US9487912B2 - Disinfectant composition for textile and related substrates, and method of treating a substrate to provide disinfecting antibacterial, antiviral and antifungal, wash durable, optionally enhanced with multifunctional properties - Google Patents

Disinfectant composition for textile and related substrates, and method of treating a substrate to provide disinfecting antibacterial, antiviral and antifungal, wash durable, optionally enhanced with multifunctional properties Download PDF

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US9487912B2
US9487912B2 US14/370,728 US201414370728A US9487912B2 US 9487912 B2 US9487912 B2 US 9487912B2 US 201414370728 A US201414370728 A US 201414370728A US 9487912 B2 US9487912 B2 US 9487912B2
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textile
textile substrate
ppm
substrate
disinfecting
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US20150140219A1 (en
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Rohini Swamy
Sanjeev Swamy
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Livinguard AG
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Green Impact Holding AG
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Assigned to GREEN IMPACT HOLDING AG reassignment GREEN IMPACT HOLDING AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SWAMY, Rohini, SWAMY, Sanjeev
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Priority to US16/752,564 priority patent/US11134686B2/en
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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/16—Heavy metals; Compounds thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
    • A01N43/08—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
    • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
    • A01N47/44—Guanidine; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/08—Filter cloth, i.e. woven, knitted or interlaced material
    • B01D39/083—Filter cloth, i.e. woven, knitted or interlaced material of organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D39/00—Filtering material for liquid or gaseous fluids
    • B01D39/08—Filter cloth, i.e. woven, knitted or interlaced material
    • B01D39/086—Filter cloth, i.e. woven, knitted or interlaced material of inorganic material
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/055—Cellulose or derivatives thereof with the residual liquors derived of the sulfatic process for the preparation of cellulose
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2202/00—Aspects relating to methods or apparatus for disinfecting or sterilising materials or objects
    • A61L2202/20—Targets to be treated
    • A61L2202/26—Textiles, e.g. towels, beds, cloths
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/04—Additives and treatments of the filtering material
    • B01D2239/0442—Antimicrobial, antibacterial, antifungal additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2239/00—Aspects relating to filtering material for liquid or gaseous fluids
    • B01D2239/10—Filtering material manufacturing
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/04—Disinfection

Definitions

  • the present invention relates to a disinfecting antimicrobial textile having essential features such as wash durability and capability for addition of multifunctional enhancements with wash durable disinfecting antimicrobial properties.
  • Textiles are used for a variety of purposes and in a variety of environments. As such, there is a very realistic danger of microbiological contamination on the textile surfaces. Additionally, danger of staining of apparel due to ketchup, blood, sputum, honey, human excreta and moisture are also problems faced by users in various circumstances. Not only do such stains look ugly, but they also are fertile breeding grounds for various harmful bacteria, fungi and viruses on the textile surface and in its cross section.
  • Sheets, pillow covers, gowns, and curtains are subjected to contamination from open wounds and other medical conditions, such as coughing, wheezing, etc.
  • Patients' gowns are contaminated by sweat and/or human excretion such as urine, stool and vomit. This leads to the growth of microorganisms like bacteria, viruses and fungi.
  • Healthcare workers are very often subjected to the contamination either from soiled textiles used by patients or due to excretions of the body. Medical personnel are major causes of transmitting bacterial infection from one patient to another.
  • Current medical textiles offer no barrier protection. Provided herein below are current situations and problems thereof in hospitals:
  • Microbiologically potable water is a pressing need today. While there is availability of fresh water resources, the water therein is often found contaminated with E. Coli and a wide range of other disease causing microbes. Indeed, many freshwater sources are used by the local population for a variety of activities ranging from bathing, to washing of clothes, to bathing their cattle, etc. As such, the levels of contamination in most of these water resources are considerable. If used for drinking, such contaminated water could lead to outbreaks of diarrhea, cholera and a host of other diseases, as indeed evidenced by studies across the world. While systems do exist which can kill the waterborne microbiology using chemical dosing, the use of such chemicals over extended periods is harmful for the human body. Moreover, yet other systems that can separate or kill bacteria in water use electricity, which is not readily available in a large chunk of underdeveloped regions across the globe.
  • microbiologically safe drinking water can be provided in a simple manner by combining the traditional technique of cloth filtration with a technology that can make the cloth disinfecting and able to kill disease causing microbes.
  • U.S. Pat. No. 2,791,518 describes a method of importing microbial properties of articles such as textiles by immersing the article in a first aqueous solution containing a water soluble base nitrogen compound (ammonia) and a monovalent silver salt soluble in a said solution, followed by a second immersion in a second solution containing a second salt capable of ion exchange with the silver salt.
  • a water soluble base nitrogen compound ammonia
  • a monovalent silver salt soluble in a said solution followed by a second immersion in a second solution containing a second salt capable of ion exchange with the silver salt.
  • U.S. Pat. No. 527,952 discloses a method of treating fibers to render them electrically conductive as well as anti bacterial comprising immersing the fibers in a bath containing an aqueous solution of a source of divalent copper ions, reducing agent, sodium thiosulphate and a source of iodide ions, where by copper iodide adsorbed into the fibers
  • U.S. Pat. No. 6,962,608 which teaches about a process for preparing an antimicrobial fiber, said process comprising a) immersing a textile in an aqueous treating solution comprising an organic acid, wherein said organic acid has a at least two carboxyl groups, b) treating said fiber with an oxidizing agent to produce a peroxycarboxylic acid function, thereby preparing an antimicrobial textile containing an average of 6 weight percent of the organic acid, which not laundered at all demonstrated over 99% reduction of E. coli.
  • the present invention solving the problems associated with the traditional use of textiles
  • the inventors of the alleged invention have developed a novel and inventive composition for treating the textiles and methods of making the solution as well as methods of treating textiles using the composition. Accordingly, the objectives of the invention are enumerated below,
  • the primary object of the present invention is to provide any textile or substrate disinfecting, antibacterial, antiviral, antifungal and wash durable properties.
  • the disinfectant textiles provide barrier protection to the wearer.
  • important object of the present invention is that it will prohibit complete growth of bacteria, smells, odors etc.
  • Very important object of the present invention is that it will drastically reduce the washing costs.
  • a textile comprising a substrate which is:
  • the resultant fabric is mildly hydrophobic across its cross section.
  • the application of chemistry to the textile is done using exhaust, padding, coating or spraying processes. Drying of the textile is done using normal heat setting processes as available.
  • the textile substrate can be made multifunctional by adding the required functional treatments along with the disinfecting coating, during the processing phase.
  • the textiles may be treated on one or both sides of the textile, either separately or jointly, with the treating composition comprising at least one treating agent selected from the group consisting of water and oil repellents, abrasion resistant agents, antistatic agents, anti-pilling agents, easy care resins, wetting agents, wicking chemicals, softeners, mosquito repellants, UV protectors, soil releasing agents, viscosity modifiers, pH modifiers, emulsifying agents and vehicles thereof.
  • the treating composition comprising at least one treating agent selected from the group consisting of water and oil repellents, abrasion resistant agents, antistatic agents, anti-pilling agents, easy care resins, wetting agents, wicking chemicals, softeners, mosquito repellants, UV protectors, soil releasing agents, viscosity modifiers, pH modifiers, emulsifying agents and vehicles thereof.
  • the present invention relates to providing disinfecting (antimicrobial) textiles in which the textiles (said to be a substrate) have been selected from a group consisting of woven, non woven, electro spun, drawn, bonded, crocheted or knitted textiles, and are useful for humans, animals, and the environment, in apparel, medical, home, hotels, furnishings (including upholstery), kitchen, table top, bathroom, automotive, bakeries, curtains, carpets, pet products and related applications.
  • textiles with disinfecting qualities we refer to the specific property wherein the textile can provide a reduction in bacterial (gram positive) contamination greater than 4 logs in less than 5 minutes as well as completely hinder the growth of Fungi.
  • the substrate such as the textile substrate which needs to be treated, is typically selected from a non-limiting group of textiles consisting of natural or synthetic woven textile, drawn textile, knitted textile, crocheted textile, bonded textile or non woven textile.
  • the natural fabric is at least one selected from the group consisting of wool, cotton, silk, linen, hemp, ramie and jute.
  • the formulation and the method of the present invention is also suitable for application to various textiles materials including synthetic fabric which is at least one selected from the group consisting of rayon, nylon, nonacrylic olefin acrylic polyester, PTFE, PP, PPE, carbon fiber, vinyon, saran, spandex, vinalon, aramids, modal, sulfar, polybenzimidazole fibre, PLA, lyocell, orlon, vectran and zylonacrylonithle.
  • the above fabric can blended from any of the above mentioned fabrics/groups, for application of the composition followed by method of application.
  • the disinfecting treating composition for the textile substrate comprises of a combination of one, several or all of a quaternary ammonium organosilane compound, and/or silver chloride and/or other types of silver salts, and/or Poly-glucosamine, and/or propiconazole, and/or biocoated silver particles and/or poly-hexa-methylene-biguanide (herein after referred to also as “functional agents”), in a concentration range of between 0.1 to 10%, more specifically 0.1 to 4%, such that the entire cross section of the substrate becomes antimicrobial, antiviral and anti fungal in nature and meets the prescribed standards to qualify as disinfecting.
  • a quaternary ammonium organosilane compound and/or silver chloride and/or other types of silver salts
  • Poly-glucosamine, and/or propiconazole and/or biocoated silver particles and/or poly-hexa-methylene-biguanide (herein after referred to also as “functional agents”), in a
  • the solution and/or composition comprising of anti viral agent used to prepare disinfecting textiles is at least one selected from the group consisting of compound methyl alcohol, octadecylaminomethyl trihydroxysilylpropyl ammonium chloride and chloropropyl trihydroxysilane, poly-glucosamine, silver chloride based compound and silver chloride in aluminosilicate carrier base and polyhexamethylene biguanide, in a concentration range of between 1 ppm to 500 ppm, depending on application, and the polysaccharide or oligosaccharide or biocoated silver nanoparticles, in a concentration range of between 0.1 ppm to 150 ppm, depending on the application.
  • the antifungal agent is at least one selected from the group of thiabendazoles or propiconazoles in a concentration of range of between 0.5 ppm to 200 ppm, depending on application. These agents also impart a small amount of antibacterial and antiviral activity by supporting those functions through their anti fungal capabilities.
  • the present invention further includes a cross-linking agent which is selected from the type of adducts of blocked isocyanate, in a concentration range of between 1 ppm to 300 ppm, depending on application.
  • a further embodiment of the present invention comprises an emulsifying agent, typically, the emulsifying agent is at least one selected from the group of polyoxyethylene monostearate, polyoxyethlene, sorbitan monolaurate, polyethylene glycol 400 monolaurate in a concentration of between 0.1 ppm to 200 ppm, depending on application.
  • the emulsifying agent is at least one selected from the group of polyoxyethylene monostearate, polyoxyethlene, sorbitan monolaurate, polyethylene glycol 400 monolaurate in a concentration of between 0.1 ppm to 200 ppm, depending on application.
  • the vehicle used to prepare the solution in accordance with present composition is water or any other solvent which is compatible with the mixture of the functional agents added in the solution to create the present composition.
  • the treated fabric is mildly hydrophobic across its cross section.
  • the application of chemistry to the textile is done using exhaust, padding, coating or spraying processes. Drying of the textile is done using normal heat setting processes as available.
  • the textile substrate can be made multifunctional by adding the required functional treatments along with the disinfecting coating, during the processing phase.
  • the textiles may be treated on one or both sides of the textile, either separately or jointly, with the treating composition comprising at least one treating agent selected from the group consisting of water and oil repellents, abrasion resistant agents, antistatic agents, anti-pilling agents, easy care resins, wetting agents, wicking chemicals, softeners, mosquito repellants, UV protectors, soil releasing agents, viscosity modifiers, pH modifiers, emulsifying agents and vehicles thereof.
  • the treating composition comprising at least one treating agent selected from the group consisting of water and oil repellents, abrasion resistant agents, antistatic agents, anti-pilling agents, easy care resins, wetting agents, wicking chemicals, softeners, mosquito repellants, UV protectors, soil releasing agents, viscosity modifiers, pH modifiers, emulsifying agents and vehicles thereof.
  • the fixation of the chemicals by complete polymerization is a non-leaching and wash durable process. As such, the resultant textile can withstand several washes without losing efficacy.
  • the pre-treatment of the textile substrate includes:
  • 0.5 to 2% add-on of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 1 to 2% add-on of silver chloride based compound and 1 to 2% polyhexamethylene biguanide, 1 to 3% of polyglucosamine are applied onto the textile substrate through aqueous media by exhaust process at mildly acidic condition followed by heat treatment polymerization at between 130° C. and 160° C., which imparts disinfecting property to textile substrate across the entire cross section along with mildly hydrophobic performance.
  • 10 to 20 g/l of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 10 to 20 of silver chloride based compound, silver chloride in aluminosilicate carrier base, 10 to 20 of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by pad impregnation method with 60 to 80% wet pickup at mildly acidic condition followed by heat treatment polymerization at between 130° C. and 160° C., which imparts antimicrobial property to textile substrate across the cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 20 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at 120° C. to 150° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety to other functionality finishes that can make it superabsorbent.
  • 0.1 to 2% add-on of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 0.1 to 2% add-on of silver chloride based compound, silver chloride in aluminosilicate carrier base, 0.1% to 2% add-on polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by coating process at mildly acidic condition followed by heat treatment polymerization at between 130° C. and 170° C., which imparts antimicrobial property to textile substrate across the entire cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 18 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at 120° C. to 160° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety to other functionality finishes that can increase the absorbency of the garments.
  • one sided sweat absorbency coating is required to be further applied 20 to 50 g/l of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 20 to 50 of silver chloride based compound, silver chloride in aluminosilicate carrier base, and 20 to 50 of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by pad impregnation method with 60% to 80% wet pickup at mildly acidic condition followed by heat treatment polymerization at between 110° C. and 150° C., which imparts antimicrobial property to textile substrate across the cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 0.5 to 2% add-on of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 1 to 2% add-on of silver chloride based compound, silver chloride in aluminosilicate carrier base, and 1 to 2% polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by exhaust process at mildly acidic condition followed by heat treatment polymerization at between 120° C. and 140° C., which imparts antimicrobial property to textile substrate across the entire cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 20 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at between 120° C. and 150° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety to further apply the fluid repellant coating.
  • 10 to 50 g/l of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 10 to 50 g/l of silver chloride based compound, silver chloride in aluminosilicate carrier base, 10 to 50 g/l of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by pad impregnation method with 60 to 80% wet pickup at mildly acidic condition followed by heat treatment polymerization at between 120° C. and 140° C., which imparts antimicrobial property to textile substrate across the cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 20 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at between 120° C. and 150° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety to apply insect repellant treatment.
  • 0.5 to 2% add-on of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 1 to 2% add-on of silver chloride based compound, silver chloride in aluminosilicate carrier base, 1 to 2% add-on of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by exhaust process at mildly acidic condition followed by heat treatment polymerization at between 130° C. and 135° C., which imparts antimicrobial property to textile substrate across the entire cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • Cross linker 2 to 18 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 18 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at between 120° C. and 140° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety to add UV reflecting and water repellant treatment.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 20 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at between 120° C. and 150° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety for other functionality finishes.
  • 0.5 to 2% add-on of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 1 to 2% add-on of silver chloride based compound, silver chloride in aluminosilicate carrier base, 1 to 2% add-on of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by exhaust process at mildly acidic condition followed by heat treatment polymerization at between 120° C. and 130° C., which imparts antimicrobial property to textile substrate across the entire cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 20 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at between 120° C. and 150° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety to other functionality finishes.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 20 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at between 120° C. and 150° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety to other functionality finishes.
  • 0.5 to 2% add-on of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 1 to 2% add-on of silver chloride based compound, silver chloride in aluminosilicate carrier base, 1 to 2% add-on of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by exhaust process at mildly acidic condition followed by heat treatment polymerization at between 130° C. and 160° C., which imparts antimicrobial property to textile substrate across the entire cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 20 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at between 120° C. and 150° C., which gets bonded to the textile substrate from both sides and creates the functionality necessary for addition of the flame retardant treatment.
  • 10 to 50 g/l of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 10 to 50 g/l of silver chloride based compound, silver chloride in aluminosilicate carrier base, 10 to 50 g/l of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by pad impregnation method with 60 to 80% wet pickup at mildly acidic condition followed by heat treatment polymerization at between 130° C. and 160° C., which imparts antimicrobial property to textile substrate across the cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 20 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at between 120° C. and 150° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety to apply the desired finish.
  • 10 to 50 g/l of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 10 to 50 g/l of silver chloride based compound, silver chloride in aluminosilicate carrier base, 10 to 50 g/l of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by spraying method with 60 to 80% wet pickup at mildly acidic condition followed by heat treatment polymerization at between 120° C. and 150° C., which imparts antimicrobial property to textile substrate across the cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 0.5 to 2% add-on of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 1 to 2% add-on of silver chloride based compound, silver chloride in aluminosilicate carrier base, 1 to 2% add-on of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by exhaust process at mildly acidic condition followed by heat treatment polymerization at between 130° C. and 150° C., which imparts antimicrobial property to textile substrate across the entire cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 20 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at between 110° C. to 160° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety to other functionality finishes.
  • 20 to 50 g/l of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 20 to 50 g/ln of silver chloride based compound, silver chloride in aluminosilicate carrier base, and 20 to 50 g/l polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by pad impregnation method with 60% to 80% wet pickup at mildly acidic condition followed by heat treatment polymerization at between 120° C. and 140° C., which imparts antimicrobial property to textile substrate across the cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 0.5 to 2% add-on of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 1 to 2% add-on of Aver chloride based compound, silver chloride in aluminosilicate carrier base, and 1 to 2% polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by exhaust process at mildly acidic condition followed by heat treatment polymerization at between 110° C. and 150° C., which imparts antimicrobial property to textile substrate across the entire cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 20 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at between 120° C. and 150° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety for adding any other required treatment finishes.
  • 0.5 to 2% add-on of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 1 to 2% add-on of silver chloride based compound, silver chloride in aluminosilicate carrier base, 1 to 2% add-on of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by exhaust process at mildly acidic condition followed by heat treatment polymerization at between 130° C. and 135° C., which imparts antimicrobial property to textile substrate across the entire cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 5 to 20 gm/lit of blocked isocyanate based thermoplastic polymer dispersion and 1 to 20 gm/lit thiabendazole, 5 to 20 gm/lit of poly-glucosamine oligosaccharide are applied onto the above antimicrobially treated textile substrate at 120° C. to 150° C., which gets bonded to the textile substrate from both sides and creates the reactant moiety to add abrasion resistant treatment.
  • 10 to 40 g/l of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 10 to 40 g/l of silver chloride based compound, silver chloride in aluminosilicate carrier base, and 10 to 40 g/l of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by spraying method at mildly acidic condition followed by heat treatment polymerization at between 130° C. and 145° C., which imparts antimicrobial property to textile substrate across the cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 20 to 50 g/l of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 20 to 50 g/l of silver chloride based compound, silver chloride in aluminosilicate carrier base, are applied onto the textile substrate through aqueous media by pad impregnation method with 60% to 80% wet pickup at mildly acidic condition followed by heat treatment polymerization at between 130° C. and 145° C., which imparts antimicrobial property to textile substrate across the cross section which displays disinfectant like qualities along with mildly hydrophobic performance.
  • 0.5 to 2% add-on of octadecylaminomethyl trihydroxysilylpropyl ammonium chloride, 1 to 2% add-on of silver chloride based compound, silver chloride in aluminosilicate carrier base, 1 to 2% add-on of polyhexamethylene biguanide are applied onto the textile substrate through aqueous media by coating process at mildly acidic condition followed by heat treatment polymerization at between 110° C. to 140° C., which imparts antimicrobial property to textile substrate across the entire cross section which displays disinfectant like qualities along with mildly hydrophobic performance.

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US16/752,564 US11134686B2 (en) 2013-08-29 2020-01-24 Disinfectant composition for textile and related substrates, and method of treating a substrate to provide disinfecting antibacterial, antiviral and antifungal, wash durable, optionally enhanced with multifunctional properties
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