WO1991009162A1 - Verfahren und spinnvorrichtung zur herstellung von mikrofilamenten - Google Patents

Verfahren und spinnvorrichtung zur herstellung von mikrofilamenten Download PDF

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Publication number
WO1991009162A1
WO1991009162A1 PCT/DE1990/000941 DE9000941W WO9109162A1 WO 1991009162 A1 WO1991009162 A1 WO 1991009162A1 DE 9000941 W DE9000941 W DE 9000941W WO 9109162 A1 WO9109162 A1 WO 9109162A1
Authority
WO
WIPO (PCT)
Prior art keywords
microfilaments
spinning
drawn
spinning device
melt
Prior art date
Application number
PCT/DE1990/000941
Other languages
German (de)
English (en)
French (fr)
Inventor
Ivo E. Ruzek
Walter Bruckner
Original Assignee
Corovin Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6395741&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO1991009162(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Corovin Gmbh filed Critical Corovin Gmbh
Priority to DE59006327T priority Critical patent/DE59006327D1/de
Priority to KR1019920701460A priority patent/KR920703889A/ko
Priority to US07/862,570 priority patent/US5310514A/en
Priority to EP90917481A priority patent/EP0541552B1/de
Publication of WO1991009162A1 publication Critical patent/WO1991009162A1/de

Links

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/02Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of forming fleeces or layers, e.g. reorientation of yarns or filaments
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D4/00Spinnerette packs; Cleaning thereof
    • D01D4/02Spinnerettes
    • D01D4/025Melt-blowing or solution-blowing dies
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/084Heating filaments, threads or the like, leaving the spinnerettes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/088Cooling filaments, threads or the like, leaving the spinnerettes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/08Melt spinning methods
    • D01D5/098Melt spinning methods with simultaneous stretching
    • D01D5/0985Melt spinning methods with simultaneous stretching by means of a flowing gas (e.g. melt-blowing)
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H3/00Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
    • D04H3/08Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
    • D04H3/16Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion

Definitions

  • the invention relates to a method for producing microfilaments according to the preamble of claim 1, and moreover the invention also relates to a spinning device for producing microfilaments.
  • Synthetic filaments with a single titer of less than 1 dtex are designated as microfilaments (the specification 1 dtex means that 10 km of the thread or filament weighs 1 gram).
  • the microfilaments therefore have a very small diameter and are twisted in a known manner to form microfilament yarns.
  • These microfilament yarns can be woven or knitted to make a textile. Due to the single titer of less than 1 dtex, the textiles are characterized by 'a very soft feel and an ⁇ dall case, so that they have a silk-like character and can follow the fashion trend of silk fabrics.
  • microfilaments takes place in that the microfilament is drawn off and stretched at a high take-off speed from the spinning hole of a spinneret fed with a melt and is taken up on a roll after passing through an area blown transversely with cooling air. This is followed by twisting with a large number of microfilaments into a microfilament yarn from which the desired textile can be produced by weaving.
  • spunbonded nonwovens from the microfilaments by pulling the filaments emerging from spinning nozzles under the action of an injector after passing through an area blown transversely with cooling air and depositing them on a continuously moving deposit belt.
  • Such spunbonded fabrics made from microfilaments are also covered by the invention.
  • the fila diameter depending on the synthetic polymer used, is below 12 ⁇ m for polypropylene and below 11 ⁇ m for polyamide or below 10 ⁇ m for polyester.
  • the microfiber yarns and textile products resemble the fashionably preferred natural silk due to their soft feel.
  • the textile yarns made from microfilaments have yet another advantage that can be attributed to the tightness of the fabric. Fabrics made from microfilament yarns can be woven so densely that their diffusion properties are similar to those of impervious diaphragms. These flat structures breathe, ie they let gases and also vapors, such as water vapor, through easily, even though they are poorly wettable at the same time. The. poor wettability is due to the small filament diameter and the resulting unfavorable angles between two filament surfaces.
  • the polymer melt is extruded through the spinneret, cooled by an air stream below the spinneret and drawn off at high speed - usually around 6,000 m / min.
  • the aim in practice is to reduce the diameter of the microfilaments to a single titer of well below 1 dtex to reduce.
  • the number 'of the microfilaments in the yarn or the number of nozzle holes per must Mikrofila- dewaxing proportional to the reduction of the single titer i. d-tex rise because several microfilaments are then required to produce a microfilament yarn with the same diameter.
  • the filament surface is inversely proportional to the third power of the filament diameter for the same volume. If, for example, the individual titer is halved, the thinner filament has an eightfold surface.
  • the larger surface area can be seen in connection with the cooling of the microfilament.
  • the stretching of the microfilament presupposes a certain temperature, and if it cools down too much, there is a risk that the microfilament will become brittle and tear off, especially at the usual high take-off speeds of 6,000 m / min.
  • hypothermic skin will form on the surface of the microfilament. This skin is responsible for the filament breaks.
  • the skin is already rigid, while the inner mass, which is surrounded by the skin, is still in a stretchable state.
  • the invention is based on the object of specifying a method which enables the production of microfilaments with very small diameters without deterioration in economy and quality, and moreover the invention is intended to create a spinning device which enables economical production of microfilaments allowed with small diameters.
  • this object is achieved in the method presupposed in the preamble of patent claim 1 by the features of the characterizing part, and with regard to the spinning device, the task in a spinning device according to the preamble of patent claim 10 is achieved by the method characteristic features solved.
  • the invention provides that the microfilaments are accompanied by a downward flow of hot air immediately after they exit the spinning hole.
  • the extruded filament is thus embedded in a warm air stream after exiting the spinning hole, which preferably surrounds the filament in the form of a jacket.
  • the hot air coating compensates for the negative influence of the large surface area of the microfilaments, which leads to rapid cooling. This prevents the filament from cooling too quickly, owing to the much higher specific surface area.
  • a major advantage of the invention is therefore that the filament can be drawn off without problems even at the usual high speeds of 4,000-6,000 n / min. "
  • microfilament yarns produced by the process according to the invention thus provide a significantly better quality, the disadvantages described at the outset being eliminated.
  • the protective jacket made of hot air protects the just extruded and formed filament immediately after it emerges from the spinning hole of the spinneret from cooling too quickly. Thus, a rapidly cooled outer skin of the filament cannot arise, which would be damaged by the shear stress caused by the rapid filament withdrawal without cracks and would lead to a filament breakage.
  • the filament cools gradually, so that - viewed radially - a uniform structure is formed.
  • the very fine microfilament with a small diameter can also be optimally stretched.
  • differences between the individual filaments of a multifilament spinneret are largely suppressed, - Io ⁇
  • the cooling of the microfilament is under control, so that the risk of microfilaments with different diameters being avoided is avoided.
  • deviations in the diameters in the prior art are only slight, they are nevertheless noticeable, e.g. in that when the microfilaments or the textile are colored, the color of the different microfilaments with different diameters is also taken up differently. As a result, the uniform color impression of the product used as a high-quality textile suffers.
  • the method for producing microfilaments also includes known very small diameter
  • polyolefins especially polypropylene, furthermore polyester and polyamide 6 and 6,6 can be spun by the process according to the invention.
  • Known bicomponent nozzles can advantageously be used, whereby it must be ensured that the outer part of the combined spinneret is modified in such a way that a uniform distribution of the hot air over all bores is ensured. Furthermore, the outer holes of the combined nozzle must be adapted to the air flow.
  • Such bicomponent nozzles have a jacket-core arrangement / in which case only the core nozzle is used for spinning the polymer melt and the hot air flow is generated at the jacket nozzle.
  • the spinning conditions with regard to the polymer melt can essentially be maintained as they are set when spinning a conventional spinning device.
  • the air temperatures in the outer part of the spinneret (bicomponent nozzle) depend on the melting temperature.
  • moderate embodiment of the invention provides that the temperature difference between the two components should not be exceeded ⁇ 10 ° C. In the optimal case, the temperatures of the two components, melt and air, are equal.
  • the amount of air in the hot air can be adjusted in a simple manner, a minimum setting being necessary in order to ensure that a clean free jet forms at least briefly below the spinneret.
  • the microfilaments After running a distance of approximately 100 to 500 mm below the spinneret, the microfilaments can be cooled to a greater extent by transverse blowing, and the usual blowing shafts can be used here.
  • aerodynamic take-off devices in the form of an injector can also be used expediently within the scope of the invention, so that the microfilaments formed according to the invention are known in a known manner Way also a spinning fleece can be formed.
  • FIG. 1 shows a schematic representation of a known spinning device with a mechanical take-off device in the form of a roll
  • Fig. 2 shows a spinning device
  • FIG. 4 shows a detailed illustration of a bicomponent nozzle used in FIG. 3.
  • the spinning device designated as a whole with the reference number 10 in FIG. 1 is known per se. It has a spinneret 1-2 with a spinning hole 14, through which melt 16 exits and is stretched into a microfilament 18.
  • a rotating roller 20, on which the microfilaments 18 are rolled up, serves as the take-off device.
  • the illustration according to FIG. 1 shows only the case of a single microfilament. In practice, if a large number of microfilaments are produced, the spinneret 12 has a corresponding number of spinning holes 14.
  • the melt 16 When leaving the spinning hole 14, the melt 16 has a temperature of approximately 280 ° C. A transverse blowing with cooling air is indicated by the arrow 22, and the microfilament 18 cools down to such an extent that it still has a temperature of about 60 ° C. at the bottom of the roll.
  • the microfilament 18 is thus stretched by the roll, the rotational speed of which is decisive for the take-off speed.
  • a typical value of the take-off speed in FIG. 1 is 4000 to 6000 m / min.
  • 1 shows a spinning device for production 2 shows a known spinning device for producing spunbonded nonwovens.
  • the take-off device is aerodynamically designed and formed by an injector 24.
  • the microfilaments are deposited on a laterally moving catch belt 36.
  • a practical embodiment of the method according to the invention results from the embodiment of the spinning device according to FIG. 3.
  • the extruded microfilament 18 is embedded in a warm air flow indicated by the arrows A.
  • This warm air flow A accompanies the microfilament essentially within the stretching area 38, which is the main stretching area with a length of approximately 30 to 50 cm.
  • the total distance 1 between the bicomponent nozzle 26 and the roller 20 is approximately 1 m.
  • the microfilament 18 is blown transversely with cooling air 22, as in FIGS. 1 and 2.
  • the temperature of which is the melt temperature of 280 ° C at the exit through the spinning hole 14 should not exceed or differ by ⁇ 10 ° C., too rapid cooling of the microfilament 18 is prevented. Rather, the cooling of the microfilament 18 is delayed and carried out continuously in the invention.
  • the invention ensures that, despite a reduction in the diameter of the microfilament 18, it is possible to work with the usual take-off speed of 4000-6000 m / min, so that the economy of a spinning system is not lost if smaller diameters of the microfilaments are desired.
  • a bicomponent nozzle 26 which is shown in more detail in FIG. 4 and has a core nozzle 28 and a jacket nozzle 30 and also has an annular gap 32, can be used to generate the hot air flow A which is decisive in the invention.
  • the annular gap 32 surrounds ring-shaped the spinning hole 34 from which the melt emerges.
  • melt is extruded both through the spinning hole 34 of the core nozzle 28 and through the annular gap 32 of the jacket nozzle 30, it is provided according to FIG. 4 that the melt exits exclusively via the inner core nozzle 28 .
  • the hot air flow is supplied or generated through the annular gap 36 under pressure p and temperature T, which then surrounds the microfilament 16 in the form of a jacket.
  • the invention can also be used for the production of spunbonded fabric in a spinning device according to FIG. 2.
  • microfilament yarns with a super fine single titer of 0.33 dtex can be produced without sacrificing the economy of a spinning system, so that it is possible to produce textiles that are practically equivalent to natural silk.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
  • Artificial Filaments (AREA)
PCT/DE1990/000941 1989-12-19 1990-12-03 Verfahren und spinnvorrichtung zur herstellung von mikrofilamenten WO1991009162A1 (de)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE59006327T DE59006327D1 (de) 1989-12-19 1990-12-03 Verfahren und spinnvorrichtung zur herstellung von mikrofilamenten.
KR1019920701460A KR920703889A (ko) 1989-12-19 1990-12-03 마이크로 필라멘트를 제조하기 위한 방법 및 스피닝 장치
US07/862,570 US5310514A (en) 1989-12-19 1990-12-03 Process and spinning device for making microfilaments
EP90917481A EP0541552B1 (de) 1989-12-19 1990-12-03 Verfahren und spinnvorrichtung zur herstellung von mikrofilamenten

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3941824.3 1989-12-19
DE3941824A DE3941824A1 (de) 1989-12-19 1989-12-19 Verfahren und spinnvorrichtung zur herstellung von mikrofilamenten

Publications (1)

Publication Number Publication Date
WO1991009162A1 true WO1991009162A1 (de) 1991-06-27

Family

ID=6395741

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/DE1990/000941 WO1991009162A1 (de) 1989-12-19 1990-12-03 Verfahren und spinnvorrichtung zur herstellung von mikrofilamenten

Country Status (7)

Country Link
US (1) US5310514A (en, 2012)
EP (1) EP0541552B1 (en, 2012)
JP (1) JP2918332B2 (en, 2012)
KR (1) KR920703889A (en, 2012)
AT (1) ATE107971T1 (en, 2012)
DE (2) DE3941824A1 (en, 2012)
WO (1) WO1991009162A1 (en, 2012)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1056203C (zh) * 1991-09-06 2000-09-06 阿克佐公司 复丝纱熔融纺丝设备

Families Citing this family (13)

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Publication number Priority date Publication date Assignee Title
US5382400A (en) 1992-08-21 1995-01-17 Kimberly-Clark Corporation Nonwoven multicomponent polymeric fabric and method for making same
US5405682A (en) 1992-08-26 1995-04-11 Kimberly Clark Corporation Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material
CA2092604A1 (en) 1992-11-12 1994-05-13 Richard Swee-Chye Yeo Hydrophilic, multicomponent polymeric strands and nonwoven fabrics made therewith
US5482772A (en) 1992-12-28 1996-01-09 Kimberly-Clark Corporation Polymeric strands including a propylene polymer composition and nonwoven fabric and articles made therewith
BR9400682A (pt) * 1993-03-05 1994-10-18 Akzo Nv Aparelho para a fiação em fusão de fios multifilamentares e sua aplicação
US5759926A (en) * 1995-06-07 1998-06-02 Kimberly-Clark Worldwide, Inc. Fine denier fibers and fabrics made therefrom
DE69626303T2 (de) 1995-11-30 2003-12-11 Kimberly-Clark Worldwide, Inc. Vliesstoff aus sehr dünnen mikrofasern
JP3662455B2 (ja) * 1999-11-22 2005-06-22 ユニ・チャーム株式会社 ポリプロピレン製不織布およびその製造方法
DE10026281B4 (de) * 2000-05-26 2005-06-02 Sächsisches Textilforschungsinstitut e.V. Verfahren zur Herstellung von Spinnvliesen
BR0107280A (pt) 2001-09-17 2004-03-23 Rhodia Poliamida Ltda Microfibras para reforço de matrizes inorgânicas, como cimento, argamassa. gesso e concreto, microfibras à base de poliamida para reforço de matrizes inorgânicas, processo para obtenção de microfibras à base de poliamida para reforço de matrizes inorgânicas e produtos à base de fibrocimento
EP2245077B1 (en) * 2008-01-21 2018-06-06 Imerys Pigments, Inc. Monofilament fibers comprising ground calcium carbonate
CN106835417B (zh) * 2016-12-02 2019-05-10 武汉纺织大学 一种利用熔喷超细纤维制备包芯纱的装置及方法
CN106555257B (zh) * 2016-12-02 2019-05-10 武汉纺织大学 一种利用熔喷超细纤维进行喷气纺纱的装置和方法

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DE2514874A1 (de) * 1975-04-05 1976-10-14 Zimmer Ag Verfahren zum schnellspinnen von polyamiden
GB2135629A (en) * 1983-02-25 1984-09-05 Barmag Barmer Maschf A spinning installation for synthetic filaments
EP0244217A2 (en) * 1986-04-30 1987-11-04 E.I. Du Pont De Nemours And Company Process and apparatus
EP0245011A2 (en) * 1986-04-30 1987-11-11 E.I. Du Pont De Nemours And Company New uniform polymeric filaments
EP0334604A2 (en) * 1988-03-24 1989-09-27 Mitsui Petrochemical Industries, Ltd. Method and apparatus for cooling molten filaments in spinning apparatus

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Publication number Priority date Publication date Assignee Title
DE2514874A1 (de) * 1975-04-05 1976-10-14 Zimmer Ag Verfahren zum schnellspinnen von polyamiden
GB2135629A (en) * 1983-02-25 1984-09-05 Barmag Barmer Maschf A spinning installation for synthetic filaments
EP0244217A2 (en) * 1986-04-30 1987-11-04 E.I. Du Pont De Nemours And Company Process and apparatus
EP0245011A2 (en) * 1986-04-30 1987-11-11 E.I. Du Pont De Nemours And Company New uniform polymeric filaments
EP0334604A2 (en) * 1988-03-24 1989-09-27 Mitsui Petrochemical Industries, Ltd. Method and apparatus for cooling molten filaments in spinning apparatus

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1056203C (zh) * 1991-09-06 2000-09-06 阿克佐公司 复丝纱熔融纺丝设备

Also Published As

Publication number Publication date
US5310514A (en) 1994-05-10
KR920703889A (ko) 1992-12-18
EP0541552A1 (de) 1993-05-19
JP2918332B2 (ja) 1999-07-12
DE59006327D1 (de) 1994-08-04
ATE107971T1 (de) 1994-07-15
EP0541552B1 (de) 1994-06-29
DE3941824A1 (de) 1991-06-27
DE3941824C2 (en, 2012) 1992-01-16
JPH05502483A (ja) 1993-04-28

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