Process for preparing propylene homopolymers and copolymers
US6503993B1 (en) 1997-11-07 2003-01-07 Borealis Technology Oy Propylene polymers and products thereof
US6664352B1 (en) 1998-10-09 2003-12-16 Borealis Technology Oy Supported polymerization catalysts
US6683125B1 (en) 1997-11-07 2004-01-27 Borealis A/S Talc containing polypropylene compositions
US6730756B1 (en) 1998-12-07 2004-05-04 Borealis A/S Catalyst and process for olefin polymerization
US6875826B1 (en) 1997-09-26 2005-04-05 Borealis A/S High melt strength polypropylene
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IL111532A0 (en) 1995-01-24
FI934917A (fi) 1995-05-06
HU216545B (hu) 1999-07-28
BR9407968A (pt) 1996-12-03
ATE195325T1 (de) 2000-08-15
CN1044481C (zh) 1999-08-04
JPH09504567A (ja) 1997-05-06
CZ130596A3 (en) 1996-07-17
ES2149950T3 (es) 2000-11-16
CA2175702C (en) 2002-12-31
AU685870B2 (en) 1998-01-29
SK281632B6 (sk) 2001-06-11
FI96866B (fi) 1996-05-31
AU8107894A (en) 1995-05-23
DE69425485T3 (de) 2007-05-24
EP0678103B1 (en) 2000-08-09
DE69425485T2 (de) 2001-01-11
JP2990299B2 (ja) 1999-12-13
MY131681A (en) 2007-08-30
CN1134160A (zh) 1996-10-23
DE69425485D1 (de) 2000-09-14
HU9601153D0 (en) 1996-07-29
EP0678103A1 (en) 1995-10-25
CA2175702A1 (en) 1995-05-11
SK56096A3 (en) 1997-04-09
IL111532A (en) 2000-02-29
CZ284859B6 (cs) 1999-03-17
US6291611B1 (en) 2001-09-18
FI934917A0 (fi) 1993-11-05
EP0678103B2 (en) 2007-02-14
FI96866C (fi) 1996-09-10
HUT75187A (en) 1997-04-28
ES2149950T5 (es) 2007-09-16
TW341578B (en) 1998-10-01
KR100262245B1 (ko) 2000-07-15

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